Articles | Volume 16, issue 4
Atmos. Chem. Phys., 16, 2273–2284, 2016
Atmos. Chem. Phys., 16, 2273–2284, 2016

Research article 26 Feb 2016

Research article | 26 Feb 2016

Observations of fluorescent aerosol–cloud interactions in the free troposphere at the High-Altitude Research Station Jungfraujoch

I. Crawford1, G. Lloyd1,2, E. Herrmann3, C. R. Hoyle3,4, K. N. Bower1, P. J. Connolly1, M. J. Flynn1, P. H. Kaye5, T. W. Choularton1, and M. W. Gallagher1 I. Crawford et al.
  • 1Centre for Atmospheric Science, SEAES, University of Manchester, Manchester, UK
  • 2NCAS, National Centre for Atmospheric Science, University of Manchester, Manchester, UK
  • 3Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
  • 4WSL Institute for Snow and Avalanche Research SLF, Davos, Switzerland
  • 5Science and Technology Research Institute, University of Hertfordshire, Hatfield, UK

Abstract. The fluorescent nature of aerosol at a high-altitude Alpine site was studied using a wide-band integrated bioaerosol (WIBS-4) single particle multi-channel ultraviolet – light-induced fluorescence (UV-LIF) spectrometer. This was supported by comprehensive cloud microphysics and meteorological measurements with the aims of cataloguing concentrations of bio-fluorescent aerosols at this high-altitude site and also investigating possible influences of UV–fluorescent particle types on cloud–aerosol processes.

Analysis of background free tropospheric air masses, using a total aerosol inlet, showed there to be a minor increase in the fluorescent aerosol fraction during in-cloud cases compared to out-of-cloud cases. The size dependence of the fluorescent aerosol fraction showed the larger aerosol to be more likely to be fluorescent with 80 % of 10 μm particles being fluorescent. Whilst the fluorescent particles were in the minority (NFlNAll  =  0.27 ± 0.19), a new hierarchical agglomerative cluster analysis approach, Crawford et al. (2015) revealed the majority of the fluorescent aerosols were likely to be representative of fluorescent mineral dust. A minor episodic contribution from a cluster likely to be representative of primary biological aerosol particles (PBAP) was also observed with a wintertime baseline concentration of 0.1 ± 0.4 L−1. Given the low concentration of this cluster and the typically low ice-active fraction of studied PBAP (e.g. pseudomonas syringae), we suggest that the contribution to the observed ice crystal concentration at this location is not significant during the wintertime.

Short summary
In this manuscript we discuss observations of fluorescent aerosol and their interactions with cloud at a high-alpine site in the wintertime under background conditions. We find the majority of the fluorescent aerosol to be consistent in nature to mineral dust and no apparent trend was observed between the fluorescent aerosol fraction and meteorological or cloud microphysical parameters, suggesting that particle fluorescence does not impact cloud evolution or formation at the site.
Final-revised paper