Articles | Volume 19, issue 2
https://doi.org/10.5194/acp-19-1357-2019
https://doi.org/10.5194/acp-19-1357-2019
Research article
 | 
01 Feb 2019
Research article |  | 01 Feb 2019

Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze

Shaojie Song, Meng Gao, Weiqi Xu, Yele Sun, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. Jacob, and Michael B. McElroy

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Cited articles

Barnes, I., Hjorth, J., and Mihalopoulos, N.: Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere, Chem. Rev., 106, 940–975, https://doi.org/10.1021/cr020529+, 2006. 
Boyce, S. D. and Hoffmann, M. R.: Kinetics and mechanism of the formation of hydroxymethanesulfonic acid at low pH, J. Phys. Chem., 88, 4740–4746, https://doi.org/10.1021/j150664a059, 1984. 
Cai, W., Li, K., Liao, H., Wang, H., and Wu, L.: Weather conditions conducive to Beijing severe haze more frequent under climate change, Nat. Clim. Change., 7, 257–262, https://doi.org/10.1038/nclimate3249, 2017. 
Cao, J., Wang, Q., Chow, J. C., Watson, J. G., Tie, X., Shen, Z., Wang, P., and An, Z.: Impacts of aerosol compositions on visibility impairment in Xi'an, China, Atmos. Environ., 59, 559–566, https://doi.org/10.1016/j.atmosenv.2012.05.036, 2012. 
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Short summary
Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).
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