Articles | Volume 15, issue 3
https://doi.org/10.5194/acp-15-1289-2015
https://doi.org/10.5194/acp-15-1289-2015
Research article
 | 
06 Feb 2015
Research article |  | 06 Feb 2015

Evidence for an unidentified non-photochemical ground-level source of formaldehyde in the Po Valley with potential implications for ozone production

J. Kaiser, G. M. Wolfe, B. Bohn, S. Broch, H. Fuchs, L. N. Ganzeveld, S. Gomm, R. Häseler, A. Hofzumahaus, F. Holland, J. Jäger, X. Li, I. Lohse, K. Lu, A. S. H. Prévôt, F. Rohrer, R. Wegener, R. Wolf, T. F. Mentel, A. Kiendler-Scharr, A. Wahner, and F. N. Keutsch

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Cited articles

Alam, M. S., Camredon, M., Rickard, A. R., Carr, T., Wyche, K. P., Hornsby, K. E., Monks, P. S., and Bloss, W. J.: Total radical yields from tropospheric ethene ozonolysis, Phys. Chem. Chem. Phys., 13, 11002–11015, https://doi.org/10.1039/c0cp02342f, 2011.
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J. C., and Pilling, M. J.: Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons, Atmos. Chem. Phys., 5, 641–664, https://doi.org/10.5194/acp-5-641-2005, 2005.
Bukowiecki, N., Dommen, J., Prévôt, A. S. H., Richter, R., Weingartner, E., and Baltensperger, U.: A mobile pollutant measurement laboratory – measuring gas phase and aerosol ambient concentrations with high spatial and temporal resolution, Atmos. Environ., 36, 5569–5579, https://doi.org/10.1016/S1352-2310(02)00694-5, 2002.
DiGangi, J. P., Boyle, E. S., Karl, T., Harley, P., Turnipseed, A., Kim, S., Cantrell, C., Maudlin III, R. L., Zheng, W., Flocke, F., Hall, S. R., Ullmann, K., Nakashima, Y., Paul, J. B., Wolfe, G. M., Desai, A. R., Kajii, Y., Guenther, A., and Keutsch, F. N.: First direct measurements of formaldehyde flux via eddy covariance: implications for missing in-canopy formaldehyde sources, Atmos. Chem. Phys., 11, 10565–10578, https://doi.org/10.5194/acp-11-10565-2011, 2011.
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Using measurements acquired from a Zeppelin airship during the PEGASOS 2012 campaign, we show that VOC oxidation alone cannot account for the formaldehyde concentrations observed in the morning over rural Italy. Vertical profiles suggest a ground-level source of HCHO. Incorporating this additional HCHO source into a photochemical model increases calculated O3 production by as much as 12%.
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