Articles | Volume 16, issue 5
Atmos. Chem. Phys., 16, 3595–3607, 2016

Special issue: CHemistry and AeRosols Mediterranean EXperiments (ChArMEx)...

Atmos. Chem. Phys., 16, 3595–3607, 2016

Research article 17 Mar 2016

Research article | 17 Mar 2016

Source apportionment vs. emission inventories of non-methane hydrocarbons (NMHC) in an urban area of the Middle East: local and global perspectives

Thérèse Salameh1,2,3,a, Stéphane Sauvage1,2, Charbel Afif3, Agnès Borbon4,b, and Nadine Locoge1,2 Thérèse Salameh et al.
  • 1Mines Douai, Sciences de l'Atmosphère et Génie de l'Environnement (SAGE), 59508 Douai CEDEX, France
  • 2Université de Lille, 59000 Lille, France
  • 3Emissions, Measurements, and Modeling of the Atmosphere (EMMA) Laboratory, Unité Environnement, Génomique Fonctionnelle et Études Mathématiques, Centre d'Analyses et de Recherche, Faculty of Sciences, Saint Joseph University, Beirut, Lebanon
  • 4Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), IPSL, CNRS, UMR 7583, University of Paris Est Créteil (UPEC) and Paris Diderot (UPD), Créteil, France
  • anow at: Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), IPSL, CNRS, UMR 7583, University of Paris Est Créteil (UPEC) and Paris Diderot (UPD), Créteil, France
  • bnow at: Laboratoire de Météorologie Physique (LaMP), CNRS – UMR 6016, University of Blaise Pascal, Clermont-Ferrand, France

Abstract. We applied the positive matrix factorization model to two large data sets collected during two intensive measurement campaigns (summer 2011 and winter 2012) at a sub-urban site in Beirut, Lebanon, in order to identify NMHC (non-methane hydrocarbons) sources and quantify their contribution to ambient levels. Six factors were identified in winter and five factors in summer. PMF-resolved source profiles were consistent with source profiles established by near-field measurements. The major sources were traffic-related emissions (combustion and gasoline evaporation) in winter and in summer accounting for 51 and 74 wt %, respectively, in agreement with the national emission inventory. The gasoline evaporation related to traffic source had a significant contribution regardless of the season (22 wt % in winter and 30 wt % in summer). The NMHC emissions from road transport are estimated from observations and PMF results, and compared to local and global emission inventories. The PMF analysis finds reasonable differences on emission rates, of 20–39 % higher than the national road transport inventory. However, global inventories (ACCMIP, EDGAR, MACCity) underestimate the emissions up to a factor of 10 for the transportation sector. When combining emission inventory to our results, there is strong evidence that control measures in Lebanon should be targeted on mitigating the NMHC emissions from the traffic-related sources. From a global perspective, an assessment of VOC (volatile organic compounds) anthropogenic emission inventories for the Middle East region as a whole seems necessary as these emissions could be much higher than expected at least from the road transport sector.

Final-revised paper