Articles | Volume 16, issue 20
Atmos. Chem. Phys., 16, 12875–12896, 2016
Atmos. Chem. Phys., 16, 12875–12896, 2016

Research article 18 Oct 2016

Research article | 18 Oct 2016

Variations in the chemical composition of the submicron aerosol and in the sources of the organic fraction at a regional background site of the Po Valley (Italy)

Michael Bressi1, Fabrizia Cavalli1, Claudio A. Belis1, Jean-Philippe Putaud1, Roman Fröhlich2, Sebastiao Martins dos Santos1, Ettore Petralia3, André S. H. Prévôt2, Massimo Berico3, Antonella Malaguti3, and Francesco Canonaco2 Michael Bressi et al.
  • 1European Commission, Joint Research Centre, Institute for Environment and Sustainability, Air and Climate Unit, Via Enrico Fermi 2749, Ispra (VA) 21027, Italy
  • 2Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, Villigen 5232, Switzerland
  • 3Italian National Agency for New Technologies, Energy and Sustainable Economic Development (ENEA), Via Martiri di Monte Sole 4, Bologna 40129, Italy

Abstract. Fine particulate matter (PM) levels and resulting impacts on human health are in the Po Valley (Italy) among the highest in Europe. To build effective PM abatement strategies, it is necessary to characterize fine PM chemical composition, sources and atmospheric processes on long timescales (> months), with short time resolution (< day), and with particular emphasis on the predominant organic fraction. Although previous studies have been conducted in this region, none of them addressed all these aspects together. For the first time in the Po Valley, we investigate the chemical composition of nonrefractory submicron PM (NR-PM1) with a time resolution of 30 min at the regional background site of Ispra during 1 full year, using the Aerodyne Aerosol Chemical Speciation Monitor (ACSM) under the most up-to-date and stringent quality assurance protocol. The identification of the main components of the organic fraction is made using the Multilinear-Engine 2 algorithm implemented within the latest version of the SoFi toolkit. In addition, with the aim of a potential implementation of ACSM measurements in European air quality networks as a replacement of traditional filter-based techniques, parallel multiple offline analyses were carried out to assess the performance of the ACSM in the determination of PM chemical species regulated by air quality directives. The annual NR-PM1 level monitored at the study site (14.2 µg m−3) is among the highest in Europe and is even comparable to levels reported in urban areas like New York City and Tokyo. On the annual basis, submicron particles are primarily composed of organic aerosol (OA, 58 % of NR-PM1). This fraction was apportioned into oxygenated OA (OOA, 66 %), hydrocarbon-like OA (HOA, 11 % of OA) and biomass burning OA (BBOA, 23 %). Among the primary sources of OA, biomass burning (23 %) is thus bigger than fossil fuel combustion (11 %). Significant contributions of aged secondary organic aerosol (OOA) are observed throughout the year. The unexpectedly high degree of oxygenation estimated during wintertime is probably due to the contribution of secondary BBOA and the enhancement of aqueous-phase production of OOA during cold months. BBOA and nitrate are the only components of which contributions increase with the NR-PM1 levels. Therefore, biomass burning and NOx emission reductions would be particularly efficient in limiting submicron aerosol pollution events. Abatement strategies conducted during cold seasons appear to be more efficient than annual-based policies. In a broader context, further studies using high-time-resolution analytical techniques on a long-term basis for the characterization of fine aerosol should help better shape our future air quality policies, which constantly need refinement.

Short summary
Atmospheric particulate matter (PM) levels and resulting impacts on human health are in the Po Valley (Italy) among the highest in Europe. This study discusses submicron PM chemical composition, sources and atmospheric processes in this region, using state-of-the-art measurement techniques and receptor models. Based on these results, effective PM abatement strategies are suggested in the upper Po Valley.
Final-revised paper