Articles | Volume 20, issue 1
https://doi.org/10.5194/acp-20-181-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-181-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Jan 2020
Research article |
| 06 Jan 2020
| 06 Jan 2020
Evaluation and uncertainty investigation of the NO2, CO and NH3 modeling over China under the framework of MICS-Asia III
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Xiao Tang
CORRESPONDING AUTHOR
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Jiang Zhu
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Zifa Wang
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Joshua S. Fu
Department of Civil and Environmental Engineering, University of
Tennessee, Knoxville, TN 37996, USA
Xuemei Wang
Institute for Environment and Climate Research, Jinan University,
Guangzhou, 510632, China
Syuichi Itahashi
Central Research Institute of Electric Power Industry, Abiko, Chiba 270-1194, Japan
Department of Marine, Earth, and Atmospheric Sciences, North Carolina State University, Raleigh, NC 27607, USA
Kazuyo Yamaji
Graduate School of Maritime Sciences, Kobe University, Kobe, Hyogo
658-0022, Japan
Tatsuya Nagashima
National Institute for Environmental Studies, Onogawa, Tsukuba
305-8506, Japan
Hyo-Jung Lee
Department of Atmospheric Sciences, Pusan National University, Busan, 46241, South Korea
Cheol-Hee Kim
Department of Atmospheric Sciences, Pusan National University, Busan, 46241, South Korea
Chuan-Yao Lin
Research Center for Environmental Changes, Academia Sinica, Taipei, 115, Taiwan
Lei Chen
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Meigen Zhang
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Zhining Tao
Universities Space Research Association, Columbia, MD 21046, USA
NASA Goddard Space Flight Center, Greenbelt, MD 20771, USA
Jie Li
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Mizuo Kajino
Meteorological Research Institute, Japan Meteorological Agency,
Tsukuba, Ibaraki 305-0052, Japan
Faculty of Life and Environmental Sciences, University of Tsukuba,
Tsukuba, Ibaraki 305-8577, Japan
Hong Liao
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and
Pollution Control, Collaborative Innovation Center of Atmospheric
Environment and Equipment Technology, School of Environmental Science and
Engineering, Nanjing University of Information Science and Technology,
Nanjing, 210044, China
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Research Institute for Applied Mechanics (RIAM), Kyushu University, Kasuga, Fukuoka 816-8580, Japan
Kengo Sudo
Graduate School of Environmental Studies, Nagoya University, Nagoya, Aichi 464-0814, Japan
Yuesi Wang
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Yuepeng Pan
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Guiqian Tang
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Ministry of Education Key laboratory for Earth System Modeling,
Department of Earth System Science, Tsinghua University, Beijing, 100084,
China
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, 55128, Germany
Qizhong Wu
College of Global Change and Earth System Science, Beijing Normal
University, Beijing, 100875, China
Joint Center for Global Change Studies, Beijing Normal University, Beijing, 100875, China
Baozhu Ge
LAPC & ICCES, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Gregory R. Carmichael
Center for Global and Regional Environmental Research, University of Iowa, Iowa City, IA 52242, USA
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Yang Yang, Yang Zhou, Hailong Wang, Mengyun Li, Huimin Li, Pinya Wang, Xu Yue, Ke Li, Jia Zhu, and Hong Liao
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This study reveals that extreme ozone pollution over the North China Plain and Yangtze River Delta is due to the chemical production related to hot and dry conditions, and the regional transport explains the ozone pollution over the Sichuan Basin and Pearl River Delta. The frequency of meteorological conditions of the extreme ozone pollution increases from the past to the future. The sustainable scenario is the optimal path to retaining clean air in China in the future.
Victoria A. Flood, Kimberly Strong, Cynthia H. Whaley, Kaley A. Walker, Thomas Blumenstock, James W. Hannigan, Johan Mellqvist, Justus Notholt, Mathias Palm, Amelie N. Röhling, Stephen Arnold, Stephen Beagley, Rong-You Chien, Jesper Christensen, Makoto Deushi, Srdjan Dobricic, Xinyi Dong, Joshua S. Fu, Michael Gauss, Wanmin Gong, Joakim Langner, Kathy S. Law, Louis Marelle, Tatsuo Onishi, Naga Oshima, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Manu A. Thomas, Svetlana Tsyro, and Steven Turnock
Atmos. Chem. Phys., 24, 1079–1118, https://doi.org/10.5194/acp-24-1079-2024, https://doi.org/10.5194/acp-24-1079-2024, 2024
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It is important to understand the composition of the Arctic atmosphere and how it is changing. Atmospheric models provide simulations that can inform policy. This study examines simulations of CH4, CO, and O3 by 11 models. Model performance is assessed by comparing results matched in space and time to measurements from five high-latitude ground-based infrared spectrometers. This work finds that models generally underpredict the concentrations of these gases in the Arctic troposphere.
Audrey Gaudel, Ilann Bourgeois, Meng Li, Kai-Lan Chang, Jerald Ziemke, Bastien Sauvage, Ryan M. Stauffer, Anne M. Thompson, Debra E. Kollonige, Nadia Smith, Daan Hubert, Arno Keppens, Juan Cuesta, Klaus-Peter Heue, Pepijn Veefkind, Kenneth Aikin, Jeff Peischl, Chelsea R. Thompson, Thomas B. Ryerson, Gregory J. Frost, Brian C. McDonald, and Owen R. Cooper
EGUsphere, https://doi.org/10.5194/egusphere-2023-3095, https://doi.org/10.5194/egusphere-2023-3095, 2024
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The study examines tropical tropospheric ozone changes. In situ data from 1994−2019 display increased ozone, notably over India, Southeast Asia, and Malaysia/Indonesia. Sparse in situ data limit trend detection for the 15-year period. In situ and satellite data, with limited sampling, struggle to consistently detect trends. Continuous observations are vital over the tropical Pacific Ocean, Indian Ocean, Western Africa, and South Asia for accurate ozone trend estimation in these regions.
Kai Cao, Qizhong Wu, Lingling Wang, Hengliang Guo, Nan Wang, Huaqiong Cheng, Xiao Tang, Lina Liu, Dongqing Li, Hao Wu, and Lanning Wang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-222, https://doi.org/10.5194/gmd-2023-222, 2024
Revised manuscript under review for GMD
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AMD’s HIP was implemented to port the PPM solver from the NVIDIA GPUs to China’s GPU-like accelerators. The results show that the larger the model scale, the more acceleration effect on the GPU-like accelerator, up to the 28.9x. The multi-level hybrid parallelism enables achieve up to 32.7x speedup on the heterogeneous cluster. By comparing the simulation results, it is found that the GPU-like accelerators get more accuracy for the geoscience numerical models.
Lei Kong, Xiao Tang, Zifa Wang, Jiang Zhu, Jianjun Li, Huangjian Wu, Qizhong Wu, Huansheng Chen, Lili Zhu, Wei Wang, Bing Liu, Qian Wang, Duohong Chen, Yuepeng Pan, Jie Li, Lin Wu, and Gregory R. Carmichael
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-477, https://doi.org/10.5194/essd-2023-477, 2023
Revised manuscript under review for ESSD
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A new long-term inversed emission inventory for Chinese air quality (CAQIEI) is developed in this study which contains constrained monthly emissions of NOx, SO2, CO, PM2.5, PM10 and NMVOC in China from 2013 to 2020 with a horizontal resolution of 15km. Emissions of different air pollutants and their changes during 2013–2020 were investigated, and compared with previous emission inventories, which sheds new light on the complex variations of the air pollutant emissions in China.
Mijie Pang, Jianbing Jin, Segers Arjo, Huiya Jiang, Wei Han, Ji Xia, Li Fang, Jiandong Li, Hai Xiang Lin, and Hong Liao
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-219, https://doi.org/10.5194/gmd-2023-219, 2023
Revised manuscript under review for GMD
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Dust storms can cause harm to health and infrastructure. Forecasting their intensity and position is important but challenging. We propose a new algorithm, NTEnKF, that considers both intensity and positional errors to improve dust storm forecasting. Evaluations on three major dust events in 2021 showed significant improvements compared to traditional EnKF methods. This research has implications for accurate dust forecasting.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyang Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
EGUsphere, https://doi.org/10.5194/egusphere-2023-2684, https://doi.org/10.5194/egusphere-2023-2684, 2023
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We investigated aerosol composition, sources, and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more-oxidized SOA; however, cloud evaporation leads to the production of less-oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Yaqi Wang, Lanning Wang, Juan Feng, Zhenya Song, Qizhong Wu, and Huaqiong Cheng
Geosci. Model Dev., 16, 6857–6873, https://doi.org/10.5194/gmd-16-6857-2023, https://doi.org/10.5194/gmd-16-6857-2023, 2023
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In this study, to noticeably improve precipitation simulation in steep mountains, we propose a sub-grid parameterization scheme for the topographic vertical motion in CAM5-SE to revise the original vertical velocity by adding the topographic vertical motion. The dynamic lifting effect of topography is extended from the lowest layer to multiple layers, thus improving the positive deviations of precipitation simulation in high-altitude regions and negative deviations in low-altitude regions.
Zhen Peng, Lili Lei, Zhe-Min Tan, Meigen Zhang, Aijun Ding, and Xingxia Kou
Atmos. Chem. Phys., 23, 14505–14520, https://doi.org/10.5194/acp-23-14505-2023, https://doi.org/10.5194/acp-23-14505-2023, 2023
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Annual PM2.5 emissions in China consistently decreased by about 3% to 5% from 2017 to 2020 with spatial variations and seasonal dependencies. High-temporal-resolution and dynamics-based PM2.5 emission estimates provide quantitative diurnal variations for each season. Significant reductions in PM2.5 emissions in the North China Plain and northeast of China in 2020 were caused by COVID-19.
Aodong Du, Jiaxing Sun, Hang Liu, Weiqi Xu, Wei Zhou, Yuting Zhang, Lei Li, Xubing Du, Yan Li, Xiaole Pan, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 23, 13597–13611, https://doi.org/10.5194/acp-23-13597-2023, https://doi.org/10.5194/acp-23-13597-2023, 2023
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We characterized the impacts of emission controls on particle mixing state and density during the Beijing Olympic Winter Games using a SPAMS in tandem with a DMA and an AAC. OC and sulfate-containing particles increased, while those from primary emissions decreased. The effective particle densities increased and varied largely for different particles, highlighting the impacts of aging and formation processes on the changes of particle density and mixing state.
Yanfeng He and Kengo Sudo
Atmos. Chem. Phys., 23, 13061–13085, https://doi.org/10.5194/acp-23-13061-2023, https://doi.org/10.5194/acp-23-13061-2023, 2023
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Lightning has big social impacts. Lightning-produced NOx (LNOx) plays a vital role in atmospheric chemistry and climate. Investigating past lightning and LNOx trends can provide essential indicators of all lightning-related phenomena. Simulations show almost flat global lightning and LNOx trends during 1960–2014. Past global warming enhances the trends positively, but increases in aerosol have the opposite effect. Moreover, global lightning decreased markedly after the Pinatubo eruption.
Tao Wang, Hang Liu, Jie Li, Shuai Wang, Youngseob Kim, Yele Sun, Wenyi Yang, Huiyun Du, Zhe Wang, and Zifa Wang
Geosci. Model Dev., 16, 5585–5599, https://doi.org/10.5194/gmd-16-5585-2023, https://doi.org/10.5194/gmd-16-5585-2023, 2023
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This paper developed a two-way coupled module in a new version of a regional urban–street network model, IAQMS-street v2.0, in which the mass flux from streets to background is considered. Test cases are defined to evaluate the performance of IAQMS-street v2.0 in Beijing by comparing it with that simulated by IAQMS-street v1.0 and a regional model. The contribution of local emissions and the influence of on-road vehicle control measures on air quality are evaluated by using IAQMS-street v2.0.
Xi Chen, Ting Yang, Zifa Wang, Futing Wang, and Haibo Wang
Atmos. Meas. Tech., 16, 4289–4302, https://doi.org/10.5194/amt-16-4289-2023, https://doi.org/10.5194/amt-16-4289-2023, 2023
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Uncertainties remain great in the planetary boundary layer height (PBLH) determination from radiosonde, especially during the transition period of different PBL regimes. We combine seven existing methods along with statistical modification on gradient-based methods. We find that the ensemble method can eliminate the overestimation of PBLH and reduce the inconsistency between individual methods. The ensemble method improves the effectiveness of PBLH determination to 62.6 %.
Xiaodong Xie, Jianlin Hu, Momei Qin, Song Guo, Min Hu, Dongsheng Ji, Hongli Wang, Shengrong Lou, Cheng Huang, Chong Liu, Hongliang Zhang, Qi Ying, Hong Liao, and Yuanhang Zhang
Atmos. Chem. Phys., 23, 10563–10578, https://doi.org/10.5194/acp-23-10563-2023, https://doi.org/10.5194/acp-23-10563-2023, 2023
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The atmospheric age of particles reflects how long particles have been formed and suspended in the atmosphere, which is closely associated with the evolution processes of particles. An analysis of the atmospheric age of PM2.5 provides a unique perspective on the evolution processes of different PM2.5 components. The results also shed lights on how to design effective emission control actions under unfavorable meteorological conditions.
Junsu Gil, Meehye Lee, Jeonghwan Kim, Gangwoong Lee, Joonyoung Ahn, and Cheol-Hee Kim
Geosci. Model Dev., 16, 5251–5263, https://doi.org/10.5194/gmd-16-5251-2023, https://doi.org/10.5194/gmd-16-5251-2023, 2023
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In this study, the framework for calculating reactive nitrogen species using a deep neural network (RND) was developed. It works through simple Python codes and provides high-accuracy reactive nitrogen oxide data. In the first version (RNDv1.0), the model calculates the nitrous acid (HONO) in urban areas, which has an important role in producing O3 and fine aerosol.
Li Fang, Jianbing Jin, Arjo Segers, Hong Liao, Ke Li, Bufan Xu, Wei Han, Mijie Pang, and Hai Xiang Lin
Geosci. Model Dev., 16, 4867–4882, https://doi.org/10.5194/gmd-16-4867-2023, https://doi.org/10.5194/gmd-16-4867-2023, 2023
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Machine learning models have gained great popularity in air quality prediction. However, they are only available at air quality monitoring stations. In contrast, chemical transport models (CTM) provide predictions that are continuous in the 3D field. Owing to complex error sources, they are typically biased. In this study, we proposed a gridded prediction with high accuracy by fusing predictions from our regional feature selection machine learning prediction (RFSML v1.0) and a CTM prediction.
Zhenxin Liu, Yuanhao Chen, Yuhang Wang, Cheng Liu, Shuhua Liu, and Hong Liao
Geosci. Model Dev., 16, 4385–4403, https://doi.org/10.5194/gmd-16-4385-2023, https://doi.org/10.5194/gmd-16-4385-2023, 2023
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The heterogeneous layout of urban buildings leads to the complex wind field in and over the urban canopy. Large discrepancies between the observations and the current simulations result from misunderstanding the character of the wind field. The Inhomogeneous Wind Scheme in Urban Street (IWSUS) was developed to simulate the heterogeneity of the wind speed in a typical street and then improve the simulated energy budget in the lower atmospheric layer over the urban canopy.
Kai Cao, Qizhong Wu, Lingling Wang, Nan Wang, Huaqiong Cheng, Xiao Tang, Dongqing Li, and Lanning Wang
Geosci. Model Dev., 16, 4367–4383, https://doi.org/10.5194/gmd-16-4367-2023, https://doi.org/10.5194/gmd-16-4367-2023, 2023
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Offline performance experiment results show that the GPU-HADVPPM on a V100 GPU can achieve up to 1113.6 × speedups to its original version on an E5-2682 v4 CPU. A series of optimization measures are taken, and the CAMx-CUDA model improves the computing efficiency by 128.4 × on a single V100 GPU card. A parallel architecture with an MPI plus CUDA hybrid paradigm is presented, and it can achieve up to 4.5 × speedup when launching eight CPU cores and eight GPU cards.
Lichao Yang, Wansuo Duan, and Zifa Wang
Geosci. Model Dev., 16, 3827–3848, https://doi.org/10.5194/gmd-16-3827-2023, https://doi.org/10.5194/gmd-16-3827-2023, 2023
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An approach is proposed to refine a ground meteorological observation network to improve the PM2.5 forecasts in the Beijing–Tianjin–Hebei region. A cost-effective observation network is obtained and makes the relevant PM2.5 forecasts assimilate fewer observations but achieve the forecasting skill comparable to or higher than that obtained by assimilating all ground station observations, suggesting that many of the current ground stations can be greatly scattered to avoid much unnecessary work.
Jinming Feng, Meng Luo, Jun Wang, Yuan Qiu, Qizhong Wu, and Ke Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-867, https://doi.org/10.5194/egusphere-2023-867, 2023
Preprint withdrawn
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We modified the code of the Weather Research and Forecasting Model (WRF) v3.8.1 to include the forcing components more than the Greenhouse Gases and evaluate the impact of forcing configurations on the climate simulation results in China. It showed that different external forcing configurations in WRF could result in considerable impact on the annual temperature and precipitation trend, which was stronger than parameterization schemes but was weaker than spectral nudging.
Hang Liu, Xiaole Pan, Shandong Lei, Yuting Zhang, Aodong Du, Weijie Yao, Guiqian Tang, Tao Wang, Jinyuan Xin, Jie Li, Yele Sun, Junji Cao, and Zifa Wang
Atmos. Chem. Phys., 23, 7225–7239, https://doi.org/10.5194/acp-23-7225-2023, https://doi.org/10.5194/acp-23-7225-2023, 2023
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We provide the average vertical profiles of black carbon (BC) concentration, size distribution and coating thickness at different times of the day in an urban area based on 112 vertical profiles. In addition, it is found that BC in the residual layer generally has a thicker coating, higher absorption enhancement and hygroscopicity than on the surface. Such aged BC could enter into the boundary layer and influence the BC properties in the early morning.
Hannah J. Rubin, Joshua S. Fu, Frank Dentener, Rui Li, Kan Huang, and Hongbo Fu
Atmos. Chem. Phys., 23, 7091–7102, https://doi.org/10.5194/acp-23-7091-2023, https://doi.org/10.5194/acp-23-7091-2023, 2023
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We update the 2010 global deposition budget for nitrogen (N) and sulfur (S) with new regional wet deposition measurements, improving the ensemble results of 11 global chemistry transport models from HTAP II. Our study demonstrates that a global measurement–model fusion approach can substantially improve N and S deposition model estimates at a regional scale and represents a step forward toward the WMO goal of global fusion products for accurately mapping harmful air pollution.
Xingxia Kou, Zhen Peng, Meigen Zhang, Fei Hu, Xiao Han, Ziming Li, and Lili Lei
Atmos. Chem. Phys., 23, 6719–6741, https://doi.org/10.5194/acp-23-6719-2023, https://doi.org/10.5194/acp-23-6719-2023, 2023
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A CMAQ EnSRF-based regional inversion system was extended to resolve satellite retrievals into biogenic source–sink changes. The size of the assimilated biosphere sink in China inferred from GOSAT was −0.47 Pg C yr−1. The biosphere flux at the provincial scale was re-estimated following the refined description in the regional inversion.
Wen Lu, Bin Zhu, Shuqi Yan, Jie Li, and Zifa Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-1089, https://doi.org/10.5194/egusphere-2023-1089, 2023
Preprint archived
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Parameterized the minimum turbulent diffusivity (Kzmin) by sensible heat flux and latent heat flux and embedded it into the WRF-Chem model. New scheme improved the underestimation of turbulence diffusion underestimation and overestimation of surface PM2.5 under stable boundary layer simulation over eastern China. The physical relationship between Kzmin and two factors was discussed. Process analysis showed that vertical mixing is the key process to improve surface PM2.5 simulations.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Yele Sun, Pingqing Fu, Meng Gao, Huangjian Wu, Miaomiao Lu, Qian Wu, Shuyuan Huang, Wenxuan Sui, Jie Li, Xiaole Pan, Lin Wu, Hajime Akimoto, and Gregory R. Carmichael
Atmos. Chem. Phys., 23, 6217–6240, https://doi.org/10.5194/acp-23-6217-2023, https://doi.org/10.5194/acp-23-6217-2023, 2023
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A multi-air-pollutant inversion system has been developed in this study to estimate emission changes in China during COVID-19 lockdown. The results demonstrate that the lockdown is largely a nationwide road traffic control measure with NOx emissions decreasing by ~40 %. Emissions of other species only decreased by ~10 % due to smaller effects of lockdown on other sectors. Assessment results further indicate that the lockdown only had limited effects on the control of PM2.5 and O3 in China.
Pengwei Li, Yang Yang, Hailong Wang, Su Li, Ke Li, Pinya Wang, Baojie Li, and Hong Liao
Atmos. Chem. Phys., 23, 5403–5417, https://doi.org/10.5194/acp-23-5403-2023, https://doi.org/10.5194/acp-23-5403-2023, 2023
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We use a novel technique that can attribute O3 to precursors to investigate O3 changes in the United States during 1995–2019. We found that the US domestic energy and surface transportation emission reductions are primarily responsible for the O3 decrease in summer. In winter, factors such as nitrogen oxide emission reduction in the context of its inhibition of ozone production, increased aviation and shipping activities, and large-scale circulation changes contribute to the O3 increases.
Junhua Wang, Baozhu Ge, Xueshun Chen, Jie Li, Keding Lu, Yayuan Dong, Lei Kong, Zifa Wang, and Yuanhang Zhang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-22, https://doi.org/10.5194/gmd-2023-22, 2023
Revised manuscript not accepted
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We developed a quantitative decoupling analysis (QDA) method to quantify the contributions of emissions, meteorology, chemical reactions, and their nonlinear interactions on PM2.5. We found the effects of adverse meteorological conditions and the importance of nonlinear interactions. This method can provide valuable information for understanding of key factors to heavy pollution, but also help the modelers to find out the sources of uncertainties in numerical models.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
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Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Nadia K. Colombi, Daniel J. Jacob, Laura Hyesung Yang, Shixian Zhai, Viral Shah, Stuart K. Grange, Robert M. Yantosca, Soontae Kim, and Hong Liao
Atmos. Chem. Phys., 23, 4031–4044, https://doi.org/10.5194/acp-23-4031-2023, https://doi.org/10.5194/acp-23-4031-2023, 2023
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Surface ozone, detrimental to human and ecosystem health, is very high and increasing in South Korea. Using a global model of the atmosphere, we found that emissions from South Korea and China contribute equally to the high ozone observed. We found that in the absence of all anthropogenic emissions over East Asia, ozone is still very high, implying that the air quality standard in South Korea is not practically achievable unless this background external to East Asia can be decreased.
Chuan-Yao Lin, Wan-Chin Chen, Yi-Yun Chien, Charles C. K. Chou, Chian-Yi Liu, Helmut Ziereis, Hans Schlager, Eric Förster, Florian Obersteiner, Ovid O. Krüger, Bruna A. Holanda, Mira L. Pöhlker, Katharina Kaiser, Johannes Schneider, Birger Bohn, Klaus Pfeilsticker, Benjamin Weyland, Maria Dolores Andrés Hernández, and John P. Burrows
Atmos. Chem. Phys., 23, 2627–2647, https://doi.org/10.5194/acp-23-2627-2023, https://doi.org/10.5194/acp-23-2627-2023, 2023
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During the EMeRGe campaign in Asia, atmospheric pollutants were measured on board the HALO aircraft. The WRF-Chem model was employed to evaluate the biomass burning (BB) plume transported from Indochina and its impact on the downstream areas. The combination of BB aerosol enhancement with cloud water resulted in a reduction in incoming shortwave radiation at the surface in southern China and the East China Sea, which potentially has significant regional climate implications.
Shujun Zhong, Shuang Chen, Junjun Deng, Yanbing Fan, Qiang Zhang, Qiaorong Xie, Yulin Qi, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Jialei Zhu, Xin Wang, Di Liu, Xiaole Pan, Yele Sun, Zifa Wang, Yisheng Xu, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 2061–2077, https://doi.org/10.5194/acp-23-2061-2023, https://doi.org/10.5194/acp-23-2061-2023, 2023
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This study investigated the role of the secondary organic aerosol (SOA) loading on the molecular composition of wintertime urban aerosols by ultrahigh-resolution mass spectrometry. Results demonstrate that the SOA loading is an important factor associated with the oxidation degree, nitrate group content, and chemodiversity of nitrooxy–organosulfates. Our study also found that the hydrolysis of nitrooxy–organosulfates is a possible pathway for the formation of organosulfates.
Phuc Thi Minh Ha, Yugo Kanaya, Fumikazu Taketani, Maria Dolores Andrés Hernández, Benjamin Schreiner, Klaus Pfeilsticker, and Kengo Sudo
Geosci. Model Dev., 16, 927–960, https://doi.org/10.5194/gmd-16-927-2023, https://doi.org/10.5194/gmd-16-927-2023, 2023
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HONO affects tropospheric oxidizing capacity; thus, it is implemented into the chemistry–climate model CHASER. The model substantially underpredicts daytime HONO, while nitrate photolysis on surfaces can supplement the daytime HONO budget. Current HONO chemistry predicts reductions of 20.4 % for global tropospheric NOx, 40–67 % for OH, and 30–45 % for O3 in the summer North Pacific. In contrast, OH and O3 winter levels in China are greatly enhanced.
Mengyun Li, Yang Yang, Hailong Wang, Huimin Li, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 23, 1533–1544, https://doi.org/10.5194/acp-23-1533-2023, https://doi.org/10.5194/acp-23-1533-2023, 2023
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Using the GEOS-Chem model, the impact of the quasi-biennial oscillation (QBO) on summertime tropospheric O3 in China is investigated. In the warm phases of sea surface temperature anomalies over the eastern tropical Pacific, the QBO has a significant positive correlation with near-surface O3 concentrations over central China. The QBO impacts on O3 pollution in China are mainly a result of changing vertical transport of O3.
Huimin Li, Yang Yang, Jianbing Jin, Hailong Wang, Ke Li, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 23, 1131–1145, https://doi.org/10.5194/acp-23-1131-2023, https://doi.org/10.5194/acp-23-1131-2023, 2023
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Future climate change will aggravate ozone pollution in Asia, especially in high-forcing scenarios. Ozone pollution in China will expand from North China to South China and extend into the cold season in a warmer future. The emphasis of this work is to quantify the impacts of future climate change on O3 pollution in Asia, which is of great significance for future O3 pollution mitigation strategies.
Cynthia H. Whaley, Kathy S. Law, Jens Liengaard Hjorth, Henrik Skov, Stephen R. Arnold, Joakim Langner, Jakob Boyd Pernov, Garance Bergeron, Ilann Bourgeois, Jesper H. Christensen, Rong-You Chien, Makoto Deushi, Xinyi Dong, Peter Effertz, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Greg Huey, Ulas Im, Rigel Kivi, Louis Marelle, Tatsuo Onishi, Naga Oshima, Irina Petropavlovskikh, Jeff Peischl, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Tom Ryerson, Ragnhild Skeie, Sverre Solberg, Manu A. Thomas, Chelsea Thompson, Kostas Tsigaridis, Svetlana Tsyro, Steven T. Turnock, Knut von Salzen, and David W. Tarasick
Atmos. Chem. Phys., 23, 637–661, https://doi.org/10.5194/acp-23-637-2023, https://doi.org/10.5194/acp-23-637-2023, 2023
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This study summarizes recent research on ozone in the Arctic, a sensitive and rapidly warming region. We find that the seasonal cycles of near-surface atmospheric ozone are variable depending on whether they are near the coast, inland, or at high altitude. Several global model simulations were evaluated, and we found that because models lack some of the ozone chemistry that is important for the coastal Arctic locations, they do not accurately simulate ozone there.
Yongkang Wu, Weihua Chen, Yingchang You, Qianqian Xie, Shiguo Jia, and Xuemei Wang
Atmos. Chem. Phys., 23, 453–469, https://doi.org/10.5194/acp-23-453-2023, https://doi.org/10.5194/acp-23-453-2023, 2023
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Relying on observed and simulated data, we determine the spatiotemporal characteristics of nocturnal O3 increase (NOI) events in the Pearl River Delta region during 2006–2019. Low-level jets and convective storms are the main meteorological processes causing NOI. Daytime O3 is another essential influencing factor. More importantly, a more prominent role of meteorological processes in NOI has been demonstrated. Our study highlights the important role of meteorology in nocturnal O3 pollution.
Huibin Dai, Hong Liao, Ke Li, Xu Yue, Yang Yang, Jia Zhu, Jianbing Jin, Baojie Li, and Xingwen Jiang
Atmos. Chem. Phys., 23, 23–39, https://doi.org/10.5194/acp-23-23-2023, https://doi.org/10.5194/acp-23-23-2023, 2023
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We apply the 3-D global chemical transport model (GEOS-Chem) to simulate co-polluted days by O3 and PM2.5 (O3–PM2.5PDs) in Beijing–Tianjin–Hebei in 2013–2020 and investigate the chemical and physical characteristics of O3–PM2.5PDs by composited analyses of such days that are captured by both the observations and the model. We report for the first time the unique features in vertical distributions of aerosols during O3–PM2.5PDs and the physical and chemical characteristics of O3–PM2.5PDs.
Haichao Wang, Bin Yuan, E Zheng, Xiaoxiao Zhang, Jie Wang, Keding Lu, Chenshuo Ye, Lei Yang, Shan Huang, Weiwei Hu, Suxia Yang, Yuwen Peng, Jipeng Qi, Sihang Wang, Xianjun He, Yubin Chen, Tiange Li, Wenjie Wang, Yibo Huangfu, Xiaobing Li, Mingfu Cai, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 14837–14858, https://doi.org/10.5194/acp-22-14837-2022, https://doi.org/10.5194/acp-22-14837-2022, 2022
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We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large variation in the level, formation, and atmospheric impacts of ClNO2 was found in different air masses. ClNO2 formation was limited by the particulate chloride (Cl−) and aerosol surface area. Our results reveal that Cl− originated from various anthropogenic emissions rather than sea sources and show minor contribution to the O3 pollution and photochemistry.
Tian Tian, Lijing Cheng, Gongjie Wang, John Abraham, Wangxu Wei, Shihe Ren, Jiang Zhu, Junqiang Song, and Hongze Leng
Earth Syst. Sci. Data, 14, 5037–5060, https://doi.org/10.5194/essd-14-5037-2022, https://doi.org/10.5194/essd-14-5037-2022, 2022
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A high-resolution gridded dataset is crucial for understanding ocean processes at various spatiotemporal scales. Here we used a machine learning approach and successfully reconstructed a high-resolution (0.25° × 0.25°) ocean subsurface (1–2000 m) salinity dataset for the period 1993–2018 (monthly) by merging in situ salinity profile observations with high-resolution satellite remote-sensing data. This new product could be useful in various applications in ocean and climate fields.
Yang Yang, Liangying Zeng, Hailong Wang, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 22, 14489–14502, https://doi.org/10.5194/acp-22-14489-2022, https://doi.org/10.5194/acp-22-14489-2022, 2022
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Using an aerosol–climate model, dust pollution in China affected by different spatial and temporal types of El Niño are examined. Both eastern and central Pacific El Niño and short-duration El Niño increase winter dust concentrations over northern China, while long-duration El Niño decreases concentrations. Only long-duration El Niño events can significantly affect dust over China in the following spring. This study has profound implications for air pollution control and dust storm prediction.
Guo Li, Hang Su, Meng Li, Uwe Kuhn, Guangjie Zheng, Lei Han, Fengxia Bao, Ulrich Pöschl, and Yafang Cheng
Atmos. Meas. Tech., 15, 6433–6446, https://doi.org/10.5194/amt-15-6433-2022, https://doi.org/10.5194/amt-15-6433-2022, 2022
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A large fraction of previous work using dynamic flow chambers was to quantify gas exchange in terms of flux or deposition/emission rate. Here, we extended the usage of this technique to examine uptake kinetics on sample surfaces. The good performance of the chamber system was validated. This technique can be further used for liquid samples and real atmospheric aerosol samples without complicated coating procedures, which complements the existing techniques in atmospheric kinetic studies.
Juseon Bak, Eun-Ji Song, Hyo-Jung Lee, Xiong Liu, Ja-Ho Koo, Joowan Kim, Wonbae Jeon, Jae-Hwan Kim, and Cheol-Hee Kim
Atmos. Chem. Phys., 22, 14177–14187, https://doi.org/10.5194/acp-22-14177-2022, https://doi.org/10.5194/acp-22-14177-2022, 2022
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Our study investigates the temporal variations of ozone profiles at Pohang in the Korean Peninsula from multiple ozone products. We discuss the quantitative relationships between daily surface measurements and key meteorological variables, different seasonality of ozone between the troposphere and stratosphere, and interannual changes in the lower tropospheric ozone, linked by the weather pattern driven by the East Asian summer monsoon.
Li Fang, Jianbing Jin, Arjo Segers, Hai Xiang Lin, Mijie Pang, Cong Xiao, Tuo Deng, and Hong Liao
Geosci. Model Dev., 15, 7791–7807, https://doi.org/10.5194/gmd-15-7791-2022, https://doi.org/10.5194/gmd-15-7791-2022, 2022
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This study proposes a regional feature selection-based machine learning system to predict short-term air quality in China. The system has a tool that can figure out the importance of input data for better prediction. It provides large-scale air quality prediction that exhibits improved interpretability, fewer training costs, and higher accuracy compared with a standard machine learning system. It can act as an early warning for citizens and reduce exposure to PM2.5 and other air pollutants.
Futing Wang, Ting Yang, Zifa Wang, Haibo Wang, Xi Chen, Yele Sun, Jianjun Li, Guigang Tang, and Wenxuan Chai
Atmos. Meas. Tech., 15, 6127–6144, https://doi.org/10.5194/amt-15-6127-2022, https://doi.org/10.5194/amt-15-6127-2022, 2022
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We develop a new algorithm to get the vertical mass concentration profiles of fine aerosol components based on the synergy of ground-based remote sensing for the first time. The comparisons with in situ observations and chemistry transport models validate the performance of the algorithm. Uncertainties caused by input parameters are also assessed in this paper. We expected that the algorithm can provide a new idea for lidar inversion and promote the development of aerosol component profiles.
Zhenqi Xu, Wei Feng, Yicheng Wang, Haoran Ye, Yuhang Wang, Hong Liao, and Mingjie Xie
Atmos. Chem. Phys., 22, 13739–13752, https://doi.org/10.5194/acp-22-13739-2022, https://doi.org/10.5194/acp-22-13739-2022, 2022
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This work uses a solvent (DMF) that can efficiently dissolve low-volatility OC to examine BrC absorption and sources, which will benefit future investigations on the physicochemical properties of large organic molecules. The study results also shed light on potential sources for methanol-insoluble OC. These results highlight the importance of testing different solvents to investigate the structures and light absorption of low-volatility BrC.
Hossain Mohammed Syedul Hoque, Kengo Sudo, Hitoshi Irie, Alessandro Damiani, Manish Naja, and Al Mashroor Fatmi
Atmos. Chem. Phys., 22, 12559–12589, https://doi.org/10.5194/acp-22-12559-2022, https://doi.org/10.5194/acp-22-12559-2022, 2022
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Nitrogen dioxide (NO2) and formaldehyde (HCHO) are essential trace graces regulating tropospheric ozone chemistry. These trace constituents are measured using an optical passive remote sensing technique. In addition, NO2 and HCHO are simulated with a computer model and evaluated against the observations. Such evaluations are essential to assess model uncertainties and improve their predictability. The results yielded good agreement between the two datasets with some discrepancies.
Chenguang Tian, Xu Yue, Jun Zhu, Hong Liao, Yang Yang, Yadong Lei, Xinyi Zhou, Hao Zhou, Yimian Ma, and Yang Cao
Atmos. Chem. Phys., 22, 12353–12366, https://doi.org/10.5194/acp-22-12353-2022, https://doi.org/10.5194/acp-22-12353-2022, 2022
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We quantify the impacts of fire aerosols on climate through direct, indirect, and albedo effects. In atmosphere-only simulations, we find global fire aerosols cause surface cooling and rainfall inhibition over many land regions. These fast atmospheric perturbations further lead to a reduction in regional leaf area index and lightning activities. By considering the feedback of fire aerosols on humidity, lightning, and leaf area index, we predict a slight reduction in fire emissions.
Mengying Li, Shaocai Yu, Xue Chen, Zhen Li, Yibo Zhang, Zhe Song, Weiping Liu, Pengfei Li, Xiaoye Zhang, Meigen Zhang, Yele Sun, Zirui Liu, Caiping Sun, Jingkun Jiang, Shuxiao Wang, Benjamin N. Murphy, Kiran Alapaty, Rohit Mathur, Daniel Rosenfeld, and John H. Seinfeld
Atmos. Chem. Phys., 22, 11845–11866, https://doi.org/10.5194/acp-22-11845-2022, https://doi.org/10.5194/acp-22-11845-2022, 2022
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This study constructed an emission inventory of condensable particulate matter (CPM) in China with a focus on organic aerosols (OAs), based on collected CPM emission information. The results show that OA emissions are enhanced twofold for the years 2014 and 2017 after the inclusion of CPM in the new inventory. Sensitivity cases demonstrated the significant contributions of CPM emissions from stationary combustion and mobile sources to primary, secondary, and total OA concentrations.
Lichao Yang, Wansuo Duan, Zifa Wang, and Wenyi Yang
Atmos. Chem. Phys., 22, 11429–11453, https://doi.org/10.5194/acp-22-11429-2022, https://doi.org/10.5194/acp-22-11429-2022, 2022
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The initial meteorological state has a great impact on PM2.5 forecasts. Assimilating additional observations is an effective way to improve the accuracy of the initial meteorological state. Here we used an advanced optimization approach to identify where we should preferentially place the meteorological observations associated with PM2.5 forecasts in the Beijing–Tianjin–Hebei region of China. We provide evidence that the target observation strategy is effective for improving PM2.5 forecasts.
Lim-Seok Chang, Donghee Kim, Hyunkee Hong, Deok-Rae Kim, Jeong-Ah Yu, Kwangyul Lee, Hanlim Lee, Daewon Kim, Jinkyu Hong, Hyun-Young Jo, and Cheol-Hee Kim
Atmos. Chem. Phys., 22, 10703–10720, https://doi.org/10.5194/acp-22-10703-2022, https://doi.org/10.5194/acp-22-10703-2022, 2022
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Our study explored the synergy of combined column and surface measurements during GMAP (GEMS Map of Air Pollution) campaign. It has several points to note for vertical distribution analysis. Particularly under prevailing local wind meteorological conditions, Pandora-based vertical structures sometimes showed negative correlations between column and surface measurements. Vertical analysis should be done carefully in some local meteorological conditions when employing either surface or columns.
Xiao-Bing Li, Bin Yuan, Sihang Wang, Chunlin Wang, Jing Lan, Zhijie Liu, Yongxin Song, Xianjun He, Yibo Huangfu, Chenglei Pei, Peng Cheng, Suxia Yang, Jipeng Qi, Caihong Wu, Shan Huang, Yingchang You, Ming Chang, Huadan Zheng, Wenda Yang, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, https://doi.org/10.5194/acp-22-10567-2022, 2022
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High-time-resolution measurements of volatile organic compounds (VOCs) were made using an online mass spectrometer at a 600 m tall tower in urban region. Compositions, temporal variations, and sources of VOCs were quantitatively investigated in this study. We find that VOC measurements in urban regions aloft could better characterize source characteristics of anthropogenic emissions. Our results could provide important implications in making future strategies for control of VOCs.
Xiaoxi Zhao, Kan Huang, Joshua S. Fu, and Sabur F. Abdullaev
Atmos. Chem. Phys., 22, 10389–10407, https://doi.org/10.5194/acp-22-10389-2022, https://doi.org/10.5194/acp-22-10389-2022, 2022
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Long-range transport of Asian dust to the Arctic was considered an important source of Arctic air pollution. Different transport routes to the Arctic had divergent effects on the evolution of aerosol properties. Depositions of long-range-transported dust particles can reduce the Arctic surface albedo considerably. This study implied that the ubiquitous long-transport dust from China exerted considerable aerosol indirect effects on the Arctic and may have potential biogeochemical significance.
Zhiqiang Zhang, Yele Sun, Chun Chen, Bo You, Aodong Du, Weiqi Xu, Yan Li, Zhijie Li, Lu Lei, Wei Zhou, Jiaxing Sun, Yanmei Qiu, Lianfang Wei, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 22, 10409–10423, https://doi.org/10.5194/acp-22-10409-2022, https://doi.org/10.5194/acp-22-10409-2022, 2022
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We present a comprehensive characterization of water-soluble organic aerosol and the first mass spectral characterization of water-insoluble organic aerosol in the cold season in Beijing by integrating online and offline aerosol mass spectrometer measurements. WSOA comprised dominantly secondary OA and showed large changes during the transition season from autumn to winter. WIOA was characterized by prominent hydrocarbon ions series, low oxidation states, and significant day–night differences.
Yanfeng He, Hossain Mohammed Syedul Hoque, and Kengo Sudo
Geosci. Model Dev., 15, 5627–5650, https://doi.org/10.5194/gmd-15-5627-2022, https://doi.org/10.5194/gmd-15-5627-2022, 2022
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Lightning-produced NOx (LNOx) is a major source of NOx. Hence, it is crucial to improve the prediction accuracy of lightning and LNOx in chemical climate models. By modifying existing lightning schemes and testing them in the chemical climate model CHASER, we improved the prediction accuracy of lightning in CHASER. Different lightning schemes respond very differently under global warming, which indicates further research is needed considering the reproducibility of long-term trends of lightning.
Qi Zhang, Shiguo Jia, Weihua Chen, Jingying Mao, Liming Yang, Padmaja Krishnan, Sayantan Sarkar, Min Shao, and Xuemei Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-394, https://doi.org/10.5194/acp-2022-394, 2022
Revised manuscript not accepted
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We use satellite data in the establishment of methylamines marine biological emission (MBE) inventory for the first time, which considers effects of actual marine environment on methylamines emission fluxes. MBE fluxes of monomethylamine and trimethylamines can be comparable with or even higher than that of terrestrial anthropogenic emissions , while for dimethylamines, the ocean acts as a sink. Wind and Chlorophyll-a were potentially the most important factors affecting MBE fluxes.
Shijie Cui, Dan Dan Huang, Yangzhou Wu, Junfeng Wang, Fuzhen Shen, Jiukun Xian, Yunjiang Zhang, Hongli Wang, Cheng Huang, Hong Liao, and Xinlei Ge
Atmos. Chem. Phys., 22, 8073–8096, https://doi.org/10.5194/acp-22-8073-2022, https://doi.org/10.5194/acp-22-8073-2022, 2022
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Refractory black carbon (rBC) aerosols are important to air quality and climate change. rBC can mix with many other species, which can significantly change its properties and impacts. We used a specific set of techniques to exclusively characterize rBC-containing (rBCc) particles in Shanghai. We elucidated their composition, sources and size distributions and factors that affect their properties. Our findings are very valuable for advancing the understanding of BC and controlling BC pollution.
Jiaxing Sun, Yele Sun, Conghui Xie, Weiqi Xu, Chun Chen, Zhe Wang, Lei Li, Xubing Du, Fugui Huang, Yan Li, Zhijie Li, Xiaole Pan, Nan Ma, Wanyun Xu, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 22, 7619–7630, https://doi.org/10.5194/acp-22-7619-2022, https://doi.org/10.5194/acp-22-7619-2022, 2022
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We analyzed the chemical composition and mixing state of BC-containing particles at urban and rural sites in winter in the North China Plain and evaluated their impact on light absorption enhancement. BC was dominantly mixed with organic carbon, nitrate, and sulfate, and the mixing state evolved significantly as a function of relative humidity (RH) at both sites. The absorption enhancement depended strongly on coated secondary inorganic aerosol and was up to ~1.3–1.4 during aging processes.
Chenhong Zhou, Fan Wang, Yike Guo, Cheng Liu, Dongsheng Ji, Yuesi Wang, Xiaobin Xu, Xiao Lu, Yan Wang, Gregory Carmichael, and Meng Gao
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2022-187, https://doi.org/10.5194/essd-2022-187, 2022
Manuscript not accepted for further review
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We develop an eXtreme Gradient Boosting (XGBoost) model integrating high-resolution meteorological data, satellite retrievals of trace gases, etc. to provide reconstructed daily ground-level O3 over 2005–2021 in China. It can facilitate climatological, ecological, and health research. The dataset is freely available at Zenodo (https://zenodo.org/record/6507706#.Yo8hKujP13g; Zhou, 2022).
Jiyuan Gao, Yang Yang, Hailong Wang, Pinya Wang, Huimin Li, Mengyun Li, Lili Ren, Xu Yue, and Hong Liao
Atmos. Chem. Phys., 22, 7131–7142, https://doi.org/10.5194/acp-22-7131-2022, https://doi.org/10.5194/acp-22-7131-2022, 2022
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China has been implementing a sequence of policies for clean air since the year 2013. The aerosol decline produced a 0.09 ± 0.10°C warming during 2013–2017 estimated in this study, and the increase in ozone in the lower troposphere during this time period accelerated the warming, leading to a total 0.16 ± 0.15°C temperature increase in eastern China. Residential emission reductions led to a cooling effect because of a substantial decrease in light-absorbing aerosols.
Zixuan Jia, Ruth M. Doherty, Carlos Ordóñez, Chaofan Li, Oliver Wild, Shipra Jain, and Xiao Tang
Atmos. Chem. Phys., 22, 6471–6487, https://doi.org/10.5194/acp-22-6471-2022, https://doi.org/10.5194/acp-22-6471-2022, 2022
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This study investigates the modulation of daily PM2.5 over three major populated regions in China by regional meteorology and large-scale circulation during winter. These results demonstrate the benefits of considering the large-scale circulation for air quality studies. The novel circulation indices proposed here can explain a considerable fraction of the day-to-day variability of PM2.5 and can be combined with regional meteorology to improve our capability to predict the variability of PM2.5.
Junjun Deng, Hao Ma, Xinfeng Wang, Shujun Zhong, Zhimin Zhang, Jialei Zhu, Yanbing Fan, Wei Hu, Libin Wu, Xiaodong Li, Lujie Ren, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 22, 6449–6470, https://doi.org/10.5194/acp-22-6449-2022, https://doi.org/10.5194/acp-22-6449-2022, 2022
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Light-absorbing brown carbon (BrC) plays an important role in climate change and atmospheric chemistry. Here we investigated the seasonal and diurnal variations in water-soluble BrC in PM2.5 in the megacity Tianjin in coastal China. Results of the source apportionments from the combination with organic molecular compositions and optical properties of water-soluble BrC reveal a large contribution from primary bioaerosol particles to BrC in the urban atmosphere.
Jianbing Jin, Mijie Pang, Arjo Segers, Wei Han, Li Fang, Baojie Li, Haochuan Feng, Hai Xiang Lin, and Hong Liao
Atmos. Chem. Phys., 22, 6393–6410, https://doi.org/10.5194/acp-22-6393-2022, https://doi.org/10.5194/acp-22-6393-2022, 2022
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Super dust storms reappeared in East Asia last spring after being absent for one and a half decades. Accurate simulation of such super sandstorms is valuable, but challenging due to imperfect emissions. In this study, the emissions of these dust storms are estimated by assimilating multiple observations. The results reveal that emissions originated from both China and Mongolia. However, for northern China, long-distance transport from Mongolia contributes much more dust than Chinese deserts.
Haibo Wang, Ting Yang, Zifa Wang, Jianjun Li, Wenxuan Chai, Guigang Tang, Lei Kong, and Xueshun Chen
Geosci. Model Dev., 15, 3555–3585, https://doi.org/10.5194/gmd-15-3555-2022, https://doi.org/10.5194/gmd-15-3555-2022, 2022
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In this paper, we develop an online data coupled assimilation system (NAQPMS-PDAF) with the Eulerian atmospheric chemistry-transport model. NAQPMS-PDAF allows efficient use of large computational resources. The application and performance of the system are investigated by assimilating 1 month of vertical aerosol observations. The results show that NAQPMS-PDAF can significantly improve the performance of aerosol vertical structure simulation and reduce the uncertainty to a large extent.
Cynthia H. Whaley, Rashed Mahmood, Knut von Salzen, Barbara Winter, Sabine Eckhardt, Stephen Arnold, Stephen Beagley, Silvia Becagli, Rong-You Chien, Jesper Christensen, Sujay Manish Damani, Xinyi Dong, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Fabio Giardi, Wanmin Gong, Jens Liengaard Hjorth, Lin Huang, Ulas Im, Yugo Kanaya, Srinath Krishnan, Zbigniew Klimont, Thomas Kühn, Joakim Langner, Kathy S. Law, Louis Marelle, Andreas Massling, Dirk Olivié, Tatsuo Onishi, Naga Oshima, Yiran Peng, David A. Plummer, Olga Popovicheva, Luca Pozzoli, Jean-Christophe Raut, Maria Sand, Laura N. Saunders, Julia Schmale, Sangeeta Sharma, Ragnhild Bieltvedt Skeie, Henrik Skov, Fumikazu Taketani, Manu A. Thomas, Rita Traversi, Kostas Tsigaridis, Svetlana Tsyro, Steven Turnock, Vito Vitale, Kaley A. Walker, Minqi Wang, Duncan Watson-Parris, and Tahya Weiss-Gibbons
Atmos. Chem. Phys., 22, 5775–5828, https://doi.org/10.5194/acp-22-5775-2022, https://doi.org/10.5194/acp-22-5775-2022, 2022
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Air pollutants, like ozone and soot, play a role in both global warming and air quality. Atmospheric models are often used to provide information to policy makers about current and future conditions under different emissions scenarios. In order to have confidence in those simulations, in this study we compare simulated air pollution from 18 state-of-the-art atmospheric models to measured air pollution in order to assess how well the models perform.
Haoran Zhang, Nan Li, Keqin Tang, Hong Liao, Chong Shi, Cheng Huang, Hongli Wang, Song Guo, Min Hu, Xinlei Ge, Mindong Chen, Zhenxin Liu, Huan Yu, and Jianlin Hu
Atmos. Chem. Phys., 22, 5495–5514, https://doi.org/10.5194/acp-22-5495-2022, https://doi.org/10.5194/acp-22-5495-2022, 2022
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We developed a new algorithm with low economic/technique costs to identify primary and secondary components of PM2.5. Our model was shown to be reliable by comparison with different observation datasets. We systematically explored the patterns and changes in the secondary PM2.5 pollution in China at large spatial and time scales. We believe that this method is a promising tool for efficiently estimating primary and secondary PM2.5, and has huge potential for future PM mitigation.
Pinya Wang, Yang Yang, Huimin Li, Lei Chen, Ruijun Dang, Daokai Xue, Baojie Li, Jianping Tang, L. Ruby Leung, and Hong Liao
Atmos. Chem. Phys., 22, 4705–4719, https://doi.org/10.5194/acp-22-4705-2022, https://doi.org/10.5194/acp-22-4705-2022, 2022
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China is now suffering from both severe ozone (O3) pollution and heat events. We highlight that North China Plain is the hot spot of the co-occurrences of extremes in O3 and high temperatures in China. Such coupled extremes exhibit an increasing trend during 2014–2019 and will continue to increase until the middle of this century. And the coupled extremes impose more severe health impacts to human than O3 pollution occurring alone because of elevated O3 levels and temperatures.
Suxia Yang, Bin Yuan, Yuwen Peng, Shan Huang, Wei Chen, Weiwei Hu, Chenglei Pei, Jun Zhou, David D. Parrish, Wenjie Wang, Xianjun He, Chunlei Cheng, Xiao-Bing Li, Xiaoyun Yang, Yu Song, Haichao Wang, Jipeng Qi, Baolin Wang, Chen Wang, Chaomin Wang, Zelong Wang, Tiange Li, E Zheng, Sihang Wang, Caihong Wu, Mingfu Cai, Chenshuo Ye, Wei Song, Peng Cheng, Duohong Chen, Xinming Wang, Zhanyi Zhang, Xuemei Wang, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4539–4556, https://doi.org/10.5194/acp-22-4539-2022, https://doi.org/10.5194/acp-22-4539-2022, 2022
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We use a model constrained using observations to study the formation of nitrate aerosol in and downwind of a representative megacity. We found different contributions of various chemical reactions to ground-level nitrate concentrations between urban and suburban regions. We also show that controlling VOC emissions are effective for decreasing nitrate formation in both urban and regional environments, although VOCs are not direct precursors of nitrate aerosol.
Hao Yang, Lei Chen, Hong Liao, Jia Zhu, Wenjie Wang, and Xin Li
Atmos. Chem. Phys., 22, 4101–4116, https://doi.org/10.5194/acp-22-4101-2022, https://doi.org/10.5194/acp-22-4101-2022, 2022
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Aerosols can influence O3 through aerosol–radiation interactions, including aerosol–photolysis interaction (API) and aerosol–radiation feedback (ARF). The weakened photolysis rates and changed meteorological conditions reduce surface-layer O3 concentrations by up to 9.3–11.4 ppb, with API and ARF contributing 74.6 %–90.0 % and 10.0 %–25.4 % of the O3 decrease in three episodes, respectively, which indicates that API is the dominant way for O3 reduction related to aerosol–radiation interactions.
Takashi Sekiya, Kazuyuki Miyazaki, Henk Eskes, Kengo Sudo, Masayuki Takigawa, and Yugo Kanaya
Atmos. Meas. Tech., 15, 1703–1728, https://doi.org/10.5194/amt-15-1703-2022, https://doi.org/10.5194/amt-15-1703-2022, 2022
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This study gives a systematic comparison of TROPOMI version 1.2 and OMI QA4ECV tropospheric NO2 column through global chemical data assimilation (DA) integration for April–May 2018. DA performance is controlled by measurement sensitivities, retrieval errors, and coverage. Due to reduced errors in TROPOMI, agreements against assimilated and independent observations were improved by TROPOMI DA compared to OMI DA. These results demonstrate that TROPOMI DA improves global analyses of NO2 and ozone.
Drew C. Pendergrass, Shixian Zhai, Jhoon Kim, Ja-Ho Koo, Seoyoung Lee, Minah Bae, Soontae Kim, Hong Liao, and Daniel J. Jacob
Atmos. Meas. Tech., 15, 1075–1091, https://doi.org/10.5194/amt-15-1075-2022, https://doi.org/10.5194/amt-15-1075-2022, 2022
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This paper uses a machine learning algorithm to infer high-resolution maps of particulate air quality in eastern China, Japan, and the Korean peninsula, using data from a geostationary satellite along with meteorology. We then perform an extensive evaluation of this inferred air quality and use it to diagnose trends in the region. We hope this paper and the associated data will be valuable to other scientists interested in epidemiology, air quality, remote sensing, and machine learning.
Donglin Chen, Hong Liao, Yang Yang, Lei Chen, Delong Zhao, and Deping Ding
Atmos. Chem. Phys., 22, 1825–1844, https://doi.org/10.5194/acp-22-1825-2022, https://doi.org/10.5194/acp-22-1825-2022, 2022
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The black carbon (BC) vertical profile plays a critical role in BC–meteorology interaction, which also influences PM2.5 concentrations. More BC mass was assigned into high altitudes (above 1000 m) in the model, which resulted in a stronger cooling effect near the surface, a larger temperature inversion below 421 m, more reductions in PBLH, and a larger increase in near-surface PM2.5 in the daytime caused by the direct radiative effect of BC.
Qian Ma, Kaicun Wang, Yanyi He, Liangyuan Su, Qizhong Wu, Han Liu, and Youren Zhang
Earth Syst. Sci. Data, 14, 463–477, https://doi.org/10.5194/essd-14-463-2022, https://doi.org/10.5194/essd-14-463-2022, 2022
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Surface incident solar radiation plays a key role in atmospheric circulation, the water cycle, and ecological equilibrium on Earth. A homogenized century-long surface incident solar radiation dataset was obtained over Japan.
Ming Chang, Jiachen Cao, Qi Zhang, Weihua Chen, Guotong Wu, Liping Wu, Weiwen Wang, and Xuemei Wang
Geosci. Model Dev., 15, 787–801, https://doi.org/10.5194/gmd-15-787-2022, https://doi.org/10.5194/gmd-15-787-2022, 2022
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Despite the importance of nitrogen deposition, its simulation is still insufficiently represented in current atmospheric chemistry models. In this study, the improvement of the canopy stomatal resistance mechanism and the nitrogen-limiting schemes in Noah-MP-WDDM v1.42 give new options for simulating nitrogen dry deposition velocity. This study finds that the combined BN-23 mechanism agrees better with the observed NO2 dry deposition velocity, with the mean bias reduced by 50.1 %.
Fei Liu, Zhining Tao, Steffen Beirle, Joanna Joiner, Yasuko Yoshida, Steven J. Smith, K. Emma Knowland, and Thomas Wagner
Atmos. Chem. Phys., 22, 1333–1349, https://doi.org/10.5194/acp-22-1333-2022, https://doi.org/10.5194/acp-22-1333-2022, 2022
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In this work, we present a novel method to infer NOx emissions and lifetimes based on tropospheric NO2 observations together with reanalysis wind fields for cities located in polluted backgrounds. We evaluate the accuracy of the method using synthetic NO2 observations derived from a high-resolution model simulation. Our work provides an estimate for uncertainties in satellite-derived emissions inferred from chemical transport model (CTM)-independent approaches.
Mizuo Kajino, Akira Watanabe, Masahide Ishizuka, Kazuyuki Kita, Yuji Zaizen, Takeshi Kinase, Rikuya Hirai, Kakeru Konnai, Akane Saya, Kazuki Iwaoka, Yoshitaka Shiroma, Hidenao Hasegawa, Naofumi Akata, Masahiro Hosoda, Shinji Tokonami, and Yasuhito Igarashi
Atmos. Chem. Phys., 22, 783–803, https://doi.org/10.5194/acp-22-783-2022, https://doi.org/10.5194/acp-22-783-2022, 2022
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Using a numerical model and observations of surface concentration and depositions, the current study provides quantitative assessments of resuspension, transport, and deposition of radio-Cs in eastern Japan in 2013, which was once deposited to the ground surface after the Fukushima nuclear accident. The areal mean resuspension rate of radio-Cs from the ground to the air is estimated as 0.96 % per year, which is equivalent to 1–10 % of the decreasing rate of the ambient gamma dose in Fukushima.
Akira Watanabe, Mizuo Kajino, Kazuhiko Ninomiya, Yoshitaka Nagahashi, and Atsushi Shinohara
Atmos. Chem. Phys., 22, 675–692, https://doi.org/10.5194/acp-22-675-2022, https://doi.org/10.5194/acp-22-675-2022, 2022
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This study summarizes continuous measurements of surface air concentrations and deposition of radiocesium in Fukushima city over 8 years after the Fukushima nuclear accident. The concentration in the city was high in winter and low in summer (inverse of the forest area). The decreasing trends were much faster in the earlier stage, probably because dissolved cesium discharged faster from the local environment. Biotite might play a key role in circulation of particulate cesium in Fukushima city.
Jiaxing Sun, Zhe Wang, Wei Zhou, Conghui Xie, Cheng Wu, Chun Chen, Tingting Han, Qingqing Wang, Zhijie Li, Jie Li, Pingqing Fu, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 22, 561–575, https://doi.org/10.5194/acp-22-561-2022, https://doi.org/10.5194/acp-22-561-2022, 2022
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We analyzed 9-year measurements of BC and aerosol optical properties from 2012 to 2020 in Beijing, China. Our results showed large reductions in BC and light extinction coefficient due to the Clean Air Action Plan. As a response, both SSA and mass extinction efficiency (MEE) showed considerable increases, demonstrating a future challenge in visibility improvement. The primary and secondary BrC was also separated and quantified, and the changes in radiative forcing of BC and BrC were estimated.
Qian Ye, Jie Li, Xueshun Chen, Huansheng Chen, Wenyi Yang, Huiyun Du, Xiaole Pan, Xiao Tang, Wei Wang, Lili Zhu, Jianjun Li, Zhe Wang, and Zifa Wang
Geosci. Model Dev., 14, 7573–7604, https://doi.org/10.5194/gmd-14-7573-2021, https://doi.org/10.5194/gmd-14-7573-2021, 2021
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We developed a global tropospheric atmospheric chemistry source–receptor model. This model can quantify the contributions of multiple air pollutants from various source regions in one simulation without introducing the nonlinear error of atmospheric chemistry. The S-R relationships of PM2.5 and O3 from a global high-resolution (0.5° × 0.5°) simulation were given and compared with previous studies. This model will be useful for creating a link between the scientific community and policymakers.
Yulu Qiu, Zhiqiang Ma, Ke Li, Mengyu Huang, Jiujiang Sheng, Ping Tian, Jia Zhu, Weiwei Pu, Yingxiao Tang, Tingting Han, Huaigang Zhou, and Hong Liao
Atmos. Chem. Phys., 21, 17995–18010, https://doi.org/10.5194/acp-21-17995-2021, https://doi.org/10.5194/acp-21-17995-2021, 2021
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Photochemical pollution over the North China Plain (NCP) is attracting much concern. Our observations at a rural site in the NCP identified high peroxyacetyl nitrate (PAN) concentrations, even on cold days. Increased acetaldehyde concentration and hydroxyl radical production rates drive fast PAN formation. Moreover, our study emphasizes the importance of formaldehyde photolysis in PAN formation and calls for implementing strict volatile organic compound controls after summer over the NCP.
Yuting Zhang, Hang Liu, Shandong Lei, Wanyun Xu, Yu Tian, Weijie Yao, Xiaoyong Liu, Qi Liao, Jie Li, Chun Chen, Yele Sun, Pingqing Fu, Jinyuan Xin, Junji Cao, Xiaole Pan, and Zifa Wang
Atmos. Chem. Phys., 21, 17631–17648, https://doi.org/10.5194/acp-21-17631-2021, https://doi.org/10.5194/acp-21-17631-2021, 2021
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In this study, the authors used a single-particle soot photometer (SP2) to characterize the particle size, mixing state, and optical properties of black carbon aerosols in rural areas of the North China Plain in winter. Relatively warm and high-RH environments (RH > 50 %, −4° < T < 4 °) were more favorable to rBC aging than dry and cold environments (RH < 60 %, T < −8°). The paper emphasizes the importance of meteorological parameters in the mixing state of black carbon.
Jianping Guo, Jian Zhang, Kun Yang, Hong Liao, Shaodong Zhang, Kaiming Huang, Yanmin Lv, Jia Shao, Tao Yu, Bing Tong, Jian Li, Tianning Su, Steve H. L. Yim, Ad Stoffelen, Panmao Zhai, and Xiaofeng Xu
Atmos. Chem. Phys., 21, 17079–17097, https://doi.org/10.5194/acp-21-17079-2021, https://doi.org/10.5194/acp-21-17079-2021, 2021
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The planetary boundary layer (PBL) is the lowest part of the troposphere, and boundary layer height (BLH) is the depth of the PBL and is of critical importance to the dispersion of air pollution. The study presents the first near-global BLH climatology by using high-resolution (5-10 m) radiosonde measurements. The variations in BLH exhibit large spatial and temporal dependence, with a peak at 17:00 local solar time. The most promising reanalysis product is ERA-5 in terms of modeling BLH.
Chuan-Yao Lin, Yang-Fan Sheng, Wan-Chin Chen, Charles C. K. Chou, Yi-Yun Chien, and Wen-Mei Chen
Atmos. Chem. Phys., 21, 16893–16910, https://doi.org/10.5194/acp-21-16893-2021, https://doi.org/10.5194/acp-21-16893-2021, 2021
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Taiwan and Hong Kong experience air quality deterioration as typhoons approach. However, the mechanism of the formation of poor air quality may differ and still not be well documented in Taiwan. The interaction between easterly typhoon circulation and Taiwan’s Central Mountain Range resulted in a lee side vortex formation. Simulation results indicated that the lee vortex and land–sea breeze, as well as the boundary layer development, were the key mechanisms.
Shixian Zhai, Daniel J. Jacob, Jared F. Brewer, Ke Li, Jonathan M. Moch, Jhoon Kim, Seoyoung Lee, Hyunkwang Lim, Hyun Chul Lee, Su Keun Kuk, Rokjin J. Park, Jaein I. Jeong, Xuan Wang, Pengfei Liu, Gan Luo, Fangqun Yu, Jun Meng, Randall V. Martin, Katherine R. Travis, Johnathan W. Hair, Bruce E. Anderson, Jack E. Dibb, Jose L. Jimenez, Pedro Campuzano-Jost, Benjamin A. Nault, Jung-Hun Woo, Younha Kim, Qiang Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 16775–16791, https://doi.org/10.5194/acp-21-16775-2021, https://doi.org/10.5194/acp-21-16775-2021, 2021
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Geostationary satellite aerosol optical depth (AOD) has tremendous potential for monitoring surface fine particulate matter (PM2.5). Our study explored the physical relationship between AOD and PM2.5 by integrating data from surface networks, aircraft, and satellites with the GEOS-Chem chemical transport model. We quantitatively showed that accurate simulation of aerosol size distributions, boundary layer depths, relative humidity, coarse particles, and diurnal variations in PM2.5 are essential.
Baojie Li, Lei Chen, Weishou Shen, Jianbing Jin, Teng Wang, Pinya Wang, Yang Yang, and Hong Liao
Atmos. Chem. Phys., 21, 15883–15900, https://doi.org/10.5194/acp-21-15883-2021, https://doi.org/10.5194/acp-21-15883-2021, 2021
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This study focused on improving fertilizer-application-related NH3 emission inventories. We comprehensively evaluated the dates and times of fertilizer application to the major crops in China, improved the spatial allocation methods for NH3 emissions from croplands with different rice types, and established a NH3 emission inventory for mainland China in 2016. The inventory showed a higher level of accuracy than other inventories based on evaluation using the WRF-Chem and observation data.
Hossain M. S. Hoque, Kengo Sudo, Hitoshi Irie, Alessandro Damiani, and Al Mashroor Fatmi
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-815, https://doi.org/10.5194/acp-2021-815, 2021
Revised manuscript not accepted
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Nitrogen dioxide (NO2) and formaldehyde (HCHO) profiles, retrieved from remote sensing observations, are used to evaluate the global chemistry transport model CHASER. Overall, CHASER has demonstrated good skills in reproducing the seasonal climatology of NO2 and HCHO on a local scale at sites in South and East Asia. Around mountainous terrains, the model performs better on a regional scale. The improved spatial resolution of CHASER can likely reduce the observed discrepancies in the datasets.
Lili Ren, Yang Yang, Hailong Wang, Pinya Wang, Lei Chen, Jia Zhu, and Hong Liao
Atmos. Chem. Phys., 21, 15431–15445, https://doi.org/10.5194/acp-21-15431-2021, https://doi.org/10.5194/acp-21-15431-2021, 2021
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Due to the COVID-19 pandemic, human activities were strictly restricted in China. Even though anthropogenic aerosol emissions largely decreased, haze events still occurred. Our results shows that PM2.5 over the North China Plain is largely contributed by local sources. For other regions in China, PM2.5 is largely contributed from nonlocal sources. As emission reduction is a future goal, aerosol long-range transport and unfavorable meteorology are increasingly important to air quality.
Quan Liu, Dantong Liu, Yangzhou Wu, Kai Bi, Wenkang Gao, Ping Tian, Delong Zhao, Siyuan Li, Chenjie Yu, Guiqian Tang, Yunfei Wu, Kang Hu, Shuo Ding, Qian Gao, Fei Wang, Shaofei Kong, Hui He, Mengyu Huang, and Deping Ding
Atmos. Chem. Phys., 21, 14749–14760, https://doi.org/10.5194/acp-21-14749-2021, https://doi.org/10.5194/acp-21-14749-2021, 2021
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Through simultaneous online measurements of detailed aerosol compositions at both surface and surface-influenced mountain sites, the evolution of aerosol composition during daytime vertical transport was investigated. The results show that, from surface to the top of the planetary boundary layer, the oxidation state of organic aerosol had been significantly enhanced due to evaporation and further oxidation of these evaporated gases.
Syuichi Itahashi, Rohit Mathur, Christian Hogrefe, Sergey L. Napelenok, and Yang Zhang
Geosci. Model Dev., 14, 5751–5768, https://doi.org/10.5194/gmd-14-5751-2021, https://doi.org/10.5194/gmd-14-5751-2021, 2021
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The Community Multiscale Air Quality (CMAQ) modeling system extended for hemispheric-scale applications (H-CMAQ) incorporated the satellite-constrained degassing SO2 emissions from 50 volcanos across the Northern Hemisphere. The impact on tropospheric sulfate aerosol (SO42−) is assessed for 2010. Although the considered volcanic emissions occurred at or below the middle of free troposphere (500 hPa), SO42− enhancements of more than 10 % were detected up to the top of free troposphere (250 hPa).
Ziwei Mo, Ru Cui, Bin Yuan, Huihua Cai, Brian C. McDonald, Meng Li, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, https://doi.org/10.5194/acp-21-13655-2021, 2021
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There is a lack of detailed understanding of NMVOC emissions from the use of volatile chemical products (VCPs) in China. This study used a mass balance method to compile a long-term emission inventory for solvent use (including coatings, adhesives, inks, pesticides, cleaners and personal care products) in China during 2000–2017. The striking growth and recent trend of solvent use NMVOC emissions can give important implications for air quality modeling and NMVOC control strategies in China.
Jianbing Jin, Arjo Segers, Hai Xiang Lin, Bas Henzing, Xiaohui Wang, Arnold Heemink, and Hong Liao
Geosci. Model Dev., 14, 5607–5622, https://doi.org/10.5194/gmd-14-5607-2021, https://doi.org/10.5194/gmd-14-5607-2021, 2021
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When discussing the accuracy of a dust forecast, the shape and position of the plume as well as the intensity are key elements. The position forecast determines which locations will be affected, while the intensity only describes the actual dust level. A dust forecast with position misfit directly results in incorrect timing profiles of dust loads. In this paper, an image-morphing-based data assimilation is designed for realigning a simulated dust plume to correct for the position error.
Yun Fat Lam, Chi Chiu Cheung, Xuguo Zhang, Joshua S. Fu, and Jimmy Chi Hung Fung
Atmos. Chem. Phys., 21, 12895–12908, https://doi.org/10.5194/acp-21-12895-2021, https://doi.org/10.5194/acp-21-12895-2021, 2021
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In recent years, air pollution forecasting has become an important municipal service of the government. In this study, a new spatial allocation method based on satellite remote sensing and GIS techniques was developed to address the spatial deficiency of industrial source emissions in China, providing a substantial improvement on NO2 and PM2.5 forecast for the Pearl River Delta/Greater Bay Area.
Hong Ren, Wei Hu, Lianfang Wei, Siyao Yue, Jian Zhao, Linjie Li, Libin Wu, Wanyu Zhao, Lujie Ren, Mingjie Kang, Qiaorong Xie, Sihui Su, Xiaole Pan, Zifa Wang, Yele Sun, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 21, 12949–12963, https://doi.org/10.5194/acp-21-12949-2021, https://doi.org/10.5194/acp-21-12949-2021, 2021
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This study presents vertical profiles of biogenic and anthropogenic secondary organic aerosols (SOAs) in the urban boundary layer based on a 325 m tower in Beijing in late summer. The increases in the isoprene and toluene SOAs with height were found to be more related to regional transport, whereas the decrease in those from monoterpenes and sesquiterpene were more subject to local emissions. Such complicated vertical distributions of SOA should be considered in future modeling work.
Junhua Wang, Baozhu Ge, Xueshun Chen, Jie Li, Keding Lu, Yayuan Dong, Lei Kong, Zifa Wang, and Yuanhang Zhang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2021-259, https://doi.org/10.5194/gmd-2021-259, 2021
Revised manuscript not accepted
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This paper developed a novel quantitative decoupling analysis (QDA) method to quantify the contributions of emission, meteorology, chemical reaction, and their nonlinear interactions on PM2.5 and applied it to a pollution episode in Beijing. This method can provides the researchers and policy makers with valuable information for understanding of key factors to heavy pollution, but also help the modelers to find out the sources of uncertainties among numerical models.
Maggie Chel-Gee Ooi, Ming-Tung Chuang, Joshua S. Fu, Steven S. Kong, Wei-Syun Huang, Sheng-Hsiang Wang, Sittichai Pimonsree, Andy Chan, Shantanu Kumar Pani, and Neng-Huei Lin
Atmos. Chem. Phys., 21, 12521–12541, https://doi.org/10.5194/acp-21-12521-2021, https://doi.org/10.5194/acp-21-12521-2021, 2021
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There is very limited local modeling effort in Southeast Asia, where haze is an annually recurring threat. In this work, the accuracy of haze prediction is improved not only at the burning source but also at the downwind site in northern Southeast Asia to highlight the influence of trans-boundary haze, which is often regional. The burning haze is carried to the populated west of Taiwan via several mechanisms, with the most severe conditions related to the boreal winter pressure system.
Zhiyong Wu, Leiming Zhang, John T. Walker, Paul A. Makar, Judith A. Perlinger, and Xuemei Wang
Geosci. Model Dev., 14, 5093–5105, https://doi.org/10.5194/gmd-14-5093-2021, https://doi.org/10.5194/gmd-14-5093-2021, 2021
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A community dry deposition algorithm for modeling the gaseous dry deposition process in chemistry transport models was extended to include an additional 12 oxidized volatile organic compounds and hydrogen cyanide based on their physicochemical properties and was then evaluated using field flux measurements over a mixed forest. This study provides a useful tool that is needed in chemistry transport models with increasing complexity for simulating an important atmospheric process.
Chao Qin, Yafeng Gou, Yuhang Wang, Yuhao Mao, Hong Liao, Qin'geng Wang, and Mingjie Xie
Atmos. Chem. Phys., 21, 12141–12153, https://doi.org/10.5194/acp-21-12141-2021, https://doi.org/10.5194/acp-21-12141-2021, 2021
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In this study, we found that the aqueous solution in aerosols is an important absorbing phase for gaseous polyols in the atmosphere, indicating that the dissolution in aerosol liquid water should not be ignored when investigating gas–particle partitioning of water-soluble organics. The exponential increase in effective partitioning coefficients of polyol tracers with sulfate ion concentrations could be attributed to organic–inorganic interactions in the particle phase.
Zhaohui Chen, Parvadha Suntharalingam, Andrew J. Watson, Ute Schuster, Jiang Zhu, and Ning Zeng
Biogeosciences, 18, 4549–4570, https://doi.org/10.5194/bg-18-4549-2021, https://doi.org/10.5194/bg-18-4549-2021, 2021
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As the global temperature continues to increase, carbon dioxide (CO2) is a major driver of this global warming. The increased CO2 is mainly caused by emissions from fossil fuel use and land use. At the same time, the ocean is a significant sink in the carbon cycle. The North Atlantic is a critical ocean region in reducing CO2 concentration. We estimate the CO2 uptake in this region based on a carbon inverse system and atmospheric CO2 observations.
Yadong Lei, Xu Yue, Hong Liao, Lin Zhang, Yang Yang, Hao Zhou, Chenguang Tian, Cheng Gong, Yimian Ma, Lan Gao, and Yang Cao
Atmos. Chem. Phys., 21, 11531–11543, https://doi.org/10.5194/acp-21-11531-2021, https://doi.org/10.5194/acp-21-11531-2021, 2021
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We present the first estimate of ozone enhancement by fire emissions through ozone–vegetation interactions using a fully coupled chemistry–vegetation model (GC-YIBs). In fire-prone areas, fire-induced ozone causes a positive feedback to surface ozone mainly because of the inhibition effects on stomatal conductance.
Qiaorong Xie, Sihui Su, Jing Chen, Yuqing Dai, Siyao Yue, Hang Su, Haijie Tong, Wanyu Zhao, Lujie Ren, Yisheng Xu, Dong Cao, Ying Li, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, Guibin Jiang, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 21, 11453–11465, https://doi.org/10.5194/acp-21-11453-2021, https://doi.org/10.5194/acp-21-11453-2021, 2021
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This study investigated the role of nighttime chemistry during Chinese New Year's Eve that enhances the formation of nitrooxy organosulfates in the aerosol phase. Results show that anthropogenic precursors, together with biogenic ones, considerably contribute to the formation of low-volatility nitrooxy OSs. Our study provides detailed molecular composition of firework-related aerosols, which gives new insights into the physicochemical properties and potential health effects of urban aerosols.
Meng Gao, Yang Yang, Hong Liao, Bin Zhu, Yuxuan Zhang, Zirui Liu, Xiao Lu, Chen Wang, Qiming Zhou, Yuesi Wang, Qiang Zhang, Gregory R. Carmichael, and Jianlin Hu
Atmos. Chem. Phys., 21, 11405–11421, https://doi.org/10.5194/acp-21-11405-2021, https://doi.org/10.5194/acp-21-11405-2021, 2021
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Light absorption and radiative forcing of black carbon (BC) is influenced by both BC itself and its interactions with other aerosol chemical compositions. In this study, we used the online coupled WRF-Chem model to examine how emission control measures during the Asian-Pacific Economic Cooperation (APEC) conference affect the mixing state and light absorption of BC and the associated implications for BC-PBL interactions.
Luolin Wu, Jian Hang, Xuemei Wang, Min Shao, and Cheng Gong
Geosci. Model Dev., 14, 4655–4681, https://doi.org/10.5194/gmd-14-4655-2021, https://doi.org/10.5194/gmd-14-4655-2021, 2021
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In order to investigate street-scale flow and air quality, this study has developed APFoam 1.0 to examine the reactive pollutant formation and dispersion in the urban area. The model has been validated and shows good agreement with wind tunnel experimental data. Model sensitivity cases reveal that vehicle emissions, background concentrations, and wind conditions are the key factors affecting the photochemical reaction process.
Benjamin A. Nault, Duseong S. Jo, Brian C. McDonald, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Jason C. Schroder, James Allan, Donald R. Blake, Manjula R. Canagaratna, Hugh Coe, Matthew M. Coggon, Peter F. DeCarlo, Glenn S. Diskin, Rachel Dunmore, Frank Flocke, Alan Fried, Jessica B. Gilman, Georgios Gkatzelis, Jacqui F. Hamilton, Thomas F. Hanisco, Patrick L. Hayes, Daven K. Henze, Alma Hodzic, James Hopkins, Min Hu, L. Greggory Huey, B. Thomas Jobson, William C. Kuster, Alastair Lewis, Meng Li, Jin Liao, M. Omar Nawaz, Ilana B. Pollack, Jeffrey Peischl, Bernhard Rappenglück, Claire E. Reeves, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Min Shao, Jacob M. Sommers, James Walega, Carsten Warneke, Petter Weibring, Glenn M. Wolfe, Dominique E. Young, Bin Yuan, Qiang Zhang, Joost A. de Gouw, and Jose L. Jimenez
Atmos. Chem. Phys., 21, 11201–11224, https://doi.org/10.5194/acp-21-11201-2021, https://doi.org/10.5194/acp-21-11201-2021, 2021
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Secondary organic aerosol (SOA) is an important aspect of poor air quality for urban regions around the world, where a large fraction of the population lives. However, there is still large uncertainty in predicting SOA in urban regions. Here, we used data from 11 urban campaigns and show that the variability in SOA production in these regions is predictable and is explained by key emissions. These results are used to estimate the premature mortality associated with SOA in urban regions.
Ying Wei, Xueshun Chen, Huansheng Chen, Yele Sun, Wenyi Yang, Huiyun Du, Qizhong Wu, Dan Chen, Xiujuan Zhao, Jie Li, and Zifa Wang
Geosci. Model Dev., 14, 4411–4428, https://doi.org/10.5194/gmd-14-4411-2021, https://doi.org/10.5194/gmd-14-4411-2021, 2021
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The sub-grid particle formation (SGPF) in plumes plays an important role in air pollution and climate. We coupled an SGPF scheme to a chemical transport model with an aerosol microphysics module and applied it to investigate the SGPF impact over China. The scheme clearly improved the model performance in simulating aerosol components and particle number at typical sites influenced by point sources. The results indicate the significant effects of SGPF on aerosol particles in industrial areas.
Liangying Zeng, Yang Yang, Hailong Wang, Jing Wang, Jing Li, Lili Ren, Huimin Li, Yang Zhou, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 21, 10745–10761, https://doi.org/10.5194/acp-21-10745-2021, https://doi.org/10.5194/acp-21-10745-2021, 2021
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Using an aerosol–climate model, the impacts of El Niño with different durations on aerosols in China are examined. The modulation on aerosol concentrations and haze days by short-duration El Niño events is 2–3 times more than that by long-duration El Niño events in China. The frequency of short-duration El Niño has been increasing significantly in recent decades, suggesting that El Niño events have exerted increasingly intense modulation on aerosol pollution in China over the past few decades.
Phuc T. M. Ha, Ryoki Matsuda, Yugo Kanaya, Fumikazu Taketani, and Kengo Sudo
Geosci. Model Dev., 14, 3813–3841, https://doi.org/10.5194/gmd-14-3813-2021, https://doi.org/10.5194/gmd-14-3813-2021, 2021
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Policies to mitigate air pollution require an understanding of tropospheric oxidizing capacity, which is controlled by mechanisms including heterogeneous processes on aerosols and clouds. This study uses a chemistry–climate model CHASER (MIROC) to explore the heterogeneous effects in the troposphere for -2.96 % O3, -2.19 % NOx, +3.28 % CO, and +5.91 % CH4 lifetime. Besides, these processes affect polluted areas and remote areas and can bring challenges to pollution reduction efforts.
Baozhu Ge, Danhui Xu, Oliver Wild, Xuefeng Yao, Junhua Wang, Xueshun Chen, Qixin Tan, Xiaole Pan, and Zifa Wang
Atmos. Chem. Phys., 21, 9441–9454, https://doi.org/10.5194/acp-21-9441-2021, https://doi.org/10.5194/acp-21-9441-2021, 2021
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In this study, an improved sequential sampling method is developed and implemented to estimate the contribution of below-cloud and in-cloud wet deposition over four years of measurements in Beijing. We find that the contribution of below-cloud scavenging for Ca2+, SO4 2–, and NH4+ decreases from above 50 % in 2014 to below 40 % in 2017. This suggests that the Action Plan has mitigated particulate matter pollution in the surface layer and hence decreased scavenging due to the washout process.
Xueshun Chen, Fangqun Yu, Wenyi Yang, Yele Sun, Huansheng Chen, Wei Du, Jian Zhao, Ying Wei, Lianfang Wei, Huiyun Du, Zhe Wang, Qizhong Wu, Jie Li, Junling An, and Zifa Wang
Atmos. Chem. Phys., 21, 9343–9366, https://doi.org/10.5194/acp-21-9343-2021, https://doi.org/10.5194/acp-21-9343-2021, 2021
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Atmospheric aerosol particles have significant climate and health effects that depend on aerosol size, composition, and mixing state. A new global-regional nested aerosol model with an advanced particle microphysics module and a volatility basis set organic aerosol module was developed to simulate aerosol microphysical processes. Simulations strongly suggest the important role of anthropogenic organic species in particle formation over the areas influenced by anthropogenic sources.
Zhaobin Sun, Xiujuan Zhao, Ziming Li, Guiqian Tang, and Shiguang Miao
Atmos. Chem. Phys., 21, 8863–8882, https://doi.org/10.5194/acp-21-8863-2021, https://doi.org/10.5194/acp-21-8863-2021, 2021
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Different weather types will shape significantly different structures of the pollution boundary layer. The findings of this study allow us to understand the inherent difference among heavy pollution boundary layers; in addition, they reveal the formation mechanism of haze pollution from an integrated synoptic-scale and boundary layer structure perspective.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Zhe Wang, Junichi Kurokawa, Jiani Tan, Kan Huang, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 21, 8709–8734, https://doi.org/10.5194/acp-21-8709-2021, https://doi.org/10.5194/acp-21-8709-2021, 2021
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This study presents the detailed analysis of acid deposition over southeast Asia based on the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Simulated wet deposition is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The difficulties of models to capture observations are related to the model performance on precipitation. The precipitation-adjusted approach was applied, and the distribution of wet deposition was successfully revised.
Na Zhao, Xinyi Dong, Kan Huang, Joshua S. Fu, Marianne Tronstad Lund, Kengo Sudo, Daven Henze, Tom Kucsera, Yun Fat Lam, Mian Chin, and Simone Tilmes
Atmos. Chem. Phys., 21, 8637–8654, https://doi.org/10.5194/acp-21-8637-2021, https://doi.org/10.5194/acp-21-8637-2021, 2021
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Black carbon acts as a strong climate forcer, especially in vulnerable pristine regions such as the Arctic. This work utilizes ensemble modeling results from the task force Hemispheric Transport of Air Pollution Phase 2 to investigate the responses of Arctic black carbon and surface temperature to various source emission reductions. East Asia contributed the most to Arctic black carbon. The response of Arctic temperature to black carbon was substantially more sensitive than the global average.
Chenshuo Ye, Bin Yuan, Yi Lin, Zelong Wang, Weiwei Hu, Tiange Li, Wei Chen, Caihong Wu, Chaomin Wang, Shan Huang, Jipeng Qi, Baolin Wang, Chen Wang, Wei Song, Xinming Wang, E Zheng, Jordan E. Krechmer, Penglin Ye, Zhanyi Zhang, Xuemei Wang, Douglas R. Worsnop, and Min Shao
Atmos. Chem. Phys., 21, 8455–8478, https://doi.org/10.5194/acp-21-8455-2021, https://doi.org/10.5194/acp-21-8455-2021, 2021
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We performed measurements of gaseous and particulate organic compounds using a state-of-the-art online mass spectrometer in urban air. Using the dataset, we provide a holistic chemical characterization of oxygenated organic compounds in the polluted urban atmosphere, which can serve as a reference for the future field measurements of organic compounds in cities.
Mizuo Kajino, Makoto Deushi, Tsuyoshi Thomas Sekiyama, Naga Oshima, Keiya Yumimoto, Taichu Yasumichi Tanaka, Joseph Ching, Akihiro Hashimoto, Tetsuya Yamamoto, Masaaki Ikegami, Akane Kamada, Makoto Miyashita, Yayoi Inomata, Shin-ichiro Shima, Pradeep Khatri, Atsushi Shimizu, Hitoshi Irie, Kouji Adachi, Yuji Zaizen, Yasuhito Igarashi, Hiromasa Ueda, Takashi Maki, and Masao Mikami
Geosci. Model Dev., 14, 2235–2264, https://doi.org/10.5194/gmd-14-2235-2021, https://doi.org/10.5194/gmd-14-2235-2021, 2021
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This study compares performance of aerosol representation methods of the Japan Meteorological Agency's regional-scale nonhydrostatic meteorology–chemistry model (NHM-Chem). It indicates separate treatment of sea salt and dust in coarse mode and that of light-absorptive and non-absorptive particles in fine mode could provide accurate assessments on aerosol feedback processes.
Yunyan Jiang, Jinyuan Xin, Ying Wang, Guiqian Tang, Yuxin Zhao, Danjie Jia, Dandan Zhao, Meng Wang, Lindong Dai, Lili Wang, Tianxue Wen, and Fangkun Wu
Atmos. Chem. Phys., 21, 6111–6128, https://doi.org/10.5194/acp-21-6111-2021, https://doi.org/10.5194/acp-21-6111-2021, 2021
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Multiscale-circulation coupling affects pollution by changing the planetary boundary layer (PBL) structure. The multilayer PBL under cyclonic circulation has no diurnal variation; the temperature inversion and zero-speed zone can reach 600–900 m with strong mountain winds. The monolayer PBL under southwestern circulation can reach 2000 m; the inversion is lower than nocturnal PBL (400 m) with strong ambient winds. The zonal winds' vertical shear produces the inversion under western circulation.
Dandan Zhao, Jinyuan Xin, Chongshui Gong, Jiannong Quan, Yuesi Wang, Guiqian Tang, Yongxiang Ma, Lindong Dai, Xiaoyan Wu, Guangjing Liu, and Yongjing Ma
Atmos. Chem. Phys., 21, 5739–5753, https://doi.org/10.5194/acp-21-5739-2021, https://doi.org/10.5194/acp-21-5739-2021, 2021
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The influence of aerosol radiative forcing (ARF) on the boundary layer structure is nonlinear. The threshold of the modification effects of ARF on the boundary layer structure was determined for the first time, highlighting that once ARF exceeded a certain value, the boundary layer would quickly stabilize and aggravate air pollution. This could provide useful information for relevant atmospheric-environment improvement measures and policies.
Weiqi Xu, Chun Chen, Yanmei Qiu, Ying Li, Zhiqiang Zhang, Eleni Karnezi, Spyros N. Pandis, Conghui Xie, Zhijie Li, Jiaxing Sun, Nan Ma, Wanyun Xu, Pingqing Fu, Zifa Wang, Jiang Zhu, Douglas R. Worsnop, Nga Lee Ng, and Yele Sun
Atmos. Chem. Phys., 21, 5463–5476, https://doi.org/10.5194/acp-21-5463-2021, https://doi.org/10.5194/acp-21-5463-2021, 2021
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Here aerosol volatility and viscosity at a rural site (Gucheng) and an urban site (Beijing) in the North China Plain (NCP) were investigated in summer and winter. Our results showed that organic aerosol (OA) in winter in the NCP is more volatile than that in summer due to enhanced primary emissions from coal combustion and biomass burning. We also found that OA existed mainly as a solid in winter in Beijing but as semisolids in Beijing in summer and Gucheng in winter.
Santosh Kumar Verma, Kimitaka Kawamura, Fei Yang, Pingqing Fu, Yugo Kanaya, and Zifa Wang
Atmos. Chem. Phys., 21, 4959–4978, https://doi.org/10.5194/acp-21-4959-2021, https://doi.org/10.5194/acp-21-4959-2021, 2021
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We studied aerosol samples collected in autumn 2007 with day and night intervals in a rural site of Mangshan, north of Beijing, for sugar compounds (SCs) that are abundant organic aerosol components and can influence the air quality and climate. We found higher concentrations of biomass burning (BB) products at nighttime than daytime, whereas pollen tracers and other SCs showed an opposite diurnal trend, because this site is meteorologically characterized by a mountain/valley breeze.
Hui Wang, Qizhong Wu, Alex B. Guenther, Xiaochun Yang, Lanning Wang, Tang Xiao, Jie Li, Jinming Feng, Qi Xu, and Huaqiong Cheng
Atmos. Chem. Phys., 21, 4825–4848, https://doi.org/10.5194/acp-21-4825-2021, https://doi.org/10.5194/acp-21-4825-2021, 2021
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We assessed the influence of the greening trend on BVOC emission in China. The comparison among different scenarios showed that vegetation changes resulting from land cover management are the main driver of BVOC emission change in China. Climate variability contributed significantly to interannual variations but not much to the long-term trend during the study period.
Jiayun Li, Liming Cao, Wenkang Gao, Lingyan He, Yingchao Yan, Yuexin He, Yuepeng Pan, Dongsheng Ji, Zirui Liu, and Yuesi Wang
Atmos. Chem. Phys., 21, 4521–4539, https://doi.org/10.5194/acp-21-4521-2021, https://doi.org/10.5194/acp-21-4521-2021, 2021
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For the first time, we investigated the highly time-resolved chemical characterization, sources and evolution of atmospheric submicron aerosols at a regional background site in the North China Plain (NCP) using an Aerodyne high-resolution time-of-flight aerosol mass spectrometer and evaluated the seasonal differentials of photochemical and aqueous-phase processing on SOA composition and oxidation degree of OA. The results will help to understand air pollution in the NCP on a regional scale.
Tabish Umar Ansari, Oliver Wild, Edmund Ryan, Ying Chen, Jie Li, and Zifa Wang
Atmos. Chem. Phys., 21, 4471–4485, https://doi.org/10.5194/acp-21-4471-2021, https://doi.org/10.5194/acp-21-4471-2021, 2021
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We use novel modelling approaches to quantify the lingering effects of 1 d local and regional emission controls on subsequent days, the effects of longer continuous emission controls of individual sectors over different regions, and the effects of combined emission controls of multiple sectors and regions on air quality in Beijing under varying weather conditions to inform precise short-term emission control policies for avoiding heavy haze pollution in Beijing.
Tie Dai, Yueming Cheng, Daisuke Goto, Yingruo Li, Xiao Tang, Guangyu Shi, and Teruyuki Nakajima
Atmos. Chem. Phys., 21, 4357–4379, https://doi.org/10.5194/acp-21-4357-2021, https://doi.org/10.5194/acp-21-4357-2021, 2021
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The anthropogenic emission of sulfur dioxide (SO2) over China has significantly declined as a consequence of the clean air actions. We have developed a new emission inversion system to dynamically update the SO2 emission grid by grid over China by assimilating ground-based SO2 observations. The inverted SO2 emission over China in November 2016 on average had declined by 49.4 % since 2010, which is well in agreement with the bottom-up estimation of 48.0 %.
Behrooz Roozitalab, Gregory R. Carmichael, and Sarath K. Guttikunda
Atmos. Chem. Phys., 21, 2837–2860, https://doi.org/10.5194/acp-21-2837-2021, https://doi.org/10.5194/acp-21-2837-2021, 2021
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We used air quality modeling to study an extreme pollution episode in November 2017 in India. We found both local and regional emissions contribute to high pollution levels. The extreme pollution values were the result of agricultural fires in the northwest of India. Ozone should be considered in future air quality management strategies.
Ling Huang, Yonghui Zhu, Hehe Zhai, Shuhui Xue, Tianyi Zhu, Yun Shao, Ziyi Liu, Chris Emery, Greg Yarwood, Yangjun Wang, Joshua Fu, Kun Zhang, and Li Li
Atmos. Chem. Phys., 21, 2725–2743, https://doi.org/10.5194/acp-21-2725-2021, https://doi.org/10.5194/acp-21-2725-2021, 2021
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Numerical air quality models (AQMs) are being applied extensively to address diverse scientific and regulatory compliance associated with deteriorating air quality in China. For any AQM applications, model performance evaluation is a critical step that guarantees the robustness and reliability of the baseline modeling results and subsequent applications. We provided benchmarks for model performance evaluation of AQM applications in China to demonstrate model robustness.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Jianjun Li, Huangjian Wu, Qizhong Wu, Huansheng Chen, Lili Zhu, Wei Wang, Bing Liu, Qian Wang, Duohong Chen, Yuepeng Pan, Tao Song, Fei Li, Haitao Zheng, Guanglin Jia, Miaomiao Lu, Lin Wu, and Gregory R. Carmichael
Earth Syst. Sci. Data, 13, 529–570, https://doi.org/10.5194/essd-13-529-2021, https://doi.org/10.5194/essd-13-529-2021, 2021
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China's air pollution has changed substantially since 2013. Here we have developed a 6-year-long high-resolution air quality reanalysis dataset over China from 2013 to 2018 to illustrate such changes and to provide a basic dataset for relevant studies. Surface fields of PM2.5, PM10, SO2, NO2, CO, and O3 concentrations are provided, and the evaluation results indicate that the reanalysis dataset has excellent performance in reproducing the magnitude and variation of air pollution in China.
Zhongjing Jiang, Jing Li, Xiao Lu, Cheng Gong, Lin Zhang, and Hong Liao
Atmos. Chem. Phys., 21, 2601–2613, https://doi.org/10.5194/acp-21-2601-2021, https://doi.org/10.5194/acp-21-2601-2021, 2021
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This study demonstrates that the intensity of the western Pacific subtropical high (WPSH), a major synoptic pattern in the northern Pacific during summer, can induce a dipole change in surface ozone pollution over eastern China. Ozone concentration increases in the north and decreases in the south during the strong WPSH phase, and vice versa. The change in chemical processes associated with the WPSH change plays a decisive role, whereas the natural emission of ozone precursors accounts for ~ 30 %.
Youhua Tang, Huisheng Bian, Zhining Tao, Luke D. Oman, Daniel Tong, Pius Lee, Patrick C. Campbell, Barry Baker, Cheng-Hsuan Lu, Li Pan, Jun Wang, Jeffery McQueen, and Ivanka Stajner
Atmos. Chem. Phys., 21, 2527–2550, https://doi.org/10.5194/acp-21-2527-2021, https://doi.org/10.5194/acp-21-2527-2021, 2021
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Chemical lateral boundary condition (CLBC) impact is essential for regional air quality prediction during intrusion events. We present a model mapping Goddard Earth Observing System (GEOS) to Community Multi-scale Air Quality (CMAQ) CB05–AERO6 (Carbon Bond 5; version 6 of the aerosol module) species. Influence depends on distance from the inflow boundary and species and their regional characteristics. We use aerosol optical thickness to derive CLBCs, achieving reasonable prediction.
Jens Redemann, Robert Wood, Paquita Zuidema, Sarah J. Doherty, Bernadette Luna, Samuel E. LeBlanc, Michael S. Diamond, Yohei Shinozuka, Ian Y. Chang, Rei Ueyama, Leonhard Pfister, Ju-Mee Ryoo, Amie N. Dobracki, Arlindo M. da Silva, Karla M. Longo, Meloë S. Kacenelenbogen, Connor J. Flynn, Kristina Pistone, Nichola M. Knox, Stuart J. Piketh, James M. Haywood, Paola Formenti, Marc Mallet, Philip Stier, Andrew S. Ackerman, Susanne E. Bauer, Ann M. Fridlind, Gregory R. Carmichael, Pablo E. Saide, Gonzalo A. Ferrada, Steven G. Howell, Steffen Freitag, Brian Cairns, Brent N. Holben, Kirk D. Knobelspiesse, Simone Tanelli, Tristan S. L'Ecuyer, Andrew M. Dzambo, Ousmane O. Sy, Greg M. McFarquhar, Michael R. Poellot, Siddhant Gupta, Joseph R. O'Brien, Athanasios Nenes, Mary Kacarab, Jenny P. S. Wong, Jennifer D. Small-Griswold, Kenneth L. Thornhill, David Noone, James R. Podolske, K. Sebastian Schmidt, Peter Pilewskie, Hong Chen, Sabrina P. Cochrane, Arthur J. Sedlacek, Timothy J. Lang, Eric Stith, Michal Segal-Rozenhaimer, Richard A. Ferrare, Sharon P. Burton, Chris A. Hostetler, David J. Diner, Felix C. Seidel, Steven E. Platnick, Jeffrey S. Myers, Kerry G. Meyer, Douglas A. Spangenberg, Hal Maring, and Lan Gao
Atmos. Chem. Phys., 21, 1507–1563, https://doi.org/10.5194/acp-21-1507-2021, https://doi.org/10.5194/acp-21-1507-2021, 2021
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Southern Africa produces significant biomass burning emissions whose impacts on regional and global climate are poorly understood. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) is a 5-year NASA investigation designed to study the key processes that determine these climate impacts. The main purpose of this paper is to familiarize the broader scientific community with the ORACLES project, the dataset it produced, and the most important initial findings.
Lei Zhang, Sunling Gong, Tianliang Zhao, Chunhong Zhou, Yuesi Wang, Jiawei Li, Dongsheng Ji, Jianjun He, Hongli Liu, Ke Gui, Xiaomei Guo, Jinhui Gao, Yunpeng Shan, Hong Wang, Yaqiang Wang, Huizheng Che, and Xiaoye Zhang
Geosci. Model Dev., 14, 703–718, https://doi.org/10.5194/gmd-14-703-2021, https://doi.org/10.5194/gmd-14-703-2021, 2021
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Development of chemical transport models with advanced physics and chemical schemes is important for improving air-quality forecasts. This study develops the chemical module CUACE by updating with a new particle dry deposition scheme and adding heterogenous chemical reactions and couples it with the WRF model. The coupled model (WRF/CUACE) was able to capture well the variations of PM2.5, O3, NO2, and secondary inorganic aerosols in eastern China.
Han Xiao, Qizhong Wu, Xiaochun Yang, Lanning Wang, and Huaqiong Cheng
Geosci. Model Dev., 14, 223–238, https://doi.org/10.5194/gmd-14-223-2021, https://doi.org/10.5194/gmd-14-223-2021, 2021
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Few studies have investigated the effects of initial conditions on the simulation or prediction of PM2.5 concentrations. Here, sensitivity experiments are used to explore the effects of three initial mechanisms (clean, restart, and continuous) and emissions in Xi’an in December 2016. According to this work, if the restart mechanism cannot be used due to computing resource and storage space limitations when forecasting PM2.5 concentrations, a spin-up time of at least 27 h is needed.
Jianbing Jin, Arjo Segers, Hong Liao, Arnold Heemink, Richard Kranenburg, and Hai Xiang Lin
Atmos. Chem. Phys., 20, 15207–15225, https://doi.org/10.5194/acp-20-15207-2020, https://doi.org/10.5194/acp-20-15207-2020, 2020
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Data assimilation provides a powerful tool to estimate emission inventories by feeding observations. This emission inversion relies on the correct assumption about the emission uncertainty, which describes the potential spatiotemporal spreads of sources. However, an unrepresentative uncertainty is unavoidable. Especially in the complex dust emission, the uncertainties can hardly all be taken into account. This study reports how adjoint can be used to detect errors in the emission uncertainty.
Yarong Peng, Hongli Wang, Qian Wang, Shengao Jing, Jingyu An, Yaqin Gao, Cheng Huang, Rusha Yan, Haixia Dai, Tiantao Cheng, Qiang Zhang, Meng Li, Li Li, Shengrong Lou, Shikang Tao, Qinyao Hu, Jun Lu, and Changhong Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1108, https://doi.org/10.5194/acp-2020-1108, 2020
Revised manuscript not accepted
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The evolution of NMHCs emissions and the effectiveness of control measures were investigated based on long term measurements in a megacity of China. Discrepancies between measurements and emission inventories emphasized the need for emission validation both in speciation and sources. Varied trends of NMHCs speciation and sources suggested the differential effect of the past control measures, which provided new insights into future clean air policies in polluted region including China.
Ming-Tung Chuang, Maggie Chel Gee Ooi, Neng-Huei Lin, Joshua S. Fu, Chung-Te Lee, Sheng-Hsiang Wang, Ming-Cheng Yen, Steven Soon-Kai Kong, and Wei-Syun Huang
Atmos. Chem. Phys., 20, 14947–14967, https://doi.org/10.5194/acp-20-14947-2020, https://doi.org/10.5194/acp-20-14947-2020, 2020
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This study evaluated the impact of Asian haze from the three biggest industrial regions on Taiwan and analyzed the process during transport. The production and removal process revealed the mechanisms of long-range transport. This is the first time that the brute force method and process analysis technique has been applied in a Community Multiscale Air Quality Modeling System. Also, this study simulated the interesting transboundary transport of pollutants from southern mainland China to Taiwan.
Hajime Akimoto, Tatsuya Nagashima, Natsumi Kawano, Li Jie, Joshua S. Fu, and Zifa Wang
Atmos. Chem. Phys., 20, 15003–15014, https://doi.org/10.5194/acp-20-15003-2020, https://doi.org/10.5194/acp-20-15003-2020, 2020
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In order to perform proper model simulation of ozone near the ground in the coastal area of northeastern Asia, it has been found that it is very important to select appropriate dry deposition velocities of ozone on the oceanic water of specific area of the northwestern Pacific. Empirical measurement of the mixing ratios and dry deposition flux of ozone over the ocean in this area is highly recommended.
Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Bin Yuan, Jipeng Qi, Baolin Wang, Hongli Wang, Chen Wang, Wei Song, Xinming Wang, Weiwei Hu, Shengrong Lou, Chenshuo Ye, Yuwen Peng, Zelong Wang, Yibo Huangfu, Yan Xie, Manni Zhu, Junyu Zheng, Xuemei Wang, Bin Jiang, Zhanyi Zhang, and Min Shao
Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, https://doi.org/10.5194/acp-20-14769-2020, 2020
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Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Qingqing Yu, Xiang Ding, Quanfu He, Weiqiang Yang, Ming Zhu, Sheng Li, Runqi Zhang, Ruqin Shen, Yanli Zhang, Xinhui Bi, Yuesi Wang, Ping'an Peng, and Xinming Wang
Atmos. Chem. Phys., 20, 14581–14595, https://doi.org/10.5194/acp-20-14581-2020, https://doi.org/10.5194/acp-20-14581-2020, 2020
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We carried out a 1-year PM concurrent observation at 12 sites across six regions of China, and size-segregated PAHs were measured. We found both PAHs and BaPeq were concentrated in PM1.1, and northern China had higher PAHs' pollution and inhalation cancer risk than southern China. Nationwide increases in both PAH levels and inhalation cancer risk occurred in winter. We suggest reducing coal and biofuel consumption in the residential sector is an important option to mitigate PAHs' health risks.
Yixuan Gu, Fengxia Yan, Jianming Xu, Yuanhao Qu, Wei Gao, Fangfang He, and Hong Liao
Atmos. Chem. Phys., 20, 14361–14375, https://doi.org/10.5194/acp-20-14361-2020, https://doi.org/10.5194/acp-20-14361-2020, 2020
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High levels and statistically insignificant changes of ozone are detected at a remote monitoring site on Sheshan Island in Shanghai, China, from 2012 to 2017; 6-year observations suggest regional transport exerted minimum influence on the offshore oceanic air in September and October. Both city plumes and oceanic air inflows could contribute to ozone enhancements in Shanghai, and the latter are found to lead to 20–30 % increases in urban ozone concentrations based on WRF-Chem simulations.
Jingsha Xu, Shaojie Song, Roy M. Harrison, Congbo Song, Lianfang Wei, Qiang Zhang, Yele Sun, Lu Lei, Chao Zhang, Xiaohong Yao, Dihui Chen, Weijun Li, Miaomiao Wu, Hezhong Tian, Lining Luo, Shengrui Tong, Weiran Li, Junling Wang, Guoliang Shi, Yanqi Huangfu, Yingze Tian, Baozhu Ge, Shaoli Su, Chao Peng, Yang Chen, Fumo Yang, Aleksandra Mihajlidi-Zelić, Dragana Đorđević, Stefan J. Swift, Imogen Andrews, Jacqueline F. Hamilton, Ye Sun, Agung Kramawijaya, Jinxiu Han, Supattarachai Saksakulkrai, Clarissa Baldo, Siqi Hou, Feixue Zheng, Kaspar R. Daellenbach, Chao Yan, Yongchun Liu, Markku Kulmala, Pingqing Fu, and Zongbo Shi
Atmos. Meas. Tech., 13, 6325–6341, https://doi.org/10.5194/amt-13-6325-2020, https://doi.org/10.5194/amt-13-6325-2020, 2020
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An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
Chaomin Wang, Bin Yuan, Caihong Wu, Sihang Wang, Jipeng Qi, Baolin Wang, Zelong Wang, Weiwei Hu, Wei Chen, Chenshuo Ye, Wenjie Wang, Yele Sun, Chen Wang, Shan Huang, Wei Song, Xinming Wang, Suxia Yang, Shenyang Zhang, Wanyun Xu, Nan Ma, Zhanyi Zhang, Bin Jiang, Hang Su, Yafang Cheng, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, https://doi.org/10.5194/acp-20-14123-2020, 2020
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We utilized a novel online mass spectrometry method to measure the total concentration of higher alkanes at each carbon number at two different sites in China, allowing us to take into account SOA contributions from all isomers for higher alkanes. We found that higher alkanes account for significant fractions of SOA formation at the two sites. The contributions are comparable to or even higher than single-ring aromatics, the most-recognized SOA precursors in urban air.
Yongchun Liu, Yusheng Zhang, Chaofan Lian, Chao Yan, Zeming Feng, Feixue Zheng, Xiaolong Fan, Yan Chen, Weigang Wang, Biwu Chu, Yonghong Wang, Jing Cai, Wei Du, Kaspar R. Daellenbach, Juha Kangasluoma, Federico Bianchi, Joni Kujansuu, Tuukka Petäjä, Xuefei Wang, Bo Hu, Yuesi Wang, Maofa Ge, Hong He, and Markku Kulmala
Atmos. Chem. Phys., 20, 13023–13040, https://doi.org/10.5194/acp-20-13023-2020, https://doi.org/10.5194/acp-20-13023-2020, 2020
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Understanding of the chemical and physical processes leading to atmospheric aerosol particle formation is crucial to devising effective mitigation strategies to protect the public and reduce uncertainties in climate predictions. We found that the photolysis of nitrous acid could promote the formation of organic and nitrate aerosol and that traffic-related emission is a major contributor to ambient nitrous acid on haze days in wintertime in Beijing.
Wei Tao, Hang Su, Guangjie Zheng, Jiandong Wang, Chao Wei, Lixia Liu, Nan Ma, Meng Li, Qiang Zhang, Ulrich Pöschl, and Yafang Cheng
Atmos. Chem. Phys., 20, 11729–11746, https://doi.org/10.5194/acp-20-11729-2020, https://doi.org/10.5194/acp-20-11729-2020, 2020
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We simulated the thermodynamic and multiphase reactions in aerosol water during a wintertime haze event over the North China Plain. It was found that aerosol pH exhibited a strong spatiotemporal variability, and multiple oxidation pathways were predominant for particulate sulfate formation in different locations. Sensitivity tests further showed that ammonia, crustal particles, and dissolved transition metal ions were important factors for multiphase chemistry during haze episodes.
Zhenhao Ling, Qianqian Xie, Min Shao, Zhe Wang, Tao Wang, Hai Guo, and Xuemei Wang
Atmos. Chem. Phys., 20, 11451–11467, https://doi.org/10.5194/acp-20-11451-2020, https://doi.org/10.5194/acp-20-11451-2020, 2020
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The observation data from a receptor site in the Pearl River Delta region were analyzed by a photochemical box model with near-explicit chemical mechanisms (i.e., the Master Chemical Mechanism, MCM), improvements with reversible and irreversible heterogeneous processes of glyoxal and methylglyoxal, and the gas-particle partitioning of oxidation products in the present study.
Ke Li, Daniel J. Jacob, Lu Shen, Xiao Lu, Isabelle De Smedt, and Hong Liao
Atmos. Chem. Phys., 20, 11423–11433, https://doi.org/10.5194/acp-20-11423-2020, https://doi.org/10.5194/acp-20-11423-2020, 2020
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Surface summer ozone increased in China from 2013 to 2019 despite new governmental efforts targeting ozone pollution. We find that the ozone increase is mostly due to anthropogenic drivers, although meteorology also plays a role. Further analysis for the North China Plain shows that PM2.5 continued to decrease through 2019, while emissions of volatile organic compounds (VOCs) stayed flat. This could explain the anthropogenic increase in ozone, as PM2.5 scavenges the radical precursors of ozone.
Kazuyuki Miyazaki, Kevin Bowman, Takashi Sekiya, Henk Eskes, Folkert Boersma, Helen Worden, Nathaniel Livesey, Vivienne H. Payne, Kengo Sudo, Yugo Kanaya, Masayuki Takigawa, and Koji Ogochi
Earth Syst. Sci. Data, 12, 2223–2259, https://doi.org/10.5194/essd-12-2223-2020, https://doi.org/10.5194/essd-12-2223-2020, 2020
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This study presents the results from the Tropospheric Chemistry Reanalysis version 2 (TCR-2) for 2005–2018 obtained from the assimilation of multiple satellite measurements of ozone, CO, NO2, HNO3, and SO2 from the OMI, SCIAMACHY, GOME-2, TES, MLS, and MOPITT instruments. The evaluation results demonstrate the capability of the reanalysis products to improve understanding of the processes controlling variations in atmospheric composition, including long-term changes in air quality and emissions.
Baozhu Ge, Syuichi Itahashi, Keiichi Sato, Danhui Xu, Junhua Wang, Fan Fan, Qixin Tan, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Jung-Hun Woo, Junichi Kurokawa, Yuepeng Pan, Qizhong Wu, Xuejun Liu, and Zifa Wang
Atmos. Chem. Phys., 20, 10587–10610, https://doi.org/10.5194/acp-20-10587-2020, https://doi.org/10.5194/acp-20-10587-2020, 2020
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Performances of the simulated deposition for different reduced N (Nr) species in China were conducted with the Model Inter-Comparison Study for Asia. Results showed that simulated wet deposition of oxidized N was overestimated in northeastern China and underestimated in south China, but Nr was underpredicted in all regions by all models. Oxidized N has larger uncertainties than Nr, indicating that the chemical reaction process is one of the most importance factors affecting model performance.
Wanyu Zhao, Hong Ren, Kimitaka Kawamura, Huiyun Du, Xueshun Chen, Siyao Yue, Qiaorong Xie, Lianfang Wei, Ping Li, Xin Zeng, Shaofei Kong, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 10331–10350, https://doi.org/10.5194/acp-20-10331-2020, https://doi.org/10.5194/acp-20-10331-2020, 2020
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Our observations provide detailed information on the abundance and vertical distribution of dicarboxylic acids, oxoacids and α-dicarbonyls in PM2.5 collected at three heights based on a 325 m meteorological tower in Beijing in summer. Our results demonstrate that organic acids at the ground surface are largely associated with local traffic emissions, while long-range atmospheric transport followed by photochemical ageing contributes more in the urban boundary layer than the ground surface.
Satoru Chatani, Hikari Shimadera, Syuichi Itahashi, and Kazuyo Yamaji
Atmos. Chem. Phys., 20, 10311–10329, https://doi.org/10.5194/acp-20-10311-2020, https://doi.org/10.5194/acp-20-10311-2020, 2020
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Source sensitivities and apportionments of PM2.5 and ozone concentrations over Japan for 2016 were evaluated using multiple numerical techniques including BFM, HDDM, and ISAM, embedded in regional chemical transport models. Influences of stringent emission controls recently implemented in Asian countries were reflected. Differences between sensitivities and apportionments greatly helped distinguish various direct and indirect effects of emission sources on PM2.5 and ozone concentrations.
Xiao Han, Lingyun Zhu, Mingxu Liu, Yu Song, and Meigen Zhang
Atmos. Chem. Phys., 20, 9979–9996, https://doi.org/10.5194/acp-20-9979-2020, https://doi.org/10.5194/acp-20-9979-2020, 2020
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China is one of the largest agricultural countries in the world. Some of the major PM2.5 particles that cause the atmospheric haze and impact the climate change were converted from agricultural NH3 emission. This paper applied the numerical modeling system, coupled with a high-resolution agricultural NH3 emissions inventory, to investigate the contribution of agricultural NH3 to PM2.5 mass burden in China and obtained some interesting results.
Juan Feng, Jianlei Zhu, Jianping Li, and Hong Liao
Atmos. Chem. Phys., 20, 9883–9893, https://doi.org/10.5194/acp-20-9883-2020, https://doi.org/10.5194/acp-20-9883-2020, 2020
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This paper explores the month-to-month variability of aerosol concentrations (ACs) over China. The AC variability is dominated by the monopole mode and the meridional dipole mode. The associated dynamic and thermal impacts of the climate systems are examined to explain their contributions to the formation of the two modes. The result suggests the variations are originating from the tropical Pacific, and extratropical atmospheric systems contribute to the dominant variabilities of ACs over China.
Matt Amos, Paul J. Young, J. Scott Hosking, Jean-François Lamarque, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Markus Kunze, Marion Marchand, David A. Plummer, David Saint-Martin, Kengo Sudo, Simone Tilmes, and Yousuke Yamashita
Atmos. Chem. Phys., 20, 9961–9977, https://doi.org/10.5194/acp-20-9961-2020, https://doi.org/10.5194/acp-20-9961-2020, 2020
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We present an updated projection of Antarctic ozone hole recovery using an ensemble of chemistry–climate models. To do so, we employ a method, more advanced and skilful than the current multi-model mean standard, which is applicable to other ensemble analyses. It calculates the performance and similarity of the models, which we then use to weight the model. Calculating model similarity allows us to account for models which are constructed from similar components.
Miao Yu, Guiqian Tang, Yang Yang, Qingchun Li, Yonghong Wang, Shiguang Miao, Yizhou Zhang, and Yuesi Wang
Atmos. Chem. Phys., 20, 9855–9870, https://doi.org/10.5194/acp-20-9855-2020, https://doi.org/10.5194/acp-20-9855-2020, 2020
Lili Ren, Yang Yang, Hailong Wang, Rudong Zhang, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 20, 9067–9085, https://doi.org/10.5194/acp-20-9067-2020, https://doi.org/10.5194/acp-20-9067-2020, 2020
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Observations show that the concentrations of Arctic aerosols have declined since the early 1980s, which potentially contributed to the recent, rapid Arctic warming. We found that changes in sulfate and black carbon aerosols over the midlatitudes of the Northern Hemisphere had a larger impact on Arctic temperature than other regions and that the aerosol-induced temperature change explained approximately 20 % of the observed Arctic warming during 1980–2018.
Yuan Yang, Yonghong Wang, Putian Zhou, Dan Yao, Dongsheng Ji, Jie Sun, Yinghong Wang, Shuman Zhao, Wei Huang, Shuanghong Yang, Dean Chen, Wenkang Gao, Zirui Liu, Bo Hu, Renjian Zhang, Limin Zeng, Maofa Ge, Tuukka Petäjä, Veli-Matti Kerminen, Markku Kulmala, and Yuesi Wang
Atmos. Chem. Phys., 20, 8181–8200, https://doi.org/10.5194/acp-20-8181-2020, https://doi.org/10.5194/acp-20-8181-2020, 2020
Junchen Guo, Shengzhen Zhou, Mingfu Cai, Jun Zhao, Wei Song, Weixiong Zhao, Weiwei Hu, Yele Sun, Yao He, Chengqiang Yang, Xuezhe Xu, Zhisheng Zhang, Peng Cheng, Qi Fan, Jian Hang, Shaojia Fan, Xinming Wang, and Xuemei Wang
Atmos. Chem. Phys., 20, 7595–7615, https://doi.org/10.5194/acp-20-7595-2020, https://doi.org/10.5194/acp-20-7595-2020, 2020
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We characterized non-refractory submicron particulate matter (PM1.0) during winter in Guangzhou, south China. Chemical composition and key sources of ambient PM1.0 are revealed, highlighting the significant role of SOA. The relationship with SOA and peroxy radicals indicated gas-phase oxidation contributed predominantly to SOA formation during non-pollution periods, while heterogeneous/multiphase reactions played more important roles in SOA formation during pollution periods.
Daniele Visioni, Giovanni Pitari, Vincenzo Rizi, Marco Iarlori, Irene Cionni, Ilaria Quaglia, Hideharu Akiyoshi, Slimane Bekki, Neal Butchart, Martin Chipperfield, Makoto Deushi, Sandip S. Dhomse, Rolando Garcia, Patrick Joeckel, Douglas Kinnison, Jean-François Lamarque, Marion Marchand, Martine Michou, Olaf Morgenstern, Tatsuya Nagashima, Fiona M. O'Connor, Luke D. Oman, David Plummer, Eugene Rozanov, David Saint-Martin, Robyn Schofield, John Scinocca, Andrea Stenke, Kane Stone, Kengo Sudo, Taichu Y. Tanaka, Simone Tilmes, Holger Tost, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-525, https://doi.org/10.5194/acp-2020-525, 2020
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In this work we analyse the trend in ozone profiles taken at L'Aquila (Italy, 42.4° N) for seventeen years, between 2000 and 2016 and compare them against already available measured ozone trends. We try to understand and explain the observed trends at various heights in light of the simulations from seventeen different model, highlighting the contribution of changes in circulation and chemical ozone loss during this time period.
Jiani Tan, Joshua S. Fu, Gregory R. Carmichael, Syuichi Itahashi, Zhining Tao, Kan Huang, Xinyi Dong, Kazuyo Yamaji, Tatsuya Nagashima, Xuemei Wang, Yiming Liu, Hyo-Jung Lee, Chuan-Yao Lin, Baozhu Ge, Mizuo Kajino, Jia Zhu, Meigen Zhang, Hong Liao, and Zifa Wang
Atmos. Chem. Phys., 20, 7393–7410, https://doi.org/10.5194/acp-20-7393-2020, https://doi.org/10.5194/acp-20-7393-2020, 2020
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This study evaluated the performance of 12 chemical transport models from MICS-Asia III for predicting the particulate matter (PM) over East Asia. Four model processes were investigated as the possible reasons for model bias with measurements and the factors causing inconsistent predictions of PM from different models: (1) model inputs, (2) gas–particle conversion, (3) dust emission modules and (4) removal mechanisms (wet and dry depositions). The influence of each process was discussed.
Weiqi Xu, Yao He, Yanmei Qiu, Chun Chen, Conghui Xie, Lu Lei, Zhijie Li, Jiaxing Sun, Junyao Li, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Meas. Tech., 13, 3205–3219, https://doi.org/10.5194/amt-13-3205-2020, https://doi.org/10.5194/amt-13-3205-2020, 2020
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We characterized mass spectral features of organic aerosol (OA) and water-soluble OA (WSOA) from 21 cooking, crop straw, wood, and coal burning experiments using aerosol mass spectrometers with standard and capture vaporizers, and we demonstrated the applications of source spectral profiles in improving source apportionment of ambient OA at a highly polluted rural site in the North China Plain in winter.
Jing Yang, Wanyu Zhao, Lianfang Wei, Qiang Zhang, Yue Zhao, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 20, 6841–6860, https://doi.org/10.5194/acp-20-6841-2020, https://doi.org/10.5194/acp-20-6841-2020, 2020
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Our observations provide novel detailed information on the atmospheric abundances and spatial distributions of dicarboxylic acids, oxoacids, and α-dicarbonyls in marine aerosols collected from the South China Sea to the East Indian Ocean. Our results demonstrate that the continental outflow of both biogenic and anthropogenic precursors followed by photochemical aging is one of the main sources and formation processes of marine organic aerosols over the tropical oceanic regions.
Qiaorong Xie, Sihui Su, Shuang Chen, Yisheng Xu, Dong Cao, Jing Chen, Lujie Ren, Siyao Yue, Wanyu Zhao, Yele Sun, Zifa Wang, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, Guibin Jiang, Cong-Qiang Liu, and Pingqing Fu
Atmos. Chem. Phys., 20, 6803–6820, https://doi.org/10.5194/acp-20-6803-2020, https://doi.org/10.5194/acp-20-6803-2020, 2020
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Current knowledge on firework-related organic aerosols is very limited. Here the detailed molecular composition of organics in urban aerosols was characterized using ultrahigh-resolution FT-ICR mass spectrometry. Our findings highlight that firework emission leads to a sharp increase in CHO, CHNO, and CHOS containing high-molecular-weight species, particularly aromatic-like substances, which affect the physicochemical properties such as the light absorption and health effects of urban aerosols.
Yugo Kanaya, Kazuyo Yamaji, Takuma Miyakawa, Fumikazu Taketani, Chunmao Zhu, Yongjoo Choi, Yuichi Komazaki, Kohei Ikeda, Yutaka Kondo, and Zbigniew Klimont
Atmos. Chem. Phys., 20, 6339–6356, https://doi.org/10.5194/acp-20-6339-2020, https://doi.org/10.5194/acp-20-6339-2020, 2020
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Fundamental disagreements among bottom-up emission inventories exist about the sign of the black carbon emissions trend from China over the past decade. Our decadal observations on Fukue Island clearly indicate its rapid reduction, after correcting for interannual meteorological variability, which supports inventories reflecting governmental clean air actions after 2010. The reduction pace surpasses those of SSP1 scenarios for 2015–2030, suggesting highly successful emission control policies.
Shengzhen Zhou, Luolin Wu, Junchen Guo, Weihua Chen, Xuemei Wang, Jun Zhao, Yafang Cheng, Zuzhao Huang, Jinpu Zhang, Yele Sun, Pingqing Fu, Shiguo Jia, Jun Tao, Yanning Chen, and Junxia Kuang
Atmos. Chem. Phys., 20, 6435–6453, https://doi.org/10.5194/acp-20-6435-2020, https://doi.org/10.5194/acp-20-6435-2020, 2020
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In this work, measurements of size-segregated aerosols were conducted at three altitudes (ground level, 118 m, and 488 m) on the 610 m high Canton Tower in southern China. Vertical variations of PM and size-segregated chemical compositions were investigated. The results indicated that meteorological parameters and atmospheric aqueous and heterogeneous reactions together led to aerosol formation and haze episodes in the Pearl River Delta region during the measurement periods.
Zhi-Zhen Ni, Kun Luo, Yang Gao, Xiang Gao, Fei Jiang, Cheng Huang, Jian-Ren Fan, Joshua S. Fu, and Chang-Hong Chen
Atmos. Chem. Phys., 20, 5963–5976, https://doi.org/10.5194/acp-20-5963-2020, https://doi.org/10.5194/acp-20-5963-2020, 2020
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The Weather Research Forecast with Chemistry (WRF-Chem) model was used to simulate spatial and temporal O3 evolution in the Yangtze River Delta (YRD) region. Various atmospheric processes were analyzed to determine the influential factors of ozone formation through the integrated process rate method. This paper provides insight into urban O3 formation and dispersion during tropical cyclone events and supports the Model Intercomparison Study Asia Phase III (MICS-Asia Phase III).
Tao Ma, Hiroshi Furutani, Fengkui Duan, Takashi Kimoto, Jingkun Jiang, Qiang Zhang, Xiaobin Xu, Ying Wang, Jian Gao, Guannan Geng, Meng Li, Shaojie Song, Yongliang Ma, Fei Che, Jie Wang, Lidan Zhu, Tao Huang, Michisato Toyoda, and Kebin He
Atmos. Chem. Phys., 20, 5887–5897, https://doi.org/10.5194/acp-20-5887-2020, https://doi.org/10.5194/acp-20-5887-2020, 2020
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The formation mechanisms of organic matter and sulfate in winter haze in the North China Plain remain unclear. This paper presents the identification and quantification of hydroxymethanesulfonate (HMS) in PM2.5 in Beijing winter and elucidates the heterogeneous HMS chemistry in favorable winter haze conditions. We show that the HMS not only contributes a substantial mass of organic matter, but also leads to an overestimation of sulfate in conventional measurements.
Hang Liu, Xiaole Pan, Dantong Liu, Xiaoyong Liu, Xueshun Chen, Yu Tian, Yele Sun, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 20, 5771–5785, https://doi.org/10.5194/acp-20-5771-2020, https://doi.org/10.5194/acp-20-5771-2020, 2020
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The bare black carbon (BC) was in a fractal structure. With coating thickness increasing, BC changed from a fractal structure to a core–shell structure. In the ambient atmosphere, plenty of BC particles were not in a perfect core–shell structure. This study brought attention to the combined effects of morphology and coating thickness on the absorption enhancement of BC-containing particles, which is helpful for determining the climatic effects of BC.
Yuning Xie, Gehui Wang, Xinpei Wang, Jianmin Chen, Yubao Chen, Guiqian Tang, Lili Wang, Shuangshuang Ge, Guoyan Xue, Yuesi Wang, and Jian Gao
Atmos. Chem. Phys., 20, 5019–5033, https://doi.org/10.5194/acp-20-5019-2020, https://doi.org/10.5194/acp-20-5019-2020, 2020
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As a result of strict emission control, nitrate-dominated PM2.5 in pollution episodes was observed in urban Beijing during the winter of 2017–2018. With the help of sufficient ammonia, particle pH could increase to near neutral (5.4) as particulate nitrate fraction increases. Further tests imply that airborne particle hygroscopicity would be enhanced at moderate RH in nitrate-dominated particles, and pH elevation will be accelerated when ammonia and particulate nitrate both increase.
Genki Katata, Kazuhide Matsuda, Atsuyuki Sorimachi, Mizuo Kajino, and Kentaro Takagi
Atmos. Chem. Phys., 20, 4933–4949, https://doi.org/10.5194/acp-20-4933-2020, https://doi.org/10.5194/acp-20-4933-2020, 2020
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This work quantified the role of aerosol dynamics and gas–particle conversion processes in the dry deposition of inorganic reactive nitrogen using a new multilayer land surface model. It also revealed a potential impact of the above processes on improving the predictive accuracy of chemical transport models.
Dandan Zhao, Guangjing Liu, Jinyuan Xin, Jiannong Quan, Yuesi Wang, Xin Wang, Lindong Dai, Wenkang Gao, Guiqian Tang, Bo Hu, Yongxiang Ma, Xiaoyan Wu, Lili Wang, Zirui Liu, and Fangkun Wu
Atmos. Chem. Phys., 20, 4575–4592, https://doi.org/10.5194/acp-20-4575-2020, https://doi.org/10.5194/acp-20-4575-2020, 2020
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Under strong atmospheric oxidization capacity, haze pollution in the summer in Beijing was the result of the synergistic effect of the physicochemical process in the atmospheric boundary layer (ABL). With the premise of an extremely stable ABL structure, the formation of secondary aerosols dominated by nitrate was quite intense, driving the outbreak of haze pollution.
Cheng Gong, Yadong Lei, Yimian Ma, Xu Yue, and Hong Liao
Atmos. Chem. Phys., 20, 3841–3857, https://doi.org/10.5194/acp-20-3841-2020, https://doi.org/10.5194/acp-20-3841-2020, 2020
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We evaluate ozone–vegetation feedback using a fully coupled chemistry–carbon–climate global model (ModelE2-YIBs). Ozone damage to photosynthesis, stomatal conductance, and isoprene emissions parameterized by different schemes and sensitivities is jointly considered. In general, surface ozone concentrations are increased due to ozone–vegetation interactions, especially over the regions with a high ambient ozone level such as the eastern US, eastern China, and western Europe.
Shaofeng Xu, Lujie Ren, Yunchao Lang, Shengjie Hou, Hong Ren, Lianfang Wei, Libin Wu, Junjun Deng, Wei Hu, Xiaole Pan, Yele Sun, Zifa Wang, Hang Su, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 20, 3623–3644, https://doi.org/10.5194/acp-20-3623-2020, https://doi.org/10.5194/acp-20-3623-2020, 2020
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Current knowledge on the size distribution of biogenic primary organic aerosols in urban regions with heavy haze pollution is very limited. Here we performed a year-round study focusing on the organic molecular composition of size-segregated aerosol samples collected in urban Beijing during haze and non-haze days to elucidate the seasonal contributions of biomass burning, fungal spores, and plant debris to organic carbon as well as the influences from local emissions and long-range transport.
Syuichi Itahashi, Rohit Mathur, Christian Hogrefe, and Yang Zhang
Atmos. Chem. Phys., 20, 3373–3396, https://doi.org/10.5194/acp-20-3373-2020, https://doi.org/10.5194/acp-20-3373-2020, 2020
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The state-of-the-science Community Multiscale Air Quality model extended for hemispheric applications (H-CMAQ) is used to model the trans-Pacific transport which has been recognized as a potential source of air pollutants over the US. In Part 1, modeled ozone is evaluated with observations at surface, by ozonesonde and airplane, and by satellite across the Northern Hemisphere. In addition, a newly developed air mass characterization method to estimate stratospheric intrusion is presented.
Syuichi Itahashi, Rohit Mathur, Christian Hogrefe, Sergey L. Napelenok, and Yang Zhang
Atmos. Chem. Phys., 20, 3397–3413, https://doi.org/10.5194/acp-20-3397-2020, https://doi.org/10.5194/acp-20-3397-2020, 2020
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The state-of-the-science Community Multiscale Air Quality model extended for hemispheric applications (H-CMAQ) is used to model the trans-Pacific transport which has been recognized as a potential source of air pollutants over the US. In Part 2, the higher-order decoupled direct method (HDDM) is applied to investigate the emission impacts from east Asia and the US during April 2010. Furthermore, changes in trans-Pacific transport caused by the recent emissions are examined.
Hao He, Xin-Zhong Liang, Chao Sun, Zhining Tao, and Daniel Q. Tong
Atmos. Chem. Phys., 20, 3191–3208, https://doi.org/10.5194/acp-20-3191-2020, https://doi.org/10.5194/acp-20-3191-2020, 2020
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We studied the trend of US ozone pollution from 1990 to 2015 using EPA observations and computer simulations. Observations indicated a decrease in peak ozone at noon due to regulations and a slight increase in ozone in early morning and late afternoon possibly. Our modeling system confirmed these findings and provided detailed information about ozone photochemistry. These results revealed the success of previous control measures and provide scientific evidence for the future regulations.
Yadong Lei, Xu Yue, Hong Liao, Cheng Gong, and Lin Zhang
Geosci. Model Dev., 13, 1137–1153, https://doi.org/10.5194/gmd-13-1137-2020, https://doi.org/10.5194/gmd-13-1137-2020, 2020
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We coupled a dynamic vegetation model YIBs with the chemical transport model GEOS-Chem to develop a new tool for studying interactions between atmospheric chemistry and biosphere. Within this framework, leaf area index and stomatal conductance are predicted for chemical simulations. In turn, surface ozone causes negative impacts to plant growth and the consequent dry deposition. Such interactions are important for air pollution prediction but ignored in most of current chemical models.
Lu Lei, Conghui Xie, Dawei Wang, Yao He, Qingqing Wang, Wei Zhou, Wei Hu, Pingqing Fu, Yong Chen, Xiaole Pan, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 20, 2877–2890, https://doi.org/10.5194/acp-20-2877-2020, https://doi.org/10.5194/acp-20-2877-2020, 2020
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We characterized aerosol composition and sources near two steel plants in a coastal region in fall and spring seasons. Our results showed substantially different aerosol composition and sources between the two seasons. We observed significant impacts of steel plant emissions on aerosol chemistry nearby, and we found that aerosol particles emitted from the steel plants were dominated by ammonium sulfate/bisulfate; NOx/CO and NOx/SO2 were distinct from those in the absence of industrial plumes.
Michael Biggart, Jenny Stocker, Ruth M. Doherty, Oliver Wild, Michael Hollaway, David Carruthers, Jie Li, Qiang Zhang, Ruili Wu, Simone Kotthaus, Sue Grimmond, Freya A. Squires, James Lee, and Zongbo Shi
Atmos. Chem. Phys., 20, 2755–2780, https://doi.org/10.5194/acp-20-2755-2020, https://doi.org/10.5194/acp-20-2755-2020, 2020
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Ambient air pollution is a major cause of premature death in China. We examine the street-scale variation of pollutant levels in Beijing using air pollution dispersion and chemistry model ADMS-Urban. Campaign measurements are compared with simulated pollutant levels, providing a valuable means of evaluating the impact of key processes on urban air quality. Air quality modelling at such fine scales is essential for human exposure studies and for informing choices on future emission controls.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Junichi Kurokawa, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 20, 2667–2693, https://doi.org/10.5194/acp-20-2667-2020, https://doi.org/10.5194/acp-20-2667-2020, 2020
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This study gives an overview of acid deposition from the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Wet deposition simulated by a total of nine models is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The total deposition maps comparing to emissions over Asia are presented. To seek a way to improve the model performance, ensemble approaches and the precipitation-adjusted method are discussed.
Yang Yang, Sijia Lou, Hailong Wang, Pinya Wang, and Hong Liao
Atmos. Chem. Phys., 20, 2579–2590, https://doi.org/10.5194/acp-20-2579-2020, https://doi.org/10.5194/acp-20-2579-2020, 2020
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Aerosol concentration decreased in Europe during 1980–2018, of which 7 % was induced by the changes in non-European emissions. Aerosols transported from other source regions are increasingly important to air quality in Europe. Contributions to the sulfate radiative forcing over Europe from both European and non-European emissions should decrease at a comparable rate in the next three decades. Future changes in non-European emissions are important in causing regional climate change in Europe.
Xu Yue, Hong Liao, Huijun Wang, Tianyi Zhang, Nadine Unger, Stephen Sitch, Zhaozhong Feng, and Jia Yang
Atmos. Chem. Phys., 20, 2353–2366, https://doi.org/10.5194/acp-20-2353-2020, https://doi.org/10.5194/acp-20-2353-2020, 2020
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We explore ecosystem responses in China to 1.5 °C global warming under stabilized versus transient pathways. Remarkably, GPP shows 30 % higher enhancement in the stabilized than the transient pathway because of the lower ozone (smaller damages to photosynthesis) and fewer aerosols (higher light availability) in the former pathway. Our analyses suggest that an associated reduction of CO2 and pollution emissions brings more benefits to ecosystems in China via 1.5 °C global warming.
Khalid Mehmood, Yujie Wu, Liqiang Wang, Shaocai Yu, Pengfei Li, Xue Chen, Zhen Li, Yibo Zhang, Mengying Li, Weiping Liu, Yuesi Wang, Zirui Liu, Yannian Zhu, Daniel Rosenfeld, and John H. Seinfeld
Atmos. Chem. Phys., 20, 2419–2443, https://doi.org/10.5194/acp-20-2419-2020, https://doi.org/10.5194/acp-20-2419-2020, 2020
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We selected June 2014 as our study period, which exhibited a complete evolution process of open biomass burning (OBB) dominated by open crop straw burning (OCSB) over central and eastern China (CEC). We established a constraining method that integrates ground-based PM2.5 measurements with the two-way coupled WRF-CMAQ model to derive optimal OBB emissions. It was found that these emissions could allow the model to reproduce meteorological and chemical fields over CEC during the study period.
Zhining Tao, Mian Chin, Meng Gao, Tom Kucsera, Dongchul Kim, Huisheng Bian, Jun-ichi Kurokawa, Yuesi Wang, Zirui Liu, Gregory R. Carmichael, Zifa Wang, and Hajime Akimoto
Atmos. Chem. Phys., 20, 2319–2339, https://doi.org/10.5194/acp-20-2319-2020, https://doi.org/10.5194/acp-20-2319-2020, 2020
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One goal of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III is to identify strengths and weaknesses of current air quality models to provide insights into reducing uncertainties. This study identified that a 15 km grid would be the optimal horizontal resolution in terms of performance and resource usage to capture average and extreme air quality over East Asia and is thus suggested for use in future MICS-Asia modeling activities if the investigation domain remains the same.
Meng Gao, Zirui Liu, Bo Zheng, Dongsheng Ji, Peter Sherman, Shaojie Song, Jinyuan Xin, Cheng Liu, Yuesi Wang, Qiang Zhang, Jia Xing, Jingkun Jiang, Zifa Wang, Gregory R. Carmichael, and Michael B. McElroy
Atmos. Chem. Phys., 20, 1497–1505, https://doi.org/10.5194/acp-20-1497-2020, https://doi.org/10.5194/acp-20-1497-2020, 2020
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We quantified the relative influences of anthropogenic emissions and meteorological conditions on PM2.5 concentrations in Beijing over the winters of 2002–2016. Meteorological conditions over the study period would have led to an increase of haze in Beijing, but the strict emission control measures have suppressed the unfavorable influences of the recent climate.
Meng Gao, Zhiwei Han, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Meng Li, Jung-Hun Woo, Qiang Zhang, Yafang Cheng, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 1147–1161, https://doi.org/10.5194/acp-20-1147-2020, https://doi.org/10.5194/acp-20-1147-2020, 2020
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Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative feedbacks. This paper discusses the estimates of aerosol radiative forcing, aerosol feedbacks, and possible causes for the differences among the models.
Kazuyuki Miyazaki, Kevin W. Bowman, Keiya Yumimoto, Thomas Walker, and Kengo Sudo
Atmos. Chem. Phys., 20, 931–967, https://doi.org/10.5194/acp-20-931-2020, https://doi.org/10.5194/acp-20-931-2020, 2020
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We introduce a multi-model, multi-constituent chemical data assimilation framework that directly accounts for model error in transport and chemistry by integrating a portfolio of forward chemical transport models. The assimilation was able to reduce ensemble forward model spread and bias relative to independent measurements. Diagnostic information readily available from the framework has the potential to improve chemical predictions through relationships such as emergent constraints.
Yonghong Wang, Miao Yu, Yuesi Wang, Guiqian Tang, Tao Song, Putian Zhou, Zirui Liu, Bo Hu, Dongsheng Ji, Lili Wang, Xiaowan Zhu, Chao Yan, Mikael Ehn, Wenkang Gao, Yuepeng Pan, Jinyuan Xin, Yang Sun, Veli-Matti Kerminen, Markku Kulmala, and Tuukka Petäjä
Atmos. Chem. Phys., 20, 45–53, https://doi.org/10.5194/acp-20-45-2020, https://doi.org/10.5194/acp-20-45-2020, 2020
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We found a positive particle matter-mixing layer height feedback at three observation platforms at the 325 m Beijing meteorology tower, which is characterized by a shallower mixing layer height and a higher particle matter concentration. Measurements of solar radiation, aerosol chemical composition, meteorology parameters, trace gases and turbulent kinetic energy (TKE) could explain the feedback mechanism to some extent.
Luolin Wu, Ming Chang, Xuemei Wang, Jian Hang, Jinpu Zhang, Liqing Wu, and Min Shao
Geosci. Model Dev., 13, 23–40, https://doi.org/10.5194/gmd-13-23-2020, https://doi.org/10.5194/gmd-13-23-2020, 2020
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We developed the Real-time On-road Emission (ROE v1.0) model to obtain the street-scale on-road hot emissions by using real-time big data for traffic provided by the Gaode Map navigation application. The results are close to other emission inventories. Meanwhile, we applied our results to a street-level air quality model for studying the impact of the national holiday traffic volume change on air quality. The model can be further extended to more districts in China or other countries.
Yanbing Fan, Cong-Qiang Liu, Linjie Li, Lujie Ren, Hong Ren, Zhimin Zhang, Qinkai Li, Shuang Wang, Wei Hu, Junjun Deng, Libin Wu, Shujun Zhong, Yue Zhao, Chandra Mouli Pavuluri, Xiaodong Li, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, Zongbo Shi, and Pingqing Fu
Atmos. Chem. Phys., 20, 117–137, https://doi.org/10.5194/acp-20-117-2020, https://doi.org/10.5194/acp-20-117-2020, 2020
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This study provides useful knowledge on the abundance, sources, and formation processes of organic aerosols in the coastal megacity of Tianjin, North China, based on the investigation of the molecular composition, diurnal variation, and winter/summer differences under the influence of land/sea breezes and the Asian summer monsoon.
Danhui Xu, Baozhu Ge, Xueshun Chen, Yele Sun, Nianliang Cheng, Mei Li, Xiaole Pan, Zhiqiang Ma, Yuepeng Pan, and Zifa Wang
Atmos. Chem. Phys., 19, 15569–15581, https://doi.org/10.5194/acp-19-15569-2019, https://doi.org/10.5194/acp-19-15569-2019, 2019
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Wet deposition is one of the most important and efficient removal mechanisms in the evolution of the air pollution. Due to the lack of a localized parameterization scheme and some mechanisms being neglected in theoretical estimations and modeling calculations, below-cloud wet scavenging coefficients (BWSC) have large uncertainties. We compare the BWSCs under the same conditions to perform a multi-method evaluation in order to describe their characteristics.
Hang Liu, Xiaole Pan, Yu Wu, Dawei Wang, Yu Tian, Xiaoyong Liu, Lu Lei, Yele Sun, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 19, 14791–14804, https://doi.org/10.5194/acp-19-14791-2019, https://doi.org/10.5194/acp-19-14791-2019, 2019
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The relationship among the effective density, rBC's coating thickness, and rBC's morphology was investigated. rBC with larger effective density adopted a more regular shape due to more coating thickness. The effective density distribution of ambient rBC was also measured. From the information of effective density, the ambient rBC mainly adopts an irregular shape, which can cause large uncertainties in the rBC's optical properties.
Cheng Gong and Hong Liao
Atmos. Chem. Phys., 19, 13725–13740, https://doi.org/10.5194/acp-19-13725-2019, https://doi.org/10.5194/acp-19-13725-2019, 2019
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Severe O3 pollution events (OPEs) were observed frequently in summer in North China. We found a typical weather pattern that was responsible for the 21 OPEs observed in North China in May to July of 2014–2017. This weather pattern is characterized by high daily maximum temperature, low relative humidity and an anomalous high-pressure system at 500 hPa. Under such a weather pattern, chemical production of O3 is high between 800 and 900 hPa, which is then transported downward to enhance O3 levels.
Jie Li, Tatsuya Nagashima, Lei Kong, Baozhu Ge, Kazuyo Yamaji, Joshua S. Fu, Xuemei Wang, Qi Fan, Syuichi Itahashi, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Meigen Zhang, Zhining Tao, Mizuo Kajino, Hong Liao, Meng Li, Jung-Hun Woo, Jun-ichi Kurokawa, Zhe Wang, Qizhong Wu, Hajime Akimoto, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 19, 12993–13015, https://doi.org/10.5194/acp-19-12993-2019, https://doi.org/10.5194/acp-19-12993-2019, 2019
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This study evaluated and intercompared 14 CTMs with ozone observations in East Asia, within the framework of the Model Inter-Comparison Study for ASIA Phase III (MICS-Asia III). Potential causes of the discrepancies between model results and observation were investigated by assessing the planetary boundary layer heights, emission fluxes, dry deposition, chemistry and vertical transport among models. Finally, a multi-model estimate of pollution distributions was provided.
Lei Chen, Yi Gao, Meigen Zhang, Joshua S. Fu, Jia Zhu, Hong Liao, Jialin Li, Kan Huang, Baozhu Ge, Xuemei Wang, Yun Fat Lam, Chuan-Yao Lin, Syuichi Itahashi, Tatsuya Nagashima, Mizuo Kajino, Kazuyo Yamaji, Zifa Wang, and Jun-ichi Kurokawa
Atmos. Chem. Phys., 19, 11911–11937, https://doi.org/10.5194/acp-19-11911-2019, https://doi.org/10.5194/acp-19-11911-2019, 2019
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Simulated aerosol concentrations from 14 CTMs within the framework of MICS-Asia III are detailedly evaluated with an extensive set of measurements in East Asia. Similarities and differences among model performances are also analyzed. Although more considerable capacities for reproducing the aerosol concentrations and their variations are shown in current CTMs than those in MICS-Asia II, more efforts are needed to reduce diversities of simulated aerosol concentrations among air quality models.
Meng Li, Hang Su, Guo Li, Nan Ma, Ulrich Pöschl, and Yafang Cheng
Atmos. Chem. Phys., 19, 10981–11011, https://doi.org/10.5194/acp-19-10981-2019, https://doi.org/10.5194/acp-19-10981-2019, 2019
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Aerosols and the ground provide two kinds of surfaces for multiphase reactions in the planetary boundary layer. However, the relative importance of these two surfaces for gas uptake has not been quantified. We compare the uptake fluxes of aerosols and the ground surface for reactive trace gases under various conditions. More studies regarding O3 uptake on liquid organic aerosols and H2O2 uptakes on various aerosols are needed considering their potential important roles in atmospheric chemistry.
Shixian Zhai, Daniel J. Jacob, Xuan Wang, Lu Shen, Ke Li, Yuzhong Zhang, Ke Gui, Tianliang Zhao, and Hong Liao
Atmos. Chem. Phys., 19, 11031–11041, https://doi.org/10.5194/acp-19-11031-2019, https://doi.org/10.5194/acp-19-11031-2019, 2019
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Observed annual mean PM2.5 decreased by 30–50 % in China from 2013–2018. However, meteorologically PM2.5 variability complicates trend attribution. We used a stepwise multiple linear regression model to quantitatively separate contributions from anthropogenic emissions and meteorology. Results show that 88 % of the PM2.5 decrease across China is attributable to anthropogenic emission changes, and 12 % is attributable to meteorology.
Lei Chen, Jia Zhu, Hong Liao, Yi Gao, Yulu Qiu, Meigen Zhang, Zirui Liu, Nan Li, and Yuesi Wang
Atmos. Chem. Phys., 19, 10845–10864, https://doi.org/10.5194/acp-19-10845-2019, https://doi.org/10.5194/acp-19-10845-2019, 2019
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The formation mechanism of a severe haze episode that occurred over North China in December 2015, the aerosol radiative impacts on the haze event and the influence mechanism were examined. The PM2.5 increase during the aerosol accumulation stage was mainly attributed to strong production by the aerosol chemistry process and weak removal by advection and vertical mixing. Restrained vertical mixing was the main reason for near-surface PM2.5 increase when aerosol radiative feedback was considered.
Juan Feng, Jianping Li, Hong Liao, and Jianlei Zhu
Atmos. Chem. Phys., 19, 10787–10800, https://doi.org/10.5194/acp-19-10787-2019, https://doi.org/10.5194/acp-19-10787-2019, 2019
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Background climate can affect the aerosol concentration (AC). It is found that when negative NAO overlaps El Niño, the anomalous circulations are not favorable for the transportation of aerosol, resulting in enhanced AC over eastern China. By contrast, a sole negative NAO event is linked with increased AC over central China. The results suggest that both the extratropical and tropical climate systems play an important role in impacting the AC over China.
Ruijun Dang and Hong Liao
Atmos. Chem. Phys., 19, 10801–10816, https://doi.org/10.5194/acp-19-10801-2019, https://doi.org/10.5194/acp-19-10801-2019, 2019
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We used a global chemical transport model to examine the historical changes in severe winter haze days (SWHDs) in Beijing–Tianjin–Hebei (BTH) in China. Simulated frequency of SWHDs in BTH showed an increasing trend over 1985–2017 with obvious fluctuations. We found that meteorology has dominated the frequency decrease in 1992–2001, and both anthropogenic emissions and meteorology contributed to the increase in 2003–2012. These results have important implications for the control of SWHDs in BTH.
Weiqi Xu, Conghui Xie, Eleni Karnezi, Qi Zhang, Junfeng Wang, Spyros N. Pandis, Xinlei Ge, Jingwei Zhang, Junling An, Qingqing Wang, Jian Zhao, Wei Du, Yanmei Qiu, Wei Zhou, Yao He, Ying Li, Jie Li, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 19, 10205–10216, https://doi.org/10.5194/acp-19-10205-2019, https://doi.org/10.5194/acp-19-10205-2019, 2019
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We present the first aerosol volatility measurements in Beijing in summer using a thermodenuder coupled with aerosol mass spectrometers. Our results showed that organic aerosol (OA) comprised mainly semi-volatile organic compounds in summer, and the freshly oxidized secondary OA was the most volatile component. We also found quite different volatility distributions in black-carbon-containing primary and secondary OA, ambient OA, ambient secondary OA and the WRF-Chem model.
Kévin Lamy, Thierry Portafaix, Béatrice Josse, Colette Brogniez, Sophie Godin-Beekmann, Hassan Bencherif, Laura Revell, Hideharu Akiyoshi, Slimane Bekki, Michaela I. Hegglin, Patrick Jöckel, Oliver Kirner, Ben Liley, Virginie Marecal, Olaf Morgenstern, Andrea Stenke, Guang Zeng, N. Luke Abraham, Alexander T. Archibald, Neil Butchart, Martyn P. Chipperfield, Glauco Di Genova, Makoto Deushi, Sandip S. Dhomse, Rong-Ming Hu, Douglas Kinnison, Michael Kotkamp, Richard McKenzie, Martine Michou, Fiona M. O'Connor, Luke D. Oman, Giovanni Pitari, David A. Plummer, John A. Pyle, Eugene Rozanov, David Saint-Martin, Kengo Sudo, Taichu Y. Tanaka, Daniele Visioni, and Kohei Yoshida
Atmos. Chem. Phys., 19, 10087–10110, https://doi.org/10.5194/acp-19-10087-2019, https://doi.org/10.5194/acp-19-10087-2019, 2019
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In this study, we simulate the ultraviolet radiation evolution during the 21st century on Earth's surface using the output from several numerical models which participated in the Chemistry-Climate Model Initiative. We present four possible futures which depend on greenhouse gases emissions. The role of ozone-depleting substances, greenhouse gases and aerosols are investigated. Our results emphasize the important role of aerosols for future ultraviolet radiation in the Northern Hemisphere.
Wei Zhang, Chunyan Liu, Xunhua Zheng, Kai Wang, Feng Cui, Rui Wang, Siqi Li, Zhisheng Yao, and Jiang Zhu
Biogeosciences, 16, 2905–2922, https://doi.org/10.5194/bg-16-2905-2019, https://doi.org/10.5194/bg-16-2905-2019, 2019
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A biogeochemical process model-based approach for screening the best management practices (BMPs) of a three-crop system was proposed. The BMPs are the management alternatives with the lowest negative impact potentials that still satisfy all given constraints. Three BMP alternatives with overlapping uncertainties of simulated NIPs were screened from 6000 scenarios using the modified DNDC95 model, which could sustain crop yields, enlarge SOC stock, mitigate GHG, and reduce other nitrogen losses.
Yuxuan Zhang, Meng Li, Yafang Cheng, Guannan Geng, Chaopeng Hong, Haiyan Li, Xin Li, Dan Tong, Nana Wu, Xin Zhang, Bo Zheng, Yixuan Zheng, Yu Bo, Hang Su, and Qiang Zhang
Atmos. Chem. Phys., 19, 9663–9680, https://doi.org/10.5194/acp-19-9663-2019, https://doi.org/10.5194/acp-19-9663-2019, 2019
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In this work, we developed a new approach to simulate BC mixing state based on an emissions inventory and back-trajectory analysis. The model tracks the evolution of BC aging degree during atmospheric transport. Our simulations identified the important roles of extensive emission regions in the BC aging process during atmospheric transport, which provided more clues for improving air pollution and climate change.
Yusi Liu, Guiqian Tang, Libo Zhou, Bo Hu, Baoxian Liu, Yunting Li, Shu Liu, and Yuesi Wang
Atmos. Chem. Phys., 19, 9531–9540, https://doi.org/10.5194/acp-19-9531-2019, https://doi.org/10.5194/acp-19-9531-2019, 2019
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Weak atmospheric dilution capability is a key factor leading to the frequent occurrence of serious air pollution. This study aims to analyze the mixing layer dilution capability of the atmosphere and to quantify the mixing layer PM2.5 transport flux. Our results showed the main controlling factors during the transition and heavy polluted period in Beijing. The results help in understanding the causes of air pollution and making decisions on prevention and control of air pollution.
Mien-Tze Kueh, Wen-Mei Chen, Yang-Fan Sheng, Simon C. Lin, Tso-Ren Wu, Eric Yen, Yu-Lin Tsai, and Chuan-Yao Lin
Nat. Hazards Earth Syst. Sci., 19, 1509–1539, https://doi.org/10.5194/nhess-19-1509-2019, https://doi.org/10.5194/nhess-19-1509-2019, 2019
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In this study, we show that both the model horizontal resolution and air–sea flux parameterization can exert a large influence on tropical cyclone intensity simulation but with different impacts on wind structures. We highlight the intensification and contraction of the TC eyewall in response to the reduction of grid spacing. We also suggest that a well-developed eyewall is more conducive to the positive effect of flux formulas on TC development.
Huiyun Du, Jie Li, Xueshun Chen, Zifa Wang, Yele Sun, Pingqing Fu, Jianjun Li, Jian Gao, and Ying Wei
Atmos. Chem. Phys., 19, 9351–9370, https://doi.org/10.5194/acp-19-9351-2019, https://doi.org/10.5194/acp-19-9351-2019, 2019
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Regional transport and heterogeneous reactions play crucial roles in haze formation. Using a chemical transport model, we found that chemical transformation of SO2 along the transport pathway from source regions to Beijing was the major source of sulfate. Heterogeneous chemistry had a stronger effect under high humidity and high pollution levels. Aerosols underwent aging during transport which altered the aerosol size and the degree of aging.
Li Li, Shuhui Zhu, Jingyu An, Min Zhou, Hongli Wang, Rusha Yan, Liping Qiao, Xudong Tian, Lijuan Shen, Ling Huang, Yangjun Wang, Cheng Huang, Jeremy C. Avise, and Joshua S. Fu
Atmos. Chem. Phys., 19, 9037–9060, https://doi.org/10.5194/acp-19-9037-2019, https://doi.org/10.5194/acp-19-9037-2019, 2019
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Heavy haze usually occurs in winter in eastern China. To control the severe air pollution during the season, comprehensive regional joint-control strategies were implemented throughout a campaign. To evaluate the effectiveness of these strategies and to provide some insight into strengthening the joint-control mechanism, the influence of control measures on levels of air pollution was estimated in this paper.
Meng Li, Qiang Zhang, Bo Zheng, Dan Tong, Yu Lei, Fei Liu, Chaopeng Hong, Sicong Kang, Liu Yan, Yuxuan Zhang, Yu Bo, Hang Su, Yafang Cheng, and Kebin He
Atmos. Chem. Phys., 19, 8897–8913, https://doi.org/10.5194/acp-19-8897-2019, https://doi.org/10.5194/acp-19-8897-2019, 2019
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A long-term non-methane volatile organic compound (NMVOC) emission inventory is crucial for air quality management but still absent in China. We estimated China’s NMVOCs during 1990–2017 with speciation based on updated databases and investigated the trend of ozone formation potential (OFP) for the same period. Persistent growth of emissions and OFP highlights the need of control measures for solvent use and industrial sources and the importance of designing multi-pollutant control strategies.
Zhuoran He, Xuemei Wang, Zhenhao Ling, Jun Zhao, Hai Guo, Min Shao, and Zhe Wang
Atmos. Chem. Phys., 19, 8801–8816, https://doi.org/10.5194/acp-19-8801-2019, https://doi.org/10.5194/acp-19-8801-2019, 2019
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In this study, source apportionment of volatile organic compounds (VOCs) and their contributions to photochemical O3 formation were analyzed by the positive matrix factorization model and an observation-based model using data collected at a receptor site in the Pearl River Delta (PRD) region. Furthermore, the policies for controlling VOCs are briefly reviewed. The findings could provide quantitative information for devising appropriate measures against VOCs, NOx and O3 pollution in the PRD.
Tabish Umar Ansari, Oliver Wild, Jie Li, Ting Yang, Weiqi Xu, Yele Sun, and Zifa Wang
Atmos. Chem. Phys., 19, 8651–8668, https://doi.org/10.5194/acp-19-8651-2019, https://doi.org/10.5194/acp-19-8651-2019, 2019
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We explore the effectiveness of short-term emission controls on haze events in Beijing in October–November 2014 with high-resolution model studies. The model captures observed hourly variation in key pollutants well, but representation of boundary layer processes remains a key constraint. The controls contributed to improved air quality in early November but would not have been sufficient had the meteorology been less favourable. We quantify the much more stringent controls needed in that case.
Hiroaki Tatebe, Tomoo Ogura, Tomoko Nitta, Yoshiki Komuro, Koji Ogochi, Toshihiko Takemura, Kengo Sudo, Miho Sekiguchi, Manabu Abe, Fuyuki Saito, Minoru Chikira, Shingo Watanabe, Masato Mori, Nagio Hirota, Yoshio Kawatani, Takashi Mochizuki, Kei Yoshimura, Kumiko Takata, Ryouta O'ishi, Dai Yamazaki, Tatsuo Suzuki, Masao Kurogi, Takahito Kataoka, Masahiro Watanabe, and Masahide Kimoto
Geosci. Model Dev., 12, 2727–2765, https://doi.org/10.5194/gmd-12-2727-2019, https://doi.org/10.5194/gmd-12-2727-2019, 2019
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For a deeper understanding of a wide range of climate science issues, the latest version of the Japanese climate model, called MIROC6, was developed. The climate model represents observed mean climate and climate variations well, for example tropical precipitation, the midlatitude westerlies, and the East Asian monsoon, which influence human activity all over the world. The improved climate simulations could add reliability to climate predictions under global warming.
Dongsheng Ji, Wenkang Gao, Willy Maenhaut, Jun He, Zhe Wang, Jiwei Li, Wupeng Du, Lili Wang, Yang Sun, Jinyuan Xin, Bo Hu, and Yuesi Wang
Atmos. Chem. Phys., 19, 8569–8590, https://doi.org/10.5194/acp-19-8569-2019, https://doi.org/10.5194/acp-19-8569-2019, 2019
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This study reveals an obvious decreasing trend in OC and EC concentrations in urban Beijing. Higher concentrations were related to air masses originating from the northeast sector at wind speeds of approximately 5 km h−1. The potential source regions of the carbonaceous aerosols stretched to broader areas in the northwestern and western regions where coal mining and coal-fired power generation activities are intensive, which is fairly consistent with the MEIC inventory for China.
Run Liu, Lu Mao, Shaw Chen Liu, Yuanhang Zhang, Hong Liao, Huopo Chen, and Yuhang Wang
Atmos. Chem. Phys., 19, 8563–8568, https://doi.org/10.5194/acp-19-8563-2019, https://doi.org/10.5194/acp-19-8563-2019, 2019
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The recent paper by Shen et al. (2018; referred to hereafter as SHEN) made a sweeping statement on the winter haze pollution in Beijing by claiming an
Insignificant effect of climate change on winter haze in Beijing. We argue that the paper contains three serious flaws. Any one of the three flaws can nullify the claim of SHEN.
Xiaole Pan, Hang Liu, Yu Wu, Yu Tian, Yele Sun, Conghui Xie, Xiaoyong Liu, Tianhai Cheng, and Zifa Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-433, https://doi.org/10.5194/acp-2019-433, 2019
Revised manuscript not accepted
Ying Wei, Xueshun Chen, Huansheng Chen, Jie Li, Zifa Wang, Wenyi Yang, Baozhu Ge, Huiyun Du, Jianqi Hao, Wei Wang, Jianjun Li, Yele Sun, and Huili Huang
Atmos. Chem. Phys., 19, 8269–8296, https://doi.org/10.5194/acp-19-8269-2019, https://doi.org/10.5194/acp-19-8269-2019, 2019
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This study presents a full description and evaluation of a global–regional nested aerosol and atmospheric chemistry model (IAP-AACM). The simulation for 2014 is evaluated against model datasets and a range of observational datasets. The results show that IAP-AACM is within the range of other models, and reproduces both spatial and seasonal variation of trace gases and aerosols over most areas well. In future, we recommend improving the model's ability to capture high spatial variation of PM2.5.
Liqing Wu, Xuemei Wang, Sihua Lu, Min Shao, and Zhenhao Ling
Atmos. Chem. Phys., 19, 8141–8161, https://doi.org/10.5194/acp-19-8141-2019, https://doi.org/10.5194/acp-19-8141-2019, 2019
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Semi-volatile and intermediate-volatility organic compounds (S–IVOCs) are considered critical precursors of secondary organic aerosol (SOA), which is an important component of fine particulate matter (PM2.5). In this study, an emission inventory of S–IVOCs in the Pearl River Delta (PRD) region was developed for the first time for the year 2010, while the contributions of S–IVOCs to SOA formation was evaluated by the WRF-Chem model.
Keiichiro Hara, Kengo Sudo, Takato Ohnishi, Kazuo Osada, Masanori Yabuki, Masataka Shiobara, and Takashi Yamanouchi
Atmos. Chem. Phys., 19, 7817–7837, https://doi.org/10.5194/acp-19-7817-2019, https://doi.org/10.5194/acp-19-7817-2019, 2019
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We measured equivalent black carbon (EBC) concentrations at Syowa Station, Antarctica, from February 2005. EBC might be transported directly to Syowa Station from mid-latitudes mainly via the boundary layer and the lower free troposphere. Some BC was transported to Antarctic regions via the upper free troposphere. Biomass burning in South America and southern Africa is the most dominant source. Fossil fuel combustion in South America and southern Africa also have important contributions.
Zongbo Shi, Tuan Vu, Simone Kotthaus, Roy M. Harrison, Sue Grimmond, Siyao Yue, Tong Zhu, James Lee, Yiqun Han, Matthias Demuzere, Rachel E. Dunmore, Lujie Ren, Di Liu, Yuanlin Wang, Oliver Wild, James Allan, W. Joe Acton, Janet Barlow, Benjamin Barratt, David Beddows, William J. Bloss, Giulia Calzolai, David Carruthers, David C. Carslaw, Queenie Chan, Lia Chatzidiakou, Yang Chen, Leigh Crilley, Hugh Coe, Tie Dai, Ruth Doherty, Fengkui Duan, Pingqing Fu, Baozhu Ge, Maofa Ge, Daobo Guan, Jacqueline F. Hamilton, Kebin He, Mathew Heal, Dwayne Heard, C. Nicholas Hewitt, Michael Hollaway, Min Hu, Dongsheng Ji, Xujiang Jiang, Rod Jones, Markus Kalberer, Frank J. Kelly, Louisa Kramer, Ben Langford, Chun Lin, Alastair C. Lewis, Jie Li, Weijun Li, Huan Liu, Junfeng Liu, Miranda Loh, Keding Lu, Franco Lucarelli, Graham Mann, Gordon McFiggans, Mark R. Miller, Graham Mills, Paul Monk, Eiko Nemitz, Fionna O'Connor, Bin Ouyang, Paul I. Palmer, Carl Percival, Olalekan Popoola, Claire Reeves, Andrew R. Rickard, Longyi Shao, Guangyu Shi, Dominick Spracklen, David Stevenson, Yele Sun, Zhiwei Sun, Shu Tao, Shengrui Tong, Qingqing Wang, Wenhua Wang, Xinming Wang, Xuejun Wang, Zifang Wang, Lianfang Wei, Lisa Whalley, Xuefang Wu, Zhijun Wu, Pinhua Xie, Fumo Yang, Qiang Zhang, Yanli Zhang, Yuanhang Zhang, and Mei Zheng
Atmos. Chem. Phys., 19, 7519–7546, https://doi.org/10.5194/acp-19-7519-2019, https://doi.org/10.5194/acp-19-7519-2019, 2019
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APHH-Beijing is a collaborative international research programme to study the sources, processes and health effects of air pollution in Beijing. This introduction to the special issue provides an overview of (i) the APHH-Beijing programme, (ii) the measurement and modelling activities performed as part of it and (iii) the air quality and meteorological conditions during joint intensive field campaigns as a core activity within APHH-Beijing.
Yugo Kanaya, Kazuyuki Miyazaki, Fumikazu Taketani, Takuma Miyakawa, Hisahiro Takashima, Yuichi Komazaki, Xiaole Pan, Saki Kato, Kengo Sudo, Takashi Sekiya, Jun Inoue, Kazutoshi Sato, and Kazuhiro Oshima
Atmos. Chem. Phys., 19, 7233–7254, https://doi.org/10.5194/acp-19-7233-2019, https://doi.org/10.5194/acp-19-7233-2019, 2019
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Ozone and carbon monoxide levels were uniquely observed (for > 10 000 h) over oceans from 67° S to 75° N. Tropospheric chemistry reanalysis v2 reproduced the observed evolution of pollution plumes from continents but underpredicted and overpredicted ozone levels in the Arctic and in the western Pacific equatorial region, respectively. Processes to explain the gaps are proposed, including halogen-mediated destruction in the low latitudes. Our open data set will complement the TOAR data collection.
Yue Liu, Mei Zheng, Mingyuan Yu, Xuhui Cai, Huiyun Du, Jie Li, Tian Zhou, Caiqing Yan, Xuesong Wang, Zongbo Shi, Roy M. Harrison, Qiang Zhang, and Kebin He
Atmos. Chem. Phys., 19, 6595–6609, https://doi.org/10.5194/acp-19-6595-2019, https://doi.org/10.5194/acp-19-6595-2019, 2019
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This study is part of the UK–China APHH campaign. To identify both source types and source regions at the same time, this study developed a combined method including receptor model, footprint model, and air quality model for the first time to investigate sources of PM2.5 during haze episodes in Beijing. It is an expansion of the application of the receptor model and is helpful for formulating effective control strategies to improve air quality in this region.
Lu Shen, Daniel J. Jacob, Xiong Liu, Guanyu Huang, Ke Li, Hong Liao, and Tao Wang
Atmos. Chem. Phys., 19, 6551–6560, https://doi.org/10.5194/acp-19-6551-2019, https://doi.org/10.5194/acp-19-6551-2019, 2019
Jialin Li, Meigen Zhang, Guiqian Tang, Yele Sun, Fangkun Wu, and Yongfu Xu
Atmos. Chem. Phys., 19, 6481–6495, https://doi.org/10.5194/acp-19-6481-2019, https://doi.org/10.5194/acp-19-6481-2019, 2019
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There are large uncertainties in the sources of secondary organic aerosol (SOA). Simulations of SOA concentrations in China with aqueous SOA formation pathway updated and glyoxal simulation improved reveal that dicarbonyl-derived SOA (AAQ) can explain a significant fraction of the unaccounted SOA sources. The mean AAQ can contribute 60.6 % and 64.5 % to the total concentration of SOA in summer and fall, respectively.
Zainab Q. Hakim, Scott Archer-Nicholls, Gufran Beig, Gerd A. Folberth, Kengo Sudo, Nathan Luke Abraham, Sachin Ghude, Daven K. Henze, and Alexander T. Archibald
Atmos. Chem. Phys., 19, 6437–6458, https://doi.org/10.5194/acp-19-6437-2019, https://doi.org/10.5194/acp-19-6437-2019, 2019
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Surface ozone is an important air pollutant and recent work has calculated that large numbers of people die prematurely because of exposure to high levels of surface ozone in India. However, these calculations require model simulations of ozone as key inputs.
Here we perform the most thorough evaluation of global model surface ozone over India to date. These analyses of model simulations and observations highlight some successes and shortcomings and the need for further process-based studies.
Yonghong Wang, Yuesi Wang, Lili Wang, Tuukka Petäjä, Qiaozhi Zha, Chongshui Gong, Sixuan Li, Yuepeng Pan, Bo Hu, Jinyuan Xin, and Markku Kulmala
Atmos. Chem. Phys., 19, 5881–5888, https://doi.org/10.5194/acp-19-5881-2019, https://doi.org/10.5194/acp-19-5881-2019, 2019
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Satellite observations combined with in situ measurements demonstrate that increased inorganic aerosol fractions of NO2 and SO2 contribute to air pollution and frequently occurring haze in China from 1980 to 2010. Currently, the reduction of nitrate, sulfate and their precursor gases would contribute towards better visibility in China.
Zhenying Xu, Mingxu Liu, Minsi Zhang, Yu Song, Shuxiao Wang, Lin Zhang, Tingting Xu, Tiantian Wang, Caiqing Yan, Tian Zhou, Yele Sun, Yuepeng Pan, Min Hu, Mei Zheng, and Tong Zhu
Atmos. Chem. Phys., 19, 5605–5613, https://doi.org/10.5194/acp-19-5605-2019, https://doi.org/10.5194/acp-19-5605-2019, 2019
Xuan Wang, Daniel J. Jacob, Sebastian D. Eastham, Melissa P. Sulprizio, Lei Zhu, Qianjie Chen, Becky Alexander, Tomás Sherwen, Mathew J. Evans, Ben H. Lee, Jessica D. Haskins, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Gregory L. Huey, and Hong Liao
Atmos. Chem. Phys., 19, 3981–4003, https://doi.org/10.5194/acp-19-3981-2019, https://doi.org/10.5194/acp-19-3981-2019, 2019
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Chlorine radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a comprehensive simulation of tropospheric chlorine in a global 3-D model, which includes explicit accounting of chloride mobilization from sea salt aerosol. We find the chlorine chemistry contributes 1.0 % of the global oxidation of methane and decreases global burdens of tropospheric ozone by 7 % and OH by 3 % through the associated bromine radical chemistry.
Kai-Lan Chang, Owen R. Cooper, J. Jason West, Marc L. Serre, Martin G. Schultz, Meiyun Lin, Virginie Marécal, Béatrice Josse, Makoto Deushi, Kengo Sudo, Junhua Liu, and Christoph A. Keller
Geosci. Model Dev., 12, 955–978, https://doi.org/10.5194/gmd-12-955-2019, https://doi.org/10.5194/gmd-12-955-2019, 2019
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We developed a new method for combining surface ozone observations from thousands of monitoring sites worldwide with the output from multiple atmospheric chemistry models. The result is a global surface ozone distribution with greater accuracy than any single model can achieve. We focused on an ozone metric relevant to human mortality caused by long-term ozone exposure. Our method can be applied to studies that quantify the impacts of ozone on human health and mortality.
Hui Wang, Junmin Lin, Qizhong Wu, Huansheng Chen, Xiao Tang, Zifa Wang, Xueshun Chen, Huaqiong Cheng, and Lanning Wang
Geosci. Model Dev., 12, 749–764, https://doi.org/10.5194/gmd-12-749-2019, https://doi.org/10.5194/gmd-12-749-2019, 2019
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A new framework was designed for the widely used Carbon Bond Mechanism Z (CBM-Z) gas-phase chemical kinetics kernel to adapt the single-instruction, multiple-data (SIMD) technology in next-generation processors like Knights Landing (KNL) to improve their calculation performance. The optimization is aimed at implementing the fine-grain level parallelization of CBM-Z. The test results showed significant acceleration with our optimization on both CPU and KNL platforms.
Guo Li, Yafang Cheng, Uwe Kuhn, Rongjuan Xu, Yudong Yang, Hannah Meusel, Zhibin Wang, Nan Ma, Yusheng Wu, Meng Li, Jonathan Williams, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Hang Su
Atmos. Chem. Phys., 19, 2209–2232, https://doi.org/10.5194/acp-19-2209-2019, https://doi.org/10.5194/acp-19-2209-2019, 2019
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VOCs play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air–soil exchange of 13 VOCs at ambient air conditions of an urban background site in Beijing.
Junxi Zhang, Yang Gao, L. Ruby Leung, Kun Luo, Huan Liu, Jean-Francois Lamarque, Jianren Fan, Xiaohong Yao, Huiwang Gao, and Tatsuya Nagashima
Atmos. Chem. Phys., 19, 887–900, https://doi.org/10.5194/acp-19-887-2019, https://doi.org/10.5194/acp-19-887-2019, 2019
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ACCMIP simulations were used to study NOy deposition over East Asia in the future. Both dry and wet NOy deposition show significant decreases in the 2100s under RCP4.5 and RCP8.5 due to large anthropogenic emission reduction. The changes in climate only significantly affect the wet deposition primarily linked to changes in precipitation. Over the coastal seas of China, weaker transport of NOy from land due to emission reduction infers a larger impact from shipping and lightning emissions.
Hajime Akimoto, Tatsuya Nagashima, Jie Li, Joshua S. Fu, Dongsheng Ji, Jiani Tan, and Zifa Wang
Atmos. Chem. Phys., 19, 603–615, https://doi.org/10.5194/acp-19-603-2019, https://doi.org/10.5194/acp-19-603-2019, 2019
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The regional model intercomparison study called MICS-Asia III revealed that substantial discrepancy still exists for surface ozone simulation in East Asia, even though common emissions, meteorological field, and boundary conditions have been used among the models. Three factors have been identified as possible causes of such discrepancy, (1) chemistry sub-models, (2) heterogeneous reactions, and (3) vertical transport parameters, and each component has been discussed.
Xiaole Pan, Baozhu Ge, Zhe Wang, Yu Tian, Hang Liu, Lianfang Wei, Siyao Yue, Itsushi Uno, Hiroshi Kobayashi, Tomoaki Nishizawa, Atsushi Shimizu, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 19, 219–232, https://doi.org/10.5194/acp-19-219-2019, https://doi.org/10.5194/acp-19-219-2019, 2019
Conghui Xie, Weiqi Xu, Junfeng Wang, Qingqing Wang, Dantong Liu, Guiqian Tang, Ping Chen, Wei Du, Jian Zhao, Yingjie Zhang, Wei Zhou, Tingting Han, Qingyun Bian, Jie Li, Pingqing Fu, Zifa Wang, Xinlei Ge, James Allan, Hugh Coe, and Yele Sun
Atmos. Chem. Phys., 19, 165–179, https://doi.org/10.5194/acp-19-165-2019, https://doi.org/10.5194/acp-19-165-2019, 2019
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We present the first simultaneous real-time online measurements of aerosol optical properties at ground level and at 260 m on a meteorological tower in urban Beijing in winter. The vertical similarities and differences in scattering and absorption coefficients were characterized. The increases in MAC of BC were mainly associated with the coating materials on rBC. Coal combustion was the dominant source contribution of brown carbon followed by biomass burning and SOA in winter in Beijing.
Yu Tian, Xiaole Pan, Tomoaki Nishizawa, Hiroshi Kobayashi, Itsushi Uno, Xiquan Wang, Atsushi Shimizu, and Zifa Wang
Atmos. Chem. Phys., 18, 18203–18217, https://doi.org/10.5194/acp-18-18203-2018, https://doi.org/10.5194/acp-18-18203-2018, 2018
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East Asia is characterized by severe anthropogenic pollution and dust storms due to fuel consumption and the downwind location of dust sources. We studied the mixing states of dust and pollutants using an optical particle counter equipped with a polarization detection module, providing a deeper understanding of possible mechanisms of aerosols’ morphological change. In Beijing, the heterogeneous processes in the mixture of dust and emitted pollutants have a great influence on smog formation.
Mingxu Liu, Xin Huang, Yu Song, Tingting Xu, Shuxiao Wang, Zhijun Wu, Min Hu, Lin Zhang, Qiang Zhang, Yuepeng Pan, Xuejun Liu, and Tong Zhu
Atmos. Chem. Phys., 18, 17933–17943, https://doi.org/10.5194/acp-18-17933-2018, https://doi.org/10.5194/acp-18-17933-2018, 2018
Xinyi Dong, Joshua S. Fu, Qingzhao Zhu, Jian Sun, Jiani Tan, Terry Keating, Takashi Sekiya, Kengo Sudo, Louisa Emmons, Simone Tilmes, Jan Eiof Jonson, Michael Schulz, Huisheng Bian, Mian Chin, Yanko Davila, Daven Henze, Toshihiko Takemura, Anna Maria Katarina Benedictow, and Kan Huang
Atmos. Chem. Phys., 18, 15581–15600, https://doi.org/10.5194/acp-18-15581-2018, https://doi.org/10.5194/acp-18-15581-2018, 2018
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We have applied the HTAP phase II multi-model data to investigate the long-range transport impacts on surface concentration and column density of PM from Europe and Russia, Belarus, and Ukraine to eastern Asia, with a special focus on the long-range transport contribution during haze episodes in China. We found that long-range transport plays a more important role in elevating the background concentration of surface PM during the haze days.
Hansen Cao, Tzung-May Fu, Lin Zhang, Daven K. Henze, Christopher Chan Miller, Christophe Lerot, Gonzalo González Abad, Isabelle De Smedt, Qiang Zhang, Michel van Roozendael, François Hendrick, Kelly Chance, Jie Li, Junyu Zheng, and Yuanhong Zhao
Atmos. Chem. Phys., 18, 15017–15046, https://doi.org/10.5194/acp-18-15017-2018, https://doi.org/10.5194/acp-18-15017-2018, 2018
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Our top-down estimates for annual total Chinese NMVOC emissions was 30.7 to 49.5 Tg y−1, including 16.4 to 23.6 Tg y−1 from anthropogenic sources, 12.2 to 22.8 Tg y−1 from biogenic sources, and 2.08 to 3.13 Tg y−1 from biomass burning. Our four inversions consistently showed that the emissions of Chinese anthropogenic NMVOC precursors of glyoxal were larger than the a priori estimates. The glyoxal and formaldehyde constraints helped distinguish the NMVOC species from different sources.
Lei Liu, Jian Zhang, Liang Xu, Qi Yuan, Dao Huang, Jianmin Chen, Zongbo Shi, Yele Sun, Pingqing Fu, Zifa Wang, Daizhou Zhang, and Weijun Li
Atmos. Chem. Phys., 18, 14681–14693, https://doi.org/10.5194/acp-18-14681-2018, https://doi.org/10.5194/acp-18-14681-2018, 2018
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Using transmission electron microscopy, we studied individual cloud droplet residual and interstitial particles collected in cloud events at Mt. Tai in the polluted North China region. We found that individual cloud droplets were an extremely complicated mixture containing abundant refractory soot (i.e., black carbon), fly ash, and metals. The complicated cloud droplets have not been reported in clean continental or marine air before.
Mingjie Kang, Pingqing Fu, Kimitaka Kawamura, Fan Yang, Hongliang Zhang, Zhengchen Zang, Hong Ren, Lujie Ren, Ye Zhao, Yele Sun, and Zifa Wang
Atmos. Chem. Phys., 18, 13947–13967, https://doi.org/10.5194/acp-18-13947-2018, https://doi.org/10.5194/acp-18-13947-2018, 2018
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Molecular characterization and spatial distribution of biogenic primary organic aerosol (POA) and secondary organic aerosol (SOA) in the marine atmosphere are not well known. Here, we analysed the organic molecular composition of marine aerosols collected during a marine cruise in the East China Sea during May–June 2014. Our results suggest that the Asian continent can be a natural emitter of biogenic POA and SOA, which can be transported to the downwind marine atmosphere.
Jan Eiof Jonson, Michael Schulz, Louisa Emmons, Johannes Flemming, Daven Henze, Kengo Sudo, Marianne Tronstad Lund, Meiyun Lin, Anna Benedictow, Brigitte Koffi, Frank Dentener, Terry Keating, Rigel Kivi, and Yanko Davila
Atmos. Chem. Phys., 18, 13655–13672, https://doi.org/10.5194/acp-18-13655-2018, https://doi.org/10.5194/acp-18-13655-2018, 2018
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Focusing on Europe, this HTAP 2 study computes ozone in several global models when reducing anthropogenic emissions by 20 % in different world regions. The differences in model results are explored
by use of a novel stepwise approach combining a tracer, CO and ozone. For ozone the contributions from the rest of the world are larger than from Europe, with the largest contributions from North America and eastern Asia. Contributions do, however, depend on the choice of ozone metric.
Jiani Tan, Joshua S. Fu, Frank Dentener, Jian Sun, Louisa Emmons, Simone Tilmes, Johannes Flemming, Toshihiko Takemura, Huisheng Bian, Qingzhao Zhu, Cheng-En Yang, and Terry Keating
Atmos. Chem. Phys., 18, 12223–12240, https://doi.org/10.5194/acp-18-12223-2018, https://doi.org/10.5194/acp-18-12223-2018, 2018
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Have contributions of hemispheric air pollution to deposition at global scale been overlooked in the past years? How do we assess the critical load for the acid deposition when we look for the demand of forest and crop? This study highlights the significant impact of hemispheric transport on deposition in coastal regions, open ocean and low-emission regions. Further research is proposed for improving ecosystem and human health in these regions, with regards to the enhanced hemispheric transport.
Xiao Han, Lingyun Zhu, Shulan Wang, Xiaoyan Meng, Meigen Zhang, and Jun Hu
Atmos. Chem. Phys., 18, 12207–12221, https://doi.org/10.5194/acp-18-12207-2018, https://doi.org/10.5194/acp-18-12207-2018, 2018
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In this paper, we applied an air quality modeling system called RAMS-CMAQ coupled with the ISAM module to investigate the regional contributions of O3 among major regions of the NCP and to quantify the relative amount of O3 originating from specific VOC and NOx emissions sources. The modeling system allows us to capture valuable information regarding how to choose the correct sequence and efficient combinations by exploring the key thresholds from the bulk of sensitivity tests.
Pakawat Phalitnonkiat, Peter G. M. Hess, Mircea D. Grigoriu, Gennady Samorodnitsky, Wenxiu Sun, Ellie Beaudry, Simone Tilmes, Makato Deushi, Beatrice Josse, David Plummer, and Kengo Sudo
Atmos. Chem. Phys., 18, 11927–11948, https://doi.org/10.5194/acp-18-11927-2018, https://doi.org/10.5194/acp-18-11927-2018, 2018
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The co-occurrence of heat waves and pollution events and the resulting high mortality rates emphasize the importance of the co-occurrence of pollution and temperature extremes. We analyze ozone and temperature extremes and their joint occurrence over the United States during the summer months (JJA) in measurement data and in model simulations of the present and future climates.
Wei Zhou, Jian Zhao, Bin Ouyang, Archit Mehra, Weiqi Xu, Yuying Wang, Thomas J. Bannan, Stephen D. Worrall, Michael Priestley, Asan Bacak, Qi Chen, Conghui Xie, Qingqing Wang, Junfeng Wang, Wei Du, Yingjie Zhang, Xinlei Ge, Penglin Ye, James D. Lee, Pingqing Fu, Zifa Wang, Douglas Worsnop, Roderic Jones, Carl J. Percival, Hugh Coe, and Yele Sun
Atmos. Chem. Phys., 18, 11581–11597, https://doi.org/10.5194/acp-18-11581-2018, https://doi.org/10.5194/acp-18-11581-2018, 2018
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We present measurements of gas-phase N2O5 and ClNO2 by ToF-CIMS during summer in urban Beijing as part of the APHH campaign. High reactivity of N2O5 indicative of active nocturnal chemistry was observed. The lifetime of N2O5 as a function of aerosol surface area and relative humidity was characterized, and N2O5 uptake coefficients were estimated. We also found that the N2O5 loss in this study is mainly attributed to its indirect loss via reactions of NO3 with VOCs and NO.
Shiguo Jia, Xuemei Wang, Qi Zhang, Sayantan Sarkar, Luolin Wu, Minjuan Huang, Jinpu Zhang, and Liming Yang
Atmos. Chem. Phys., 18, 11125–11133, https://doi.org/10.5194/acp-18-11125-2018, https://doi.org/10.5194/acp-18-11125-2018, 2018
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Aerosol pH are often directly compared across studies while ignoring the inconsistency in standard states. This study attempts to address this issue by comparing aerosol pH with different standard states on the basis of theoretical considerations followed with a set of field data as an example. Application of a pH standardization protocol including a precise statement of thermodynamic model parameters is recommended to avoid biases in cross-comparison.
Wen Xu, Lei Liu, Miaomiao Cheng, Yuanhong Zhao, Lin Zhang, Yuepeng Pan, Xiuming Zhang, Baojing Gu, Yi Li, Xiuying Zhang, Jianlin Shen, Li Lu, Xiaosheng Luo, Yu Zhao, Zhaozhong Feng, Jeffrey L. Collett Jr., Fusuo Zhang, and Xuejun Liu
Atmos. Chem. Phys., 18, 10931–10954, https://doi.org/10.5194/acp-18-10931-2018, https://doi.org/10.5194/acp-18-10931-2018, 2018
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Our main results demonstrate that atmospheric Nr pollution in eastern China is more serious in the northern region than in the southern region. Any effects of current emission controls are not yet apparent in Nr pollution. NH3 emissions from fertilizer use were the largest contributor (36 %) to total inorganic Nr deposition. Our results provide useful information for policy-makers that mitigation of NH3 emissions should be a priority to tackle serious N deposition.
Ciao-Kai Liang, J. Jason West, Raquel A. Silva, Huisheng Bian, Mian Chin, Yanko Davila, Frank J. Dentener, Louisa Emmons, Johannes Flemming, Gerd Folberth, Daven Henze, Ulas Im, Jan Eiof Jonson, Terry J. Keating, Tom Kucsera, Allen Lenzen, Meiyun Lin, Marianne Tronstad Lund, Xiaohua Pan, Rokjin J. Park, R. Bradley Pierce, Takashi Sekiya, Kengo Sudo, and Toshihiko Takemura
Atmos. Chem. Phys., 18, 10497–10520, https://doi.org/10.5194/acp-18-10497-2018, https://doi.org/10.5194/acp-18-10497-2018, 2018
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Emissions from one continent affect air quality and health elsewhere. Here we quantify the effects of intercontinental PM2.5 and ozone transport on human health using a new multi-model ensemble, evaluating the health effects of emissions from six world regions and three emission source sectors. Emissions from one region have significant health impacts outside of that source region; similarly, foreign emissions contribute significantly to air-pollution-related deaths in several world regions.
Yuxuan Zhang, Xin Li, Meng Li, Yixuan Zheng, Guannan Geng, Chaopeng Hong, Haiyan Li, Dan Tong, Xin Zhang, Yafang Cheng, Hang Su, Kebin He, and Qiang Zhang
Atmos. Chem. Phys., 18, 10275–10287, https://doi.org/10.5194/acp-18-10275-2018, https://doi.org/10.5194/acp-18-10275-2018, 2018
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When emission controls were implemented during APEC, we found that the reduction in BC light absorption was driven by simultaneously reducing the mass concentration and light-absorption capability of BC. The weakening of BC light-absorption capability could be attributed to less coating material on BC surfaces due to the decreased chemical production of secondary aerosols. Our results imply that a synergetic reduction in multiple-pollutant emissions could benefit both air quality and climate.
Yuxuan Zhang, Qiang Zhang, Yafang Cheng, Hang Su, Haiyan Li, Meng Li, Xin Zhang, Aijun Ding, and Kebin He
Atmos. Chem. Phys., 18, 9879–9896, https://doi.org/10.5194/acp-18-9879-2018, https://doi.org/10.5194/acp-18-9879-2018, 2018
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The light absorption of BC-containing particles strongly depends on their aging process in the atmosphere. Whether and how the aging degree and light absorption capability of BC-containing particles will change with air pollution development is still unclear. Our results reveal that under a more polluted environment, the BC-containing particles are characterized not only by higher BC mass concentrations but also by more coating materials on BC surfaces and thus higher light absorption capacity.
Hui Wang, Qizhong Wu, Hongjun Liu, Yuanlin Wang, Huaqiong Cheng, Rongrong Wang, Lanning Wang, Han Xiao, and Xiaochun Yang
Atmos. Chem. Phys., 18, 9583–9596, https://doi.org/10.5194/acp-18-9583-2018, https://doi.org/10.5194/acp-18-9583-2018, 2018
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The Beijing area has suffered from severe air quality pollution in recent years, including ozone pollution in summer. BVOC emissions play a non-negligible role in air quality and climate. Since the forest cover rate increased from 20.6 % to 35.8 % during 1998–2013 in Beijing, we presented a new estimation of local BVOC emissions in a current scenario based on the latest emission model MEGAN v2.1 and also adopted diverse input datasets for the sensitivities of the model and results.
Zirui Liu, Wenkang Gao, Yangchun Yu, Bo Hu, Jinyuan Xin, Yang Sun, Lili Wang, Gehui Wang, Xinhui Bi, Guohua Zhang, Honghui Xu, Zhiyuan Cong, Jun He, Jingsha Xu, and Yuesi Wang
Atmos. Chem. Phys., 18, 8849–8871, https://doi.org/10.5194/acp-18-8849-2018, https://doi.org/10.5194/acp-18-8849-2018, 2018
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We have established a national-level network (CARE-China) that conducted continuous monitoring of PM2.5 and its chemical compositions in China. Our analysis reveals the spatial and seasonal variabilities of the urban and background aerosol species and their contributions to the PM2.5 budget. The integration of data provided an extensive spatial coverage of fine-particle concentrations and could be used to validate model results and implement effective air pollution control strategies.
Stefano Galmarini, Ioannis Kioutsioukis, Efisio Solazzo, Ummugulsum Alyuz, Alessandra Balzarini, Roberto Bellasio, Anna M. K. Benedictow, Roberto Bianconi, Johannes Bieser, Joergen Brandt, Jesper H. Christensen, Augustin Colette, Gabriele Curci, Yanko Davila, Xinyi Dong, Johannes Flemming, Xavier Francis, Andrea Fraser, Joshua Fu, Daven K. Henze, Christian Hogrefe, Ulas Im, Marta Garcia Vivanco, Pedro Jiménez-Guerrero, Jan Eiof Jonson, Nutthida Kitwiroon, Astrid Manders, Rohit Mathur, Laura Palacios-Peña, Guido Pirovano, Luca Pozzoli, Marie Prank, Martin Schultz, Rajeet S. Sokhi, Kengo Sudo, Paolo Tuccella, Toshihiko Takemura, Takashi Sekiya, and Alper Unal
Atmos. Chem. Phys., 18, 8727–8744, https://doi.org/10.5194/acp-18-8727-2018, https://doi.org/10.5194/acp-18-8727-2018, 2018
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An ensemble of model results relating to ozone concentrations in Europe in 2010 has been produced and studied. The novelty consists in the fact that the ensemble is made of results of models working at two different scales (regional and global), therefore contributing in detail two different parts of the atmospheric spectrum. The ensemble defined as a hybrid has been studied in detail and shown to bring additional value to the assessment of air quality.
Mizuo Kajino, Makoto Deushi, Tsuyoshi Thomas Sekiyama, Naga Oshima, Keiya Yumimoto, Taichu Yasumichi Tanaka, Joseph Ching, Akihiro Hashimoto, Tetsuya Yamamoto, Masaaki Ikegami, Akane Kamada, Makoto Miyashita, Yayoi Inomata, Shin-ichiro Shima, Kouji Adachi, Yuji Zaizen, Yasuhito Igarashi, Hiromasa Ueda, Takashi Maki, and Masao Mikami
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2018-128, https://doi.org/10.5194/gmd-2018-128, 2018
Revised manuscript not accepted
Yele Sun, Weiqi Xu, Qi Zhang, Qi Jiang, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Jie Li, John Jayne, Douglas R. Worsnop, and Zifa Wang
Atmos. Chem. Phys., 18, 8469–8489, https://doi.org/10.5194/acp-18-8469-2018, https://doi.org/10.5194/acp-18-8469-2018, 2018
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We present a 2–year analysis of organic aerosol (OA) from highly time–resolved measurements by an aerosol chemical speciation monitor in the megacity of Beijing. The sources of OA were analyzed with the advanced factor analysis of a multilinear engine (ME-2). Our results showed very different seasonal patterns, relative humidity and temperature dependence, and sources regions among different OA factors. The sources and processes of OA factors, and their roles in haze pollution are elucidated.
Sandip S. Dhomse, Douglas Kinnison, Martyn P. Chipperfield, Ross J. Salawitch, Irene Cionni, Michaela I. Hegglin, N. Luke Abraham, Hideharu Akiyoshi, Alex T. Archibald, Ewa M. Bednarz, Slimane Bekki, Peter Braesicke, Neal Butchart, Martin Dameris, Makoto Deushi, Stacey Frith, Steven C. Hardiman, Birgit Hassler, Larry W. Horowitz, Rong-Ming Hu, Patrick Jöckel, Beatrice Josse, Oliver Kirner, Stefanie Kremser, Ulrike Langematz, Jared Lewis, Marion Marchand, Meiyun Lin, Eva Mancini, Virginie Marécal, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke Oman, Giovanni Pitari, David A. Plummer, John A. Pyle, Laura E. Revell, Eugene Rozanov, Robyn Schofield, Andrea Stenke, Kane Stone, Kengo Sudo, Simone Tilmes, Daniele Visioni, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys., 18, 8409–8438, https://doi.org/10.5194/acp-18-8409-2018, https://doi.org/10.5194/acp-18-8409-2018, 2018
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We analyse simulations from the Chemistry-Climate Model Initiative (CCMI) to estimate the return dates of the stratospheric ozone layer from depletion by anthropogenic chlorine and bromine. The simulations from 20 models project that global column ozone will return to 1980 values in 2047 (uncertainty range 2042–2052). Return dates in other regions vary depending on factors related to climate change and importance of chlorine and bromine. Column ozone in the tropics may continue to decline.
Xiao-Xiao Zhang, Brenton Sharratt, Lian-You Liu, Zi-Fa Wang, Xiao-Le Pan, Jia-Qiang Lei, Shi-Xin Wu, Shuang-Yan Huang, Yu-Hong Guo, Jie Li, Xiao Tang, Ting Yang, Yu Tian, Xue-Shun Chen, Jian-Qi Hao, Hai-Tao Zheng, Yan-Yan Yang, and Yan-Li Lyu
Atmos. Chem. Phys., 18, 8353–8371, https://doi.org/10.5194/acp-18-8353-2018, https://doi.org/10.5194/acp-18-8353-2018, 2018
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The impact of a strong East Asian dust event during 2–7 May 2017 was quantified and assessed based upon environmental observations, lidar measurements, and satellite products along with simulation techniques. This dust storm impacted a wide area of China and other Asian nations and reached North America within 1 week. Dust storms are a significant contributor to the global dust budget. Asian dust storms such as that observed in early May 2017 may lead to wider climate forcing on a global scale.
Nan Li, Qingyang He, Jim Greenberg, Alex Guenther, Jingyi Li, Junji Cao, Jun Wang, Hong Liao, Qiyuan Wang, and Qiang Zhang
Atmos. Chem. Phys., 18, 7489–7507, https://doi.org/10.5194/acp-18-7489-2018, https://doi.org/10.5194/acp-18-7489-2018, 2018
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O3 pollution has been increasing in most Chinese cities in recent years. Our study reveals that the synergistic impact of individual source contributions to O3 formation should be considered in the formation of air pollution control strategies, especially for big cities in the vicinity of forests.
Jiani Tan, Joshua S. Fu, Frank Dentener, Jian Sun, Louisa Emmons, Simone Tilmes, Kengo Sudo, Johannes Flemming, Jan Eiof Jonson, Sylvie Gravel, Huisheng Bian, Yanko Davila, Daven K. Henze, Marianne T. Lund, Tom Kucsera, Toshihiko Takemura, and Terry Keating
Atmos. Chem. Phys., 18, 6847–6866, https://doi.org/10.5194/acp-18-6847-2018, https://doi.org/10.5194/acp-18-6847-2018, 2018
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We study the distributions of sulfur and nitrogen deposition, which are associated with current environmental issues such as formation of acid rain and ecosystem eutrophication and result in widespread problems such as loss of environmental diversity, harming the crop yield and even food insecurity. According to our study, both the amount and distribution of sulfate and nitrogen deposition have changed significantly in the last decade, particularly in East Asia, South Asia and Southeast Asia.
Xiaowan Zhu, Guiqian Tang, Jianping Guo, Bo Hu, Tao Song, Lili Wang, Jinyuan Xin, Wenkang Gao, Christoph Münkel, Klaus Schäfer, Xin Li, and Yuesi Wang
Atmos. Chem. Phys., 18, 4897–4910, https://doi.org/10.5194/acp-18-4897-2018, https://doi.org/10.5194/acp-18-4897-2018, 2018
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Our study first conducted a long-term observation of mixing layer height (MLH) with high resolution on the North China Plain (NCP), analyzed the spatiotemporal variations of regional MLH, investigated the reasons for MLH differences in the NCP and revealed the meteorological reasons for heavy haze pollution in southern Hebei. The study results provide scientific suggestions for regional industrial structure readjustment and have great importance for achieving the integrated development goals.
Meng Gao, Zhiwei Han, Zirui Liu, Meng Li, Jinyuan Xin, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Yafang Cheng, Yuesi Wang, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Jung-Hun Woo, Qiang Zhang, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 18, 4859–4884, https://doi.org/10.5194/acp-18-4859-2018, https://doi.org/10.5194/acp-18-4859-2018, 2018
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Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative and microphysical feedbacks. A comprehensive overview of the MICS-ASIA III Topic 3 study design is presented.
Wei Zhou, Qingqing Wang, Xiujuan Zhao, Weiqi Xu, Chen Chen, Wei Du, Jian Zhao, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 18, 3951–3968, https://doi.org/10.5194/acp-18-3951-2018, https://doi.org/10.5194/acp-18-3951-2018, 2018
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We present a 3-month analysis of submicron aerosols that were measured at 260 m on a meteorological tower in Beijing, China. The sources of organic aerosol (OA) were analyzed by using a multi-linear engine (ME-2). Our results showed significant changes in both primary and secondary OA composition from the non-heating season to the heating season. We also observed a considerable contribution (10–13%) of cooking OA at 260 m and very different OA composition between ground level and 260 m.
Takashi Sekiya, Kazuyuki Miyazaki, Koji Ogochi, Kengo Sudo, and Masayuki Takigawa
Geosci. Model Dev., 11, 959–988, https://doi.org/10.5194/gmd-11-959-2018, https://doi.org/10.5194/gmd-11-959-2018, 2018
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We evaluate global tropospheric NO2 simulations using a chemical transport model (CTM) at horizontal resolutions of 0.56, 1.1, and 2.8°. Agreement against satellite retrievals improved greatly at 0.56 and 1.1° resolutions (compared to 2.8°) over polluted and biomass burning regions, especially over areas with strong local sources, such as a megacity. The evaluations demonstrate the potential of using a high-resolution global CTM for studying megacity-scale air pollutants across the entire globe.
Qiongzhen Wang, Xinyi Dong, Joshua S. Fu, Jian Xu, Congrui Deng, Yilun Jiang, Qingyan Fu, Yanfen Lin, Kan Huang, and Guoshun Zhuang
Atmos. Chem. Phys., 18, 3505–3521, https://doi.org/10.5194/acp-18-3505-2018, https://doi.org/10.5194/acp-18-3505-2018, 2018
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A synergy of ground-based atmospheric chemistry observation, lidar, and numerical modeling was used to investigate a super dust event passing over Shanghai. The degree of dust that was modified by anthropogenic sources highly depended on the transport pathways. A community regional air quality model with improved dust scheme reproduced reasonable dust chemistry results. The chemical and optical properties of evolving dust are crucial for evaluating the climatic effects of dust.
Meng Li, Zbigniew Klimont, Qiang Zhang, Randall V. Martin, Bo Zheng, Chris Heyes, Janusz Cofala, Yuxuan Zhang, and Kebin He
Atmos. Chem. Phys., 18, 3433–3456, https://doi.org/10.5194/acp-18-3433-2018, https://doi.org/10.5194/acp-18-3433-2018, 2018
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In this paper, we conducted a comprehensive evaluation of two widely used anthropogenic emission inventories over China, ECLIPSE and MIX, to explore the potential sources of uncertainties and find clues to improving emission inventories. We found that SO2 emission estimates are consistent between the two inventories (with 1 % differences), while NOx emissions in ECLIPSE's estimates are 16 % lower than those in MIX. Discrepancies at the sector and provincial levels are much higher.
Syuichi Itahashi, Keiya Yumimoto, Itsushi Uno, Hiroshi Hayami, Shin-ichi Fujita, Yuepeng Pan, and Yuesi Wang
Atmos. Chem. Phys., 18, 2835–2852, https://doi.org/10.5194/acp-18-2835-2018, https://doi.org/10.5194/acp-18-2835-2018, 2018
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Ground-based observations of precipitation chemistry over China, Korea, and Japan from 2001 to 2015 were compiled, and the ratio of nitrate to non-sea-salt sulfate concentration in precipitation was analyzed to identify the long-term record of acidifying species. The variations in the ratio in East Asia corresponded to the NOx / SO2 emission ratio and the NO2 / SO2 column ratio in China. The results indicated that the acidity of precipitation shifted from sulfur to nitrogen.
Wanyu Zhao, Kimitaka Kawamura, Siyao Yue, Lianfang Wei, Hong Ren, Yu Yan, Mingjie Kang, Linjie Li, Lujie Ren, Senchao Lai, Jie Li, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 18, 2749–2767, https://doi.org/10.5194/acp-18-2749-2018, https://doi.org/10.5194/acp-18-2749-2018, 2018
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In this paper, we investigate the seasonal trends in concentrations and compound-specific stable carbon isotope ratios of low molecular weight dicarboxylic acids (C2–C12) and related compounds in fine aerosols (PM2.5) in Beijing. Our study demonstrates that, in addition to the production via photo-oxidation, high abundances of diacids and related compounds in Beijing are largely associated with anthropogenic primary emissions such as biomass burning, fossil fuel combustion and plastic burning.
Qingqing Wang, Yele Sun, Weiqi Xu, Wei Du, Libo Zhou, Guiqian Tang, Chen Chen, Xueling Cheng, Xiujuan Zhao, Dongsheng Ji, Tingting Han, Zhe Wang, Jie Li, and Zifa Wang
Atmos. Chem. Phys., 18, 2495–2509, https://doi.org/10.5194/acp-18-2495-2018, https://doi.org/10.5194/acp-18-2495-2018, 2018
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We conducted the first real-time continuous vertical measurements of particle extinction, NO2, and BC from ground level to 260 m during two severe winter haze episodes in urban Beijing, China. Our results show very complex and dynamic vertical profiles that interact closely with boundary layer and meteorological conditions. Further analysis demonstrate that vertical convection, temperature inversion, and local emissions are three major factors affecting the changes in vertical profiles.
Shengzhen Zhou, Perry K. Davy, Minjuan Huang, Jingbo Duan, Xuemei Wang, Qi Fan, Ming Chang, Yiming Liu, Weihua Chen, Shanju Xie, Travis Ancelet, and William J. Trompetter
Atmos. Chem. Phys., 18, 2049–2064, https://doi.org/10.5194/acp-18-2049-2018, https://doi.org/10.5194/acp-18-2049-2018, 2018
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We collected hourly samples of PM2.5 and PM2.5–10 at an industrial city in the PRD, China. The samples were analyzed for black carbon and elemental compositions. Receptor modeling of the dataset by positive matrix factorization was used to identify PM sources. Human health exposure risks to the selected trace elements in PM released from the specific sources were estimated. The source–risk apportionment method helps decision makers to manage air quality more effectively.
Rachel M. Hoesly, Steven J. Smith, Leyang Feng, Zbigniew Klimont, Greet Janssens-Maenhout, Tyler Pitkanen, Jonathan J. Seibert, Linh Vu, Robert J. Andres, Ryan M. Bolt, Tami C. Bond, Laura Dawidowski, Nazar Kholod, June-ichi Kurokawa, Meng Li, Liang Liu, Zifeng Lu, Maria Cecilia P. Moura, Patrick R. O'Rourke, and Qiang Zhang
Geosci. Model Dev., 11, 369–408, https://doi.org/10.5194/gmd-11-369-2018, https://doi.org/10.5194/gmd-11-369-2018, 2018
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Historical emission trends are key inputs to Earth systems and atmospheric chemistry models. We present a new data set of historical (1750–2014) anthropogenic gases (CO, CH4, NH3, NOx, SO2, NMVOCs, BC, OC, and CO2) developed with the Community Emissions Data System (CEDS). This improves on existing inventories as it uses consistent methods and data across emissions species, has annual resolution for a longer and more recent time series, and is designed to be transparent and reproducible.
Olaf Morgenstern, Kane A. Stone, Robyn Schofield, Hideharu Akiyoshi, Yousuke Yamashita, Douglas E. Kinnison, Rolando R. Garcia, Kengo Sudo, David A. Plummer, John Scinocca, Luke D. Oman, Michael E. Manyin, Guang Zeng, Eugene Rozanov, Andrea Stenke, Laura E. Revell, Giovanni Pitari, Eva Mancini, Glauco Di Genova, Daniele Visioni, Sandip S. Dhomse, and Martyn P. Chipperfield
Atmos. Chem. Phys., 18, 1091–1114, https://doi.org/10.5194/acp-18-1091-2018, https://doi.org/10.5194/acp-18-1091-2018, 2018
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We assess how ozone as simulated by a group of chemistry–climate models responds to variations in man-made climate gases and ozone-depleting substances. We find some agreement, particularly in the middle and upper stratosphere, but also considerable disagreement elsewhere. Such disagreement affects the reliability of future ozone projections based on these models, and also constitutes a source of uncertainty in climate projections using prescribed ozone derived from these simulations.
Lin Zhang, Youfan Chen, Yuanhong Zhao, Daven K. Henze, Liye Zhu, Yu Song, Fabien Paulot, Xuejun Liu, Yuepeng Pan, Yi Lin, and Binxiang Huang
Atmos. Chem. Phys., 18, 339–355, https://doi.org/10.5194/acp-18-339-2018, https://doi.org/10.5194/acp-18-339-2018, 2018
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Substantial differences exist in current estimates of agricultural ammonia emissions in China, hindering understanding of their environmental consequences. This study applies both bottom-up and top-down methods to better quantify agricultural ammonia sources in China using observations from satellite and surface networks interpreted by a chemical transport model. Our estimate of annual Chinese anthropogenic ammonia emission is 11.7 tg (teragram) for 2008 with a strong seasonality peak in summer.
Zhaoyang Meng, Xiaobin Xu, Weili Lin, Baozhu Ge, Yulin Xie, Bo Song, Shihui Jia, Rui Zhang, Wei Peng, Ying Wang, Hongbing Cheng, Wen Yang, and Huarong Zhao
Atmos. Chem. Phys., 18, 167–184, https://doi.org/10.5194/acp-18-167-2018, https://doi.org/10.5194/acp-18-167-2018, 2018
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This paper presents simultaneous measurements of NH3, other trace gases, and water-soluble ions in PM2.5 from May to September 2013 at a rural site in the North China Plain. Atmospheric ammonia and related parameters are characterised and the impact of ammonia on formation of secondary aerosols is investigated. The results presented in this paper may improve our understanding of the role of ammonia in aerosol formation.
Itsushi Uno, Kazuo Osada, Keiya Yumimoto, Zhe Wang, Syuichi Itahashi, Xiaole Pan, Yukari Hara, Yugo Kanaya, Shigekazu Yamamoto, and Thomas Duncan Fairlie
Atmos. Chem. Phys., 17, 14181–14197, https://doi.org/10.5194/acp-17-14181-2017, https://doi.org/10.5194/acp-17-14181-2017, 2017
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We analyzed long-term fine- and coarse-mode nitrate and related aerosols synergetic observations at Fukuoka, Japan. GEOS Chem model including dust and sea-salt acid uptake processes was used to assess the observed seasonal variation, and the impact of long-range transport from the Asian continent. A numerical model reproduced the seasonal variations of fine aerosols. For coarse nitrate, large-scale dust-nitrate outflow from China was confirmed during all dust events between January and June.
Xiaole Pan, Yugo Kanaya, Fumikazu Taketani, Takuma Miyakawa, Satoshi Inomata, Yuichi Komazaki, Hiroshi Tanimoto, Zhe Wang, Itsushi Uno, and Zifa Wang
Atmos. Chem. Phys., 17, 13001–13016, https://doi.org/10.5194/acp-17-13001-2017, https://doi.org/10.5194/acp-17-13001-2017, 2017
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Characteristics of refractory black carbon (rBC) from open biomass burning (OBB) have a great impact on regional pollution and climate, in particular in East Asia. However, experimental study on characteristics of rBC from agricultural residue burning in East China was limited. This study performed laboratory experiments: we found that emission of rBC is highly related to flaming burning, and non-rBC to smoldering burning. Rapid condensation of semi-volatile organics resulted in coated rBC.
Huisheng Bian, Mian Chin, Didier A. Hauglustaine, Michael Schulz, Gunnar Myhre, Susanne E. Bauer, Marianne T. Lund, Vlassis A. Karydis, Tom L. Kucsera, Xiaohua Pan, Andrea Pozzer, Ragnhild B. Skeie, Stephen D. Steenrod, Kengo Sudo, Kostas Tsigaridis, Alexandra P. Tsimpidi, and Svetlana G. Tsyro
Atmos. Chem. Phys., 17, 12911–12940, https://doi.org/10.5194/acp-17-12911-2017, https://doi.org/10.5194/acp-17-12911-2017, 2017
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Atmospheric nitrate contributes notably to total aerosol mass in the present day and is likely to be more important over the next century, with a projected decline in SO2 and NOx emissions and increase in NH3 emissions. This paper investigates atmospheric nitrate using multiple global models and measurements. The study is part of the AeroCom phase III activity. The study is the first attempt to look at global atmospheric nitrate simulation at physical and chemical process levels.
Xiaojuan Huang, Zirui Liu, Jingyun Liu, Bo Hu, Tianxue Wen, Guiqian Tang, Junke Zhang, Fangkun Wu, Dongsheng Ji, Lili Wang, and Yuesi Wang
Atmos. Chem. Phys., 17, 12941–12962, https://doi.org/10.5194/acp-17-12941-2017, https://doi.org/10.5194/acp-17-12941-2017, 2017
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Recently, haze pollution has frequently occurred in North China. Therefore, we conducted synchronous measurements of PM2.5 for 1 year to investigate the haze formation mechanism, sources, and influences of regional transport. The results revealed that secondary aerosols, coal combustion, and motor vehicle exhaust exerted significant impacts on urban haze formation. The mitigation strategy of reducing gaseous precursors emitted from fossil fuel combustion was suggested.
Bin Zhao, Wenjing Wu, Shuxiao Wang, Jia Xing, Xing Chang, Kuo-Nan Liou, Jonathan H. Jiang, Yu Gu, Carey Jang, Joshua S. Fu, Yun Zhu, Jiandong Wang, Yan Lin, and Jiming Hao
Atmos. Chem. Phys., 17, 12031–12050, https://doi.org/10.5194/acp-17-12031-2017, https://doi.org/10.5194/acp-17-12031-2017, 2017
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Using over 1000 chemical transport model simulations in the Beijing–Tianjin–Hebei region, we find that the emissions of primary inorganic PM2.5 make the largest contribution to PM2.5 concentrations and thus should be prioritized in PM2.5 control strategies. Among the precursors, PM2.5 concentrations are primarily sensitive to the emissions of NH3, NMVOC+IVOC, and POA, and the sensitivities increase substantially for NH3 and NHx with the increase in emission reduction ratio.
Hongyan Zhao, Xin Li, Qiang Zhang, Xujia Jiang, Jintai Lin, Glen P. Peters, Meng Li, Guannan Geng, Bo Zheng, Hong Huo, Lin Zhang, Haikun Wang, Steven J. Davis, and Kebin He
Atmos. Chem. Phys., 17, 10367–10381, https://doi.org/10.5194/acp-17-10367-2017, https://doi.org/10.5194/acp-17-10367-2017, 2017
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Effective and efficient control of air pollution relies upon an understanding of the pollution sources. We conduct an interdisciplinary study and find that 33 % of China’s PM2.5-related premature mortality in 2010 were caused by production emission in other regions; 56 % of the mortality was related to consumption in other regions. Multilateral and multi-stage cooperation under a regional sustainable development framework is in urgent need to mitigate air pollution and related health impacts.
Yuanhong Zhao, Lin Zhang, Amos P. K. Tai, Youfan Chen, and Yuepeng Pan
Atmos. Chem. Phys., 17, 9781–9796, https://doi.org/10.5194/acp-17-9781-2017, https://doi.org/10.5194/acp-17-9781-2017, 2017
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Human activities have substantially enhanced atmospheric deposition of reactive nitrogen, inducing complex environmental consequences. This study presents a first quantitative investigation of how anthropogenic nitrogen deposition could impact surface ozone air quality through surface–atmosphere exchange processes. We find important surface ozone changes driven by nitrogen deposition, which can be comparable with those due to historical climate and land use changes.
Li Zhang, Qinyi Li, Tao Wang, Ravan Ahmadov, Qiang Zhang, Meng Li, and Mengyao Lv
Atmos. Chem. Phys., 17, 9733–9750, https://doi.org/10.5194/acp-17-9733-2017, https://doi.org/10.5194/acp-17-9733-2017, 2017
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Little is known of the integrated impacts of HONO and ClNO2 on lower-tropospheric ozone so far. In this study, we updated WRF-Chem with the CBMZ_ReNOM module, which considers both the sources and chemistry of HONO and ClNO2. The revised model revealed that the two reactive nitrogen compounds significantly affected the oxidation capacity and ozone formation at the surface and within the lower troposphere over polluted regions and noticeably improved summertime O3 predictions over China.
Yujiao Zhu, Caiqing Yan, Renyi Zhang, Zifa Wang, Mei Zheng, Huiwang Gao, Yang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 17, 9469–9484, https://doi.org/10.5194/acp-17-9469-2017, https://doi.org/10.5194/acp-17-9469-2017, 2017
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This study reports the distinct effects of street canyons on new particle formation (NPF) under warm or cold ambient temperature conditions because of on-road vehicle emissions; i.e., stronger condensation sinks are responsible for the reduced NPF in the springtime, but efficient nucleation and partitioning of gaseous species contribute to the enhanced NPF in the wintertime. The oxidization of biogenic organics is suggested to play an important role in growing new particles.
Hui Wang, Huansheng Chen, Qizhong Wu, Junmin Lin, Xueshun Chen, Xinwei Xie, Rongrong Wang, Xiao Tang, and Zifa Wang
Geosci. Model Dev., 10, 2891–2904, https://doi.org/10.5194/gmd-10-2891-2017, https://doi.org/10.5194/gmd-10-2891-2017, 2017
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We introduced some methods to port our Global Nested Air Quality Prediction Modeling System (GNAQPMS) model on Intel Knight Landing (KNL). In this paper, we introduced both common and specific methods to accelerate out model better. With the guidance of the resources material on Intel Websites (http://www.intel.com/content/www/us/en/products/processors/xeon-phi.html) and relative books, this paper could be an example for the model developers to take advantage of KNL for their model.
Guannan Geng, Qiang Zhang, Dan Tong, Meng Li, Yixuan Zheng, Siwen Wang, and Kebin He
Atmos. Chem. Phys., 17, 9187–9203, https://doi.org/10.5194/acp-17-9187-2017, https://doi.org/10.5194/acp-17-9187-2017, 2017
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We presented the characteristics of PM2.5 chemical composition over China during 2005–2012 by synthesis of in situ measurement data and satellite-based estimates. We also investigated the driving forces behind the changes by examining the changes in precursor emissions. We found that the decrease in sulfate is partly offset by the increase in nitrate. The results indicate that the synchronized abatement of emissions for multipollutants is necessary for reducing ambient PM2.5 over China.
Tatsuya Nagashima, Kengo Sudo, Hajime Akimoto, Junichi Kurokawa, and Toshimasa Ohara
Atmos. Chem. Phys., 17, 8231–8246, https://doi.org/10.5194/acp-17-8231-2017, https://doi.org/10.5194/acp-17-8231-2017, 2017
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We showed the large contribution of different source regions in Asia to the recent increasing trend in surface ozone over Japan by using a global chemical transport model. China accounted for the largest part of the increasing trend, not only through the domestic ozone production (36 %) but also the ozone production in the adjacent countries due to the ozone precursors emitted in China (10 %). Other factors such as temporal change in climate and methane concentration were also investigated.
Yudong Yang, Min Shao, Stephan Keßel, Yue Li, Keding Lu, Sihua Lu, Jonathan Williams, Yuanhang Zhang, Liming Zeng, Anke C. Nölscher, Yusheng Wu, Xuemei Wang, and Junyu Zheng
Atmos. Chem. Phys., 17, 7127–7142, https://doi.org/10.5194/acp-17-7127-2017, https://doi.org/10.5194/acp-17-7127-2017, 2017
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Total OH reactivity is an important parameter to evaluate understanding of atmospheric chemistry, especially the VOC contribution to air pollution. Measured by comparative reactivity methods, total OH reactivity in Beijing and Heshan revealed significant differences between measured and calculated results, such as missing reactivity, which were related to unmeasured primary or secondary species. This missing reactivity would introduce a 21–30 % underestimation for ozone production efficiency.
Jing Zheng, Min Hu, Zhuofei Du, Dongjie Shang, Zhaoheng Gong, Yanhong Qin, Jingyao Fang, Fangting Gu, Mengren Li, Jianfei Peng, Jie Li, Yuqia Zhang, Xiaofeng Huang, Lingyan He, Yusheng Wu, and Song Guo
Atmos. Chem. Phys., 17, 6853–6864, https://doi.org/10.5194/acp-17-6853-2017, https://doi.org/10.5194/acp-17-6853-2017, 2017
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By monitoring aerosol properties as a function of high-resolution chemical composition, this study sheds light on the evolution processes of particles in the Tibetan Plateau background environment during the pre-monsoon season. A positive matrix factorization analysis integrated with a mesoscale meteorological model clearly shows that the southeastern edge of the Tibetan Plateau was affected by air pollutants transported from active biomass burning areas in South Asia.
Wei Du, Jian Zhao, Yuying Wang, Yingjie Zhang, Qingqing Wang, Weiqi Xu, Chen Chen, Tingting Han, Fang Zhang, Zhanqing Li, Pingqing Fu, Jie Li, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 17, 6797–6811, https://doi.org/10.5194/acp-17-6797-2017, https://doi.org/10.5194/acp-17-6797-2017, 2017
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We conducted the first simultaneous measurements of size-resolved particle number concentrations at ground level and 260 m in urban Beijing. The vertical differences strongly depend on particle sizes, with accumulation-mode particles being highly correlated at the two heights. We further demonstrated that regional emission controls have a dominant impact on accumulation-mode particles, while the influences on Aitken particles were much smaller due to the enhanced NPF events.
Ting Yang, Zifa Wang, Wei Zhang, Alex Gbaguidi, Nobuo Sugimoto, Xiquan Wang, Ichiro Matsui, and Yele Sun
Atmos. Chem. Phys., 17, 6215–6225, https://doi.org/10.5194/acp-17-6215-2017, https://doi.org/10.5194/acp-17-6215-2017, 2017
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Predicting air pollution events over megacities requires, notably, continuous and accurate determination of the boundary layer height (BLH). Based on gravity wave theory, a new approach (CRGM) is developed to overcome existing algorithms' weakness in order to accurately reproduce the fluctuations of the BLH under various atmospheric pollution conditions from lidar observation. Comprehensive evaluation highlights strong effectiveness of this new method.
Xu Yue, Nadine Unger, Kandice Harper, Xiangao Xia, Hong Liao, Tong Zhu, Jingfeng Xiao, Zhaozhong Feng, and Jing Li
Atmos. Chem. Phys., 17, 6073–6089, https://doi.org/10.5194/acp-17-6073-2017, https://doi.org/10.5194/acp-17-6073-2017, 2017
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While it is widely recognized that air pollutants adversely affect human health and climate change, their impacts on the regional carbon balance are less well understood. We apply an Earth system model to quantify the combined effects of ozone and aerosol particles on net primary production in China. Ozone vegetation damage dominates over the aerosol effects, leading to a substantial net suppression of land carbon uptake in the present and future worlds.
Min Huang, Gregory R. Carmichael, R. Bradley Pierce, Duseong S. Jo, Rokjin J. Park, Johannes Flemming, Louisa K. Emmons, Kevin W. Bowman, Daven K. Henze, Yanko Davila, Kengo Sudo, Jan Eiof Jonson, Marianne Tronstad Lund, Greet Janssens-Maenhout, Frank J. Dentener, Terry J. Keating, Hilke Oetjen, and Vivienne H. Payne
Atmos. Chem. Phys., 17, 5721–5750, https://doi.org/10.5194/acp-17-5721-2017, https://doi.org/10.5194/acp-17-5721-2017, 2017
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In support of the HTAP phase 2 experiment, we conducted a number of regional-scale Sulfur Transport and dEposition Model base and sensitivity simulations over North America during May–June 2010. The STEM chemical boundary conditions were downscaled from three (GEOS-Chem, RAQMS, and ECMWF C-IFS) global chemical transport models' simulations. Analyses were performed on large spatial–temporal scales relative to HTAP1 and also on subcontinental and event scales including the use of satellite data.
Yu-Hao Mao, Hong Liao, and Hai-Shan Chen
Atmos. Chem. Phys., 17, 4799–4816, https://doi.org/10.5194/acp-17-4799-2017, https://doi.org/10.5194/acp-17-4799-2017, 2017
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We applied a global 3-D CTM to examine the impacts of the East Asian summer and winter monsoons on the interannual variations of surface concentrations, vertical distributions, and direct radiative forcing of black carbon (BC) over eastern China and the mechanisms through which the monsoon influences the variations of BC. Model results from our study have important implications for guiding measures to reduce BC emissions to mitigate near-term climate warming and to improve air quality in China.
Syuichi Itahashi, Itsushi Uno, Kazuo Osada, Yusuke Kamiguchi, Shigekazu Yamamoto, Kei Tamura, Zhe Wang, Yasunori Kurosaki, and Yugo Kanaya
Atmos. Chem. Phys., 17, 3823–3843, https://doi.org/10.5194/acp-17-3823-2017, https://doi.org/10.5194/acp-17-3823-2017, 2017
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Over East Asia, the transboundary air pollution of SO42− has been recognized. The importance of the transboundary air pollution of NO3− in winter was demonstrated in this study through synergetic ground-based observations with state-of-the-art measurements of secondary inorganic aerosols (SO42−, NO3−, and NH4+) and a regional chemical transport model analysis. This study will help to refine the understanding of transboundary heavy PM2.5 pollution in winter.
Jia Zhu, Hong Liao, Yuhao Mao, Yang Yang, and Hui Jiang
Atmos. Chem. Phys., 17, 3729–3747, https://doi.org/10.5194/acp-17-3729-2017, https://doi.org/10.5194/acp-17-3729-2017, 2017
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Asian O3 outflow exhibited a small and statistically insignificant decadal trend with large interannual variations from 1986–2006. The latter were mainly caused by variations in the meteorological conditions. Future climate change will aggravate the effects of the increases in anthropogenic emissions on future changes in the Asian O3 outflow. These findings help us to understand the variations in tropospheric O3 in the regions downwind of East Asia on different timescales.
Dongwei Liu, Weixing Zhu, Xiaobo Wang, Yuepeng Pan, Chao Wang, Dan Xi, Edith Bai, Yuesi Wang, Xingguo Han, and Yunting Fang
Biogeosciences, 14, 989–1001, https://doi.org/10.5194/bg-14-989-2017, https://doi.org/10.5194/bg-14-989-2017, 2017
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The use of 15N natural abundance of soil ammonium and nitrate demonstrates a clear shifting contribution from abiotic to biotic controls on N cycling along a 3200 km dryland transect in northern China, with a threshold at mean annual precipitation of 100 mm. Abiotic factors were the main driver below threshold, shown by the accumulation of atmospheric N and NH3 losses. In the area above threshold, soil N cycling was controlled mainly by biological factors, e.g., plant uptake and denitrification.
Jian Zhao, Wei Du, Yingjie Zhang, Qingqing Wang, Chen Chen, Weiqi Xu, Tingting Han, Yuying Wang, Pingqing Fu, Zifa Wang, Zhanqing Li, and Yele Sun
Atmos. Chem. Phys., 17, 3215–3232, https://doi.org/10.5194/acp-17-3215-2017, https://doi.org/10.5194/acp-17-3215-2017, 2017
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We conducted aerosol particle composition measurements at ground level and 260 m with two aerosol mass spectrometers in Beijing during the 2015 China Victory Day parade. Our results showed a stronger impact of emission controls on inorganic aerosol than OA. A larger decrease in more oxidized SOA than the less oxidized one during the control period was also observed. Our results indicate that emission controls and the changes in meteorological conditions have affected SOA formation mechanisms.
Olaf Morgenstern, Michaela I. Hegglin, Eugene Rozanov, Fiona M. O'Connor, N. Luke Abraham, Hideharu Akiyoshi, Alexander T. Archibald, Slimane Bekki, Neal Butchart, Martyn P. Chipperfield, Makoto Deushi, Sandip S. Dhomse, Rolando R. Garcia, Steven C. Hardiman, Larry W. Horowitz, Patrick Jöckel, Beatrice Josse, Douglas Kinnison, Meiyun Lin, Eva Mancini, Michael E. Manyin, Marion Marchand, Virginie Marécal, Martine Michou, Luke D. Oman, Giovanni Pitari, David A. Plummer, Laura E. Revell, David Saint-Martin, Robyn Schofield, Andrea Stenke, Kane Stone, Kengo Sudo, Taichu Y. Tanaka, Simone Tilmes, Yousuke Yamashita, Kohei Yoshida, and Guang Zeng
Geosci. Model Dev., 10, 639–671, https://doi.org/10.5194/gmd-10-639-2017, https://doi.org/10.5194/gmd-10-639-2017, 2017
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We present a review of the make-up of 20 models participating in the Chemistry–Climate Model Initiative (CCMI). In comparison to earlier such activities, most of these models comprise a whole-atmosphere chemistry, and several of them include an interactive ocean module. This makes them suitable for studying the interactions of tropospheric air quality, stratospheric ozone, and climate. The paper lays the foundation for other studies using the CCMI simulations for scientific analysis.
Xiao-Xiao Zhang, Brenton Sharratt, Xi Chen, Zi-Fa Wang, Lian-You Liu, Yu-Hong Guo, Jie Li, Huan-Sheng Chen, and Wen-Yi Yang
Atmos. Chem. Phys., 17, 1699–1711, https://doi.org/10.5194/acp-17-1699-2017, https://doi.org/10.5194/acp-17-1699-2017, 2017
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To improve our understanding of the fate and transport of airborne dust, there is a need for long-term records of dust deposition and concentration. This study characterized the spatial and temporal distribution in dust deposition and concentration in central Asia. The occurrence of high dust deposition and concentration suggests this region is a potential contributor to the global dust budget. This work will strengthen our comprehension of aerosol transport in global desertification regions.
Stefano Galmarini, Brigitte Koffi, Efisio Solazzo, Terry Keating, Christian Hogrefe, Michael Schulz, Anna Benedictow, Jan Jurgen Griesfeller, Greet Janssens-Maenhout, Greg Carmichael, Joshua Fu, and Frank Dentener
Atmos. Chem. Phys., 17, 1543–1555, https://doi.org/10.5194/acp-17-1543-2017, https://doi.org/10.5194/acp-17-1543-2017, 2017
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We present an overview of the coordinated global numerical modelling experiments performed during 2012–2016 by the Task Force on Hemispheric Transport of Air Pollution (TF HTAP), the regional experiments by the Air Quality Model Evaluation International Initiative (AQMEII) over Europe and North America, and the Model Intercomparison Study for Asia (MICS-Asia). Given the organizational complexity of bringing together these three initiatives, the experiment organization is presented.
Shurui Chen, Liang Xu, Yinxiao Zhang, Bing Chen, Xinfeng Wang, Xiaoye Zhang, Mei Zheng, Jianmin Chen, Wenxing Wang, Yele Sun, Pingqing Fu, Zifa Wang, and Weijun Li
Atmos. Chem. Phys., 17, 1259–1270, https://doi.org/10.5194/acp-17-1259-2017, https://doi.org/10.5194/acp-17-1259-2017, 2017
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Many studies have focused on the unusually severe hazes instead of the more frequent light and moderate hazes (22–63 %) in winter in the North China Plain (NCP). The morphology, mixing state, and size of organic aerosols in the L & M hazes were characterized. We conclude that the direct emissions from residential coal stoves without any pollution controls in rural and urban outskirts contribute large amounts of primary OM particles to the regional L & M hazes in winter in the NCP.
Kazuyuki Miyazaki, Henk Eskes, Kengo Sudo, K. Folkert Boersma, Kevin Bowman, and Yugo Kanaya
Atmos. Chem. Phys., 17, 807–837, https://doi.org/10.5194/acp-17-807-2017, https://doi.org/10.5194/acp-17-807-2017, 2017
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Global surface emissions of nitrogen oxides (NOx) over a 10-year period (2005–2014) are estimated from assimilation of multiple satellite datasets. We present detailed distributions of the estimated NOx emission distributions for all major regions, the diurnal, seasonal, and decadal variability. The estimated emissions show a positive trend over India, China, and the Middle East, and a negative trend over the United States, southern Africa, and western Europe.
Chaopeng Hong, Qiang Zhang, Kebin He, Dabo Guan, Meng Li, Fei Liu, and Bo Zheng
Atmos. Chem. Phys., 17, 1227–1239, https://doi.org/10.5194/acp-17-1227-2017, https://doi.org/10.5194/acp-17-1227-2017, 2017
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We found that the apparent uncertainties in China’s energy consumption increased from 2004 to 2012. SO2 emissions are most sensitive to energy uncertainties because of the high contributions from industrial coal combustion. The energy-induced emission uncertainties for some species are comparable to total uncertainties of emissions as estimated by previous studies, indicating variations in energy consumption could be an important source of China’s emission uncertainties.
Meng Li, Qiang Zhang, Jun-ichi Kurokawa, Jung-Hun Woo, Kebin He, Zifeng Lu, Toshimasa Ohara, Yu Song, David G. Streets, Gregory R. Carmichael, Yafang Cheng, Chaopeng Hong, Hong Huo, Xujia Jiang, Sicong Kang, Fei Liu, Hang Su, and Bo Zheng
Atmos. Chem. Phys., 17, 935–963, https://doi.org/10.5194/acp-17-935-2017, https://doi.org/10.5194/acp-17-935-2017, 2017
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An anthropogenic emission inventory for Asia is developed for the years 2008 and 2010 to support the Model Inter-Comparison Study for Asia (MICS-Asia) and the Task Force on Hemispheric Transport of Air Pollution (TF HTAP) projects by a mosaic of up-to-date regional emission inventories. The total Asian emissions in 2010 are estimated as follows: 51.3 Tg SO2, 52.1 Tg NOx, 336.5 Tg CO, 67.0 Tg NMVOC, 28.7 Tg NH3, 31.7 Tg PM10, 22.7 Tg PM2.5, 3.5 Tg BC, 8.3 Tg OC, and 17.3 Pg CO2.
Bo Zheng, Qiang Zhang, Dan Tong, Chuchu Chen, Chaopeng Hong, Meng Li, Guannan Geng, Yu Lei, Hong Huo, and Kebin He
Atmos. Chem. Phys., 17, 921–933, https://doi.org/10.5194/acp-17-921-2017, https://doi.org/10.5194/acp-17-921-2017, 2017
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The resolution dependence of uncertainties in proxy-based gridded inventories can be explained by the decoupling of emission facility locations from spatial proxies on fine scales. We conclude that proxy-based inventories are of sufficient quality to support regional and global models (larger than 0.25° in this case study); however, to support urban-scale models with accurate emission inputs, bottom-up inventories incorporating exact locations of emitting facilities have to be developed instead.
Bin Liu, Zhiyuan Cong, Yuesi Wang, Jinyuan Xin, Xin Wan, Yuepeng Pan, Zirui Liu, Yonghong Wang, Guoshuai Zhang, Zhongyan Wang, Yongjie Wang, and Shichang Kang
Atmos. Chem. Phys., 17, 449–463, https://doi.org/10.5194/acp-17-449-2017, https://doi.org/10.5194/acp-17-449-2017, 2017
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The first observation net of background atmospheric aerosols of the Himalayas and Tibetan Plateau were conducted in 2011–2013, and the aerosol mass loadings were especially illustrated in this paper. Consequently, these terrestrial aerosol masses were strongly ecosystem-dependent, with various seasonality and diurnal cycles at these sites. These findings implicate that regional characteristics and fine-particle emissions need to be treated sensitively when assessing their climatic effects.
Wen Xu, Wei Song, Yangyang Zhang, Xuejun Liu, Lin Zhang, Yuanhong Zhao, Duanyang Liu, Aohan Tang, Daowei Yang, Dandan Wang, Zhang Wen, Yuepeng Pan, David Fowler, Jeffrey L. Collett Jr., Jan Willem Erisman, Keith Goulding, Yi Li, and Fusuo Zhang
Atmos. Chem. Phys., 17, 31–46, https://doi.org/10.5194/acp-17-31-2017, https://doi.org/10.5194/acp-17-31-2017, 2017
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This paper evaluates the effectiveness of emission control measures implemented in Beijing during the Parade Blue period by integrating our own results, official-released data and modeling data. We demonstrate that emission control measures make a major contribution to air quality improvement in Beijing and surrounding regions. We conclude a joint local and regional control of secondary aerosol precursors to be key to curbing air pollution in Beijing.
Camilla Weum Stjern, Bjørn Hallvard Samset, Gunnar Myhre, Huisheng Bian, Mian Chin, Yanko Davila, Frank Dentener, Louisa Emmons, Johannes Flemming, Amund Søvde Haslerud, Daven Henze, Jan Eiof Jonson, Tom Kucsera, Marianne Tronstad Lund, Michael Schulz, Kengo Sudo, Toshihiko Takemura, and Simone Tilmes
Atmos. Chem. Phys., 16, 13579–13599, https://doi.org/10.5194/acp-16-13579-2016, https://doi.org/10.5194/acp-16-13579-2016, 2016
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Air pollution can reach distant regions through intercontinental transport. Here we first present results from the Hemispheric Transport of Air Pollution Phase 2 exercise, where many models performed the same set of coordinated emission-reduction experiments. We find that mitigations have considerable extra-regional effects, and show that this is particularly true for black carbon emissions, as long-range transport elevates aerosols to higher levels where their radiative influence is stronger.
Weihua Chen, Xuemei Wang, Jason Blake Cohen, Shengzhen Zhou, Zhisheng Zhang, Ming Chang, and Chuen-Yu Chan
Atmos. Chem. Phys., 16, 13271–13289, https://doi.org/10.5194/acp-16-13271-2016, https://doi.org/10.5194/acp-16-13271-2016, 2016
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Measurements of size-resolved aerosols (0.25–18 μm) were conducted at three sites (urban, suburban and background sites) in southern China during monsoon season (May–June) in 2010 aqueous-phase reaction was the main formation pathway of droplet mode sulfate. New particle formation, chemical aging, and long-range transport from upwind urban or biomass burning regions were also found to be important in at least some of the sights on some of the sampling days.
Mizuo Kajino, Masahide Ishizuka, Yasuhito Igarashi, Kazuyuki Kita, Chisato Yoshikawa, and Masaru Inatsu
Atmos. Chem. Phys., 16, 13149–13172, https://doi.org/10.5194/acp-16-13149-2016, https://doi.org/10.5194/acp-16-13149-2016, 2016
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The current study provides the first quantitative budget analysis of radiocesium re-suspended from ground surface contaminated by the Fukushima nuclear accident. It provides useful information to society since our simulation can be used for the long-term assessment of internal exposure to residents in Japan. It also discussed that the re-suspension from forest ecosystems could be a dominant source of suspended radiocesium in the warm season in Japan.
Meng Gao, Gregory R. Carmichael, Pablo E. Saide, Zifeng Lu, Man Yu, David G. Streets, and Zifa Wang
Atmos. Chem. Phys., 16, 11837–11851, https://doi.org/10.5194/acp-16-11837-2016, https://doi.org/10.5194/acp-16-11837-2016, 2016
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The WRF-Chem model was used to examine how the winter PM2.5 concentrations change in response to changes in emissions and meteorology in North China from 1960 to 2010. The discussions in this study indicate that dramatic changes in emissions are the main cause of increasing haze events in North China, and long-term trends in atmospheric circulations maybe another important cause. We also found aerosol feedbacks have been significantly enhanced from 1960 to 2010, due to higher aerosol loadings.
Yu Fu, Amos P. K. Tai, and Hong Liao
Atmos. Chem. Phys., 16, 10369–10383, https://doi.org/10.5194/acp-16-10369-2016, https://doi.org/10.5194/acp-16-10369-2016, 2016
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The effects of climate change would partly counteract the emission-driven increase in PM2.5 in winter in most of eastern China, but exacerbate PM2.5 pollution in summer in North China Plain. Land cover and land use change might partially offset the increase in summertime PM2.5 but further enhance wintertime PM2.5 in the model by modifying the dry deposition of various PM2.5 precursors and biogenic volatile organic compound emissions, which also act as important factors in modulating air quality.
Xiaole Pan, Itsushi Uno, Yukari Hara, Kazuo Osada, Shigekazu Yamamoto, Zhe Wang, Nobuo Sugimoto, Hiroshi Kobayashi, and Zifa Wang
Atmos. Chem. Phys., 16, 9863–9873, https://doi.org/10.5194/acp-16-9863-2016, https://doi.org/10.5194/acp-16-9863-2016, 2016
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Polarization properties of aerosol particles at a suburban site in the western Japan was studied on the basis of long-term observation and trajectory analysis. This study provides the detailed information on the polarization characteristics of particles from different origins, and proposed a reliable criterion to classify spherical and non-spherical particles. This study introduced a new method to investigate the mixed state of dust particle with anthropogenic pollutant.
Raquel A. Silva, J. Jason West, Jean-François Lamarque, Drew T. Shindell, William J. Collins, Stig Dalsoren, Greg Faluvegi, Gerd Folberth, Larry W. Horowitz, Tatsuya Nagashima, Vaishali Naik, Steven T. Rumbold, Kengo Sudo, Toshihiko Takemura, Daniel Bergmann, Philip Cameron-Smith, Irene Cionni, Ruth M. Doherty, Veronika Eyring, Beatrice Josse, Ian A. MacKenzie, David Plummer, Mattia Righi, David S. Stevenson, Sarah Strode, Sophie Szopa, and Guang Zengast
Atmos. Chem. Phys., 16, 9847–9862, https://doi.org/10.5194/acp-16-9847-2016, https://doi.org/10.5194/acp-16-9847-2016, 2016
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Using ozone and PM2.5 concentrations from the ACCMIP ensemble of chemistry-climate models for the four Representative Concentration Pathway scenarios (RCPs), together with projections of future population and baseline mortality rates, we quantify the human premature mortality impacts of future ambient air pollution in 2030, 2050 and 2100, relative to 2000 concentrations. We also estimate the global mortality burden of ozone and PM2.5 in 2000 and each future period.
Yele Sun, Wei Du, Pingqing Fu, Qingqing Wang, Jie Li, Xinlei Ge, Qi Zhang, Chunmao Zhu, Lujie Ren, Weiqi Xu, Jian Zhao, Tingting Han, Douglas R. Worsnop, and Zifa Wang
Atmos. Chem. Phys., 16, 8309–8329, https://doi.org/10.5194/acp-16-8309-2016, https://doi.org/10.5194/acp-16-8309-2016, 2016
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We have a comprehensive characterization of the sources, variations and processes of submicron aerosols in Beijing in winter using HR-AMS and GC/MS measurements. The primary sources including traffic, cooking, biomass burning and coal combustion emissions, and secondary components were separated and quantified with PMF. Our results elucidated the important roles of primary emissions, particularly coal combustion, and aqueous-phase processing in the formation of severe air pollution in winter.
Xinyi Dong, Joshua S. Fu, Kan Huang, Daniel Tong, and Guoshun Zhuang
Atmos. Chem. Phys., 16, 8157–8180, https://doi.org/10.5194/acp-16-8157-2016, https://doi.org/10.5194/acp-16-8157-2016, 2016
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The Community Multiscale Air Quality (CMAQ) model has been further developed in terms of simulating natural wind-blown dust in this study, with a series of modifications aimed at improving the model's capability to predict the emission, transport, and chemical reactions of dust aerosols. Evaluation with observations suggested improved model performance by correcting the double counting of soil moisture impact, applying source-dependent speciation profile, and implementing heterogeneous chemitry.
Yixuan Gu, Hong Liao, and Jianchun Bian
Atmos. Chem. Phys., 16, 6641–6663, https://doi.org/10.5194/acp-16-6641-2016, https://doi.org/10.5194/acp-16-6641-2016, 2016
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This is the first study to examine nitrate aerosol in the upper troposphere and lower stratosphere (UTLS) over the Tibetan Plateau (TP) and the South Asian summer monsoon (SASM) region in summer. Nitrate aerosol is simulated to be the most dominant aerosol species in the UTLS over the studied region. The mechanisms for the accumulation of nitrate in the UTLS over the TP/SASM region include vertical transport and the gas-to-aerosol conversion of nitric acid to form nitrate.
Xiao Tang, Jiang Zhu, ZiFa Wang, Alex Gbaguidi, CaiYan Lin, JinYuan Xin, Tao Song, and Bo Hu
Atmos. Chem. Phys., 16, 6395–6405, https://doi.org/10.5194/acp-16-6395-2016, https://doi.org/10.5194/acp-16-6395-2016, 2016
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Chemical data assimilation through adjusting precursor emissions has brought out notable impacts on improving ozone forecasts in previous studies. This paper, from another point of view, investigated in detail the impacts of adjusting nitrogen oxide emissions on the forecasts of nitrogen dioxide through assimilating ozone observations. Limitations of the existing chemical data assimilation methods in a highly nonlinear system were identified and highlighted.
Jin Feng, Hong Liao, and Jianping Li
Atmos. Chem. Phys., 16, 4927–4943, https://doi.org/10.5194/acp-16-4927-2016, https://doi.org/10.5194/acp-16-4927-2016, 2016
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We examine the impacts of monthly variations in Pacific-North America (PNA) teleconnection on aerosol concentrations in the United States during wintertime by observations from the EPA-AQS and the model results from the GEOS-Chem. The surface-layer PM2.5 concentrations in the PNA positive phases were higher by 8.7 % (12.2 %) relative to the PNA negative phases based on observed (simulated) concentrations, which have important implications for understanding and prediction of air quality in the US.
Andrea Ghirardo, Junfei Xie, Xunhua Zheng, Yuesi Wang, Rüdiger Grote, Katja Block, Jürgen Wildt, Thomas Mentel, Astrid Kiendler-Scharr, Mattias Hallquist, Klaus Butterbach-Bahl, and Jörg-Peter Schnitzler
Atmos. Chem. Phys., 16, 2901–2920, https://doi.org/10.5194/acp-16-2901-2016, https://doi.org/10.5194/acp-16-2901-2016, 2016
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Trees can impact urban air quality. Large emissions of plant volatiles are emitted in Beijing as a stress response to the urban polluted environment, but their impacts on secondary particulate matter remain relatively low compared to those originated from anthropogenic activities. The present study highlights the importance of including stress-induced compounds when studying plant volatile emissions.
Guiqian Tang, Jinqiang Zhang, Xiaowan Zhu, Tao Song, Christoph Münkel, Bo Hu, Klaus Schäfer, Zirui Liu, Junke Zhang, Lili Wang, Jinyuan Xin, Peter Suppan, and Yuesi Wang
Atmos. Chem. Phys., 16, 2459–2475, https://doi.org/10.5194/acp-16-2459-2016, https://doi.org/10.5194/acp-16-2459-2016, 2016
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This is the first paper to validate and characterize mixing layer height and discuss its relationship with air pollution, using a ceilometer in Beijing. The novelty, originality, and importance of this paper are as follows: (1) the applicable conditions of the ceilometer; (2) the variations of mixing layer height; (3) thermal/dynamic structure inside mixing layers with different degrees of pollution; and (4) critical meteorological conditions for the formation of heavy air pollution.
Chuan-Yao Lin, Chiung-Jui Su, Hiroyuki Kusaka, Yuko Akimoto, Yang-Fan Sheng, Jr-Chuan Huang, and Huang-Hsiung Hsu
Atmos. Chem. Phys., 16, 1809–1822, https://doi.org/10.5194/acp-16-1809-2016, https://doi.org/10.5194/acp-16-1809-2016, 2016
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This study evaluated the impact of urbanization over northern Taiwan using the Weather Research and Forecasting (WRF) Model coupled with the Noah land-surface model and a modified urban canopy model (WRF-UCM2D). WRF-UCM2D performed much better than the original UCM coupled with WRF (WRF-UCM) at non-urban stations with a low urban fraction during nighttime. The result of this study has crucial implications for assessing the impacts of urbanization on air quality and regional climate.
M. Gao, G. R. Carmichael, Y. Wang, P. E. Saide, M. Yu, J. Xin, Z. Liu, and Z. Wang
Atmos. Chem. Phys., 16, 1673–1691, https://doi.org/10.5194/acp-16-1673-2016, https://doi.org/10.5194/acp-16-1673-2016, 2016
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The WRF-Chem model was applied to study the 2010 winter haze in North China. Air pollutants outside Beijing contributed about 64.5 % to the PM2.5 levels in Beijing during this haze event, and most of them are from south Hebei, Tianjin city, Shandong and Henan provinces. In addition, aerosol feedback has important impacts on surface temperature, Relative Humidity (RH) and wind speeds, and these meteorological variables affect aerosol distribution and formation in turn.
S. L. Tian, Y. P. Pan, and Y. S. Wang
Atmos. Chem. Phys., 16, 1–19, https://doi.org/10.5194/acp-16-1-2016, https://doi.org/10.5194/acp-16-1-2016, 2016
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Size-resolved chemical information of particulate matter remains unclear in China due to a paucity of measurement data. One-year observation of water-soluble ions, carbonaceous species and trace elements in size-resolved particles with cutoff points as 0.43, 0.65, 1.1, 2.1, 3.3, 4.7, 5.8 and 9.0 μm were conducted in mega city Beijing. This unique dataset provided multidimensional insights into the sources among different size fractions, seasons or wind flows and between non-haze and haze days.
W. Q. Xu, Y. L. Sun, C. Chen, W. Du, T. T. Han, Q. Q. Wang, P. Q. Fu, Z. F. Wang, X. J. Zhao, L. B. Zhou, D. S. Ji, P. C. Wang, and D. R. Worsnop
Atmos. Chem. Phys., 15, 13681–13698, https://doi.org/10.5194/acp-15-13681-2015, https://doi.org/10.5194/acp-15-13681-2015, 2015
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We have investigated the response of aerosol composition, size distributions, and oxidation properties to emission controls during the 2014 Asia- Pacific Economic Cooperation (APEC) summit in Beijing. Our results showed substantial changes of aerosol bulk composition during APEC with the most reductions in secondary aerosols in large accumulation modes, demonstrating that that emission controls over regional scales can substantially reduce secondary particulates.
W. J. Li, S. R. Chen, Y. S. Xu, X. C. Guo, Y. L. Sun, X. Y. Yang, Z. F. Wang, X. D. Zhao, J. M. Chen, and W. X. Wang
Atmos. Chem. Phys., 15, 13365–13376, https://doi.org/10.5194/acp-15-13365-2015, https://doi.org/10.5194/acp-15-13365-2015, 2015
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We found that anthropogenic soot, fly ash, and visible organic particles likely adhere to the surface of secondary inorganic particles larger than 200nm due to coagulation. Biomass burning and coal combustion both constantly contribute to anthropogenic particles in the Qinghai-Tibet Plateau (QTP) background atmosphere. Organic coating and soot on the surface of the aged particles could have different impacts on their hygroscopic and optical properties in the QTP compared to the urban aerosols.
F. Liu, Q. Zhang, D. Tong, B. Zheng, M. Li, H. Huo, and K. B. He
Atmos. Chem. Phys., 15, 13299–13317, https://doi.org/10.5194/acp-15-13299-2015, https://doi.org/10.5194/acp-15-13299-2015, 2015
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This is the first study in which emissions from China’s coal-fired power plants were estimated at unit level for a 20-year period. This new emission inventory is constructed from a unit-based database compiled in this work, named the China coal-fired Power plant Emissions Database (CPED), which includes detailed information on the technologies, activity data, operation situation, emission factors, and locations of individual units.
N. Li, T.-M. Fu, J. J. Cao, J. Y. Zheng, Q. Y. He, X. Long, Z. Z. Zhao, N. Y. Cao, J. S. Fu, and Y. F. Lam
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-33583-2015, https://doi.org/10.5194/acpd-15-33583-2015, 2015
Revised manuscript not accepted
C. Chen, Y. L. Sun, W. Q. Xu, W. Du, L. B. Zhou, T. T. Han, Q. Q. Wang, P. Q. Fu, Z. F. Wang, Z. Q. Gao, Q. Zhang, and D. R. Worsnop
Atmos. Chem. Phys., 15, 12879–12895, https://doi.org/10.5194/acp-15-12879-2015, https://doi.org/10.5194/acp-15-12879-2015, 2015
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A comprehensive characterization of submicron aerosol composition and sources at 260m in urban Beijing during APEC 2014 is presented. Aerosol species were shown to decrease substantially by 40–80% during APEC, whereas the bulk composition was relatively similar to the result of synergetic controls of secondary precursors. Our results elucidated that the good air quality during APEC was the combined result of emission controls and meteorological effects, with the former playing the dominant role.
G. Tang, X. Zhu, B. Hu, J. Xin, L. Wang, C. Münkel, G. Mao, and Y. Wang
Atmos. Chem. Phys., 15, 12667–12680, https://doi.org/10.5194/acp-15-12667-2015, https://doi.org/10.5194/acp-15-12667-2015, 2015
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The manuscript is the first paper to validate and discuss the high-resolution vertical profiles of aerosols using a ceilometer in Beijing, China. We introduce the contribution of aerosols during different air pollution episodes in Beijing. Also, we seize the opportunity of emission reduction during APEC to study the contribution of aerosols. The results are helpful to provide guidance in redefining coordinated emission control strategies to control the regional pollution over northern China.
W. Xu, X. S. Luo, Y. P. Pan, L. Zhang, A. H. Tang, J. L. Shen, Y. Zhang, K. H. Li, Q. H. Wu, D. W. Yang, Y. Y. Zhang, J. Xue, W. Q. Li, Q. Q. Li, L. Tang, S. H. Lu, T. Liang, Y. A. Tong, P. Liu, Q. Zhang, Z. Q. Xiong, X. J. Shi, L. H. Wu, W. Q. Shi, K. Tian, X. H. Zhong, K. Shi, Q. Y. Tang, L. J. Zhang, J. L. Huang, C. E. He, F. H. Kuang, B. Zhu, H. Liu, X. Jin, Y. J. Xin, X. K. Shi, E. Z. Du, A. J. Dore, S. Tang, J. L. Collett Jr., K. Goulding, Y. X. Sun, J. Ren, F. S. Zhang, and X. J. Liu
Atmos. Chem. Phys., 15, 12345–12360, https://doi.org/10.5194/acp-15-12345-2015, https://doi.org/10.5194/acp-15-12345-2015, 2015
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The annual average concentrations (1.3-47.0µg N m-3) and dry plus wet/bulk deposition fluxes (2.9-83.3kg N ha-1 yr-1) of inorganic Nr species ranked by land use as urban > rural > background sites and by regions as north China > southeast China > southwest China > northeast China > northwest China > Tibetan Plateau, reflecting the impact of anthropogenic Nr emission. Average dry and wet/bulk N deposition fluxes were 20.6 ± 11.2 and 19.3 ± 9.2kg kg N ha-1 yr-1 across China, respectively.
J. Zheng, J. Zhu, Z. Wang, F. Fang, C. C. Pain, and J. Xiang
Geosci. Model Dev., 8, 3421–3440, https://doi.org/10.5194/gmd-8-3421-2015, https://doi.org/10.5194/gmd-8-3421-2015, 2015
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A new anisotropic hr-adaptive mesh technique has been applied to modelling of multiscale transport phenomena. Over existing air quality models typically based on static-structured grids using a locally nesting technique, the advantage of the anisotropic hr-adaptive model has the ability to adapt the mesh according to the evolving pollutant distribution and flow features. To illustrate its capability, comparisons have been made between the results obtained using adaptive and uniform meshes.
Y. W. Liu, Xu-Ri, Y. S. Wang, Y. P. Pan, and S. L. Piao
Atmos. Chem. Phys., 15, 11683–11700, https://doi.org/10.5194/acp-15-11683-2015, https://doi.org/10.5194/acp-15-11683-2015, 2015
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We investigated inorganic N wet deposition at five sites in the Tibetan Plateau (TP). Combining in situ measurements in this and previous studies, the average wet deposition of NH4+-N, NO3--N, and inorganic N in the TP was estimated to be 1.06, 0.51, and 1.58 kg N ha−1 yr−1, respectively. Results suggest that earlier estimations based on chemical transport model simulations and/or limited field measurements likely overestimated substantially the regional inorganic N wet deposition in the TP.
G. Janssens-Maenhout, M. Crippa, D. Guizzardi, F. Dentener, M. Muntean, G. Pouliot, T. Keating, Q. Zhang, J. Kurokawa, R. Wankmüller, H. Denier van der Gon, J. J. P. Kuenen, Z. Klimont, G. Frost, S. Darras, B. Koffi, and M. Li
Atmos. Chem. Phys., 15, 11411–11432, https://doi.org/10.5194/acp-15-11411-2015, https://doi.org/10.5194/acp-15-11411-2015, 2015
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This paper provides monthly emission grid maps at 0.1deg x 0.1deg resolution with global coverage for air pollutants and aerosols anthropogenic emissions in 2008 and 2010.
Countries are consistently inter-compared with sector-specific implied emission factors, per capita emissions and emissions per unit of GDP.
The emission grid maps compose the reference emissions data set for the community modelling hemispheric transport of air pollution (HTAP).
Y. Zhao, L. Zhang, Y. Pan, Y. Wang, F. Paulot, and D. K. Henze
Atmos. Chem. Phys., 15, 10905–10924, https://doi.org/10.5194/acp-15-10905-2015, https://doi.org/10.5194/acp-15-10905-2015, 2015
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Rapid Asian industrialization has led to increased atmospheric nitrogen deposition downwind. This work analyzes the sources and processes controlling atmospheric nitrogen deposition to the northwestern Pacific. Both nitrogen emissions and meteorology, largely controlled by the East Asian Monsoon, determine the seasonality of nitrogen deposition. Ascribing deposition over the marginal seas to nitrogen sources from different regions and sectors shows important contribution from fertilizer use.
J. L. Schnell, M. J. Prather, B. Josse, V. Naik, L. W. Horowitz, P. Cameron-Smith, D. Bergmann, G. Zeng, D. A. Plummer, K. Sudo, T. Nagashima, D. T. Shindell, G. Faluvegi, and S. A. Strode
Atmos. Chem. Phys., 15, 10581–10596, https://doi.org/10.5194/acp-15-10581-2015, https://doi.org/10.5194/acp-15-10581-2015, 2015
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We test global chemistry--climate models in their ability to simulate present-day surface ozone. Models are tested against observed hourly ozone from 4217 stations in North America and Europe that are averaged over 1°x1° grid cells. Using novel metrics, we find most models match the shape but not the amplitude of regional summertime diurnal and annual cycles and match the pattern but not the magnitude of summer ozone enhancement. Most also match the observed distribution of extreme episode sizes
L. Zhang, D. K. Henze, G. A. Grell, G. R. Carmichael, N. Bousserez, Q. Zhang, O. Torres, C. Ahn, Z. Lu, J. Cao, and Y. Mao
Atmos. Chem. Phys., 15, 10281–10308, https://doi.org/10.5194/acp-15-10281-2015, https://doi.org/10.5194/acp-15-10281-2015, 2015
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We attempt to reduce uncertainties in BC emissions and improve BC model simulations by developing top-down, spatially resolved, estimates of BC emissions through assimilation of OMI observations of aerosol absorption optical depth (AAOD) with the GEOS-Chem model and its adjoint for April and October of 2006. Despite the limitations and uncertainties, using OMI AAOD to constrain BC sources we are able to improve model representation of BC distributions, particularly over China.
H. S. Chen, Z. F. Wang, J. Li, X. Tang, B. Z. Ge, X. L. Wu, O. Wild, and G. R. Carmichael
Geosci. Model Dev., 8, 2857–2876, https://doi.org/10.5194/gmd-8-2857-2015, https://doi.org/10.5194/gmd-8-2857-2015, 2015
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A new global nested atmospheric mercury transport model was developed and introduced. Model performance was found significantly better in North America and Europe than in East Asia. Nested simulation has been conducted in East Asia and shows improved skill at capturing the high spatial variability of Hg concentrations and deposition. The trans-boundary transport of Chinese primary anthropogenic mercury emissions was quantified for the first time.
Y. L. Sun, Z. F. Wang, W. Du, Q. Zhang, Q. Q. Wang, P. Q. Fu, X. L. Pan, J. Li, J. Jayne, and D. R. Worsnop
Atmos. Chem. Phys., 15, 10149–10165, https://doi.org/10.5194/acp-15-10149-2015, https://doi.org/10.5194/acp-15-10149-2015, 2015
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We conducted the first long-term real-time measurement of submicron aerosol composition in Beijing using an ACSM for 1 year. The seasonal variations of mass concentrations and chemical composition of submicron aerosol were investigated in detail, and the meteorological effects on aerosol chemistry, particularly temperature and relative humidity, were elucidated. Finally, the potential source areas of aerosol species during four seasons were identified.
K. Miyazaki, H. J. Eskes, and K. Sudo
Atmos. Chem. Phys., 15, 8315–8348, https://doi.org/10.5194/acp-15-8315-2015, https://doi.org/10.5194/acp-15-8315-2015, 2015
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This paper reports on an 8-year reanalysis of tropospheric chemistry based on an assimilation of multiple satellite-derived data sets. The reanalysis performed well on regional and global scales and for seasonal and interannual variations. The simultaneous assimilation of multiple-species data, involving the optimisation of both concentration and emission fields, provides unique information on year-to-year variations in the atmospheric environment.
K. Ishijima, M. Takigawa, K. Sudo, S. Toyoda, N. Yoshida, T. Röckmann, J. Kaiser, S. Aoki, S. Morimoto, S. Sugawara, and T. Nakazawa
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-19947-2015, https://doi.org/10.5194/acpd-15-19947-2015, 2015
Revised manuscript not accepted
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We developed an atmospheric N2O isotopocule model based on a chemistry-coupled atmospheric general circulation model and a simple method to optimize the model, and estimated the isotopic signatures of surface sources at the hemispheric scale. Data obtained from ground-based observations, measurements of firn air, and balloon and aircraft flights were used to optimize the long-term trends, interhemispheric gradients, and photolytic fractionation, respectively, in the model.
Z. Y. Wu, L. Zhang, X. M. Wang, and J. W. Munger
Atmos. Chem. Phys., 15, 7487–7496, https://doi.org/10.5194/acp-15-7487-2015, https://doi.org/10.5194/acp-15-7487-2015, 2015
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In this study, we have developed a modified micrometeorological gradient method (MGM), although based on existing micrometeorological theory, to estimate O3 dry deposition fluxes over a forest canopy using concentration gradients between a level above and a level below the canopy top. The new method provides an alternative approach in monitoring/estimating long-term deposition fluxes of similar pollutants over tall canopies and is expected to be useful for the scientific community.
J. K. Zhang, D. S. Ji, Z. R. Liu, B. Hu, L. L. Wang, X. J. Huang, and Y. S. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-18537-2015, https://doi.org/10.5194/acpd-15-18537-2015, 2015
Revised manuscript has not been submitted
X. Pan, Y. Kanaya, H. Tanimoto, S. Inomata, Z. Wang, S. Kudo, and I. Uno
Atmos. Chem. Phys., 15, 6101–6111, https://doi.org/10.5194/acp-15-6101-2015, https://doi.org/10.5194/acp-15-6101-2015, 2015
Q. Jiang, Y. L. Sun, Z. Wang, and Y. Yin
Atmos. Chem. Phys., 15, 6023–6034, https://doi.org/10.5194/acp-15-6023-2015, https://doi.org/10.5194/acp-15-6023-2015, 2015
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Aerosol composition and sources during the Chinese spring festival are characterized in detail. The roles of fireworks and secondary aerosol in fine particle pollution were elucidated. We observed large reductions of primary species, whereas changes of secondary aerosol during the holiday period were minor. This has significant implications; reducing primary emissions on a local scale during severe haze episodes might have a limited effect on improving air quality in megacities.
R. Kumar, M. C. Barth, V. S. Nair, G. G. Pfister, S. Suresh Babu, S. K. Satheesh, K. Krishna Moorthy, G. R. Carmichael, Z. Lu, and D. G. Streets
Atmos. Chem. Phys., 15, 5415–5428, https://doi.org/10.5194/acp-15-5415-2015, https://doi.org/10.5194/acp-15-5415-2015, 2015
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We examine differences in the surface BC between the Bay of Bengal (BoB) and the Arabian Sea (AS) and identify dominant sources of BC in South Asia during ICARB. Anthropogenic emissions were the main source of BC during ICARB and had about 5 times stronger influence on the BoB compared to the AS. Regional-scale transport contributes up to 25% of BC mass concentrations in western and eastern India, suggesting that surface BC mass concentrations cannot be linked directly to the local emissions.
Y. Gao, M. Zhang, Z. Liu, L. Wang, P. Wang, X. Xia, M. Tao, and L. Zhu
Atmos. Chem. Phys., 15, 4279–4295, https://doi.org/10.5194/acp-15-4279-2015, https://doi.org/10.5194/acp-15-4279-2015, 2015
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By using an online coupled meteorology and aerosol/chemistry model (WRF-Chem), the increase of surface PM2.5 concentration is estimated to be up to 30% during a severe fog--haze event (10--15 January 2013) over North China Plain owing to the aerosol-induced decreased surface temperature, wind speed and atmosphere boundary layer height, increased surface relative humidity, and more stable atmosphere. A mechanism of positive feedback exists and contributes to the formation of fog--haze events.
D. C. Wong, C. E. Yang, J. S. Fu, K. Wong, and Y. Gao
Geosci. Model Dev., 8, 1033–1046, https://doi.org/10.5194/gmd-8-1033-2015, https://doi.org/10.5194/gmd-8-1033-2015, 2015
Y. H. Wang, Z. R. Liu, J. K. Zhang, B. Hu, D. S. Ji, Y. C. Yu, and Y. S. Wang
Atmos. Chem. Phys., 15, 3205–3215, https://doi.org/10.5194/acp-15-3205-2015, https://doi.org/10.5194/acp-15-3205-2015, 2015
Z. Peng, M. Zhang, X. Kou, X. Tian, and X. Ma
Atmos. Chem. Phys., 15, 1087–1104, https://doi.org/10.5194/acp-15-1087-2015, https://doi.org/10.5194/acp-15-1087-2015, 2015
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We associated the smoothing operator with the atmospheric transport model to constitute the persistence dynamical model to forecast the surface CO2 flux scaling factors for the purpose of resolving the "signal-to-noise" problem, as well as transporting the useful observed information onto the next assimilation cycle. Based on this improvement, a regional surface CO2 flux inversion system, CFI-CMAQ, has been developed. The OSSEs showed that the performance of CFI-CMAQ is effective and promising.
B. Zhao, S. X. Wang, J. Xing, K. Fu, J. S. Fu, C. Jang, Y. Zhu, X. Y. Dong, Y. Gao, W. J. Wu, J. D. Wang, and J. M. Hao
Geosci. Model Dev., 8, 115–128, https://doi.org/10.5194/gmd-8-115-2015, https://doi.org/10.5194/gmd-8-115-2015, 2015
Y. P. Pan and Y. S. Wang
Atmos. Chem. Phys., 15, 951–972, https://doi.org/10.5194/acp-15-951-2015, https://doi.org/10.5194/acp-15-951-2015, 2015
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This paper presents the first concurrent measurements of wet and dry deposition of various trace elements in Northern China, covering an extensive area over 3 years in a global hotspot of air pollution. The unique field data can serve as a sound basis for the validation of regional emission inventories and biogeochemical or atmospheric chemistry models. The findings are very important for policy makers to create legislation to reduce the emissions and protect soil and water from air pollution.
M. C. Wyant, C. S. Bretherton, R. Wood, G. R. Carmichael, A. Clarke, J. Fast, R. George, W. I. Gustafson Jr., C. Hannay, A. Lauer, Y. Lin, J.-J. Morcrette, J. Mulcahy, P. E. Saide, S. N. Spak, and Q. Yang
Atmos. Chem. Phys., 15, 153–172, https://doi.org/10.5194/acp-15-153-2015, https://doi.org/10.5194/acp-15-153-2015, 2015
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Simulations from a group of GCMs, forecast models, and regional models are compared with aircraft and ship observations of the marine boundary layer (MBL) in the southeast Pacific region during the VOCALS-REx field campaign of October-November 2008. Gradients of cloud, aerosol, and chemical properties in and above the MBL extending from the Peruvian coast westward along 20 degrees south are compared during the period.
T. Amnuaylojaroen, M. C. Barth, L. K. Emmons, G. R. Carmichael, J. Kreasuwun, S. Prasitwattanaseree, and S. Chantara
Atmos. Chem. Phys., 14, 12983–13012, https://doi.org/10.5194/acp-14-12983-2014, https://doi.org/10.5194/acp-14-12983-2014, 2014
S. Nordmann, Y. F. Cheng, G. R. Carmichael, M. Yu, H. A. C. Denier van der Gon, Q. Zhang, P. E. Saide, U. Pöschl, H. Su, W. Birmili, and A. Wiedensohler
Atmos. Chem. Phys., 14, 12683–12699, https://doi.org/10.5194/acp-14-12683-2014, https://doi.org/10.5194/acp-14-12683-2014, 2014
T. Wang, F. Hendrick, P. Wang, G. Tang, K. Clémer, H. Yu, C. Fayt, C. Hermans, C. Gielen, J.-F. Müller, G. Pinardi, N. Theys, H. Brenot, and M. Van Roozendael
Atmos. Chem. Phys., 14, 11149–11164, https://doi.org/10.5194/acp-14-11149-2014, https://doi.org/10.5194/acp-14-11149-2014, 2014
P. Marrapu, Y. Cheng, G. Beig, S. Sahu, R. Srinivas, and G. R. Carmichael
Atmos. Chem. Phys., 14, 10619–10630, https://doi.org/10.5194/acp-14-10619-2014, https://doi.org/10.5194/acp-14-10619-2014, 2014
Q. Z. Wu, W. S. Xu, A. J. Shi, Y. T. Li, X. J. Zhao, Z. F. Wang, J. X. Li, and L. N. Wang
Geosci. Model Dev., 7, 2243–2259, https://doi.org/10.5194/gmd-7-2243-2014, https://doi.org/10.5194/gmd-7-2243-2014, 2014
X. Han, M. Zhang, J. Gao, S. Wang, and F. Chai
Atmos. Chem. Phys., 14, 10231–10248, https://doi.org/10.5194/acp-14-10231-2014, https://doi.org/10.5194/acp-14-10231-2014, 2014
Q. Mu and H. Liao
Atmos. Chem. Phys., 14, 9597–9612, https://doi.org/10.5194/acp-14-9597-2014, https://doi.org/10.5194/acp-14-9597-2014, 2014
D. Ji, L. Wang, J. Feng, Q. Wu, H. Cheng, Q. Zhang, J. Yang, W. Dong, Y. Dai, D. Gong, R.-H. Zhang, X. Wang, J. Liu, J. C. Moore, D. Chen, and M. Zhou
Geosci. Model Dev., 7, 2039–2064, https://doi.org/10.5194/gmd-7-2039-2014, https://doi.org/10.5194/gmd-7-2039-2014, 2014
Y. Kanaya, H. Irie, H. Takashima, H. Iwabuchi, H. Akimoto, K. Sudo, M. Gu, J. Chong, Y. J. Kim, H. Lee, A. Li, F. Si, J. Xu, P.-H. Xie, W.-Q. Liu, A. Dzhola, O. Postylyakov, V. Ivanov, E. Grechko, S. Terpugova, and M. Panchenko
Atmos. Chem. Phys., 14, 7909–7927, https://doi.org/10.5194/acp-14-7909-2014, https://doi.org/10.5194/acp-14-7909-2014, 2014
Y. Yang, H. Liao, and J. Li
Atmos. Chem. Phys., 14, 6867–6879, https://doi.org/10.5194/acp-14-6867-2014, https://doi.org/10.5194/acp-14-6867-2014, 2014
Q. Zhang, B. Yuan, M. Shao, X. Wang, S. Lu, K. Lu, M. Wang, L. Chen, C.-C. Chang, and S. C. Liu
Atmos. Chem. Phys., 14, 6089–6101, https://doi.org/10.5194/acp-14-6089-2014, https://doi.org/10.5194/acp-14-6089-2014, 2014
M. Li, Q. Zhang, D. G. Streets, K. B. He, Y. F. Cheng, L. K. Emmons, H. Huo, S. C. Kang, Z. Lu, M. Shao, H. Su, X. Yu, and Y. Zhang
Atmos. Chem. Phys., 14, 5617–5638, https://doi.org/10.5194/acp-14-5617-2014, https://doi.org/10.5194/acp-14-5617-2014, 2014
O. Uchino, T. Sakai, T. Nagai, I. Morino, T. Maki, M. Deushi, K. Shibata, M. Kajino, T. Kawasaki, T. Akaho, S. Takubo, H. Okumura, K. Arai, M. Nakazato, T. Matsunaga, T. Yokota, S. Kawakami, K. Kita, and Y. Sasano
Atmos. Meas. Tech., 7, 1385–1394, https://doi.org/10.5194/amt-7-1385-2014, https://doi.org/10.5194/amt-7-1385-2014, 2014
S. Itahashi, I. Uno, H. Irie, J.-I. Kurokawa, and T. Ohara
Atmos. Chem. Phys., 14, 3623–3635, https://doi.org/10.5194/acp-14-3623-2014, https://doi.org/10.5194/acp-14-3623-2014, 2014
K. Miyazaki, H. J. Eskes, K. Sudo, and C. Zhang
Atmos. Chem. Phys., 14, 3277–3305, https://doi.org/10.5194/acp-14-3277-2014, https://doi.org/10.5194/acp-14-3277-2014, 2014
J. K. Zhang, Y. Sun, Z. R. Liu, D. S. Ji, B. Hu, Q. Liu, and Y. S. Wang
Atmos. Chem. Phys., 14, 2887–2903, https://doi.org/10.5194/acp-14-2887-2014, https://doi.org/10.5194/acp-14-2887-2014, 2014
K. Huang, G. Zhuang, Q. Wang, J. S. Fu, Y. Lin, T. Liu, L. Han, and C. Deng
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-7517-2014, https://doi.org/10.5194/acpd-14-7517-2014, 2014
Revised manuscript not accepted
N. Chao, G. Tang, Y. Wang, H. Wang, J. Huang, and J. Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-4905-2014, https://doi.org/10.5194/acpd-14-4905-2014, 2014
Revised manuscript not accepted
H. Lei, D. J. Wuebbles, X.-Z. Liang, Z. Tao, S. Olsen, R. Artz, X. Ren, and M. Cohen
Atmos. Chem. Phys., 14, 783–795, https://doi.org/10.5194/acp-14-783-2014, https://doi.org/10.5194/acp-14-783-2014, 2014
A. Baklanov, K. Schlünzen, P. Suppan, J. Baldasano, D. Brunner, S. Aksoyoglu, G. Carmichael, J. Douros, J. Flemming, R. Forkel, S. Galmarini, M. Gauss, G. Grell, M. Hirtl, S. Joffre, O. Jorba, E. Kaas, M. Kaasik, G. Kallos, X. Kong, U. Korsholm, A. Kurganskiy, J. Kushta, U. Lohmann, A. Mahura, A. Manders-Groot, A. Maurizi, N. Moussiopoulos, S. T. Rao, N. Savage, C. Seigneur, R. S. Sokhi, E. Solazzo, S. Solomos, B. Sørensen, G. Tsegas, E. Vignati, B. Vogel, and Y. Zhang
Atmos. Chem. Phys., 14, 317–398, https://doi.org/10.5194/acp-14-317-2014, https://doi.org/10.5194/acp-14-317-2014, 2014
H. Liu, X. M. Wang, J. M. Pang, and K. B. He
Atmos. Chem. Phys., 13, 12013–12027, https://doi.org/10.5194/acp-13-12013-2013, https://doi.org/10.5194/acp-13-12013-2013, 2013
S. Situ, A. Guenther, X. Wang, X. Jiang, A. Turnipseed, Z. Wu, J. Bai, and X. Wang
Atmos. Chem. Phys., 13, 11803–11817, https://doi.org/10.5194/acp-13-11803-2013, https://doi.org/10.5194/acp-13-11803-2013, 2013
H. Lei, X.-Z. Liang, D. J. Wuebbles, and Z. Tao
Atmos. Chem. Phys., 13, 10807–10825, https://doi.org/10.5194/acp-13-10807-2013, https://doi.org/10.5194/acp-13-10807-2013, 2013
P. E. Saide, G. R. Carmichael, Z. Liu, C. S. Schwartz, H. C. Lin, A. M. da Silva, and E. Hyer
Atmos. Chem. Phys., 13, 10425–10444, https://doi.org/10.5194/acp-13-10425-2013, https://doi.org/10.5194/acp-13-10425-2013, 2013
Y. Gao, J. S. Fu, J. B. Drake, J.-F. Lamarque, and Y. Liu
Atmos. Chem. Phys., 13, 9607–9621, https://doi.org/10.5194/acp-13-9607-2013, https://doi.org/10.5194/acp-13-9607-2013, 2013
Y. Kanaya, H. Akimoto, Z.-F. Wang, P. Pochanart, K. Kawamura, Y. Liu, J. Li, Y. Komazaki, H. Irie, X.-L. Pan, F. Taketani, K. Yamaji, H. Tanimoto, S. Inomata, S. Kato, J. Suthawaree, K. Okuzawa, G. Wang, S. G. Aggarwal, P. Q. Fu, T. Wang, J. Gao, Y. Wang, and G. Zhuang
Atmos. Chem. Phys., 13, 8265–8283, https://doi.org/10.5194/acp-13-8265-2013, https://doi.org/10.5194/acp-13-8265-2013, 2013
K. Kawamura, E. Tachibana, K. Okuzawa, S. G. Aggarwal, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys., 13, 8285–8302, https://doi.org/10.5194/acp-13-8285-2013, https://doi.org/10.5194/acp-13-8285-2013, 2013
H. Jiang, H. Liao, H. O. T. Pye, S. Wu, L. J. Mickley, J. H. Seinfeld, and X. Y. Zhang
Atmos. Chem. Phys., 13, 7937–7960, https://doi.org/10.5194/acp-13-7937-2013, https://doi.org/10.5194/acp-13-7937-2013, 2013
Y. Zhang, K. Sartelet, S. Zhu, W. Wang, S.-Y. Wu, X. Zhang, K. Wang, P. Tran, C. Seigneur, and Z.-F. Wang
Atmos. Chem. Phys., 13, 6845–6875, https://doi.org/10.5194/acp-13-6845-2013, https://doi.org/10.5194/acp-13-6845-2013, 2013
Z. Tao, J. A. Santanello, M. Chin, S. Zhou, Q. Tan, E. M. Kemp, and C. D. Peters-Lidard
Atmos. Chem. Phys., 13, 6207–6226, https://doi.org/10.5194/acp-13-6207-2013, https://doi.org/10.5194/acp-13-6207-2013, 2013
N. He, K. Kawamura, K. Okuzawa, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-16699-2013, https://doi.org/10.5194/acpd-13-16699-2013, 2013
Revised manuscript not accepted
K. Huang, G. Zhuang, Y. Lin, Q. Wang, J. S. Fu, Q. Fu, T. Liu, and C. Deng
Atmos. Chem. Phys., 13, 5927–5942, https://doi.org/10.5194/acp-13-5927-2013, https://doi.org/10.5194/acp-13-5927-2013, 2013
K. Kawamura, K. Okuzawa, S. G. Aggarwal, H. Irie, Y. Kanaya, and Z. Wang
Atmos. Chem. Phys., 13, 5369–5380, https://doi.org/10.5194/acp-13-5369-2013, https://doi.org/10.5194/acp-13-5369-2013, 2013
H. Irie, K. Yamaji, K. Ikeda, I. Uno, S. Itahashi, T. Ohara, and J. Kurokawa
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-14037-2013, https://doi.org/10.5194/acpd-13-14037-2013, 2013
Preprint withdrawn
V. Naik, A. Voulgarakis, A. M. Fiore, L. W. Horowitz, J.-F. Lamarque, M. Lin, M. J. Prather, P. J. Young, D. Bergmann, P. J. Cameron-Smith, I. Cionni, W. J. Collins, S. B. Dalsøren, R. Doherty, V. Eyring, G. Faluvegi, G. A. Folberth, B. Josse, Y. H. Lee, I. A. MacKenzie, T. Nagashima, T. P. C. van Noije, D. A. Plummer, M. Righi, S. T. Rumbold, R. Skeie, D. T. Shindell, D. S. Stevenson, S. Strode, K. Sudo, S. Szopa, and G. Zeng
Atmos. Chem. Phys., 13, 5277–5298, https://doi.org/10.5194/acp-13-5277-2013, https://doi.org/10.5194/acp-13-5277-2013, 2013
Y. L. Sun, Z. F. Wang, P. Q. Fu, T. Yang, Q. Jiang, H. B. Dong, J. Li, and J. J. Jia
Atmos. Chem. Phys., 13, 4577–4592, https://doi.org/10.5194/acp-13-4577-2013, https://doi.org/10.5194/acp-13-4577-2013, 2013
K. W. Bowman, D. T. Shindell, H. M. Worden, J.F. Lamarque, P. J. Young, D. S. Stevenson, Z. Qu, M. de la Torre, D. Bergmann, P. J. Cameron-Smith, W. J. Collins, R. Doherty, S. B. Dalsøren, G. Faluvegi, G. Folberth, L. W. Horowitz, B. M. Josse, Y. H. Lee, I. A. MacKenzie, G. Myhre, T. Nagashima, V. Naik, D. A. Plummer, S. T. Rumbold, R. B. Skeie, S. A. Strode, K. Sudo, S. Szopa, A. Voulgarakis, G. Zeng, S. S. Kulawik, A. M. Aghedo, and J. R. Worden
Atmos. Chem. Phys., 13, 4057–4072, https://doi.org/10.5194/acp-13-4057-2013, https://doi.org/10.5194/acp-13-4057-2013, 2013
D. T. Shindell, J.-F. Lamarque, M. Schulz, M. Flanner, C. Jiao, M. Chin, P. J. Young, Y. H. Lee, L. Rotstayn, N. Mahowald, G. Milly, G. Faluvegi, Y. Balkanski, W. J. Collins, A. J. Conley, S. Dalsoren, R. Easter, S. Ghan, L. Horowitz, X. Liu, G. Myhre, T. Nagashima, V. Naik, S. T. Rumbold, R. Skeie, K. Sudo, S. Szopa, T. Takemura, A. Voulgarakis, J.-H. Yoon, and F. Lo
Atmos. Chem. Phys., 13, 2939–2974, https://doi.org/10.5194/acp-13-2939-2013, https://doi.org/10.5194/acp-13-2939-2013, 2013
D. S. Stevenson, P. J. Young, V. Naik, J.-F. Lamarque, D. T. Shindell, A. Voulgarakis, R. B. Skeie, S. B. Dalsoren, G. Myhre, T. K. Berntsen, G. A. Folberth, S. T. Rumbold, W. J. Collins, I. A. MacKenzie, R. M. Doherty, G. Zeng, T. P. C. van Noije, A. Strunk, D. Bergmann, P. Cameron-Smith, D. A. Plummer, S. A. Strode, L. Horowitz, Y. H. Lee, S. Szopa, K. Sudo, T. Nagashima, B. Josse, I. Cionni, M. Righi, V. Eyring, A. Conley, K. W. Bowman, O. Wild, and A. Archibald
Atmos. Chem. Phys., 13, 3063–3085, https://doi.org/10.5194/acp-13-3063-2013, https://doi.org/10.5194/acp-13-3063-2013, 2013
Y. H. Lee, J.-F. Lamarque, M. G. Flanner, C. Jiao, D. T. Shindell, T. Berntsen, M. M. Bisiaux, J. Cao, W. J. Collins, M. Curran, R. Edwards, G. Faluvegi, S. Ghan, L. W. Horowitz, J. R. McConnell, J. Ming, G. Myhre, T. Nagashima, V. Naik, S. T. Rumbold, R. B. Skeie, K. Sudo, T. Takemura, F. Thevenon, B. Xu, and J.-H. Yoon
Atmos. Chem. Phys., 13, 2607–2634, https://doi.org/10.5194/acp-13-2607-2013, https://doi.org/10.5194/acp-13-2607-2013, 2013
A. Voulgarakis, V. Naik, J.-F. Lamarque, D. T. Shindell, P. J. Young, M. J. Prather, O. Wild, R. D. Field, D. Bergmann, P. Cameron-Smith, I. Cionni, W. J. Collins, S. B. Dalsøren, R. M. Doherty, V. Eyring, G. Faluvegi, G. A. Folberth, L. W. Horowitz, B. Josse, I. A. MacKenzie, T. Nagashima, D. A. Plummer, M. Righi, S. T. Rumbold, D. S. Stevenson, S. A. Strode, K. Sudo, S. Szopa, and G. Zeng
Atmos. Chem. Phys., 13, 2563–2587, https://doi.org/10.5194/acp-13-2563-2013, https://doi.org/10.5194/acp-13-2563-2013, 2013
P. J. Young, A. T. Archibald, K. W. Bowman, J.-F. Lamarque, V. Naik, D. S. Stevenson, S. Tilmes, A. Voulgarakis, O. Wild, D. Bergmann, P. Cameron-Smith, I. Cionni, W. J. Collins, S. B. Dalsøren, R. M. Doherty, V. Eyring, G. Faluvegi, L. W. Horowitz, B. Josse, Y. H. Lee, I. A. MacKenzie, T. Nagashima, D. A. Plummer, M. Righi, S. T. Rumbold, R. B. Skeie, D. T. Shindell, S. A. Strode, K. Sudo, S. Szopa, and G. Zeng
Atmos. Chem. Phys., 13, 2063–2090, https://doi.org/10.5194/acp-13-2063-2013, https://doi.org/10.5194/acp-13-2063-2013, 2013
Y. P. Pan, Y. S. Wang, G. Q. Tang, and D. Wu
Atmos. Chem. Phys., 13, 1675–1688, https://doi.org/10.5194/acp-13-1675-2013, https://doi.org/10.5194/acp-13-1675-2013, 2013
J.-F. Lamarque, D. T. Shindell, B. Josse, P. J. Young, I. Cionni, V. Eyring, D. Bergmann, P. Cameron-Smith, W. J. Collins, R. Doherty, S. Dalsoren, G. Faluvegi, G. Folberth, S. J. Ghan, L. W. Horowitz, Y. H. Lee, I. A. MacKenzie, T. Nagashima, V. Naik, D. Plummer, M. Righi, S. T. Rumbold, M. Schulz, R. B. Skeie, D. S. Stevenson, S. Strode, K. Sudo, S. Szopa, A. Voulgarakis, and G. Zeng
Geosci. Model Dev., 6, 179–206, https://doi.org/10.5194/gmd-6-179-2013, https://doi.org/10.5194/gmd-6-179-2013, 2013
M. Huang, G. R. Carmichael, T. Chai, R. B. Pierce, S. J. Oltmans, D. A. Jaffe, K. W. Bowman, A. Kaduwela, C. Cai, S. N. Spak, A. J. Weinheimer, L. G. Huey, and G. S. Diskin
Atmos. Chem. Phys., 13, 359–391, https://doi.org/10.5194/acp-13-359-2013, https://doi.org/10.5194/acp-13-359-2013, 2013
K. Huang, G. Zhuang, Y. Lin, Q. Wang, J. S. Fu, R. Zhang, J. Li, C. Deng, and Q. Fu
Atmos. Chem. Phys., 12, 11631–11645, https://doi.org/10.5194/acp-12-11631-2012, https://doi.org/10.5194/acp-12-11631-2012, 2012
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Revealing the significant acceleration of hydrofluorocarbon (HFC) emissions in eastern Asia through long-term atmospheric observations
Interpreting Geostationary Environment Monitoring Spectrometer (GEMS) geostationary satellite observations of the diurnal variation in nitrogen dioxide (NO2) over East Asia
An intercomparison of satellite, airborne, and ground-level observations with WRF–CAMx simulations of NO2 columns over Houston, Texas, during the September 2021 TRACER-AQ campaign
Interannual variability of summertime formaldehyde (HCHO) vertical column density and its main drivers at northern high latitudes
The impact of multi-decadal changes in VOC speciation on urban ozone chemistry: a case study in Birmingham, United Kingdom
Technical note: Challenges in detecting free tropospheric ozone trends in a sparsely sampled environment
Combined assimilation of NOAA surface and MIPAS satellite observations to constrain the global budget of carbonyl sulfide
The impact of gaseous degradation on the gas–particle partitioning of methylated polycyclic aromatic hydrocarbons
Technical note: An assessment of the performance of statistical bias correction techniques for global chemistry–climate model surface ozone fields
A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles
High-resolution US methane emissions inferred from an inversion of 2019 TROPOMI satellite data: contributions from individual states, urban areas, and landfills
Summertime tropospheric ozone source apportionment study in the Madrid region (Spain)
CO anthropogenic emissions in Europe from 2011 to 2021: insights from Measurement of Pollution in the Troposphere (MOPITT) satellite data
Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks
Analysis of an intense O3 pollution episode on the Atlantic coast of the Iberian Peninsula using photochemical modeling: characterization of transport pathways and accumulation processes
Atmospheric oxygen as a tracer for fossil fuel carbon dioxide: a sensitivity study in the UK
MIXv2: a long-term mosaic emission inventory for Asia (2010–2017)
Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation
Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol
Development of a detailed gaseous oxidation scheme of naphthalene for SOA formation and speciation
Spatial disparities of ozone pollution in the Sichuan Basin spurred by extreme, hot weather
Global impacts of aviation on air quality evaluated at high resolution
Enhancing Long-Term Trend Simulation of Global Tropospheric OH and Its Drivers from 2005–2019: A Synergistic Integration of Model Simulations and Satellite Observations
Large contribution of soil emissions to the atmospheric nitrogen budget and their impacts on air quality and temperature rise in North China
Bias correction of OMI HCHO columns based on FTIR and aircraft measurements and impact on top-down emission estimates
Intercomparison of GEOS-Chem and CAM-chem tropospheric oxidant chemistry within the Community Earth System Model version 2 (CESM2)
Investigation of the renewed methane growth post-2007 with high-resolution 3-D variational inverse modeling and isotopic constraints
NOx emissions in France in 2019–2021 as estimated by the high spatial resolution assimilation of TROPOMI NO2 observations
Estimating NOx emissions of stack plumes using a high-resolution atmospheric chemistry model and satellite-derived NO2 columns
Revisiting day-of-week ozone patterns in an era of evolving US air quality
Changes in South American Surface Ozone Trends: Exploring the Influences of Precursors and Extreme Events
Air quality and radiative impacts of downward-propagating sudden stratospheric warmings (SSWs)
Estimation of the atmospheric hydroxyl radical oxidative capacity using multiple hydrofluorocarbons (HFCs)
Investigating the differences in calculating global mean surface CO2 abundance: the impact of analysis methodologies and site selection
Meteorological characteristics of extreme ozone pollution events in China and their future predictions
Evaluating modelled tropospheric columns of CH4, CO, and O3 in the Arctic using ground-based Fourier transform infrared (FTIR) measurements
Evaluation of modelled versus observed NMVOC compounds at EMEP sites in Europe
The high-resolution Global Aviation emissions Inventory based on ADS-B (GAIA) for 2019–2021
Zonal variability of methane trends derived from satellite data
Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021
Current status of model predictions of volatile organic compounds and impacts on surface ozone predictions during summer in China
Utility of Geostationary Lightning Mapper-derived lightning NO emission estimates in air quality modeling studies
Constraint of non-methane volatile organic compound emissions with TROPOMI HCHO observations and its impact on summertime surface ozone simulation over China
The suitability of atmospheric oxygen measurements to constrain western European fossil-fuel CO2 emissions and their trends
Identifying decadal trends in deweathered concentrations of criteria air pollutants in Canadian urban atmospheres with machine learning approaches
Future tropospheric ozone budget and distribution over east Asia under a net-zero scenario
Why Did Ozone Concentrations Increase During Shanghai’s Static Management? A Statistical and Radical Chemistry Perspective
Comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA: implications for atmospheric oxidative capacity
Insights into soil NO emissions and the contribution to surface ozone formation in China
Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model
Haklim Choi, Alison L. Redington, Hyeri Park, Jooil Kim, Rona L. Thompson, Jens Mühle, Peter K. Salameh, Christina M. Harth, Ray F. Weiss, Alistair J. Manning, and Sunyoung Park
Atmos. Chem. Phys., 24, 7309–7330, https://doi.org/10.5194/acp-24-7309-2024, https://doi.org/10.5194/acp-24-7309-2024, 2024
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We analyzed with an inversion model the atmospheric abundance of hydrofluorocarbons (HFCs), potent greenhouse gases, from 2008 to 2020 at Gosan station in South Korea and revealed a significant increase in emissions, especially from eastern China and Japan. This increase contradicts reported data, underscoring the need for accurate monitoring and reporting. Our findings are crucial for understanding and managing global HFCs emissions, highlighting the importance of efforts to reduce HFCs.
Laura Hyesung Yang, Daniel J. Jacob, Ruijun Dang, Yujin J. Oak, Haipeng Lin, Jhoon Kim, Shixian Zhai, Nadia K. Colombi, Drew C. Pendergrass, Ellie Beaudry, Viral Shah, Xu Feng, Robert M. Yantosca, Heesung Chong, Junsung Park, Hanlim Lee, Won-Jin Lee, Soontae Kim, Eunhye Kim, Katherine R. Travis, James H. Crawford, and Hong Liao
Atmos. Chem. Phys., 24, 7027–7039, https://doi.org/10.5194/acp-24-7027-2024, https://doi.org/10.5194/acp-24-7027-2024, 2024
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The Geostationary Environment Monitoring Spectrometer (GEMS) provides hourly measurements of NO2. We use the chemical transport model to find how emissions, chemistry, and transport drive the changes in NO2 observed by GEMS at different times of the day. In winter, the chemistry plays a minor role, and high daytime emissions dominate the diurnal variation in NO2, balanced by transport. In summer, emissions, chemistry, and transport play an important role in shaping the diurnal variation in NO2.
M. Omar Nawaz, Jeremiah Johnson, Greg Yarwood, Benjamin de Foy, Laura Judd, and Daniel L. Goldberg
Atmos. Chem. Phys., 24, 6719–6741, https://doi.org/10.5194/acp-24-6719-2024, https://doi.org/10.5194/acp-24-6719-2024, 2024
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NO2 is a gas with implications for air pollution. A campaign conducted in Houston provided an opportunity to compare NO2 from different instruments and a model. Aircraft and satellite observations agreed well with measurements on the ground; however, the latter estimated lower values. We find that model-simulated NO2 was lower than observations, especially downtown, suggesting that NO2 sources associated with the urban core of Houston, such as vehicle emissions, may be underestimated.
Tianlang Zhao, Jingqiu Mao, Zolal Ayazpour, Gonzalo González Abad, Caroline R. Nowlan, and Yiqi Zheng
Atmos. Chem. Phys., 24, 6105–6121, https://doi.org/10.5194/acp-24-6105-2024, https://doi.org/10.5194/acp-24-6105-2024, 2024
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HCHO variability is a key tracer in understanding VOC emissions in response to climate change. We investigate the role of methane oxidation and biogenic and wildfire emissions in HCHO interannual variability over northern high latitudes in summer, emphasizing wildfires as a key driver of HCHO interannual variability in Alaska, Siberia and northern Canada using satellite HCHO and SIF retrievals and then GEOS-Chem model. We show SIF is a tool to understand biogenic HCHO variability in this region.
Jianghao Li, Alastair C. Lewis, Jim R. Hopkins, Stephen J. Andrews, Tim Murrells, Neil Passant, Ben Richmond, Siqi Hou, William J. Bloss, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 24, 6219–6231, https://doi.org/10.5194/acp-24-6219-2024, https://doi.org/10.5194/acp-24-6219-2024, 2024
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A summertime ozone event at an urban site in Birmingham is sensitive to volatile organic compounds (VOCs) – particularly those of oxygenated VOCs. The roles of anthropogenic VOC sources in urban ozone chemistry are examined by integrating the 1990–2019 national atmospheric emission inventory into model scenarios. Road transport remains the most powerful means of further reducing ozone in this case study, but the benefits may be offset if solvent emissions of VOCs continue to increase.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Jin Ma, Linda M. J. Kooijmans, Norbert Glatthor, Stephen A. Montzka, Marc von Hobe, Thomas Röckmann, and Maarten C. Krol
Atmos. Chem. Phys., 24, 6047–6070, https://doi.org/10.5194/acp-24-6047-2024, https://doi.org/10.5194/acp-24-6047-2024, 2024
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The global budget of atmospheric COS can be optimised by inverse modelling using TM5-4DVAR, with the co-constraints of NOAA surface observations and MIPAS satellite data. We found reduced COS biosphere uptake from inversions and improved land and ocean separation using MIPAS satellite data assimilation. Further improvements are expected from better quantification of COS ocean and biosphere fluxes.
Fu-Jie Zhu, Zi-Feng Zhang, Li-Yan Liu, Pu-Fei Yang, Peng-Tuan Hu, Geng-Bo Ren, Meng Qin, and Wan-Li Ma
Atmos. Chem. Phys., 24, 6095–6103, https://doi.org/10.5194/acp-24-6095-2024, https://doi.org/10.5194/acp-24-6095-2024, 2024
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Gas–particle (G–P) partitioning is an important atmospheric behavior for semi-volatile organic compounds (SVOCs). Diurnal variation in G–P partitioning of methylated polycyclic aromatic hydrocarbons (Me-PAHs) demonstrates the possible influence of gaseous degradation; the enhancement of gaseous degradation (1.10–5.58 times) on G–P partitioning is verified by a steady-state G–P partitioning model. The effect of gaseous degradation on G–P partitioning of (especially light) SVOCs is important.
Christoph Staehle, Harald E. Rieder, Arlene M. Fiore, and Jordan L. Schnell
Atmos. Chem. Phys., 24, 5953–5969, https://doi.org/10.5194/acp-24-5953-2024, https://doi.org/10.5194/acp-24-5953-2024, 2024
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Chemistry–climate models show biases compared to surface ozone observations and thus require bias correction for impact studies and the assessment of air quality changes. We compare the performance of commonly used correction techniques for model outputs available via CMIP6. While all methods can reduce model biases, better results are obtained from more complex approaches. Thus, our study suggests broader use of these techniques in studies seeking to inform air quality management and policy.
Qindan Zhu, Rebecca H. Schwantes, Matthew Coggon, Colin Harkins, Jordan Schnell, Jian He, Havala O. T. Pye, Meng Li, Barry Baker, Zachary Moon, Ravan Ahmadov, Eva Y. Pfannerstill, Bryan Place, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Anthony Bucholtz, John H. Seinfeld, Carsten Warneke, Chelsea E. Stockwell, Lu Xu, Kristen Zuraski, Michael A. Robinson, J. Andrew Neuman, Patrick R. Veres, Jeff Peischl, Steven S. Brown, Allen H. Goldstein, Ronald C. Cohen, and Brian C. McDonald
Atmos. Chem. Phys., 24, 5265–5286, https://doi.org/10.5194/acp-24-5265-2024, https://doi.org/10.5194/acp-24-5265-2024, 2024
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Volatile organic compounds (VOCs) fuel the production of air pollutants like ozone and particulate matter. The representation of VOC chemistry remains challenging due to its complexity in speciation and reactions. Here, we develop a chemical mechanism, RACM2B-VCP, that better represents VOC chemistry in urban areas such as Los Angeles. We also discuss the contribution of VOCs emitted from volatile chemical products and other anthropogenic sources to total VOC reactivity and O3.
Hannah Nesser, Daniel J. Jacob, Joannes D. Maasakkers, Alba Lorente, Zichong Chen, Xiao Lu, Lu Shen, Zhen Qu, Melissa P. Sulprizio, Margaux Winter, Shuang Ma, A. Anthony Bloom, John R. Worden, Robert N. Stavins, and Cynthia A. Randles
Atmos. Chem. Phys., 24, 5069–5091, https://doi.org/10.5194/acp-24-5069-2024, https://doi.org/10.5194/acp-24-5069-2024, 2024
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We quantify 2019 methane emissions in the contiguous US (CONUS) at a ≈ 25 km × 25 km resolution using satellite methane observations. We find a 13 % upward correction to the 2023 US Environmental Protection Agency (EPA) Greenhouse Gas Emissions Inventory (GHGI) for 2019, with large corrections to individual states, urban areas, and landfills. This may present a challenge for US climate policies and goals, many of which target significant reductions in methane emissions.
David de la Paz, Rafael Borge, Juan Manuel de Andrés, Luis Tovar, Golam Sarwar, and Sergey L. Napelenok
Atmos. Chem. Phys., 24, 4949–4972, https://doi.org/10.5194/acp-24-4949-2024, https://doi.org/10.5194/acp-24-4949-2024, 2024
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This source apportionment modeling study shows that around 70 % of ground-level O3 in Madrid (Spain) is transported from other regions. Nonetheless, emissions from local sources, mainly road traffic, play a significant role, especially under atmospheric stagnation. Local measures during those conditions may be able to reduce O3 peaks by up to 30 % and, thus, lessen impacts from high-O3 episodes in the Madrid metropolitan area.
Audrey Fortems-Cheiney, Gregoire Broquet, Elise Potier, Robin Plauchu, Antoine Berchet, Isabelle Pison, Hugo Denier van der Gon, and Stijn Dellaert
Atmos. Chem. Phys., 24, 4635–4649, https://doi.org/10.5194/acp-24-4635-2024, https://doi.org/10.5194/acp-24-4635-2024, 2024
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We have estimated the carbon monixide (CO) European emissions from satellite observations of the MOPITT instrument at the relatively high resolution of 0.5° for a period of over 10 years from 2011 to 2021. The analysis of the inversion results reveals the challenges associated with the inversion of CO emissions at the regional scale over Europe.
Amy Christiansen, Loretta J. Mickley, and Lu Hu
Atmos. Chem. Phys., 24, 4569–4589, https://doi.org/10.5194/acp-24-4569-2024, https://doi.org/10.5194/acp-24-4569-2024, 2024
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In this work, we provide an additional constraint on emissions and trends of nitrogen oxides using nitrate wet deposition (NWD) fluxes over the United States and Europe from 1980–2020. We find that NWD measurements constrain total NOx emissions well. We also find evidence of NOx emission overestimates in both domains, but especially over Europe, where NOx emissions are overestimated by a factor of 2. Reducing NOx emissions over Europe improves model representation of ozone at the surface.
Eduardo Torre-Pascual, Gotzon Gangoiti, Ana Rodríguez-García, Estibaliz Sáez de Cámara, Joana Ferreira, Carla Gama, María Carmen Gómez, Iñaki Zuazo, Jose Antonio García, and Maite de Blas
Atmos. Chem. Phys., 24, 4305–4329, https://doi.org/10.5194/acp-24-4305-2024, https://doi.org/10.5194/acp-24-4305-2024, 2024
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We present an analysis of an intense air pollution episode of tropospheric ozone (O3) along the Atlantic coast of the Iberian Peninsula, incorporating both measured and simulated parameters. Our study extends beyond surface-level factors to include altitude-related parameters. These episodes stem from upper-atmosphere O3 accumulation in preceding days, transported to surface layers, causing rapid O3 concentration increase.
Hannah Chawner, Eric Saboya, Karina E. Adcock, Tim Arnold, Yuri Artioli, Caroline Dylag, Grant L. Forster, Anita Ganesan, Heather Graven, Gennadi Lessin, Peter Levy, Ingrid T. Luijkx, Alistair Manning, Penelope A. Pickers, Chris Rennick, Christian Rödenbeck, and Matthew Rigby
Atmos. Chem. Phys., 24, 4231–4252, https://doi.org/10.5194/acp-24-4231-2024, https://doi.org/10.5194/acp-24-4231-2024, 2024
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The quantity of atmospheric potential oxygen (APO), derived from coincident measurements of carbon dioxide (CO2) and oxygen (O2), has been proposed as a tracer for fossil fuel CO2 emissions. In this model sensitivity study, we examine the use of APO for this purpose in the UK and compare our model to observations. We find that our model simulations are most sensitive to uncertainties relating to ocean fluxes and boundary conditions.
Meng Li, Junichi Kurokawa, Qiang Zhang, Jung-Hun Woo, Tazuko Morikawa, Satoru Chatani, Zifeng Lu, Yu Song, Guannan Geng, Hanwen Hu, Jinseok Kim, Owen R. Cooper, and Brian C. McDonald
Atmos. Chem. Phys., 24, 3925–3952, https://doi.org/10.5194/acp-24-3925-2024, https://doi.org/10.5194/acp-24-3925-2024, 2024
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In this work, we developed MIXv2, a mosaic Asian emission inventory for 2010–2017. With high spatial (0.1°) and monthly temporal resolution, MIXv2 integrates anthropogenic and open biomass burning emissions across seven sectors following a mosaic methodology. It provides CO2 emissions data alongside nine key pollutants and three chemical mechanisms. Our publicly accessible gridded monthly emissions data can facilitate long-term atmospheric and climate model analyses.
Xiaomeng Zhang, Yongjian Lian, Shendong Tan, and Shi Yin
Atmos. Chem. Phys., 24, 3593–3612, https://doi.org/10.5194/acp-24-3593-2024, https://doi.org/10.5194/acp-24-3593-2024, 2024
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Atmospheric new particle formation (NPF) has a significant influence on the global climate, local air quality and human health. Using a combination of quantum chemical calculations and kinetics modeling, we find that thhe gas-phase organosulfate produced from consumption of SO3 can significantly enhance SA–DMA nucleation in the polluted boundary layer, resulting in non-negligible contributions to NPF. Our findings provide important insights into organic sulfur in atmospheric aerosol formation.
Linia Tashmim, William C. Porter, Qianjie Chen, Becky Alexander, Charles H. Fite, Christopher D. Holmes, Jeffrey R. Pierce, Betty Croft, and Sakiko Ishino
Atmos. Chem. Phys., 24, 3379–3403, https://doi.org/10.5194/acp-24-3379-2024, https://doi.org/10.5194/acp-24-3379-2024, 2024
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Dimethyl sulfide (DMS) is mostly emitted from ocean surfaces and represents the largest natural source of sulfur for the atmosphere. Once in the atmosphere, DMS forms stable oxidation products such as SO2 and H2SO4, which can subsequently contribute to airborne particle formation and growth. In this study, we update the DMS oxidation mechanism in the chemical transport model GEOS-Chem and describe resulting changes in particle growth as well as the overall global sulfur budget.
Victor Lannuque and Karine Sartelet
EGUsphere, https://doi.org/10.5194/egusphere-2024-711, https://doi.org/10.5194/egusphere-2024-711, 2024
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation and speciation from naphthalene oxidation. This study details the development of the first near-explicit chemical scheme for naphthalene oxidation by OH including kinetic and mechanistic data and able to reproduce most of the experimentally identified products in both gas and particle phases.
Nan Wang, Yunsong Du, Dongyang Chen, Haiyan Meng, Xi Chen, Li Zhou, Guangming Shi, Yu Zhan, Miao Feng, Wei Li, Mulan Chen, Zhenliang Li, and Fumo Yang
Atmos. Chem. Phys., 24, 3029–3042, https://doi.org/10.5194/acp-24-3029-2024, https://doi.org/10.5194/acp-24-3029-2024, 2024
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In the scorching August 2022 heatwave, China's Sichuan Basin saw a stark contrast in ozone (O3) levels between Chengdu and Chongqing. The regional disparities were studied considering meteorology, precursors, photochemistry, and transportation. The study highlighted the importance of tailored pollution control measures and underlined the necessity for region-specific strategies to combat O3 pollution on a regional scale.
Sebastian D. Eastham, Guillaume P. Chossière, Raymond L. Speth, Daniel J. Jacob, and Steven R. H. Barrett
Atmos. Chem. Phys., 24, 2687–2703, https://doi.org/10.5194/acp-24-2687-2024, https://doi.org/10.5194/acp-24-2687-2024, 2024
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Emissions from aircraft are known to cause air quality impacts worldwide, but the scale and mechanisms of this impact are not well understood. This work uses high-resolution computational modeling of the atmosphere to show that air pollution changes from aviation are mostly the result of emissions during cruise (high-altitude) operations, that these impacts are related to how much non-aviation pollution is present, and that prior regional assessments have underestimated these impacts.
Amir H. Souri, Bryan N. Duncan, Sarah A. Strode, Daniel C. Anderson, Michael E. Manyin, Junhua Liu, Luke D. Oman, Zhen Zhang, and Brad Weir
EGUsphere, https://doi.org/10.5194/egusphere-2024-410, https://doi.org/10.5194/egusphere-2024-410, 2024
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We explore a new method to make use of the wealth of information obtained from satellite observations of Aura OMI NO2, HCHO, along with MERRA2 reanalysis in NASA’s GEOS model equipped with an efficient tropospheric OH (TOH) estimator to enhance the representation of TOH spatial distribution and its long-term trends. This new framework helps us pinpoint regional inaccuracies in TOH and differentiate between established prior knowledge and newly acquired information from satellites on TOH trends.
Tong Sha, Siyu Yang, Qingcai Chen, Liangqing Li, Xiaoyan Ma, Yan-Lin Zhang, Zhaozhong Feng, K. Folkert Boersma, and Jun Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-359, https://doi.org/10.5194/egusphere-2024-359, 2024
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By using an updated soil reactive nitrogen emission scheme in the UI-WRF-Chem model, we investigate the underappreciated role of soil NO and HONO (Nr) emissions on air quality and temperature rise in North China. The significant contributions of soil Nr emissions to O3 and secondary pollutants, exceeding the effects of soil NOx or HONO emission alone. And soil Nr emissions play an important role in mitigating O3 pollution and addressing climate change.
Jean-François Müller, Trissevgeni Stavrakou, Glenn-Michael Oomen, Beata Opacka, Isabelle De Smedt, Alex Guenther, Corinne Vigouroux, Bavo Langerock, Carlos Augusto Bauer Aquino, Michel Grutter, James Hannigan, Frank Hase, Rigel Kivi, Erik Lutsch, Emmanuel Mahieu, Maria Makarova, Jean-Marc Metzger, Isamu Morino, Isao Murata, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Amelie Röhling, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Alan Fried
Atmos. Chem. Phys., 24, 2207–2237, https://doi.org/10.5194/acp-24-2207-2024, https://doi.org/10.5194/acp-24-2207-2024, 2024
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Formaldehyde observations from satellites can be used to constrain the emissions of volatile organic compounds, but those observations have biases. Using an atmospheric model, aircraft and ground-based remote sensing data, we quantify these biases, propose a correction to the data, and assess the consequence of this correction for the evaluation of emissions.
Haipeng Lin, Louisa K. Emmons, Elizabeth W. Lundgren, Laura Hyesung Yang, Xu Feng, Ruijun Dang, Shixian Zhai, Yunxiao Tang, Makoto M. Kelp, Nadia K. Colombi, Sebastian D. Eastham, Thibaud M. Fritz, and Daniel J. Jacob
EGUsphere, https://doi.org/10.5194/egusphere-2024-470, https://doi.org/10.5194/egusphere-2024-470, 2024
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Tropospheric ozone is a major air pollutant, greenhouse gas, and a major indicator of model skill. Global atmospheric chemistry models show large differences in simulations of tropospheric ozone but isolating sources of differences is complicated by different model environments. By implementing the GEOS-Chem model side-by-side to CAM-chem within a common Earth system model, we identify and evaluate specific differences between the two models and their impacts on key chemical species.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, and Philippe Bousquet
Atmos. Chem. Phys., 24, 2129–2167, https://doi.org/10.5194/acp-24-2129-2024, https://doi.org/10.5194/acp-24-2129-2024, 2024
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We investigate the causes of the renewed growth of atmospheric methane (CH4) after 2007 using inverse modeling. We use the additional information provided by observations of CH4 isotopic compositions to better differentiate between the emission categories. Accounting for the large uncertainties in source signatures, our results suggest that the post-2007 increase in atmospheric CH4 was caused by similar increases in emissions from (1) fossil fuels and (2) agriculture and waste.
Robin Plauchu, Audrey Fortems-Cheiney, Grégoire Broquet, Isabelle Pison, Antoine Berchet, Elise Potier, Gaëlle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, and Henk Eskes
EGUsphere, https://doi.org/10.5194/egusphere-2024-103, https://doi.org/10.5194/egusphere-2024-103, 2024
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Over 2019–2021, our study used satellite data to assess NOx emissions in France. National budgets decreased due to effective policies, but COVID-19 lockdowns in 2020 didn't uniformly reduce emissions. Focusing on urban areas revealed varied impacts, with challenges like cloud coverage and model errors limiting precision. These findings contribute valuable insights into factors influencing emission assessments, informing future research.
Maarten Krol, Bart van Stratum, Isidora Anglou, and Klaas Folkert Boersma
EGUsphere, https://doi.org/10.5194/egusphere-2023-2519, https://doi.org/10.5194/egusphere-2023-2519, 2024
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This paper presents detailed plume simulations of nitrogen oxides and carbon dioxide that are emitted from four large industrial facilities world-wide. Results from the high-resolution simulations that include atmospheric chemistry are compared to nitrogen-dioxide observations from satellites. We find good performance of the model and show that common assumptions that are used in simplified models need revision. This work is important for the monitoring of emissions using satellite data.
Heather Simon, Christian Hogrefe, Andrew Whitehill, Kristen M. Foley, Jennifer Liljegren, Norm Possiel, Benjamin Wells, Barron H. Henderson, Lukas C. Valin, Gail Tonnesen, K. Wyat Appel, and Shannon Koplitz
Atmos. Chem. Phys., 24, 1855–1871, https://doi.org/10.5194/acp-24-1855-2024, https://doi.org/10.5194/acp-24-1855-2024, 2024
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We assess observed and modeled ozone weekend–weekday differences in the USA from 2002–2019. A subset of urban areas that were NOx-saturated at the beginning of the period transitioned to NOx-limited conditions. Multiple rural areas of California were NOx-limited for the entire period but become less influenced by local day-of-week emission patterns in more recent years. The model produces more NOx-saturated conditions than the observations but captures trends in weekend–weekday ozone patterns.
Rodrigo J. Seguel, Lucas Castillo, Charlie Opazo, Néstor Y. Rojas, Thiago Nogueira, María Cazorla, Mario Gavidia-Calderón, Laura Gallardo, René Garreaud, Tomás Carrasco-Escaff, and Yasin Elshorbany
EGUsphere, https://doi.org/10.5194/egusphere-2024-328, https://doi.org/10.5194/egusphere-2024-328, 2024
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Our research found that surface ozone trends in major South American cities increase or remain steady but show no signs of decreasing. Extra-tropical cities (Santiago and São Paulo), in particular, face the highest risk of ozone exposure. Furthermore, we found that prolonged heat waves and large fires explain many of the most extreme ozone values.
Ryan S. Williams, Michaela I. Hegglin, Patrick Jöckel, Hella Garny, and Keith P. Shine
Atmos. Chem. Phys., 24, 1389–1413, https://doi.org/10.5194/acp-24-1389-2024, https://doi.org/10.5194/acp-24-1389-2024, 2024
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During winter, a brief but abrupt reversal of the mean stratospheric westerly flow (~30 km high) around the Arctic occurs ~6 times a decade. Using a chemistry–climate model, about half of these events are shown to induce large anomalies in Arctic ozone (>25 %) and water vapour (>±25 %) around ~8–12 km altitude for up to 2–3 months, important for weather forecasting. We also calculate a doubling to trebling of the risk in breaches of mid-latitude surface air quality (ozone) standards (~60 ppbv).
Rona L. Thompson, Stephen A. Montzka, Martin K. Vollmer, Jgor Arduini, Molly Crotwell, Paul B. Krummel, Chris Lunder, Jens Mühle, Simon O'Doherty, Ronald G. Prinn, Stefan Reimann, Isaac Vimont, Hsiang Wang, Ray F. Weiss, and Dickon Young
Atmos. Chem. Phys., 24, 1415–1427, https://doi.org/10.5194/acp-24-1415-2024, https://doi.org/10.5194/acp-24-1415-2024, 2024
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The hydroxyl radical determines the atmospheric lifetimes of numerous species including methane. Since OH is very short-lived, it is not possible to directly measure its concentration on scales relevant for understanding its effect on other species. Here, OH is inferred by looking at changes in hydrofluorocarbons (HFCs). We find that OH levels have been fairly stable over our study period (2004 to 2021), suggesting that OH is not the main driver of the recent increase in atmospheric methane.
Zhendong Wu, Alex Vermeulen, Yousuke Sawa, Ute Karstens, Wouter Peters, Remco de Kok, Xin Lan, Yasuyuki Nagai, Akinori Ogi, and Oksana Tarasova
Atmos. Chem. Phys., 24, 1249–1264, https://doi.org/10.5194/acp-24-1249-2024, https://doi.org/10.5194/acp-24-1249-2024, 2024
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This study focuses on exploring the differences in calculating global surface CO2 and its growth rate, considering the impact of analysis methodologies and site selection. Our study reveals that the current global CO2 network has a good capacity to represent global surface CO2 and its growth rate, as well as trends in atmospheric CO2 mass changes. However, small differences exist in different analyses due to the impact of methodology and site selection.
Yang Yang, Yang Zhou, Hailong Wang, Mengyun Li, Huimin Li, Pinya Wang, Xu Yue, Ke Li, Jia Zhu, and Hong Liao
Atmos. Chem. Phys., 24, 1177–1191, https://doi.org/10.5194/acp-24-1177-2024, https://doi.org/10.5194/acp-24-1177-2024, 2024
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This study reveals that extreme ozone pollution over the North China Plain and Yangtze River Delta is due to the chemical production related to hot and dry conditions, and the regional transport explains the ozone pollution over the Sichuan Basin and Pearl River Delta. The frequency of meteorological conditions of the extreme ozone pollution increases from the past to the future. The sustainable scenario is the optimal path to retaining clean air in China in the future.
Victoria A. Flood, Kimberly Strong, Cynthia H. Whaley, Kaley A. Walker, Thomas Blumenstock, James W. Hannigan, Johan Mellqvist, Justus Notholt, Mathias Palm, Amelie N. Röhling, Stephen Arnold, Stephen Beagley, Rong-You Chien, Jesper Christensen, Makoto Deushi, Srdjan Dobricic, Xinyi Dong, Joshua S. Fu, Michael Gauss, Wanmin Gong, Joakim Langner, Kathy S. Law, Louis Marelle, Tatsuo Onishi, Naga Oshima, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Manu A. Thomas, Svetlana Tsyro, and Steven Turnock
Atmos. Chem. Phys., 24, 1079–1118, https://doi.org/10.5194/acp-24-1079-2024, https://doi.org/10.5194/acp-24-1079-2024, 2024
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It is important to understand the composition of the Arctic atmosphere and how it is changing. Atmospheric models provide simulations that can inform policy. This study examines simulations of CH4, CO, and O3 by 11 models. Model performance is assessed by comparing results matched in space and time to measurements from five high-latitude ground-based infrared spectrometers. This work finds that models generally underpredict the concentrations of these gases in the Arctic troposphere.
Yao Ge, Sverre Solberg, Mathew Heal, Stefan Reimann, Willem van Caspel, Bryan Hellack, Thérèse Salameh, and David Simpson
EGUsphere, https://doi.org/10.5194/egusphere-2023-3102, https://doi.org/10.5194/egusphere-2023-3102, 2024
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Atmospheric volatile organic compounds (VOC) constitute many species, acting as precursors to ozone and aerosol. Given the uncertainties in VOC emissions, lack of evaluation studies, and recent changes in emissions, this work adapts the EMEP MSC-W to evaluate emission inventories in Europe. We focus on the varying agreement between modelled and measured VOCs across different species, and underscore potential inaccuracies in total and sector-specific emission estimates.
Roger Teoh, Zebediah Engberg, Marc Shapiro, Lynnette Dray, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 725–744, https://doi.org/10.5194/acp-24-725-2024, https://doi.org/10.5194/acp-24-725-2024, 2024
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Emissions from aircraft contribute to climate change and degrade air quality. We describe an up-to-date 4D emissions inventory of global aviation from 2019 to 2021 based on actual flown trajectories. In 2019, 40.2 million flights collectively travelled 61 billion kilometres using 283 Tg of fuel. Long-haul flights were responsible for 43 % of CO2. The emissions inventory is made available for use in future studies to evaluate the negative externalities arising from global aviation.
Jonas Hachmeister, Oliver Schneising, Michael Buchwitz, John P. Burrows, Justus Notholt, and Matthias Buschmann
Atmos. Chem. Phys., 24, 577–595, https://doi.org/10.5194/acp-24-577-2024, https://doi.org/10.5194/acp-24-577-2024, 2024
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We quantified changes in atmospheric methane concentrations using satellite data and a dynamic linear model approach. We calculated global annual methane increases for the years 2019–2022, which are in good agreement with other sources. For zonal methane growth rates, we identified strong inter-hemispheric differences in 2019 and 2022. For 2022, we could attribute decreases in the global growth rate to the Northern Hemisphere, possibly related to a reduction in anthropogenic emissions.
Glenn-Michael Oomen, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, Thomas Blumenstock, Rigel Kivi, Maria Makarova, Mathias Palm, Amelie Röhling, Yao Té, Corinne Vigouroux, Martina M. Friedrich, Udo Frieß, François Hendrick, Alexis Merlaud, Ankie Piters, Andreas Richter, Michel Van Roozendael, and Thomas Wagner
Atmos. Chem. Phys., 24, 449–474, https://doi.org/10.5194/acp-24-449-2024, https://doi.org/10.5194/acp-24-449-2024, 2024
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Natural emissions from vegetation have a profound impact on air quality for their role in the formation of harmful tropospheric ozone and organic aerosols, yet these emissions are highly uncertain. In this study, we quantify emissions of organic gases over Europe using high-quality satellite measurements of formaldehyde. These satellite observations suggest that emissions from vegetation are much higher than predicted by models, especially in southern Europe.
Yongliang She, Jingyi Li, Xiaopu Lyu, Hai Guo, Momei Qin, Xiaodong Xie, Kangjia Gong, Fei Ye, Jianjiong Mao, Lin Huang, and Jianlin Hu
Atmos. Chem. Phys., 24, 219–233, https://doi.org/10.5194/acp-24-219-2024, https://doi.org/10.5194/acp-24-219-2024, 2024
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In this study, we use multi-site volatile organic compound (VOC) measurements to evaluate the CMAQ-model-predicted VOCs and assess the impacts of VOC bias on O3 simulation. Our results demonstrate that current modeling setups and emission inventories are likely to underpredict VOC concentrations, and this underprediction of VOCs contributes to lower O3 predictions in China.
Peiyang Cheng, Arastoo Pour-Biazar, Yuling Wu, Shi Kuang, Richard T. McNider, and William J. Koshak
Atmos. Chem. Phys., 24, 41–63, https://doi.org/10.5194/acp-24-41-2024, https://doi.org/10.5194/acp-24-41-2024, 2024
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Lightning-induced nitrogen monoxide (LNO) emission can be estimated from geostationary satellite observations. The present study uses the LNO emission estimates derived from geostationary satellite observations in an air quality modeling system to investigate the impact of LNO on air quality. Results indicate that significant ozone increase could be due to long-distance chemical transport, lightning activity in the upwind direction, and the mixing of high LNO (or ozone) plumes.
Shuzhuang Feng, Fei Jiang, Tianlu Qian, Nan Wang, Mengwei Jia, Songci Zheng, Jiansong Chen, Fang Ying, and Weimin Ju
EGUsphere, https://doi.org/10.5194/egusphere-2023-2654, https://doi.org/10.5194/egusphere-2023-2654, 2024
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We developed a multi-air pollutant inversion system to estimate non-methane volatile organic compound (NMVOC) emissions using TROPOMI formaldehyde retrievals. We found that the inversion significantly improved formaldehyde simulations and reduced NMVOC emission uncertainties. The optimized NMVOC emissions effectively corrected the overestimation of O3 levels, mainly by decreasing the rate of the RO2 + NO reaction and increasing the rate of the NO2 + OH reaction.
Christian Rödenbeck, Karina E. Adcock, Markus Eritt, Maksym Gachkivskyi, Christoph Gerbig, Samuel Hammer, Armin Jordan, Ralph F. Keeling, Ingeborg Levin, Fabian Maier, Andrew C. Manning, Heiko Moossen, Saqr Munassar, Penelope A. Pickers, Michael Rothe, Yasunori Tohjima, and Sönke Zaehle
Atmos. Chem. Phys., 23, 15767–15782, https://doi.org/10.5194/acp-23-15767-2023, https://doi.org/10.5194/acp-23-15767-2023, 2023
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The carbon dioxide content of the Earth atmosphere is increasing due to human emissions from burning of fossil fuels, causing global climate change. The strength of the fossil-fuel emissions is estimated by inventories based on energy data, but independent validation of these inventories has been recommended by the Intergovernmental Panel on Climate Change. Here we investigate the potential to validate inventories based on measurements of small changes in the atmospheric oxygen content.
Xiaohong Yao and Leiming Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2023-2968, https://doi.org/10.5194/egusphere-2023-2968, 2023
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This study investigates long-term trends of criteria air pollutants, including NO2, CO, SO2, O3 and PM2.5, and (NO2+O3) measured in ten Canadian cities during the last two to three decades and associated driving forces in terms of emission reductions, perturbations from varying weather conditions and large-scale wildfires, and changes in O3 sources and sinks.
Xuewei Hou, Oliver Wild, Bin Zhu, and James Lee
Atmos. Chem. Phys., 23, 15395–15411, https://doi.org/10.5194/acp-23-15395-2023, https://doi.org/10.5194/acp-23-15395-2023, 2023
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In response to the climate crisis, many countries have committed to net zero in a certain future year. The impacts of net-zero scenarios on tropospheric O3 are less well studied and remain unclear. In this study, we quantified the changes of tropospheric O3 budgets, spatiotemporal distributions of future surface O3 in east Asia and regional O3 source contributions for 2060 under a net-zero scenario using the NCAR Community Earth System Model (CESM) and online O3-tagging methods.
Jian Zhu, Shanshan Wang, Chuanqi Gu, Zhiwen Jiang, Sanbao Zhang, Ruibin Xue, Yuhao Yan, and Bin Zhou
EGUsphere, https://doi.org/10.5194/egusphere-2023-2142, https://doi.org/10.5194/egusphere-2023-2142, 2023
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In 2022, Shanghai implemented city-wide static management measures during the high-ozone season in April and May, providing a change to study ozone pollution control. Despite significant emissions reductions, ozone levels increased by 23 %. Statistically, the number of days with higher ozone diurnal variation types increased during the lockdown period. The uneven decline in VOC and NO2 emissions led to heightened photochemical processes, resulting in the observed ozone level rise.
Meghna Soni, Rolf Sander, Lokesh K. Sahu, Domenico Taraborrelli, Pengfei Liu, Ankit Patel, Imran A. Girach, Andrea Pozzer, Sachin S. Gunthe, and Narendra Ojha
Atmos. Chem. Phys., 23, 15165–15180, https://doi.org/10.5194/acp-23-15165-2023, https://doi.org/10.5194/acp-23-15165-2023, 2023
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The study presents the implementation of comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA. Simulations for contrasting urban environments of Asia and Europe highlight the significant impacts of chlorine on atmospheric oxidation capacity and composition. Chemical processes governing the production and loss of chlorine-containing species has been discussed. The updated chemical mechanism will be useful to interpret field measurements and for future air quality studies.
Ling Huang, Jiong Fang, Jiaqiang Liao, Greg Yarwood, Hui Chen, Yangjun Wang, and Li Li
Atmos. Chem. Phys., 23, 14919–14932, https://doi.org/10.5194/acp-23-14919-2023, https://doi.org/10.5194/acp-23-14919-2023, 2023
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Surface ozone concentrations have emerged as a major environmental issue in China. Although control strategies aimed at reducing NOx emissions from conventional combustion sources are widely recognized, soil NOx emissions have received little attention. The impact of soil NO emissions on ground-level ozone concentration is yet to be evaluated. In this study, we estimated the soil NO emissions and evaluated its impact on ozone formation in China.
Ben A. Cala, Scott Archer-Nicholls, James Weber, N. Luke Abraham, Paul T. Griffiths, Lorrie Jacob, Y. Matthew Shin, Laura E. Revell, Matthew Woodhouse, and Alexander T. Archibald
Atmos. Chem. Phys., 23, 14735–14760, https://doi.org/10.5194/acp-23-14735-2023, https://doi.org/10.5194/acp-23-14735-2023, 2023
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Dimethyl sulfide (DMS) is an important trace gas emitted from the ocean recognised as setting the sulfate aerosol background, but its oxidation is complex. As a result representation in chemistry-climate models is greatly simplified. We develop and compare a new mechanism to existing mechanisms via a series of global and box model experiments. Our studies show our updated DMS scheme is a significant improvement but significant variance exists between mechanisms.
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Short summary
Evaluation and uncertainty investigation of NO2, CO and NH3 modeling over China were conducted in this study using 14 chemical transport model results from MICS-Asia III. All models largely underestimated CO concentrations and showed very poor performance in reproducing the observed monthly variations of NH3 concentrations. Potential factors related to such deficiencies are investigated and discussed in this paper.
Evaluation and uncertainty investigation of NO2, CO and NH3 modeling over China were conducted...
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