Articles | Volume 17, issue 4
https://doi.org/10.5194/acp-17-2613-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-2613-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Feb 2017
Research article |
| 21 Feb 2017
Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland)
Carla Frege
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Federico Bianchi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Ugo Molteni
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Jasmin Tröstl
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Heikki Junninen
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Stephan Henne
Laboratory for Air Pollution/Environmental Technology, Swiss Federal Laboratories for Materials Science and Technology, Empa, 8600 Dübendorf, Switzerland
Mikko Sipilä
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Erik Herrmann
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Michel J. Rossi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Markku Kulmala
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Christopher R. Hoyle
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
WSL (Swiss Federal Institute for Forest, Snow and Landscape Research) Institute for Snow and Avalanche Research SLF, 7260 Davos, Switzerland
Urs Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
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- Organic acid-ammonia ion-induced nucleation pathways unveiled by quantum chemical calculation and kinetics modeling: A case study of 3-methyl-1,2,3-butanetricarboxylic acid D. Xia et al. 10.1016/j.chemosphere.2021.131354
- Atmospheric new particle formation and growth: review of field observations V. Kerminen et al. 10.1088/1748-9326/aadf3c
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- Heatwave reveals potential for enhanced aerosol formation in Siberian boreal forest O. Garmash et al. 10.1088/1748-9326/ad10d5
- Col Margherita Observatory: A background site in the Eastern Italian Alps for investigating the chemical composition of atmospheric aerosols E. Barbaro et al. 10.1016/j.atmosenv.2019.117071
- Chemical identification of new particle formation and growth precursors through positive matrix factorization of ambient ion measurements D. Katz et al. 10.5194/acp-23-5567-2023
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- High-Resolution Photoelectron Imaging and Photodetachment Spectroscopy of Cryogenically Cooled IO– Y. Wang et al. 10.1021/acs.jpca.0c04080
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Aircraft measurements of single particle size and composition reveal aerosol size and mixing state dictate their activation into cloud droplets G. Saliba et al. 10.1039/D3EA00052D
- Nucleation mechanisms of iodic acid in clean and polluted coastal regions H. Rong et al. 10.1016/j.chemosphere.2020.126743
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- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- Actinic Wavelength Action Spectroscopy of the IO– Reaction Intermediate B. McKinnon et al. 10.1021/acs.jpclett.1c03456
- Gas phase reactions of iodide and bromide anions with ozone: evidence for stepwise and reversible reactions M. Bhujel et al. 10.1039/D0CP01498B
24 citations as recorded by crossref.
- Mass spectrometric measurements of ambient ions and estimation of gaseous sulfuric acid in the free troposphere and lowermost stratosphere during the CAFE-EU/BLUESKY campaign M. Zauner-Wieczorek et al. 10.5194/acp-22-11781-2022
- Atmospheric chemistry of iodine anions: elementary reactions of I−, IO−, and IO2− with ozone studied in the gas-phase at 300 K using an ion trap R. Teiwes et al. 10.1039/C8CP05721D
- Organic acid-ammonia ion-induced nucleation pathways unveiled by quantum chemical calculation and kinetics modeling: A case study of 3-methyl-1,2,3-butanetricarboxylic acid D. Xia et al. 10.1016/j.chemosphere.2021.131354
- Atmospheric new particle formation and growth: review of field observations V. Kerminen et al. 10.1088/1748-9326/aadf3c
- Atmospheric Bases-Enhanced Iodic Acid Nucleation: Altitude-Dependent Characteristics and Molecular Mechanisms J. Li et al. 10.1021/acs.est.4c06053
- Field Evidence of Nocturnal Multiphase Production of Iodic Acid D. Li et al. 10.1021/acs.estlett.4c00244
- Impact of a hydrophobic ion on the early stage of atmospheric aerosol formation L. Feketeová et al. 10.1073/pnas.1911136116
- The gas-phase formation mechanism of iodic acid as an atmospheric aerosol source H. Finkenzeller et al. 10.1038/s41557-022-01067-z
- Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion) R. Salignat et al. 10.5194/acp-24-3785-2024
- Heatwave reveals potential for enhanced aerosol formation in Siberian boreal forest O. Garmash et al. 10.1088/1748-9326/ad10d5
- Col Margherita Observatory: A background site in the Eastern Italian Alps for investigating the chemical composition of atmospheric aerosols E. Barbaro et al. 10.1016/j.atmosenv.2019.117071
- Chemical identification of new particle formation and growth precursors through positive matrix factorization of ambient ion measurements D. Katz et al. 10.5194/acp-23-5567-2023
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- Investigation of several proxies to estimate sulfuric acid concentration under volcanic plume conditions C. Rose et al. 10.5194/acp-21-4541-2021
- Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes Q. Zha et al. 10.5194/acp-23-4559-2023
- High-Resolution Photoelectron Imaging and Photodetachment Spectroscopy of Cryogenically Cooled IO– Y. Wang et al. 10.1021/acs.jpca.0c04080
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Aircraft measurements of single particle size and composition reveal aerosol size and mixing state dictate their activation into cloud droplets G. Saliba et al. 10.1039/D3EA00052D
- Nucleation mechanisms of iodic acid in clean and polluted coastal regions H. Rong et al. 10.1016/j.chemosphere.2020.126743
- New particle formation induced by anthropogenic–biogenic interactions on the southeastern Tibetan Plateau S. Lai et al. 10.5194/acp-24-2535-2024
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- Actinic Wavelength Action Spectroscopy of the IO– Reaction Intermediate B. McKinnon et al. 10.1021/acs.jpclett.1c03456
- Gas phase reactions of iodide and bromide anions with ozone: evidence for stepwise and reversible reactions M. Bhujel et al. 10.1039/D0CP01498B
Discussed (final revised paper)
Latest update: 20 Nov 2024
Short summary
We present measurements of the chemical composition of atmospheric ions at high altitude (3450 m a.s.l.) during a 9-month campaign. We detected remarkably high correlation between methanesulfonic acid (MSA) and SO5−. Halogenated species were also detected frequently at this continental location. New-particle formation events occurred via the condensation of highly oxygenated molecules (HOMs) at very low sulfuric acid concentration or, less frequently, due to ammonia–sulfuric acid clusters.
We present measurements of the chemical composition of atmospheric ions at high altitude...
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