Articles | Volume 15, issue 3
https://doi.org/10.5194/acp-15-1289-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-1289-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
06 Feb 2015
Research article |
| 06 Feb 2015
Evidence for an unidentified non-photochemical ground-level source of formaldehyde in the Po Valley with potential implications for ozone production
J. Kaiser
Chemistry, University of Wisconsin-Madison, Madison, WI, USA
G. M. Wolfe
Chemistry, University of Wisconsin-Madison, Madison, WI, USA
now at: Joint Center for Earth Systems Technology, University of Maryland Baltimore County, Baltimore, MD, USA
now at: Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD, USA
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
L. N. Ganzeveld
Earth System Science and Climate Change, Wageningen University and Research Center, Wageningen, Netherlands
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
R. Häseler
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
A. Hofzumahaus
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
F. Holland
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
J. Jäger
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
I. Lohse
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: College of Environmental Sciences & Engineering, Peking University, Beijing, China
A. S. H. Prévôt
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
F. Rohrer
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
R. Wegener
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
R. Wolf
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
T. F. Mentel
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
A. Kiendler-Scharr
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
A. Wahner
Institut für Energie- und Klimaforschung Troposphäre IEK-8, Forschungszentrum Jülich GmbH, Jülich, Germany
F. N. Keutsch
CORRESPONDING AUTHOR
Chemistry, University of Wisconsin-Madison, Madison, WI, USA
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Cited
28 citations as recorded by crossref.
- Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS) A. Zogka et al. 10.5194/amt-15-2001-2022
- Field Determination of Nitrate Formation Pathway in Winter Beijing X. Chen et al. 10.1021/acs.est.0c00972
- Optical receiver characterizations and corrections for ground-based and airborne measurements of spectral actinic flux densities B. Bohn & I. Lohse 10.5194/amt-16-209-2023
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Ambient Formaldehyde over the United States from Ground-Based (AQS) and Satellite (OMI) Observations P. Wang et al. 10.3390/rs14092191
- Sources and Potential Photochemical Roles of Formaldehyde in an Urban Atmosphere in South China C. Wang et al. 10.1002/2017JD027266
- Global Surface HCHO Distribution Derived from Satellite Observations with Neural Networks Technique J. Guan et al. 10.3390/rs13204055
- Modeling secondary organic aerosol formation from volatile chemical products E. Pennington et al. 10.5194/acp-21-18247-2021
- A New Portable Instrument for Online Measurements of Formaldehyde: From Ambient to Mobile Emission Sources M. Zhu et al. 10.1021/acs.estlett.0c00169
- Biogenic volatile organic compound emission patterns and secondary pollutant formation potentials of dominant greening trees in Chengdu, southwest China L. Liu et al. 10.1016/j.jes.2021.08.033
- Characterizing Operating Condition-Based Formaldehyde Emissions of Light-Duty Diesel Trucks in China Using a PEMS-HCHO System M. Zhu et al. 10.1021/acs.est.2c07744
- Effect of Seasonal Variation on the Levels and Behaviours of Formaldehyde in the Atmosphere of a Suburban Area in Cairo, Egypt S. Hassan et al. 10.5572/ajae.2018.12.4.356
- Release of formaldehyde and other organic compounds from nitrogen fertilizers T. Salthammer & J. Gunschera 10.1016/j.chemosphere.2020.127913
- Identifying forecast uncertainties for biogenic gases in the Po Valley related to model configuration in EURAD-IM during PEGASOS 2012 A. Vogel & H. Elbern 10.5194/acp-21-4039-2021
- Spatiotemporal Variations in Satellite-Based Formaldehyde (HCHO) in the Beijing-Tianjin-Hebei Region in China from 2005 to 2015 S. Zhu et al. 10.3390/atmos9010005
- Long term (2005–2016) study of formaldehyde (HCHO) columns from satellite data in two regions in the south of Mexico. Evidence of the impact of agricultural activity C. Mendoza-Rodríguez et al. 10.1016/j.rsase.2022.100894
- Detailed budget analysis of HONO in Beijing, China: Implication on atmosphere oxidation capacity in polluted megacity J. Liu et al. 10.1016/j.atmosenv.2020.117957
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Real-Time Measurements of Formaldehyde Emissions from Modern Vehicles R. Suarez-Bertoa et al. 10.3390/en15207680
- Atmospheric OH reactivity in central London: observations, model predictions and estimates of in situ ozone production L. Whalley et al. 10.5194/acp-16-2109-2016
- The effect of photocatalytic coatings on NOx concentrations in real-world street canyons E. Brattich et al. 10.1016/j.buildenv.2021.108312
- Measurement report: Observation-based formaldehyde production rates and their relation to OH reactivity around the Arabian Peninsula D. Dienhart et al. 10.5194/acp-21-17373-2021
- Field Experience for Determination of Formaldehyde in Stack Emissions A. Cefalì et al. 10.3390/app121910150
- Formaldehyde in the Tropical Western Pacific: Chemical Sources and Sinks, Convective Transport, and Representation in CAM‐Chem and the CCMI Models D. Anderson et al. 10.1002/2016JD026121
- Continental pollution in the western Mediterranean basin: vertical profiles of aerosol and trace gases measured over the sea during TRAQA 2012 and SAFMED 2013 C. Di Biagio et al. 10.5194/acp-15-9611-2015
- Formaldehyde production from isoprene oxidation across NO<sub><i>x</i></sub> regimes G. Wolfe et al. 10.5194/acp-16-2597-2016
- Summertime high resolution variability of atmospheric formaldehyde and non-methane volatile organic compounds in a rural background area M. de Blas et al. 10.1016/j.scitotenv.2018.07.411
28 citations as recorded by crossref.
- Formaldehyde and glyoxal measurement deploying a selected ion flow tube mass spectrometer (SIFT-MS) A. Zogka et al. 10.5194/amt-15-2001-2022
- Field Determination of Nitrate Formation Pathway in Winter Beijing X. Chen et al. 10.1021/acs.est.0c00972
- Optical receiver characterizations and corrections for ground-based and airborne measurements of spectral actinic flux densities B. Bohn & I. Lohse 10.5194/amt-16-209-2023
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Ambient Formaldehyde over the United States from Ground-Based (AQS) and Satellite (OMI) Observations P. Wang et al. 10.3390/rs14092191
- Sources and Potential Photochemical Roles of Formaldehyde in an Urban Atmosphere in South China C. Wang et al. 10.1002/2017JD027266
- Global Surface HCHO Distribution Derived from Satellite Observations with Neural Networks Technique J. Guan et al. 10.3390/rs13204055
- Modeling secondary organic aerosol formation from volatile chemical products E. Pennington et al. 10.5194/acp-21-18247-2021
- A New Portable Instrument for Online Measurements of Formaldehyde: From Ambient to Mobile Emission Sources M. Zhu et al. 10.1021/acs.estlett.0c00169
- Biogenic volatile organic compound emission patterns and secondary pollutant formation potentials of dominant greening trees in Chengdu, southwest China L. Liu et al. 10.1016/j.jes.2021.08.033
- Characterizing Operating Condition-Based Formaldehyde Emissions of Light-Duty Diesel Trucks in China Using a PEMS-HCHO System M. Zhu et al. 10.1021/acs.est.2c07744
- Effect of Seasonal Variation on the Levels and Behaviours of Formaldehyde in the Atmosphere of a Suburban Area in Cairo, Egypt S. Hassan et al. 10.5572/ajae.2018.12.4.356
- Release of formaldehyde and other organic compounds from nitrogen fertilizers T. Salthammer & J. Gunschera 10.1016/j.chemosphere.2020.127913
- Identifying forecast uncertainties for biogenic gases in the Po Valley related to model configuration in EURAD-IM during PEGASOS 2012 A. Vogel & H. Elbern 10.5194/acp-21-4039-2021
- Spatiotemporal Variations in Satellite-Based Formaldehyde (HCHO) in the Beijing-Tianjin-Hebei Region in China from 2005 to 2015 S. Zhu et al. 10.3390/atmos9010005
- Long term (2005–2016) study of formaldehyde (HCHO) columns from satellite data in two regions in the south of Mexico. Evidence of the impact of agricultural activity C. Mendoza-Rodríguez et al. 10.1016/j.rsase.2022.100894
- Detailed budget analysis of HONO in Beijing, China: Implication on atmosphere oxidation capacity in polluted megacity J. Liu et al. 10.1016/j.atmosenv.2020.117957
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Real-Time Measurements of Formaldehyde Emissions from Modern Vehicles R. Suarez-Bertoa et al. 10.3390/en15207680
- Atmospheric OH reactivity in central London: observations, model predictions and estimates of in situ ozone production L. Whalley et al. 10.5194/acp-16-2109-2016
- The effect of photocatalytic coatings on NOx concentrations in real-world street canyons E. Brattich et al. 10.1016/j.buildenv.2021.108312
- Measurement report: Observation-based formaldehyde production rates and their relation to OH reactivity around the Arabian Peninsula D. Dienhart et al. 10.5194/acp-21-17373-2021
- Field Experience for Determination of Formaldehyde in Stack Emissions A. Cefalì et al. 10.3390/app121910150
- Formaldehyde in the Tropical Western Pacific: Chemical Sources and Sinks, Convective Transport, and Representation in CAM‐Chem and the CCMI Models D. Anderson et al. 10.1002/2016JD026121
- Continental pollution in the western Mediterranean basin: vertical profiles of aerosol and trace gases measured over the sea during TRAQA 2012 and SAFMED 2013 C. Di Biagio et al. 10.5194/acp-15-9611-2015
- Formaldehyde production from isoprene oxidation across NO<sub><i>x</i></sub> regimes G. Wolfe et al. 10.5194/acp-16-2597-2016
- Summertime high resolution variability of atmospheric formaldehyde and non-methane volatile organic compounds in a rural background area M. de Blas et al. 10.1016/j.scitotenv.2018.07.411
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Latest update: 02 Dec 2023
Short summary
Using measurements acquired from a Zeppelin airship during the PEGASOS 2012 campaign, we show that VOC oxidation alone cannot account for the formaldehyde concentrations observed in the morning over rural Italy. Vertical profiles suggest a ground-level source of HCHO. Incorporating this additional HCHO source into a photochemical model increases calculated O3 production by as much as 12%.
Using measurements acquired from a Zeppelin airship during the PEGASOS 2012 campaign, we show...
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