Articles | Volume 16, issue 16
Atmos. Chem. Phys., 16, 10419–10440, 2016
Atmos. Chem. Phys., 16, 10419–10440, 2016

Research article 18 Aug 2016

Research article | 18 Aug 2016

Assessing the ammonium nitrate formation regime in the Paris megacity and its representation in the CHIMERE model

Hervé Petetin1,a, Jean Sciare2,3, Michael Bressi2, Valérie Gros2, Amandine Rosso4, Olivier Sanchez4, Roland Sarda-Estève2, Jean-Eudes Petit2,b, and Matthias Beekmann1 Hervé Petetin et al.
  • 1LISA/IPSL, Laboratoire Interuniversitaire des Systèmes Atmosphériques, UMR CNRS 7583, Université Paris Est Créteil (UPEC) and Université Paris Diderot (UPD), France
  • 2LSCE, Laboratoire des Sciences du Climat et de l'Environnement, CNRS-CEA-UVSQ, Gif-sur-Yvette, France
  • 3Energy Environment Water Research Center (EEWRC), The Cyprus Institute, Nicosia, Cyprus
  • 4AIRPARIF, Agence de surveillance de la qualité de l'air, Paris, France
  • anow at: Laboratoire d'Aérologie, Université Paul Sabatier and CNRS, Toulouse, France
  • bnow at: Air Lorraine, Villers-les-Nancy, France

Abstract. Secondary inorganic compounds represent a major fraction of fine aerosol in the Paris megacity. The thermodynamics behind their formation is now relatively well constrained but, due to sparse direct measurements of their precursors (in particular NH3 and HNO3), uncertainties remain on their concentrations and variability as well as the formation regime of ammonium nitrate (in terms of limited species among NH3 and HNO3) in urban environments such as Paris. This study presents the first urban background measurements of both inorganic aerosol compounds and their gaseous precursors during several months within the city of Paris. Intense agriculture-related NH3 episodes are observed in spring/summer while HNO3 concentrations remain relatively low, even during summer, which leads to a NH3-rich regime in Paris. The local formation of ammonium nitrate within the city appears low, despite high NOx emissions. The data set also allows evaluating the CHIMERE chemistry-transport model (CTM). Interestingly, the rather good results obtained on ammonium nitrates hide significant errors on gaseous precursors (e.g., mean bias of −75 and +195 % for NH3 and HNO3, respectively). This leads to a misrepresentation of the nitrate formation regime through a highly underestimated gas ratio metric (introduced by Ansari and Pandis, 1998) and a much higher sensitivity of nitrate concentrations to ammonia changes. Several uncertainty sources are investigated, pointing out the importance of better assessing both NH3 agricultural emissions and OH concentrations in the future. These results remind us of the caution required when using of CTMs for emission scenario analysis, highlighting the importance of prior diagnostic and dynamic evaluations.

Short summary
This paper presents the first combined measurements of both ammonium nitrate aerosols and their gaseous precursors (HNO3, NH3) in the Paris megacity, obtained during the FRANCIPOL and PARTICULES campaigns. This data set is used to investigate the nitrate formation regime within the city, which is particularly important considering the high contribution of nitrates in the fine aerosol pollution of Paris. In addition, it is also used to evaluate the CHIMERE chemistry-transport model.
Final-revised paper