Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze

Song, Shaojie; Gao, Meng; Xu, Weiqi; Sun, Yele; Worsnop, Douglas R.; Jayne, John T.; Zhang, Yuzhong; Zhu, Lei; Li, Mei; Zhou, Zhen; Cheng, Chunlei; Lv, Yibing; Wang, Ying; Peng, Wei; Xu, Xiaobin; Lin, Nan; Wang, Yuxuan; Wang, Shuxiao; Munger, J. William; Jacob, Daniel J.; McElroy, Michael B.

doi:https://doi.org/10.5194/acp-19-1357-2019

Articles | Volume 19, issue 2

https://doi.org/10.5194/acp-19-1357-2019

© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Special issue:

Multiphase chemistry of secondary aerosol formation under...

https://doi.org/10.5194/acp-19-1357-2019

© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Articles | Volume 19, issue 2

Research article

|

01 Feb 2019

Research article |

| 01 Feb 2019

Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze

Shaojie Song, Meng Gao, Weiqi Xu, Yele Sun, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. Jacob, and Michael B. McElroy

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Interactive discussion

Status: closed

AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment

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RC1: 'Interesting and comprehensive analysis of HMS contributions to Beijing haze', Jeffrey Collett, 27 Nov 2018
SC1: 'Hydroxymethanesulfonate (HMS) in China - Additional Evidence from size distribution retrievals', Thomas Eck, 29 Nov 2018
RC2: 'Possible heterogeneous hydroxymethanesulfonate (HMS) chemistry in northern China winter haze and implications for rapid sulfate formation', Anonymous Referee #2, 04 Jan 2019
AC1: 'Author responses', Shaojie Song, 12 Jan 2019

Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision

AR by Shaojie Song on behalf of the Authors (12 Jan 2019) Author's response Manuscript

ED: Publish as is (19 Jan 2019) by Aijun Ding

AR by Shaojie Song on behalf of the Authors (19 Jan 2019)

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Short summary

Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).