Articles | Volume 19, issue 2
https://doi.org/10.5194/acp-19-1357-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-1357-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Possible heterogeneous chemistry of hydroxymethanesulfonate (HMS) in northern China winter haze
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
Weiqi Xu
State Key Laboratory of Atmospheric Boundary Physics and Atmospheric
Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences,
Beijing 100029, China
College of Earth Sciences, University of Chinese Academy of Sciences,
Beijing 100049, China
State Key Laboratory of Atmospheric Boundary Physics and Atmospheric
Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences,
Beijing 100029, China
College of Earth Sciences, University of Chinese Academy of Sciences,
Beijing 100049, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Douglas R. Worsnop
Aerodyne Research, Inc., Billerica, MA 01821, USA
John T. Jayne
Aerodyne Research, Inc., Billerica, MA 01821, USA
Yuzhong Zhang
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
Mei Li
Institute of Mass Spectrometer and Atmospheric Environment, Jinan
University, Guangzhou 510632, China
Guangdong Provincial Engineering Research Center for Online Source
Apportionment System of Air Pollution, Guangzhou 510632, China
Zhen Zhou
Institute of Mass Spectrometer and Atmospheric Environment, Jinan
University, Guangzhou 510632, China
Guangdong Provincial Engineering Research Center for Online Source
Apportionment System of Air Pollution, Guangzhou 510632, China
Chunlei Cheng
Institute of Mass Spectrometer and Atmospheric Environment, Jinan
University, Guangzhou 510632, China
Guangdong Provincial Engineering Research Center for Online Source
Apportionment System of Air Pollution, Guangzhou 510632, China
Yibing Lv
China National Environmental Monitoring Center, Beijing 100012, China
Ying Wang
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences,
Beijing 100081, China
Wei Peng
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences,
Beijing 100081, China
Xiaobin Xu
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences,
Beijing 100081, China
Nan Lin
Department of Earth System Science, Tsinghua University, Beijing
100084, China
Yuxuan Wang
Department of Earth and Atmospheric Sciences, University of Houston,
Houston, TX 77004, USA
Shuxiao Wang
School of Environment, Tsinghua University, Beijing 100084, China
J. William Munger
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
Daniel J. Jacob
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
Michael B. McElroy
CORRESPONDING AUTHOR
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
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- Enhancing Seasonal PM2.5 Estimations in China through Terrain–Wind–Rained Index (TWRI): A Geographically Weighted Regression Approach B. Peng et al. 10.3390/rs16122145
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- A critical review of sulfate aerosol formation mechanisms during winter polluted periods C. Ye et al. 10.1016/j.jes.2022.07.011
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- The importance of hydroxymethanesulfonate (HMS) in winter haze episodes in North China Plain C. Chen et al. 10.1016/j.envres.2022.113093
- Can we reach consensus on the dominant sulfate formation pathway in China's haze? M. Liu et al. 10.1093/pnasnexus/pgae291
- Review of online source apportionment research based on observation for ambient particulate matter F. Wang et al. 10.1016/j.scitotenv.2020.144095
- Distinct diurnal chemical compositions and formation processes of individual organic-containing particles in Beijing winter T. Ma et al. 10.1016/j.envpol.2022.120846
- Sulfate Formation Apportionment during Winter Haze Events in North China T. Wang et al. 10.1021/acs.est.2c02533
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- Effects of NO<sub>2</sub> and C<sub>3</sub>H<sub>6</sub> on the heterogeneous oxidation of SO<sub>2</sub> on TiO<sub>2</sub> in the presence or absence of UV–Vis irradiation B. Chu et al. 10.5194/acp-19-14777-2019
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Short summary
Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).
Chemistry responsible for sulfate production in northern China winter haze remains mysterious....
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