Articles | Volume 17, issue 4
https://doi.org/10.5194/acp-17-2613-2017
https://doi.org/10.5194/acp-17-2613-2017
Research article
 | 
21 Feb 2017
Research article |  | 21 Feb 2017

Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland)

Carla Frege, Federico Bianchi, Ugo Molteni, Jasmin Tröstl, Heikki Junninen, Stephan Henne, Mikko Sipilä, Erik Herrmann, Michel J. Rossi, Markku Kulmala, Christopher R. Hoyle, Urs Baltensperger, and Josef Dommen

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Cited articles

Arnold, F.: Atmospheric ions and aerosol formation, Space Sci. Rev., 137, 225–239, https://doi.org/10.1007/s11214-008-9390-8, 2008.
Bardouki, H., Berresheim, H., Vrekoussis, M., Sciare, J., Kouvarakis, G., Oikonomou, K., Schneider, J., and Mihalopoulos, N.: Gaseous (DMS, MSA, SO2, H2SO4 and DMSO) and particulate (sulfate and methanesulfonate) sulfur species over the northeastern coast of Crete, Atmos. Chem. Phys., 3, 1871–1886, https://doi.org/10.5194/acp-3-1871-2003, 2003.
Berresheim, H., Elste, T., Tremmel, H. G., Allen, A. G., Hansson, H.-C., Rosman, K., Maso, M. D., Makela, J. M., Kulmala, M., and O'Downd, C. D.: Gas-aerosol relationships of H2SO4, MSA, and OH: Observations in the coastal marine boundary layer at Mace Head, Ireland, J. Geophys. Res., 107, 8100, https://doi.org/10.1029/2000JD000229, 2002.
Berresheim, H., Adam, M., Monahan, C., O'Dowd, C., Plane, J. M. C., Bohn, B., and Rohrer, F.: Missing SO2 oxidant in the coastal atmosphere – observations from high-resolution measurements of OH and atmospheric sulfur compounds, Atmos. Chem. Phys., 14, 12209–12223, https://doi.org/10.5194/acp-14-12209-2014, 2014.
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We present measurements of the chemical composition of atmospheric ions at high altitude (3450 m a.s.l.) during a 9-month campaign. We detected remarkably high correlation between methanesulfonic acid (MSA) and SO5. Halogenated species were also detected frequently at this continental location. New-particle formation events occurred via the condensation of highly oxygenated molecules (HOMs) at very low sulfuric acid concentration or, less frequently, due to ammonia–sulfuric acid clusters.
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