Articles | Volume 18, issue 10
https://doi.org/10.5194/acp-18-7287-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-7287-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 May 2018
Research article |
| 25 May 2018
| 25 May 2018
Simulation of fine organic aerosols in the western Mediterranean area during the ChArMEx 2013 summer campaign
Arineh Cholakian
CORRESPONDING AUTHOR
Laboratoire Inter-Universitaire des Systèmes Atmosphériques
(LISA), UMR CNRS 7583, Université Paris Est Créteil et Université
Paris Diderot, Institut Pierre Simon Laplace, Créteil, France
Institut National de l'Environnement Industriel et des Risques,
Parc Technologique ALATA, Verneuil-en-Halatte, France
Matthias Beekmann
Laboratoire Inter-Universitaire des Systèmes Atmosphériques
(LISA), UMR CNRS 7583, Université Paris Est Créteil et Université
Paris Diderot, Institut Pierre Simon Laplace, Créteil, France
Augustin Colette
Institut National de l'Environnement Industriel et des Risques,
Parc Technologique ALATA, Verneuil-en-Halatte, France
Isabelle Coll
Laboratoire Inter-Universitaire des Systèmes Atmosphériques
(LISA), UMR CNRS 7583, Université Paris Est Créteil et Université
Paris Diderot, Institut Pierre Simon Laplace, Créteil, France
Guillaume Siour
Laboratoire Inter-Universitaire des Systèmes Atmosphériques
(LISA), UMR CNRS 7583, Université Paris Est Créteil et Université
Paris Diderot, Institut Pierre Simon Laplace, Créteil, France
Jean Sciare
Laboratoire
des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
The
Cyprus Institute, Energy, Environment and Water Research Center, Nicosia,
Cyprus
Nicolas Marchand
Aix-Marseille
Université, CNRS, LCE FRE 3416, Marseille, 13331, France
Florian Couvidat
Institut National de l'Environnement Industriel et des Risques,
Parc Technologique ALATA, Verneuil-en-Halatte, France
Jorge Pey
Aix-Marseille
Université, CNRS, LCE FRE 3416, Marseille, 13331, France
now at: the Spanish Geological Survey, IGME, 50006
Zaragoza, Spain
Valerie Gros
Laboratoire
des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
Stéphane Sauvage
IMT Lille Douai, Univ. Lille, Département Sciences de
l'Atmosphère et Génie de l'Environnement, 59000 Lille, France
Vincent Michoud
IMT Lille Douai, Univ. Lille, Département Sciences de
l'Atmosphère et Génie de l'Environnement, 59000 Lille, France
now at: Laboratoire Inter-Universitaire des
Systèmes Atmosphériques (LISA), UMR CNRS 7583, Université Paris
Est, France
Karine Sellegri
LAMP, Campus universitaire des Cezeaux, 4 Avenue Blaise Pascal,
63178 Aubière, France
Aurélie Colomb
LAMP, Campus universitaire des Cezeaux, 4 Avenue Blaise Pascal,
63178 Aubière, France
Karine Sartelet
CEREA, Joint Laboratory École des Ponts
ParisTech – EDF R and D, Université Paris-Est, 77455 Marne la
Vallée, France
Helen Langley DeWitt
Aix-Marseille
Université, CNRS, LCE FRE 3416, Marseille, 13331, France
Miriam Elser
Paul Scherrer Institute, 5232 Villigen – PSI,
Switzerland
now at: Laboratory for Advanced Analytical
Technologies, Empa, Dübendorf, 8600, Switzerland
André S. H. Prévot
Paul Scherrer Institute, 5232 Villigen – PSI,
Switzerland
Sonke Szidat
University of Bern, Freiestrasse 3, 3012 Bern,
Switzerland
François Dulac
Laboratoire
des Sciences du Climat et de l'Environnement, LSCE/IPSL,
CEA-CNRS-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
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Long-term (2015–2021) quasi-continuous measurements have been obtained at 13 French urban sites using online mass spectrometry, to acquire the comprehensive chemical composition of submicron particulate matter. The results show their spatial and temporal differences and confirm the predominance of organics in France (40–60 %). These measurements can be used for many future studies, such as trend and epidemiological analyses, or comparisons with chemical transport models.
Imad El Haddad, Danielle Vienneau, Kaspar R. Daellenbach, Robin Modini, Jay G. Slowik, Abhishek Upadhyay, Petros N. Vasilakos, David Bell, Kees de Hoogh, and Andre S. H. Prevot
Atmos. Chem. Phys., 24, 11981–12011, https://doi.org/10.5194/acp-24-11981-2024, https://doi.org/10.5194/acp-24-11981-2024, 2024
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This opinion paper explores how advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution. We advocate for a shift in the way we target PM pollution, focusing on the most harmful anthropogenic emissions. We highlight key observations, modelling developments, and emission measurements needed to achieve this shift.
Lise Le Berre, Brice Temime-Roussel, Grazia Maria Lanzafame, Barbara D’Anna, Nicolas Marchand, Stéphane Sauvage, Marvin Dufresne, Liselotte Tinel, Thierry Leonardis, Joel Ferreira de Brito, Alexandre Armengaud, Grégory Gille, Ludovic Lanzi, Romain Bourjot, and Henri Wortham
EGUsphere, https://doi.org/10.5194/egusphere-2024-2903, https://doi.org/10.5194/egusphere-2024-2903, 2024
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A summer campaign in a Mediterranean port examined pollution caused by ships. Two stations in the port measured pollution levels and captured over 350 ship plumes to study their chemical composition. Results showed that pollution levels, like ultra-fine particles, were higher in the port than in the city and offer a strong support to improve emission inventories. These findings may also serve as reference for assessing the benefits of a Sulphur Emission Control Area in the Mediterranean in 2025.
Matthieu Vida, Gilles Foret, Guillaume Siour, Florian Couvidat, Olivier Favez, Gaelle Uzu, Arineh Cholakian, Sébastien Conil, Matthias Beekmann, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 24, 10601–10615, https://doi.org/10.5194/acp-24-10601-2024, https://doi.org/10.5194/acp-24-10601-2024, 2024
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We simulate 2 years of atmospheric fungal spores over France and use observations of polyols and primary biogenic factors from positive matrix factorisation. The representation of emissions taking into account a proxy for vegetation surface and specific humidity enables us to reproduce very accurately the seasonal cycle of fungal spores. Furthermore, we estimate that fungal spores can account for 20 % of PM10 and 40 % of the organic fraction of PM10 over vegetated areas in summer.
Ludovico Di Antonio, Matthias Beekmann, Guillaume Siour, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Joel F. de Brito, Paola Formenti, Cecile Gaimoz, Olivier Garret, Aline Gratien, Valérie Gros, Martial Haeffelin, Lelia N. Hawkins, Simone Kotthaus, Gael Noyalet, Diana Pereira, Jean-Eudes Petit, Eva Drew Pronovost, Véronique Riffault, Chenjie Yu, Gilles Foret, Jean-François Doussin, and Claudia Di Biagio
EGUsphere, https://doi.org/10.5194/egusphere-2024-2175, https://doi.org/10.5194/egusphere-2024-2175, 2024
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Summer 2022 has been considered a proxy for future climate scenarios, given the registered hot and dry conditions. In this paper, we used the measurements from the ACROSS campaign, occurred over the Paris area in June–July 2022, in addition to observations from existing networks, to evaluate the WRF–CHIMERE model simulation over France and the Ile-de-France regions. Results over the Ile–de–France show to be satisfactory, allowing to explain the gas and aerosol variability at the ACROSS sites.
Pierre Tulet, Joel Van Baelen, Pierre Bosser, Jérome Brioude, Aurélie Colomb, Philippe Goloub, Andrea Pazmino, Thierry Portafaix, Michel Ramonet, Karine Sellegri, Melilotus Thyssen, Léa Gest, Nicolas Marquestaut, Dominique Mékiès, Jean-Marc Metzger, Gilles Athier, Luc Blarel, Marc Delmotte, Guillaume Desprairies, Mérédith Dournaux, Gaël Dubois, Valentin Duflot, Kevin Lamy, Lionel Gardes, Jean-François Guillemot, Valérie Gros, Joanna Kolasinski, Morgan Lopez, Olivier Magand, Erwan Noury, Manuel Nunes-Pinharanda, Guillaume Payen, Joris Pianezze, David Picard, Olivier Picard, Sandrine Prunier, François Rigaud-Louise, Michael Sicard, and Benjamin Torres
Earth Syst. Sci. Data, 16, 3821–3849, https://doi.org/10.5194/essd-16-3821-2024, https://doi.org/10.5194/essd-16-3821-2024, 2024
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The MAP-IO program aims to compensate for the lack of atmospheric and oceanographic observations in the Southern Ocean by equipping the ship Marion Dufresne with a set of 17 scientific instruments. This program collected 700 d of measurements under different latitudes, seasons, sea states, and weather conditions. These new data will support the calibration and validation of numerical models and the understanding of the atmospheric composition of this region of Earth.
Oscar Jacquot and Karine Sartelet
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-150, https://doi.org/10.5194/gmd-2024-150, 2024
Revised manuscript under review for GMD
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As the health impact of ultrafine particles is better understood, modeling the size distribution and the number concentration becomes increasingly important. A new analytic formulation is presented to compute coagulation partition coefficients, allowing to lower down the numerical diffusion associated to the resolution of aerosol dynamics. The significance of this effect is assessed over Greater Paris with a chemistry transport model, using different size resolution of the particle distribution.
Victor Lannuque and Karine Sartelet
Atmos. Chem. Phys., 24, 8589–8606, https://doi.org/10.5194/acp-24-8589-2024, https://doi.org/10.5194/acp-24-8589-2024, 2024
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation and speciation from naphthalene oxidation. This study details the development of the first near-explicit chemical scheme for naphthalene oxidation by OH, which includes kinetic and mechanistic data, and is able to reproduce most of the experimentally identified products in both gas and particle phases.
Robin Plauchu, Audrey Fortems-Cheiney, Grégoire Broquet, Isabelle Pison, Antoine Berchet, Elise Potier, Gaëlle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, and Henk Eskes
Atmos. Chem. Phys., 24, 8139–8163, https://doi.org/10.5194/acp-24-8139-2024, https://doi.org/10.5194/acp-24-8139-2024, 2024
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This study uses the Community Inversion Framework and CHIMERE model to assess the potential of TROPOMI-S5P PAL NO2 tropospheric column data to estimate NOx emissions in France (2019–2021). Results show a 3 % decrease in average emissions compared to the 2016 CAMS-REG/INS, lower than the 14 % decrease from CITEPA. The study highlights challenges in capturing emission anomalies due to limited data coverage and error levels but shows promise for local inventory improvements.
Laurent Menut, Arineh Cholakian, Romain Pennel, Guillaume Siour, Sylvain Mailler, Myrto Valari, Lya Lugon, and Yann Meurdesoif
Geosci. Model Dev., 17, 5431–5457, https://doi.org/10.5194/gmd-17-5431-2024, https://doi.org/10.5194/gmd-17-5431-2024, 2024
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A new version of the CHIMERE model is presented. This version contains both computational and physico-chemical changes. The computational changes make it easy to choose the variables to be extracted as a result, including values of maximum sub-hourly concentrations. Performance tests show that the model is 1.5 to 2 times faster than the previous version for the same setup. Processes such as turbulence, transport schemes and dry deposition have been modified and updated.
Ashutosh Kumar Shukla, Sachchida Nand Tripathi, Shamitaksha Talukdar, Vishnu Murari, Sreenivas Gaddamidi, Manousos-Ioannis Manousakas, Vipul Lalchandani, Kuldeep Dixit, Vinayak M Ruge, Peeyush Khare, Mayank Kumar, Vikram Singh, Neeraj Rastogi, Suresh Tiwari, Atul K. Srivastava, Dilip Ganguly, Kaspar Rudolf Daellenbach, and Andre Stephan Henry Prevot
EGUsphere, https://doi.org/10.5194/egusphere-2024-1385, https://doi.org/10.5194/egusphere-2024-1385, 2024
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Our study delves into the elemental composition of aerosols across the Indo-Gangetic Plain (IGP), revealing distinct patterns during pollution episodes. We found significant increases in Cl-rich and SFC1 sources, indicating dynamic emissions and agricultural burning impacts. Surges in Cl-rich particles during cold periods highlight their role in particle growth under specific conditions.
Alice Maison, Lya Lugon, Soo-Jin Park, Alexia Baudic, Christopher Cantrell, Florian Couvidat, Barbara D'Anna, Claudia Di Biagio, Aline Gratien, Valérie Gros, Carmen Kalalian, Julien Kammer, Vincent Michoud, Jean-Eudes Petit, Marwa Shahin, Leila Simon, Myrto Valari, Jérémy Vigneron, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 24, 6011–6046, https://doi.org/10.5194/acp-24-6011-2024, https://doi.org/10.5194/acp-24-6011-2024, 2024
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This study presents the development of a bottom-up inventory of urban tree biogenic emissions. Emissions are computed for each tree based on their location and characteristics and are integrated in the regional air quality model WRF-CHIMERE. The impact of these biogenic emissions on air quality is quantified for June–July 2022. Over Paris city, urban trees increase the concentrations of particulate organic matter by 4.6 %, of PM2.5 by 0.6 %, and of ozone by 1.0 % on average over 2 months.
Laurent Menut, Bertrand Bessagnet, Arineh Cholakian, Guillaume Siour, Sylvain Mailler, and Romain Pennel
Geosci. Model Dev., 17, 3645–3665, https://doi.org/10.5194/gmd-17-3645-2024, https://doi.org/10.5194/gmd-17-3645-2024, 2024
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This study is about the modelling of the atmospheric composition in Europe during the summer of 2022, when massive wildfires were observed. It is a sensitivity study dedicated to the relative impacts of two modelling processes that are able to modify the meteorology used for the calculation of the atmospheric chemistry and transport of pollutants.
Maud Leriche, Pierre Tulet, Laurent Deguillaume, Frédéric Burnet, Aurélie Colomb, Agnès Borbon, Corinne Jambert, Valentin Duflot, Stéphan Houdier, Jean-Luc Jaffrezo, Mickaël Vaïtilingom, Pamela Dominutti, Manon Rocco, Camille Mouchel-Vallon, Samira El Gdachi, Maxence Brissy, Maroua Fathalli, Nicolas Maury, Bert Verreyken, Crist Amelynck, Niels Schoon, Valérie Gros, Jean-Marc Pichon, Mickael Ribeiro, Eric Pique, Emmanuel Leclerc, Thierry Bourrianne, Axel Roy, Eric Moulin, Joël Barrie, Jean-Marc Metzger, Guillaume Péris, Christian Guadagno, Chatrapatty Bhugwant, Jean-Mathieu Tibere, Arnaud Tournigand, Evelyn Freney, Karine Sellegri, Anne-Marie Delort, Pierre Amato, Muriel Joly, Jean-Luc Baray, Pascal Renard, Angelica Bianco, Anne Réchou, and Guillaume Payen
Atmos. Chem. Phys., 24, 4129–4155, https://doi.org/10.5194/acp-24-4129-2024, https://doi.org/10.5194/acp-24-4129-2024, 2024
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Aerosol particles in the atmosphere play a key role in climate change and air pollution. A large number of aerosol particles are formed from the oxidation of volatile organic compounds (VOCs and secondary organic aerosols – SOA). An important field campaign was organized on Réunion in March–April 2019 to understand the formation of SOA in a tropical atmosphere mostly influenced by VOCs emitted by forest and in the presence of clouds. This work synthesizes the results of this campaign.
Julie Camman, Benjamin Chazeau, Nicolas Marchand, Amandine Durand, Grégory Gille, Ludovic Lanzi, Jean-Luc Jaffrezo, Henri Wortham, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 3257–3278, https://doi.org/10.5194/acp-24-3257-2024, https://doi.org/10.5194/acp-24-3257-2024, 2024
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Fine particle (PM1) pollution is a major health issue in the city of Marseille, which is subject to numerous pollution sources. Sampling carried out during the summer enabled a fine characterization of the PM1 sources and their oxidative potential, a promising new metric as a proxy for health impact. PM1 came mainly from combustion sources, secondary ammonium sulfate, and organic nitrate, while the oxidative potential of PM1 came from these sources and from resuspended dust in the atmosphere.
Adrien Deroubaix, Marco Vountas, Benjamin Gaubert, Maria Dolores Andrés Hernández, Stephan Borrmann, Guy Brasseur, Bruna Holanda, Yugo Kanaya, Katharina Kaiser, Flora Kluge, Ovid Oktavian Krüger, Inga Labuhn, Michael Lichtenstern, Klaus Pfeilsticker, Mira Pöhlker, Hans Schlager, Johannes Schneider, Guillaume Siour, Basudev Swain, Paolo Tuccella, Kameswara S. Vinjamuri, Mihalis Vrekoussis, Benjamin Weyland, and John P. Burrows
EGUsphere, https://doi.org/10.5194/egusphere-2024-516, https://doi.org/10.5194/egusphere-2024-516, 2024
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This study assesses atmospheric composition using air quality models during aircraft campaigns in Europe and Asia, focusing on carbonaceous aerosols and trace gases. While carbon monoxide is well modeled, other pollutants have moderate to weak agreement with observations. Wind speed modeling is reliable for identifying pollution plumes, where models tend to overestimate concentrations. This highlights challenges in accurately modeling aerosol and trace gas composition, particularly in cities.
Adrien Deroubaix, Marco Vountas, Benjamin Gaubert, Maria Dolores Andrés Hernández, Stephan Borrmann, Guy Brasseur, Bruna Holanda, Yugo Kanaya, Katharina Kaiser, Flora Kluge, Ovid Oktavian Krüger, Inga Labuhn, Michael Lichtenstern, Klaus Pfeilsticker, Mira Pöhlker, Hans Schlager, Johannes Schneider, Guillaume Siour, Basudev Swain, Paolo Tuccella, Kameswara S. Vinjamuri, Mihalis Vrekoussis, Benjamin Weyland, and John P. Burrows
EGUsphere, https://doi.org/10.5194/egusphere-2024-521, https://doi.org/10.5194/egusphere-2024-521, 2024
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This study explores the proportional relationships between carbonaceous aerosols (black and organic carbon) and trace gases using airborne measurements from two campaigns in Europe and East Asia. Differences between regions were found, but air quality models struggled to reproduce them accurately. We show that these proportional relationships can help to constrain models and can be used to infer aerosol concentrations from satellite observations of trace gases, especially in urban areas.
Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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We discuss carbonaceous aerosol (CA) observed at the high Arctic Zeppelin Observatory (2017 to 2020). We find that organic aerosol is a significant fraction of the Arctic aerosol, though less than sea salt aerosol and mineral dust, as well as non-sea-salt sulfate, originating mainly from anthropogenic sources in winter and from natural sources in summer, emphasizing the importance of wildfires for biogenic secondary organic aerosol and primary biological aerosol particles observed in the Arctic.
Evangelia Kostenidou, Baptiste Marques, Brice Temime-Roussel, Yao Liu, Boris Vansevenant, Karine Sartelet, and Barbara D'Anna
Atmos. Chem. Phys., 24, 2705–2729, https://doi.org/10.5194/acp-24-2705-2024, https://doi.org/10.5194/acp-24-2705-2024, 2024
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Secondary organic aerosol (SOA) from gasoline vehicles can be a significant source of particulate matter in urban areas. Here the chemical composition of secondary volatile organic compounds and SOA produced by photo-oxidation of Euro 5 gasoline vehicle emissions was studied. The volatility of the SOA formed was calculated. Except for the temperature and the concentration of the aerosol, additional parameters may play a role in the gas-to-particle partitioning.
Arto Heitto, Cheng Wu, Diego Aliaga, Luis Blacutt, Xuemeng Chen, Yvette Gramlich, Liine Heikkinen, Wei Huang, Radovan Krejci, Paolo Laj, Isabel Moreno, Karine Sellegri, Fernando Velarde, Kay Weinhold, Alfred Wiedensohler, Qiaozhi Zha, Federico Bianchi, Marcos Andrade, Kari E. J. Lehtinen, Claudia Mohr, and Taina Yli-Juuti
Atmos. Chem. Phys., 24, 1315–1328, https://doi.org/10.5194/acp-24-1315-2024, https://doi.org/10.5194/acp-24-1315-2024, 2024
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Particle growth at the Chacaltaya station in Bolivia was simulated based on measured vapor concentrations and ambient conditions. Major contributors to the simulated growth were low-volatility organic compounds (LVOCs). Also, sulfuric acid had major role when volcanic activity was occurring in the area. This study provides insight on nanoparticle growth at this high-altitude Southern Hemispheric site and hence contributes to building knowledge of early growth of atmospheric particles.
Pauline Buysse, Benjamin Loubet, Raluca Ciuraru, Florence Lafouge, Brigitte Durand, Olivier Zurfluh, Céline Décuq, Olivier Fanucci, Lais Gonzaga Gomez, Jean-Christophe Gueudet, Sandy Bsaibes, Nora Zannoni, and Valérie Gros
EGUsphere, https://doi.org/10.5194/egusphere-2023-2438, https://doi.org/10.5194/egusphere-2023-2438, 2024
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This research aimed at quantifying biogenic volatile organic compounds (BVOCs) emissions by a rapeseed crop field. Such compounds are precursors of atmospheric pollutants. Our study revealed that methanol, a BVOC that is not very reactive in the atmosphere, is by far the most emitted BVOC, while monoterpenes, being highly reactive, were emitted in larger quantities than expected. Our study therefore points out the potentially more significant contribution of croplands to atmospheric pollution.
Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet
Atmos. Chem. Phys., 23, 15537–15560, https://doi.org/10.5194/acp-23-15537-2023, https://doi.org/10.5194/acp-23-15537-2023, 2023
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
Jun Zhang, Kun Li, Tiantian Wang, Erlend Gammelsæter, Rico K. Y. Cheung, Mihnea Surdu, Sophie Bogler, Deepika Bhattu, Dongyu S. Wang, Tianqu Cui, Lu Qi, Houssni Lamkaddam, Imad El Haddad, Jay G. Slowik, Andre S. H. Prevot, and David M. Bell
Atmos. Chem. Phys., 23, 14561–14576, https://doi.org/10.5194/acp-23-14561-2023, https://doi.org/10.5194/acp-23-14561-2023, 2023
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We conducted burning experiments to simulate various types of solid fuel combustion, including residential burning, wildfires, agricultural burning, cow dung, and plastic bag burning. The chemical composition of the particles was characterized using mass spectrometers, and new potential markers for different fuels were identified using statistical analysis. This work improves our understanding of emissions from solid fuel burning and offers support for refined source apportionment.
Sudip Acharya, Maximilian Prochnow, Thomas Kasper, Linda Langhans, Peter Frenzel, Paul Strobel, Marcel Bliedtner, Gerhard Daut, Christopher Berndt, Sönke Szidat, Gary Salazar, Antje Schwalb, and Roland Zech
E&G Quaternary Sci. J., 72, 219–234, https://doi.org/10.5194/egqsj-72-219-2023, https://doi.org/10.5194/egqsj-72-219-2023, 2023
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This study presents a palaeoenvironmental record from Lake Höglwörth, Bavaria, Germany. Before 870 CE peat deposits existed. Erosion increased from 1240 to 1380 CE, followed by aquatic productivity and anoxia from 1310 to 1470 CE. Increased allochthonous input and a substantial shift in the aquatic community in 1701 were caused by construction of a mill. Recent anoxia has been observed since the 1960s.
Anthony Rey-Pommier, Frédéric Chevallier, Philippe Ciais, Jonilda Kushta, Theodoros Christoudias, I. Safak Bayram, and Jean Sciare
Atmos. Chem. Phys., 23, 13565–13583, https://doi.org/10.5194/acp-23-13565-2023, https://doi.org/10.5194/acp-23-13565-2023, 2023
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We use four years (2019–2022) of TROPOMI NO2 data to map NOx emissions in Qatar. We estimate average monthly emissions for the country and industrial facilities and derive an emission factor for the power sector. Monthly emissions have a weekly cycle reflecting the social norms in Qatar and an annual cycle consistent with the electricity production by gas-fired power plants. Their mean value is lower than the NOx emissions in global inventories but similar to the emissions reported for 2007.
Ludovico Di Antonio, Claudia Di Biagio, Gilles Foret, Paola Formenti, Guillaume Siour, Jean-François Doussin, and Matthias Beekmann
Atmos. Chem. Phys., 23, 12455–12475, https://doi.org/10.5194/acp-23-12455-2023, https://doi.org/10.5194/acp-23-12455-2023, 2023
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Long-term (2000–2021) 1 km resolution satellite data have been used to investigate the climatological aerosol optical depth (AOD) variability and trends at different scales in Europe. Average enhancements of the local-to-regional AOD ratio at 550 nm of 57 %, 55 %, 39 % and 32 % are found for large metropolitan areas such as Barcelona, Lisbon, Paris and Athens, respectively, suggesting a non-negligible enhancement of the aerosol burden through local emissions.
Thibaud Sarica, Alice Maison, Yelva Roustan, Matthias Ketzel, Steen Solvang Jensen, Youngseob Kim, Christophe Chaillou, and Karine Sartelet
Geosci. Model Dev., 16, 5281–5303, https://doi.org/10.5194/gmd-16-5281-2023, https://doi.org/10.5194/gmd-16-5281-2023, 2023
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A new version of the Model of Urban Network of Intersecting Canyons and Highways (MUNICH) is developed to represent heterogeneities of concentrations in streets. The street volume is discretized vertically and horizontally to limit the artificial dilution of emissions and concentrations. This new version is applied to street networks in Copenhagen and Paris. The comparisons to observations are improved, with higher concentrations of pollutants emitted by traffic at the bottom of the street.
Jean-Philippe Putaud, Enrico Pisoni, Alexander Mangold, Christoph Hueglin, Jean Sciare, Michael Pikridas, Chrysanthos Savvides, Jakub Ondracek, Saliou Mbengue, Alfred Wiedensohler, Kay Weinhold, Maik Merkel, Laurent Poulain, Dominik van Pinxteren, Hartmut Herrmann, Andreas Massling, Claus Nordstroem, Andrés Alastuey, Cristina Reche, Noemí Pérez, Sonia Castillo, Mar Sorribas, Jose Antonio Adame, Tuukka Petaja, Katrianne Lehtipalo, Jarkko Niemi, Véronique Riffault, Joel F. de Brito, Augustin Colette, Olivier Favez, Jean-Eudes Petit, Valérie Gros, Maria I. Gini, Stergios Vratolis, Konstantinos Eleftheriadis, Evangelia Diapouli, Hugo Denier van der Gon, Karl Espen Yttri, and Wenche Aas
Atmos. Chem. Phys., 23, 10145–10161, https://doi.org/10.5194/acp-23-10145-2023, https://doi.org/10.5194/acp-23-10145-2023, 2023
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Many European people are still exposed to levels of air pollution that can affect their health. COVID-19 lockdowns in 2020 were used to assess the impact of the reduction in human mobility on air pollution across Europe by comparing measurement data with values that would be expected if no lockdown had occurred. We show that lockdown measures did not lead to consistent decreases in the concentrations of fine particulate matter suspended in the air, and we investigate why.
Yong Zhang, Jie Tian, Qiyuan Wang, Lu Qi, Manousos Ioannis Manousakas, Yuemei Han, Weikang Ran, Yele Sun, Huikun Liu, Renjian Zhang, Yunfei Wu, Tianqu Cui, Kaspar Rudolf Daellenbach, Jay Gates Slowik, André S. H. Prévôt, and Junji Cao
Atmos. Chem. Phys., 23, 9455–9471, https://doi.org/10.5194/acp-23-9455-2023, https://doi.org/10.5194/acp-23-9455-2023, 2023
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PM2.5 pollution still frequently occurs in northern China during winter, and it is necessary to figure out the causes of air pollution based on intensive real-time measurement. The findings elaborate the chemical characteristics and source contributions of PM2.5 in three pilot cities, reveal potential formation mechanisms of secondary aerosols, and highlight the importance of controlling biomass burning and inhibiting generation of secondary aerosol for air quality improvement.
Sophie L. Haslett, David M. Bell, Varun Kumar, Jay G. Slowik, Dongyu S. Wang, Suneeti Mishra, Neeraj Rastogi, Atinderpal Singh, Dilip Ganguly, Joel Thornton, Feixue Zheng, Yuanyuan Li, Wei Nie, Yongchun Liu, Wei Ma, Chao Yan, Markku Kulmala, Kaspar R. Daellenbach, David Hadden, Urs Baltensperger, Andre S. H. Prevot, Sachchida N. Tripathi, and Claudia Mohr
Atmos. Chem. Phys., 23, 9023–9036, https://doi.org/10.5194/acp-23-9023-2023, https://doi.org/10.5194/acp-23-9023-2023, 2023
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In Delhi, some aspects of daytime and nighttime atmospheric chemistry are inverted, and parodoxically, vehicle emissions may be limiting other forms of particle production. This is because the nighttime emissions of nitrogen oxide (NO) by traffic and biomass burning prevent some chemical processes that would otherwise create even more particles and worsen the urban haze.
Sachiko Okamoto, Juan Cuesta, Matthias Beekmann, Gaëlle Dufour, Maxim Eremenko, Kazuyuki Miyazaki, Cathy Boonne, Hiroshi Tanimoto, and Hajime Akimoto
Atmos. Chem. Phys., 23, 7399–7423, https://doi.org/10.5194/acp-23-7399-2023, https://doi.org/10.5194/acp-23-7399-2023, 2023
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We present a detailed analysis of the daily evolution of the lowermost tropospheric ozone documented by IASI+GOME2 multispectral satellite observations and that of its precursors from TCR-2 tropospheric chemistry reanalysis. It reveals that the ozone outbreak across Europe in July 2017 was produced during favorable condition for photochemical production of ozone and was associated with multiple sources of ozone precursors: biogenic, anthropogenic, and biomass burning emissions.
Laurent Menut, Arineh Cholakian, Guillaume Siour, Rémy Lapere, Romain Pennel, Sylvain Mailler, and Bertrand Bessagnet
Atmos. Chem. Phys., 23, 7281–7296, https://doi.org/10.5194/acp-23-7281-2023, https://doi.org/10.5194/acp-23-7281-2023, 2023
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This study is about the wildfires occurring in France during the summer 2022. We study the forest fires that took place in the Landes during the summer of 2022. We show the direct impact of these fires on the air quality, especially downstream of the smoke plume towards the Paris region. We quantify the impact of these fires on the pollutants peak concentrations and the possible exceedance of thresholds.
Samira Atabakhsh, Laurent Poulain, Gang Chen, Francesco Canonaco, André S. H. Prévôt, Mira Pöhlker, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 6963–6988, https://doi.org/10.5194/acp-23-6963-2023, https://doi.org/10.5194/acp-23-6963-2023, 2023
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The study focuses on the aerosol chemical variations found in the rural-background station of Melpitz based on ACSM and MAAP measurements. Source apportionment on both organic aerosol (OA) and black carbon (eBC) was performed, and source seasonality was also linked to air mass trajectories. Overall, three anthropogenic sources were identified in OA and eBC plus two additional aged OA. Our results demonstrate the influence of transported coal-combustion-related OA even during summer time.
Leïla Simon, Valérie Gros, Jean-Eudes Petit, François Truong, Roland Sarda-Estève, Carmen Kalalian, Alexia Baudic, Caroline Marchand, and Olivier Favez
Earth Syst. Sci. Data, 15, 1947–1968, https://doi.org/10.5194/essd-15-1947-2023, https://doi.org/10.5194/essd-15-1947-2023, 2023
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Long-term measurements of volatile organic compounds (VOCs) have been set up to better characterize the atmospheric chemistry at the SIRTA national facility (Paris area, France). Results obtained from the first 2 years (2020–2021) confirm the importance of local sources for short-lived compounds and the role played by meteorology and air mass origins in the long-term analysis of VOCs. They also point to a substantial influence of anthropogenic on the monoterpene loadings.
Jean-Maxime Bertrand, Frédérik Meleux, Anthony Ung, Gaël Descombes, and Augustin Colette
Atmos. Chem. Phys., 23, 5317–5333, https://doi.org/10.5194/acp-23-5317-2023, https://doi.org/10.5194/acp-23-5317-2023, 2023
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Post-processing methods based on machine learning algorithms were applied to refine the forecasts of four key pollutants at monitoring sites across Europe. Performances show significant improvements compared to those of the deterministic model raw outputs. Taking advantage of the large modelling domain extension, an innovative
globalapproach is proposed to drastically reduce the period necessary to train the models and thus facilitate the implementation in an operational context.
Manon Rocco, Erin Dunne, Alexia Saint-Macary, Maija Peltola, Theresa Barthelmeß, Neill Barr, Karl Safi, Andrew Marriner, Stacy Deppeler, James Harnwell, Anja Engel, Aurélie Colomb, Alfonso Saiz-Lopez, Mike Harvey, Cliff S. Law, and Karine Sellegri
EGUsphere, https://doi.org/10.5194/egusphere-2023-516, https://doi.org/10.5194/egusphere-2023-516, 2023
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During the Sea2cloud campaign in the Southern Pacific Ocean, we measured air-sea emissions from phytopankton of two key atmospheric compounds: DMS and MeSH. These compounds are well-known to play a great role in atmospheric chemistry and climate. We see in this paper that these compounds are most emited by the nanophytoplankton population. We provide here parameters for climate models to predict future trends of the emissions of these compounds and their roles and impacts on the global warming.
Maija Peltola, Clémence Rose, Jonathan V. Trueblood, Sally Gray, Mike Harvey, and Karine Sellegri
Atmos. Chem. Phys., 23, 3955–3983, https://doi.org/10.5194/acp-23-3955-2023, https://doi.org/10.5194/acp-23-3955-2023, 2023
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We measured the chemical composition of ambient ions at a coastal New Zealand site and connected these data with aerosol size distribution data to study the chemical precursors of new particle formation at the site. Our results showed that iodine oxides and sulfur species were important for particle formation in marine air, while in land-influenced air sulfuric acid and organics were connected to new particle formation events.
Arineh Cholakian, Matthias Beekmann, Guillaume Siour, Isabelle Coll, Manuela Cirtog, Elena Ormeño, Pierre-Marie Flaud, Emilie Perraudin, and Eric Villenave
Atmos. Chem. Phys., 23, 3679–3706, https://doi.org/10.5194/acp-23-3679-2023, https://doi.org/10.5194/acp-23-3679-2023, 2023
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This article revolves around the simulation of biogenic secondary organic aerosols in the Landes forest (southwestern France). Several sensitivity cases involving biogenic emission factors, land cover data, anthropogenic emissions, and physical or meteorological parameters were performed and each compared to measurements both in the forest canopy and around the forest. The chemistry behind the formation of these aerosols and their production and transport in the forest canopy is discussed.
Vaishali Jain, Nidhi Tripathi, Sachchida N. Tripathi, Mansi Gupta, Lokesh K. Sahu, Vishnu Murari, Sreenivas Gaddamidi, Ashutosh K. Shukla, and Andre S. H. Prevot
Atmos. Chem. Phys., 23, 3383–3408, https://doi.org/10.5194/acp-23-3383-2023, https://doi.org/10.5194/acp-23-3383-2023, 2023
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This research chemically characterises 173 different NMVOCs (non-methane volatile organic compounds) measured in real time for three seasons in the city of the central Indo-Gangetic basin of India, Lucknow. Receptor modelling is used to analyse probable sources of NMVOCs and their crucial role in forming ozone and secondary organic aerosols. It is observed that vehicular emissions and solid fuel combustion are the highest contributors to the emission of primary and secondary NMVOCs.
Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
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The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
Martin Rauber, Gary Salazar, Karl Espen Yttri, and Sönke Szidat
Atmos. Meas. Tech., 16, 825–844, https://doi.org/10.5194/amt-16-825-2023, https://doi.org/10.5194/amt-16-825-2023, 2023
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Carbon-containing aerosols from ambient air are analysed for radioactive isotope radiocarbon to determine the contribution from fossil-fuel emissions. Light-absorbing soot-like aerosols are isolated by water extraction and thermal separation. This separation is affected by artefacts, for which we developed a new correction method. The investigation of aerosols from the Arctic shows that our approach works well for such samples, where many artefacts are expected.
Rémy Lapere, Nicolás Huneeus, Sylvain Mailler, Laurent Menut, and Florian Couvidat
Atmos. Chem. Phys., 23, 1749–1768, https://doi.org/10.5194/acp-23-1749-2023, https://doi.org/10.5194/acp-23-1749-2023, 2023
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Glaciers in the Andes of central Chile are shrinking rapidly in response to global warming. This melting is accelerated by the deposition of opaque particles onto snow and ice. In this work, model simulations quantify typical deposition rates of soot on glaciers in summer and winter months and show that the contribution of emissions from Santiago is not as high as anticipated. Additionally, the combination of regional- and local-scale meteorology explains the seasonality in deposition.
Chao Lin, Yunyi Wang, Ryozo Ooka, Cédric Flageul, Youngseob Kim, Hideki Kikumoto, Zhizhao Wang, and Karine Sartelet
Atmos. Chem. Phys., 23, 1421–1436, https://doi.org/10.5194/acp-23-1421-2023, https://doi.org/10.5194/acp-23-1421-2023, 2023
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In this study, SSH-aerosol, a modular box model that simulates the evolution of gas, primary, and secondary aerosols, is coupled with the computational fluid dynamics (CFD) software, OpenFOAM and Code_Saturne. The transient dispersion of pollutants emitted from traffic in a street canyon of Greater Paris is simulated. The coupled model achieved better agreement in NO2 and PM10 with measurement data than the conventional CFD simulation which regards pollutants as passive scalars.
John Douros, Henk Eskes, Jos van Geffen, K. Folkert Boersma, Steven Compernolle, Gaia Pinardi, Anne-Marlene Blechschmidt, Vincent-Henri Peuch, Augustin Colette, and Pepijn Veefkind
Geosci. Model Dev., 16, 509–534, https://doi.org/10.5194/gmd-16-509-2023, https://doi.org/10.5194/gmd-16-509-2023, 2023
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We focus on the challenges associated with comparing atmospheric composition models with satellite products such as tropospheric NO2 columns. The aim is to highlight the methodological difficulties and propose sound ways of doing such comparisons. Building on the comparisons, a new satellite product is proposed and made available, which takes advantage of higher-resolution, regional atmospheric modelling to improve estimates of troposheric NO2 columns over Europe.
Tingting Feng, Yingkun Wang, Weiwei Hu, Ming Zhu, Wei Song, Wei Chen, Yanyan Sang, Zheng Fang, Wei Deng, Hua Fang, Xu Yu, Cheng Wu, Bin Yuan, Shan Huang, Min Shao, Xiaofeng Huang, Lingyan He, Young Ro Lee, Lewis Gregory Huey, Francesco Canonaco, Andre S. H. Prevot, and Xinming Wang
Atmos. Chem. Phys., 23, 611–636, https://doi.org/10.5194/acp-23-611-2023, https://doi.org/10.5194/acp-23-611-2023, 2023
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To investigate the impact of aging processes on organic aerosols (OA), we conducted a comprehensive field study at a continental remote site using an on-line mass spectrometer. The results show that OA in the Chinese outflows were strongly influenced by upwind anthropogenic emissions. The aging processes can significantly decrease the OA volatility and result in a varied viscosity of OA under different circumstances, signifying the complex physiochemical properties of OA in aged plumes.
Yandong Tong, Lu Qi, Giulia Stefenelli, Dongyu Simon Wang, Francesco Canonaco, Urs Baltensperger, André Stephan Henry Prévôt, and Jay Gates Slowik
Atmos. Meas. Tech., 15, 7265–7291, https://doi.org/10.5194/amt-15-7265-2022, https://doi.org/10.5194/amt-15-7265-2022, 2022
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We present a method for positive matrix factorisation (PMF) analysis on a single dataset that includes measurements from both EESI-TOF and AMS in Zurich, Switzerland. For the first time, we resolved and quantified secondary organic aerosol (SOA) sources. Meanwhile, we also determined the retrieved EESI-TOF factor-dependent sensitivities. This method provides a framework for exploiting semi-quantitative, high-resolution instrumentation for quantitative source apportionment.
Zhizhao Wang, Florian Couvidat, and Karine Sartelet
Geosci. Model Dev., 15, 8957–8982, https://doi.org/10.5194/gmd-15-8957-2022, https://doi.org/10.5194/gmd-15-8957-2022, 2022
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Air quality models need to reliably predict secondary organic aerosols (SOAs) at a reasonable computational cost. Thus, we developed GENOA v1.0, a mechanism reduction algorithm that preserves the accuracy of detailed gas-phase chemical mechanisms for SOA formation, thereby improving the practical use of actual chemistry in SOA models. With GENOA, a near-explicit chemical scheme was reduced to 2 % of its original size and computational time, with an average error of less than 3 %.
Mathieu Lachatre, Sylvain Mailler, Laurent Menut, Arineh Cholakian, Pasquale Sellitto, Guillaume Siour, Henda Guermazi, Giuseppe Salerno, and Salvatore Giammanco
Atmos. Chem. Phys., 22, 13861–13879, https://doi.org/10.5194/acp-22-13861-2022, https://doi.org/10.5194/acp-22-13861-2022, 2022
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In this study, we have evaluated the predominance of various pathways of volcanic SO2 conversion to sulfates in the upper troposphere. We show that the main conversion pathway was gaseous oxidation by OH, although the liquid pathways were expected to be predominant. These results are interesting with respect to a better understanding of sulfate formation in the middle and upper troposphere and are an important component to help evaluate particulate matter radiative forcing.
David M. Bell, Cheng Wu, Amelie Bertrand, Emelie Graham, Janne Schoonbaert, Stamatios Giannoukos, Urs Baltensperger, Andre S. H. Prevot, Ilona Riipinen, Imad El Haddad, and Claudia Mohr
Atmos. Chem. Phys., 22, 13167–13182, https://doi.org/10.5194/acp-22-13167-2022, https://doi.org/10.5194/acp-22-13167-2022, 2022
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A series of studies designed to investigate the evolution of organic aerosol were performed in an atmospheric simulation chamber, using a common oxidant found at night (NO3). The chemical composition steadily changed from its initial composition via different chemical reactions that were taking place inside of the aerosol particle. These results show that the composition of organic aerosol steadily changes during its lifetime in the atmosphere.
Youngseob Kim, Lya Lugon, Alice Maison, Thibaud Sarica, Yelva Roustan, Myrto Valari, Yang Zhang, Michel André, and Karine Sartelet
Geosci. Model Dev., 15, 7371–7396, https://doi.org/10.5194/gmd-15-7371-2022, https://doi.org/10.5194/gmd-15-7371-2022, 2022
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This paper presents the latest version of the street-network model MUNICH, v2.0. The description of MUNICH v1.0, which models gas-phase pollutants in a street network, was published in GMD in 2018. Since then, major modifications have been made to MUNICH. The comprehensive aerosol model SSH-aerosol is now coupled to MUNICH to simulate primary and secondary aerosol concentrations. New parameterisations have also been introduced. Test cases are defined to illustrate the new model functionalities.
Marta Via, Gang Chen, Francesco Canonaco, Kaspar R. Daellenbach, Benjamin Chazeau, Hasna Chebaicheb, Jianhui Jiang, Hannes Keernik, Chunshui Lin, Nicolas Marchand, Cristina Marin, Colin O'Dowd, Jurgita Ovadnevaite, Jean-Eudes Petit, Michael Pikridas, Véronique Riffault, Jean Sciare, Jay G. Slowik, Leïla Simon, Jeni Vasilescu, Yunjiang Zhang, Olivier Favez, André S. H. Prévôt, Andrés Alastuey, and María Cruz Minguillón
Atmos. Meas. Tech., 15, 5479–5495, https://doi.org/10.5194/amt-15-5479-2022, https://doi.org/10.5194/amt-15-5479-2022, 2022
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This work presents the differences resulting from two techniques (rolling and seasonal) of the positive matrix factorisation model that can be run for organic aerosol source apportionment. The current state of the art suggests that the rolling technique is more accurate, but no proof of its effectiveness has been provided yet. This paper tackles this issue in the context of a synthetic dataset and a multi-site real-world comparison.
Alice Maison, Cédric Flageul, Bertrand Carissimo, Yunyi Wang, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 22, 9369–9388, https://doi.org/10.5194/acp-22-9369-2022, https://doi.org/10.5194/acp-22-9369-2022, 2022
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This paper presents a parameterization of the tree crown effect on air flow and pollutant dispersion in a street network model used to simulate air quality at the street level. The new parameterization is built using a finer-scale model (computational fluid dynamics). The tree effect increases with the leaf area index and the crown volume fraction of the trees; the street horizontal velocity is reduced by up to 68 % and the vertical transfer into or out of the street by up to 23 %.
Karine Sartelet, Youngseob Kim, Florian Couvidat, Maik Merkel, Tuukka Petäjä, Jean Sciare, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 8579–8596, https://doi.org/10.5194/acp-22-8579-2022, https://doi.org/10.5194/acp-22-8579-2022, 2022
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A methodology is defined to estimate number emissions from an inventory providing mass emissions. Number concentrations are simulated over Greater Paris using different nucleation parameterisations (binary, ternary involving sulfuric acid and ammonia, and heteromolecular involving sulfuric acid and extremely low-volatility organics, ELVOCs). The comparisons show that ternary nucleation may not be a dominant process for new particle formation in cities, but they stress the role of ELVOCs.
Chuan Ping Lee, Mihnea Surdu, David M. Bell, Josef Dommen, Mao Xiao, Xueqin Zhou, Andrea Baccarini, Stamatios Giannoukos, Günther Wehrle, Pascal André Schneider, Andre S. H. Prevot, Jay G. Slowik, Houssni Lamkaddam, Dongyu Wang, Urs Baltensperger, and Imad El Haddad
Atmos. Meas. Tech., 15, 3747–3760, https://doi.org/10.5194/amt-15-3747-2022, https://doi.org/10.5194/amt-15-3747-2022, 2022
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Real-time detection of both the gas and particle phase is needed to elucidate the sources and chemical reaction pathways of organic vapors and particulate matter. The Dual-EESI was developed to measure gas- and particle-phase species to provide new insights into aerosol sources or formation mechanisms. After characterizing the relative gas and particle response factors of EESI via organic aerosol uptake experiments, the Dual-EESI is more sensitive toward gas-phase analyes.
Varun Kumar, Stamatios Giannoukos, Sophie L. Haslett, Yandong Tong, Atinderpal Singh, Amelie Bertrand, Chuan Ping Lee, Dongyu S. Wang, Deepika Bhattu, Giulia Stefenelli, Jay S. Dave, Joseph V. Puthussery, Lu Qi, Pawan Vats, Pragati Rai, Roberto Casotto, Rangu Satish, Suneeti Mishra, Veronika Pospisilova, Claudia Mohr, David M. Bell, Dilip Ganguly, Vishal Verma, Neeraj Rastogi, Urs Baltensperger, Sachchida N. Tripathi, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 22, 7739–7761, https://doi.org/10.5194/acp-22-7739-2022, https://doi.org/10.5194/acp-22-7739-2022, 2022
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Here we present source apportionment results from the first field deployment in Delhi of an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF). The EESI-TOF is a recently developed instrument capable of providing uniquely detailed online chemical characterization of organic aerosol (OA), in particular the secondary OA (SOA) fraction. Here, we are able to apportion not only primary OA but also SOA to specific sources, which is performed for the first time in Delhi.
Svetlana Tsyro, Wenche Aas, Augustin Colette, Camilla Andersson, Bertrand Bessagnet, Giancarlo Ciarelli, Florian Couvidat, Kees Cuvelier, Astrid Manders, Kathleen Mar, Mihaela Mircea, Noelia Otero, Maria-Teresa Pay, Valentin Raffort, Yelva Roustan, Mark R. Theobald, Marta G. Vivanco, Hilde Fagerli, Peter Wind, Gino Briganti, Andrea Cappelletti, Massimo D'Isidoro, and Mario Adani
Atmos. Chem. Phys., 22, 7207–7257, https://doi.org/10.5194/acp-22-7207-2022, https://doi.org/10.5194/acp-22-7207-2022, 2022
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Particulate matter (PM) air pollution causes adverse health effects. In Europe, the emissions caused by anthropogenic activities have been reduced in the last decades. To assess the efficiency of emission reductions in improving air quality, we have studied the evolution of PM pollution in Europe. Simulations with six air quality models and observational data indicate a decrease in PM concentrations by 10 % to 30 % across Europe from 2000 to 2010, which is mainly a result of emission reductions.
Elsa Real, Florian Couvidat, Anthony Ung, Laure Malherbe, Blandine Raux, Alicia Gressent, and Augustin Colette
Earth Syst. Sci. Data, 14, 2419–2443, https://doi.org/10.5194/essd-14-2419-2022, https://doi.org/10.5194/essd-14-2419-2022, 2022
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This paper describes a 16-year (2000–2015) dataset of air pollution concentrations and air quality indicators over France combining background measurements and modeling. Hourly concentrations and regulatory indicators of NO2, O3, PM10 and PM2.5 are produced with 4 km spatial resolution. The overall dataset has been cross-validated and showed overall very good results. We hope that this open-access publication will facilitate further studies on the impacts of air pollution.
Maija Peltola, Clémence Rose, Jonathan V. Trueblood, Sally Gray, Mike Harvey, and Karine Sellegri
Atmos. Chem. Phys., 22, 6231–6254, https://doi.org/10.5194/acp-22-6231-2022, https://doi.org/10.5194/acp-22-6231-2022, 2022
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Despite the importance of marine aerosol measurements for constraining climate models, these measurements are scarce. We measured the aerosol particle number size distribution in coastal New Zealand over a total period of 10 months. This paper analyses the aerosol properties at the site, with a special focus on new particle formation and marine air masses. New particle formation was observed frequently, but in marine air masses it did not follow traditional event criteria.
Amir Yazdani, Nikunj Dudani, Satoshi Takahama, Amelie Bertrand, André S. H. Prévôt, Imad El Haddad, and Ann M. Dillner
Atmos. Meas. Tech., 15, 2857–2874, https://doi.org/10.5194/amt-15-2857-2022, https://doi.org/10.5194/amt-15-2857-2022, 2022
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While the aerosol mass spectrometer provides high-time-resolution characterization of the overall extent of oxidation, the extensive fragmentation of molecules and specificity of the technique have posed challenges toward deeper understanding of molecular structures in aerosols. This work demonstrates how functional group information can be extracted from a suite of commonly measured mass fragments using collocated infrared spectroscopy measurements.
Ranjeet S. Sokhi, Nicolas Moussiopoulos, Alexander Baklanov, John Bartzis, Isabelle Coll, Sandro Finardi, Rainer Friedrich, Camilla Geels, Tiia Grönholm, Tomas Halenka, Matthias Ketzel, Androniki Maragkidou, Volker Matthias, Jana Moldanova, Leonidas Ntziachristos, Klaus Schäfer, Peter Suppan, George Tsegas, Greg Carmichael, Vicente Franco, Steve Hanna, Jukka-Pekka Jalkanen, Guus J. M. Velders, and Jaakko Kukkonen
Atmos. Chem. Phys., 22, 4615–4703, https://doi.org/10.5194/acp-22-4615-2022, https://doi.org/10.5194/acp-22-4615-2022, 2022
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This review of air quality research focuses on developments over the past decade. The article considers current and future challenges that are important from air quality research and policy perspectives and highlights emerging prominent gaps of knowledge. The review also examines how air pollution management needs to adapt to new challenges and makes recommendations to guide the direction for future air quality research within the wider community and to provide support for policy.
Juan Cuesta, Lorenzo Costantino, Matthias Beekmann, Guillaume Siour, Laurent Menut, Bertrand Bessagnet, Tony C. Landi, Gaëlle Dufour, and Maxim Eremenko
Atmos. Chem. Phys., 22, 4471–4489, https://doi.org/10.5194/acp-22-4471-2022, https://doi.org/10.5194/acp-22-4471-2022, 2022
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We present the first comprehensive study integrating satellite observations of near-surface ozone pollution, surface in situ measurements, and a chemistry-transport model for quantifying the role of anthropogenic emission reductions during the COVID-19 lockdown in spring 2020. It confirms the occurrence of a net enhancement of ozone in central Europe and a reduction elsewhere, except for some hotspots, linked with the reduction of precursor emissions from Europe and the Northern Hemisphere.
Adrien Deroubaix, Laurent Menut, Cyrille Flamant, Peter Knippertz, Andreas H. Fink, Anneke Batenburg, Joel Brito, Cyrielle Denjean, Cheikh Dione, Régis Dupuy, Valerian Hahn, Norbert Kalthoff, Fabienne Lohou, Alfons Schwarzenboeck, Guillaume Siour, Paolo Tuccella, and Christiane Voigt
Atmos. Chem. Phys., 22, 3251–3273, https://doi.org/10.5194/acp-22-3251-2022, https://doi.org/10.5194/acp-22-3251-2022, 2022
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During the summer monsoon in West Africa, pollutants emitted in urbanized areas modify cloud cover and precipitation patterns. We analyze these patterns with the WRF-CHIMERE model, integrating the effects of aerosols on meteorology, based on the numerous observations provided by the Dynamics-Aerosol-Climate-Interactions campaign. This study adds evidence to recent findings that increased pollution levels in West Africa delay the breakup time of low-level clouds and reduce precipitation.
Benjamin Loubet, Pauline Buysse, Lais Gonzaga-Gomez, Florence Lafouge, Raluca Ciuraru, Céline Decuq, Julien Kammer, Sandy Bsaibes, Christophe Boissard, Brigitte Durand, Jean-Christophe Gueudet, Olivier Fanucci, Olivier Zurfluh, Letizia Abis, Nora Zannoni, François Truong, Dominique Baisnée, Roland Sarda-Estève, Michael Staudt, and Valérie Gros
Atmos. Chem. Phys., 22, 2817–2842, https://doi.org/10.5194/acp-22-2817-2022, https://doi.org/10.5194/acp-22-2817-2022, 2022
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Volatile organic compounds (VOCs) are precursors of tropospheric pollutants like ozone or aerosols. Emission by agricultural land was still poorly characterized. We report experimental measurements of ecosystem-scale VOC fluxes above a wheat field with a highly sensitive proton transfer mass spectrometer. We report the fluxes of 123 compounds and confirm that methanol is the most emitted VOC by wheat. The second most emitted compound was C6H4O. Around 75 % of the compounds were deposited.
Augustin Colette, Laurence Rouïl, Frédérik Meleux, Vincent Lemaire, and Blandine Raux
Geosci. Model Dev., 15, 1441–1465, https://doi.org/10.5194/gmd-15-1441-2022, https://doi.org/10.5194/gmd-15-1441-2022, 2022
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We introduce the first toolbox that allows exploration of the benefits of air pollution mitigation scenarios in the every-day air quality forecasts through a web interface. The toolbox relies on the joint use of chemistry-transport models (CTMs) and surrogate modelling techniques.
Karine Desboeufs, Franck Fu, Matthieu Bressac, Antonio Tovar-Sánchez, Sylvain Triquet, Jean-François Doussin, Chiara Giorio, Patrick Chazette, Julie Disnaquet, Anaïs Feron, Paola Formenti, Franck Maisonneuve, Araceli Rodríguez-Romero, Pascal Zapf, François Dulac, and Cécile Guieu
Atmos. Chem. Phys., 22, 2309–2332, https://doi.org/10.5194/acp-22-2309-2022, https://doi.org/10.5194/acp-22-2309-2022, 2022
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This article reports the first concurrent sampling of wet deposition samples and surface seawater and was performed during the PEACETIME cruise in the remote Mediterranean (May–June 2017). Through the chemical composition of trace metals (TMs) in these samples, it emphasizes the decrease of atmospheric metal pollution in this area during the last few decades and the critical role of wet deposition as source of TMs for Mediterranean surface seawater, especially for intense dust deposition events.
Pamela A. Dominutti, Pascal Renard, Mickaël Vaïtilingom, Angelica Bianco, Jean-Luc Baray, Agnès Borbon, Thierry Bourianne, Frédéric Burnet, Aurélie Colomb, Anne-Marie Delort, Valentin Duflot, Stephan Houdier, Jean-Luc Jaffrezo, Muriel Joly, Martin Leremboure, Jean-Marc Metzger, Jean-Marc Pichon, Mickaël Ribeiro, Manon Rocco, Pierre Tulet, Anthony Vella, Maud Leriche, and Laurent Deguillaume
Atmos. Chem. Phys., 22, 505–533, https://doi.org/10.5194/acp-22-505-2022, https://doi.org/10.5194/acp-22-505-2022, 2022
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We present here the results obtained during an intensive field campaign conducted in March to April 2019 in Reunion. Our study integrates a comprehensive chemical and microphysical characterization of cloud water. Our investigations reveal that air mass history and cloud microphysical properties do not fully explain the variability observed in their chemical composition. This highlights the complexity of emission sources, multiphasic exchanges, and transformations in clouds.
Dalrin Ampritta Amaladhasan, Claudia Heyn, Christopher R. Hoyle, Imad El Haddad, Miriam Elser, Simone M. Pieber, Jay G. Slowik, Antonio Amorim, Jonathan Duplissy, Sebastian Ehrhart, Vladimir Makhmutov, Ugo Molteni, Matti Rissanen, Yuri Stozhkov, Robert Wagner, Armin Hansel, Jasper Kirkby, Neil M. Donahue, Rainer Volkamer, Urs Baltensperger, Martin Gysel-Beer, and Andreas Zuend
Atmos. Chem. Phys., 22, 215–244, https://doi.org/10.5194/acp-22-215-2022, https://doi.org/10.5194/acp-22-215-2022, 2022
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We use a combination of models for gas-phase chemical reactions and equilibrium gas–particle partitioning of isoprene-derived secondary organic aerosols (SOAs) informed by dark ozonolysis experiments conducted in the CLOUD chamber. Our predictions cover high to low relative humidities (RHs) and quantify how SOA mass yields are enhanced at high RH as well as the impact of inorganic seeds of distinct hygroscopicities and acidities on the coupled partitioning of water and semi-volatile organics.
Andrea Pazmiño, Matthias Beekmann, Florence Goutail, Dmitry Ionov, Ariane Bazureau, Manuel Nunes-Pinharanda, Alain Hauchecorne, and Sophie Godin-Beekmann
Atmos. Chem. Phys., 21, 18303–18317, https://doi.org/10.5194/acp-21-18303-2021, https://doi.org/10.5194/acp-21-18303-2021, 2021
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UV-Visible Système d'Analyse par Observations Zénithales (SAOZ) NO2 tropospheric columns were evaluated to quantify the impact of the lockdown in limiting the COVID-19 propagation. Meteorological conditions and NO2 trends were considered. The negative anomaly in tropospheric columns in 2020, attributed to the lockdown (17 March–10 May and related emissions reductions), was 56 % at Paris and 46 % at a suburban site. A similar anomaly was found in the Airparif data of surface concentrations.
Matthieu Bressac, Thibaut Wagener, Nathalie Leblond, Antonio Tovar-Sánchez, Céline Ridame, Vincent Taillandier, Samuel Albani, Sophie Guasco, Aurélie Dufour, Stéphanie H. M. Jacquet, François Dulac, Karine Desboeufs, and Cécile Guieu
Biogeosciences, 18, 6435–6453, https://doi.org/10.5194/bg-18-6435-2021, https://doi.org/10.5194/bg-18-6435-2021, 2021
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Phytoplankton growth is limited by the availability of iron in about 50 % of the ocean. Atmospheric deposition of desert dust represents a key source of iron. Here, we present direct observations of dust deposition in the Mediterranean Sea. A key finding is that the input of iron from dust primarily occurred in the deep ocean, while previous studies mainly focused on the ocean surface. This new insight will enable us to better represent controls on global marine productivity in models.
Boris Vansevenant, Cédric Louis, Corinne Ferronato, Ludovic Fine, Patrick Tassel, Pascal Perret, Evangelia Kostenidou, Brice Temime-Roussel, Barbara D'Anna, Karine Sartelet, Véronique Cerezo, and Yao Liu
Atmos. Meas. Tech., 14, 7627–7655, https://doi.org/10.5194/amt-14-7627-2021, https://doi.org/10.5194/amt-14-7627-2021, 2021
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A new method was developed to correct wall losses of particles on Teflon walls using a new environmental chamber. It was applied to experiments with six diesel vehicles (Euro 3 to 6), tested on a chassis dynamometer. Emissions of particles and precursors were obtained under urban and motorway conditions. The chamber experiments help understand the role of physical processes in diesel particle evolutions in the dark. These results can be applied to situations such as tunnels or winter rush hours.
Jean-Eudes Petit, Jean-Charles Dupont, Olivier Favez, Valérie Gros, Yunjiang Zhang, Jean Sciare, Leila Simon, François Truong, Nicolas Bonnaire, Tanguy Amodeo, Robert Vautard, and Martial Haeffelin
Atmos. Chem. Phys., 21, 17167–17183, https://doi.org/10.5194/acp-21-17167-2021, https://doi.org/10.5194/acp-21-17167-2021, 2021
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The COVID-19 outbreak led to lockdowns at national scales in spring 2020. Large cuts in emissions occurred, but the quantitative assessment of their role from observations is hindered by weather and interannual variability. That is why we developed an innovative methodology in order to best characterize the impact of lockdown on atmospheric chemistry. We find that a local decrease in traffic-related pollutants triggered a decrease of secondary aerosols and an increase in ozone.
Sharmine Akter Simu, Yuzo Miyazaki, Eri Tachibana, Henning Finkenzeller, Jérôme Brioude, Aurélie Colomb, Olivier Magand, Bert Verreyken, Stephanie Evan, Rainer Volkamer, and Trissevgeni Stavrakou
Atmos. Chem. Phys., 21, 17017–17029, https://doi.org/10.5194/acp-21-17017-2021, https://doi.org/10.5194/acp-21-17017-2021, 2021
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The tropical Indian Ocean (IO) is expected to be a significant source of water-soluble organic carbon (WSOC), which is relevant to cloud formation. Our study showed that marine secondary organic formation dominantly contributed to the aerosol WSOC mass at the high-altitude observatory in the southwest IO in the wet season in both marine boundary layer and free troposphere (FT). This suggests that the effect of marine secondary sources is important up to FT, a process missing in climate models.
Lya Lugon, Jérémy Vigneron, Christophe Debert, Olivier Chrétien, and Karine Sartelet
Geosci. Model Dev., 14, 7001–7019, https://doi.org/10.5194/gmd-14-7001-2021, https://doi.org/10.5194/gmd-14-7001-2021, 2021
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The multiscale Street-in-Grid model is used to simulate black carbon (BC) concentrations in streets. To respect street-surface mass balance, particle resuspension is estimated with a new approach based on deposited mass. The contribution of resuspension is low, but non-exhaust emissions from tyre wear may largely contribute to BC concentrations. The impact of the two-way dynamic coupling between scales on BC concentrations varies depending on the street geometry and traffic emission intensity.
Laurent Menut, Bertrand Bessagnet, Régis Briant, Arineh Cholakian, Florian Couvidat, Sylvain Mailler, Romain Pennel, Guillaume Siour, Paolo Tuccella, Solène Turquety, and Myrto Valari
Geosci. Model Dev., 14, 6781–6811, https://doi.org/10.5194/gmd-14-6781-2021, https://doi.org/10.5194/gmd-14-6781-2021, 2021
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The CHIMERE chemistry-transport model is presented in its new version, V2020r1. Many changes are proposed compared to the previous version. These include online modeling, new parameterizations for aerosols, new emissions schemes, a new parameter file format, the subgrid-scale variability of urban concentrations and new transport schemes.
Dongyu S. Wang, Chuan Ping Lee, Jordan E. Krechmer, Francesca Majluf, Yandong Tong, Manjula R. Canagaratna, Julia Schmale, André S. H. Prévôt, Urs Baltensperger, Josef Dommen, Imad El Haddad, Jay G. Slowik, and David M. Bell
Atmos. Meas. Tech., 14, 6955–6972, https://doi.org/10.5194/amt-14-6955-2021, https://doi.org/10.5194/amt-14-6955-2021, 2021
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To understand the sources and fate of particulate matter in the atmosphere, the ability to quantitatively describe its chemical composition is essential. In this work, we developed a calibration method for a state-of-the-art measurement technique without the need for chemical standards. Statistical analyses identified the driving factors behind instrument sensitivity variability towards individual components of particulate matter.
Gaëlle Dufour, Didier Hauglustaine, Yunjiang Zhang, Maxim Eremenko, Yann Cohen, Audrey Gaudel, Guillaume Siour, Mathieu Lachatre, Axel Bense, Bertrand Bessagnet, Juan Cuesta, Jerry Ziemke, Valérie Thouret, and Bo Zheng
Atmos. Chem. Phys., 21, 16001–16025, https://doi.org/10.5194/acp-21-16001-2021, https://doi.org/10.5194/acp-21-16001-2021, 2021
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The IASI observations and the LMDZ-OR-INCA model simulations show negative ozone trends in the Central East China region in the lower free (3–6 km column) and the upper free (6–9 km column) troposphere. Sensitivity studies from the model show that the Chinese anthropogenic emissions contribute to more than 50 % in the trend. The reduction in NOx emissions that has occurred since 2013 in China seems to lead to a decrease in ozone in the free troposphere, contrary to the increase at the surface.
Igor B. Konovalov, Nikolai A. Golovushkin, Matthias Beekmann, Mikhail V. Panchenko, and Meinrat O. Andreae
Atmos. Meas. Tech., 14, 6647–6673, https://doi.org/10.5194/amt-14-6647-2021, https://doi.org/10.5194/amt-14-6647-2021, 2021
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The absorption of solar light by organic matter, known as brown carbon (BrC), contributes significantly to the radiative budget of the Earth’s atmosphere, but its representation in atmospheric models is uncertain. This paper advances a methodology to constrain model parameters characterizing BrC absorption of atmospheric aerosol originating from biomass burning with the available remote ground-based observations of atmospheric aerosol.
Gang Chen, Yulia Sosedova, Francesco Canonaco, Roman Fröhlich, Anna Tobler, Athanasia Vlachou, Kaspar R. Daellenbach, Carlo Bozzetti, Christoph Hueglin, Peter Graf, Urs Baltensperger, Jay G. Slowik, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 21, 15081–15101, https://doi.org/10.5194/acp-21-15081-2021, https://doi.org/10.5194/acp-21-15081-2021, 2021
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A novel, advanced source apportionment technique was applied to a dataset measured in Magadino. Rolling positive matrix factorisation (PMF) allows for retrieving more realistic, time-dependent, and detailed information on organic aerosol sources. The strength of the rolling PMF mechanism is highlighted by comparing it with results derived from conventional seasonal PMF. Overall, this comprehensive interpretation of aerosol chemical speciation monitor data could be a role model for similar work.
Wenfei Zhu, Song Guo, Zirui Zhang, Hui Wang, Ying Yu, Zheng Chen, Ruizhe Shen, Rui Tan, Kai Song, Kefan Liu, Rongzhi Tang, Yi Liu, Shengrong Lou, Yuanju Li, Wenbin Zhang, Zhou Zhang, Shijin Shuai, Hongming Xu, Shuangde Li, Yunfa Chen, Min Hu, Francesco Canonaco, and Andre S. H. Prévôt
Atmos. Chem. Phys., 21, 15065–15079, https://doi.org/10.5194/acp-21-15065-2021, https://doi.org/10.5194/acp-21-15065-2021, 2021
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The experiments of primary emissions and secondary organic aerosol (SOA) formation from urban lifestyle sources (cooking and vehicles) were conducted. The mass spectral features of primary organic aerosol (POA) and SOA were characterized by using a high-resolution time-of-flight aerosol mass spectrometer. This work, for the first time, establishes the vehicle and cooking SOA source profiles and can be further used as source constraints in the OA source apportionment in the ambient atmosphere.
Anna K. Tobler, Alicja Skiba, Francesco Canonaco, Griša Močnik, Pragati Rai, Gang Chen, Jakub Bartyzel, Miroslaw Zimnoch, Katarzyna Styszko, Jaroslaw Nęcki, Markus Furger, Kazimierz Różański, Urs Baltensperger, Jay G. Slowik, and Andre S. H. Prevot
Atmos. Chem. Phys., 21, 14893–14906, https://doi.org/10.5194/acp-21-14893-2021, https://doi.org/10.5194/acp-21-14893-2021, 2021
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Kraków is among the cities with the highest particulate matter levels within Europe. We conducted long-term and highly time-resolved measurements of the chemical composition of submicron particlulate matter (PM1). Combined with advanced source apportionment techniques, which allow for time-dependent factor profiles, our results elucidate that traffic and residential heating (biomass burning and coal combustion) as well as oxygenated organic aerosol are the key PM sources in Kraków.
Cheng Wu, David M. Bell, Emelie L. Graham, Sophie Haslett, Ilona Riipinen, Urs Baltensperger, Amelie Bertrand, Stamatios Giannoukos, Janne Schoonbaert, Imad El Haddad, Andre S. H. Prevot, Wei Huang, and Claudia Mohr
Atmos. Chem. Phys., 21, 14907–14925, https://doi.org/10.5194/acp-21-14907-2021, https://doi.org/10.5194/acp-21-14907-2021, 2021
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Night-time reactions of biogenic volatile organic compounds and nitrate radicals can lead to the formation of secondary organic aerosol (BSOANO3). Here, we study the impacts of light exposure on the BSOANO3 from three biogenic precursors. Our results suggest that photolysis causes photodegradation of a substantial fraction of BSOANO3, changes the chemical composition and bulk volatility, and might be a potentially important loss pathway of BSOANO3 during the night-to-day transition.
Alexandre Kukui, Michel Chartier, Jinhe Wang, Hui Chen, Sébastien Dusanter, Stéphane Sauvage, Vincent Michoud, Nadine Locoge, Valérie Gros, Thierry Bourrianne, Karine Sellegri, and Jean-Marc Pichon
Atmos. Chem. Phys., 21, 13333–13351, https://doi.org/10.5194/acp-21-13333-2021, https://doi.org/10.5194/acp-21-13333-2021, 2021
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Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles. It is generally accepted that the major atmospheric source of H2SO4 is the reaction of OH radicals with SO2. In this study, importance of an additional H2SO4 source via oxidation of SO2 by stabilized Criegee intermediates was estimated based on measurements at a remote site on Cape Corsica. It was found that the oxidation of SO2 by SCI may be an important source of H2SO4, especially during nighttime.
Chuan Ping Lee, Mihnea Surdu, David M. Bell, Houssni Lamkaddam, Mingyi Wang, Farnoush Ataei, Victoria Hofbauer, Brandon Lopez, Neil M. Donahue, Josef Dommen, Andre S. H. Prevot, Jay G. Slowik, Dongyu Wang, Urs Baltensperger, and Imad El Haddad
Atmos. Meas. Tech., 14, 5913–5923, https://doi.org/10.5194/amt-14-5913-2021, https://doi.org/10.5194/amt-14-5913-2021, 2021
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Extractive electrospray ionization mass spectrometry (EESI-MS) has been deployed for high throughput online detection of particles with minimal fragmentation. Our study elucidates the extraction mechanism between the particles and electrospray (ES) droplets of different properties. The results show that the extraction rate is likely affected by the coagulation rate between the particles and ES droplets. Once coagulated, the particles undergo complete extraction within the ES droplet.
Bert Verreyken, Crist Amelynck, Niels Schoon, Jean-François Müller, Jérôme Brioude, Nicolas Kumps, Christian Hermans, Jean-Marc Metzger, Aurélie Colomb, and Trissevgeni Stavrakou
Atmos. Chem. Phys., 21, 12965–12988, https://doi.org/10.5194/acp-21-12965-2021, https://doi.org/10.5194/acp-21-12965-2021, 2021
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We present a 2-year dataset of trace gas concentrations, specifically an array of volatile organic compounds (VOCs), recorded at the Maïdo observatory, a remote tropical high-altitude site located on a small island in the southwest Indian Ocean. We found that island-scale transport is an important driver for the daily cycle of VOC concentrations. During the day, surface emissions from the island affect the atmospheric composition at Maïdo greatly, while at night this impact is strongly reduced.
Vaios Moschos, Martin Gysel-Beer, Robin L. Modini, Joel C. Corbin, Dario Massabò, Camilla Costa, Silvia G. Danelli, Athanasia Vlachou, Kaspar R. Daellenbach, Sönke Szidat, Paolo Prati, André S. H. Prévôt, Urs Baltensperger, and Imad El Haddad
Atmos. Chem. Phys., 21, 12809–12833, https://doi.org/10.5194/acp-21-12809-2021, https://doi.org/10.5194/acp-21-12809-2021, 2021
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This study provides a holistic approach to studying the spectrally resolved light absorption by atmospheric brown carbon (BrC) and black carbon using long time series of daily samples from filter-based measurements. The obtained results provide (1) a better understanding of the aerosol absorption profile and its dependence on BrC and on lensing from less absorbing coatings and (2) an estimation of the most important absorbers at typical European locations.
Isabelle Chiapello, Paola Formenti, Lydie Mbemba Kabuiku, Fabrice Ducos, Didier Tanré, and François Dulac
Atmos. Chem. Phys., 21, 12715–12737, https://doi.org/10.5194/acp-21-12715-2021, https://doi.org/10.5194/acp-21-12715-2021, 2021
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The Mediterranean atmosphere is impacted by a variety of particle pollution, which exerts a complex pressure on climate and air quality. We analyze the 2005–2013 POLDER-3 satellite advanced aerosol data set over the Western Mediterranean Sea. Aerosols' spatial distribution and temporal evolution suggests a large-scale improvement of air quality related to the fine aerosol component, most probably resulting from reduction of anthropogenic particle emissions in the surrounding European countries.
Hongming Yi, Mathieu Cazaunau, Aline Gratien, Vincent Michoud, Edouard Pangui, Jean-Francois Doussin, and Weidong Chen
Atmos. Meas. Tech., 14, 5701–5715, https://doi.org/10.5194/amt-14-5701-2021, https://doi.org/10.5194/amt-14-5701-2021, 2021
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HONO and NO2 play a crucial role in the atmospheric oxidation capacity that affects the regional air quality and global climate. Accurate measurements of HONO are challenging due to the drawback of existing detection methods. Calibration-free high-sensitivity direct, simultaneous measurements of NO2, HONO and CH2O with UV-IBBCEAS provide accurate and fast quantitative analysis of their concentration variation within their lifetime by intercomparison with NOx, FTIR and NitroMAC sensors.
Rebecca D. Kutzner, Juan Cuesta, Pascale Chelin, Jean-Eudes Petit, Mokhtar Ray, Xavier Landsheere, Benoît Tournadre, Jean-Charles Dupont, Amandine Rosso, Frank Hase, Johannes Orphal, and Matthias Beekmann
Atmos. Chem. Phys., 21, 12091–12111, https://doi.org/10.5194/acp-21-12091-2021, https://doi.org/10.5194/acp-21-12091-2021, 2021
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Our work investigates the diurnal evolution of atmospheric ammonia concentrations during a major pollution event. It analyses it in regard of both chemical (gas–particle conversion) and physical (vertical mixing, meteorology) processes in the atmosphere. These mechanisms are key for understanding the evolution of the physicochemical state of the atmosphere; therefore, it clearly fits into the scope of Atmospheric Chemistry and Physics.
Paul Strobel, Marcel Bliedtner, Andrew S. Carr, Peter Frenzel, Björn Klaes, Gary Salazar, Julian Struck, Sönke Szidat, Roland Zech, and Torsten Haberzettl
Clim. Past, 17, 1567–1586, https://doi.org/10.5194/cp-17-1567-2021, https://doi.org/10.5194/cp-17-1567-2021, 2021
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This study presents a multi-proxy record from Lake Voёlvlei and provides new insights into the sea level and paleoclimate history of the past 8.5 ka at South Africa’s southern Cape coast. Our results show that sea level changes at the southern coast are in good agreement with the western coast of South Africa. In terms of climate our record provides valuable insights into changing sources of precipitation at the southern Cape coast, i.e. westerly- and easterly-derived precipitation contribution.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Evelyn Freney, Karine Sellegri, Alessia Nicosia, Leah R. Williams, Matteo Rinaldi, Jonathan T. Trueblood, André S. H. Prévôt, Melilotus Thyssen, Gérald Grégori, Nils Haëntjens, Julie Dinasquet, Ingrid Obernosterer, France Van Wambeke, Anja Engel, Birthe Zäncker, Karine Desboeufs, Eija Asmi, Hilkka Timonen, and Cécile Guieu
Atmos. Chem. Phys., 21, 10625–10641, https://doi.org/10.5194/acp-21-10625-2021, https://doi.org/10.5194/acp-21-10625-2021, 2021
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In this work, we present observations of the organic aerosol content in primary sea spray aerosols (SSAs) continuously generated along a 5-week cruise in the Mediterranean. This information is combined with seawater biogeochemical properties also measured continuously along the ship track to develop a number of parametrizations that can be used in models to determine SSA organic content in oligotrophic waters that represent 60 % of the oceans from commonly measured seawater variables.
Michael Zech, Marcel Lerch, Marcel Bliedtner, Tobias Bromm, Fabian Seemann, Sönke Szidat, Gary Salazar, Roland Zech, Bruno Glaser, Jean Nicolas Haas, Dieter Schäfer, and Clemens Geitner
E&G Quaternary Sci. J., 70, 171–186, https://doi.org/10.5194/egqsj-70-171-2021, https://doi.org/10.5194/egqsj-70-171-2021, 2021
Amir Yazdani, Nikunj Dudani, Satoshi Takahama, Amelie Bertrand, André S. H. Prévôt, Imad El Haddad, and Ann M. Dillner
Atmos. Chem. Phys., 21, 10273–10293, https://doi.org/10.5194/acp-21-10273-2021, https://doi.org/10.5194/acp-21-10273-2021, 2021
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Functional group compositions of primary and aged aerosols from wood burning and coal combustion sources from chamber experiments are interpreted through compounds present in the fuels and known gas-phase oxidation products. Infrared spectra of aged wood burning in the chamber and ambient biomass burning samples reveal striking similarities, and a new method for identifying burning-impacted samples in monitoring network measurements is presented.
Stefanie Kremser, Mike Harvey, Peter Kuma, Sean Hartery, Alexia Saint-Macary, John McGregor, Alex Schuddeboom, Marc von Hobe, Sinikka T. Lennartz, Alex Geddes, Richard Querel, Adrian McDonald, Maija Peltola, Karine Sellegri, Israel Silber, Cliff S. Law, Connor J. Flynn, Andrew Marriner, Thomas C. J. Hill, Paul J. DeMott, Carson C. Hume, Graeme Plank, Geoffrey Graham, and Simon Parsons
Earth Syst. Sci. Data, 13, 3115–3153, https://doi.org/10.5194/essd-13-3115-2021, https://doi.org/10.5194/essd-13-3115-2021, 2021
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Aerosol–cloud interactions over the Southern Ocean are poorly understood and remain a major source of uncertainty in climate models. This study presents ship-borne measurements, collected during a 6-week voyage into the Southern Ocean in 2018, that are an important supplement to satellite-based measurements. For example, these measurements include data on low-level clouds and aerosol composition in the marine boundary layer, which can be used in climate model evaluation efforts.
Yandong Tong, Veronika Pospisilova, Lu Qi, Jing Duan, Yifang Gu, Varun Kumar, Pragati Rai, Giulia Stefenelli, Liwei Wang, Ying Wang, Haobin Zhong, Urs Baltensperger, Junji Cao, Ru-Jin Huang, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 21, 9859–9886, https://doi.org/10.5194/acp-21-9859-2021, https://doi.org/10.5194/acp-21-9859-2021, 2021
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We investigate SOA sources and formation processes by a field deployment of the EESI-TOF-MS and L-TOF AMS in Beijing in late autumn and early winter. Our study shows that the sources and processes giving rise to haze events in Beijing are variable and seasonally dependent: (1) in the heating season, SOA formation is driven by oxidation of aromatics from solid fuel combustion; and (2) under high-NOx and RH conditions, aqueous-phase chemistry can be a major contributor to SOA formation.
Siqi Hou, Di Liu, Jingsha Xu, Tuan V. Vu, Xuefang Wu, Deepchandra Srivastava, Pingqing Fu, Linjie Li, Yele Sun, Athanasia Vlachou, Vaios Moschos, Gary Salazar, Sönke Szidat, André S. H. Prévôt, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 8273–8292, https://doi.org/10.5194/acp-21-8273-2021, https://doi.org/10.5194/acp-21-8273-2021, 2021
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This study provides a newly developed method which combines radiocarbon (14C) with organic tracers to enable source apportionment of primary and secondary fossil vs. non-fossil sources of carbonaceous aerosols at an urban and a rural site of Beijing. The source apportionment results were compared with those by chemical mass balance and AMS/ACSM-PMF methods. Correlations of WINSOC and WSOC with different sources of OC were also performed to elucidate the formation mechanisms of SOC.
Audrey Fortems-Cheiney, Isabelle Pison, Grégoire Broquet, Gaëlle Dufour, Antoine Berchet, Elise Potier, Adriana Coman, Guillaume Siour, and Lorenzo Costantino
Geosci. Model Dev., 14, 2939–2957, https://doi.org/10.5194/gmd-14-2939-2021, https://doi.org/10.5194/gmd-14-2939-2021, 2021
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Up-to-date and accurate emission inventories for air pollutants are essential for understanding their role in the formation of tropospheric ozone and particulate matter, for anticipating pollution peaks and for identifying the key drivers that could help mitigate their emissions. Complementarily with bottom-up inventories, the system described here aims at updating and improving the knowledge on the high spatiotemporal variability of emissions of air pollutants.
Vincent Michoud, Elise Hallemans, Laura Chiappini, Eva Leoz-Garziandia, Aurélie Colomb, Sébastien Dusanter, Isabelle Fronval, François Gheusi, Jean-Luc Jaffrezo, Thierry Léonardis, Nadine Locoge, Nicolas Marchand, Stéphane Sauvage, Jean Sciare, and Jean-François Doussin
Atmos. Chem. Phys., 21, 8067–8088, https://doi.org/10.5194/acp-21-8067-2021, https://doi.org/10.5194/acp-21-8067-2021, 2021
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A multiphasic molecular characterization of oxygenated compounds has been carried out during the ChArMEx field campaign using offline analysis. It leads to the identification of 97 different compounds in the gas and aerosol phases and reveals the important contribution of organic acids to organic aerosol. In addition, comparison between experimental and theoretical partitioning coefficients revealed in most cases a large underestimation by the theory reaching 1 to 7 orders of magnitude.
Jean-Philippe Putaud, Luca Pozzoli, Enrico Pisoni, Sebastiao Martins Dos Santos, Friedrich Lagler, Guido Lanzani, Umberto Dal Santo, and Augustin Colette
Atmos. Chem. Phys., 21, 7597–7609, https://doi.org/10.5194/acp-21-7597-2021, https://doi.org/10.5194/acp-21-7597-2021, 2021
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To determine the impact of the COVID lockdown on air quality in northern Italy, measurements of atmospheric pollutants (NO2, PM10, O3, NO, SO2 ) were compared to the output of a model ignoring the lockdown. We found that NO2 decreased on average by −30 % to −40 %. Unlike NO2, PM10 was not significantly affected due to the compensation of decreased emissions from traffic by increased emissions from domestic heating and/or by changes in atmospheric chemistry enhancing secondary aerosol formation.
Eve-Agnès Fiorentino, Henri Wortham, and Karine Sartelet
Geosci. Model Dev., 14, 2747–2780, https://doi.org/10.5194/gmd-14-2747-2021, https://doi.org/10.5194/gmd-14-2747-2021, 2021
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Indoor air quality (IAQ) is strongly influenced by reactivity with surfaces, which is called heterogeneous reactivity. To date, this reactivity is barely integrated into numerical models due to the strong uncertainties it is subjected to. In this work, an open-source IAQ model, called the H2I model, is developed to consider both gas-phase and heterogeneous reactivity and simulate indoor concentrations of inorganic compounds.
Jérôme Barré, Hervé Petetin, Augustin Colette, Marc Guevara, Vincent-Henri Peuch, Laurence Rouil, Richard Engelen, Antje Inness, Johannes Flemming, Carlos Pérez García-Pando, Dene Bowdalo, Frederik Meleux, Camilla Geels, Jesper H. Christensen, Michael Gauss, Anna Benedictow, Svetlana Tsyro, Elmar Friese, Joanna Struzewska, Jacek W. Kaminski, John Douros, Renske Timmermans, Lennart Robertson, Mario Adani, Oriol Jorba, Mathieu Joly, and Rostislav Kouznetsov
Atmos. Chem. Phys., 21, 7373–7394, https://doi.org/10.5194/acp-21-7373-2021, https://doi.org/10.5194/acp-21-7373-2021, 2021
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This study provides a comprehensive assessment of air quality changes across the main European urban areas induced by the COVID-19 lockdown using satellite observations, surface site measurements, and the forecasting system from the Copernicus Atmospheric Monitoring Service (CAMS). We demonstrate the importance of accounting for weather and seasonal variability when calculating such estimates.
Benjamin Chazeau, Brice Temime-Roussel, Grégory Gille, Boualem Mesbah, Barbara D'Anna, Henri Wortham, and Nicolas Marchand
Atmos. Chem. Phys., 21, 7293–7319, https://doi.org/10.5194/acp-21-7293-2021, https://doi.org/10.5194/acp-21-7293-2021, 2021
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The temporal trends in the chemical composition and particle number of the submicron aerosols in a Mediterranean city, Marseille, are investigated over 14 months. Fifteen days were found to exceed the WHO PM2.5 daily limit (25 µg m−3) only during the cold period, with two distinct origins: local pollution events with an increased fraction of the carbonaceous fraction due to domestic wood burning and long-range pollution events with a high level of oxygenated organic aerosol and ammonium nitrate.
Karl Espen Yttri, Francesco Canonaco, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Hans Gundersen, Anne-Gunn Hjellbrekke, Cathrine Lund Myhre, Stephen Matthew Platt, André S. H. Prévôt, David Simpson, Sverre Solberg, Jason Surratt, Kjetil Tørseth, Hilde Uggerud, Marit Vadset, Xin Wan, and Wenche Aas
Atmos. Chem. Phys., 21, 7149–7170, https://doi.org/10.5194/acp-21-7149-2021, https://doi.org/10.5194/acp-21-7149-2021, 2021
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Carbonaceous aerosol sources and trends were studied at the Birkenes Observatory. A large decrease in elemental carbon (EC; 2001–2018) and a smaller decline in levoglucosan (2008–2018) suggest that organic carbon (OC)/EC from traffic/industry is decreasing, whereas the abatement of OC/EC from biomass burning has been less successful. Positive matrix factorization apportioned 72 % of EC to fossil fuel sources and 53 % (PM2.5) and 78 % (PM10–2.5) of OC to biogenic sources.
Clémence Rose, Matti P. Rissanen, Siddharth Iyer, Jonathan Duplissy, Chao Yan, John B. Nowak, Aurélie Colomb, Régis Dupuy, Xu-Cheng He, Janne Lampilahti, Yee Jun Tham, Daniela Wimmer, Jean-Marc Metzger, Pierre Tulet, Jérôme Brioude, Céline Planche, Markku Kulmala, and Karine Sellegri
Atmos. Chem. Phys., 21, 4541–4560, https://doi.org/10.5194/acp-21-4541-2021, https://doi.org/10.5194/acp-21-4541-2021, 2021
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Sulfuric acid (H2SO4) is commonly accepted as a key precursor for atmospheric new particle formation. However, direct measurements of [H2SO4] remain challenging, motivating the development of proxies. Using data collected in two different volcanic plumes, we show, under these specific conditions, the good performance of a proxy from the literature and also highlight the benefit of the newly developed proxies for the prediction of the highest [H2SO4] values.
Jianhui Jiang, Imad El Haddad, Sebnem Aksoyoglu, Giulia Stefenelli, Amelie Bertrand, Nicolas Marchand, Francesco Canonaco, Jean-Eudes Petit, Olivier Favez, Stefania Gilardoni, Urs Baltensperger, and André S. H. Prévôt
Geosci. Model Dev., 14, 1681–1697, https://doi.org/10.5194/gmd-14-1681-2021, https://doi.org/10.5194/gmd-14-1681-2021, 2021
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We developed a box model with a volatility basis set to simulate organic aerosol (OA) from biomass burning and optimized the vapor-wall-loss-corrected OA yields with a genetic algorithm. The optimized parameterizations were then implemented in the air quality model CAMx v6.5. Comparisons with ambient measurements indicate that the vapor-wall-loss-corrected parameterization effectively improves the model performance in predicting OA, which reduced the mean fractional bias from −72.9 % to −1.6 %.
Alkuin Maximilian Koenig, Olivier Magand, Paolo Laj, Marcos Andrade, Isabel Moreno, Fernando Velarde, Grover Salvatierra, René Gutierrez, Luis Blacutt, Diego Aliaga, Thomas Reichler, Karine Sellegri, Olivier Laurent, Michel Ramonet, and Aurélien Dommergue
Atmos. Chem. Phys., 21, 3447–3472, https://doi.org/10.5194/acp-21-3447-2021, https://doi.org/10.5194/acp-21-3447-2021, 2021
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The environmental cycling of atmospheric mercury, a harmful global contaminant, is still not sufficiently constrained, partly due to missing data in remote regions. Here, we address this issue by presenting 20 months of atmospheric mercury measurements, sampled in the Bolivian Andes. We observe a significant seasonal pattern, whose key features we explore. Moreover, we deduce ratios to constrain South American biomass burning mercury emissions and the mercury uptake by the Amazon rainforest.
Ana Moreno, Miguel Bartolomé, Juan Ignacio López-Moreno, Jorge Pey, Juan Pablo Corella, Jordi García-Orellana, Carlos Sancho, María Leunda, Graciela Gil-Romera, Penélope González-Sampériz, Carlos Pérez-Mejías, Francisco Navarro, Jaime Otero-García, Javier Lapazaran, Esteban Alonso-González, Cristina Cid, Jerónimo López-Martínez, Belén Oliva-Urcia, Sérgio Henrique Faria, María José Sierra, Rocío Millán, Xavier Querol, Andrés Alastuey, and José M. García-Ruíz
The Cryosphere, 15, 1157–1172, https://doi.org/10.5194/tc-15-1157-2021, https://doi.org/10.5194/tc-15-1157-2021, 2021
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Our study of the chronological sequence of Monte Perdido Glacier in the Central Pyrenees (Spain) reveals that, although the intense warming associated with the Roman period or Medieval Climate Anomaly produced important ice mass losses, it was insufficient to make this glacier disappear. By contrast, recent global warming has melted away almost 600 years of ice accumulated since the Little Ice Age, jeopardising the survival of this and other southern European glaciers over the next few decades.
Nikolaos Evangeliou, Stephen M. Platt, Sabine Eckhardt, Cathrine Lund Myhre, Paolo Laj, Lucas Alados-Arboledas, John Backman, Benjamin T. Brem, Markus Fiebig, Harald Flentje, Angela Marinoni, Marco Pandolfi, Jesus Yus-Dìez, Natalia Prats, Jean P. Putaud, Karine Sellegri, Mar Sorribas, Konstantinos Eleftheriadis, Stergios Vratolis, Alfred Wiedensohler, and Andreas Stohl
Atmos. Chem. Phys., 21, 2675–2692, https://doi.org/10.5194/acp-21-2675-2021, https://doi.org/10.5194/acp-21-2675-2021, 2021
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Following the transmission of SARS-CoV-2 to Europe, social distancing rules were introduced to prevent further spread. We investigate the impacts of the European lockdowns on black carbon (BC) emissions by means of in situ observations and inverse modelling. BC emissions declined by 23 kt in Europe during the lockdowns as compared with previous years and by 11 % as compared to the period prior to lockdowns. Residential combustion prevailed in Eastern Europe, as confirmed by remote sensing data.
Francesco Canonaco, Anna Tobler, Gang Chen, Yulia Sosedova, Jay Gates Slowik, Carlo Bozzetti, Kaspar Rudolf Daellenbach, Imad El Haddad, Monica Crippa, Ru-Jin Huang, Markus Furger, Urs Baltensperger, and André Stephan Henry Prévôt
Atmos. Meas. Tech., 14, 923–943, https://doi.org/10.5194/amt-14-923-2021, https://doi.org/10.5194/amt-14-923-2021, 2021
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Long-term ambient aerosol mass spectrometric data were analyzed with a statistical model (PMF) to obtain source contributions and fingerprints. The new aspects of this paper involve time-dependent source fingerprints by a rolling technique and the replacement of the full visual inspection of each run by a user-defined set of criteria to monitor the quality of each of these runs more efficiently. More reliable sources will finally provide better instruments for political mitigation strategies.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Thérèse Salameh, Jean Sciare, François Dulac, and Nadine Locoge
Atmos. Chem. Phys., 21, 1449–1484, https://doi.org/10.5194/acp-21-1449-2021, https://doi.org/10.5194/acp-21-1449-2021, 2021
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This study provides a better characterization of the seasonal variations in VOC sources impacting the western Mediterranean region, based on a comprehensive chemical composition measured over 25 months at a representative receptor site (Ersa) and by determining factors controlling their temporal variations. Some insights into dominant drivers for VOC concentration variations in Europe are also provided, built on comparisons of Ersa observations with the concomitant ones of 17 European sites.
Pragati Rai, Jay G. Slowik, Markus Furger, Imad El Haddad, Suzanne Visser, Yandong Tong, Atinderpal Singh, Günther Wehrle, Varun Kumar, Anna K. Tobler, Deepika Bhattu, Liwei Wang, Dilip Ganguly, Neeraj Rastogi, Ru-Jin Huang, Jaroslaw Necki, Junji Cao, Sachchida N. Tripathi, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 21, 717–730, https://doi.org/10.5194/acp-21-717-2021, https://doi.org/10.5194/acp-21-717-2021, 2021
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We present a simple conceptual framework based on elemental size distributions and enrichment factors that allows for a characterization of major sources, site-to-site similarities, and local differences and the identification of key information required for efficient policy development. Absolute concentrations are by far the highest in Delhi, followed by Beijing, and then the European cities.
Igor B. Konovalov, Nikolai A. Golovushkin, Matthias Beekmann, and Meinrat O. Andreae
Atmos. Chem. Phys., 21, 357–392, https://doi.org/10.5194/acp-21-357-2021, https://doi.org/10.5194/acp-21-357-2021, 2021
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A lack of consistent observational constraints on the atmospheric evolution of the optical properties of biomass burning (BB) aerosol limits the accuracy of assessments of the aerosol radiative and climate effects. We show that useful insights into the evolution of the BB aerosol optical properties can be inferred from a combination of satellite observations and 3D modeling. We report major changes that occurred in the optical properties of Siberian BB aerosol during its long-range transport.
Sebnem Aksoyoglu, Jianhui Jiang, Giancarlo Ciarelli, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 20, 15665–15680, https://doi.org/10.5194/acp-20-15665-2020, https://doi.org/10.5194/acp-20-15665-2020, 2020
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We investigated the role of ammonia in European air quality between 1990 and 2030 under varying land and ship emissions. If ship emissions will be regulated more strictly in the future, particulate nitrate will decrease in coastal areas in northern Europe, while sulfate aerosol will decrease in the Mediterranean region. We predict a shift in the sensitivity of aerosol formation from NH3 towards NOx emissions between 1990 and 2030 in most of Europe except the eastern part of the model domain.
Bert Verreyken, Crist Amelynck, Jérôme Brioude, Jean-François Müller, Niels Schoon, Nicolas Kumps, Aurélie Colomb, Jean-Marc Metzger, Christopher F. Lee, Theodore K. Koenig, Rainer Volkamer, and Trissevgeni Stavrakou
Atmos. Chem. Phys., 20, 14821–14845, https://doi.org/10.5194/acp-20-14821-2020, https://doi.org/10.5194/acp-20-14821-2020, 2020
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Biomass burning (BB) plumes arriving at the Maïdo observatory located in the south-west Indian Ocean during August 2018 and August 2019 are studied using trace gas measurements, Lagrangian transport models and the CAMS near-real-time atmospheric composition service. We investigate (i) secondary production of volatile organic compounds during transport, (ii) efficacy of the CAMS model to reproduce the chemical makeup of BB plumes and (iii) the impact of BB on the remote marine boundary layer.
Axel Fouqueau, Manuela Cirtog, Mathieu Cazaunau, Edouard Pangui, Pascal Zapf, Guillaume Siour, Xavier Landsheere, Guillaume Méjean, Daniele Romanini, and Bénédicte Picquet-Varrault
Atmos. Meas. Tech., 13, 6311–6323, https://doi.org/10.5194/amt-13-6311-2020, https://doi.org/10.5194/amt-13-6311-2020, 2020
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An incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) technique has been developed for the in situ monitoring of NO3 radicals in the CSA simulation chamber at LISA. The optical cavity allows a high sensitivity for NO3 detection up to 6 ppt for an integration time of 10 s. The technique is now fully operational and can be used to determine rate constants for fast reactions involving complex volatile organic compounds (with rate constants up to 10−10 cm3 molecule−1 s−1).
Cécile Guieu, Fabrizio D'Ortenzio, François Dulac, Vincent Taillandier, Andrea Doglioli, Anne Petrenko, Stéphanie Barrillon, Marc Mallet, Pierre Nabat, and Karine Desboeufs
Biogeosciences, 17, 5563–5585, https://doi.org/10.5194/bg-17-5563-2020, https://doi.org/10.5194/bg-17-5563-2020, 2020
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We describe here the objectives and strategy of the PEACETIME project and cruise, dedicated to dust deposition and its impacts in the Mediterranean Sea. Our strategy to go a step further forward than in previous approaches in understanding these impacts by catching a real deposition event at sea is detailed. We summarize the work performed at sea, the type of data acquired and their valorization in the papers published in the special issue.
Audrey Fortems-Cheiney, Gaëlle Dufour, Karine Dufossé, Florian Couvidat, Jean-Marc Gilliot, Guillaume Siour, Matthias Beekmann, Gilles Foret, Frederik Meleux, Lieven Clarisse, Pierre-François Coheur, Martin Van Damme, Cathy Clerbaux, and Sophie Génermont
Atmos. Chem. Phys., 20, 13481–13495, https://doi.org/10.5194/acp-20-13481-2020, https://doi.org/10.5194/acp-20-13481-2020, 2020
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Studies have suggested the importance of ammonia emissions on pollution particle formation over Europe, whose main atmospheric source is agriculture. In this study, we performed an inter-comparison of two alternative inventories, both with a reference inventory, that quantify the French ammonia emissions during spring 2011. Over regions with large mineral fertilizer use, like over northeastern France, NH3 emissions are probably considerably underestimated by the reference inventory.
Ashish Kumar, Vinayak Sinha, Muhammed Shabin, Haseeb Hakkim, Bernard Bonsang, and Valerie Gros
Atmos. Chem. Phys., 20, 12133–12152, https://doi.org/10.5194/acp-20-12133-2020, https://doi.org/10.5194/acp-20-12133-2020, 2020
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Source apportionment studies require information on the chemical fingerprints of pollution sources to correctly quantify source contributions to ambient composition. These chemical fingerprints vary from region to region, depending on fuel composition and combustion conditions, and are poorly constrained over developing regions such as South Asia. This work characterises the chemical fingerprints of urban and agricultural sources using 49 non-methane hydrocarbons and their environmental impacts.
Anna K. Tobler, Alicja Skiba, Dongyu S. Wang, Philip Croteau, Katarzyna Styszko, Jarosław Nęcki, Urs Baltensperger, Jay G. Slowik, and André S. H. Prévôt
Atmos. Meas. Tech., 13, 5293–5301, https://doi.org/10.5194/amt-13-5293-2020, https://doi.org/10.5194/amt-13-5293-2020, 2020
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Some quadrupole aerosol chemical speciation monitors (Q-ACSMs) have had issues with the quantification of particulate chloride, resulting in apparent negative chloride concentrations. We can show that this is due to the different behavior of Cl+ and HCl+, and we present a correction for the more accurate quantification of chloride. The correction can be applied to measurements in environments where the particulate chloride is dominated by NH4Cl.
James Brean, David C. S. Beddows, Zongbo Shi, Brice Temime-Roussel, Nicolas Marchand, Xavier Querol, Andrés Alastuey, María Cruz Minguillón, and Roy M. Harrison
Atmos. Chem. Phys., 20, 10029–10045, https://doi.org/10.5194/acp-20-10029-2020, https://doi.org/10.5194/acp-20-10029-2020, 2020
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New particle formation is a key process influencing both local air quality and climatically active cloud condensation nuclei concentrations. This study has carried out fundamental measurements of nucleation processes in Barcelona, Spain, and concludes that a mechanism involving stabilisation of sulfuric acid clusters by low molecular weight amines is primarily responsible for new particle formation events.
Liwei Wang, Jay G. Slowik, Nidhi Tripathi, Deepika Bhattu, Pragati Rai, Varun Kumar, Pawan Vats, Rangu Satish, Urs Baltensperger, Dilip Ganguly, Neeraj Rastogi, Lokesh K. Sahu, Sachchida N. Tripathi, and André S. H. Prévôt
Atmos. Chem. Phys., 20, 9753–9770, https://doi.org/10.5194/acp-20-9753-2020, https://doi.org/10.5194/acp-20-9753-2020, 2020
Martin Rigler, Luka Drinovec, Gašper Lavrič, Athanasia Vlachou, André S. H. Prévôt, Jean Luc Jaffrezo, Iasonas Stavroulas, Jean Sciare, Judita Burger, Irena Kranjc, Janja Turšič, Anthony D. A. Hansen, and Griša Močnik
Atmos. Meas. Tech., 13, 4333–4351, https://doi.org/10.5194/amt-13-4333-2020, https://doi.org/10.5194/amt-13-4333-2020, 2020
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Carbonaceous aerosols are a large fraction of fine particulate matter. They are extremely diverse, and they directly impact air quality, visibility, cloud formation and public health. In this paper we present a new instrument and new method to measure carbon content in particulate matter in real time and at a high time resolution. The new method was validated in a 1-month winter field campaign in Ljubljana, Slovenia.
Paolo Laj, Alessandro Bigi, Clémence Rose, Elisabeth Andrews, Cathrine Lund Myhre, Martine Collaud Coen, Yong Lin, Alfred Wiedensohler, Michael Schulz, John A. Ogren, Markus Fiebig, Jonas Gliß, Augustin Mortier, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, Pasi Aalto, Erik Ahlberg, Lucas Alados Arboledas, Andrés Alastuey, Marcos Andrade, Begoña Artíñano, Stina Ausmeel, Todor Arsov, Eija Asmi, John Backman, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Sébastien Conil, Cedric Couret, Derek Day, Wan Dayantolis, Anna Degorska, Konstantinos Eleftheriadis, Prodromos Fetfatzis, Olivier Favez, Harald Flentje, Maria I. Gini, Asta Gregorič, Martin Gysel-Beer, A. Gannet Hallar, Jenny Hand, Andras Hoffer, Christoph Hueglin, Rakesh K. Hooda, Antti Hyvärinen, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Jeong Eun Kim, Giorgos Kouvarakis, Irena Kranjc, Radovan Krejci, Markku Kulmala, Casper Labuschagne, Hae-Jung Lee, Heikki Lihavainen, Neng-Huei Lin, Gunter Löschau, Krista Luoma, Angela Marinoni, Sebastiao Martins Dos Santos, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Nhat Anh Nguyen, Jakub Ondracek, Noemi Pérez, Maria Rita Perrone, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Natalia Prats, Anthony Prenni, Fabienne Reisen, Salvatore Romano, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Maik Schütze, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Martin Steinbacher, Junying Sun, Gloria Titos, Barbara Toczko, Thomas Tuch, Pierre Tulet, Peter Tunved, Ville Vakkari, Fernando Velarde, Patricio Velasquez, Paolo Villani, Sterios Vratolis, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Jesus Yus-Diez, Vladimir Zdimal, Paul Zieger, and Nadezda Zikova
Atmos. Meas. Tech., 13, 4353–4392, https://doi.org/10.5194/amt-13-4353-2020, https://doi.org/10.5194/amt-13-4353-2020, 2020
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The paper establishes the fiducial reference of the GAW aerosol network providing the fully characterized value chain to the provision of four climate-relevant aerosol properties from ground-based sites. Data from almost 90 stations worldwide are reported for a reference year, 2017, providing a unique and very robust view of the variability of these variables worldwide. Current gaps in the GAW network are analysed and requirements for the Global Climate Monitoring System are proposed.
Eirini Boleti, Christoph Hueglin, Stuart K. Grange, André S. H. Prévôt, and Satoshi Takahama
Atmos. Chem. Phys., 20, 9051–9066, https://doi.org/10.5194/acp-20-9051-2020, https://doi.org/10.5194/acp-20-9051-2020, 2020
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Long-term temporal evolution of ozone concentrations between 2000 and 2015 in Europe was estimated using a signal decomposition technique. The seasonal cycles are correlated with local climate conditions and vary according to geographic region, while ozone levels are indicative of distance to emission sources. The site's environment plays a key role in ozone trends, with the most polluted environments showing the least reduction in ozone, while in less polluted areas ozone has decreased.
Fabian Rey, Erika Gobet, Christoph Schwörer, Albert Hafner, Sönke Szidat, and Willy Tinner
Clim. Past, 16, 1347–1367, https://doi.org/10.5194/cp-16-1347-2020, https://doi.org/10.5194/cp-16-1347-2020, 2020
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We present a novel post Last Glacial Maximum sediment record from Moossee (Swiss Plateau, southern central Europe). For the first time, five major reorganizations of vegetation could be definitely linked to paramount postglacial temperature and/or moisture changes. Present-day beech-dominated forests have been resilient to long-term climate change and human land use. They may prevail in future if climate warming does not exceed the amplitude of Mid Holocene temperature and moisture variability.
Martine Collaud Coen, Elisabeth Andrews, Andrés Alastuey, Todor Petkov Arsov, John Backman, Benjamin T. Brem, Nicolas Bukowiecki, Cédric Couret, Konstantinos Eleftheriadis, Harald Flentje, Markus Fiebig, Martin Gysel-Beer, Jenny L. Hand, András Hoffer, Rakesh Hooda, Christoph Hueglin, Warren Joubert, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Casper Labuschagne, Neng-Huei Lin, Yong Lin, Cathrine Lund Myhre, Krista Luoma, Hassan Lyamani, Angela Marinoni, Olga L. Mayol-Bracero, Nikos Mihalopoulos, Marco Pandolfi, Natalia Prats, Anthony J. Prenni, Jean-Philippe Putaud, Ludwig Ries, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Patrick Sheridan, James Patrick Sherman, Junying Sun, Gloria Titos, Elvis Torres, Thomas Tuch, Rolf Weller, Alfred Wiedensohler, Paul Zieger, and Paolo Laj
Atmos. Chem. Phys., 20, 8867–8908, https://doi.org/10.5194/acp-20-8867-2020, https://doi.org/10.5194/acp-20-8867-2020, 2020
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Long-term trends of aerosol radiative properties (52 stations) prove that aerosol load has significantly decreased over the last 20 years. Scattering trends are negative in Europe (EU) and North America (NA), not ss in Asia, and show a mix of positive and negative trends at polar stations. Absorption has mainly negative trends. The single scattering albedo has positive trends in Asia and eastern EU and negative in western EU and NA, leading to a global positive median trend of 0.02 % per year.
Tuukka Petäjä, Ella-Maria Duplissy, Ksenia Tabakova, Julia Schmale, Barbara Altstädter, Gerard Ancellet, Mikhail Arshinov, Yurii Balin, Urs Baltensperger, Jens Bange, Alison Beamish, Boris Belan, Antoine Berchet, Rossana Bossi, Warren R. L. Cairns, Ralf Ebinghaus, Imad El Haddad, Beatriz Ferreira-Araujo, Anna Franck, Lin Huang, Antti Hyvärinen, Angelika Humbert, Athina-Cerise Kalogridis, Pavel Konstantinov, Astrid Lampert, Matthew MacLeod, Olivier Magand, Alexander Mahura, Louis Marelle, Vladimir Masloboev, Dmitri Moisseev, Vaios Moschos, Niklas Neckel, Tatsuo Onishi, Stefan Osterwalder, Aino Ovaska, Pauli Paasonen, Mikhail Panchenko, Fidel Pankratov, Jakob B. Pernov, Andreas Platis, Olga Popovicheva, Jean-Christophe Raut, Aurélie Riandet, Torsten Sachs, Rosamaria Salvatori, Roberto Salzano, Ludwig Schröder, Martin Schön, Vladimir Shevchenko, Henrik Skov, Jeroen E. Sonke, Andrea Spolaor, Vasileios K. Stathopoulos, Mikko Strahlendorff, Jennie L. Thomas, Vito Vitale, Sterios Vratolis, Carlo Barbante, Sabine Chabrillat, Aurélien Dommergue, Konstantinos Eleftheriadis, Jyri Heilimo, Kathy S. Law, Andreas Massling, Steffen M. Noe, Jean-Daniel Paris, André S. H. Prévôt, Ilona Riipinen, Birgit Wehner, Zhiyong Xie, and Hanna K. Lappalainen
Atmos. Chem. Phys., 20, 8551–8592, https://doi.org/10.5194/acp-20-8551-2020, https://doi.org/10.5194/acp-20-8551-2020, 2020
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The role of polar regions is increasing in terms of megatrends such as globalization, new transport routes, demography, and the use of natural resources with consequent effects on regional and transported pollutant concentrations. Here we summarize initial results from our integrative project exploring the Arctic environment and pollution to deliver data products, metrics, and indicators for stakeholders.
Yunle Chen, Masayuki Takeuchi, Theodora Nah, Lu Xu, Manjula R. Canagaratna, Harald Stark, Karsten Baumann, Francesco Canonaco, André S. H. Prévôt, L. Gregory Huey, Rodney J. Weber, and Nga L. Ng
Atmos. Chem. Phys., 20, 8421–8440, https://doi.org/10.5194/acp-20-8421-2020, https://doi.org/10.5194/acp-20-8421-2020, 2020
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Two online mass spectrometry instruments, an aerosol mass spectrometer and a chemical ionization mass spectrometer equipped with a filter inlet for gases and aerosols, were deployed at Yorkville, GA, for a comprehensive characterization of organic aerosol. We observed notable secondary organic aerosol formation from isoprene and monoterpenes via different pathways during both day and night, and a series of highly oxidized acid-like compounds was found to be closely related to aged SOA.
Carl Malings, Daniel M. Westervelt, Aliaksei Hauryliuk, Albert A. Presto, Andrew Grieshop, Ashley Bittner, Matthias Beekmann, and R. Subramanian
Atmos. Meas. Tech., 13, 3873–3892, https://doi.org/10.5194/amt-13-3873-2020, https://doi.org/10.5194/amt-13-3873-2020, 2020
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Most air quality information comes from accurate but expensive instruments. These can be supplemented by lower-cost sensors to increase the density of ground data and expand monitoring into less well-instrumented areas, like sub-Saharan Africa. In this paper, we look at how low-cost sensor data can be combined with satellite information on air quality (which requires ground data to properly calibrate measurements) and assess the benefits these low-cost sensors provide in this context.
Eve-Agnès Fiorentino, Henri Wortham, and Karine Sartelet
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2020-192, https://doi.org/10.5194/gmd-2020-192, 2020
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Solène Turquety, Laurent Menut, Guillaume Siour, Sylvain Mailler, Juliette Hadji-Lazaro, Maya George, Cathy Clerbaux, Daniel Hurtmans, and Pierre-François Coheur
Geosci. Model Dev., 13, 2981–3009, https://doi.org/10.5194/gmd-13-2981-2020, https://doi.org/10.5194/gmd-13-2981-2020, 2020
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Biomass burning emissions are a major source of trace gases and aerosols that need to be accounted for in air quality assessment and forecasting. The APIFLAME model presented in this paper allows the calculation of these emissions based on merged satellite observations at hourly time steps and kilometer scales. Implementing emissions in a chemistry transport model allows realistic simulations of fire plumes as illustrated for wildfires in Portugal in August 2016 using the CHIMERE model.
Lu Qi, Alexander L. Vogel, Sepideh Esmaeilirad, Liming Cao, Jing Zheng, Jean-Luc Jaffrezo, Paola Fermo, Anne Kasper-Giebl, Kaspar R. Daellenbach, Mindong Chen, Xinlei Ge, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 20, 7875–7893, https://doi.org/10.5194/acp-20-7875-2020, https://doi.org/10.5194/acp-20-7875-2020, 2020
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We present the first application of this online and offline strategy using the new extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF), which achieves increased chemical specificity relative to other online techniques. Measurement and source apportionment of 1 year of filter samples collected in Zurich, Switzerland, show seasonal contributions from fresh and aged wood combustion in winter and biogenic emission-derived SOA in summer, as well as other sources.
Lya Lugon, Karine Sartelet, Youngseob Kim, Jérémy Vigneron, and Olivier Chrétien
Atmos. Chem. Phys., 20, 7717–7740, https://doi.org/10.5194/acp-20-7717-2020, https://doi.org/10.5194/acp-20-7717-2020, 2020
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This study presents a new version of the multi-scale model Street-in-Grid (SinG) that interconnects regional and local scales in air-quality modeling in urban areas. The new version of SinG performs the finest coupling between transport and chemistry, leading to a numerically stable partitioning between NO and NO2. Multi-scale, local-scale and regional-scale simulations of NO, NO2 and NOx over Paris are compared to observations, and SinG shows good performance for both local and regional scales.
Jean-Luc Baray, Laurent Deguillaume, Aurélie Colomb, Karine Sellegri, Evelyn Freney, Clémence Rose, Joël Van Baelen, Jean-Marc Pichon, David Picard, Patrick Fréville, Laëtitia Bouvier, Mickaël Ribeiro, Pierre Amato, Sandra Banson, Angelica Bianco, Agnès Borbon, Lauréline Bourcier, Yannick Bras, Marcello Brigante, Philippe Cacault, Aurélien Chauvigné, Tiffany Charbouillot, Nadine Chaumerliac, Anne-Marie Delort, Marc Delmotte, Régis Dupuy, Antoine Farah, Guy Febvre, Andrea Flossmann, Christophe Gourbeyre, Claude Hervier, Maxime Hervo, Nathalie Huret, Muriel Joly, Victor Kazan, Morgan Lopez, Gilles Mailhot, Angela Marinoni, Olivier Masson, Nadège Montoux, Marius Parazols, Frédéric Peyrin, Yves Pointin, Michel Ramonet, Manon Rocco, Martine Sancelme, Stéphane Sauvage, Martina Schmidt, Emmanuel Tison, Mickaël Vaïtilingom, Paolo Villani, Miao Wang, Camille Yver-Kwok, and Paolo Laj
Atmos. Meas. Tech., 13, 3413–3445, https://doi.org/10.5194/amt-13-3413-2020, https://doi.org/10.5194/amt-13-3413-2020, 2020
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CO-PDD (Cézeaux-Aulnat-Opme-puy de Dôme) is a fully instrumented platform for atmospheric research. The four sites located at different altitudes from 330 to 1465 m around Clermont-Ferrand (France) host in situ and remote sensing instruments to measure atmospheric composition, including long-term trends and variability, to study interconnected processes (microphysical, chemical, biological, chemical, and dynamical) and to provide a reference point for climate models.
Luyao Tu, Paul Zander, Sönke Szidat, Ronald Lloren, and Martin Grosjean
Biogeosciences, 17, 2715–2729, https://doi.org/10.5194/bg-17-2715-2020, https://doi.org/10.5194/bg-17-2715-2020, 2020
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In a small, deep lake on the Swiss Plateau, net fluxes of labile P fractions in sediments that can be released to surface waters have been predominately controlled by past hypolimnetic anoxic conditions since the early 1900s. More than 40 years of hypolimnetic withdrawal can effectively reduce net P fluxes in sediments and internal P loads but not effectively decrease eutrophication. These findings should likely serve the management of deep eutrophic lakes in temperate zones.
Antonio Tovar-Sánchez, Araceli Rodríguez-Romero, Anja Engel, Birthe Zäncker, Franck Fu, Emilio Marañón, María Pérez-Lorenzo, Matthieu Bressac, Thibaut Wagener, Sylvain Triquet, Guillaume Siour, Karine Desboeufs, and Cécile Guieu
Biogeosciences, 17, 2349–2364, https://doi.org/10.5194/bg-17-2349-2020, https://doi.org/10.5194/bg-17-2349-2020, 2020
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Residence times of particulate metals derived from aerosol deposition in the Sea Surface Microlayer of the Mediterranean Sea ranged from a couple of minutes (e.g., for Fe) to a few hours (e.g., for Cu). Microbial activity seems to play an important role in in this process and in the concentration and distribution of metals between diferent water layers.
Marcel Bliedtner, Hans von Suchodoletz, Imke Schäfer, Caroline Welte, Gary Salazar, Sönke Szidat, Mischa Haas, Nathalie Dubois, and Roland Zech
Hydrol. Earth Syst. Sci., 24, 2105–2120, https://doi.org/10.5194/hess-24-2105-2020, https://doi.org/10.5194/hess-24-2105-2020, 2020
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This study investigates the age and origin of leaf wax n-alkanes from a fluvial sediment–paleosol sequence (FSPS) by compound-class 14C dating. Our results show varying age offsets between the formation and sedimentation of leaf wax n-alkanes from well-developed (paleo)soils and fluvial sediments that are mostly due to their complex origin in such sequences. Thus, dating the leaf wax n-alkanes is an important step for more robust leaf-wax-based paleoenvironmental reconstructions in FSPSs.
Victor Lannuque, Florian Couvidat, Marie Camredon, Bernard Aumont, and Bertrand Bessagnet
Atmos. Chem. Phys., 20, 4905–4931, https://doi.org/10.5194/acp-20-4905-2020, https://doi.org/10.5194/acp-20-4905-2020, 2020
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Large uncertainties remain in modeling secondary organic aerosol (SOA) and evolution and properties in air quality models. In this article, the recently developed VBS-GECKO parameterization for SOA formation has been implemented in the air quality model CHIMERE. Simulations have been driven to identify the main SOA sources and to evaluate the sensitivity of simulated SOA concentrations to (i) secondary organic compound properties and (ii) emissions from traffic and transportation sources.
Laurent Menut, Guillaume Siour, Bertrand Bessagnet, Florian Couvidat, Emilie Journet, Yves Balkanski, and Karine Desboeufs
Geosci. Model Dev., 13, 2051–2071, https://doi.org/10.5194/gmd-13-2051-2020, https://doi.org/10.5194/gmd-13-2051-2020, 2020
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Modelling of mineral dust is often done using one single mean species. In this study, differentiated mineral species with their chemical composition are implemented in the CHIMERE regional chemistry-transport model by using global databases. Simulations are carried out to quantify the realism and gain of such mineralogy.
Cyrielle Denjean, Thierry Bourrianne, Frederic Burnet, Marc Mallet, Nicolas Maury, Aurélie Colomb, Pamela Dominutti, Joel Brito, Régis Dupuy, Karine Sellegri, Alfons Schwarzenboeck, Cyrille Flamant, and Peter Knippertz
Atmos. Chem. Phys., 20, 4735–4756, https://doi.org/10.5194/acp-20-4735-2020, https://doi.org/10.5194/acp-20-4735-2020, 2020
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This paper presents aircraft measurements of aerosol optical properties over southern West Africa. We show that aerosol optical properties in the boundary layer were dominated by a persistent biomass burning loading from the Southern Hemisphere. Biomass burning aerosols were more light absorbing that those previously measured in other areas (Amazonia, North America). Our study suggests that lens-coated black carbon particles were the dominant absorber for these biomass burning aerosols.
Paul D. Zander, Sönke Szidat, Darrell S. Kaufman, Maurycy Żarczyński, Anna I. Poraj-Górska, Petra Boltshauser-Kaltenrieder, and Martin Grosjean
Geochronology, 2, 63–79, https://doi.org/10.5194/gchron-2-63-2020, https://doi.org/10.5194/gchron-2-63-2020, 2020
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Recent technological advances allow researchers to obtain radiocarbon ages from smaller samples than previously possible. We investigate the reliability and precision of radiocarbon ages obtained from miniature (11–150 μg C) samples of terrestrial plant fragments taken from sediment cores from Lake Żabińskie, Poland. We further investigate how sampling density (the number of ages per 1000 years) and sample mass (which is related to age precision) influence the performance of age–depth models.
Pavlos Kalabokas, Niels Roland Jensen, Mauro Roveri, Jens Hjorth, Maxim Eremenko, Juan Cuesta, Gaëlle Dufour, Gilles Foret, and Matthias Beekmann
Atmos. Chem. Phys., 20, 1861–1885, https://doi.org/10.5194/acp-20-1861-2020, https://doi.org/10.5194/acp-20-1861-2020, 2020
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The influence of tropospheric ozone on the surface measurements at a regional air pollution station in the pre-Alpine area of northern Italy is investigated. During such episodes the local air pollution parameters show generally very low values, while the ozone levels reach high values, occasionally exceeding the ozone air quality standards. Better understanding of ozone variability over the examined region will help in the formulation of more effective policies for the environment and climate.
Pragati Rai, Markus Furger, Jay G. Slowik, Francesco Canonaco, Roman Fröhlich, Christoph Hüglin, María Cruz Minguillón, Krag Petterson, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 20, 1657–1674, https://doi.org/10.5194/acp-20-1657-2020, https://doi.org/10.5194/acp-20-1657-2020, 2020
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A source apportionment study of hourly resolved elements in PM10 measured at a traffic-influenced site in Härkingen, Switzerland, using positive matrix factorization (PMF) and multilinear engine-2 (ME-2) offered resolution of robust and unambiguous factor profiles and contributions. We show that the rotational control available in ME-2 provides a means for treating extreme events such as fireworks within a PMF analysis.
Sandy Bsaibes, Mohamad Al Ajami, Kenneth Mermet, François Truong, Sébastien Batut, Christophe Hecquet, Sébastien Dusanter, Thierry Léornadis, Stéphane Sauvage, Julien Kammer, Pierre-Marie Flaud, Emilie Perraudin, Eric Villenave, Nadine Locoge, Valérie Gros, and Coralie Schoemaecker
Atmos. Chem. Phys., 20, 1277–1300, https://doi.org/10.5194/acp-20-1277-2020, https://doi.org/10.5194/acp-20-1277-2020, 2020
Marco Paglione, Stefania Gilardoni, Matteo Rinaldi, Stefano Decesari, Nicola Zanca, Silvia Sandrini, Lara Giulianelli, Dimitri Bacco, Silvia Ferrari, Vanes Poluzzi, Fabiana Scotto, Arianna Trentini, Laurent Poulain, Hartmut Herrmann, Alfred Wiedensohler, Francesco Canonaco, André S. H. Prévôt, Paola Massoli, Claudio Carbone, Maria Cristina Facchini, and Sandro Fuzzi
Atmos. Chem. Phys., 20, 1233–1254, https://doi.org/10.5194/acp-20-1233-2020, https://doi.org/10.5194/acp-20-1233-2020, 2020
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Our multi-year observational study regarding organic aerosol (OA) in the Po Valley indicates that more than half of OA is of secondary origin (SOA) through all the year and at both urban and rural sites. Within the SOA, the measurements show the importance of biomass burning (BB) aging products during cold seasons and indicate aqueous-phase processing of BB emissions as a fundamental driver of SOA formation in wintertime, with important consequences for air quality policy at the global level.
Marco Pandolfi, Dennis Mooibroek, Philip Hopke, Dominik van Pinxteren, Xavier Querol, Hartmut Herrmann, Andrés Alastuey, Olivier Favez, Christoph Hüglin, Esperanza Perdrix, Véronique Riffault, Stéphane Sauvage, Eric van der Swaluw, Oksana Tarasova, and Augustin Colette
Atmos. Chem. Phys., 20, 409–429, https://doi.org/10.5194/acp-20-409-2020, https://doi.org/10.5194/acp-20-409-2020, 2020
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In the last scientific assessment report from the LRTAP Convention, it is stated that because non-urban sources are often major contributors to urban pollution, many cities will be unable to meet WHO guideline levels for air pollutants through local action alone. Consequently, it is very important to estimate how much the local and non-local sources contribute to urban pollution in order to design global strategies to reduce the levels of pollutants in European cities.
Jianhui Jiang, Sebnem Aksoyoglu, Imad El-Haddad, Giancarlo Ciarelli, Hugo A. C. Denier van der Gon, Francesco Canonaco, Stefania Gilardoni, Marco Paglione, María Cruz Minguillón, Olivier Favez, Yunjiang Zhang, Nicolas Marchand, Liqing Hao, Annele Virtanen, Kalliopi Florou, Colin O'Dowd, Jurgita Ovadnevaite, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 19, 15247–15270, https://doi.org/10.5194/acp-19-15247-2019, https://doi.org/10.5194/acp-19-15247-2019, 2019
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We use an air quality model with a modified organic aerosol (OA) module based on chamber experiments to identify the OA sources and their contributions in Europe. Comparisons with long-term measurements at nine sites in 2011 show an improvement in OA simulation. Our results suggest that the biomass burning and biogenic emissions are the dominant sources in winter and summer, respectively. Contributions of diesel and gasoline vehicles are relatively small compared to a previous study in the US.
Baye T. P. Thera, Pamela Dominutti, Fatma Öztürk, Thérèse Salameh, Stéphane Sauvage, Charbel Afif, Banu Çetin, Cécile Gaimoz, Melek Keleş, Stéphanie Evan, and Agnès Borbon
Atmos. Chem. Phys., 19, 15131–15156, https://doi.org/10.5194/acp-19-15131-2019, https://doi.org/10.5194/acp-19-15131-2019, 2019
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A large set of volatile organic compound observations was collected for the first time in Istanbul in September 2014. A source–receptor approach has been carried out to apportion emission sources, estimate anthropogenic emissions, and evaluate emission inventories. Unexpectedly, transport was not the most dominant source in this study. Our work stresses the need to better represent VOC emissions in the eastern Mediterranean region with an effort on non-traffic sources and oxygenated VOCs.
Giulia Stefenelli, Veronika Pospisilova, Felipe D. Lopez-Hilfiker, Kaspar R. Daellenbach, Christoph Hüglin, Yandong Tong, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 19, 14825–14848, https://doi.org/10.5194/acp-19-14825-2019, https://doi.org/10.5194/acp-19-14825-2019, 2019
Aurélien Chauvigné, Diego Aliaga, Karine Sellegri, Nadège Montoux, Radovan Krejci, Griša Močnik, Isabel Moreno, Thomas Müller, Marco Pandolfi, Fernando Velarde, Kay Weinhold, Patrick Ginot, Alfred Wiedensohler, Marcos Andrade, and Paolo Laj
Atmos. Chem. Phys., 19, 14805–14824, https://doi.org/10.5194/acp-19-14805-2019, https://doi.org/10.5194/acp-19-14805-2019, 2019
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The study presents for the first time the analysis of aerosol optical properties at the unique high-altitude station of Chacaltaya, Bolivia. Ideally located, the station allows us to better understand influences of urban areas and the Amazon Forest on tropospheric properties. An emerging method is applied to characterize aerosol origins and permits us to illustrate evidence of natural and anthropogenic influences.
Yunjiang Zhang, Olivier Favez, Jean-Eudes Petit, Francesco Canonaco, Francois Truong, Nicolas Bonnaire, Vincent Crenn, Tanguy Amodeo, Andre S. H. Prévôt, Jean Sciare, Valerie Gros, and Alexandre Albinet
Atmos. Chem. Phys., 19, 14755–14776, https://doi.org/10.5194/acp-19-14755-2019, https://doi.org/10.5194/acp-19-14755-2019, 2019
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We present 6-year source apportionment of organic aerosol (OA) achieved with near-continuous online measurements and subsequent receptor model analysis in the Paris region, France. The OA factors presented distinct seasonal patterns, associated with different atmospheric formation processes and roles in air pollution. Limited year-round trends for two primary anthropogenic factors and a biogenic-like secondary factor were observed, while a more oxidized secondary OA showed a decreasing feature.
Jun Zhou, Miriam Elser, Ru-Jin Huang, Manuel Krapf, Roman Fröhlich, Deepika Bhattu, Giulia Stefenelli, Peter Zotter, Emily A. Bruns, Simone M. Pieber, Haiyan Ni, Qiyuan Wang, Yichen Wang, Yaqing Zhou, Chunying Chen, Mao Xiao, Jay G. Slowik, Samuel Brown, Laure-Estelle Cassagnes, Kaspar R. Daellenbach, Thomas Nussbaumer, Marianne Geiser, André S. H. Prévôt, Imad El-Haddad, Junji Cao, Urs Baltensperger, and Josef Dommen
Atmos. Chem. Phys., 19, 14703–14720, https://doi.org/10.5194/acp-19-14703-2019, https://doi.org/10.5194/acp-19-14703-2019, 2019
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Reactive oxygen species (ROS) are believed to contribute to the adverse health effects of aerosols. We measured particle-bound ROS (PB-ROS) with an online instrument in two distinct environments, i.e., Beijing (China) and Bern (Switzerland). In both cities these exogenic ROS are predominantly related to secondary organic aerosol (SOA). PB-ROS content in SOA from various anthropogenic emission sources tested in the laboratory was comparable to that in the ambient measurements.
Giancarlo Ciarelli, Mark R. Theobald, Marta G. Vivanco, Matthias Beekmann, Wenche Aas, Camilla Andersson, Robert Bergström, Astrid Manders-Groot, Florian Couvidat, Mihaela Mircea, Svetlana Tsyro, Hilde Fagerli, Kathleen Mar, Valentin Raffort, Yelva Roustan, Maria-Teresa Pay, Martijn Schaap, Richard Kranenburg, Mario Adani, Gino Briganti, Andrea Cappelletti, Massimo D'Isidoro, Cornelis Cuvelier, Arineh Cholakian, Bertrand Bessagnet, Peter Wind, and Augustin Colette
Geosci. Model Dev., 12, 4923–4954, https://doi.org/10.5194/gmd-12-4923-2019, https://doi.org/10.5194/gmd-12-4923-2019, 2019
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The novel multi-model EURODELTA-Trends exercise provided 21 years of continuous PM components and their gas-phase precursor concentrations over Europe from the year 1990. The models’ capabilities to reproduce PM components and gas-phase PM precursor trends over the 1990–2010 period is the key focus of this study. The models were able to reproduce the observed trends relatively well, indicating a possible shift in the thermodynamic equilibrium between gas and particle phases.
Rupert Holzinger, W. Joe F. Acton, William J. Bloss, Martin Breitenlechner, Leigh R. Crilley, Sébastien Dusanter, Marc Gonin, Valerie Gros, Frank N. Keutsch, Astrid Kiendler-Scharr, Louisa J. Kramer, Jordan E. Krechmer, Baptiste Languille, Nadine Locoge, Felipe Lopez-Hilfiker, Dušan Materić, Sergi Moreno, Eiko Nemitz, Lauriane L. J. Quéléver, Roland Sarda Esteve, Stéphane Sauvage, Simon Schallhart, Roberto Sommariva, Ralf Tillmann, Sergej Wedel, David R. Worton, Kangming Xu, and Alexander Zaytsev
Atmos. Meas. Tech., 12, 6193–6208, https://doi.org/10.5194/amt-12-6193-2019, https://doi.org/10.5194/amt-12-6193-2019, 2019
Kenneth Mermet, Stéphane Sauvage, Sébastien Dusanter, Thérèse Salameh, Thierry Léonardis, Pierre-M. Flaud, Émilie Perraudin, Éric Villenave, and Nadine Locoge
Atmos. Meas. Tech., 12, 6153–6171, https://doi.org/10.5194/amt-12-6153-2019, https://doi.org/10.5194/amt-12-6153-2019, 2019
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An automated system for the online ambient measurement of 20 biogenic volatile organic compounds (BVOCs) was successfully developed and optimized. The analytical performance was satisfying for ambient measurements. The first measurements were carried out during the LANDEX field campaign in summer 2017. The 3-week field measurements displayed the excellent performance of the method with respect to providing speciated BVOC concentration values to further investigate atmospheric BVOCs' reactivity.
Radiance Calmer, Gregory C. Roberts, Kevin J. Sanchez, Jean Sciare, Karine Sellegri, David Picard, Mihalis Vrekoussis, and Michael Pikridas
Atmos. Chem. Phys., 19, 13989–14007, https://doi.org/10.5194/acp-19-13989-2019, https://doi.org/10.5194/acp-19-13989-2019, 2019
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Unmanned aerial vehicles (UAVs) bring new opportunities to study clouds and better represent these in models. This analysis presents a comparison between direct observations in clouds from a UAV flight and results of a one-dimension model. The experiment is part of the European BACCHUS project, and took place in Cyprus, considered as a polluted environment. The study shows the importance of taking into account mixing air at cloud top to better match the model results with the UAV observations.
Clémence Rose, Brice Foucart, David Picard, Aurélie Colomb, Jean-Marc Metzger, Pierre Tulet, and Karine Sellegri
Atmos. Chem. Phys., 19, 13243–13265, https://doi.org/10.5194/acp-19-13243-2019, https://doi.org/10.5194/acp-19-13243-2019, 2019
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New particle formation (NPF) is a significant climate-relevant source of aerosols in the atmosphere. We show that during the eruptive periods of the Piton de la Fournaise in 2015, NPF was favoured compared to regular days. Using the largest dataset ever reported in volcanic plume conditions, we quantify the emission rates of particles over a broad size range and provide a new statistically robust parameterization to take into account this important source of atmospheric particles in models.
Arineh Cholakian, Matthias Beekmann, Isabelle Coll, Giancarlo Ciarelli, and Augustin Colette
Atmos. Chem. Phys., 19, 13209–13226, https://doi.org/10.5194/acp-19-13209-2019, https://doi.org/10.5194/acp-19-13209-2019, 2019
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Organic aerosol simulation schemes were tested in climatic runs to assess their climate sensitivity. The test for each scheme contains five historic and five future years of simulation. Validation was performed for the three schemes to assess their performance compared to measured data. Results show that the scheme taking into account fragmentation and formation of nonvolatile secondary organic aerosol (SOA) shows higher relative biogenic SOA (BSOA) changes than historic and future scenarios.
Xiaoli Shen, Heike Vogel, Bernhard Vogel, Wei Huang, Claudia Mohr, Ramakrishna Ramisetty, Thomas Leisner, André S. H. Prévôt, and Harald Saathoff
Atmos. Chem. Phys., 19, 13189–13208, https://doi.org/10.5194/acp-19-13189-2019, https://doi.org/10.5194/acp-19-13189-2019, 2019
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This study provides good insight into the chemical nature and complex origin of aerosols by combining comprehensive field observations and transport modelling. We suggest that factors related to topography, metrological conditions, local emissions, in situ formation and growth, regional transport, and the interaction of biogenic and anthropogenic compounds need to be considered for a comprehensive understanding of aerosol processes.
Igor B. Konovalov, Matthias Beekmann, Nikolai A. Golovushkin, and Meinrat O. Andreae
Atmos. Chem. Phys., 19, 12091–12119, https://doi.org/10.5194/acp-19-12091-2019, https://doi.org/10.5194/acp-19-12091-2019, 2019
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Biomass burning (BB) aerosol has a strong impact on air quality and climate, but a wide diversity of observed effects of its atmospheric transformations (aging) is not yet sufficiently understood and thus not addressed in models. Based on the results of numerical experiments involving a box model, we show that part of this diversity can be due to the factors associated with the intrinsic nonlinearity of the processes governing the atmospheric evolution of organic components of BB aerosol.
Pamela Dominutti, Sekou Keita, Julien Bahino, Aurélie Colomb, Cathy Liousse, Véronique Yoboué, Corinne Galy-Lacaux, Eleanor Morris, Laëtitia Bouvier, Stéphane Sauvage, and Agnès Borbon
Atmos. Chem. Phys., 19, 11721–11741, https://doi.org/10.5194/acp-19-11721-2019, https://doi.org/10.5194/acp-19-11721-2019, 2019
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Several field campaigns were performed in southern West Africa in the framework of the DACCIWA project with the purpose of measuring a broad range of atmospheric constituents. Our study presents the analysis of a comprehensive dataset which integrates up to 56 species of VOCs measured at different ambient sites and emission sources. Our detailed VOC estimation for Cote d'Ivoire is 3 to 6 times higher than the whole of Europe, transportation being the dominant source of VOCs.
Giulia Stefenelli, Jianhui Jiang, Amelie Bertrand, Emily A. Bruns, Simone M. Pieber, Urs Baltensperger, Nicolas Marchand, Sebnem Aksoyoglu, André S. H. Prévôt, Jay G. Slowik, and Imad El Haddad
Atmos. Chem. Phys., 19, 11461–11484, https://doi.org/10.5194/acp-19-11461-2019, https://doi.org/10.5194/acp-19-11461-2019, 2019
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Box model simulations, based on the volatility basis set approach, of smog chamber wood combustion experiments conducted at different temperatures (−10 °C, 2 °C, 15 °C), emission loads, combustion conditions (flaming and smoldering) and residential stoves fabricated in the last 2 decades. Novel parameterization methods based on a genetic algorithm approach allowed estimation of precursor class contributions to SOA and evaluation of the effect of emission variability on SOA yield predictions.
Felipe D. Lopez-Hilfiker, Veronika Pospisilova, Wei Huang, Markus Kalberer, Claudia Mohr, Giulia Stefenelli, Joel A. Thornton, Urs Baltensperger, Andre S. H. Prevot, and Jay G. Slowik
Atmos. Meas. Tech., 12, 4867–4886, https://doi.org/10.5194/amt-12-4867-2019, https://doi.org/10.5194/amt-12-4867-2019, 2019
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We present a novel, field-deployable extractive electrospray time-of-flight mass spectrometer (EESI-TOF), which provides real-time, near-molecular measurements of organic aerosol at atmospherically relevant concentrations, addressing a critical gap in existing measurement capabilities. Successful deployments of the EESI-TOF for laboratory measurements, ground-based ambient sampling, and aboard a research aircraft highlight the versatility and potential of the EESI-TOF system.
Abdoulaye Samaké, Jean-Luc Jaffrezo, Olivier Favez, Samuël Weber, Véronique Jacob, Trishalee Canete, Alexandre Albinet, Aurélie Charron, Véronique Riffault, Esperanza Perdrix, Antoine Waked, Benjamin Golly, Dalia Salameh, Florie Chevrier, Diogo Miguel Oliveira, Jean-Luc Besombes, Jean M. F. Martins, Nicolas Bonnaire, Sébastien Conil, Géraldine Guillaud, Boualem Mesbah, Benoit Rocq, Pierre-Yves Robic, Agnès Hulin, Sébastien Le Meur, Maxence Descheemaecker, Eve Chretien, Nicolas Marchand, and Gaëlle Uzu
Atmos. Chem. Phys., 19, 11013–11030, https://doi.org/10.5194/acp-19-11013-2019, https://doi.org/10.5194/acp-19-11013-2019, 2019
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We conducted a large study focusing on the daily (24 h) PM10 sugar compound (SC) concentrations for 16 increasing space-scale sites in France (local to nationwide) over at least 1 complete year. Our main results clearly show distance-dependent covariation patterns, with SC concentrations being highly synchronous at an urban city scale and remaining well correlated throughout the same geographic regions. However, sampling sites located in two distinct geographic areas are poorly correlated.
Valentin Duflot, Pierre Tulet, Olivier Flores, Christelle Barthe, Aurélie Colomb, Laurent Deguillaume, Mickael Vaïtilingom, Anne Perring, Alex Huffman, Mark T. Hernandez, Karine Sellegri, Ellis Robinson, David J. O'Connor, Odessa M. Gomez, Frédéric Burnet, Thierry Bourrianne, Dominique Strasberg, Manon Rocco, Allan K. Bertram, Patrick Chazette, Julien Totems, Jacques Fournel, Pierre Stamenoff, Jean-Marc Metzger, Mathilde Chabasset, Clothilde Rousseau, Eric Bourrianne, Martine Sancelme, Anne-Marie Delort, Rachel E. Wegener, Cedric Chou, and Pablo Elizondo
Atmos. Chem. Phys., 19, 10591–10618, https://doi.org/10.5194/acp-19-10591-2019, https://doi.org/10.5194/acp-19-10591-2019, 2019
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The Forests gAses aeRosols Clouds Exploratory (FARCE) campaign was conducted in March–April 2015 on the tropical island of La Réunion. For the first time, several scientific teams from different disciplines collaborated to provide reference measurements and characterization of La Réunion vegetation, volatile organic compounds (VOCs), biogenic VOCs (BVOCs), (bio)aerosols and composition of clouds, with a strong focus on the Maïdo mount slope area.
Lu Qi, Mindong Chen, Giulia Stefenelli, Veronika Pospisilova, Yandong Tong, Amelie Bertrand, Christoph Hueglin, Xinlei Ge, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 19, 8037–8062, https://doi.org/10.5194/acp-19-8037-2019, https://doi.org/10.5194/acp-19-8037-2019, 2019
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Current understanding of OA sources is limited by the chemical resolution of existing real-time measurement technology. We describe the first wintertime deployment of a novel extractive electrospray ionization time-of-flight mass spectrometer, which provides near-molecular OA measurements with high time resolution. We show that biomass combustion strongly influences winter OA. Via factor analysis, aging-dependent signatures and time contributions of biomass-combustion-derived OA are resolved.
Athanasia Vlachou, Anna Tobler, Houssni Lamkaddam, Francesco Canonaco, Kaspar R. Daellenbach, Jean-Luc Jaffrezo, María Cruz Minguillón, Marek Maasikmets, Erik Teinemaa, Urs Baltensperger, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 19, 7279–7295, https://doi.org/10.5194/acp-19-7279-2019, https://doi.org/10.5194/acp-19-7279-2019, 2019
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The resolution of rotational ambiguity in positive matrix factorization (PMF) models is a major challenge. Here, we developed a method based on bootstrapping and correlations to extract environmentally meaningful solutions from PMF analysis based on offline aerosol mass spectrometry data. The method has been tested on a dataset that covers 1 full year of filter samples collected at three different sites in Estonia.
Miriam Elser, Benjamin Tobias Brem, Lukas Durdina, David Schönenberger, Frithjof Siegerist, Andrea Fischer, and Jing Wang
Atmos. Chem. Phys., 19, 6809–6820, https://doi.org/10.5194/acp-19-6809-2019, https://doi.org/10.5194/acp-19-6809-2019, 2019
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This work presents the link between the chemical composition and the optical properties of the aerosol emissions of an aircraft turbofan using conventional and alternative fuels. A high organic carbon fraction at low thrusts is linked to high single scattering albedos. The optical properties at cruise conditions are used to evaluate the radiative forcing efficiency of aircraft aerosol emissions, which have a substantial warming effect when emitted over highly reflective surfaces such as snow.
Mathieu Lachatre, Audrey Fortems-Cheiney, Gilles Foret, Guillaume Siour, Gaëlle Dufour, Lieven Clarisse, Cathy Clerbaux, Pierre-François Coheur, Martin Van Damme, and Matthias Beekmann
Atmos. Chem. Phys., 19, 6701–6716, https://doi.org/10.5194/acp-19-6701-2019, https://doi.org/10.5194/acp-19-6701-2019, 2019
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It has been observed from satellite-based instruments that ammonia levels strongly increased between 2011 and 2015. We have used the CHIMERE CTM to understand what could explain such an increase. We first focused on meteorological condition variations, and it has been concluded that meteorology did not explain ammonia evolution. Then, we focused on SO2 and NOx emission evolution rates to evaluate their influences on ammonia. It appears that theses decreases were the main explanation.
Kaspar R. Daellenbach, Ivan Kourtchev, Alexander L. Vogel, Emily A. Bruns, Jianhui Jiang, Tuukka Petäjä, Jean-Luc Jaffrezo, Sebnem Aksoyoglu, Markus Kalberer, Urs Baltensperger, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 19, 5973–5991, https://doi.org/10.5194/acp-19-5973-2019, https://doi.org/10.5194/acp-19-5973-2019, 2019
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Here we present the molecular composition of the organic aerosol (OA) at an urban site in Central Europe (Zurich, Switzerland) and compare it to smog chamber wood smoke and ambient biogenic secondary OA (SOA) (Orbitrap analyses). Accordingly, we are able to explain the strong seasonality of the molecular composition by aged wood smoke and biogenic SOA during winter and summer. Our results could also explain the predominance of non-fossil organic carbon at European locations throughout the year.
Marwa Majdi, Karine Sartelet, Grazia Maria Lanzafame, Florian Couvidat, Youngseob Kim, Mounir Chrit, and Solene Turquety
Atmos. Chem. Phys., 19, 5543–5569, https://doi.org/10.5194/acp-19-5543-2019, https://doi.org/10.5194/acp-19-5543-2019, 2019
David Picard, Michel Attoui, and Karine Sellegri
Atmos. Meas. Tech., 12, 2531–2543, https://doi.org/10.5194/amt-12-2531-2019, https://doi.org/10.5194/amt-12-2531-2019, 2019
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We report here how we managed to improve the performance of an aerosol particle counter model TSI3010. Our device is based on a secondhand unit and reuses its core elements (saturator, condenser, optics). We redesigned the electronics and thermal management. Laboratory experiments show that the cutoff diameter was decreased from 10 to 2.5 nm, bringing the B3010 close to more complex and expensive products. These results may help designers and users improve the performance of their devices.
Aurélie Charron, Lucie Polo-Rehn, Jean-Luc Besombes, Benjamin Golly, Christine Buisson, Hervé Chanut, Nicolas Marchand, Géraldine Guillaud, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 19, 5187–5207, https://doi.org/10.5194/acp-19-5187-2019, https://doi.org/10.5194/acp-19-5187-2019, 2019
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This research quantified particulate species that could be used to trace non-exhaust and exhaust traffic emissions. Results showed the important contribution of heavy metals from brake wear to total particulate traffic emissions. In France the traffic largely dominated by diesel vehicles led to important emissions of elemental carbon, as well as significant emissions of low-molecular-weight polycyclic aromatic compounds.
Arineh Cholakian, Augustin Colette, Isabelle Coll, Giancarlo Ciarelli, and Matthias Beekmann
Atmos. Chem. Phys., 19, 4459–4484, https://doi.org/10.5194/acp-19-4459-2019, https://doi.org/10.5194/acp-19-4459-2019, 2019
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Multiple future scenario sets have been compared to reference simulations in order to assess the effects of different climate change drivers (regional climate, anthropogenic emissions, long-range transport) on the concentration of PM10 and its components. The effect of different meteorological parameters has been explored on the concentration of PM components in the case of changes due to regional climate. A cumulative impact study on the three aforementioned drivers has also been included.
Karl Espen Yttri, David Simpson, Robert Bergström, Gyula Kiss, Sönke Szidat, Darius Ceburnis, Sabine Eckhardt, Christoph Hueglin, Jacob Klenø Nøjgaard, Cinzia Perrino, Ignazio Pisso, Andre Stephan Henry Prevot, Jean-Philippe Putaud, Gerald Spindler, Milan Vana, Yan-Lin Zhang, and Wenche Aas
Atmos. Chem. Phys., 19, 4211–4233, https://doi.org/10.5194/acp-19-4211-2019, https://doi.org/10.5194/acp-19-4211-2019, 2019
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Carbonaceous aerosols from natural sources were abundant regardless of season. Residential wood burning (RWB) emissions were occasionally equally as large as or larger than of fossil-fuel sources, depending on season and region. RWB emissions are poorly constrained; thus emissions inventories need improvement. Harmonizing emission factors between countries is likely the most important step to improve model calculations for biomass burning emissions and European PM2.5 concentrations in general.
Jianhui Jiang, Sebnem Aksoyoglu, Giancarlo Ciarelli, Emmanouil Oikonomakis, Imad El-Haddad, Francesco Canonaco, Colin O'Dowd, Jurgita Ovadnevaite, María Cruz Minguillón, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 19, 3747–3768, https://doi.org/10.5194/acp-19-3747-2019, https://doi.org/10.5194/acp-19-3747-2019, 2019
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Biogenic volatile organic compound (BVOC) emissions from vegetation are essential inputs for air quality models but their uncertainties are very high. In this study we show the importance of BVOC emissions for modelled ozone and aerosol concentrations in Europe. Using different biogenic emissions from MEGAN and PSI models significantly affected organic aerosols (smaller effect on ozone), indicating the importance of harmonising the BVOC emissions in the model inter-comparison studies.
Mikko Äijälä, Kaspar R. Daellenbach, Francesco Canonaco, Liine Heikkinen, Heikki Junninen, Tuukka Petäjä, Markku Kulmala, André S. H. Prévôt, and Mikael Ehn
Atmos. Chem. Phys., 19, 3645–3672, https://doi.org/10.5194/acp-19-3645-2019, https://doi.org/10.5194/acp-19-3645-2019, 2019
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Aerosol mass spectrometry produces large amounts of complex data, the analysis of which necessitates chemometrics – the application of advanced statistical and mathematical tools to chemical data. Here, we perform a data-driven analysis of multiple aerosol mass spectrometric data sets, to show that the traditional separation of organics and inorganics is not necessary. The resulting 7-component aerosol speciation explains 83 % to 96 % of observed variability at our boreal forest experiment site.
Abdoulaye Samaké, Jean-Luc Jaffrezo, Olivier Favez, Samuël Weber, Véronique Jacob, Alexandre Albinet, Véronique Riffault, Esperanza Perdrix, Antoine Waked, Benjamin Golly, Dalia Salameh, Florie Chevrier, Diogo Miguel Oliveira, Nicolas Bonnaire, Jean-Luc Besombes, Jean M. F. Martins, Sébastien Conil, Géraldine Guillaud, Boualem Mesbah, Benoit Rocq, Pierre-Yves Robic, Agnès Hulin, Sébastien Le Meur, Maxence Descheemaecker, Eve Chretien, Nicolas Marchand, and Gaëlle Uzu
Atmos. Chem. Phys., 19, 3357–3374, https://doi.org/10.5194/acp-19-3357-2019, https://doi.org/10.5194/acp-19-3357-2019, 2019
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The contribution of primary biogenic organic aerosols to PM is barely documented. This work provides a broad overview of the spatiotemporal evolution of concentrations and contributions to OM of dominant primary sugar alcohols and saccharides for a large selection of environmental conditions in France (28 sites and more than 5 340 samples). These chemicals are ubiquitous, and are associated with coarse aerosols. Their concentrations display site-to-site and clear seasonal variations.
Li Xing, Jiarui Wu, Miriam Elser, Shengrui Tong, Suixin Liu, Xia Li, Lang Liu, Junji Cao, Jiamao Zhou, Imad El-Haddad, Rujin Huang, Maofa Ge, Xuexi Tie, André S. H. Prévôt, and Guohui Li
Atmos. Chem. Phys., 19, 2343–2359, https://doi.org/10.5194/acp-19-2343-2019, https://doi.org/10.5194/acp-19-2343-2019, 2019
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We used the WRF-CHEM model to simulate wintertime secondary organic aerosol (SOA) concentrations over Beijing–Tianjin–Hebei (BTH), China. Heterogeneous HONO sources increased the near-surface SOA by 46.3 % in BTH. Direct emissions of glyoxal and methylglyoxal from residential sources contributed 25.5 % to the total SOA mass. Our study highlights the importance of heterogeneous HONO sources and primary residential emissions of glyoxal and methylglyoxal to SOA formation in winter over BTH.
Ru-Jin Huang, Yichen Wang, Junji Cao, Chunshui Lin, Jing Duan, Qi Chen, Yongjie Li, Yifang Gu, Jin Yan, Wei Xu, Roman Fröhlich, Francesco Canonaco, Carlo Bozzetti, Jurgita Ovadnevaite, Darius Ceburnis, Manjula R. Canagaratna, John Jayne, Douglas R. Worsnop, Imad El-Haddad, André S. H. Prévôt, and Colin D. O'Dowd
Atmos. Chem. Phys., 19, 2283–2298, https://doi.org/10.5194/acp-19-2283-2019, https://doi.org/10.5194/acp-19-2283-2019, 2019
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We found that in wintertime Shijiazhuang fine PM was mostly from primary emissions without sufficient atmospheric aging. In addition, secondary inorganic and organic aerosol dominated in pollution events under high-RH conditions, likely due to enhanced aqueous-phase chemistry, whereas primary organic aerosol dominated in pollution events under low-RH and stagnant conditions. Our results also highlighted the importance of meteorological conditions for PM pollution in this highly polluted city.
Youngseob Kim, Karine Sartelet, and Florian Couvidat
Atmos. Chem. Phys., 19, 1241–1261, https://doi.org/10.5194/acp-19-1241-2019, https://doi.org/10.5194/acp-19-1241-2019, 2019
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Assumptions (ideality and thermodynamic equilibrium) commonly made in 3-dimensional air quality models were reconsidered to evaluate their impacts on secondary organic aerosol (SOA) formation. Non-ideality (short-, medium- and long-range interactions of organics and inorganics) influences SOA concentrations by about 30 % over Europe. If SOA are highly viscous rather than inviscid, hydrophobic SOA concentrations increase by 6 % but can increase by an order of magnitude for volatile compounds.
Marwa Majdi, Solene Turquety, Karine Sartelet, Carole Legorgeu, Laurent Menut, and Youngseob Kim
Atmos. Chem. Phys., 19, 785–812, https://doi.org/10.5194/acp-19-785-2019, https://doi.org/10.5194/acp-19-785-2019, 2019
Camille Richon, Jean-Claude Dutay, Laurent Bopp, Briac Le Vu, James C. Orr, Samuel Somot, and François Dulac
Biogeosciences, 16, 135–165, https://doi.org/10.5194/bg-16-135-2019, https://doi.org/10.5194/bg-16-135-2019, 2019
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We evaluate the effects of climate change and biogeochemical forcing evolution on the nutrient and plankton cycles of the Mediterranean Sea for the first time. We use a high-resolution coupled physical and biogeochemical model and perform 120-year transient simulations. The results indicate that changes in external nutrient fluxes and climate change may have synergistic or antagonistic effects on nutrient concentrations, depending on the region and the scenario.
Adrien Deroubaix, Laurent Menut, Cyrille Flamant, Joel Brito, Cyrielle Denjean, Volker Dreiling, Andreas Fink, Corinne Jambert, Norbert Kalthoff, Peter Knippertz, Russ Ladkin, Sylvain Mailler, Marlon Maranan, Federica Pacifico, Bruno Piguet, Guillaume Siour, and Solène Turquety
Atmos. Chem. Phys., 19, 473–497, https://doi.org/10.5194/acp-19-473-2019, https://doi.org/10.5194/acp-19-473-2019, 2019
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This article presents a detailed analysis of anthropogenic and biomass burning pollutants over the Gulf of Guinea coastal region, using observations from the DACCIWA field campaign and modeling. The novelty is that we focus on how these two pollution sources are mixed and transported further inland. We show that during the day pollutants are accumulated along the coastline and transported northward as soon as the daytime convection in the atmospheric boundary layer ceases (16:00 UTC).
Mark R. Theobald, Marta G. Vivanco, Wenche Aas, Camilla Andersson, Giancarlo Ciarelli, Florian Couvidat, Kees Cuvelier, Astrid Manders, Mihaela Mircea, Maria-Teresa Pay, Svetlana Tsyro, Mario Adani, Robert Bergström, Bertrand Bessagnet, Gino Briganti, Andrea Cappelletti, Massimo D'Isidoro, Hilde Fagerli, Kathleen Mar, Noelia Otero, Valentin Raffort, Yelva Roustan, Martijn Schaap, Peter Wind, and Augustin Colette
Atmos. Chem. Phys., 19, 379–405, https://doi.org/10.5194/acp-19-379-2019, https://doi.org/10.5194/acp-19-379-2019, 2019
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Model estimates of the mean European wet deposition of nitrogen and sulfur for 1990 to 2010 were within 40 % of the observed values. As a result of systematic biases, the models were better at estimating relative trends for the periods 1990–2000 and 2000–2010 than the absolute trends. Although the predominantly decreasing trends were mostly due to emission reductions, they were partially offset by other factors (e.g. changes in precipitation) during the first period, but not the second.
Gabriele Curci, Ummugulsum Alyuz, Rocio Barò, Roberto Bianconi, Johannes Bieser, Jesper H. Christensen, Augustin Colette, Aidan Farrow, Xavier Francis, Pedro Jiménez-Guerrero, Ulas Im, Peng Liu, Astrid Manders, Laura Palacios-Peña, Marje Prank, Luca Pozzoli, Ranjeet Sokhi, Efisio Solazzo, Paolo Tuccella, Alper Unal, Marta G. Vivanco, Christian Hogrefe, and Stefano Galmarini
Atmos. Chem. Phys., 19, 181–204, https://doi.org/10.5194/acp-19-181-2019, https://doi.org/10.5194/acp-19-181-2019, 2019
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Atmospheric carbonaceous aerosols are able to absorb solar radiation and they continue to contribute some of the largest uncertainties in projected climate change. One important detail is how the chemical species are arranged inside each particle, i.e. the knowledge of their mixing state. We use an ensemble of regional model simulations to test different mixing state assumptions and found that a combination of internal and external mixing may better reproduce sunphotometer observations.
Mounir Chrit, Karine Sartelet, Jean Sciare, Marwa Majdi, José Nicolas, Jean-Eudes Petit, and François Dulac
Atmos. Chem. Phys., 18, 18079–18100, https://doi.org/10.5194/acp-18-18079-2018, https://doi.org/10.5194/acp-18-18079-2018, 2018
Paola Formenti, Lydie Mbemba Kabuiku, Isabelle Chiapello, Fabrice Ducos, François Dulac, and Didier Tanré
Atmos. Meas. Tech., 11, 6761–6784, https://doi.org/10.5194/amt-11-6761-2018, https://doi.org/10.5194/amt-11-6761-2018, 2018
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Aerosol particles from natural and anthropogenic sources are climate regulators as they can counteract or amplify the warming effect of greenhouse gases, but are difficult to observe due to their temporal and spatial variability. Satellite sensors can provide the needed global coverage but need validation. In this paper we explore the capability of the POLDER-3 advanced space-borne sensor to observe aerosols over the western Mediterranean region.
Nivedita K. Kumar, Joel C. Corbin, Emily A. Bruns, Dario Massabó, Jay G. Slowik, Luka Drinovec, Griša Močnik, Paolo Prati, Athanasia Vlachou, Urs Baltensperger, Martin Gysel, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 17843–17861, https://doi.org/10.5194/acp-18-17843-2018, https://doi.org/10.5194/acp-18-17843-2018, 2018
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It is clear that considerable uncertainties still exist in understanding the magnitude of aerosol absorption on a global scale and its contribution to global warming. This manuscript provides a comprehensive assessment of the optical absorption by organic aerosols (brown carbon) from residential wood combustion as a function of atmospheric aging.
Arthur Elessa Etuman and Isabelle Coll
Geosci. Model Dev., 11, 5085–5111, https://doi.org/10.5194/gmd-11-5085-2018, https://doi.org/10.5194/gmd-11-5085-2018, 2018
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OLYMPUS is a model of air pollutant and greenhouse gas emissions for cities. This modeling platform was designed to quantify the impact of urban policies on anthropogenic air pollutants by integrating household behavior into mobility and energy consumption in the residential and commercial sectors.
Paola Formenti, Stuart John Piketh, Andreas Namwoonde, Danitza Klopper, Roelof Burger, Mathieu Cazaunau, Anaïs Feron, Cécile Gaimoz, Stephen Broccardo, Nicola Walton, Karine Desboeufs, Guillaume Siour, Mattheus Hanghome, Samuel Mafwila, Edosa Omoregie, Wolfgang Junkermann, and Willy Maenhaut
Atmos. Chem. Phys., 18, 17003–17016, https://doi.org/10.5194/acp-18-17003-2018, https://doi.org/10.5194/acp-18-17003-2018, 2018
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Three-years of continuous measurements at the Henties Bay Aerosol Observatory (HBAO; 22°S, 14°05’E), Namibia, show that during the austral wintertime, long- and medium-range transport of pollution from biomass and fossil fuel burning give rise to peaks of light-absorbing black carbon aerosols into the marine boundary layer ahead of the main biomass burning season. This could affect the cloud properties.
Cristina Carnerero, Noemí Pérez, Cristina Reche, Marina Ealo, Gloria Titos, Hong-Ku Lee, Hee-Ram Eun, Yong-Hee Park, Lubna Dada, Pauli Paasonen, Veli-Matti Kerminen, Enrique Mantilla, Miguel Escudero, Francisco J. Gómez-Moreno, Elisabeth Alonso-Blanco, Esther Coz, Alfonso Saiz-Lopez, Brice Temime-Roussel, Nicolas Marchand, David C. S. Beddows, Roy M. Harrison, Tuukka Petäjä, Markku Kulmala, Kang-Ho Ahn, Andrés Alastuey, and Xavier Querol
Atmos. Chem. Phys., 18, 16601–16618, https://doi.org/10.5194/acp-18-16601-2018, https://doi.org/10.5194/acp-18-16601-2018, 2018
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The vertical distribution of new particle formation events was studied using tethered balloons carrying miniaturized instrumentation. Results show that new particle formation and growth occurs only in the lower layer of the atmosphere, where aerosols are mixed due to convection, especially when the atmosphere is clean. A comparison of urban and suburban surface stations was also made, suggesting that such events may have a significant impact on ultrafine particle concentrations in a wide area.
Anastasia Panopoulou, Eleni Liakakou, Valérie Gros, Stéphane Sauvage, Nadine Locoge, Bernard Bonsang, Basil E. Psiloglou, Evangelos Gerasopoulos, and Nikolaos Mihalopoulos
Atmos. Chem. Phys., 18, 16139–16154, https://doi.org/10.5194/acp-18-16139-2018, https://doi.org/10.5194/acp-18-16139-2018, 2018
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This work presents time-resolved data of non-methane hydrocarbons (NMHC) from automatic chromatographs, measured over a period of 5 months in the greater Athens area. The measured concentrations are higher relative to other recent studies for the majority of NMHCs. A remarkable day-to-day variability is also observed. The contributions from traffic and residential heating to NMHCs are investigated, as they were the major sources impacting the air quality during the study period.
Florian Couvidat, Marta G. Vivanco, and Bertrand Bessagnet
Atmos. Chem. Phys., 18, 15743–15766, https://doi.org/10.5194/acp-18-15743-2018, https://doi.org/10.5194/acp-18-15743-2018, 2018
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Several new parameterizations and mechanisms for SOA formation are developed based on available experimental results. To evaluate the parameterizations, a box model was developed to simulate SOA formation from monoterpenes and aromatics in the environmental chamber EUPHORE. This box model takes oligomerization, nonideality of the aerosol, multiphase partitioning, aging, vapor wall losses and particle-phase diffusion into account. All these phenomena are rarely taken into account together.
Vincent Michoud, Stéphane Sauvage, Thierry Léonardis, Isabelle Fronval, Alexandre Kukui, Nadine Locoge, and Sébastien Dusanter
Atmos. Meas. Tech., 11, 5729–5740, https://doi.org/10.5194/amt-11-5729-2018, https://doi.org/10.5194/amt-11-5729-2018, 2018
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This study presents the first measurements of ambient methylglyoxal, an important atmospheric α-dicarbonyl, using proton transfer reaction time-of-flight mass spectrometry. These measurements mostly agree with concomitant measurements from a reference technique: the DNPH derivatization technique and high-performance liquid chromatography with UV detection. In addition, a careful investigation of the differences between the two techniques is carried out to explain the disagreements observed.
Igor B. Konovalov, Daria A. Lvova, Matthias Beekmann, Hiren Jethva, Eugene F. Mikhailov, Jean-Daniel Paris, Boris D. Belan, Valerii S. Kozlov, Philippe Ciais, and Meinrat O. Andreae
Atmos. Chem. Phys., 18, 14889–14924, https://doi.org/10.5194/acp-18-14889-2018, https://doi.org/10.5194/acp-18-14889-2018, 2018
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A good knowledge of black carbon (BC) emissions from open biomass burning (BB) is an important prerequisite for reliable climate predictions, especially in the Arctic. This paper introduces a method to constrain a regional budget of BB BC emissions using satellite measurements of the absorption and extinction optical depths and evaluates its potential application in a large Siberian region.
Yingjie Zhang, Wei Du, Yuying Wang, Qingqing Wang, Haofei Wang, Haitao Zheng, Fang Zhang, Hongrong Shi, Yuxuan Bian, Yongxiang Han, Pingqing Fu, Francesco Canonaco, André S. H. Prévôt, Tong Zhu, Pucai Wang, Zhanqing Li, and Yele Sun
Atmos. Chem. Phys., 18, 14637–14651, https://doi.org/10.5194/acp-18-14637-2018, https://doi.org/10.5194/acp-18-14637-2018, 2018
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We have a comprehensive characterization of aerosol chemistry and particle growth events at a downwind site of a highly polluted city in the North China Plain. Aerosol particles at the urban downwind site were highly aged and mainly from secondary formation. New particle growth events were also frequently observed on both clean and polluted days. While both sulfate and SOA played important roles in particle growth during clean periods, SOA was more important than sulfate during polluted events.
Tuomo Nieminen, Veli-Matti Kerminen, Tuukka Petäjä, Pasi P. Aalto, Mikhail Arshinov, Eija Asmi, Urs Baltensperger, David C. S. Beddows, Johan Paul Beukes, Don Collins, Aijun Ding, Roy M. Harrison, Bas Henzing, Rakesh Hooda, Min Hu, Urmas Hõrrak, Niku Kivekäs, Kaupo Komsaare, Radovan Krejci, Adam Kristensson, Lauri Laakso, Ari Laaksonen, W. Richard Leaitch, Heikki Lihavainen, Nikolaos Mihalopoulos, Zoltán Németh, Wei Nie, Colin O'Dowd, Imre Salma, Karine Sellegri, Birgitta Svenningsson, Erik Swietlicki, Peter Tunved, Vidmantas Ulevicius, Ville Vakkari, Marko Vana, Alfred Wiedensohler, Zhijun Wu, Annele Virtanen, and Markku Kulmala
Atmos. Chem. Phys., 18, 14737–14756, https://doi.org/10.5194/acp-18-14737-2018, https://doi.org/10.5194/acp-18-14737-2018, 2018
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Atmospheric aerosols have diverse effects on air quality, human health, and global climate. One important source of aerosols is their formation via nucleation and growth in the atmosphere. We have analyzed long-term observations of regional new particle formation events around the globe and provide a comprehensive view on the characteristics of this phenomenon in diverse environments. The results are useful in developing more realistic representation of atmospheric aerosols in global models.
Karine Desboeufs, Elisabeth Bon Nguyen, Servanne Chevaillier, Sylvain Triquet, and François Dulac
Atmos. Chem. Phys., 18, 14477–14492, https://doi.org/10.5194/acp-18-14477-2018, https://doi.org/10.5194/acp-18-14477-2018, 2018
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Atmospheric deposition is known to be a major source of nutrients for the marine biosphere in the Mediterranean Sea. The study of the origin of nutrients and trace metals in Corsica presented here shows that the dust events were the major sources of Si and Fe. Conversely, combustion sources predominated the inputs of N, P, and trace metals. This work showed the importance of considering background anthropogenic deposition for estimating the impact of atmospheric forcing on marine biota.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Karine Sellegri, Jean Sciare, Michael Pikridas, Iasonas Stavroulas, Thierry Leonardis, Vincent Gaudion, Laurence Depelchin, Isabelle Fronval, Roland Sarda-Esteve, Dominique Baisnée, Bernard Bonsang, Chrysanthos Savvides, Mihalis Vrekoussis, and Nadine Locoge
Atmos. Chem. Phys., 18, 14297–14325, https://doi.org/10.5194/acp-18-14297-2018, https://doi.org/10.5194/acp-18-14297-2018, 2018
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This work focuses on the study of the sources and fates of BVOCs and new particle formation (NPF) events in the eastern Mediterranean. NPF events were found on 14 out of 20 days of the campaign. NPF occurred at various condensational sinks and both under polluted and clean atmospheric conditions. Analysis of specific NPF periods of the mixed influence type highlighted that BVOC interactions with anthropogenic compounds enhanced nucleation formation and growth of new particles.
Victor Lannuque, Marie Camredon, Florian Couvidat, Alma Hodzic, Richard Valorso, Sasha Madronich, Bertrand Bessagnet, and Bernard Aumont
Atmos. Chem. Phys., 18, 13411–13428, https://doi.org/10.5194/acp-18-13411-2018, https://doi.org/10.5194/acp-18-13411-2018, 2018
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Large uncertainties remain in understanding the influence of atmospheric environmental conditions on secondary organic aerosol (SOA) formation, evolution and properties. In this article, the GECKO-A modelling tool has been used in a box model under various environmental conditions to (i) explore the sensitivity of SOA formation and properties to changes on physical and chemical conditions and (ii) develop a volatility-basis-set-type parameterization for air quality models.
Cyrille Flamant, Adrien Deroubaix, Patrick Chazette, Joel Brito, Marco Gaetani, Peter Knippertz, Andreas H. Fink, Gaëlle de Coetlogon, Laurent Menut, Aurélie Colomb, Cyrielle Denjean, Rémi Meynadier, Philip Rosenberg, Regis Dupuy, Pamela Dominutti, Jonathan Duplissy, Thierry Bourrianne, Alfons Schwarzenboeck, Michel Ramonet, and Julien Totems
Atmos. Chem. Phys., 18, 12363–12389, https://doi.org/10.5194/acp-18-12363-2018, https://doi.org/10.5194/acp-18-12363-2018, 2018
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This work sheds light on the complex mechanisms by which coastal shallow circulations distribute atmospheric pollutants over the densely populated southern West African region. Pollutants of concern are anthropogenic emissions from coastal cities, as well as biomass burning aerosol and dust associated with long-range transport. The complex vertical distribution of aerosols over coastal southern West Africa is investigated using airborne observations and numerical simulations.
Martine Collaud Coen, Elisabeth Andrews, Diego Aliaga, Marcos Andrade, Hristo Angelov, Nicolas Bukowiecki, Marina Ealo, Paulo Fialho, Harald Flentje, A. Gannet Hallar, Rakesh Hooda, Ivo Kalapov, Radovan Krejci, Neng-Huei Lin, Angela Marinoni, Jing Ming, Nhat Anh Nguyen, Marco Pandolfi, Véronique Pont, Ludwig Ries, Sergio Rodríguez, Gerhard Schauer, Karine Sellegri, Sangeeta Sharma, Junying Sun, Peter Tunved, Patricio Velasquez, and Dominique Ruffieux
Atmos. Chem. Phys., 18, 12289–12313, https://doi.org/10.5194/acp-18-12289-2018, https://doi.org/10.5194/acp-18-12289-2018, 2018
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High altitude stations are often emphasized as free tropospheric measuring sites but they remain influenced by atmospheric boundary layer. An ABL-TopoIndex is defined from a topography analysis around the stations. This new index allows ranking stations as a function of the ABL influence due to topography or help to choose a new site to sample FT. The ABL-TopoIndex is validated by aerosol optical properties and number concentration measured at 29 high altitude stations of five continents.
Noelia Otero, Jana Sillmann, Kathleen A. Mar, Henning W. Rust, Sverre Solberg, Camilla Andersson, Magnuz Engardt, Robert Bergström, Bertrand Bessagnet, Augustin Colette, Florian Couvidat, Cournelius Cuvelier, Svetlana Tsyro, Hilde Fagerli, Martijn Schaap, Astrid Manders, Mihaela Mircea, Gino Briganti, Andrea Cappelletti, Mario Adani, Massimo D'Isidoro, María-Teresa Pay, Mark Theobald, Marta G. Vivanco, Peter Wind, Narendra Ojha, Valentin Raffort, and Tim Butler
Atmos. Chem. Phys., 18, 12269–12288, https://doi.org/10.5194/acp-18-12269-2018, https://doi.org/10.5194/acp-18-12269-2018, 2018
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This paper evaluates the capability of air-quality models to capture the observed relationship between surface ozone concentrations and meteorology over Europe. The air-quality models tended to overestimate the influence of maximum temperature and surface solar radiation. None of the air-quality models captured the strength of the observed relationship between ozone and relative humidity appropriately, underestimating the effect of relative humidity, a key factor in the ozone removal processes.
Xiao-Feng Huang, Bei-Bing Zou, Ling-Yan He, Min Hu, André S. H. Prévôt, and Yuan-Hang Zhang
Atmos. Chem. Phys., 18, 11563–11580, https://doi.org/10.5194/acp-18-11563-2018, https://doi.org/10.5194/acp-18-11563-2018, 2018
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A novel multilinear engine (ME-2) model was applied to the PM2.5 dataset observed in the Pearl River Delta (PRD) of China in 2015 and identified the sources of secondary sulfate (21 %), vehicle emissions (14 %), industrial emissions (13 %), secondary nitrate (11 %), biomass burning (11 %), secondary organic aerosol (7 %), coal burning (6 %), fugitive dust (5 %), ship emissions (3 %) and aged sea salt (2 %). The central PRD area was clearly identified as the key emission area in the PRD.
Amelie Bertrand, Giulia Stefenelli, Simone M. Pieber, Emily A. Bruns, Brice Temime-Roussel, Jay G. Slowik, Henri Wortham, André S. H. Prévôt, Imad El Haddad, and Nicolas Marchand
Atmos. Chem. Phys., 18, 10915–10930, https://doi.org/10.5194/acp-18-10915-2018, https://doi.org/10.5194/acp-18-10915-2018, 2018
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We model the evolution of several BBOA markers including levoglucosan during aging experiments conducted in an atmospheric Teflon chamber, in order to evaluate the influence of vapor wall loss on the determination of the rate constants of the compounds with hydroxyl radicals (OH).
Xia Li, Jiarui Wu, Miriam Elser, Tian Feng, Junji Cao, Imad El-Haddad, Rujin Huang, Xuexi Tie, André S. H. Prévôt, and Guohui Li
Atmos. Chem. Phys., 18, 10675–10691, https://doi.org/10.5194/acp-18-10675-2018, https://doi.org/10.5194/acp-18-10675-2018, 2018
Marta G. Vivanco, Mark R. Theobald, Héctor García-Gómez, Juan Luis Garrido, Marje Prank, Wenche Aas, Mario Adani, Ummugulsum Alyuz, Camilla Andersson, Roberto Bellasio, Bertrand Bessagnet, Roberto Bianconi, Johannes Bieser, Jørgen Brandt, Gino Briganti, Andrea Cappelletti, Gabriele Curci, Jesper H. Christensen, Augustin Colette, Florian Couvidat, Cornelis Cuvelier, Massimo D'Isidoro, Johannes Flemming, Andrea Fraser, Camilla Geels, Kaj M. Hansen, Christian Hogrefe, Ulas Im, Oriol Jorba, Nutthida Kitwiroon, Astrid Manders, Mihaela Mircea, Noelia Otero, Maria-Teresa Pay, Luca Pozzoli, Efisio Solazzo, Svetlana Tsyro, Alper Unal, Peter Wind, and Stefano Galmarini
Atmos. Chem. Phys., 18, 10199–10218, https://doi.org/10.5194/acp-18-10199-2018, https://doi.org/10.5194/acp-18-10199-2018, 2018
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European wet and dry atmospheric deposition of N and S estimated by 14 air quality models was found to vary substantially. An ensemble of models meeting acceptability criteria was used to estimate the exceedances of the critical loads for N in habitats within the Natura 2000 network, as well as their lower and upper limits. Scenarios with 20 % emission reductions in different regions of the world showed that European emissions are responsible for most of the N and S deposition in Europe.
Simone M. Pieber, Nivedita K. Kumar, Felix Klein, Pierre Comte, Deepika Bhattu, Josef Dommen, Emily A. Bruns, Doǧuşhan Kılıç, Imad El Haddad, Alejandro Keller, Jan Czerwinski, Norbert Heeb, Urs Baltensperger, Jay G. Slowik, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 9929–9954, https://doi.org/10.5194/acp-18-9929-2018, https://doi.org/10.5194/acp-18-9929-2018, 2018
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We studied primary emissions and secondary organic aerosol (SOA) from gasoline direct injection (GDI) vehicles including GDIs retrofitted with gasoline particle filters (GPF). GPF retrofitting significantly decreased the primary particulate matter, particularly through removal of refractory black carbon and, to a lesser extent, of non-refractory organic particulates. SOA experiments were conducted in a batch and flow reactor. GPF retrofitting did not significantly affect precursors or yields.
Emmanouil Oikonomakis, Sebnem Aksoyoglu, Martin Wild, Giancarlo Ciarelli, Urs Baltensperger, and André Stephan Henry Prévôt
Atmos. Chem. Phys., 18, 9741–9765, https://doi.org/10.5194/acp-18-9741-2018, https://doi.org/10.5194/acp-18-9741-2018, 2018
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We report a model sensitivity study on the impact of aerosol–radiation interaction (ARI) changes in Europe between 1990 and 2010 on summer surface ozone via effects on photolysis rates and biogenic emissions. The overall impact of ARI changes on ozone was relatively small when compared to the total ozone concentrations, but it was more important when compared to the order of magnitude of ozone trends, indicating a potential partial damping of the effects of ozone precursor emissions' reduction.
Mounir Chrit, Karine Sartelet, Jean Sciare, Jorge Pey, José B. Nicolas, Nicolas Marchand, Evelyn Freney, Karine Sellegri, Matthias Beekmann, and François Dulac
Atmos. Chem. Phys., 18, 9631–9659, https://doi.org/10.5194/acp-18-9631-2018, https://doi.org/10.5194/acp-18-9631-2018, 2018
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Fine particulate matter (PM) in the atmosphere is of concern due to its effects on health, climate, ecosystems and biological cycles, and visibility.
These effects are especially important in the Mediterranean region. In this study, the air quality model Polyphemus is used to understand the
sources of inorganic and organic particles in the western Mediterranean and evaluate the uncertainties linked to the model parameters and hypotheses related to condensation/evaporation in the model.
Juan Cuesta, Yugo Kanaya, Masayuki Takigawa, Gaëlle Dufour, Maxim Eremenko, Gilles Foret, Kazuyuki Miyazaki, and Matthias Beekmann
Atmos. Chem. Phys., 18, 9499–9525, https://doi.org/10.5194/acp-18-9499-2018, https://doi.org/10.5194/acp-18-9499-2018, 2018
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This paper tackles a major issue for air quality over East Asia: ozone pollution produced over a major source, like the North China Plain, and the contribution of ozone produced while being transported across the continent and the surrounding seas. The main originality of the paper lays in the fact that this photochemical production of ozone is observationally quantified with new multispectral satellite observations offering unique skills to observe the ozone pollution plumes near the surface.
Nizar Jaidan, Laaziz El Amraoui, Jean-Luc Attié, Philippe Ricaud, and François Dulac
Atmos. Chem. Phys., 18, 9351–9373, https://doi.org/10.5194/acp-18-9351-2018, https://doi.org/10.5194/acp-18-9351-2018, 2018
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The Mediterranean Basin, surrounded by three continents with diverse pollution sources, is particularly sensitive to climate change due to its location and diversity of ecosystems. In this work, we investigate the future change of surface ozone from 2000 to 2100 over this region using a set of atmospheric model outputs and ground-based observations. We also highlight how the future climate change and the increase of methane concentrations can offset the benefit of the pollution reduction policy.
Brice Foucart, Karine Sellegri, Pierre Tulet, Clémence Rose, Jean-Marc Metzger, and David Picard
Atmos. Chem. Phys., 18, 9243–9261, https://doi.org/10.5194/acp-18-9243-2018, https://doi.org/10.5194/acp-18-9243-2018, 2018
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The main objective of this study is to reinforce the observations of new particle formation (NPF) events in the Southern Hemisphere and more particularly for a site that is both marine and at altitude, the Maïdo observatory (2150 m), on Réunion. We recorded a high annual NPF frequency of 65 % and we note that monthly averages show a bimodal variation. We estimate the intensity and the characteristics of the events and describe their seasonality by comparing them to other parameters.
Ulas Im, Jesper Heile Christensen, Camilla Geels, Kaj Mantzius Hansen, Jørgen Brandt, Efisio Solazzo, Ummugulsum Alyuz, Alessandra Balzarini, Rocio Baro, Roberto Bellasio, Roberto Bianconi, Johannes Bieser, Augustin Colette, Gabriele Curci, Aidan Farrow, Johannes Flemming, Andrea Fraser, Pedro Jimenez-Guerrero, Nutthida Kitwiroon, Peng Liu, Uarporn Nopmongcol, Laura Palacios-Peña, Guido Pirovano, Luca Pozzoli, Marje Prank, Rebecca Rose, Ranjeet Sokhi, Paolo Tuccella, Alper Unal, Marta G. Vivanco, Greg Yarwood, Christian Hogrefe, and Stefano Galmarini
Atmos. Chem. Phys., 18, 8929–8952, https://doi.org/10.5194/acp-18-8929-2018, https://doi.org/10.5194/acp-18-8929-2018, 2018
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We evaluate the impact of global and regional anthropogenic emission reductions on major air pollutant levels over Europe and North America, using a multi-model ensemble of regional chemistry and transport models. Results show that ozone levels are largely driven by long-range transport over both continents while other pollutants such as carbon monoxide or aerosols are mainly controlled by domestic sources. Use of multi-model ensembles can help to reduce the uncertainties in individual models.
Stefano Galmarini, Ioannis Kioutsioukis, Efisio Solazzo, Ummugulsum Alyuz, Alessandra Balzarini, Roberto Bellasio, Anna M. K. Benedictow, Roberto Bianconi, Johannes Bieser, Joergen Brandt, Jesper H. Christensen, Augustin Colette, Gabriele Curci, Yanko Davila, Xinyi Dong, Johannes Flemming, Xavier Francis, Andrea Fraser, Joshua Fu, Daven K. Henze, Christian Hogrefe, Ulas Im, Marta Garcia Vivanco, Pedro Jiménez-Guerrero, Jan Eiof Jonson, Nutthida Kitwiroon, Astrid Manders, Rohit Mathur, Laura Palacios-Peña, Guido Pirovano, Luca Pozzoli, Marie Prank, Martin Schultz, Rajeet S. Sokhi, Kengo Sudo, Paolo Tuccella, Toshihiko Takemura, Takashi Sekiya, and Alper Unal
Atmos. Chem. Phys., 18, 8727–8744, https://doi.org/10.5194/acp-18-8727-2018, https://doi.org/10.5194/acp-18-8727-2018, 2018
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An ensemble of model results relating to ozone concentrations in Europe in 2010 has been produced and studied. The novelty consists in the fact that the ensemble is made of results of models working at two different scales (regional and global), therefore contributing in detail two different parts of the atmospheric spectrum. The ensemble defined as a hybrid has been studied in detail and shown to bring additional value to the assessment of air quality.
Yele Sun, Weiqi Xu, Qi Zhang, Qi Jiang, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Jie Li, John Jayne, Douglas R. Worsnop, and Zifa Wang
Atmos. Chem. Phys., 18, 8469–8489, https://doi.org/10.5194/acp-18-8469-2018, https://doi.org/10.5194/acp-18-8469-2018, 2018
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We present a 2–year analysis of organic aerosol (OA) from highly time–resolved measurements by an aerosol chemical speciation monitor in the megacity of Beijing. The sources of OA were analyzed with the advanced factor analysis of a multilinear engine (ME-2). Our results showed very different seasonal patterns, relative humidity and temperature dependence, and sources regions among different OA factors. The sources and processes of OA factors, and their roles in haze pollution are elucidated.
Marco Pandolfi, Lucas Alados-Arboledas, Andrés Alastuey, Marcos Andrade, Christo Angelov, Begoña Artiñano, John Backman, Urs Baltensperger, Paolo Bonasoni, Nicolas Bukowiecki, Martine Collaud Coen, Sébastien Conil, Esther Coz, Vincent Crenn, Vadimas Dudoitis, Marina Ealo, Kostas Eleftheriadis, Olivier Favez, Prodromos Fetfatzis, Markus Fiebig, Harald Flentje, Patrick Ginot, Martin Gysel, Bas Henzing, Andras Hoffer, Adela Holubova Smejkalova, Ivo Kalapov, Nikos Kalivitis, Giorgos Kouvarakis, Adam Kristensson, Markku Kulmala, Heikki Lihavainen, Chris Lunder, Krista Luoma, Hassan Lyamani, Angela Marinoni, Nikos Mihalopoulos, Marcel Moerman, José Nicolas, Colin O'Dowd, Tuukka Petäjä, Jean-Eudes Petit, Jean Marc Pichon, Nina Prokopciuk, Jean-Philippe Putaud, Sergio Rodríguez, Jean Sciare, Karine Sellegri, Erik Swietlicki, Gloria Titos, Thomas Tuch, Peter Tunved, Vidmantas Ulevicius, Aditya Vaishya, Milan Vana, Aki Virkkula, Stergios Vratolis, Ernest Weingartner, Alfred Wiedensohler, and Paolo Laj
Atmos. Chem. Phys., 18, 7877–7911, https://doi.org/10.5194/acp-18-7877-2018, https://doi.org/10.5194/acp-18-7877-2018, 2018
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This investigation presents the variability in near-surface in situ aerosol particle light-scattering measurements obtained over the past decade at 28 measuring atmospheric observatories which are part of the ACTRIS Research Infrastructure, and most of them belong to the GAW network. This paper provides a comprehensive picture of the spatial and temporal variability of aerosol particles optical properties in Europe.
Sekou Keita, Cathy Liousse, Véronique Yoboué, Pamela Dominutti, Benjamin Guinot, Eric-Michel Assamoi, Agnès Borbon, Sophie L. Haslett, Laetitia Bouvier, Aurélie Colomb, Hugh Coe, Aristide Akpo, Jacques Adon, Julien Bahino, Madina Doumbia, Julien Djossou, Corinne Galy-Lacaux, Eric Gardrat, Sylvain Gnamien, Jean F. Léon, Money Ossohou, E. Touré N'Datchoh, and Laurent Roblou
Atmos. Chem. Phys., 18, 7691–7708, https://doi.org/10.5194/acp-18-7691-2018, https://doi.org/10.5194/acp-18-7691-2018, 2018
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This study provides emission factor (EF) data for elemental and organic carbon, total particulate matter and 58 volatile organic compound species for combustion sources specific to Africa to establish emission inventories with less uncertainty. EFs obtained in this study are generally higher than those in the literature whose values are used in emissions inventories for Africa. This shows that particles and VOC emissions were sometimes underestimated and underlines this study's importance.
Amelie Bertrand, Giulia Stefenelli, Coty N. Jen, Simone M. Pieber, Emily A. Bruns, Haiyan Ni, Brice Temime-Roussel, Jay G. Slowik, Allen H. Goldstein, Imad El Haddad, Urs Baltensperger, André S. H. Prévôt, Henri Wortham, and Nicolas Marchand
Atmos. Chem. Phys., 18, 7607–7624, https://doi.org/10.5194/acp-18-7607-2018, https://doi.org/10.5194/acp-18-7607-2018, 2018
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A thermal desorption aerosol gas chromatograph coupled to an aerosol mass spectrometer (TAG–AMS) is connected to an atmospheric chamber. The setup serves the quantitative study of the impact of combustion conditions and atmospheric aging on the chemical fingerprint at the molecular level of biomass burning organic aerosol.
Doğuşhan Kılıç, Imad El Haddad, Benjamin T. Brem, Emily Bruns, Carlo Bozetti, Joel Corbin, Lukas Durdina, Ru-Jin Huang, Jianhui Jiang, Felix Klein, Avi Lavi, Simone M. Pieber, Theo Rindlisbacher, Yinon Rudich, Jay G. Slowik, Jing Wang, Urs Baltensperger, and Andre S. H. Prévôt
Atmos. Chem. Phys., 18, 7379–7391, https://doi.org/10.5194/acp-18-7379-2018, https://doi.org/10.5194/acp-18-7379-2018, 2018
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We study primary emissions and secondary aerosol (SA) from an aircraft turbofan. By monitoring the chemical composition of both gaseous and particulate emissions at different engine loads, we explained SA formed in an oxidation flow reactor (PAM) by the oxidation of gaseous species. At idle, more than 90 % of the secondary particle mass was organic and could be explained by the oxidation of gaseous aromatic species, while at an approximated cruise load sulfates comprised 85 % of the total SA.
Evelyn Freney, Karine Sellegri, Mounir Chrit, Kouji Adachi, Joel Brito, Antoine Waked, Agnès Borbon, Aurélie Colomb, Régis Dupuy, Jean-Marc Pichon, Laetitia Bouvier, Claire Delon, Corinne Jambert, Pierre Durand, Thierry Bourianne, Cécile Gaimoz, Sylvain Triquet, Anaïs Féron, Matthias Beekmann, François Dulac, and Karine Sartelet
Atmos. Chem. Phys., 18, 7041–7056, https://doi.org/10.5194/acp-18-7041-2018, https://doi.org/10.5194/acp-18-7041-2018, 2018
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The focus of these experiments, within the ChArMEx project, were to better understand the chemical properties of ambient aerosols over the Mediterranean region. A series of airborne measurements were performed aboard the French research aircraft, the ATR42, during the summer period. Aerosol and gas-phase chemical mass spectrometry allowed us to understand the sources and formation of organic aerosols. Numerical models were incorporated into this study to help interpret our observations.
Jun Zhou, Peter Zotter, Emily A. Bruns, Giulia Stefenelli, Deepika Bhattu, Samuel Brown, Amelie Bertrand, Nicolas Marchand, Houssni Lamkaddam, Jay G. Slowik, André S. H. Prévôt, Urs Baltensperger, Thomas Nussbaumer, Imad El-Haddad, and Josef Dommen
Atmos. Chem. Phys., 18, 6985–7000, https://doi.org/10.5194/acp-18-6985-2018, https://doi.org/10.5194/acp-18-6985-2018, 2018
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We thoroughly studied the reactive oxygen species (ROS) generation potential of particulate wood combustion emissions, from different combustion technologies, fuel types, operation methods, combustion regimes and phases. ROS from automatically operated combustion devices under optimal conditions were much lower than those from manually operated appliances. We examined the impact of atmospheric aging on ROS content in SOA and determined the controlling parameters, by using an online ROS analyzer.
Vanessa Brocchi, Gisèle Krysztofiak, Valéry Catoire, Jonathan Guth, Virginie Marécal, Régina Zbinden, Laaziz El Amraoui, François Dulac, and Philippe Ricaud
Atmos. Chem. Phys., 18, 6887–6906, https://doi.org/10.5194/acp-18-6887-2018, https://doi.org/10.5194/acp-18-6887-2018, 2018
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The Mediterranean Basin still suffers from a limited amount of in situ measurements for a good characterization of its environmental state. This study shows that intercontinental transport of very high CO concentrations can affect the upper Mediterranean Basin troposphere. By using modeling, 5- to 12-day eastward transport of biomass burning starting from North America and Siberia impacts the mid-troposphere of the Mediterranean Basin.
Xavier Querol, Andrés Alastuey, Gotzon Gangoiti, Noemí Perez, Hong K. Lee, Heeram R. Eun, Yonghee Park, Enrique Mantilla, Miguel Escudero, Gloria Titos, Lucio Alonso, Brice Temime-Roussel, Nicolas Marchand, Juan R. Moreta, M. Arantxa Revuelta, Pedro Salvador, Begoña Artíñano, Saúl García dos Santos, Mónica Anguas, Alberto Notario, Alfonso Saiz-Lopez, Roy M. Harrison, Millán Millán, and Kang-Ho Ahn
Atmos. Chem. Phys., 18, 6511–6533, https://doi.org/10.5194/acp-18-6511-2018, https://doi.org/10.5194/acp-18-6511-2018, 2018
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We show the main drivers of high O3 episodes in and around Madrid. High levels of ultrafine particles (UFPs) are evidenced, but we demonstrate that most O3 arises from the fumigation of high atmospheric layers, whereas UFPs are generated inside the PBL. O3 contributions from the fumigation of the vertical recirculation of regional air masses, hemispheric transport, and horizontally from direct urban plume transport are shown. Complexity arises from the need to quantify them to abate surface O3.
Athanasia Vlachou, Kaspar R. Daellenbach, Carlo Bozzetti, Benjamin Chazeau, Gary A. Salazar, Soenke Szidat, Jean-Luc Jaffrezo, Christoph Hueglin, Urs Baltensperger, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 6187–6206, https://doi.org/10.5194/acp-18-6187-2018, https://doi.org/10.5194/acp-18-6187-2018, 2018
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Carbonaceous aerosols are related to adverse human health effects, which depend on the aerosol chemical composition and size. Here, we combine aerosol mass spectrometry and radiocarbon measurements of size-resolved samples collected over a long term to identify the origins of primary and secondary carbonaceous aerosols in the fine and coarse modes.
Ulas Im, Jørgen Brandt, Camilla Geels, Kaj Mantzius Hansen, Jesper Heile Christensen, Mikael Skou Andersen, Efisio Solazzo, Ioannis Kioutsioukis, Ummugulsum Alyuz, Alessandra Balzarini, Rocio Baro, Roberto Bellasio, Roberto Bianconi, Johannes Bieser, Augustin Colette, Gabriele Curci, Aidan Farrow, Johannes Flemming, Andrea Fraser, Pedro Jimenez-Guerrero, Nutthida Kitwiroon, Ciao-Kai Liang, Uarporn Nopmongcol, Guido Pirovano, Luca Pozzoli, Marje Prank, Rebecca Rose, Ranjeet Sokhi, Paolo Tuccella, Alper Unal, Marta Garcia Vivanco, Jason West, Greg Yarwood, Christian Hogrefe, and Stefano Galmarini
Atmos. Chem. Phys., 18, 5967–5989, https://doi.org/10.5194/acp-18-5967-2018, https://doi.org/10.5194/acp-18-5967-2018, 2018
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The impacts of air pollution on human health and their costs in Europe and the United States for the year 2010 ared modeled by a multi-model ensemble. In Europe, the number of premature deaths is calculated to be 414 000, while in the US it is estimated to be 160 000. Health impacts estimated by individual models can vary up to a factor of 3. Results show that the domestic emissions have the largest impact on premature deaths, compared to foreign sources.
Camille Richon, Jean-Claude Dutay, François Dulac, Rong Wang, and Yves Balkanski
Biogeosciences, 15, 2499–2524, https://doi.org/10.5194/bg-15-2499-2018, https://doi.org/10.5194/bg-15-2499-2018, 2018
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This work is part of the Mermex and ChArMEx projects of the MISTRALS program. It aims at studying the impacts of phosphorus deposition from contrasted sources on the biogeochemical cycles of the Mediterranean Sea.
The results show that combustion-related phosphorus deposition effects dominate P deposition over the northern Mediterranean, whereas dust-derived phosphorus deposition effects dominate in the southern part.
Di Liu, Matthias Vonwiller, Jun Li, Junwen Liu, Sönke Szidat, Yanlin Zhang, Chongguo Tian, Yinjun Chen, Zhineng Cheng, Guangcai Zhong, Pingqing Fu, and Gan Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-295, https://doi.org/10.5194/acp-2018-295, 2018
Revised manuscript not accepted
Yan-Lin Zhang, Imad El-Haddad, Ru-Jin Huang, Kin-Fai Ho, Jun-Ji Cao, Yongming Han, Peter Zotter, Carlo Bozzetti, Kaspar R. Daellenbach, Jay G. Slowik, Gary Salazar, André S. H. Prévôt, and Sönke Szidat
Atmos. Chem. Phys., 18, 4005–4017, https://doi.org/10.5194/acp-18-4005-2018, https://doi.org/10.5194/acp-18-4005-2018, 2018
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Here we present a quantitative source apportionment of WSOC, isolated from aerosols in China using radiocarbon (14C) and offline high-resolution time of flight aerosol mass spectrometer measurements. We demonstrate a dominant contribution of non-fossil emissions to WSOC aerosols in the Northern Hemisphere. However, the fossil fraction is substantially larger in aerosols from East Asia and the east Asian pollution outflow, especially during winter, due to increasing coal combustion.
Wei Zhou, Qingqing Wang, Xiujuan Zhao, Weiqi Xu, Chen Chen, Wei Du, Jian Zhao, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 18, 3951–3968, https://doi.org/10.5194/acp-18-3951-2018, https://doi.org/10.5194/acp-18-3951-2018, 2018
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We present a 3-month analysis of submicron aerosols that were measured at 260 m on a meteorological tower in Beijing, China. The sources of organic aerosol (OA) were analyzed by using a multi-linear engine (ME-2). Our results showed significant changes in both primary and secondary OA composition from the non-heating season to the heating season. We also observed a considerable contribution (10–13%) of cooking OA at 260 m and very different OA composition between ground level and 260 m.
Jean-Baptiste Renard, François Dulac, Pierre Durand, Quentin Bourgeois, Cyrielle Denjean, Damien Vignelles, Benoit Couté, Matthieu Jeannot, Nicolas Verdier, and Marc Mallet
Atmos. Chem. Phys., 18, 3677–3699, https://doi.org/10.5194/acp-18-3677-2018, https://doi.org/10.5194/acp-18-3677-2018, 2018
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A campaign was performed in the summer of 2013 above the Mediterranean basin, including in situ counting balloon-borne aerosol measurements (LOAC), for the detection of mineral dust. Three modes in the dust particle volume size distributions were detected, at roughly 0.2, 4, and 30 mm. Particles larger than 40 mm were often observed. They were lifted several days before and their persistence after transport over long distances is in conflict with dust sedimentation calculations.
Julia Schmale, Silvia Henning, Stefano Decesari, Bas Henzing, Helmi Keskinen, Karine Sellegri, Jurgita Ovadnevaite, Mira L. Pöhlker, Joel Brito, Aikaterini Bougiatioti, Adam Kristensson, Nikos Kalivitis, Iasonas Stavroulas, Samara Carbone, Anne Jefferson, Minsu Park, Patrick Schlag, Yoko Iwamoto, Pasi Aalto, Mikko Äijälä, Nicolas Bukowiecki, Mikael Ehn, Göran Frank, Roman Fröhlich, Arnoud Frumau, Erik Herrmann, Hartmut Herrmann, Rupert Holzinger, Gerard Kos, Markku Kulmala, Nikolaos Mihalopoulos, Athanasios Nenes, Colin O'Dowd, Tuukka Petäjä, David Picard, Christopher Pöhlker, Ulrich Pöschl, Laurent Poulain, André Stephan Henry Prévôt, Erik Swietlicki, Meinrat O. Andreae, Paulo Artaxo, Alfred Wiedensohler, John Ogren, Atsushi Matsuki, Seong Soo Yum, Frank Stratmann, Urs Baltensperger, and Martin Gysel
Atmos. Chem. Phys., 18, 2853–2881, https://doi.org/10.5194/acp-18-2853-2018, https://doi.org/10.5194/acp-18-2853-2018, 2018
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Collocated long-term observations of cloud condensation nuclei (CCN) number concentrations, particle number size distributions and chemical composition from 12 sites are synthesized. Observations cover coastal environments, the Arctic, the Mediterranean, the boreal and rain forest, high alpine and continental background sites, and Monsoon-influenced areas. We interpret regional and seasonal variability. CCN concentrations are predicted with the κ–Köhler model and compared to the measurements.
Qiao Zhu, Xiao-Feng Huang, Li-Ming Cao, Lin-Tong Wei, Bin Zhang, Ling-Yan He, Miriam Elser, Francesco Canonaco, Jay G. Slowik, Carlo Bozzetti, Imad El-Haddad, and André S. H. Prévôt
Atmos. Meas. Tech., 11, 1049–1060, https://doi.org/10.5194/amt-11-1049-2018, https://doi.org/10.5194/amt-11-1049-2018, 2018
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Organic aerosol constitutes one of the major components of atmospheric particulate matter globally and is emitted from various sources. Therefore, identifying and quantifying the sources of organic aerosol accurately is a key task in the field. In this study, we applied a rather novel procedure for an improved source apportionment method (ME-2) to resolve the
less meaningful or mixed factorsproblems for organic aerosol using the traditional method (PMF).
Kaspar R. Daellenbach, Imad El-Haddad, Lassi Karvonen, Athanasia Vlachou, Joel C. Corbin, Jay G. Slowik, Maarten F. Heringa, Emily A. Bruns, Samuel M. Luedin, Jean-Luc Jaffrezo, Sönke Szidat, Andrea Piazzalunga, Raquel Gonzalez, Paola Fermo, Valentin Pflueger, Guido Vogel, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 18, 2155–2174, https://doi.org/10.5194/acp-18-2155-2018, https://doi.org/10.5194/acp-18-2155-2018, 2018
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A novel offline LDI-MS method was developed to analyse particulate matter (PM) collected at multiple sites in central Europe during the entire year of 2013. PM sources were identified by positive matrix factorization. Wood burning emissions were separated according to the burning conditions; inefficient burns had a larger impact on air quality in southern Alpine valleys than in northern Switzerland. Moreover, primary tailpipe exhaust was distinguished from aged/secondary traffic emissions.
Emmanouil Oikonomakis, Sebnem Aksoyoglu, Giancarlo Ciarelli, Urs Baltensperger, and André Stephan Henry Prévôt
Atmos. Chem. Phys., 18, 2175–2198, https://doi.org/10.5194/acp-18-2175-2018, https://doi.org/10.5194/acp-18-2175-2018, 2018
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We report a modeling study investigating the uncertainties in ozone production in Europe. Using various methods for different emission and meteorological scenarios, we searched for the possible reasons for underestimation of high ozone levels in Europe by models. Our results suggest that emissions, especially NOx, might be too low in the European inventories. Improvement of the modeled ozone production will contribute to more consistent and effective ozone mitigation strategies for the future.
Joel Brito, Evelyn Freney, Pamela Dominutti, Agnes Borbon, Sophie L. Haslett, Anneke M. Batenburg, Aurelie Colomb, Regis Dupuy, Cyrielle Denjean, Frederic Burnet, Thierry Bourriane, Adrien Deroubaix, Karine Sellegri, Stephan Borrmann, Hugh Coe, Cyrille Flamant, Peter Knippertz, and Alfons Schwarzenboeck
Atmos. Chem. Phys., 18, 757–772, https://doi.org/10.5194/acp-18-757-2018, https://doi.org/10.5194/acp-18-757-2018, 2018
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This work focuses on sources of submicron aerosol particles over southern West Africa (SWA). Results have shown that isoprene, a gas-phase compound of biogenic origin, is responsible for roughly 25 % of the organic aerosol (OA) loading, under most background or urban plumes alike. This fraction represents a lower estimate from the biogenic contribution in this fairly polluted region. This work sheds light upon the role of anthropogenic and biogenic emissions on the pollution burden over SWA.
Adrien Deroubaix, Cyrille Flamant, Laurent Menut, Guillaume Siour, Sylvain Mailler, Solène Turquety, Régis Briant, Dmitry Khvorostyanov, and Suzanne Crumeyrolle
Atmos. Chem. Phys., 18, 445–465, https://doi.org/10.5194/acp-18-445-2018, https://doi.org/10.5194/acp-18-445-2018, 2018
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CO and PM2.5 are analyzed over the Guinean Gulf coastal region during the beginning of the 2006 West African monsoon. A biomass burning plume from Central Africa is observed since June at the Guinean coast. In June, the modeled anthropogenic PM2.5 concentrations are higher than in May or July. An important part of the pollution emitted along the coastline is transported to the north at night within the surface layer and within the nocturnal low-level jet.
Florian Couvidat, Bertrand Bessagnet, Marta Garcia-Vivanco, Elsa Real, Laurent Menut, and Augustin Colette
Geosci. Model Dev., 11, 165–194, https://doi.org/10.5194/gmd-11-165-2018, https://doi.org/10.5194/gmd-11-165-2018, 2018
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This paper includes the development of a new aerosol module in the air quality model CHIMERE to improve particulate matter (PM) simulation. The results of the model are compared to numerous measurements over Europe to evaluate the strengths and weaknesses of the model.
Jun Zhou, Emily A. Bruns, Peter Zotter, Giulia Stefenelli, André S. H. Prévôt, Urs Baltensperger, Imad El-Haddad, and Josef Dommen
Atmos. Meas. Tech., 11, 65–80, https://doi.org/10.5194/amt-11-65-2018, https://doi.org/10.5194/amt-11-65-2018, 2018
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Reactive oxygen species (ROS) in the particle phase may induce oxidative stress in the human lungs upon inhalation. Here we present and thoroughly characterize a modified online and offline ROS analyzer. Selected model organic compounds were tested and potential interferences from gas-phase and matrix effects of particulate constituents were evaluated. ROS measurements of filter samples revealed the rapid decay of a substantial ROS fraction, supporting the application of online measurements.
Marcel Lerch, Marcel Bliedtner, Christopher-Bastian Roettig, Jan-Uwe Schmidt, Sönke Szidat, Gary Salazar, Roland Zech, Bruno Glaser, Arno Kleber, and Michael Zech
E&G Quaternary Sci. J., 66, 103–108, https://doi.org/10.5194/egqsj-66-103-2018, https://doi.org/10.5194/egqsj-66-103-2018, 2018
Lorenz Wüthrich, Marcel Bliedtner, Imke Kathrin Schäfer, Jana Zech, Fatemeh Shajari, Dorian Gaar, Frank Preusser, Gary Salazar, Sönke Szidat, and Roland Zech
E&G Quaternary Sci. J., 66, 91–100, https://doi.org/10.5194/egqsj-66-91-2017, https://doi.org/10.5194/egqsj-66-91-2017, 2017
Allison N. Schwier, Karine Sellegri, Sébastien Mas, Bruno Charrière, Jorge Pey, Clémence Rose, Brice Temime-Roussel, Jean-Luc Jaffrezo, David Parin, David Picard, Mickael Ribeiro, Greg Roberts, Richard Sempéré, Nicolas Marchand, and Barbara D'Anna
Atmos. Chem. Phys., 17, 14645–14660, https://doi.org/10.5194/acp-17-14645-2017, https://doi.org/10.5194/acp-17-14645-2017, 2017
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In the present paper, we quantify sea-to-air emission fluxes of aerosol to the atmosphere and characterize their physical and chemical properties as a function of the seawater biochemical and physical properties. Fluxes are evaluated with an original approach, a "lab in the field" experiment that preserves the seawater and atmospheric complexity while isolating air-to-sea exchanges from their surroundings. We show different features of the aerosol emission fluxes compared to previous findings.
Ben Langford, James Cash, W. Joe F. Acton, Amy C. Valach, C. Nicholas Hewitt, Silvano Fares, Ignacio Goded, Carsten Gruening, Emily House, Athina-Cerise Kalogridis, Valérie Gros, Richard Schafers, Rick Thomas, Mark Broadmeadow, and Eiko Nemitz
Biogeosciences, 14, 5571–5594, https://doi.org/10.5194/bg-14-5571-2017, https://doi.org/10.5194/bg-14-5571-2017, 2017
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Isoprene flux measurements made above five European oak forests were reviewed to generate new emission potentials. Six variations of the Guenther algorithms were inverted to back out time series of isoprene emission potential, and then an “average” emission potential was determined using one of four commonly used approaches. Our results show that emission potentials can vary by up to a factor of 4 and highlight the need for the community to now harmonize their approach to reduce uncertainty.
Naifang Bei, Jiarui Wu, Miriam Elser, Tian Feng, Junji Cao, Imad El-Haddad, Xia Li, Rujin Huang, Zhengqiang Li, Xin Long, Li Xing, Shuyu Zhao, Xuexi Tie, André S. H. Prévôt, and Guohui Li
Atmos. Chem. Phys., 17, 14579–14591, https://doi.org/10.5194/acp-17-14579-2017, https://doi.org/10.5194/acp-17-14579-2017, 2017
Yunjiang Zhang, Lili Tang, Philip L. Croteau, Olivier Favez, Yele Sun, Manjula R. Canagaratna, Zhuang Wang, Florian Couvidat, Alexandre Albinet, Hongliang Zhang, Jean Sciare, André S. H. Prévôt, John T. Jayne, and Douglas R. Worsnop
Atmos. Chem. Phys., 17, 14501–14517, https://doi.org/10.5194/acp-17-14501-2017, https://doi.org/10.5194/acp-17-14501-2017, 2017
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We conducted the first field measurements of non-refractory fine aerosols (NR-PM2.5) in a megacity of eastern China using a PM2.5-ACSM along with a PM1-ACSM measurement. Inter-comparisons demonstrated that the NR-PM2.5 components can be characterized. Substantial mass fractions of aerosol species were observed in the size range of 1–2.5 μm, with sulfate and SOA being the two largest contributors. The impacts of aerosol water driven by secondary inorganic aerosols on SOA formation were explored.
Yinghe Fu, Karine Desboeufs, Julie Vincent, Elisabeth Bon Nguyen, Benoit Laurent, Remi Losno, and François Dulac
Atmos. Meas. Tech., 10, 4389–4401, https://doi.org/10.5194/amt-10-4389-2017, https://doi.org/10.5194/amt-10-4389-2017, 2017
Uri Dayan, Philippe Ricaud, Régina Zbinden, and François Dulac
Atmos. Chem. Phys., 17, 13233–13263, https://doi.org/10.5194/acp-17-13233-2017, https://doi.org/10.5194/acp-17-13233-2017, 2017
Kaspar R. Daellenbach, Giulia Stefenelli, Carlo Bozzetti, Athanasia Vlachou, Paola Fermo, Raquel Gonzalez, Andrea Piazzalunga, Cristina Colombi, Francesco Canonaco, Christoph Hueglin, Anne Kasper-Giebl, Jean-Luc Jaffrezo, Federico Bianchi, Jay G. Slowik, Urs Baltensperger, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 13265–13282, https://doi.org/10.5194/acp-17-13265-2017, https://doi.org/10.5194/acp-17-13265-2017, 2017
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We present offline AMS analyses for the organic aerosol (OA) in PM10 at nine sites in central Europe for 2013. Primary OA is separated into traffic, cooking, and wood-burning components. A factor explaining sulfur-containing ions, with an event-driven time series, is also separated. We observe enhanced production of secondary OA (SOA) in summer, following biogenic emissions with temperature. In winter a SOA component is dominant, which correlates with anthropogenic inorganic species.
Hendrik Fuchs, Anna Novelli, Michael Rolletter, Andreas Hofzumahaus, Eva Y. Pfannerstill, Stephan Kessel, Achim Edtbauer, Jonathan Williams, Vincent Michoud, Sebastien Dusanter, Nadine Locoge, Nora Zannoni, Valerie Gros, Francois Truong, Roland Sarda-Esteve, Danny R. Cryer, Charlotte A. Brumby, Lisa K. Whalley, Daniel Stone, Paul W. Seakins, Dwayne E. Heard, Coralie Schoemaecker, Marion Blocquet, Sebastien Coudert, Sebastien Batut, Christa Fittschen, Alexander B. Thames, William H. Brune, Cheryl Ernest, Hartwig Harder, Jennifer B. A. Muller, Thomas Elste, Dagmar Kubistin, Stefanie Andres, Birger Bohn, Thorsten Hohaus, Frank Holland, Xin Li, Franz Rohrer, Astrid Kiendler-Scharr, Ralf Tillmann, Robert Wegener, Zhujun Yu, Qi Zou, and Andreas Wahner
Atmos. Meas. Tech., 10, 4023–4053, https://doi.org/10.5194/amt-10-4023-2017, https://doi.org/10.5194/amt-10-4023-2017, 2017
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Hydroxyl radical reactivity (k(OH)) is closely related to processes that lead to the formation of oxidised, secondary pollutants such as ozone and aerosol. In order to compare the performances of instruments measuring k(OH), experiments were conducted in the simulation chamber SAPHIR. Chemical conditions were chosen either to be representative of the atmosphere or to test potential limitations of instruments. Overall, the results show that instruments are capable of measuring k(OH).
Nora Zannoni, Valerie Gros, Roland Sarda Esteve, Cerise Kalogridis, Vincent Michoud, Sebastien Dusanter, Stephane Sauvage, Nadine Locoge, Aurelie Colomb, and Bernard Bonsang
Atmos. Chem. Phys., 17, 12645–12658, https://doi.org/10.5194/acp-17-12645-2017, https://doi.org/10.5194/acp-17-12645-2017, 2017
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Our paper presents results of hydroxyl radical (OH) reactivity from a field study conducted during summer 2013 in a western Mediterranean coastal site (Corsica, France). Here, the total OH reactivity, measured with the comparative reactivity method, is compared with the summed OH reactivity from the reactive gases measured with a multitude of different technologies. Our results demonstrate the relatively high observed reactivity and the large impact of biogenic compounds.
Mounir Chrit, Karine Sartelet, Jean Sciare, Jorge Pey, Nicolas Marchand, Florian Couvidat, Karine Sellegri, and Matthias Beekmann
Atmos. Chem. Phys., 17, 12509–12531, https://doi.org/10.5194/acp-17-12509-2017, https://doi.org/10.5194/acp-17-12509-2017, 2017
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Jean Sciare, Michael Pikridas, Iasonas Stavroulas, Thérèse Salameh, Thierry Leonardis, Vincent Gaudion, Laurence Depelchin, Isabelle Fronval, Roland Sarda-Esteve, Dominique Baisnée, Bernard Bonsang, Chrysanthos Savvides, Mihalis Vrekoussis, and Nadine Locoge
Atmos. Chem. Phys., 17, 11355–11388, https://doi.org/10.5194/acp-17-11355-2017, https://doi.org/10.5194/acp-17-11355-2017, 2017
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An intensive field campaign was conducted in March 2015 in the Eastern Mediterranean region, at a background site of Cyprus. We performed a detailed analysis of the chemical composition of air masses in gas and aerosol phase, and we applied a source apportionment analysis in order to identify the various origins of VOCs. The results suggest that VOCs are mainly of biogenic and regional background origins.
Tesfaye A. Berhanu, Sönke Szidat, Dominik Brunner, Ece Satar, Rüdiger Schanda, Peter Nyfeler, Michael Battaglia, Martin Steinbacher, Samuel Hammer, and Markus Leuenberger
Atmos. Chem. Phys., 17, 10753–10766, https://doi.org/10.5194/acp-17-10753-2017, https://doi.org/10.5194/acp-17-10753-2017, 2017
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Fossil fuel CO2 is the major contributor of anthropogenic CO2 in the atmosphere, and accurate quantification is essential to better understand the carbon cycle. Such accurate quantification can be conducted based on radiocarbon measurements. In this study, we present radiocarbon measurements from a tall tower site in Switzerland. From these measurements, we have observed seasonally varying fossil fuel CO2 contributions and a biospheric CO2 component that varies diurnally and seasonally.
Efisio Solazzo, Christian Hogrefe, Augustin Colette, Marta Garcia-Vivanco, and Stefano Galmarini
Atmos. Chem. Phys., 17, 10435–10465, https://doi.org/10.5194/acp-17-10435-2017, https://doi.org/10.5194/acp-17-10435-2017, 2017
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The work here is conducted within the frame of AQMEII3 and promotes the use of diagnostic methods for the evaluation of air quality models. We highlight the need to move away from aggregated error metrics and to focus on the quality of the information that can be extracted from the model and the observation. This aids the understanding of the causes of model error, providing more useful information to model developers and users than can be gained from common evaluations.
Augustin Colette, Camilla Andersson, Astrid Manders, Kathleen Mar, Mihaela Mircea, Maria-Teresa Pay, Valentin Raffort, Svetlana Tsyro, Cornelius Cuvelier, Mario Adani, Bertrand Bessagnet, Robert Bergström, Gino Briganti, Tim Butler, Andrea Cappelletti, Florian Couvidat, Massimo D'Isidoro, Thierno Doumbia, Hilde Fagerli, Claire Granier, Chris Heyes, Zig Klimont, Narendra Ojha, Noelia Otero, Martijn Schaap, Katarina Sindelarova, Annemiek I. Stegehuis, Yelva Roustan, Robert Vautard, Erik van Meijgaard, Marta Garcia Vivanco, and Peter Wind
Geosci. Model Dev., 10, 3255–3276, https://doi.org/10.5194/gmd-10-3255-2017, https://doi.org/10.5194/gmd-10-3255-2017, 2017
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The EURODELTA-Trends numerical experiment has been designed to assess the capability of chemistry-transport models to capture the evolution of surface air quality over the 1990–2010 period in Europe. It also includes sensitivity experiments in order to analyse the relative contribution of (i) emission changes, (ii) meteorological variability, and (iii) boundary conditions to air quality trends. The article is a detailed presentation of the experiment design and participating models.
Laura-Hélèna Rivellini, Isabelle Chiapello, Emmanuel Tison, Marc Fourmentin, Anaïs Féron, Aboubacry Diallo, Thierno N'Diaye, Philippe Goloub, Francesco Canonaco, André Stephan Henry Prévôt, and Véronique Riffault
Atmos. Chem. Phys., 17, 10291–10314, https://doi.org/10.5194/acp-17-10291-2017, https://doi.org/10.5194/acp-17-10291-2017, 2017
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A 3-month field campaign was conducted in March–June 2015 in Senegal, as part of the SHADOW (SaHAran Dust Over West Africa) project. This article presents the time variability of the chemical composition of submicron particles. Organics (sulfates) were predominant for days under continental (marine) influence. Half the organic sources were identified as local, including one due to open waste-burning, and half were linked to regional air masses and enhanced photochemical processes.
Yi Ming Qin, Hao Bo Tan, Yong Jie Li, Misha I. Schurman, Fei Li, Francesco Canonaco, André S. H. Prévôt, and Chak K. Chan
Atmos. Chem. Phys., 17, 10245–10258, https://doi.org/10.5194/acp-17-10245-2017, https://doi.org/10.5194/acp-17-10245-2017, 2017
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Freshly emitted HOA contributed significantly to the high concentrations of organics at night as heavy-duty vehicles enter downtown Guangzhou, while SOA contributed to the daytime high concentration. The large input of NOx, from automobile emissions, resulted in the significant formation of nitrate in both daytime and nighttime. Mitigating the PM pollution in urbanized areas such as Guangzhou can potentially benefit their peripheral cities, by reductions in traffic-related pollutants.
Claudia Di Biagio, Paola Formenti, Mathieu Cazaunau, Edouard Pangui, Nicolas Marchand, and Jean-François Doussin
Atmos. Meas. Tech., 10, 2923–2939, https://doi.org/10.5194/amt-10-2923-2017, https://doi.org/10.5194/amt-10-2923-2017, 2017
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Mineral dust is one of the most abundant aerosol species at the global scale and an accurate estimation of its absorption at solar wavelengths is crucial to assess its impact on climate. In this work we provide an estimate of the Aethalometer multiple scattering correction for mineral dust aerosols at 450 and 660 nm. Our results suggest that the use of an optimized correction factor can lead to up to 11 % higher absorption coefficient and to 3 % higher single scattering albedo for mineral dust.
Kevin Berland, Clémence Rose, Jorge Pey, Anais Culot, Evelyn Freney, Nikolaos Kalivitis, Giorgios Kouvarakis, José Carlos Cerro, Marc Mallet, Karine Sartelet, Matthias Beckmann, Thierry Bourriane, Greg Roberts, Nicolas Marchand, Nikolaos Mihalopoulos, and Karine Sellegri
Atmos. Chem. Phys., 17, 9567–9583, https://doi.org/10.5194/acp-17-9567-2017, https://doi.org/10.5194/acp-17-9567-2017, 2017
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New particle formation (NPF) from gas-phase precursors is a process that is expected to drive the total number concentration of particles in the atmosphere. Here we use measurements performed simultaneously in Corsica, Crete and Mallorca to show that the spatial extent of the NPF events are several hundreds of kilometers large. Airborne measurements additionally show that nanoparticles in the marine atmosphere can either be of marine origin or from higher altitudes above the continent.
Prettiny K. Ma, Yunliang Zhao, Allen L. Robinson, David R. Worton, Allen H. Goldstein, Amber M. Ortega, Jose L. Jimenez, Peter Zotter, André S. H. Prévôt, Sönke Szidat, and Patrick L. Hayes
Atmos. Chem. Phys., 17, 9237–9259, https://doi.org/10.5194/acp-17-9237-2017, https://doi.org/10.5194/acp-17-9237-2017, 2017
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Airborne particulate matter (PM) negatively impacts air quality in cities throughout the world. An important fraction of PM is organic aerosol. We have evaluated and developed several new models for secondary organic aerosol (SOA), which is formed from the chemical processing of gaseous precursors. Using our model results, we have quantified important SOA sources and precursors and also identified possible model parameterizations that could be used for air quality predictions.
Vincent Michoud, Jean Sciare, Stéphane Sauvage, Sébastien Dusanter, Thierry Léonardis, Valérie Gros, Cerise Kalogridis, Nora Zannoni, Anaïs Féron, Jean-Eudes Petit, Vincent Crenn, Dominique Baisnée, Roland Sarda-Estève, Nicolas Bonnaire, Nicolas Marchand, H. Langley DeWitt, Jorge Pey, Aurélie Colomb, François Gheusi, Sonke Szidat, Iasonas Stavroulas, Agnès Borbon, and Nadine Locoge
Atmos. Chem. Phys., 17, 8837–8865, https://doi.org/10.5194/acp-17-8837-2017, https://doi.org/10.5194/acp-17-8837-2017, 2017
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The ChArMEx SOP2 field campaign took place from 15 July to 5 August 2013 in the western Mediterranean Basin at Ersa, a remote site in Cape Corse. Exhaustive descriptions of the chemical composition of air masses in gas and aerosol phase were performed. An analysis of these measurements was performed using various source-receptor approaches. This led to the identification of several factors linked to primary sources but also to secondary processes of both biogenic and anthropogenic origin.
Carlo Bozzetti, Imad El Haddad, Dalia Salameh, Kaspar Rudolf Daellenbach, Paola Fermo, Raquel Gonzalez, María Cruz Minguillón, Yoshiteru Iinuma, Laurent Poulain, Miriam Elser, Emanuel Müller, Jay Gates Slowik, Jean-Luc Jaffrezo, Urs Baltensperger, Nicolas Marchand, and André Stephan Henry Prévôt
Atmos. Chem. Phys., 17, 8247–8268, https://doi.org/10.5194/acp-17-8247-2017, https://doi.org/10.5194/acp-17-8247-2017, 2017
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We present the first long-term organic aerosol source apportionment in an environment influenced by anthropogenic emissions including biomass burning and industrial processes and an active photochemistry. Online and offline aerosol mass spectrometry were used to characterize these emissions and their transformation. Measurements of organic markers provided insights into the origin of biomass smoke in this area, with different seasonal contributions from domestic heating and agricultural burning.
Marine Claeys, Greg Roberts, Marc Mallet, Jovanna Arndt, Karine Sellegri, Jean Sciare, John Wenger, and Bastien Sauvage
Atmos. Chem. Phys., 17, 7891–7915, https://doi.org/10.5194/acp-17-7891-2017, https://doi.org/10.5194/acp-17-7891-2017, 2017
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Over a period of 5 days (summer 2013), the mass concentration of primary marine aerosols was dominant compared to other aerosols measured at a ground-based measuring site on Corsica. The characteristics of primary marine aerosols such as their size distribution, their optical properties and their direct radiative effect were studied as a function of their ageing and region of emission. These characteristics were compared to two other periods dominated by different aerosol regimes.
Reza Shaiganfar, Steffen Beirle, Hugo Denier van der Gon, Sander Jonkers, Jeroen Kuenen, Herve Petetin, Qijie Zhang, Matthias Beekmann, and Thomas Wagner
Atmos. Chem. Phys., 17, 7853–7890, https://doi.org/10.5194/acp-17-7853-2017, https://doi.org/10.5194/acp-17-7853-2017, 2017
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We determine NOx emissions for Paris in summer 2009 and winter 2009/2010 by combining car MAX-DOAS measurements of NO2 with wind fields. We compare the results with simulations from the CHIMERE model. We derive daily average NOx emissions for Paris of 4.0 × 1025 molecules s−1 for summer and of 6.9 × 1025 molecules s−1 in winter. These values are a factor of about 1.4 and 2.0 larger than the corresponding emissions in the MACC-III emission inventory.
Sylvain Mailler, Laurent Menut, Dmitry Khvorostyanov, Myrto Valari, Florian Couvidat, Guillaume Siour, Solène Turquety, Régis Briant, Paolo Tuccella, Bertrand Bessagnet, Augustin Colette, Laurent Létinois, Kostantinos Markakis, and Frédérik Meleux
Geosci. Model Dev., 10, 2397–2423, https://doi.org/10.5194/gmd-10-2397-2017, https://doi.org/10.5194/gmd-10-2397-2017, 2017
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CHIMERE is a chemistry-transport model initially designed for box-modelling of the regional atmospheric composition. In the recent years, CHIMERE has been extended to be able to model atmospheric composition at all scales from urban to hemispheric scale, which implied major changes on the coordinate systems as well as on physical processes. This study describes how and why these changes have been brought to the model, largely increasing the range of its possible use.
Sebnem Aksoyoglu, Giancarlo Ciarelli, Imad El-Haddad, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 7757–7773, https://doi.org/10.5194/acp-17-7757-2017, https://doi.org/10.5194/acp-17-7757-2017, 2017
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Sources of inorganic aerosols in Europe were investigated using a regional air quality model. Results of this study suggested that biogenic volatile organic coumpounds emitted from vegetation had a significant effect on inorganic aerosols, especially on ammonium nitrate concentrations. Sensitivity analyses showed that it is mainly terpene reactions with nitrate radical at night that lead to a decrease in ammonium nitrate.
Giancarlo Ciarelli, Imad El Haddad, Emily Bruns, Sebnem Aksoyoglu, Ottmar Möhler, Urs Baltensperger, and André S. H. Prévôt
Geosci. Model Dev., 10, 2303–2320, https://doi.org/10.5194/gmd-10-2303-2017, https://doi.org/10.5194/gmd-10-2303-2017, 2017
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In Europe, residential wood-burning emissions constitute one of the main anthropogenic sources of air pollution. Novel wood-burning experiments performed in a state-of-the-art smog chamber provide valuable information on the chemical properties of wood-burning emissions and the transformation in the atmosphere. In this study, these new data were used in a box model to constrain a parameterization suitable for predicting the contribution of wood burning to air pollution with large-scale models.
Giancarlo Ciarelli, Sebnem Aksoyoglu, Imad El Haddad, Emily A. Bruns, Monica Crippa, Laurent Poulain, Mikko Äijälä, Samara Carbone, Evelyn Freney, Colin O'Dowd, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 7653–7669, https://doi.org/10.5194/acp-17-7653-2017, https://doi.org/10.5194/acp-17-7653-2017, 2017
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Organic aerosol (OA) comprises the main fraction of fine particulate matter (PM1). Using a new VBS parameterization, we performed model-based source apportionment studies to assess the importance of different emission sources to the total OA loads in Europe during winter periods. Our results indicate that residential wood burning emissions represent the major source of OA, followed by non-residential emission sources (i.e. traffic and industries).
Juha Kangasluoma, Susanne Hering, David Picard, Gregory Lewis, Joonas Enroth, Frans Korhonen, Markku Kulmala, Karine Sellegri, Michel Attoui, and Tuukka Petäjä
Atmos. Meas. Tech., 10, 2271–2281, https://doi.org/10.5194/amt-10-2271-2017, https://doi.org/10.5194/amt-10-2271-2017, 2017
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The manuscript presents a characterization of three new particle counters able to detect airborne nanoparticles smaller than 3 nm in diameter. We explored some of the parameters affecting the smallest detectable particle size, such as sample flow relative humidity, the particle chemical composition and the electrical charging state. The characterization results help one to select a suitable particle counter for a given application.
Jovanna Arndt, Jean Sciare, Marc Mallet, Greg C. Roberts, Nicolas Marchand, Karine Sartelet, Karine Sellegri, François Dulac, Robert M. Healy, and John C. Wenger
Atmos. Chem. Phys., 17, 6975–7001, https://doi.org/10.5194/acp-17-6975-2017, https://doi.org/10.5194/acp-17-6975-2017, 2017
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The chemical composition of individual PM2.5 particles was measured at a background site on Corsica in the Mediterranean to determine the contribution of different sources to background aerosol in the region. Most of the particles were from fossil fuel combustion and biomass burning, transported to the site from France, Italy and eastern Europe, and also accumulated other species en route. This work shows that largest impact on air quality in the Mediterranean is from anthropogenic emissions.
Sabina Assan, Alexia Baudic, Ali Guemri, Philippe Ciais, Valerie Gros, and Felix R. Vogel
Atmos. Meas. Tech., 10, 2077–2091, https://doi.org/10.5194/amt-10-2077-2017, https://doi.org/10.5194/amt-10-2077-2017, 2017
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This study is dedicated to improving measurement methods when using a Cavity Ring Down Spectroscopy instrument to measure methane at sites with elevated ethane concentrations such as Oil and Gas sites. The research was undertaken after measurements of natural gas samples suggested biased δ13CH4 results. Two instruments were extensively tested to characterize the cross sensitivities to ethane and δ13CH4 and propose corrections. Results indicate that it is imperative to account for the biases.
Markus Furger, María Cruz Minguillón, Varun Yadav, Jay G. Slowik, Christoph Hüglin, Roman Fröhlich, Krag Petterson, Urs Baltensperger, and André S. H. Prévôt
Atmos. Meas. Tech., 10, 2061–2076, https://doi.org/10.5194/amt-10-2061-2017, https://doi.org/10.5194/amt-10-2061-2017, 2017
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An Xact 625 Ambient Metals Monitor was tested during a 3-week summer field campaign at a rural, traffic-influenced site in Switzerland. The objective was to characterize the operation of the instrument, evaluate the data quality by intercomparison with other independent measurements, and test its applicability for aerosol source quantification. The results demonstrate significant advantages compared to traditional elemental analysis methods, with some desirable improvements.
Célia J. Sapart, Natalia Shakhova, Igor Semiletov, Joachim Jansen, Sönke Szidat, Denis Kosmach, Oleg Dudarev, Carina van der Veen, Matthias Egger, Valentine Sergienko, Anatoly Salyuk, Vladimir Tumskoy, Jean-Louis Tison, and Thomas Röckmann
Biogeosciences, 14, 2283–2292, https://doi.org/10.5194/bg-14-2283-2017, https://doi.org/10.5194/bg-14-2283-2017, 2017
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The Arctic Ocean, especially the Siberian shelves, overlays large areas of subsea permafrost that is degrading. We show that methane with a biogenic origin is emitted from this permafrost. At locations where bubble plumes have been observed, methane can escape oxidation in the surface sediment and rapidly migrate through the very shallow water column of this region to escape to the atmosphere, generating a positive radiative feedback.
Pierre Tulet, Andréa Di Muro, Aurélie Colomb, Cyrielle Denjean, Valentin Duflot, Santiago Arellano, Brice Foucart, Jérome Brioude, Karine Sellegri, Aline Peltier, Alessandro Aiuppa, Christelle Barthe, Chatrapatty Bhugwant, Soline Bielli, Patrice Boissier, Guillaume Boudoire, Thierry Bourrianne, Christophe Brunet, Fréderic Burnet, Jean-Pierre Cammas, Franck Gabarrot, Bo Galle, Gaetano Giudice, Christian Guadagno, Fréderic Jeamblu, Philippe Kowalski, Jimmy Leclair de Bellevue, Nicolas Marquestaut, Dominique Mékies, Jean-Marc Metzger, Joris Pianezze, Thierry Portafaix, Jean Sciare, Arnaud Tournigand, and Nicolas Villeneuve
Atmos. Chem. Phys., 17, 5355–5378, https://doi.org/10.5194/acp-17-5355-2017, https://doi.org/10.5194/acp-17-5355-2017, 2017
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The STRAP campaign was conducted in 2015 to investigate the volcanic plumes of Piton de La Fournaise (La Réunion, France). For the first time, measurements were conducted at the local (near the vent) and regional scales around the island. The STRAP 2015 campaign gave a unique set of multi-disciplinary data that can now be used by modellers to improve the numerical parameterisations of the physical and chemical evolution of the volcanic plumes.
Lisa Stirnweis, Claudia Marcolli, Josef Dommen, Peter Barmet, Carla Frege, Stephen M. Platt, Emily A. Bruns, Manuel Krapf, Jay G. Slowik, Robert Wolf, Andre S. H. Prévôt, Urs Baltensperger, and Imad El-Haddad
Atmos. Chem. Phys., 17, 5035–5061, https://doi.org/10.5194/acp-17-5035-2017, https://doi.org/10.5194/acp-17-5035-2017, 2017
Haiyan Li, Qi Zhang, Qiang Zhang, Chunrong Chen, Litao Wang, Zhe Wei, Shan Zhou, Caroline Parworth, Bo Zheng, Francesco Canonaco, André S. H. Prévôt, Ping Chen, Hongliang Zhang, Timothy J. Wallington, and Kebin He
Atmos. Chem. Phys., 17, 4751–4768, https://doi.org/10.5194/acp-17-4751-2017, https://doi.org/10.5194/acp-17-4751-2017, 2017
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The sources and aerosol evolution processes of severe pollution episodes were investigated in Handan during wintertime using real-time measurements. An in-depth analysis of the data uncovered that primary emissions from coal combustion and biomass burning together with secondary formation of sulfate (mainly from SO2 emitted by coal combustion) are important driving factors for haze evolution. Our findings provide useful insights into air pollution control in heavily polluted regions.
Igor B. Konovalov, Matthias Beekmann, Evgeny V. Berezin, Paola Formenti, and Meinrat O. Andreae
Atmos. Chem. Phys., 17, 4513–4537, https://doi.org/10.5194/acp-17-4513-2017, https://doi.org/10.5194/acp-17-4513-2017, 2017
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A shortage of consistent observational evidence on biomass burning (BB) aerosol aging processes hinders the development of their adequate representations in atmospheric models. Here we show that useful insights into the BB aerosol dynamics can be obtained from analysis of satellite measurements of aerosol optical depth and carbon dioxide. Our results indicate that aging processes strongly affect the evolution of BB aerosol in smoke plumes from wildfires in Siberia.
Lorenzo Costantino, Juan Cuesta, Emanuele Emili, Adriana Coman, Gilles Foret, Gaëlle Dufour, Maxim Eremenko, Yohann Chailleux, Matthias Beekmann, and Jean-Marie Flaud
Atmos. Meas. Tech., 10, 1281–1298, https://doi.org/10.5194/amt-10-1281-2017, https://doi.org/10.5194/amt-10-1281-2017, 2017
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Using current space-borne measurements from one spectral domain (TIR or UV), only ozone down to 3–4 km altitude may be observed with adequate vertical sensitivity. Here, we evaluate the potential of a new multispectral retrieval method that combines the information from TIR and UV measurements provided by the new-generation sensors IASI-NG and UVNS. Both are on board the upcoming EPS-SG satellite. This new IASI-NG+UVNS retrieval approach allows observations of ozone layers down to 2 km a.s.l.
Peter Zotter, Hanna Herich, Martin Gysel, Imad El-Haddad, Yanlin Zhang, Griša Močnik, Christoph Hüglin, Urs Baltensperger, Sönke Szidat, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 4229–4249, https://doi.org/10.5194/acp-17-4229-2017, https://doi.org/10.5194/acp-17-4229-2017, 2017
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Most studies use a single Ångström exponent for wood burning (αWB) and traffic (αTR) emissions in the Aethalometer model, used for source apportionment of black carbon, derived from previous work. However, accurate determination of the α values is currently lacking. Comparing radiocarbon measurements (14C) with the Aehtalometer model, good agreement was found, indicating that the Aethalometer model reproduces reasonably well the 14C results using our best estimate of a single αWB and αTR.
Pavlos Kalabokas, Jens Hjorth, Gilles Foret, Gaëlle Dufour, Maxim Eremenko, Guillaume Siour, Juan Cuesta, and Matthias Beekmann
Atmos. Chem. Phys., 17, 3905–3928, https://doi.org/10.5194/acp-17-3905-2017, https://doi.org/10.5194/acp-17-3905-2017, 2017
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The main atmospheric mechanisms linked with spring surface ozone episodes over the western Mediterranean are examined. It comes out that high surface midday ozone values are usually linked with regional ozone episodes, which are strongly influenced by some specific meteorological conditions. The better understanding of the ozone variability in the lower troposphere and the boundary layer over the examined regions will help in the formulation of more effective policies in environment and climate.
Laurent Menut, Sylvain Mailler, Bertrand Bessagnet, Guillaume Siour, Augustin Colette, Florian Couvidat, and Frédérik Meleux
Geosci. Model Dev., 10, 1199–1208, https://doi.org/10.5194/gmd-10-1199-2017, https://doi.org/10.5194/gmd-10-1199-2017, 2017
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A simple and complementary model evaluation technique for regional chemistry transport is discussed. The methodology is based on the concept that we can learn about model performance by comparing the simulation results with observational data available for time periods other than the period originally targeted.
Luka Drinovec, Asta Gregorič, Peter Zotter, Robert Wolf, Emily Anne Bruns, André S. H. Prévôt, Jean-Eudes Petit, Olivier Favez, Jean Sciare, Ian J. Arnold, Rajan K. Chakrabarty, Hans Moosmüller, Agnes Filep, and Griša Močnik
Atmos. Meas. Tech., 10, 1043–1059, https://doi.org/10.5194/amt-10-1043-2017, https://doi.org/10.5194/amt-10-1043-2017, 2017
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Black carbon measurements are usually conducted with absorption filter photometers, which are prone to the filter-loading effect – a saturation of the instrumental response due to the accumulation of the sample in the filter matrix. In this paper, we conducted several field campaigns to investigate the hypothesis that this filter-loading effect depends on the optical properties of particles present in the filter matrix, especially on the coating of black carbon particles.
Ulrike Dusek, Regina Hitzenberger, Anne Kasper-Giebl, Magdalena Kistler, Harro A. J. Meijer, Sönke Szidat, Lukas Wacker, Rupert Holzinger, and Thomas Röckmann
Atmos. Chem. Phys., 17, 3233–3251, https://doi.org/10.5194/acp-17-3233-2017, https://doi.org/10.5194/acp-17-3233-2017, 2017
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Measurements of the radioactive carbon isotope 14C allow to identify the sources of aerosol carbon. We report an extensive 14C source apportionment record in the Netherlands with samples covering a whole year. We discovered that long-range transport has a large influence on aerosol carbon levels. Fossil fuel carbon is least influenced by long-range transport and more regional in origin. Biomass burning seems to be a minor source of aerosol carbon in the Netherlands.
Mikko Äijälä, Liine Heikkinen, Roman Fröhlich, Francesco Canonaco, André S. H. Prévôt, Heikki Junninen, Tuukka Petäjä, Markku Kulmala, Douglas Worsnop, and Mikael Ehn
Atmos. Chem. Phys., 17, 3165–3197, https://doi.org/10.5194/acp-17-3165-2017, https://doi.org/10.5194/acp-17-3165-2017, 2017
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Mass spectrometric measurements commonly yield data on hundreds of variables over thousands of points in time. Refining and synthesising this “raw” data into chemical information necessitates the use of advanced, statistics-based data analysis techniques. Here we present an example of combining data dimensionality reduction (factorisation) with exploratory classification (clustering) and show that the results complement and broaden our current perspectives on aerosol chemical classification.
Efisio Solazzo, Roberto Bianconi, Christian Hogrefe, Gabriele Curci, Paolo Tuccella, Ummugulsum Alyuz, Alessandra Balzarini, Rocío Baró, Roberto Bellasio, Johannes Bieser, Jørgen Brandt, Jesper H. Christensen, Augistin Colette, Xavier Francis, Andrea Fraser, Marta Garcia Vivanco, Pedro Jiménez-Guerrero, Ulas Im, Astrid Manders, Uarporn Nopmongcol, Nutthida Kitwiroon, Guido Pirovano, Luca Pozzoli, Marje Prank, Ranjeet S. Sokhi, Alper Unal, Greg Yarwood, and Stefano Galmarini
Atmos. Chem. Phys., 17, 3001–3054, https://doi.org/10.5194/acp-17-3001-2017, https://doi.org/10.5194/acp-17-3001-2017, 2017
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As part of the third phase of AQMEII, this study uses timescale analysis to apportion error to the responsible processes, detect causes of model error, and identify the processes and scales that require dedicated investigations. The analysis tackles model performance gauging through measurement-to-model comparison, error decomposition, and time series analysis of model biases for ozone, CO, SO2, NO, NO2, PM10, PM2.5, wind speed, and temperature over Europe and North America.
Xavier Querol, Gotzon Gangoiti, Enrique Mantilla, Andrés Alastuey, Maria Cruz Minguillón, Fulvio Amato, Cristina Reche, Mar Viana, Teresa Moreno, Angeliki Karanasiou, Ioar Rivas, Noemí Pérez, Anna Ripoll, Mariola Brines, Marina Ealo, Marco Pandolfi, Hong-Ku Lee, Hee-Ram Eun, Yong-Hee Park, Miguel Escudero, David Beddows, Roy M. Harrison, Amelie Bertrand, Nicolas Marchand, Andrei Lyasota, Bernat Codina, Miriam Olid, Mireia Udina, Bernat Jiménez-Esteve, María R. Soler, Lucio Alonso, Millán Millán, and Kang-Ho Ahn
Atmos. Chem. Phys., 17, 2817–2838, https://doi.org/10.5194/acp-17-2817-2017, https://doi.org/10.5194/acp-17-2817-2017, 2017
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High summer O3 episodes in NE Spain were analysed. We evidence the relevance of local emission of precursors in meteorological scenarios of vertical air mass recirculations, when transboundary contributions are also significant. Forecasting these scenarios and sensitivity analysis of possible O3 precursors drop are key for potential abatement strategies. However, this is a very difficult task due to the complexity of scenarios, the external contributions, and the complex O3 production reactions.
Jenni Kontkanen, Katrianne Lehtipalo, Lauri Ahonen, Juha Kangasluoma, Hanna E. Manninen, Jani Hakala, Clémence Rose, Karine Sellegri, Shan Xiao, Lin Wang, Ximeng Qi, Wei Nie, Aijun Ding, Huan Yu, Shanhu Lee, Veli-Matti Kerminen, Tuukka Petäjä, and Markku Kulmala
Atmos. Chem. Phys., 17, 2163–2187, https://doi.org/10.5194/acp-17-2163-2017, https://doi.org/10.5194/acp-17-2163-2017, 2017
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The concentrations of ~1–3 nm particles were investigated at nine sites around the world. Sub-3 nm particle concentrations were highest at the sites with strong anthropogenic influence. Electrically neutral particles dominated sub-3 nm particle concentrations in polluted environments and in boreal forest during spring and summer. Sub-3 nm particle concentrations were observed to be determined by the availability of precursor vapors rather than the sink caused by preexisting aerosol particles.
Clémence Rose, Karine Sellegri, Isabel Moreno, Fernando Velarde, Michel Ramonet, Kay Weinhold, Radovan Krejci, Marcos Andrade, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 17, 1529–1541, https://doi.org/10.5194/acp-17-1529-2017, https://doi.org/10.5194/acp-17-1529-2017, 2017
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Using an indirect method based on particle size distribution measurements, we show that new particle formation (NPF) is responsible for a large contribution to the cloud condensation nuclei concentration at the highest observatory in the world (Bolivia, 5240 m a.s.l.) as expected from some global model predictions. We also provide unique results related to the influence of the boundary layer on the NPF process, showing direct evidence for the important NPF frequency in the free troposphere.
Emily A. Bruns, Jay G. Slowik, Imad El Haddad, Dogushan Kilic, Felix Klein, Josef Dommen, Brice Temime-Roussel, Nicolas Marchand, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 705–720, https://doi.org/10.5194/acp-17-705-2017, https://doi.org/10.5194/acp-17-705-2017, 2017
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We characterize primary and aged gaseous emissions from residential wood combustion using proton transfer reaction time-of-flight mass spectrometry. This approach allows for improved characterization, particularly of oxygenated gases, which are a considerable fraction of the total gaseous mass emitted during residential wood combustion. This study is the first thorough characterization of organic gases from this source and provides a benchmark for future studies.
Thérèse Salameh, Agnès Borbon, Charbel Afif, Stéphane Sauvage, Thierry Leonardis, Cécile Gaimoz, and Nadine Locoge
Atmos. Chem. Phys., 17, 193–209, https://doi.org/10.5194/acp-17-193-2017, https://doi.org/10.5194/acp-17-193-2017, 2017
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We used detailed speciated measurements of VOCs (volatile organic compounds) to evaluate the spatial heterogeneity of VOC urban emission composition and the consistency of regional and global emission inventories downscaled to Lebanon (EMEP, ACCMIP, and MACCity). The results suggest that systematic and detailed measurements are needed in the eastern Mediterranean Basin in order to better constrain emission inventories.
Carlo Bozzetti, Yuliya Sosedova, Mao Xiao, Kaspar R. Daellenbach, Vidmantas Ulevicius, Vadimas Dudoitis, Genrik Mordas, Steigvilė Byčenkienė, Kristina Plauškaitė, Athanasia Vlachou, Benjamin Golly, Benjamin Chazeau, Jean-Luc Besombes, Urs Baltensperger, Jean-Luc Jaffrezo, Jay G. Slowik, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 17, 117–141, https://doi.org/10.5194/acp-17-117-2017, https://doi.org/10.5194/acp-17-117-2017, 2017
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In this study we present the offline-AMS source apportionment of the submicron organic aerosol (OA) sources conducted over 1 year at three locations in the south east Baltic region, which has so far received small attention. Offline-AMS enabled broadening the AMS spatial and temporal coverage, and provided a full characterization of the OA sources. Source apportionment results revealed that biomass burning and biogenic secondary emissions were the major OA sources during winter and summer.
Chiara Uglietti, Alexander Zapf, Theo Manuel Jenk, Michael Sigl, Sönke Szidat, Gary Salazar, and Margit Schwikowski
The Cryosphere, 10, 3091–3105, https://doi.org/10.5194/tc-10-3091-2016, https://doi.org/10.5194/tc-10-3091-2016, 2016
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A meaningful interpretation of the climatic history contained in ice cores requires a precise chronology. For dating the older and deeper part of the glaciers, radiocarbon analysis can be used when organic matter such as plant or insect fragments are found in the ice. Since this happens rarely, a complementary dating tool, based on radiocarbon dating of the insoluble fraction of carbonaceous aerosols entrapped in the ice, allows for ice dating between 200 and more than 10 000 years.
Lamia Ammoura, Irène Xueref-Remy, Felix Vogel, Valérie Gros, Alexia Baudic, Bernard Bonsang, Marc Delmotte, Yao Té, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 15653–15664, https://doi.org/10.5194/acp-16-15653-2016, https://doi.org/10.5194/acp-16-15653-2016, 2016
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We propose a new approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from atmospheric measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is little sensitive to the regional background level definition. With this new method, we may reveal spatial and seasonal variability in the ratios in Paris.
Ernesto Reyes-Villegas, David C. Green, Max Priestman, Francesco Canonaco, Hugh Coe, André S. H. Prévôt, and James D. Allan
Atmos. Chem. Phys., 16, 15545–15559, https://doi.org/10.5194/acp-16-15545-2016, https://doi.org/10.5194/acp-16-15545-2016, 2016
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For the first time in the UK, an Aerosol Chemical Speciation Monitor was used to measure aerosol concentrations in London in March–December 2013, with further organic aerosol (OA) source apportionment using the ME-2 factorization tool. Five OA sources were identified: biomass burning OA, hydrocarbon-like OA, cooking OA, semivolatile oxygenated OA and low-volatility oxygenated OA. This information can be used to take future action on the respective legislation in order to improve the air quality.
François Gheusi, Pierre Durand, Nicolas Verdier, François Dulac, Jean-Luc Attié, Philippe Commun, Brice Barret, Claude Basdevant, Antoine Clenet, Solène Derrien, Alexis Doerenbecher, Laaziz El Amraoui, Alain Fontaine, Emeric Hache, Corinne Jambert, Elodie Jaumouillé, Yves Meyerfeld, Laurent Roblou, and Flore Tocquer
Atmos. Meas. Tech., 9, 5811–5832, https://doi.org/10.5194/amt-9-5811-2016, https://doi.org/10.5194/amt-9-5811-2016, 2016
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Boundary-layer pressurised balloons allow for horizontal multi-day flights in the lower atmosphere, carrying light scientific payloads. Ozonesondes, usually used for balloon soundings have too short a lifetime for such flights. An adaptation is proposed, whereby conventional sondes are operated with short measurement phases alternating with longer periods of dormancy. The sondes were operated over the western Mediterranean, offering an original perspective on tropospheric ozone.
Jianzhong Xu, Jinsen Shi, Qi Zhang, Xinlei Ge, Francesco Canonaco, André S. H. Prévôt, Matthias Vonwiller, Sönke Szidat, Jinming Ge, Jianmin Ma, Yanqing An, Shichang Kang, and Dahe Qin
Atmos. Chem. Phys., 16, 14937–14957, https://doi.org/10.5194/acp-16-14937-2016, https://doi.org/10.5194/acp-16-14937-2016, 2016
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This study deployed an AMS field study in Lanzhou, a city in northwestern China, evaluating the chemical composition, sources, and processes of urban aerosols during wintertime. In comparison with the results during summer in Lanzhou, the air pollution during winter was more severe and the sources were more complex. In addition, this paper estimates the contributions of fossil and non-fossil sources of organic carbon to primary and secondary organic carbon using the carbon isotopic method.
Sauveur Belviso, Ilja Marco Reiter, Benjamin Loubet, Valérie Gros, Juliette Lathière, David Montagne, Marc Delmotte, Michel Ramonet, Cerise Kalogridis, Benjamin Lebegue, Nicolas Bonnaire, Victor Kazan, Thierry Gauquelin, Catherine Fernandez, and Bernard Genty
Atmos. Chem. Phys., 16, 14909–14923, https://doi.org/10.5194/acp-16-14909-2016, https://doi.org/10.5194/acp-16-14909-2016, 2016
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The role that soil, foliage, and atmospheric dynamics have on surface OCS exchange in a Mediterranean forest ecosystem in southern France (O3HP) was investigated in June of 2012 and 2013 with essentially a top-down approach. Atmospheric data suggest that the site is appropriate for estimating GPP directly from eddy covariance measurements of OCS fluxes, but it is less adequate for scaling NEE to GPP from observations of vertical gradients of OCS relative to CO2 during the daytime.
Petri Tiitta, Ari Leskinen, Liqing Hao, Pasi Yli-Pirilä, Miika Kortelainen, Julija Grigonyte, Jarkko Tissari, Heikki Lamberg, Anni Hartikainen, Kari Kuuspalo, Aki-Matti Kortelainen, Annele Virtanen, Kari E. J. Lehtinen, Mika Komppula, Simone Pieber, André S. H. Prévôt, Timothy B. Onasch, Douglas R. Worsnop, Hendryk Czech, Ralf Zimmermann, Jorma Jokiniemi, and Olli Sippula
Atmos. Chem. Phys., 16, 13251–13269, https://doi.org/10.5194/acp-16-13251-2016, https://doi.org/10.5194/acp-16-13251-2016, 2016
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Real-time measurements of OA aging and SOA formation from logwood combustion were conducted under dark and UV oxidation. Substantial SOA formation was observed in all experiments, leading to twice the initial OA mass emphasizing the importance of the burning conditions for the aging processes. The results prove that emissions are subject to intensive chemical processing in the atmosphere; e.g. the most of the POA was found to become oxidized after the ozone addition, forming aged POA.
Laurent Menut, Guillaume Siour, Sylvain Mailler, Florian Couvidat, and Bertrand Bessagnet
Atmos. Chem. Phys., 16, 12961–12982, https://doi.org/10.5194/acp-16-12961-2016, https://doi.org/10.5194/acp-16-12961-2016, 2016
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The aerosol is modelled during the summer 2013 with the WRF and CHIMERE models and over a large area encompassing Africa, Mediterranean sea and west Europe. The modelled aerosol is compared to available measurements such as the AERONET and EMEP networks. The model ability to estimate the aerosol speciation and size distribution is quantified.
Michael Bressi, Fabrizia Cavalli, Claudio A. Belis, Jean-Philippe Putaud, Roman Fröhlich, Sebastiao Martins dos Santos, Ettore Petralia, André S. H. Prévôt, Massimo Berico, Antonella Malaguti, and Francesco Canonaco
Atmos. Chem. Phys., 16, 12875–12896, https://doi.org/10.5194/acp-16-12875-2016, https://doi.org/10.5194/acp-16-12875-2016, 2016
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Atmospheric particulate matter (PM) levels and resulting impacts on human health are in the Po Valley (Italy) among the highest in Europe. This study discusses submicron PM chemical composition, sources and atmospheric processes in this region, using state-of-the-art measurement techniques and receptor models. Based on these results, effective PM abatement strategies are suggested in the upper Po Valley.
Bertrand Bessagnet, Guido Pirovano, Mihaela Mircea, Cornelius Cuvelier, Armin Aulinger, Giuseppe Calori, Giancarlo Ciarelli, Astrid Manders, Rainer Stern, Svetlana Tsyro, Marta García Vivanco, Philippe Thunis, Maria-Teresa Pay, Augustin Colette, Florian Couvidat, Frédérik Meleux, Laurence Rouïl, Anthony Ung, Sebnem Aksoyoglu, José María Baldasano, Johannes Bieser, Gino Briganti, Andrea Cappelletti, Massimo D'Isidoro, Sandro Finardi, Richard Kranenburg, Camillo Silibello, Claudio Carnevale, Wenche Aas, Jean-Charles Dupont, Hilde Fagerli, Lucia Gonzalez, Laurent Menut, André S. H. Prévôt, Pete Roberts, and Les White
Atmos. Chem. Phys., 16, 12667–12701, https://doi.org/10.5194/acp-16-12667-2016, https://doi.org/10.5194/acp-16-12667-2016, 2016
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The EURODELTA III exercise allows a very comprehensive intercomparison and evaluation of air quality models' performance. On average, the models provide a rather good picture of the particulate matter (PM) concentrations over Europe even if the highest concentrations are underestimated. The meteorology is responsible for model discrepancies, while the lack of emissions, particularly in winter, is mentioned as the main reason for the underestimations of PM.
Chao Yan, Wei Nie, Mikko Äijälä, Matti P. Rissanen, Manjula R. Canagaratna, Paola Massoli, Heikki Junninen, Tuija Jokinen, Nina Sarnela, Silja A. K. Häme, Siegfried Schobesberger, Francesco Canonaco, Lei Yao, André S. H. Prévôt, Tuukka Petäjä, Markku Kulmala, Mikko Sipilä, Douglas R. Worsnop, and Mikael Ehn
Atmos. Chem. Phys., 16, 12715–12731, https://doi.org/10.5194/acp-16-12715-2016, https://doi.org/10.5194/acp-16-12715-2016, 2016
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Highly oxidized multifunctional compounds (HOMs) are known to have a significant contribution to secondary aerosol formation, yet their dominating formation pathways remain unclear in the atmosphere. We apply positive matrix factorization (PMF) on HOM data, and successfully retrieve factors representing different formation pathways. The results improve our understanding of HOM formation, and provide new perspectives on using PMF to study the variation of short-lived specie.
Michaël Sicard, Rubén Barragan, François Dulac, Lucas Alados-Arboledas, and Marc Mallet
Atmos. Chem. Phys., 16, 12177–12203, https://doi.org/10.5194/acp-16-12177-2016, https://doi.org/10.5194/acp-16-12177-2016, 2016
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The seasonal variability of the aerosol optical, microphysical and radiative properties at three insular sites in the western Mediterranean Basin is presented. The main drivers of the observed annual cycles and NE–SW gradients are mineral dust outbreaks in summer and European continental aerosols in spring. The lack of NE–W gradients of some aerosol properties is attributed to a homogeneous spatial distribution of the fine particle load and absorption low values in the southwesternmost site.
Alexia Baudic, Valérie Gros, Stéphane Sauvage, Nadine Locoge, Olivier Sanchez, Roland Sarda-Estève, Cerise Kalogridis, Jean-Eudes Petit, Nicolas Bonnaire, Dominique Baisnée, Olivier Favez, Alexandre Albinet, Jean Sciare, and Bernard Bonsang
Atmos. Chem. Phys., 16, 11961–11989, https://doi.org/10.5194/acp-16-11961-2016, https://doi.org/10.5194/acp-16-11961-2016, 2016
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This article presents ambient air VOC measurements performed in Paris during the MEGAPOLI and FRANCIPOL campaigns (2010). For the first time, we report (O)VOC concentration levels, their temporal variations and their main emission sources. The originality of this study stands in using near-field observations to help strengthen the identification of apportioned sources derived from PMF. An important finding of this work is the high contribution of the wood burning source (50 %) in winter.
Weiwei Hu, Brett B. Palm, Douglas A. Day, Pedro Campuzano-Jost, Jordan E. Krechmer, Zhe Peng, Suzane S. de Sá, Scot T. Martin, M. Lizabeth Alexander, Karsten Baumann, Lina Hacker, Astrid Kiendler-Scharr, Abigail R. Koss, Joost A. de Gouw, Allen H. Goldstein, Roger Seco, Steven J. Sjostedt, Jeong-Hoo Park, Alex B. Guenther, Saewung Kim, Francesco Canonaco, André S. H. Prévôt, William H. Brune, and Jose L. Jimenez
Atmos. Chem. Phys., 16, 11563–11580, https://doi.org/10.5194/acp-16-11563-2016, https://doi.org/10.5194/acp-16-11563-2016, 2016
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IEPOX-SOA is biogenically derived secondary organic aerosol under anthropogenic influence, which has been shown to comprise a substantial fraction of OA globally. We investigated the lifetime of ambient IEPOX-SOA in the SE US and Amazonia, with an oxidation flow reactor and thermodenuder coupled with MS-based instrumentation. The low volatility and long lifetime of IEPOX-SOA against OH radicals' oxidation (> 2 weeks) was observed, which can help to constrain OA impact on air quality and climate.
Aurélien Chauvigné, Karine Sellegri, Maxime Hervo, Nadège Montoux, Patrick Freville, and Philippe Goloub
Atmos. Meas. Tech., 9, 4569–4585, https://doi.org/10.5194/amt-9-4569-2016, https://doi.org/10.5194/amt-9-4569-2016, 2016
A. M. Yáñez-Serrano, A. C. Nölscher, E. Bourtsoukidis, B. Derstroff, N. Zannoni, V. Gros, M. Lanza, J. Brito, S. M. Noe, E. House, C. N. Hewitt, B. Langford, E. Nemitz, T. Behrendt, J. Williams, P. Artaxo, M. O. Andreae, and J. Kesselmeier
Atmos. Chem. Phys., 16, 10965–10984, https://doi.org/10.5194/acp-16-10965-2016, https://doi.org/10.5194/acp-16-10965-2016, 2016
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This paper provides a general overview of methyl ethyl ketone (MEK) ambient observations in different ecosystems around the world in order to provide insights into the sources, sink and role of MEK in the atmosphere.
Hervé Petetin, Jean Sciare, Michael Bressi, Valérie Gros, Amandine Rosso, Olivier Sanchez, Roland Sarda-Estève, Jean-Eudes Petit, and Matthias Beekmann
Atmos. Chem. Phys., 16, 10419–10440, https://doi.org/10.5194/acp-16-10419-2016, https://doi.org/10.5194/acp-16-10419-2016, 2016
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This paper presents the first combined measurements of both ammonium nitrate aerosols and their gaseous precursors (HNO3, NH3) in the Paris megacity, obtained during the FRANCIPOL and PARTICULES campaigns. This data set is used to investigate the nitrate formation regime within the city, which is particularly important considering the high contribution of nitrates in the fine aerosol pollution of Paris. In addition, it is also used to evaluate the CHIMERE chemistry-transport model.
Giancarlo Ciarelli, Sebnem Aksoyoglu, Monica Crippa, Jose-Luis Jimenez, Eriko Nemitz, Karine Sellegri, Mikko Äijälä, Samara Carbone, Claudia Mohr, Colin O'Dowd, Laurent Poulain, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 10313–10332, https://doi.org/10.5194/acp-16-10313-2016, https://doi.org/10.5194/acp-16-10313-2016, 2016
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Recent studies based on aerosol mass spectrometer measurements revealed that the organic fraction dominates the non-refractory PM1 composition. However its representation in chemical transport models is still very challenging due to uncertainties in emission sources and formation pathways. In this study, a novel organic aerosol scheme was tested in the regional air quality model CAMx and results were compared with ambient measurements at 11 different sites in Europe.
Jean-Baptiste Renard, François Dulac, Gwenaël Berthet, Thibaut Lurton, Damien Vignelles, Fabrice Jégou, Thierry Tonnelier, Matthieu Jeannot, Benoit Couté, Rony Akiki, Nicolas Verdier, Marc Mallet, François Gensdarmes, Patrick Charpentier, Samuel Mesmin, Vincent Duverger, Jean-Charles Dupont, Thierry Elias, Vincent Crenn, Jean Sciare, Paul Zieger, Matthew Salter, Tjarda Roberts, Jérôme Giacomoni, Matthieu Gobbi, Eric Hamonou, Haraldur Olafsson, Pavla Dagsson-Waldhauserova, Claude Camy-Peyret, Christophe Mazel, Thierry Décamps, Martin Piringer, Jérémy Surcin, and Daniel Daugeron
Atmos. Meas. Tech., 9, 3673–3686, https://doi.org/10.5194/amt-9-3673-2016, https://doi.org/10.5194/amt-9-3673-2016, 2016
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We illustrate the first Light Optical Aerosol Counter (LOAC) airborne results obtained from an unmanned aerial vehicle (UAV) and a variety of scientific balloons: tethered balloons deployed in urban environments, pressurized balloons drifting in the lower troposphere over the western Mediterranean during the Chemistry-Aerosol Mediterranean Experiment (ChArMEx), and meteorological sounding balloons launched in the western Mediterranean region and in the south-west of France.
Patrick Schlag, Astrid Kiendler-Scharr, Marcus Johannes Blom, Francesco Canonaco, Jeroen Sebastiaan Henzing, Marcel Moerman, André Stephan Henry Prévôt, and Rupert Holzinger
Atmos. Chem. Phys., 16, 8831–8847, https://doi.org/10.5194/acp-16-8831-2016, https://doi.org/10.5194/acp-16-8831-2016, 2016
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This work provides chemical composition data of atmospheric aerosols acquired during 1 year in the rural site of Cabauw, the Netherlands. In some periods, we found unexpected high particle mass concentrations exceeding the WHO limits. Using these composition data, we found that reducing ammonia emissions in this region would largely reduce the main aerosol component ammonium nitrate, whereas the local mitigation of the organics turned out to be difficult due to the lack of a designated source.
Julie Vincent, Benoit Laurent, Rémi Losno, Elisabeth Bon Nguyen, Pierre Roullet, Stéphane Sauvage, Servanne Chevaillier, Patrice Coddeville, Noura Ouboulmane, Alcide Giorgio di Sarra, Antonio Tovar-Sánchez, Damiano Sferlazzo, Ana Massanet, Sylvain Triquet, Rafael Morales Baquero, Michel Fornier, Cyril Coursier, Karine Desboeufs, François Dulac, and Gilles Bergametti
Atmos. Chem. Phys., 16, 8749–8766, https://doi.org/10.5194/acp-16-8749-2016, https://doi.org/10.5194/acp-16-8749-2016, 2016
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To investigate dust deposition dynamics at the regional scale, five automatic deposition collectors named CARAGA have been deployed in the western Mediterranean basin (Lampedusa, Majorca, Corsica, Frioul and Le Casset) during 1 to 3 years depending on the station. Complementary observations provided by both satellite and air mass trajectories are used to identify the dust provenance areas and the transport pathways from the Sahara to the stations for the studied period.
Miriam Elser, Carlo Bozzetti, Imad El-Haddad, Marek Maasikmets, Erik Teinemaa, Rene Richter, Robert Wolf, Jay G. Slowik, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 7117–7134, https://doi.org/10.5194/acp-16-7117-2016, https://doi.org/10.5194/acp-16-7117-2016, 2016
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This work presents the first detailed in-situ measurements of major air pollutants (including NR-PM2.5, eBC, and trace gases) in the two biggest cities in Estonia. The sources of organic aerosols were investigated by means of positive matrix factorization. Highly time-resolved mobile measurements allowed for the identification of source areas and the determination of regional background concentrations as well as urban increments of the individual components.
María José Granados-Muñoz, Francisco Navas-Guzmán, Juan Luis Guerrero-Rascado, Juan Antonio Bravo-Aranda, Ioannis Binietoglou, Sergio Nepomuceno Pereira, Sara Basart, José María Baldasano, Livio Belegante, Anatoli Chaikovsky, Adolfo Comerón, Giuseppe D'Amico, Oleg Dubovik, Luka Ilic, Panos Kokkalis, Constantino Muñoz-Porcar, Slobodan Nickovic, Doina Nicolae, Francisco José Olmo, Alexander Papayannis, Gelsomina Pappalardo, Alejandro Rodríguez, Kerstin Schepanski, Michaël Sicard, Ana Vukovic, Ulla Wandinger, François Dulac, and Lucas Alados-Arboledas
Atmos. Chem. Phys., 16, 7043–7066, https://doi.org/10.5194/acp-16-7043-2016, https://doi.org/10.5194/acp-16-7043-2016, 2016
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This study provides a detailed overview of the Mediterranean region regarding aerosol microphysical properties during the ChArMEx/EMEP campaign in July 2012. An in-depth analysis of the horizontal, vertical, and temporal dimensions is performed using LIRIC, proving the algorithm's ability in automated retrieval of microphysical property profiles within a network. A validation of four dust models is included, obtaining fair good agreement, especially for the vertical distribution of the aerosol.
Andrés Alastuey, Xavier Querol, Wenche Aas, Franco Lucarelli, Noemí Pérez, Teresa Moreno, Fabrizia Cavalli, Hans Areskoug, Violeta Balan, Maria Catrambone, Darius Ceburnis, José C. Cerro, Sébastien Conil, Lusine Gevorgyan, Christoph Hueglin, Kornelia Imre, Jean-Luc Jaffrezo, Sarah R. Leeson, Nikolaos Mihalopoulos, Marta Mitosinkova, Colin D. O'Dowd, Jorge Pey, Jean-Philippe Putaud, Véronique Riffault, Anna Ripoll, Jean Sciare, Karine Sellegri, Gerald Spindler, and Karl Espen Yttri
Atmos. Chem. Phys., 16, 6107–6129, https://doi.org/10.5194/acp-16-6107-2016, https://doi.org/10.5194/acp-16-6107-2016, 2016
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Mineral dust content in PM10 was analysed at 20 regional background sites across Europe. Higher dust loadings were observed at most sites in summer, with the most elevated concentrations in the southern- and easternmost countries, due to external and regional sources. Saharan dust outbreaks impacted western and central European in summer and eastern Mediterranean sites in winter. The spatial distribution of some metals reveals the influence of specific anthropogenic sources on a regional scale.
Vidmantas Ulevicius, Steigvilė Byčenkienė, Carlo Bozzetti, Athanasia Vlachou, Kristina Plauškaitė, Genrik Mordas, Vadimas Dudoitis, Gülcin Abbaszade, Vidmantas Remeikis, Andrius Garbaras, Agne Masalaite, Jan Blees, Roman Fröhlich, Kaspar R. Dällenbach, Francesco Canonaco, Jay G. Slowik, Josef Dommen, Ralf Zimmermann, Jürgen Schnelle-Kreis, Gary A. Salazar, Konstantinos Agrios, Sönke Szidat, Imad El Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 5513–5529, https://doi.org/10.5194/acp-16-5513-2016, https://doi.org/10.5194/acp-16-5513-2016, 2016
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In early spring the Baltic region is frequently affected by high pollution events due to biomass burning in that area. Here we present a comprehensive study to investigate the impact of biomass/grass burning (BB) on the evolution and composition of aerosol in Preila, Lithuania, during springtime open fires.
Jean-Baptiste Renard, François Dulac, Gwenaël Berthet, Thibaut Lurton, Damien Vignelles, Fabrice Jégou, Thierry Tonnelier, Matthieu Jeannot, Benoit Couté, Rony Akiki, Nicolas Verdier, Marc Mallet, François Gensdarmes, Patrick Charpentier, Samuel Mesmin, Vincent Duverger, Jean-Charles Dupont, Thierry Elias, Vincent Crenn, Jean Sciare, Paul Zieger, Matthew Salter, Tjarda Roberts, Jérôme Giacomoni, Matthieu Gobbi, Eric Hamonou, Haraldur Olafsson, Pavla Dagsson-Waldhauserova, Claude Camy-Peyret, Christophe Mazel, Thierry Décamps, Martin Piringer, Jérémy Surcin, and Daniel Daugeron
Atmos. Meas. Tech., 9, 1721–1742, https://doi.org/10.5194/amt-9-1721-2016, https://doi.org/10.5194/amt-9-1721-2016, 2016
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LOAC is a light aerosols counter for performing measurements at the surface and under all kinds of atmospheric balloons. LOAC performs observations at two scattering angles. The first one at 12° is insensitive to the refractive index of the particles; the second one at 60° is strongly sensitive to the refractive index. By combining the measurements, it is possible to retrieve the size distribution between 0.2 and 100 micrometeres and to estimate the nature of the dominant particles.
Gerard Ancellet, Jacques Pelon, Julien Totems, Patrick Chazette, Ariane Bazureau, Michaël Sicard, Tatiana Di Iorio, Francois Dulac, and Marc Mallet
Atmos. Chem. Phys., 16, 4725–4742, https://doi.org/10.5194/acp-16-4725-2016, https://doi.org/10.5194/acp-16-4725-2016, 2016
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A multi-lidar analysis conducted in the Mediterranean basin compares the impact of the long-range transport of North American biomass burning aerosols with the role of frequently observed Saharan dust outbreaks. This paper provides a detailed analysis of the potential North American aerosol sources, their transport to Europe and the mixing of different aerosol sources, using simulations of a particle dispersion model and lidar measurements of the aerosol optical properties.
Vincent Lemaire, Isabelle Coll, Florian Couvidat, Camille Mouchel-Vallon, Christian Seigneur, and Guillaume Siour
Geosci. Model Dev., 9, 1361–1382, https://doi.org/10.5194/gmd-9-1361-2016, https://doi.org/10.5194/gmd-9-1361-2016, 2016
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Oligomerization is one of the most important identified processes of secondary organic aerosol evolution. We have simulated the formation of oligomers from biogenic precursors, using two different parameterizations implemented in the air quality model CHIMERE. This study shows that oligomer concentration fields are quite sensitive to the way the competition between local formation, evaporation and transport is restituted. The benefits and disadvantages of each approach are discussed in details.
Emma Järvinen, Karoliina Ignatius, Leonid Nichman, Thomas B. Kristensen, Claudia Fuchs, Christopher R. Hoyle, Niko Höppel, Joel C. Corbin, Jill Craven, Jonathan Duplissy, Sebastian Ehrhart, Imad El Haddad, Carla Frege, Hamish Gordon, Tuija Jokinen, Peter Kallinger, Jasper Kirkby, Alexei Kiselev, Karl-Heinz Naumann, Tuukka Petäjä, Tamara Pinterich, Andre S. H. Prevot, Harald Saathoff, Thea Schiebel, Kamalika Sengupta, Mario Simon, Jay G. Slowik, Jasmin Tröstl, Annele Virtanen, Paul Vochezer, Steffen Vogt, Andrea C. Wagner, Robert Wagner, Christina Williamson, Paul M. Winkler, Chao Yan, Urs Baltensperger, Neil M. Donahue, Rick C. Flagan, Martin Gallagher, Armin Hansel, Markku Kulmala, Frank Stratmann, Douglas R. Worsnop, Ottmar Möhler, Thomas Leisner, and Martin Schnaiter
Atmos. Chem. Phys., 16, 4423–4438, https://doi.org/10.5194/acp-16-4423-2016, https://doi.org/10.5194/acp-16-4423-2016, 2016
Christos Fountoukis, Athanasios G. Megaritis, Ksakousti Skyllakou, Panagiotis E. Charalampidis, Hugo A. C. Denier van der Gon, Monica Crippa, André S. H. Prévôt, Friederike Fachinger, Alfred Wiedensohler, Christodoulos Pilinis, and Spyros N. Pandis
Atmos. Chem. Phys., 16, 3727–3741, https://doi.org/10.5194/acp-16-3727-2016, https://doi.org/10.5194/acp-16-3727-2016, 2016
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We use PMCAMx with high grid resolution over Paris to simulate carbonaceous aerosol during the summer and winter MEGAPOLI campaigns. PMCAMx reproduces BC observations well. Addition of cooking organic aerosol emissions of 80 mg per day per capita is needed to reproduce the corresponding observations. While the oxygenated organic aerosol predictions during the summer are encouraging a major wintertime source appears to be missing.
Thérèse Salameh, Stéphane Sauvage, Charbel Afif, Agnès Borbon, and Nadine Locoge
Atmos. Chem. Phys., 16, 3595–3607, https://doi.org/10.5194/acp-16-3595-2016, https://doi.org/10.5194/acp-16-3595-2016, 2016
Miriam Elser, Ru-Jin Huang, Robert Wolf, Jay G. Slowik, Qiyuan Wang, Francesco Canonaco, Guohui Li, Carlo Bozzetti, Kaspar R. Daellenbach, Yu Huang, Renjian Zhang, Zhengqiang Li, Junji Cao, Urs Baltensperger, Imad El-Haddad, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 3207–3225, https://doi.org/10.5194/acp-16-3207-2016, https://doi.org/10.5194/acp-16-3207-2016, 2016
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This work represents the first online chemical characterization of the PM2.5 using a high-resolution time-of flight aerosol mass spectrometer during extreme haze events China. The application of novel source apportionment techniques allowed for an improved identification and quantification of the sources of organic aerosols. The main sources and processes driving the extreme haze events are assessed.
Junwen Liu, Jun Li, Di Liu, Ping Ding, Chengde Shen, Yangzhi Mo, Xinming Wang, Chunling Luo, Zhineng Cheng, Sönke Szidat, Yanlin Zhang, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 16, 2985–2996, https://doi.org/10.5194/acp-16-2985-2016, https://doi.org/10.5194/acp-16-2985-2016, 2016
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Many Chinese cities now are suffering the high loadings of fine particular matters, which can bring a lot of negative impacts on air quality, human health, and the climate system. The Chinese government generally focuses on the control of the emissions from vehicles and industry. Our results evidently show that the burning of biomass materials such as wood and agricultural residues can lead to the urban air pollution in China. The characteristic of haze covering China is distinct from regions.
Vincent E. P. Lemaire, Augustin Colette, and Laurent Menut
Atmos. Chem. Phys., 16, 2559–2574, https://doi.org/10.5194/acp-16-2559-2016, https://doi.org/10.5194/acp-16-2559-2016, 2016
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Because of its sensitivity to unfavorable weather patterns, air pollution is sensitive to climate change. Its impact is typically assessed using deterministic chemistry-transport models forced by an ensemble of climate projection. Because of the high computational cost of such initiative, elaborated techniques are required to optimize the exploration of ensemble of future projections. We develop such a technique, which also allows quantifying uncertainties in climate and air quality projections.
Andrea Paciga, Eleni Karnezi, Evangelia Kostenidou, Lea Hildebrandt, Magda Psichoudaki, Gabriella J. Engelhart, Byong-Hyoek Lee, Monica Crippa, André S. H. Prévôt, Urs Baltensperger, and Spyros N. Pandis
Atmos. Chem. Phys., 16, 2013–2023, https://doi.org/10.5194/acp-16-2013-2016, https://doi.org/10.5194/acp-16-2013-2016, 2016
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We estimate the volatility distribution for the organic aerosol (OA) components during summer and winter field campaigns in Paris, France as part of the collaborative project MEGAPOLI. The OA factors (hydrocarbon like OA, cooking OA, marine OA, oxygenated OA) had a broad spectrum of volatilities with no direct link between the average volatility and average oxygen to carbon of the OA components.
Sebnem Aksoyoglu, Urs Baltensperger, and André S. H. Prévôt
Atmos. Chem. Phys., 16, 1895–1906, https://doi.org/10.5194/acp-16-1895-2016, https://doi.org/10.5194/acp-16-1895-2016, 2016
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As a least-regulated source, ship emissions contribute significantly to air pollution. We used an air quality model to determine the effects of international shipping on the annual and seasonal concentrations of ozone, primary and secondary components of PM2.5, and dry and wet deposition of N and S compounds in Europe. The results presented in this paper suggest evolution of NOx emissions from ships and land-based NH3 emissions will play a significant role in the future European air quality.
L. Brégonzio-Rozier, C. Giorio, F. Siekmann, E. Pangui, S. B. Morales, B. Temime-Roussel, A. Gratien, V. Michoud, M. Cazaunau, H. L. DeWitt, A. Tapparo, A. Monod, and J.-F. Doussin
Atmos. Chem. Phys., 16, 1747–1760, https://doi.org/10.5194/acp-16-1747-2016, https://doi.org/10.5194/acp-16-1747-2016, 2016
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The impact of cloud events on isoprene secondary organic aerosol (SOA) formation has been studied from an isoprene/ NOx/light system in an atmospheric simulation chamber. aqSOA formation can be linked to water soluble volatile organic compounds' dissolution in the aqueous phase and to further aqueous phase reactions. Cloud-induced SOA formation is experimentally demonstrated in this study, thus highlighting the importance of aqueous multiphase systems in atmospheric SOA formation estimations.
C. R. Hoyle, C. Fuchs, E. Järvinen, H. Saathoff, A. Dias, I. El Haddad, M. Gysel, S. C. Coburn, J. Tröstl, A.-K. Bernhammer, F. Bianchi, M. Breitenlechner, J. C. Corbin, J. Craven, N. M. Donahue, J. Duplissy, S. Ehrhart, C. Frege, H. Gordon, N. Höppel, M. Heinritzi, T. B. Kristensen, U. Molteni, L. Nichman, T. Pinterich, A. S. H. Prévôt, M. Simon, J. G. Slowik, G. Steiner, A. Tomé, A. L. Vogel, R. Volkamer, A. C. Wagner, R. Wagner, A. S. Wexler, C. Williamson, P. M. Winkler, C. Yan, A. Amorim, J. Dommen, J. Curtius, M. W. Gallagher, R. C. Flagan, A. Hansel, J. Kirkby, M. Kulmala, O. Möhler, F. Stratmann, D. R. Worsnop, and U. Baltensperger
Atmos. Chem. Phys., 16, 1693–1712, https://doi.org/10.5194/acp-16-1693-2016, https://doi.org/10.5194/acp-16-1693-2016, 2016
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A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed via the aqueous phase oxidation of sulphur dioxide by ozone. The rate of this reaction has previously only been measured over a relatively small temperature range. Here, we use the state of the art CLOUD chamber at CERN to perform the first measurements of this reaction rate in super-cooled droplets, confirming that the existing extrapolation of the reaction rate to sub-zero temperatures is accurate.
S. Mailler, L. Menut, A. G. di Sarra, S. Becagli, T. Di Iorio, B. Bessagnet, R. Briant, P. Formenti, J.-F. Doussin, J. L. Gómez-Amo, M. Mallet, G. Rea, G. Siour, D. M. Sferlazzo, R. Traversi, R. Udisti, and S. Turquety
Atmos. Chem. Phys., 16, 1219–1244, https://doi.org/10.5194/acp-16-1219-2016, https://doi.org/10.5194/acp-16-1219-2016, 2016
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We studied the impact of aerosols on tropospheric photolysis rates at Lampedusa during the CharMEx/ADRIMED campaign in June 2013. It is shown by using the CHIMERE chemistry-transport model (CTM) as well as in situ and remote-sensing measurements that taking into account the radiative effect of the tropospheric aerosols improves the ability of the model to reproduce the observed photolysis rates. It is hence important for CTMs to include the radiative effect of aerosols on photochemistry.
L. Xu, L. R. Williams, D. E. Young, J. D. Allan, H. Coe, P. Massoli, E. Fortner, P. Chhabra, S. Herndon, W. A. Brooks, J. T. Jayne, D. R. Worsnop, A. C. Aiken, S. Liu, K. Gorkowski, M. K. Dubey, Z. L. Fleming, S. Visser, A. S. H. Prévôt, and N. L. Ng
Atmos. Chem. Phys., 16, 1139–1160, https://doi.org/10.5194/acp-16-1139-2016, https://doi.org/10.5194/acp-16-1139-2016, 2016
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We investigate the spatial distribution of submicron aerosol in the greater London area as part of the Clean Air for London (ClearfLo) project in winter 2012. Although the concentrations of organic aerosol (OA) are similar between a rural and an urban site, the OA sources are different. We also examine the volatility of submicron aerosol at the rural site and find that the non-volatile organics have similar sources or have undergone similar chemical processing as refractory black carbon.
C. Denjean, F. Cassola, A. Mazzino, S. Triquet, S. Chevaillier, N. Grand, T. Bourrianne, G. Momboisse, K. Sellegri, A. Schwarzenbock, E. Freney, M. Mallet, and P. Formenti
Atmos. Chem. Phys., 16, 1081–1104, https://doi.org/10.5194/acp-16-1081-2016, https://doi.org/10.5194/acp-16-1081-2016, 2016
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This study investigates the size distribution, chemical composition, and optical properties of Saharan mineral dust transported over the western Mediterranean using in situ measurements collected from aircraft. Their variability due to altitude, time of transport, and mixing rate with pollution particles are discussed. We found moderate light absorption of the dust plumes even in the presence of pollution particles and the persistence of large dust particles after transport in the Mediterranean.
M. Mallet, F. Dulac, P. Formenti, P. Nabat, J. Sciare, G. Roberts, J. Pelon, G. Ancellet, D. Tanré, F. Parol, C. Denjean, G. Brogniez, A. di Sarra, L. Alados-Arboledas, J. Arndt, F. Auriol, L. Blarel, T. Bourrianne, P. Chazette, S. Chevaillier, M. Claeys, B. D'Anna, Y. Derimian, K. Desboeufs, T. Di Iorio, J.-F. Doussin, P. Durand, A. Féron, E. Freney, C. Gaimoz, P. Goloub, J. L. Gómez-Amo, M. J. Granados-Muñoz, N. Grand, E. Hamonou, I. Jankowiak, M. Jeannot, J.-F. Léon, M. Maillé, S. Mailler, D. Meloni, L. Menut, G. Momboisse, J. Nicolas, T. Podvin, V. Pont, G. Rea, J.-B. Renard, L. Roblou, K. Schepanski, A. Schwarzenboeck, K. Sellegri, M. Sicard, F. Solmon, S. Somot, B Torres, J. Totems, S. Triquet, N. Verdier, C. Verwaerde, F. Waquet, J. Wenger, and P. Zapf
Atmos. Chem. Phys., 16, 455–504, https://doi.org/10.5194/acp-16-455-2016, https://doi.org/10.5194/acp-16-455-2016, 2016
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The aim of this article is to present an experimental campaign over the Mediterranean focused on aerosol-radiation measurements and modeling. Results indicate an important atmospheric loading associated with a moderate absorbing ability of mineral dust. Observations suggest a complex vertical structure and size distributions characterized by large aerosols within dust plumes. The radiative effect is highly variable, with negative forcing over the Mediterranean and positive over northern Africa.
K. R. Daellenbach, C. Bozzetti, A. Křepelová, F. Canonaco, R. Wolf, P. Zotter, P. Fermo, M. Crippa, J. G. Slowik, Y. Sosedova, Y. Zhang, R.-J. Huang, L. Poulain, S. Szidat, U. Baltensperger, I. El Haddad, and A. S. H. Prévôt
Atmos. Meas. Tech., 9, 23–39, https://doi.org/10.5194/amt-9-23-2016, https://doi.org/10.5194/amt-9-23-2016, 2016
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In this study, we developed an offline technique using the AMS for the characterization of the chemical fingerprints of aerosols collected on quartz filters, and evaluated the suitability of the organic mass spectral data for source apportionment. This technique may be used to enhance the AMS capabilities in measuring size-fractionated, spatially resolved long-term data sets.
Q. J. Zhang, M. Beekmann, E. Freney, K. Sellegri, J. M. Pichon, A. Schwarzenboeck, A. Colomb, T. Bourrianne, V. Michoud, and A. Borbon
Atmos. Chem. Phys., 15, 13973–13992, https://doi.org/10.5194/acp-15-13973-2015, https://doi.org/10.5194/acp-15-13973-2015, 2015
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Secondary organic aerosol (SOA) is an important pollutant formed from megacity emissions at a regional scale. An original method based on ratios of different pollutants is used to specifically validate the aerosol scheme (the volatility basis set approach) within a CTM. The method is applied to airborne measurements performed within the Paris plume during the MEGAPOLI summer campaign. Simulations indicate that SOA of anthropogenic origin has a significant impact on regional air quality.
V. Crenn, J. Sciare, P. L. Croteau, S. Verlhac, R. Fröhlich, C. A. Belis, W. Aas, M. Äijälä, A. Alastuey, B. Artiñano, D. Baisnée, N. Bonnaire, M. Bressi, M. Canagaratna, F. Canonaco, C. Carbone, F. Cavalli, E. Coz, M. J. Cubison, J. K. Esser-Gietl, D. C. Green, V. Gros, L. Heikkinen, H. Herrmann, C. Lunder, M. C. Minguillón, G. Močnik, C. D. O'Dowd, J. Ovadnevaite, J.-E. Petit, E. Petralia, L. Poulain, M. Priestman, V. Riffault, A. Ripoll, R. Sarda-Estève, J. G. Slowik, A. Setyan, A. Wiedensohler, U. Baltensperger, A. S. H. Prévôt, J. T. Jayne, and O. Favez
Atmos. Meas. Tech., 8, 5063–5087, https://doi.org/10.5194/amt-8-5063-2015, https://doi.org/10.5194/amt-8-5063-2015, 2015
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A large intercomparison study of 13 Q-ACSM was conducted for a 3-week period in the region of Paris to evaluate the performance of this instrument and to monitor the major NR-PM1 chemical components. Reproducibility expanded uncertainties of Q-ACSM concentration measurements were found to be 9, 15, 19, 28, and 36% for NR-PM1, NO3, OM, SO4, and NH4, respectively. Some recommendations regarding best calibration practices, standardized data processing and data treatment are also provided.
I. B. Konovalov, M. Beekmann, E. V. Berezin, H. Petetin, T. Mielonen, I. N. Kuznetsova, and M. O. Andreae
Atmos. Chem. Phys., 15, 13269–13297, https://doi.org/10.5194/acp-15-13269-2015, https://doi.org/10.5194/acp-15-13269-2015, 2015
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(1) The mesoscale evolution of aerosol from open biomass burning (BB) has been successfully simulated using the volatility basis set (VBS) framework. (2) The simulations disregarding semivolatile nature of organic compounds forming BB aerosol are found to be inconsistent with measurements in the region and period affected by the Russian 2010 wildfires. (3) The VBS method enables one to improve the consistency of "top-down" and "bottom-up" estimates of BB aerosol emissions.
M. Sicard, G. D'Amico, A. Comerón, L. Mona, L. Alados-Arboledas, A. Amodeo, H. Baars, J. M. Baldasano, L. Belegante, I. Binietoglou, J. A. Bravo-Aranda, A. J. Fernández, P. Fréville, D. García-Vizcaíno, A. Giunta, M. J. Granados-Muñoz, J. L. Guerrero-Rascado, D. Hadjimitsis, A. Haefele, M. Hervo, M. Iarlori, P. Kokkalis, D. Lange, R. E. Mamouri, I. Mattis, F. Molero, N. Montoux, A. Muñoz, C. Muñoz Porcar, F. Navas-Guzmán, D. Nicolae, A. Nisantzi, N. Papagiannopoulos, A. Papayannis, S. Pereira, J. Preißler, M. Pujadas, V. Rizi, F. Rocadenbosch, K. Sellegri, V. Simeonov, G. Tsaknakis, F. Wagner, and G. Pappalardo
Atmos. Meas. Tech., 8, 4587–4613, https://doi.org/10.5194/amt-8-4587-2015, https://doi.org/10.5194/amt-8-4587-2015, 2015
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In the framework of the ACTRIS summer 2012 measurement campaign (8 June–17 July 2012), EARLINET organized and performed a controlled exercise of feasibility to demonstrate its potential to perform operational, coordinated measurements and deliver products in near-real time. The paper describes the measurement protocol and discusses the delivery of real-time and near-real-time lidar-derived products.
G. Guyot, C. Gourbeyre, G. Febvre, V. Shcherbakov, F. Burnet, J.-C. Dupont, K. Sellegri, and O. Jourdan
Atmos. Meas. Tech., 8, 4347–4367, https://doi.org/10.5194/amt-8-4347-2015, https://doi.org/10.5194/amt-8-4347-2015, 2015
R. Fröhlich, M. J. Cubison, J. G. Slowik, N. Bukowiecki, F. Canonaco, P. L. Croteau, M. Gysel, S. Henne, E. Herrmann, J. T. Jayne, M. Steinbacher, D. R. Worsnop, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 15, 11373–11398, https://doi.org/10.5194/acp-15-11373-2015, https://doi.org/10.5194/acp-15-11373-2015, 2015
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This manuscript presents the first long-term (14-month) and highly time-resolved (10 min) measurements of NR-PM1 aerosol chemical composition at a high-altitude site (JFJ, Switzerland, 3580m a.s.l.). The elevated location allowed the investigation of free tropospheric aerosol year round. Total and relative mass loadings, diurnal variations as well as seasonal variations are discussed together with geographical origin, organic aerosol sources and the influence of the planetary boundary layer.
M. Lopez, M. Schmidt, M. Ramonet, J.-L. Bonne, A. Colomb, V. Kazan, P. Laj, and J.-M. Pichon
Atmos. Meas. Tech., 8, 3941–3958, https://doi.org/10.5194/amt-8-3941-2015, https://doi.org/10.5194/amt-8-3941-2015, 2015
N. Zannoni, S. Dusanter, V. Gros, R. Sarda Esteve, V. Michoud, V. Sinha, N. Locoge, and B. Bonsang
Atmos. Meas. Tech., 8, 3851–3865, https://doi.org/10.5194/amt-8-3851-2015, https://doi.org/10.5194/amt-8-3851-2015, 2015
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Our manuscript shows results of an intercomparison exercise conducted on two home-built comparative reactivity method (CRM) instruments operating under the same settings for measuring total OH reactivity. Despite the corrections of the raw data sets for instrumental artifacts having different weights on the two CRMs, we found very consistent results for the final processed data of ambient OH reactivity. Furthermore, we present in detail how to validate the instruments and process the raw data.
G. O. Mouteva, S. M. Fahrni, G. M. Santos, J. T. Randerson, Y.-L. Zhang, S. Szidat, and C. I. Czimczik
Atmos. Meas. Tech., 8, 3729–3743, https://doi.org/10.5194/amt-8-3729-2015, https://doi.org/10.5194/amt-8-3729-2015, 2015
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We describe a stepwise uncertainty analysis of 14C measurements of organic (OC) and elemental (EC) carbon fractions of aerosols. Using the Swiss_4S thermal-optical protocol with a newly established trapping setup, we show that we can efficiently isolate and trap each carbon fraction and perform 14C analysis of ultra-small OC and EC samples with high accuracy and low 14C blanks. Our study presents a first step towards the development of a common protocol for OC and EC 14C measurements.
M. Pikridas, J. Sciare, F. Freutel, S. Crumeyrolle, S.-L. von der Weiden-Reinmüller, A. Borbon, A. Schwarzenboeck, M. Merkel, M. Crippa, E. Kostenidou, M. Psichoudaki, L. Hildebrandt, G. J. Engelhart, T. Petäjä, A. S. H. Prévôt, F. Drewnick, U. Baltensperger, A. Wiedensohler, M. Kulmala, M. Beekmann, and S. N. Pandis
Atmos. Chem. Phys., 15, 10219–10237, https://doi.org/10.5194/acp-15-10219-2015, https://doi.org/10.5194/acp-15-10219-2015, 2015
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Aerosol size distribution measurements from three ground sites, two mobile laboratories, and one airplane are combined to investigate the spatial and temporal variability of ultrafine particles in and around Paris during the summer and winter MEGAPOLI campaigns. The role of nucleation as a particle source and the influence of Paris emissions on their surroundings are examined.
C. Rose, K. Sellegri, E. Freney, R. Dupuy, A. Colomb, J.-M. Pichon, M. Ribeiro, T. Bourianne, F. Burnet, and A. Schwarzenboeck
Atmos. Chem. Phys., 15, 10203–10218, https://doi.org/10.5194/acp-15-10203-2015, https://doi.org/10.5194/acp-15-10203-2015, 2015
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In the present paper we report airborne measurements of new particle formation (NPF) above the Mediterranean Sea (HYMEX campaign). We show that NPF occurs over large areas above the sea, but the process is clearly promoted at high altitude, above 1000m, i.e. frequently in the free troposphere. NPF also seems to be mainly influenced by local processes occurring above the sea. After their formation, particles slowly grow at high altitude while not being greatly depleted or affected by coagulation.
V. Marécal, V.-H. Peuch, C. Andersson, S. Andersson, J. Arteta, M. Beekmann, A. Benedictow, R. Bergström, B. Bessagnet, A. Cansado, F. Chéroux, A. Colette, A. Coman, R. L. Curier, H. A. C. Denier van der Gon, A. Drouin, H. Elbern, E. Emili, R. J. Engelen, H. J. Eskes, G. Foret, E. Friese, M. Gauss, C. Giannaros, J. Guth, M. Joly, E. Jaumouillé, B. Josse, N. Kadygrov, J. W. Kaiser, K. Krajsek, J. Kuenen, U. Kumar, N. Liora, E. Lopez, L. Malherbe, I. Martinez, D. Melas, F. Meleux, L. Menut, P. Moinat, T. Morales, J. Parmentier, A. Piacentini, M. Plu, A. Poupkou, S. Queguiner, L. Robertson, L. Rouïl, M. Schaap, A. Segers, M. Sofiev, L. Tarasson, M. Thomas, R. Timmermans, Á. Valdebenito, P. van Velthoven, R. van Versendaal, J. Vira, and A. Ung
Geosci. Model Dev., 8, 2777–2813, https://doi.org/10.5194/gmd-8-2777-2015, https://doi.org/10.5194/gmd-8-2777-2015, 2015
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This paper describes the air quality forecasting system over Europe put in place in the Monitoring Atmospheric Composition and Climate projects. It provides daily and 4-day forecasts and analyses for the previous day for major gas and particulate pollutants and their main precursors. These products are based on a multi-model approach using seven state-of-the-art models developed in Europe. An evaluation of the performance of the system is discussed in the paper.
H. Petetin, M. Beekmann, A. Colomb, H. A. C. Denier van der Gon, J.-C. Dupont, C. Honoré, V. Michoud, Y. Morille, O. Perrussel, A. Schwarzenboeck, J. Sciare, A. Wiedensohler, and Q. J. Zhang
Atmos. Chem. Phys., 15, 9799–9818, https://doi.org/10.5194/acp-15-9799-2015, https://doi.org/10.5194/acp-15-9799-2015, 2015
V. Michoud, R. F. Hansen, N. Locoge, P. S. Stevens, and S. Dusanter
Atmos. Meas. Tech., 8, 3537–3553, https://doi.org/10.5194/amt-8-3537-2015, https://doi.org/10.5194/amt-8-3537-2015, 2015
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This study presents the results of an exhaustive characterization of a CRM instrument developed at Mines Douai to measure total OH reactivity in the troposphere. To do so, a suite of laboratory experiments was conducted to assess the different corrections that need to be applied during data processing. The results were then compared to simulations from a 0-D box model, including two different chemical mechanisms, leading to reasonable agreement.
M. Beekmann, A. S. H. Prévôt, F. Drewnick, J. Sciare, S. N. Pandis, H. A. C. Denier van der Gon, M. Crippa, F. Freutel, L. Poulain, V. Ghersi, E. Rodriguez, S. Beirle, P. Zotter, S.-L. von der Weiden-Reinmüller, M. Bressi, C. Fountoukis, H. Petetin, S. Szidat, J. Schneider, A. Rosso, I. El Haddad, A. Megaritis, Q. J. Zhang, V. Michoud, J. G. Slowik, S. Moukhtar, P. Kolmonen, A. Stohl, S. Eckhardt, A. Borbon, V. Gros, N. Marchand, J. L. Jaffrezo, A. Schwarzenboeck, A. Colomb, A. Wiedensohler, S. Borrmann, M. Lawrence, A. Baklanov, and U. Baltensperger
Atmos. Chem. Phys., 15, 9577–9591, https://doi.org/10.5194/acp-15-9577-2015, https://doi.org/10.5194/acp-15-9577-2015, 2015
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A detailed characterization of air quality in the Paris (France) agglomeration, a megacity, during two summer and winter intensive campaigns and from additional 1-year observations, revealed that about 70% of the fine particulate matter (PM) at urban background is transported into the megacity from upwind regions. Unexpectedly, a major part of organic PM is of modern origin (woodburning and cooking activities, secondary formation from biogenic VOC).
C. Di Biagio, L. Doppler, C. Gaimoz, N. Grand, G. Ancellet, J.-C. Raut, M. Beekmann, A. Borbon, K. Sartelet, J.-L. Attié, F. Ravetta, and P. Formenti
Atmos. Chem. Phys., 15, 9611–9630, https://doi.org/10.5194/acp-15-9611-2015, https://doi.org/10.5194/acp-15-9611-2015, 2015
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Observations from this study indicate that continental pollution largely affects the atmospheric composition and structure of the western Mediterranean basin. Pollution plumes reach 3000-4000 m in altitude and present a very complex and highly stratified structure, characterized by fresh and aged layers both in the boundary layer and in the free troposphere. Also we report the observations of high levels of ultrafine particles over the basin, possibly linked to new particle formation events.
P. S. Monks, A. T. Archibald, A. Colette, O. Cooper, M. Coyle, R. Derwent, D. Fowler, C. Granier, K. S. Law, G. E. Mills, D. S. Stevenson, O. Tarasova, V. Thouret, E. von Schneidemesser, R. Sommariva, O. Wild, and M. L. Williams
Atmos. Chem. Phys., 15, 8889–8973, https://doi.org/10.5194/acp-15-8889-2015, https://doi.org/10.5194/acp-15-8889-2015, 2015
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Ozone holds a certain fascination in atmospheric science. It is ubiquitous in the atmosphere, central to tropospheric oxidation chemistry, and yet harmful to human and ecosystem health as well as being an important greenhouse gas. It is not emitted into the atmosphere but is a byproduct of the very oxidation chemistry it largely initiates. This review examines current understanding of the processes regulating tropospheric ozone at global to local scales from both measurements and models.
E. Athanasopoulou, A. P. Protonotariou, E. Bossioli, A. Dandou, M. Tombrou, J. D. Allan, H. Coe, N. Mihalopoulos, J. Kalogiros, A. Bacak, J. Sciare, and G. Biskos
Atmos. Chem. Phys., 15, 8401–8421, https://doi.org/10.5194/acp-15-8401-2015, https://doi.org/10.5194/acp-15-8401-2015, 2015
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A model system is evaluated versus ground and airborne aerosol measurements, towards the identification of its competencies and deficiencies over the eastern Mediterranean (EM) during summer. Secondary organic aerosol (OA) formation is investigated towards improving OA behaviour. Biomass burning is a significant particle source, largely explaining OA underestimation (ca. 50%). More than 70% of the aerosol mass over the EM is related to trans-boundary transport during strong northeastern winds.
G. Rea, S. Turquety, L. Menut, R. Briant, S. Mailler, and G. Siour
Atmos. Chem. Phys., 15, 8013–8036, https://doi.org/10.5194/acp-15-8013-2015, https://doi.org/10.5194/acp-15-8013-2015, 2015
A. N. Schwier, C. Rose, E. Asmi, A. M. Ebling, W. M. Landing, S. Marro, M.-L. Pedrotti, A. Sallon, F. Iuculano, S. Agusti, A. Tsiola, P. Pitta, J. Louis, C. Guieu, F. Gazeau, and K. Sellegri
Atmos. Chem. Phys., 15, 7961–7976, https://doi.org/10.5194/acp-15-7961-2015, https://doi.org/10.5194/acp-15-7961-2015, 2015
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The effect of ocean acidification and changing water conditions on primary (and secondary) marine aerosol emissions is not well understood on a regional or a global scale. To investigate this effect, we deployed mesocosms in the Mediterranean Sea for several weeks during both winter pre-bloom and summer oligotrophic conditions and subjected them to various levels of CO2. We observed larger effects due to the differences between a pre-bloom and oligotrophic environment than due to CO2 levels.
R. Shaiganfar, S. Beirle, H. Petetin, Q. Zhang, M. Beekmann, and T. Wagner
Atmos. Meas. Tech., 8, 2827–2852, https://doi.org/10.5194/amt-8-2827-2015, https://doi.org/10.5194/amt-8-2827-2015, 2015
C. C. Hoerger, A. Claude, C. Plass-Duelmer, S. Reimann, E. Eckart, R. Steinbrecher, J. Aalto, J. Arduini, N. Bonnaire, J. N. Cape, A. Colomb, R. Connolly, J. Diskova, P. Dumitrean, C. Ehlers, V. Gros, H. Hakola, M. Hill, J. R. Hopkins, J. Jäger, R. Junek, M. K. Kajos, D. Klemp, M. Leuchner, A. C. Lewis, N. Locoge, M. Maione, D. Martin, K. Michl, E. Nemitz, S. O'Doherty, P. Pérez Ballesta, T. M. Ruuskanen, S. Sauvage, N. Schmidbauer, T. G. Spain, E. Straube, M. Vana, M. K. Vollmer, R. Wegener, and A. Wenger
Atmos. Meas. Tech., 8, 2715–2736, https://doi.org/10.5194/amt-8-2715-2015, https://doi.org/10.5194/amt-8-2715-2015, 2015
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The performance of 20 European laboratories involved in long-term non-methane hydrocarbon (NMHC) measurements was assessed with respect to ACTRIS and GAW data quality objectives. The participants were asked to measure both a 30-component NMHC mixture in nitrogen and whole air. The NMHCs were analysed either by GC-FID or GC-MS. Most systems performed well for the NMHC in nitrogen, whereas in air more scatter was observed. Reasons for this are explained in the paper.
F. Canonaco, J. G. Slowik, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 15, 6993–7002, https://doi.org/10.5194/acp-15-6993-2015, https://doi.org/10.5194/acp-15-6993-2015, 2015
R. Fröhlich, V. Crenn, A. Setyan, C. A. Belis, F. Canonaco, O. Favez, V. Riffault, J. G. Slowik, W. Aas, M. Aijälä, A. Alastuey, B. Artiñano, N. Bonnaire, C. Bozzetti, M. Bressi, C. Carbone, E. Coz, P. L. Croteau, M. J. Cubison, J. K. Esser-Gietl, D. C. Green, V. Gros, L. Heikkinen, H. Herrmann, J. T. Jayne, C. R. Lunder, M. C. Minguillón, G. Močnik, C. D. O'Dowd, J. Ovadnevaite, E. Petralia, L. Poulain, M. Priestman, A. Ripoll, R. Sarda-Estève, A. Wiedensohler, U. Baltensperger, J. Sciare, and A. S. H. Prévôt
Atmos. Meas. Tech., 8, 2555–2576, https://doi.org/10.5194/amt-8-2555-2015, https://doi.org/10.5194/amt-8-2555-2015, 2015
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Source apportionment (SA) of organic aerosol mass spectrometric data measured with the Aerodyne ACSM using PMF/ME2 is a frequently used technique in the AMS/ACSM community. ME2 uncertainties due to instrument-to-instrument variations are elucidated by performing SA on ambient data from 14 individual, co-located ACSMs, recorded during the first ACTRIS ACSM intercomparison study at SIRTA near Paris (France). The mean uncertainty was 17.2%. Recommendations for future studies using ME2 are provided.
F. Hourdin, M. Gueye, B. Diallo, J.-L. Dufresne, J. Escribano, L. Menut, B. Marticoréna, G. Siour, and F. Guichard
Atmos. Chem. Phys., 15, 6775–6788, https://doi.org/10.5194/acp-15-6775-2015, https://doi.org/10.5194/acp-15-6775-2015, 2015
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New parameterizations of the convective boundary layer are used to better represent the diurnal cycle of near-surface wind over Sahara and Sahel in a climate model and the associated emission of dust.
M. C. Minguillón, A. Ripoll, N. Pérez, A. S. H. Prévôt, F. Canonaco, X. Querol, and A. Alastuey
Atmos. Chem. Phys., 15, 6379–6391, https://doi.org/10.5194/acp-15-6379-2015, https://doi.org/10.5194/acp-15-6379-2015, 2015
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The study focuses on the aerosol variations found in the regional background of the western Mediterranean basin and their relation with atmospheric conditions and scenarios. An Aerosol Chemical Speciation Monitor (ACSM) was deployed for 1 year and the results were validated with co-located PM1 measurements. The organic sources were investigated and the local secondary organic aerosol (SOA) formation was estimated.
L. Menut, S. Mailler, G. Siour, B. Bessagnet, S. Turquety, G. Rea, R. Briant, M. Mallet, J. Sciare, P. Formenti, and F. Meleux
Atmos. Chem. Phys., 15, 6159–6182, https://doi.org/10.5194/acp-15-6159-2015, https://doi.org/10.5194/acp-15-6159-2015, 2015
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The ozone and aerosol concentration variability is studied over the Euro-Mediterranean area during the months of June and July 2013 and in the framework of the ADRIMED project. A first analysis is performed using meteorological variables, ozone and aerosol concentrations using routine network station, satellite and specific ADRIMED project airborne measurements. This analysis is complemented by modeling using the WRF and CHIMERE regional models.
S. Zhu, K. N. Sartelet, and C. Seigneur
Geosci. Model Dev., 8, 1595–1612, https://doi.org/10.5194/gmd-8-1595-2015, https://doi.org/10.5194/gmd-8-1595-2015, 2015
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This article presents the Size-Composition Resolved Aerosol Model (SCRAM) for simulating the dynamics of externally mixed atmospheric particles. The model is first validated by comparison with a reference solution and with results of simulations using internally mixed particles. Then, the importance of representing the mixing state when modelling atmospheric aerosol concentrations is investigated in a box model simulation using data representative of air pollution in Greater Paris.
K. Violaki, J. Sciare, J. Williams, A. R. Baker, M. Martino, and N. Mihalopoulos
Biogeosciences, 12, 3131–3140, https://doi.org/10.5194/bg-12-3131-2015, https://doi.org/10.5194/bg-12-3131-2015, 2015
P. L. Hayes, A. G. Carlton, K. R. Baker, R. Ahmadov, R. A. Washenfelder, S. Alvarez, B. Rappenglück, J. B. Gilman, W. C. Kuster, J. A. de Gouw, P. Zotter, A. S. H. Prévôt, S. Szidat, T. E. Kleindienst, J. H. Offenberg, P. K. Ma, and J. L. Jimenez
Atmos. Chem. Phys., 15, 5773–5801, https://doi.org/10.5194/acp-15-5773-2015, https://doi.org/10.5194/acp-15-5773-2015, 2015
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(1) Four different parameterizations for the formation and chemical evolution of secondary organic aerosol (SOA) are evaluated using a box model representing the Los Angeles region during the CalNex campaign.
(2) The SOA formed only from the oxidation of VOCs is insufficient to explain the observed SOA concentrations.
(3) The amount of SOA mass formed from diesel vehicle emissions is estimated to be 16-27%.
(4) Modeled SOA depends strongly on the P-S/IVOC volatility distribution.
J. P. Krüger, J. Leifeld, S. Glatzel, S. Szidat, and C. Alewell
Biogeosciences, 12, 2861–2871, https://doi.org/10.5194/bg-12-2861-2015, https://doi.org/10.5194/bg-12-2861-2015, 2015
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Biogeochemical soil parameters are studied to detect peatland degradation along a land use gradient (intensive, extensive, near-natural). Stable carbon isotopes, radiocarbon ages and ash content confirm peat growth in the near-natural bog but also indicate previous degradation. When the bog is managed extensively or intensively as grassland, all parameters indicate degradation and substantial C loss of the order of 18.8 to 42.9 kg C m-2.
C. Barbet, L. Deguillaume, N. Chaumerliac, M. Leriche, A. Berger, E. Freney, A. Colomb, K. Sellegri, L. Patryl, and P. Armand
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-13395-2015, https://doi.org/10.5194/acpd-15-13395-2015, 2015
Preprint withdrawn
L. Drinovec, G. Močnik, P. Zotter, A. S. H. Prévôt, C. Ruckstuhl, E. Coz, M. Rupakheti, J. Sciare, T. Müller, A. Wiedensohler, and A. D. A. Hansen
Atmos. Meas. Tech., 8, 1965–1979, https://doi.org/10.5194/amt-8-1965-2015, https://doi.org/10.5194/amt-8-1965-2015, 2015
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We present a new real-time algorithm for compensation of the filter-loading effect in filter photometers, based on a two parallel spot measurement of optical absorption. This algorithm has been incorporated into the new Aethalometer AE33. Intercomparison studies show excellent reproducibility of the AE33 measurements and very good agreement with post-processed data obtained using earlier aethalometer models and other filter-based absorption photometers.
H. L. DeWitt, S. Hellebust, B. Temime-Roussel, S. Ravier, L. Polo, V. Jacob, C. Buisson, A. Charron, M. André, A. Pasquier, J. L. Besombes, J. L. Jaffrezo, H. Wortham, and N. Marchand
Atmos. Chem. Phys., 15, 4373–4387, https://doi.org/10.5194/acp-15-4373-2015, https://doi.org/10.5194/acp-15-4373-2015, 2015
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By performing source-apportionment modeling, the amount of primary and secondary organic emissions was resolved from a bulk aerosol data set measured adjacent to a major highway in France. Over 70% of vehicles on this highway were diesel, and a high concentration of BC and NOx were measured. Even close to a major highway, the bulk of the aerosol mass was secondary in nature. Radiocarbon data revealed that most of the fossil organic carbon was from primary vehicular emissions and not from SOA.
F. Couvidat and K. Sartelet
Geosci. Model Dev., 8, 1111–1138, https://doi.org/10.5194/gmd-8-1111-2015, https://doi.org/10.5194/gmd-8-1111-2015, 2015
J.-F. Léon, P. Augustin, M. Mallet, T. Bourrianne, V. Pont, F. Dulac, M. Fourmentin, D. Lambert, and B. Sauvage
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-9507-2015, https://doi.org/10.5194/acpd-15-9507-2015, 2015
Preprint withdrawn
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This paper presents the aerosol vertical distribution observed by lidar soundings in Corsica (western Mediterranean) between February 2012 and August 2013. A seasonal cycle is observed in the extinction coefficient profiles and aerosol optical thickness with minima in winter and maxima in spring-summer. Less than 10% of the daily observations show high AOD corresponding to the large-scale advection of desert dust from Northern Africa or pollution aerosols from Europe.
C. Rose, K. Sellegri, E. Asmi, M. Hervo, E. Freney, A. Colomb, H. Junninen, J. Duplissy, M. Sipilä, J. Kontkanen, K. Lehtipalo, and M. Kulmala
Atmos. Chem. Phys., 15, 3413–3428, https://doi.org/10.5194/acp-15-3413-2015, https://doi.org/10.5194/acp-15-3413-2015, 2015
L. R. Crilley, W. J. Bloss, J. Yin, D. C. S. Beddows, R. M. Harrison, J. D. Allan, D. E. Young, M. Flynn, P. Williams, P. Zotter, A. S. H. Prevot, M. R. Heal, J. F. Barlow, C. H. Halios, J. D. Lee, S. Szidat, and C. Mohr
Atmos. Chem. Phys., 15, 3149–3171, https://doi.org/10.5194/acp-15-3149-2015, https://doi.org/10.5194/acp-15-3149-2015, 2015
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Wood is a renewable fuel but its combustion for residential heating releases a number of locally acting air pollutants, most notably particulate matter known to have adverse effects on human health. This paper used chemical tracers for wood smoke to estimate the contribution that burning wood makes to concentrations of airborne particles in the atmosphere of southern England and most particularly in London.
J.-E. Petit, O. Favez, J. Sciare, V. Crenn, R. Sarda-Estève, N. Bonnaire, G. Močnik, J.-C. Dupont, M. Haeffelin, and E. Leoz-Garziandia
Atmos. Chem. Phys., 15, 2985–3005, https://doi.org/10.5194/acp-15-2985-2015, https://doi.org/10.5194/acp-15-2985-2015, 2015
E. Katragkou, M. García-Díez, R. Vautard, S. Sobolowski, P. Zanis, G. Alexandri, R. M. Cardoso, A. Colette, J. Fernandez, A. Gobiet, K. Goergen, T. Karacostas, S. Knist, S. Mayer, P. M. M. Soares, I. Pytharoulis, I. Tegoulias, A. Tsikerdekis, and D. Jacob
Geosci. Model Dev., 8, 603–618, https://doi.org/10.5194/gmd-8-603-2015, https://doi.org/10.5194/gmd-8-603-2015, 2015
E. A. Bruns, M. Krapf, J. Orasche, Y. Huang, R. Zimmermann, L. Drinovec, G. Močnik, I. El-Haddad, J. G. Slowik, J. Dommen, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 15, 2825–2841, https://doi.org/10.5194/acp-15-2825-2015, https://doi.org/10.5194/acp-15-2825-2015, 2015
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Residential wood combustion contributes significantly to the total atmospheric particulate burden; however, uncertainties remain in the magnitude and characteristics of wood burning products. The effects of wood loading on freshly emitted and aged emissions were investigated. Polycyclic aromatic hydrocarbons, which negatively impact health, contributed more to the total organic aerosol under highly loaded burner conditions, which has significant implications for burner operation protocols.
P. Panteliadis, T. Hafkenscheid, B. Cary, E. Diapouli, A. Fischer, O. Favez, P. Quincey, M. Viana, R. Hitzenberger, R. Vecchi, D. Saraga, J. Sciare, J. L. Jaffrezo, A. John, J. Schwarz, M. Giannoni, J. Novak, A. Karanasiou, P. Fermo, and W. Maenhaut
Atmos. Meas. Tech., 8, 779–792, https://doi.org/10.5194/amt-8-779-2015, https://doi.org/10.5194/amt-8-779-2015, 2015
Y. J. Zhang, L. L. Tang, Z. Wang, H. X. Yu, Y. L. Sun, D. Liu, W. Qin, F. Canonaco, A. S. H. Prévôt, H. L. Zhang, and H. C. Zhou
Atmos. Chem. Phys., 15, 1331–1349, https://doi.org/10.5194/acp-15-1331-2015, https://doi.org/10.5194/acp-15-1331-2015, 2015
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The chemical composition, sources, and evolution processes of PM1 were investigated with an Aerodyne ACSM during harvest seasons in the Yangtze River delta, China. Two biomass burning organic aerosol (BBOA) factors derived from PMF model were assessed. The oxidized BBOA contributes ~80% of the total BBOA loadings in the BB plumes. Evidence that BBOA may be oxidized to more aged and less volatile organics during the aging process was suggested.
J. Kaiser, G. M. Wolfe, B. Bohn, S. Broch, H. Fuchs, L. N. Ganzeveld, S. Gomm, R. Häseler, A. Hofzumahaus, F. Holland, J. Jäger, X. Li, I. Lohse, K. Lu, A. S. H. Prévôt, F. Rohrer, R. Wegener, R. Wolf, T. F. Mentel, A. Kiendler-Scharr, A. Wahner, and F. N. Keutsch
Atmos. Chem. Phys., 15, 1289–1298, https://doi.org/10.5194/acp-15-1289-2015, https://doi.org/10.5194/acp-15-1289-2015, 2015
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Using measurements acquired from a Zeppelin airship during the PEGASOS 2012 campaign, we show that VOC oxidation alone cannot account for the formaldehyde concentrations observed in the morning over rural Italy. Vertical profiles suggest a ground-level source of HCHO. Incorporating this additional HCHO source into a photochemical model increases calculated O3 production by as much as 12%.
Y.-L. Zhang, R.-J. Huang, I. El Haddad, K.-F. Ho, J.-J. Cao, Y. Han, P. Zotter, C. Bozzetti, K. R. Daellenbach, F. Canonaco, J. G. Slowik, G. Salazar, M. Schwikowski, J. Schnelle-Kreis, G. Abbaszade, R. Zimmermann, U. Baltensperger, A. S. H. Prévôt, and S. Szidat
Atmos. Chem. Phys., 15, 1299–1312, https://doi.org/10.5194/acp-15-1299-2015, https://doi.org/10.5194/acp-15-1299-2015, 2015
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Source apportionment of fine carbonaceous aerosols using radiocarbon and other organic markers measurements during 2013 winter haze episodes was conducted at four megacities in China. Our results demonstrate that fossil emissions predominate EC with a mean contribution of 75±8%, whereas non-fossil sources account for 55±10% of OC; and the increment of TC on heavily polluted days was mainly driven by the increase of secondary OC from both fossil-fuel and non-fossil emissions.
J.-B. Renard, F. Dulac, G. Berthet, T. Lurton, D. Vignelles, F. Jégou, T. Tonnelier, C. Thaury, M. Jeannot, B. Couté, R. Akiki, J.-L. Mineau, N. Verdier, M. Mallet, F. Gensdarmes, P. Charpentier, S. Mesmin, V. Duverger, J.-C. Dupont, T. Elias, V. Crenn, J. Sciare, J. Giacomoni, M. Gobbi, E. Hamonou, H. Olafsson, P. Dagsson-Waldhauserova, C. Camy-Peyret, C. Mazel, T. Décamps, M. Piringer, J. Surcin, and D. Daugeron
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amtd-8-1203-2015, https://doi.org/10.5194/amtd-8-1203-2015, 2015
Revised manuscript not accepted
J.-B. Renard, F. Dulac, G. Berthet, T. Lurton, D. Vignelle, F. Jégou, T. Tonnelier, C. Thaury, M. Jeannot, B. Couté, R. Akiki, J.-L. Mineau, N. Verdier, M. Mallet, F. Gensdarmes, P. Charpentier, S. Mesmin, V. Duverger, J.-C. Dupont, T. Elias, V. Crenn, J. Sciare, J. Giacomoni, M. Gobbi, E. Hamonou, H. Olafsson, P. Dagsson-Waldhauserova, C. Camy-Peyret, C. Mazel, T. Décamps, M. Piringer, J. Surcin, and D. Daugeron
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amtd-8-1261-2015, https://doi.org/10.5194/amtd-8-1261-2015, 2015
Revised manuscript not accepted
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We present exemples of measurements obtained by the new light optical aerosol counter LOAC. The measurement were conducted from different kinds of balloons in the troposphre and stratosphere.
E. Terrenoire, B. Bessagnet, L. Rouïl, F. Tognet, G. Pirovano, L. Létinois, M. Beauchamp, A. Colette, P. Thunis, M. Amann, and L. Menut
Geosci. Model Dev., 8, 21–42, https://doi.org/10.5194/gmd-8-21-2015, https://doi.org/10.5194/gmd-8-21-2015, 2015
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The model reproduces the temporal variability of NO2, O3, PM10, PM2.5 better at rural than urban background stations.
The fractional biases show that the model performs slightly better at RB sites than at UB sites for NO2, O3 and PM10.
At UB sites, CHIMERE reproduces PM2.5 better than PM10.
This is primarily the result of an underestimation of coarse particulate matter (PM) associated with uncertainties on SOA chemistry and their precursor emissions, dust and sea salt.
K. E. Yttri, J. Schnelle-Kreis, W. Maenhaut, G. Abbaszade, C. Alves, A. Bjerke, N. Bonnier, R. Bossi, M. Claeys, C. Dye, M. Evtyugina, D. García-Gacio, R. Hillamo, A. Hoffer, M. Hyder, Y. Iinuma, J.-L. Jaffrezo, A. Kasper-Giebl, G. Kiss, P. L. López-Mahia, C. Pio, C. Piot, C. Ramirez-Santa-Cruz, J. Sciare, K. Teinilä, R. Vermeylen, A. Vicente, and R. Zimmermann
Atmos. Meas. Tech., 8, 125–147, https://doi.org/10.5194/amt-8-125-2015, https://doi.org/10.5194/amt-8-125-2015, 2015
J.-E. Petit, O. Favez, J. Sciare, F. Canonaco, P. Croteau, G. Močnik, J. Jayne, D. Worsnop, and E. Leoz-Garziandia
Atmos. Chem. Phys., 14, 13773–13787, https://doi.org/10.5194/acp-14-13773-2014, https://doi.org/10.5194/acp-14-13773-2014, 2014
P. Zotter, V. G. Ciobanu, Y. L. Zhang, I. El-Haddad, M. Macchia, K. R. Daellenbach, G. A. Salazar, R.-J. Huang, L. Wacker, C. Hueglin, A. Piazzalunga, P. Fermo, M. Schwikowski, U. Baltensperger, S. Szidat, and A. S. H. Prévôt
Atmos. Chem. Phys., 14, 13551–13570, https://doi.org/10.5194/acp-14-13551-2014, https://doi.org/10.5194/acp-14-13551-2014, 2014
S.-L. von der Weiden-Reinmüller, F. Drewnick, Q. J. Zhang, F. Freutel, M. Beekmann, and S. Borrmann
Atmos. Chem. Phys., 14, 12931–12950, https://doi.org/10.5194/acp-14-12931-2014, https://doi.org/10.5194/acp-14-12931-2014, 2014
L. Ammoura, I. Xueref-Remy, V. Gros, A. Baudic, B. Bonsang, J.-E. Petit, O. Perrussel, N. Bonnaire, J. Sciare, and F. Chevallier
Atmos. Chem. Phys., 14, 12871–12882, https://doi.org/10.5194/acp-14-12871-2014, https://doi.org/10.5194/acp-14-12871-2014, 2014
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We present the first study of CO2, VOCs and NOx measured all together in a road tunnel around the Paris megacity with the aim to quantify the ratios of these species co-emitted within traffic emissions. It allows us to independently assess some of the ratios provided in the latest Paris emission inventory. It also reveals a large variability of the ratios to CO2, implying that traffic does not have a unique imprint in the urban plume, but rather leaves various signatures.
Y. Wang, K. N. Sartelet, M. Bocquet, P. Chazette, M. Sicard, G. D'Amico, J. F. Léon, L. Alados-Arboledas, A. Amodeo, P. Augustin, J. Bach, L. Belegante, I. Binietoglou, X. Bush, A. Comerón, H. Delbarre, D. García-Vízcaino, J. L. Guerrero-Rascado, M. Hervo, M. Iarlori, P. Kokkalis, D. Lange, F. Molero, N. Montoux, A. Muñoz, C. Muñoz, D. Nicolae, A. Papayannis, G. Pappalardo, J. Preissler, V. Rizi, F. Rocadenbosch, K. Sellegri, F. Wagner, and F. Dulac
Atmos. Chem. Phys., 14, 12031–12053, https://doi.org/10.5194/acp-14-12031-2014, https://doi.org/10.5194/acp-14-12031-2014, 2014
A.-I. Partanen, E. M. Dunne, T. Bergman, A. Laakso, H. Kokkola, J. Ovadnevaite, L. Sogacheva, D. Baisnée, J. Sciare, A. Manders, C. O'Dowd, G. de Leeuw, and H. Korhonen
Atmos. Chem. Phys., 14, 11731–11752, https://doi.org/10.5194/acp-14-11731-2014, https://doi.org/10.5194/acp-14-11731-2014, 2014
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New parameterizations for the sea spray aerosol source flux and its organic fraction were incorporated into a global aerosol-climate model. The emissions of sea salt were considerably less than previous estimates. This study demonstrates that sea spray aerosol may actually decrease the number of cloud droplets, which has a warming effect on climate. Overall, sea spray aerosol was predicted to have a global cooling effect due to the scattering of solar radiation from sea spray aerosol particles.
K. Tsigaridis, N. Daskalakis, M. Kanakidou, P. J. Adams, P. Artaxo, R. Bahadur, Y. Balkanski, S. E. Bauer, N. Bellouin, A. Benedetti, T. Bergman, T. K. Berntsen, J. P. Beukes, H. Bian, K. S. Carslaw, M. Chin, G. Curci, T. Diehl, R. C. Easter, S. J. Ghan, S. L. Gong, A. Hodzic, C. R. Hoyle, T. Iversen, S. Jathar, J. L. Jimenez, J. W. Kaiser, A. Kirkevåg, D. Koch, H. Kokkola, Y. H Lee, G. Lin, X. Liu, G. Luo, X. Ma, G. W. Mann, N. Mihalopoulos, J.-J. Morcrette, J.-F. Müller, G. Myhre, S. Myriokefalitakis, N. L. Ng, D. O'Donnell, J. E. Penner, L. Pozzoli, K. J. Pringle, L. M. Russell, M. Schulz, J. Sciare, Ø. Seland, D. T. Shindell, S. Sillman, R. B. Skeie, D. Spracklen, T. Stavrakou, S. D. Steenrod, T. Takemura, P. Tiitta, S. Tilmes, H. Tost, T. van Noije, P. G. van Zyl, K. von Salzen, F. Yu, Z. Wang, Z. Wang, R. A. Zaveri, H. Zhang, K. Zhang, Q. Zhang, and X. Zhang
Atmos. Chem. Phys., 14, 10845–10895, https://doi.org/10.5194/acp-14-10845-2014, https://doi.org/10.5194/acp-14-10845-2014, 2014
C. Guieu, C. Ridame, E. Pulido-Villena, M. Bressac, K. Desboeufs, and F. Dulac
Biogeosciences, 11, 5621–5635, https://doi.org/10.5194/bg-11-5621-2014, https://doi.org/10.5194/bg-11-5621-2014, 2014
C. Doche, G. Dufour, G. Foret, M. Eremenko, J. Cuesta, M. Beekmann, and P. Kalabokas
Atmos. Chem. Phys., 14, 10589–10600, https://doi.org/10.5194/acp-14-10589-2014, https://doi.org/10.5194/acp-14-10589-2014, 2014
I. B. Konovalov, E. V. Berezin, P. Ciais, G. Broquet, M. Beekmann, J. Hadji-Lazaro, C. Clerbaux, M. O. Andreae, J. W. Kaiser, and E.-D. Schulze
Atmos. Chem. Phys., 14, 10383–10410, https://doi.org/10.5194/acp-14-10383-2014, https://doi.org/10.5194/acp-14-10383-2014, 2014
W. Ait-Helal, A. Borbon, S. Sauvage, J. A. de Gouw, A. Colomb, V. Gros, F. Freutel, M. Crippa, C. Afif, U. Baltensperger, M. Beekmann, J.-F. Doussin, R. Durand-Jolibois, I. Fronval, N. Grand, T. Leonardis, M. Lopez, V. Michoud, K. Miet, S. Perrier, A. S. H. Prévôt, J. Schneider, G. Siour, P. Zapf, and N. Locoge
Atmos. Chem. Phys., 14, 10439–10464, https://doi.org/10.5194/acp-14-10439-2014, https://doi.org/10.5194/acp-14-10439-2014, 2014
L. Poulain, W. Birmili, F. Canonaco, M. Crippa, Z. J. Wu, S. Nordmann, G. Spindler, A. S. H. Prévôt, A. Wiedensohler, and H. Herrmann
Atmos. Chem. Phys., 14, 10145–10162, https://doi.org/10.5194/acp-14-10145-2014, https://doi.org/10.5194/acp-14-10145-2014, 2014
D. Liu, J. D. Allan, D. E. Young, H. Coe, D. Beddows, Z. L. Fleming, M. J. Flynn, M. W. Gallagher, R. M. Harrison, J. Lee, A. S. H. Prevot, J. W. Taylor, J. Yin, P. I. Williams, and P. Zotter
Atmos. Chem. Phys., 14, 10061–10084, https://doi.org/10.5194/acp-14-10061-2014, https://doi.org/10.5194/acp-14-10061-2014, 2014
L. Menut, S. Mailler, G. Siour, B. Bessagnet, S. Turquety, G. Rea, R. Briant, M. Mallet, J. Sciare, and P. Formenti
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-23075-2014, https://doi.org/10.5194/acpd-14-23075-2014, 2014
Revised manuscript not accepted
C. Aghnatios, R. Losno, and F. Dulac
Biogeosciences, 11, 4627–4633, https://doi.org/10.5194/bg-11-4627-2014, https://doi.org/10.5194/bg-11-4627-2014, 2014
M. Bressi, J. Sciare, V. Ghersi, N. Mihalopoulos, J.-E. Petit, J. B. Nicolas, S. Moukhtar, A. Rosso, A. Féron, N. Bonnaire, E. Poulakis, and C. Theodosi
Atmos. Chem. Phys., 14, 8813–8839, https://doi.org/10.5194/acp-14-8813-2014, https://doi.org/10.5194/acp-14-8813-2014, 2014
S. Segura, V. Estellés, G. Titos, H. Lyamani, M. P. Utrillas, P. Zotter, A. S. H. Prévôt, G. Močnik, L. Alados-Arboledas, and J. A. Martínez-Lozano
Atmos. Meas. Tech., 7, 2373–2387, https://doi.org/10.5194/amt-7-2373-2014, https://doi.org/10.5194/amt-7-2373-2014, 2014
H. Petetin, M. Beekmann, J. Sciare, M. Bressi, A. Rosso, O. Sanchez, and V. Ghersi
Geosci. Model Dev., 7, 1483–1505, https://doi.org/10.5194/gmd-7-1483-2014, https://doi.org/10.5194/gmd-7-1483-2014, 2014
K. Markakis, M. Valari, A. Colette, O. Sanchez, O. Perrussel, C. Honore, R. Vautard, Z. Klimont, and S. Rao
Atmos. Chem. Phys., 14, 7323–7340, https://doi.org/10.5194/acp-14-7323-2014, https://doi.org/10.5194/acp-14-7323-2014, 2014
S. Kotlarski, K. Keuler, O. B. Christensen, A. Colette, M. Déqué, A. Gobiet, K. Goergen, D. Jacob, D. Lüthi, E. van Meijgaard, G. Nikulin, C. Schär, C. Teichmann, R. Vautard, K. Warrach-Sagi, and V. Wulfmeyer
Geosci. Model Dev., 7, 1297–1333, https://doi.org/10.5194/gmd-7-1297-2014, https://doi.org/10.5194/gmd-7-1297-2014, 2014
R.-J. Huang, W.-B. Li, Y.-R. Wang, Q. Y. Wang, W. T. Jia, K.-F. Ho, J. J. Cao, G. H. Wang, X. Chen, I. EI Haddad, Z. X. Zhuang, X. R. Wang, A. S. H. Prévôt, C. D. O'Dowd, and T. Hoffmann
Atmos. Meas. Tech., 7, 2027–2035, https://doi.org/10.5194/amt-7-2027-2014, https://doi.org/10.5194/amt-7-2027-2014, 2014
R. Chirico, M. Clairotte, T. W. Adam, B. Giechaskiel, M. F. Heringa, M. Elsasser, G. Martini, U. Manfredi, T. Streibel, M. Sklorz, R. Zimmermann, P. F. DeCarlo, C. Astorga, U. Baltensperger, and A. S. H. Prevot
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-16591-2014, https://doi.org/10.5194/acpd-14-16591-2014, 2014
Revised manuscript has not been submitted
M. Crippa, F. Canonaco, V. A. Lanz, M. Äijälä, J. D. Allan, S. Carbone, G. Capes, D. Ceburnis, M. Dall'Osto, D. A. Day, P. F. DeCarlo, M. Ehn, A. Eriksson, E. Freney, L. Hildebrandt Ruiz, R. Hillamo, J. L. Jimenez, H. Junninen, A. Kiendler-Scharr, A.-M. Kortelainen, M. Kulmala, A. Laaksonen, A. A. Mensah, C. Mohr, E. Nemitz, C. O'Dowd, J. Ovadnevaite, S. N. Pandis, T. Petäjä, L. Poulain, S. Saarikoski, K. Sellegri, E. Swietlicki, P. Tiitta, D. R. Worsnop, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 14, 6159–6176, https://doi.org/10.5194/acp-14-6159-2014, https://doi.org/10.5194/acp-14-6159-2014, 2014
L. Chiappini, S. Verlhac, R. Aujay, W. Maenhaut, J. P. Putaud, J. Sciare, J. L. Jaffrezo, C. Liousse, C. Galy-Lacaux, L. Y. Alleman, P. Panteliadis, E. Leoz, and O. Favez
Atmos. Meas. Tech., 7, 1649–1661, https://doi.org/10.5194/amt-7-1649-2014, https://doi.org/10.5194/amt-7-1649-2014, 2014
M. Paglione, S. Saarikoski, S. Carbone, R. Hillamo, M. C. Facchini, E. Finessi, L. Giulianelli, C. Carbone, S. Fuzzi, F. Moretti, E. Tagliavini, E. Swietlicki, K. Eriksson Stenström, A. S. H. Prévôt, P. Massoli, M. Canaragatna, D. Worsnop, and S. Decesari
Atmos. Chem. Phys., 14, 5089–5110, https://doi.org/10.5194/acp-14-5089-2014, https://doi.org/10.5194/acp-14-5089-2014, 2014
R. Briant, L. Menut, G. Siour, and C. Prigent
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmdd-7-3441-2014, https://doi.org/10.5194/gmdd-7-3441-2014, 2014
Revised manuscript not accepted
D. C. S. Beddows, M. Dall'Osto, R. M. Harrison, M. Kulmala, A. Asmi, A. Wiedensohler, P. Laj, A.M. Fjaeraa, K. Sellegri, W. Birmili, N. Bukowiecki, E. Weingartner, U. Baltensperger, V. Zdimal, N. Zikova, J.-P. Putaud, A. Marinoni, P. Tunved, H.-C. Hansson, M. Fiebig, N. Kivekäs, E. Swietlicki, H. Lihavainen, E. Asmi, V. Ulevicius, P. P. Aalto, N. Mihalopoulos, N. Kalivitis, I. Kalapov, G. Kiss, G. de Leeuw, B. Henzing, C. O'Dowd, S. G. Jennings, H. Flentje, F. Meinhardt, L. Ries, H. A. C. Denier van der Gon, and A. J. H. Visschedijk
Atmos. Chem. Phys., 14, 4327–4348, https://doi.org/10.5194/acp-14-4327-2014, https://doi.org/10.5194/acp-14-4327-2014, 2014
L. Menut, R. Vautard, A. Colette, D. Khvorostyanov, A. Potier, L. Hamaoui-Laguel, N. Viovy, and M. Thibaudon
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-10891-2014, https://doi.org/10.5194/acpd-14-10891-2014, 2014
Revised manuscript not accepted
B. Langmann, K. Sellegri, and E. Freney
Atmos. Chem. Phys., 14, 3831–3842, https://doi.org/10.5194/acp-14-3831-2014, https://doi.org/10.5194/acp-14-3831-2014, 2014
Y. Wang, K. N. Sartelet, M. Bocquet, and P. Chazette
Atmos. Chem. Phys., 14, 3511–3532, https://doi.org/10.5194/acp-14-3511-2014, https://doi.org/10.5194/acp-14-3511-2014, 2014
V. Michoud, A. Colomb, A. Borbon, K. Miet, M. Beekmann, M. Camredon, B. Aumont, S. Perrier, P. Zapf, G. Siour, W. Ait-Helal, C. Afif, A. Kukui, M. Furger, J. C. Dupont, M. Haeffelin, and J. F. Doussin
Atmos. Chem. Phys., 14, 2805–2822, https://doi.org/10.5194/acp-14-2805-2014, https://doi.org/10.5194/acp-14-2805-2014, 2014
L. Deguillaume, T. Charbouillot, M. Joly, M. Vaïtilingom, M. Parazols, A. Marinoni, P. Amato, A.-M. Delort, V. Vinatier, A. Flossmann, N. Chaumerliac, J. M. Pichon, S. Houdier, P. Laj, K. Sellegri, A. Colomb, M. Brigante, and G. Mailhot
Atmos. Chem. Phys., 14, 1485–1506, https://doi.org/10.5194/acp-14-1485-2014, https://doi.org/10.5194/acp-14-1485-2014, 2014
E. J. Freney, K. Sellegri, F. Canonaco, A. Colomb, A. Borbon, V. Michoud, J.-F. Doussin, S. Crumeyrolle, N. Amarouche, J.-M. Pichon, T. Bourianne, L. Gomes, A. S. H. Prevot, M. Beekmann, and A. Schwarzenböeck
Atmos. Chem. Phys., 14, 1397–1412, https://doi.org/10.5194/acp-14-1397-2014, https://doi.org/10.5194/acp-14-1397-2014, 2014
C. Guieu, F. Dulac, C. Ridame, and P. Pondaven
Biogeosciences, 11, 425–442, https://doi.org/10.5194/bg-11-425-2014, https://doi.org/10.5194/bg-11-425-2014, 2014
A. Colette, B. Bessagnet, F. Meleux, E. Terrenoire, and L. Rouïl
Geosci. Model Dev., 7, 203–210, https://doi.org/10.5194/gmd-7-203-2014, https://doi.org/10.5194/gmd-7-203-2014, 2014
S.-L. von der Weiden-Reinmüller, F. Drewnick, M. Crippa, A. S. H. Prévôt, F. Meleux, U. Baltensperger, M. Beekmann, and S. Borrmann
Atmos. Meas. Tech., 7, 279–299, https://doi.org/10.5194/amt-7-279-2014, https://doi.org/10.5194/amt-7-279-2014, 2014
C. Rose, J. Boulon, M. Hervo, H. Holmgren, E. Asmi, M. Ramonet, P. Laj, and K. Sellegri
Atmos. Chem. Phys., 13, 11573–11594, https://doi.org/10.5194/acp-13-11573-2013, https://doi.org/10.5194/acp-13-11573-2013, 2013
R. Fröhlich, M. J. Cubison, J. G. Slowik, N. Bukowiecki, A. S. H. Prévôt, U. Baltensperger, J. Schneider, J. R. Kimmel, M. Gonin, U. Rohner, D. R. Worsnop, and J. T. Jayne
Atmos. Meas. Tech., 6, 3225–3241, https://doi.org/10.5194/amt-6-3225-2013, https://doi.org/10.5194/amt-6-3225-2013, 2013
J.-L. Baray, Y. Courcoux, P. Keckhut, T. Portafaix, P. Tulet, J.-P. Cammas, A. Hauchecorne, S. Godin Beekmann, M. De Mazière, C. Hermans, F. Desmet, K. Sellegri, A. Colomb, M. Ramonet, J. Sciare, C. Vuillemin, C. Hoareau, D. Dionisi, V. Duflot, H. Vérèmes, J. Porteneuve, F. Gabarrot, T. Gaudo, J.-M. Metzger, G. Payen, J. Leclair de Bellevue, C. Barthe, F. Posny, P. Ricaud, A. Abchiche, and R. Delmas
Atmos. Meas. Tech., 6, 2865–2877, https://doi.org/10.5194/amt-6-2865-2013, https://doi.org/10.5194/amt-6-2865-2013, 2013
R. M. Healy, J. Sciare, L. Poulain, M. Crippa, A. Wiedensohler, A. S. H. Prévôt, U. Baltensperger, R. Sarda-Estève, M. L. McGuire, C.-H. Jeong, E. McGillicuddy, I. P. O'Connor, J. R. Sodeau, G. J. Evans, and J. C. Wenger
Atmos. Chem. Phys., 13, 9479–9496, https://doi.org/10.5194/acp-13-9479-2013, https://doi.org/10.5194/acp-13-9479-2013, 2013
S. M. Platt, I. El Haddad, A. A. Zardini, M. Clairotte, C. Astorga, R. Wolf, J. G. Slowik, B. Temime-Roussel, N. Marchand, I. Ježek, L. Drinovec, G. Močnik, O. Möhler, R. Richter, P. Barmet, F. Bianchi, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 13, 9141–9158, https://doi.org/10.5194/acp-13-9141-2013, https://doi.org/10.5194/acp-13-9141-2013, 2013
M. Mallet, O. Dubovik, P. Nabat, F. Dulac, R. Kahn, J. Sciare, D. Paronis, and J. F. Léon
Atmos. Chem. Phys., 13, 9195–9210, https://doi.org/10.5194/acp-13-9195-2013, https://doi.org/10.5194/acp-13-9195-2013, 2013
M. Dall'Osto, X. Querol, A. Alastuey, M. C. Minguillon, M. Alier, F. Amato, M. Brines, M. Cusack, J. O. Grimalt, A. Karanasiou, T. Moreno, M. Pandolfi, J. Pey, C. Reche, A. Ripoll, R. Tauler, B. L. Van Drooge, M. Viana, R. M. Harrison, J. Gietl, D. Beddows, W. Bloss, C. O'Dowd, D. Ceburnis, G. Martucci, N. L. Ng, D. Worsnop, J. Wenger, E. Mc Gillicuddy, J. Sodeau, R. Healy, F. Lucarelli, S. Nava, J. L. Jimenez, F. Gomez Moreno, B. Artinano, A. S. H. Prévôt, L. Pfaffenberger, S. Frey, F. Wilsenack, D. Casabona, P. Jiménez-Guerrero, D. Gross, and N. Cots
Atmos. Chem. Phys., 13, 8991–9019, https://doi.org/10.5194/acp-13-8991-2013, https://doi.org/10.5194/acp-13-8991-2013, 2013
M. Crippa, F. Canonaco, J. G. Slowik, I. El Haddad, P. F. DeCarlo, C. Mohr, M. F. Heringa, R. Chirico, N. Marchand, B. Temime-Roussel, E. Abidi, L. Poulain, A. Wiedensohler, U. Baltensperger, and A. S. H. Prévôt
Atmos. Chem. Phys., 13, 8411–8426, https://doi.org/10.5194/acp-13-8411-2013, https://doi.org/10.5194/acp-13-8411-2013, 2013
I. El Haddad, B. D'Anna, B. Temime-Roussel, M. Nicolas, A. Boreave, O. Favez, D. Voisin, J. Sciare, C. George, J.-L. Jaffrezo, H. Wortham, and N. Marchand
Atmos. Chem. Phys., 13, 7875–7894, https://doi.org/10.5194/acp-13-7875-2013, https://doi.org/10.5194/acp-13-7875-2013, 2013
A. M. Gabey, M. Vaitilingom, E. Freney, J. Boulon, K. Sellegri, M. W. Gallagher, I. P. Crawford, N. H. Robinson, W. R. Stanley, and P. H. Kaye
Atmos. Chem. Phys., 13, 7415–7428, https://doi.org/10.5194/acp-13-7415-2013, https://doi.org/10.5194/acp-13-7415-2013, 2013
A. Colette, B. Bessagnet, R. Vautard, S. Szopa, S. Rao, S. Schucht, Z. Klimont, L. Menut, G. Clain, F. Meleux, G. Curci, and L. Rouïl
Atmos. Chem. Phys., 13, 7451–7471, https://doi.org/10.5194/acp-13-7451-2013, https://doi.org/10.5194/acp-13-7451-2013, 2013
M. Lopez, M. Schmidt, M. Delmotte, A. Colomb, V. Gros, C. Janssen, S. J. Lehman, D. Mondelain, O. Perrussel, M. Ramonet, I. Xueref-Remy, and P. Bousquet
Atmos. Chem. Phys., 13, 7343–7358, https://doi.org/10.5194/acp-13-7343-2013, https://doi.org/10.5194/acp-13-7343-2013, 2013
L. Menut, B. Bessagnet, D. Khvorostyanov, M. Beekmann, N. Blond, A. Colette, I. Coll, G. Curci, G. Foret, A. Hodzic, S. Mailler, F. Meleux, J.-L. Monge, I. Pison, G. Siour, S. Turquety, M. Valari, R. Vautard, and M. G. Vivanco
Geosci. Model Dev., 6, 981–1028, https://doi.org/10.5194/gmd-6-981-2013, https://doi.org/10.5194/gmd-6-981-2013, 2013
Y. Zhang, K. Sartelet, S.-Y. Wu, and C. Seigneur
Atmos. Chem. Phys., 13, 6807–6843, https://doi.org/10.5194/acp-13-6807-2013, https://doi.org/10.5194/acp-13-6807-2013, 2013
Y. Zhang, K. Sartelet, S. Zhu, W. Wang, S.-Y. Wu, X. Zhang, K. Wang, P. Tran, C. Seigneur, and Z.-F. Wang
Atmos. Chem. Phys., 13, 6845–6875, https://doi.org/10.5194/acp-13-6845-2013, https://doi.org/10.5194/acp-13-6845-2013, 2013
X. Querol, A. Alastuey, M. Viana, T. Moreno, C. Reche, M. C. Minguillón, A. Ripoll, M. Pandolfi, F. Amato, A. Karanasiou, N. Pérez, J. Pey, M. Cusack, R. Vázquez, F. Plana, M. Dall'Osto, J. de la Rosa, A. Sánchez de la Campa, R. Fernández-Camacho, S. Rodríguez, C. Pio, L. Alados-Arboledas, G. Titos, B. Artíñano, P. Salvador, S. García Dos Santos, and R. Fernández Patier
Atmos. Chem. Phys., 13, 6185–6206, https://doi.org/10.5194/acp-13-6185-2013, https://doi.org/10.5194/acp-13-6185-2013, 2013
A. Waked, C. Seigneur, F. Couvidat, Y. Kim, K. Sartelet, C. Afif, A. Borbon, P. Formenti, and S. Sauvage
Atmos. Chem. Phys., 13, 5873–5886, https://doi.org/10.5194/acp-13-5873-2013, https://doi.org/10.5194/acp-13-5873-2013, 2013
M. Laborde, M. Crippa, T. Tritscher, Z. Jurányi, P. F. Decarlo, B. Temime-Roussel, N. Marchand, S. Eckhardt, A. Stohl, U. Baltensperger, A. S. H. Prévôt, E. Weingartner, and M. Gysel
Atmos. Chem. Phys., 13, 5831–5856, https://doi.org/10.5194/acp-13-5831-2013, https://doi.org/10.5194/acp-13-5831-2013, 2013
Q. J. Zhang, M. Beekmann, F. Drewnick, F. Freutel, J. Schneider, M. Crippa, A. S. H. Prevot, U. Baltensperger, L. Poulain, A. Wiedensohler, J. Sciare, V. Gros, A. Borbon, A. Colomb, V. Michoud, J.-F. Doussin, H. A. C. Denier van der Gon, M. Haeffelin, J.-C. Dupont, G. Siour, H. Petetin, B. Bessagnet, S. N. Pandis, A. Hodzic, O. Sanchez, C. Honoré, and O. Perrussel
Atmos. Chem. Phys., 13, 5767–5790, https://doi.org/10.5194/acp-13-5767-2013, https://doi.org/10.5194/acp-13-5767-2013, 2013
E. Solazzo, R. Bianconi, G. Pirovano, M. D. Moran, R. Vautard, C. Hogrefe, K. W. Appel, V. Matthias, P. Grossi, B. Bessagnet, J. Brandt, C. Chemel, J. H. Christensen, R. Forkel, X. V. Francis, A. B. Hansen, S. McKeen, U. Nopmongcol, M. Prank, K. N. Sartelet, A. Segers, J. D. Silver, G. Yarwood, J. Werhahn, J. Zhang, S. T. Rao, and S. Galmarini
Geosci. Model Dev., 6, 791–818, https://doi.org/10.5194/gmd-6-791-2013, https://doi.org/10.5194/gmd-6-791-2013, 2013
H. Keskinen, A. Virtanen, J. Joutsensaari, G. Tsagkogeorgas, J. Duplissy, S. Schobesberger, M. Gysel, F. Riccobono, J. G. Slowik, F. Bianchi, T. Yli-Juuti, K. Lehtipalo, L. Rondo, M. Breitenlechner, A. Kupc, J. Almeida, A. Amorim, E. M. Dunne, A. J. Downard, S. Ehrhart, A. Franchin, M.K. Kajos, J. Kirkby, A. Kürten, T. Nieminen, V. Makhmutov, S. Mathot, P. Miettinen, A. Onnela, T. Petäjä, A. Praplan, F. D. Santos, S. Schallhart, M. Sipilä, Y. Stozhkov, A. Tomé, P. Vaattovaara, D. Wimmer, A. Prevot, J. Dommen, N. M. Donahue, R.C. Flagan, E. Weingartner, Y. Viisanen, I. Riipinen, A. Hansel, J. Curtius, M. Kulmala, D. R. Worsnop, U. Baltensperger, H. Wex, F. Stratmann, and A. Laaksonen
Atmos. Chem. Phys., 13, 5587–5600, https://doi.org/10.5194/acp-13-5587-2013, https://doi.org/10.5194/acp-13-5587-2013, 2013
M. Cusack, N. Pérez, J. Pey, A. Alastuey, and X. Querol
Atmos. Chem. Phys., 13, 5173–5187, https://doi.org/10.5194/acp-13-5173-2013, https://doi.org/10.5194/acp-13-5173-2013, 2013
P. Nabat, S. Somot, M. Mallet, I. Chiapello, J. J. Morcrette, F. Solmon, S. Szopa, F. Dulac, W. Collins, S. Ghan, L. W. Horowitz, J. F. Lamarque, Y. H. Lee, V. Naik, T. Nagashima, D. Shindell, and R. Skeie
Atmos. Meas. Tech., 6, 1287–1314, https://doi.org/10.5194/amt-6-1287-2013, https://doi.org/10.5194/amt-6-1287-2013, 2013
A. Guillon, K. Le Ménach, P.-M. Flaud, N. Marchand, H. Budzinski, and E. Villenave
Atmos. Chem. Phys., 13, 2703–2719, https://doi.org/10.5194/acp-13-2703-2013, https://doi.org/10.5194/acp-13-2703-2013, 2013
D. C. Oderbolz, S. Aksoyoglu, J. Keller, I. Barmpadimos, R. Steinbrecher, C. A. Skjøth, C. Plaß-Dülmer, and A. S. H. Prévôt
Atmos. Chem. Phys., 13, 1689–1712, https://doi.org/10.5194/acp-13-1689-2013, https://doi.org/10.5194/acp-13-1689-2013, 2013
J. Pey, X. Querol, A. Alastuey, F. Forastiere, and M. Stafoggia
Atmos. Chem. Phys., 13, 1395–1410, https://doi.org/10.5194/acp-13-1395-2013, https://doi.org/10.5194/acp-13-1395-2013, 2013
M. Crippa, P. F. DeCarlo, J. G. Slowik, C. Mohr, M. F. Heringa, R. Chirico, L. Poulain, F. Freutel, J. Sciare, J. Cozic, C. F. Di Marco, M. Elsasser, J. B. Nicolas, N. Marchand, E. Abidi, A. Wiedensohler, F. Drewnick, J. Schneider, S. Borrmann, E. Nemitz, R. Zimmermann, J.-L. Jaffrezo, A. S. H. Prévôt, and U. Baltensperger
Atmos. Chem. Phys., 13, 961–981, https://doi.org/10.5194/acp-13-961-2013, https://doi.org/10.5194/acp-13-961-2013, 2013
F. Freutel, J. Schneider, F. Drewnick, S.-L. von der Weiden-Reinmüller, M. Crippa, A. S. H. Prévôt, U. Baltensperger, L. Poulain, A. Wiedensohler, J. Sciare, R. Sarda-Estève, J. F. Burkhart, S. Eckhardt, A. Stohl, V. Gros, A. Colomb, V. Michoud, J. F. Doussin, A. Borbon, M. Haeffelin, Y. Morille, M. Beekmann, and S. Borrmann
Atmos. Chem. Phys., 13, 933–959, https://doi.org/10.5194/acp-13-933-2013, https://doi.org/10.5194/acp-13-933-2013, 2013
F. Couvidat, Y. Kim, K. Sartelet, C. Seigneur, N. Marchand, and J. Sciare
Atmos. Chem. Phys., 13, 983–996, https://doi.org/10.5194/acp-13-983-2013, https://doi.org/10.5194/acp-13-983-2013, 2013
C. Chou, Z. A. Kanji, O. Stetzer, T. Tritscher, R. Chirico, M. F. Heringa, E. Weingartner, A. S. H. Prévôt, U. Baltensperger, and U. Lohmann
Atmos. Chem. Phys., 13, 761–772, https://doi.org/10.5194/acp-13-761-2013, https://doi.org/10.5194/acp-13-761-2013, 2013
Y. Wang, K. N. Sartelet, M. Bocquet, and P. Chazette
Atmos. Chem. Phys., 13, 269–283, https://doi.org/10.5194/acp-13-269-2013, https://doi.org/10.5194/acp-13-269-2013, 2013
V. Michoud, A. Kukui, M. Camredon, A. Colomb, A. Borbon, K. Miet, B. Aumont, M. Beekmann, R. Durand-Jolibois, S. Perrier, P. Zapf, G. Siour, W. Ait-Helal, N. Locoge, S. Sauvage, C. Afif, V. Gros, M. Furger, G. Ancellet, and J. F. Doussin
Atmos. Chem. Phys., 12, 11951–11974, https://doi.org/10.5194/acp-12-11951-2012, https://doi.org/10.5194/acp-12-11951-2012, 2012
Related subject area
Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Population exposure to outdoor NO2, black carbon, and ultrafine and fine particles over Paris with multi-scale modelling down to the street scale
Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks (Alaska), the Northern Hemisphere, and the Contiguous United States
Critical load exceedances for North America and Europe using an ensemble of models and an investigation of causes of environmental impact estimate variability: an AQMEII4 study
Impacts of meteorology and emission reductions on haze pollution during the lockdown in the North China Plain
Impact of mineral dust on the global nitrate aerosol direct and indirect radiative effect
The surface tension and cloud condensation nuclei (CCN) activation of sea spray aerosol particles
Exploring the processes controlling secondary inorganic aerosol: evaluating the global GEOS-Chem simulation using a suite of aircraft campaigns
Influence of land cover change on atmospheric organic gases, aerosols, and radiative effects
Quantifying the impacts of marine aerosols over the southeast Atlantic Ocean using a chemical transport model: implications for aerosol–cloud interactions
Quantifying the impact of global nitrate aerosol on tropospheric composition fields and its production from lightning NOx
Driving factors of aerosol acidity: a new hierarchical quantitative analysis framework and its application in Changzhou, China
Understanding the Long-term Trend of Organic Aerosol and the Influences from Anthropogenic Emission and Regional Climate Change in China
Rapid oxidation of phenolic compounds by O3 and HO●: effects of the air–water interface and mineral dust in tropospheric chemical processes
Uncertainties in the effects of organic aerosol coatings on polycyclic aromatic hydrocarbon concentrations and their estimated health effects
Modeling the contribution of leads to sea spray aerosol in the high Arctic
Trends and Drivers of Soluble Iron Deposition from East Asian Dust to the Northwest Pacific: A Springtime Analysis (2001–2017)
Impacts of Sea Ice Leads on Sea Salt Aerosols and Atmospheric Chemistry in the Arctic
Implications of Reduced-Complexity Aerosol Thermodynamics on Organic Aerosol Mass Concentration and Composition over North America
Importance of aerosol composition and aerosol vertical profiles in global spatial variation in the relationship between PM2.5 and aerosol optical depth
Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations
The co-benefits of a low-carbon future for PM2.5 and O3 air pollution in Europe
Assessing the effectiveness of SO2, NOx, and NH3 emission reductions in mitigating winter PM2.5 in Taiwan using CMAQ
Modelling of atmospheric concentrations of fungal spores: a 2-year simulation over France using CHIMERE
Cluster-dynamics-based parameterization for sulfuric acid–dimethylamine nucleation: comparison and selection through box and three-dimensional modeling
A Comprehensive Global Modelling Assessment of Nitrate Heterogeneous Formation on Desert Dust
Modelling of atmospheric variability of gas and aerosols during the ACROSS campaign 2022 in the greater Paris area: evaluation of the meteorology, dynamics and chemistry
Observed and CMIP6-model-simulated organic aerosol response to drought in the contiguous United States during summertime
Long-term trends in aerosol properties derived from AERONET measurements
Cooling radiative forcing effect enhancement of atmospheric amines and mineral particles caused by heterogeneous uptake and oxidation
Source-resolved atmospheric metal emissions, concentrations, and deposition fluxes into the East Asian seas
Analysis of secondary inorganic aerosols over the greater Athens area using the EPISODE–CityChem source dispersion and photochemistry model
Global estimates of ambient reactive nitrogen components during 2000–2100 based on the multi-stage model
The role of naphthalene and its derivatives in the formation of secondary organic aerosol in the Yangtze River Delta region, China
Unveiling the optimal regression model for source apportionment of the oxidative potential of PM10
AERO-MAP: A data compilation and modelling approach to understand spatial variability in fine and coarse mode aerosol composition
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 2: Modeling chemical drivers and 3-D new particle formation occurrence
Technical note: Influence of different averaging metrics and temporal resolutions on the aerosol pH calculated by thermodynamic modeling
Dual roles of the inorganic aqueous phase on secondary organic aerosol growth from benzene and phenol
Global source apportionment of aerosols into major emission regions and sectors over 1850–2017
Modeling atmospheric brown carbon in the GISS ModelE Earth system model
Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere
Significant impact of urban tree biogenic emissions on air quality estimated by a bottom-up inventory and chemistry transport modeling
Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state
Spatial-temporal patterns of anthropogenic and biomass burning contributions on air pollution and mortality burden changes in India from 1995 to 2014
Modeling the drivers of fine PM pollution over Central Europe: impacts and contributions of emissions from different sources
Reaction of SO3 with H2SO4 and its implications for aerosol particle formation in the gas phase and at the air–water interface
Weakened aerosol–radiation interaction exacerbating ozone pollution in eastern China since China's clean air actions
Uncertainties from biomass burning aerosols in air quality models obscure public health impacts in Southeast Asia
Oxidative potential apportionment of atmospheric PM1: a new approach combining high-sensitive online analysers for chemical composition and offline OP measurement technique
Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon
Soo-Jin Park, Lya Lugon, Oscar Jacquot, Youngseob Kim, Alexia Baudic, Barbara D'Anna, Ludovico Di Antonio, Claudia Di Biagio, Fabrice Dugay, Olivier Favez, Véronique Ghersi, Aline Gratien, Julien Kammer, Jean-Eudes Petit, Olivier Sanchez, Myrto Valari, Jérémy Vigneron, and Karine Sartelet
Atmos. Chem. Phys., 25, 3363–3387, https://doi.org/10.5194/acp-25-3363-2025, https://doi.org/10.5194/acp-25-3363-2025, 2025
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To accurately represent the population exposure to outdoor concentrations of pollutants of interest to health (NO2, PM2.5, black carbon, and ultrafine particles), multi-scale modelling down to the street scale is set up and evaluated using measurements from field campaigns. An exposure scaling factor is defined, allowing regional-scale simulations to be corrected to evaluate population exposure. Urban heterogeneities strongly influence NO2, black carbon, and ultrafine particles but less strongly PM2.5.
Sara L. Farrell, Havala O. T. Pye, Robert Gilliam, George Pouliot, Deanna Huff, Golam Sarwar, William Vizuete, Nicole Briggs, Fengkui Duan, Tao Ma, Shuping Zhang, and Kathleen Fahey
Atmos. Chem. Phys., 25, 3287–3312, https://doi.org/10.5194/acp-25-3287-2025, https://doi.org/10.5194/acp-25-3287-2025, 2025
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In this work we implement heterogeneous sulfur chemistry into the Community Multiscale Air Quality (CMAQ) model. This new chemistry accounts for the formation of sulfate via aqueous oxidation of SO2 in aerosol liquid water and the formation of hydroxymethanesulfonate (HMS) – often confused by measurement techniques as sulfate. Model performance in predicting sulfur PM2.5 in Fairbanks, Alaska, and other places that experience dark and cold winters is improved.
Paul A. Makar, Philip Cheung, Christian Hogrefe, Ayodeji Akingunola, Ummugulsum Alyuz, Jesse O. Bash, Michael D. Bell, Roberto Bellasio, Roberto Bianconi, Tim Butler, Hazel Cathcart, Olivia E. Clifton, Alma Hodzic, Ioannis Kioutsioukis, Richard Kranenburg, Aurelia Lupascu, Jason A. Lynch, Kester Momoh, Juan L. Perez-Camanyo, Jonathan Pleim, Young-Hee Ryu, Roberto San Jose, Donna Schwede, Thomas Scheuschner, Mark W. Shephard, Ranjeet S. Sokhi, and Stefano Galmarini
Atmos. Chem. Phys., 25, 3049–3107, https://doi.org/10.5194/acp-25-3049-2025, https://doi.org/10.5194/acp-25-3049-2025, 2025
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The large range of sulfur and nitrogen deposition estimates from air quality models results in a large range of predicted impacts. We used models and deposition diagnostics to identify the processes controlling atmospheric sulfur and nitrogen deposition variability. Controlling factors included the uptake of gases and aerosols by hydrometeors, aerosol inorganic chemistry, particle dry deposition, ammonia bidirectional fluxes, gas deposition via plant cuticles and soil, and land use data.
Lang Liu, Xin Long, Yi Li, Zengliang Zang, Fengwen Wang, Yan Han, Zhier Bao, Yang Chen, Tian Feng, and Jinxin Yang
Atmos. Chem. Phys., 25, 1569–1585, https://doi.org/10.5194/acp-25-1569-2025, https://doi.org/10.5194/acp-25-1569-2025, 2025
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This study uses WRF-Chem to assess how meteorological conditions and emission reductions affected fine particulate matter (PM2.5) in the North China Plain (NCP). It highlights regional disparities: in the northern NCP, adverse weather negated emission reduction effects. In contrast, the southern NCP featured a PM2.5 decrease due to favorable weather and emission reductions. The research highlighted the interaction between emissions, meteorology, and PM2.5.
Alexandros Milousis, Klaus Klingmüller, Alexandra P. Tsimpidi, Jasper F. Kok, Maria Kanakidou, Athanasios Nenes, and Vlassis A. Karydis
Atmos. Chem. Phys., 25, 1333–1351, https://doi.org/10.5194/acp-25-1333-2025, https://doi.org/10.5194/acp-25-1333-2025, 2025
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This study investigates the impact of dust on the global radiative effect of nitrate aerosols. The results indicate both positive and negative regional shortwave and longwave radiative effects due to aerosol–radiation interactions and cloud adjustments. The global average net REari and REaci of nitrate aerosols are −0.11 and +0.17 W m−2, respectively, mainly affecting the shortwave spectrum. Sensitivity simulations evaluated the influence of mineral dust composition and emissions on the results.
Judith Kleinheins, Nadia Shardt, Ulrike Lohmann, and Claudia Marcolli
Atmos. Chem. Phys., 25, 881–903, https://doi.org/10.5194/acp-25-881-2025, https://doi.org/10.5194/acp-25-881-2025, 2025
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We model the cloud condensation nuclei (CCN) activation of sea spray aerosol particles with classical Köhler theory and with a new model approach that takes surface tension lowering into account. We categorize organic compounds into weak, intermediate, and strong surfactants, and we outline for which composition surface tension lowering is important. The results suggest that surface tension lowering allows sea spray aerosol particles in the Aitken mode to be a source of CCN in marine updraughts.
Olivia G. Norman, Colette L. Heald, Solomon Bililign, Pedro Campuzano-Jost, Hugh Coe, Marc N. Fiddler, Jaime R. Green, Jose L. Jimenez, Katharina Kaiser, Jin Liao, Ann M. Middlebrook, Benjamin A. Nault, John B. Nowak, Johannes Schneider, and André Welti
Atmos. Chem. Phys., 25, 771–795, https://doi.org/10.5194/acp-25-771-2025, https://doi.org/10.5194/acp-25-771-2025, 2025
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This study finds that one component of secondary inorganic aerosols, nitrate, is greatly overestimated by a global atmospheric chemistry model compared to observations from 11 flight campaigns. None of the loss and production pathways explored can explain the nitrate bias alone. The model’s inability to capture the variability in the observations remains and requires future investigation to avoid biases in policy-related studies (i.e., air quality, health, climate impacts of these aerosols).
Ryan Vella, Matthew Forrest, Andrea Pozzer, Alexandra P. Tsimpidi, Thomas Hickler, Jos Lelieveld, and Holger Tost
Atmos. Chem. Phys., 25, 243–262, https://doi.org/10.5194/acp-25-243-2025, https://doi.org/10.5194/acp-25-243-2025, 2025
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This study examines how land cover changes influence biogenic volatile organic compound (BVOC) emissions and atmospheric states. Using a coupled chemistry–climate–vegetation model, we compare present-day land cover (deforested for crops and grazing) with natural vegetation and an extreme reforestation scenario. We find that vegetation changes significantly impact global BVOC emissions and organic aerosols but have a relatively small effect on total aerosols, clouds, and radiative effects.
Mashiat Hossain, Rebecca M. Garland, and Hannah M. Horowitz
Atmos. Chem. Phys., 24, 14123–14143, https://doi.org/10.5194/acp-24-14123-2024, https://doi.org/10.5194/acp-24-14123-2024, 2024
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Our research examines aerosol dynamics over the southeast Atlantic, a region with significant uncertainties in aerosol radiative forcings. Using the GEOS-Chem model, we find that at cloud altitudes, organic aerosols dominate during the biomass burning season, while sulfate aerosols, driven by marine emissions, prevail during peak primary production. These findings highlight the need for accurate representation of marine aerosols in models to improve climate predictions and reduce uncertainties.
Ashok K. Luhar, Anthony C. Jones, and Jonathan M. Wilkinson
Atmos. Chem. Phys., 24, 14005–14028, https://doi.org/10.5194/acp-24-14005-2024, https://doi.org/10.5194/acp-24-14005-2024, 2024
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Nitrate aerosol is often omitted in global chemistry–climate models, partly due to the chemical complexity of its formation process. Using a global model, we show that including nitrate aerosol significantly impacts tropospheric composition fields, such as ozone, and radiation. Additionally, lightning-generated oxides of nitrogen influence both nitrate aerosol mass concentrations and aerosol size distribution, which has important implications for radiative fluxes and indirect aerosol effects.
Xiaolin Duan, Guangjie Zheng, Chuchu Chen, Qiang Zhang, and Kebin He
EGUsphere, https://doi.org/10.5194/egusphere-2024-3584, https://doi.org/10.5194/egusphere-2024-3584, 2024
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Aerosol acidity is an important parameter in atmospheric chemistry, while its driving factors, especially chemical profiles versus meteorological conditions, are not yet fully understood. Here, we established a hierarchical quantitative analysis framework to understand the driving factors of aerosol acidity on different time scales. Its application in Changzhou, China revealed distinct driving factors and corresponding mechanisms of aerosol acidity from annual trends to random residues.
Wenxin Zhang, Yaman Liu, Man Yue, Xinyi Dong, and Minghuai Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3420, https://doi.org/10.5194/egusphere-2024-3420, 2024
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Understanding long-term organic aerosols (OA) trends and their driving factors is important for air quality management. Our modeling revealed that OA in China increased by 5.6% from 1990 to 2019, primarily due to a 32.3% increase in secondary organic aerosols (SOA) and an 8.1% decrease in primary organic aerosols (POA), both largely driven by changes in anthropogenic emissions. Biogenic SOA increased due to warming but showed little response to changes in anthropogenic nitrogen oxide emissions.
Yanru Huo, Mingxue Li, Xueyu Wang, Jianfei Sun, Yuxin Zhou, Yuhui Ma, and Maoxia He
Atmos. Chem. Phys., 24, 12409–12423, https://doi.org/10.5194/acp-24-12409-2024, https://doi.org/10.5194/acp-24-12409-2024, 2024
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This work found that the air–water (A–W) interface and TiO2 clusters promote the oxidation of phenolic compounds (PhCs) to varying degrees compared with the gas phase and bulk water. Some byproducts are more harmful than their parent compounds. This work provides important evidence for the rapid oxidation observed in O3/HO• + PhC experiments at the A–W interface and in mineral dust.
Sijia Lou, Manish Shrivastava, Alexandre Albinet, Sophie Tomaz, Deepchandra Srivastava, Olivier Favez, Huizhong Shen, and Aijun Ding
EGUsphere, https://doi.org/10.5194/egusphere-2024-3269, https://doi.org/10.5194/egusphere-2024-3269, 2024
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PAHs, emitted from incomplete combustion, pose serious health risks due to their carcinogenic properties. This research demonstrates that viscous organic aerosol coatings significantly hinder PAH oxidation, with spatial distributions sensitive to the degradation modelling approach. Our findings underscore the importance of accurately modelling these processes for risk assessments, highlighting the need to consider both fresh and oxidized PAHs in evaluating human exposure and health risks.
Rémy Lapere, Louis Marelle, Pierre Rampal, Laurent Brodeau, Christian Melsheimer, Gunnar Spreen, and Jennie L. Thomas
Atmos. Chem. Phys., 24, 12107–12132, https://doi.org/10.5194/acp-24-12107-2024, https://doi.org/10.5194/acp-24-12107-2024, 2024
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Elongated open-water areas in sea ice, called leads, can release marine aerosols into the atmosphere. In the Arctic, this source of atmospheric particles could play an important role for climate. However, the amount, seasonality and spatial distribution of such emissions are all mostly unknown. Here, we propose a first parameterization for sea spray aerosols emitted through leads in sea ice and quantify their impact on aerosol populations in the high Arctic.
Hanzheng Zhu, Yaman Liu, Man Yue, Shihui Feng, Pingqing Fu, Kan Huang, Xinyi Dong, and Minghuai Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2293, https://doi.org/10.5194/egusphere-2024-2293, 2024
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Dust soluble iron deposition from East Asia plays an important role in the marine ecology of the Northwest Pacific. Using the developed model, our findings highlight a dual trend: a decrease in the overall deposition of soluble iron from dust, but an increase in the solubility of the iron itself due to the enhanced atmospheric processing. It underscores the critical roles of both dust emission and atmospheric processing in soluble iron deposition and marine ecology.
Erin Emme and Hannah Horowitz
EGUsphere, https://doi.org/10.5194/egusphere-2024-3147, https://doi.org/10.5194/egusphere-2024-3147, 2024
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There is uncertainty in the sources of Arctic cold season (November-April) sea salt aerosols. Using a chemical transport model and satellite observations, we quantify Arctic-wide sea salt aerosol emissions from fractures in sea ice, called open sea ice leads, and their atmospheric chemistry impacts for the cold season. We show sea ice leads contribute to Arctic sea salt aerosols and bromine, especially in under-observed regions.
Camilo Serrano Damha, Kyle Gorkowski, and Andreas Zuend
EGUsphere, https://doi.org/10.5194/egusphere-2024-2712, https://doi.org/10.5194/egusphere-2024-2712, 2024
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Organic aerosol water content impacts the gas–particle partitioning of semivolatile organics. We used an aerosol thermodynamic model in the GEOS-Chem chemical transport model to efficiently account for organic aerosol water uptake and nonideal mixing. This led to a substantial enhancement in mean organic aerosol mass concentration with respect to GEOS-Chem's most advanced scheme. The water-sensitive scheme could be a valuable tool for reconciling model estimations and field measurements.
Haihui Zhu, Randall V. Martin, Aaron van Donkelaar, Melanie S. Hammer, Chi Li, Jun Meng, Christopher R. Oxford, Xuan Liu, Yanshun Li, Dandan Zhang, Inderjeet Singh, and Alexei Lyapustin
Atmos. Chem. Phys., 24, 11565–11584, https://doi.org/10.5194/acp-24-11565-2024, https://doi.org/10.5194/acp-24-11565-2024, 2024
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Ambient fine particulate matter (PM2.5) contributes to 4 million deaths globally each year. Satellite remote sensing of aerosol optical depth (AOD), coupled with a simulated PM2.5–AOD relationship (η), can provide global PM2.5 estimations. This study aims to understand the spatial patterns and driving factors of η to guide future measurement and modeling efforts. We quantified η globally and regionally and found that its spatial variation is strongly influenced by aerosol composition.
Ursula A. Jongebloed, Jacob I. Chalif, Linia Tashmim, William C. Porter, Kelvin H. Bates, Qianjie Chen, Erich C. Osterberg, Bess G. Koffman, Jihong Cole-Dai, Dominic A. Winksi, David G. Ferris, Karl J. Kreutz, Cameron P. Wake, and Becky Alexander
EGUsphere, https://doi.org/10.5194/egusphere-2024-3026, https://doi.org/10.5194/egusphere-2024-3026, 2024
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Marine phytoplankton emit dimethyl sulfide (DMS), which forms methanesulfonic acid (MSA) and sulfate. MSA concentrations in ice cores decreased over the industrial era, which has been attributed to pollution-driven changes in DMS chemistry. We use a models to investigate DMS chemistry compared to observations of DMS, MSA, and sulfate. We find that modeled DMS, MSA, and sulfate are influenced by pollution-sensitive oxidant concentrations, characterization of DMS chemistry, and other variables.
Connor J. Clayton, Daniel R. Marsh, Steven T. Turnock, Ailish M. Graham, Kirsty J. Pringle, Carly L. Reddington, Rajesh Kumar, and James B. McQuaid
Atmos. Chem. Phys., 24, 10717–10740, https://doi.org/10.5194/acp-24-10717-2024, https://doi.org/10.5194/acp-24-10717-2024, 2024
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We demonstrate that strong climate mitigation could improve air quality in Europe; however, less ambitious mitigation does not result in these co-benefits. We use a high-resolution atmospheric chemistry model. This allows us to demonstrate how this varies across European countries and analyse the underlying chemistry. This may help policy-facing researchers understand which sectors and regions need to be prioritised to achieve strong air quality co-benefits of climate mitigation.
Ping-Chieh Huang, Hui-Ming Hung, Hsin-Chih Lai, and Charles C.-K. Chou
Atmos. Chem. Phys., 24, 10759–10772, https://doi.org/10.5194/acp-24-10759-2024, https://doi.org/10.5194/acp-24-10759-2024, 2024
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Models were used to study ways to reduce particulate matter (PM) pollution in Taiwan during winter. After considering various factors, such as physical processes and chemical reactions, we found that reducing NOx or NH3 emissions is more effective at mitigating PM2.5 than reducing SO2 emissions. When considering both efficiency and cost, reducing NH3 emissions seems to be a more suitable policy for the studied environment in Taiwan.
Matthieu Vida, Gilles Foret, Guillaume Siour, Florian Couvidat, Olivier Favez, Gaelle Uzu, Arineh Cholakian, Sébastien Conil, Matthias Beekmann, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 24, 10601–10615, https://doi.org/10.5194/acp-24-10601-2024, https://doi.org/10.5194/acp-24-10601-2024, 2024
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We simulate 2 years of atmospheric fungal spores over France and use observations of polyols and primary biogenic factors from positive matrix factorisation. The representation of emissions taking into account a proxy for vegetation surface and specific humidity enables us to reproduce very accurately the seasonal cycle of fungal spores. Furthermore, we estimate that fungal spores can account for 20 % of PM10 and 40 % of the organic fraction of PM10 over vegetated areas in summer.
Jiewen Shen, Bin Zhao, Shuxiao Wang, An Ning, Yuyang Li, Runlong Cai, Da Gao, Biwu Chu, Yang Gao, Manish Shrivastava, Jingkun Jiang, Xiuhui Zhang, and Hong He
Atmos. Chem. Phys., 24, 10261–10278, https://doi.org/10.5194/acp-24-10261-2024, https://doi.org/10.5194/acp-24-10261-2024, 2024
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We extensively compare various cluster-dynamics-based parameterizations for sulfuric acid–dimethylamine nucleation and identify a newly developed parameterization derived from Atmospheric Cluster Dynamic Code (ACDC) simulations as being the most reliable one. This study offers a valuable reference for developing parameterizations of other nucleation systems and is meaningful for the accurate quantification of the environmental and climate impacts of new particle formation.
Rubén Soussé-Villa, Oriol Jorba, María Gonçalves Ageitos, Dene Bowdalo, Marc Guevara, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2024-2310, https://doi.org/10.5194/egusphere-2024-2310, 2024
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Desert dust forms nitrate coatings as it travels through the atmosphere. However, current models that predict this process vary greatly due to different methods and inaccuracies. We examined how nitrate forms in a global model, focusing on how gases condense on dust, the lifespan of different particles, and the impact of alkalinity. Our findings show that models work best when they consider reversible gas condensation with alkalinity. This should lead to better estimates of climate impacts.
Ludovico Di Antonio, Matthias Beekmann, Guillaume Siour, Vincent Michoud, Christopher Cantrell, Astrid Bauville, Antonin Bergé, Mathieu Cazaunau, Servanne Chevaillier, Manuela Cirtog, Joel F. de Brito, Paola Formenti, Cecile Gaimoz, Olivier Garret, Aline Gratien, Valérie Gros, Martial Haeffelin, Lelia N. Hawkins, Simone Kotthaus, Gael Noyalet, Diana Pereira, Jean-Eudes Petit, Eva Drew Pronovost, Véronique Riffault, Chenjie Yu, Gilles Foret, Jean-François Doussin, and Claudia Di Biagio
EGUsphere, https://doi.org/10.5194/egusphere-2024-2175, https://doi.org/10.5194/egusphere-2024-2175, 2024
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Summer 2022 has been considered a proxy for future climate scenarios, given the registered hot and dry conditions. In this paper, we used the measurements from the ACROSS campaign, occurred over the Paris area in June–July 2022, in addition to observations from existing networks, to evaluate the WRF–CHIMERE model simulation over France and the Ile-de-France regions. Results over the Ile–de–France show to be satisfactory, allowing to explain the gas and aerosol variability at the ACROSS sites.
Wei Li and Yuxuan Wang
Atmos. Chem. Phys., 24, 9339–9353, https://doi.org/10.5194/acp-24-9339-2024, https://doi.org/10.5194/acp-24-9339-2024, 2024
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Droughts immensely increased organic aerosol (OA) in the contiguous United States in summer (1998–2019), notably in the Pacific Northwest (PNW) and Southeast (SEUS). The OA rise in the SEUS is driven by the enhanced formation of epoxydiol-derived secondary organic aerosol due to the increase in biogenic volatile organic compounds and sulfate, while in the PNW, it is caused by wildfires. A total of 10 climate models captured the OA increase in the PNW yet greatly underestimated it in the SEUS.
Zhenyu Zhang, Jing Li, Huizheng Che, Yueming Dong, Oleg Dubovik, Thomas Eck, Pawan Gupta, Brent Holben, Jhoon Kim, Elena Lind, Trailokya Saud, Sachchida Nand Tripathi, and Tong Ying
EGUsphere, https://doi.org/10.5194/egusphere-2024-2533, https://doi.org/10.5194/egusphere-2024-2533, 2024
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We used ground-based remote sensing data from the Aerosol Robotic Network to examine long-term trends in aerosol characteristics. We found aerosol loadings generally decreased globally, and aerosols became more scattering. These changes are closely related to variations in aerosol compositions, such as decreased anthropogenic emissions over East Asia, Europe, and North America, increased anthropogenic source over North India, increased dust activities over the Arabian Peninsula, etc.
Weina Zhang, Jianhua Mai, Zhichao Fan, Yongpeng Ji, Yuemeng Ji, Guiying Li, Yanpeng Gao, and Taicheng An
Atmos. Chem. Phys., 24, 9019–9030, https://doi.org/10.5194/acp-24-9019-2024, https://doi.org/10.5194/acp-24-9019-2024, 2024
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This study reveals heterogeneous oxidation causes further radiative forcing effect (RFE) enhancement of amine–mineral mixed particles. Note that RFE increment is higher under clean conditions than that under polluted conditions, which is contributed to high-oxygen-content products. The enhanced RFE of amine–mineral particles caused by heterogenous oxidation is expected to alleviate warming effects.
Shenglan Jiang, Yan Zhang, Guangyuan Yu, Zimin Han, Junri Zhao, Tianle Zhang, and Mei Zheng
Atmos. Chem. Phys., 24, 8363–8381, https://doi.org/10.5194/acp-24-8363-2024, https://doi.org/10.5194/acp-24-8363-2024, 2024
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This study aims to provide gridded data on sea-wide concentrations, deposition fluxes, and soluble deposition fluxes with detailed source categories of metals using the modified CMAQ model. We developed a monthly emission inventory of six metals – Fe, Al, V, Ni, Zn, and Cu – from terrestrial anthropogenic, ship, and dust sources in East Asia in 2017. Our results reveal the contribution of each source to the emissions, concentrations, and deposition fluxes of metals in the East Asian seas.
Stelios Myriokefalitakis, Matthias Karl, Kim A. Weiss, Dimitris Karagiannis, Eleni Athanasopoulou, Anastasia Kakouri, Aikaterini Bougiatioti, Eleni Liakakou, Iasonas Stavroulas, Georgios Papangelis, Georgios Grivas, Despina Paraskevopoulou, Orestis Speyer, Nikolaos Mihalopoulos, and Evangelos Gerasopoulos
Atmos. Chem. Phys., 24, 7815–7835, https://doi.org/10.5194/acp-24-7815-2024, https://doi.org/10.5194/acp-24-7815-2024, 2024
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A state-of-the-art thermodynamic model has been coupled with the city-scale chemistry transport model EPISODE–CityChem to investigate the equilibrium between the inorganic gas and aerosol phases over the greater Athens area, Greece. The simulations indicate that the formation of nitrates in an urban environment is significantly affected by local nitrogen oxide emissions, as well as ambient temperature, relative humidity, photochemical activity, and the presence of non-volatile cations.
Rui Li, Yining Gao, Lijia Zhang, Yubing Shen, Tianzhao Xu, Wenwen Sun, and Gehui Wang
Atmos. Chem. Phys., 24, 7623–7636, https://doi.org/10.5194/acp-24-7623-2024, https://doi.org/10.5194/acp-24-7623-2024, 2024
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A three-stage model was developed to obtain the global maps of reactive nitrogen components during 2000–2100. The results implied that cross-validation R2 values of four species showed satisfactory performance (R2 > 0.55). Most reactive nitrogen components, except NH3, in China showed increases during 2000–2013. In the future scenarios, SSP3-7.0 (traditional-energy scenario) and SSP1-2.6 (carbon neutrality scenario) showed the highest and lowest reactive nitrogen component concentrations.
Fei Ye, Jingyi Li, Yaqin Gao, Hongli Wang, Jingyu An, Cheng Huang, Song Guo, Keding Lu, Kangjia Gong, Haowen Zhang, Momei Qin, and Jianlin Hu
Atmos. Chem. Phys., 24, 7467–7479, https://doi.org/10.5194/acp-24-7467-2024, https://doi.org/10.5194/acp-24-7467-2024, 2024
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Naphthalene (Nap) and methylnaphthalene (MN) are key precursors of secondary organic aerosol (SOA), yet their sources and sinks are often inadequately represented in air quality models. In this study, we incorporated detailed emissions, gas-phase chemistry, and SOA parameterization of Nap and MN into CMAQ to address this issue. The findings revealed remarkably high SOA formation potentials for these compounds despite their low emissions in the Yangtze River Delta region during summer.
Vy Dinh Ngoc Thuy, Jean-Luc Jaffrezo, Ian Hough, Pamela A. Dominutti, Guillaume Salque Moreton, Grégory Gille, Florie Francony, Arabelle Patron-Anquez, Olivier Favez, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 7261–7282, https://doi.org/10.5194/acp-24-7261-2024, https://doi.org/10.5194/acp-24-7261-2024, 2024
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The capacity of particulate matter (PM) to generate reactive oxygen species in vivo is represented by oxidative potential (OP). This study focuses on finding the appropriate model to evaluate the oxidative character of PM sources in six sites using the PM sources and OP. Eight regression techniques are introduced to assess the OP of PM. The study highlights the importance of selecting a model according to the input data characteristics and establishes some recommendations for the procedure.
Natalie M. Mahowald, Longlei Li, Julius Vira, Marje Prank, Douglas S. Hamilton, Hitoshi Matsui, Ron L. Miller, Louis Lu, Ezgi Akyuz, Daphne Meidan, Peter G. Hess, Heikki Lihavainen, Christine Wiedinmyer, Jenny Hand, Maria Grazia Alaimo, Célia Alves, Andres Alastuey, Paulo Artaxo, Africa Barreto, Francisco Barraza, Silvia Becagli, Giulia Calzolai, Shankararaman Chellam, Ying Chen, Patrick Chuang, David D. Cohen, Cristina Colombi, Evangelia Diapouli, Gaetano Dongarra, Konstantinos Eleftheriadis, Johann Engelbrecht, Corinne Galy-Lacaux, Cassandra Gaston, Dario Gomez, Yenny González Ramos, Roy M. Harrison, Chris Heyes, Barak Herut, Philip Hopke, Christoph Hüglin, Maria Kanakidou, Zsofia Kertesz, Zbigniew Klimont, Katriina Kyllönen, Fabrice Lambert, Xiaohong Liu, Remi Losno, Franco Lucarelli, Willy Maenhaut, Beatrice Marticorena, Randall V. Martin, Nikolaos Mihalopoulos, Yasser Morera-Gomez, Adina Paytan, Joseph Prospero, Sergio Rodríguez, Patricia Smichowski, Daniela Varrica, Brenna Walsh, Crystal Weagle, and Xi Zhao
EGUsphere, https://doi.org/10.5194/egusphere-2024-1617, https://doi.org/10.5194/egusphere-2024-1617, 2024
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Aerosol particles are an important part of the Earth system, but their concentrations are spatially and temporally heterogeneous, as well as variable in size and composition. Here we present a new compilation of PM2.5 and PM10 aerosol observations, focusing on the spatial variability across different observational stations, including composition, and demonstrate a method for comparing the datasets to model output.
Ming Chu, Xing Wei, Shangfei Hai, Yang Gao, Huiwang Gao, Yujiao Zhu, Biwu Chu, Nan Ma, Juan Hong, Yele Sun, and Xiaohong Yao
Atmos. Chem. Phys., 24, 6769–6786, https://doi.org/10.5194/acp-24-6769-2024, https://doi.org/10.5194/acp-24-6769-2024, 2024
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We used a 20-bin WRF-Chem model to simulate NPF events in the NCP during a three-week observational period in the summer of 2019. The model was able to reproduce the observations during June 29–July 6, which was characterized by a high frequency of NPF occurrence.
Haoqi Wang, Xiao Tian, Wanting Zhao, Jiacheng Li, Haoyu Yu, Yinchang Feng, and Shaojie Song
Atmos. Chem. Phys., 24, 6583–6592, https://doi.org/10.5194/acp-24-6583-2024, https://doi.org/10.5194/acp-24-6583-2024, 2024
Short summary
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pH is a key property of ambient aerosols, which affect many atmospheric processes. As aerosol pH is a non-conservative parameter, diverse averaging metrics and temporal resolutions may influence the pH values calculated by thermodynamic models. This technical note seeks to quantitatively evaluate the average pH using varied metrics and resolutions. The ultimate goal is to establish standardized reporting practices in future research endeavors.
Jiwon Choi, Myoseon Jang, and Spencer Blau
Atmos. Chem. Phys., 24, 6567–6582, https://doi.org/10.5194/acp-24-6567-2024, https://doi.org/10.5194/acp-24-6567-2024, 2024
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Persistent phenoxy radical (PPR), formed by phenol gas oxidation and its aqueous reaction, catalytically destroys O3 and retards secondary organic aerosol (SOA) growth. Explicit gas mechanisms including the formation of PPR and low-volatility products from the oxidation of phenol or benzene are applied to the UNIPAR model to predict SOA mass via multiphase reactions of precursors. Aqueous reactions of reactive organics increase SOA mass but retard SOA growth via heterogeneously formed PPR.
Yang Yang, Shaoxuan Mou, Hailong Wang, Pinya Wang, Baojie Li, and Hong Liao
Atmos. Chem. Phys., 24, 6509–6523, https://doi.org/10.5194/acp-24-6509-2024, https://doi.org/10.5194/acp-24-6509-2024, 2024
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The variations in anthropogenic aerosol concentrations and source contributions and their subsequent radiative impact in major emission regions during historical periods are quantified based on an aerosol-tagging system in E3SMv1. Due to the industrial development and implementation of economic policies, sources of anthropogenic aerosols show different variations, which has important implications for pollution prevention and control measures and decision-making for global collaboration.
Maegan A. DeLessio, Kostas Tsigaridis, Susanne E. Bauer, Jacek Chowdhary, and Gregory L. Schuster
Atmos. Chem. Phys., 24, 6275–6304, https://doi.org/10.5194/acp-24-6275-2024, https://doi.org/10.5194/acp-24-6275-2024, 2024
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This study presents the first explicit representation of brown carbon aerosols in the GISS ModelE Earth system model (ESM). Model sensitivity to a range of brown carbon parameters and model performance compared to AERONET and MODIS retrievals of total aerosol properties were assessed. A summary of best practices for incorporating brown carbon into ModelE is also included.
Chuanyang Shen, Xiaoyan Yang, Joel Thornton, John Shilling, Chenyang Bi, Gabriel Isaacman-VanWertz, and Haofei Zhang
Atmos. Chem. Phys., 24, 6153–6175, https://doi.org/10.5194/acp-24-6153-2024, https://doi.org/10.5194/acp-24-6153-2024, 2024
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In this work, a condensed multiphase isoprene oxidation mechanism was developed to simulate isoprene SOA formation from chamber and field studies. Our results show that the measured isoprene SOA mass concentrations can be reasonably reproduced. The simulation results indicate that multifunctional low-volatility products contribute significantly to total isoprene SOA. Our findings emphasize that the pathways to produce these low-volatility species should be considered in models.
Alice Maison, Lya Lugon, Soo-Jin Park, Alexia Baudic, Christopher Cantrell, Florian Couvidat, Barbara D'Anna, Claudia Di Biagio, Aline Gratien, Valérie Gros, Carmen Kalalian, Julien Kammer, Vincent Michoud, Jean-Eudes Petit, Marwa Shahin, Leila Simon, Myrto Valari, Jérémy Vigneron, Andrée Tuzet, and Karine Sartelet
Atmos. Chem. Phys., 24, 6011–6046, https://doi.org/10.5194/acp-24-6011-2024, https://doi.org/10.5194/acp-24-6011-2024, 2024
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This study presents the development of a bottom-up inventory of urban tree biogenic emissions. Emissions are computed for each tree based on their location and characteristics and are integrated in the regional air quality model WRF-CHIMERE. The impact of these biogenic emissions on air quality is quantified for June–July 2022. Over Paris city, urban trees increase the concentrations of particulate organic matter by 4.6 %, of PM2.5 by 0.6 %, and of ozone by 1.0 % on average over 2 months.
Tommaso Galeazzo, Bernard Aumont, Marie Camredon, Richard Valorso, Yong B. Lim, Paul J. Ziemann, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 5549–5565, https://doi.org/10.5194/acp-24-5549-2024, https://doi.org/10.5194/acp-24-5549-2024, 2024
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Secondary organic aerosol (SOA) derived from n-alkanes is a major component of anthropogenic particulate matter. We provide an analysis of n-alkane SOA by chemistry modeling, machine learning, and laboratory experiments, showing that n-alkane SOA adopts low-viscous semi-solid or liquid states. Our results indicate few kinetic limitations of mass accommodation in SOA formation, supporting the application of equilibrium partitioning for simulating n-alkane SOA in large-scale atmospheric models.
Bin Luo, Yuqiang Zhang, Tao Tang, Hongliang Zhang, Jianlin Hu, Jiangshan Mu, Wenxing Wang, and Likun Xue
EGUsphere, https://doi.org/10.5194/egusphere-2024-974, https://doi.org/10.5194/egusphere-2024-974, 2024
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India is facing a severe air pollution crisis that poses significant health risks, particularly from PM2.5 and O3. Our study reveals rising levels of both pollutants from 1995 to 2014, leading to increased premature mortality. While anthropogenic emissions play a significant role, biomass burning also impacts air quality, in particular seasons and regions in India. This study highlights the urgent need for localized policies to protect public health amid escalating environmental challenges.
Lukáš Bartík, Peter Huszár, Jan Karlický, Ondřej Vlček, and Kryštof Eben
Atmos. Chem. Phys., 24, 4347–4387, https://doi.org/10.5194/acp-24-4347-2024, https://doi.org/10.5194/acp-24-4347-2024, 2024
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The presented study deals with the attribution of fine particulate matter (PM2.5) concentrations to anthropogenic emissions over Central Europe using regional-scale models. It calculates the present-day contributions of different emissions sectors to concentrations of PM2.5 and its secondary components. Moreover, the study investigates the effect of chemical nonlinearities by using multiple source attribution methods and secondary organic aerosol calculation methods.
Rui Wang, Yang Cheng, Shasha Chen, Rongrong Li, Yue Hu, Xiaokai Guo, Tianlei Zhang, Fengmin Song, and Hao Li
Atmos. Chem. Phys., 24, 4029–4046, https://doi.org/10.5194/acp-24-4029-2024, https://doi.org/10.5194/acp-24-4029-2024, 2024
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We used quantum chemical calculations, Born–Oppenheimer molecular dynamics simulations, and the ACDC kinetic model to characterize SO3–H2SO4 interaction in the gas phase and at the air–water interface and to study the effect of H2S2O7 on H2SO4–NH3-based clusters. The work expands our understanding of new pathways for the loss of SO3 in acidic polluted areas and helps reveal some missing sources of NPF in metropolitan industrial regions and understand the atmospheric organic–sulfur cycle better.
Hao Yang, Lei Chen, Hong Liao, Jia Zhu, Wenjie Wang, and Xin Li
Atmos. Chem. Phys., 24, 4001–4015, https://doi.org/10.5194/acp-24-4001-2024, https://doi.org/10.5194/acp-24-4001-2024, 2024
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The present study quantifies the response of aerosol–radiation interaction (ARI) to anthropogenic emission reduction from 2013 to 2017, with the main focus on the contribution to changed O3 concentrations over eastern China both in summer and winter using the WRF-Chem model. The weakened ARI due to decreased anthropogenic emission aggravates the summer (winter) O3 pollution by +0.81 ppb (+0.63 ppb), averaged over eastern China.
Margaret R. Marvin, Paul I. Palmer, Fei Yao, Mohd Talib Latif, and Md Firoz Khan
Atmos. Chem. Phys., 24, 3699–3715, https://doi.org/10.5194/acp-24-3699-2024, https://doi.org/10.5194/acp-24-3699-2024, 2024
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We use an atmospheric chemistry model to investigate aerosols emitted from fire activity across Southeast Asia. We find that the limited nature of measurements in this region leads to large uncertainties that significantly hinder the model representation of these aerosols and their impacts on air quality. As a result, the number of monthly attributable deaths is underestimated by as many as 4500, particularly in March at the peak of the mainland burning season.
Julie Camman, Benjamin Chazeau, Nicolas Marchand, Amandine Durand, Grégory Gille, Ludovic Lanzi, Jean-Luc Jaffrezo, Henri Wortham, and Gaëlle Uzu
Atmos. Chem. Phys., 24, 3257–3278, https://doi.org/10.5194/acp-24-3257-2024, https://doi.org/10.5194/acp-24-3257-2024, 2024
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Fine particle (PM1) pollution is a major health issue in the city of Marseille, which is subject to numerous pollution sources. Sampling carried out during the summer enabled a fine characterization of the PM1 sources and their oxidative potential, a promising new metric as a proxy for health impact. PM1 came mainly from combustion sources, secondary ammonium sulfate, and organic nitrate, while the oxidative potential of PM1 came from these sources and from resuspended dust in the atmosphere.
Yuemeng Ji, Zhang Shi, Wenjian Li, Jiaxin Wang, Qiuju Shi, Yixin Li, Lei Gao, Ruize Ma, Weijun Lu, Lulu Xu, Yanpeng Gao, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 3079–3091, https://doi.org/10.5194/acp-24-3079-2024, https://doi.org/10.5194/acp-24-3079-2024, 2024
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The formation mechanisms for secondary brown carbon (SBrC) contributed by multifunctional reduced nitrogen compounds (RNCs) remain unclear. Hence, from combined laboratory experiments and quantum chemical calculations, we investigated the heterogeneous reactions of glyoxal (GL) with multifunctional RNCs, which are driven by four-step indirect nucleophilic addition reactions. Our results show a possible missing source for SBrC formation on urban, regional, and global scales.
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Short summary
In this work, four schemes for the simulation of organic aerosols in the western Mediterranean basin are added to the CHIMERE chemistry–transport model; the resulting simulations are then compared to measurements obtained from ChArMEx. It is concluded that the scheme taking into account the fragmentation and the formation of nonvolatile organic aerosols corresponds better to measurements; the major source of this aerosol in the western Mediterranean is found to be of biogenic origin.
In this work, four schemes for the simulation of organic aerosols in the western Mediterranean...
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