Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1259-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-17-1259-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
27 Jan 2017
Research article |
| 27 Jan 2017
Direct observations of organic aerosols in common wintertime hazes in North China: insights into direct emissions from Chinese residential stoves
Shurui Chen
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Yinxiao Zhang
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Bing Chen
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Xinfeng Wang
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Xiaoye Zhang
Key Laboratory of Atmospheric Chemistry, Chinese Academy of
Meteorological Sciences, Beijing 100081, China
Mei Zheng
State Key Joint Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
Jianmin Chen
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and
Prevention, Department of Environmental Science and Engineering, Fudan
University, Shanghai 200433, China
Wenxing Wang
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
Pingqing Fu
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
Zifa Wang
State Key Laboratory of Atmospheric Boundary Layer Physics and
Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of
Sciences, Beijing 100029, China
Environment Research Institute, Shandong University, Jinan, Shandong
250100, China
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Ming Chu, Xing Wei, Shangfei Hai, Yang Gao, Huiwang Gao, Yujiao Zhu, Biwu Chu, Nan Ma, Juan Hong, Yele Sun, and Xiaohong Yao
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We used a 20-bin WRF-Chem model to simulate NPF events in the NCP during a three-week observational period in the summer of 2019. The model was able to reproduce the observations during June 29–July 6, which was characterized by a high frequency of NPF occurrence.
Xuan Wang, Lei Bi, Hong Wang, Yaqiang Wang, Wei Han, Xueshun Shen, and Xiaoye Zhang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-51, https://doi.org/10.5194/gmd-2024-51, 2024
Revised manuscript accepted for GMD
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An AI-based Nonspherical Aerosol Optical Scheme (AI-NAOS) was developed to improve the estimation of aerosol direct radiation effect (DRE). The AI-NAOS scheme considers BC as fractal aggregates and SD as super-spheroids, encapsulated with hygroscopic aerosols. The AI-NAOS scheme was coupled online with a chemical weather model. Real-case simulations emphasize the necessity of accurately representing nonpsherical and inhomogeneous aerosols in chemical weather models.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Hongyi Li, Ting Yang, Lars Nerger, Dawei Zhang, Di Zhang, Guigang Tang, Haibo Wang, Yele Sun, Pingqing Fu, Hang Su, and Zifa Wang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-78, https://doi.org/10.5194/gmd-2024-78, 2024
Revised manuscript accepted for GMD
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To accurately characterize the spatiotemporal distribution of PM2.5 chemical components, we developed a hybrid nonlinear data assimilation system (NAQPMS-PDAF v2.0), which is optimal for chemical components with non-Gaussian and nonlinear properties. NAQPMS-PDAF v2.0 has superior computing efficiency and excels when used a small ensemble size. The one-month assimilation experiments show that NAQPMS-PDAF v2.0 can significantly improve the simulation performance of chemical components.
Bin Luo, Yuqiang Zhang, Tao Tang, Hongliang Zhang, Jianlin Hu, Jiangshan Mu, Wenxing Wang, and Likun Xue
EGUsphere, https://doi.org/10.5194/egusphere-2024-974, https://doi.org/10.5194/egusphere-2024-974, 2024
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India is facing a severe air pollution crisis that poses significant health risks, particularly from PM2.5 and O3. Our study reveals rising levels of both pollutants from 1995 to 2014, leading to increased premature mortality. While anthropogenic emissions play a significant role, biomass burning also impacts air quality, in particular seasons and regions in India. This study highlights the urgent need for localized policies to protect public health amid escalating environmental challenges.
Zhiqiang Zhang, Ying Li, Haiyan Ran, Junling An, Yu Qu, Wei Zhou, Weiqi Xu, Weiwei Hu, Hongbin Xie, Zifa Wang, Yele Sun, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 4809–4826, https://doi.org/10.5194/acp-24-4809-2024, https://doi.org/10.5194/acp-24-4809-2024, 2024
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Secondary organic aerosols (SOAs) can exist in liquid, semi-solid, or amorphous solid states, which are rarely accounted for in current chemical transport models. We predict the phase state of SOA particles over China and find that in northwestern China SOA particles are mostly highly viscous or glassy solid. Our results indicate that the particle phase state should be considered in SOA formation in chemical transport models for more accurate prediction of SOA mass concentrations.
Chenliang Tao, Yanbo Peng, Qingzhu Zhang, Yuqiang Zhang, Bing Gong, Qiao Wang, and Wenxing Wang
Atmos. Chem. Phys., 24, 4177–4192, https://doi.org/10.5194/acp-24-4177-2024, https://doi.org/10.5194/acp-24-4177-2024, 2024
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We developed a novel transformer framework to bridge the sparse surface monitoring for inferring ozone–NOx–VOC–aerosol sensitivity and their urban–nonurban discrepancies at a finer scale with implications for improving our understanding of ozone variations. The change in urban–rural disparities in ozone was dominated by PM2.5 from 2019 to 2020. An aerosol-inhibited regime on top of the two traditional NOx- and VOC-limited regimes was identified in Jiaodong Peninsula, Shandong, China.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Jiawei Li, Zhiwei Han, Pingqing Fu, Xiaohong Yao, and Mingjie Liang
Atmos. Chem. Phys., 24, 3129–3161, https://doi.org/10.5194/acp-24-3129-2024, https://doi.org/10.5194/acp-24-3129-2024, 2024
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Organic aerosols of marine origin are important for aerosol climatic effects but are poorly understood. For the first time, an online coupled regional chemistry–climate model is applied to explore the characteristics of emission, distribution, and direct and indirect radiative effects of marine organic aerosols over the western Pacific, which reveals an important role of marine organic aerosols in perturbing cloud and radiation and promotes understanding of global aerosol climatic impact.
Xiao-San Luo, Weijie Huang, Guofeng Shen, Yuting Pang, Mingwei Tang, Weijun Li, Zhen Zhao, Hanhan Li, Yaqian Wei, Longjiao Xie, and Tariq Mehmood
Atmos. Chem. Phys., 24, 1345–1360, https://doi.org/10.5194/acp-24-1345-2024, https://doi.org/10.5194/acp-24-1345-2024, 2024
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PM2.5 are air pollutants threatening health globally, but they are a mixture of chemical compositions from many sources and result in unequal toxicity. Which composition from which source of PM2.5 as the most hazardous object is a question hindering effective pollution control policy-making. With chemical and toxicity experiments, we found automobile exhaust and coal combustion to be priority emissions with higher toxic compositions for precise air pollution control, ensuring public health.
Xinlei Ge, Yele Sun, Justin Trousdell, Mindong Chen, and Qi Zhang
Atmos. Meas. Tech., 17, 423–439, https://doi.org/10.5194/amt-17-423-2024, https://doi.org/10.5194/amt-17-423-2024, 2024
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This study aims to enhance the application of the Aerodyne high-resolution aerosol mass spectrometer (HR-AMS) in characterizing organic nitrogen (ON) species within aerosol particles and droplets. A thorough analysis was conducted on 75 ON standards that represent a diverse spectrum of ambient ON types. The results underscore the capacity of the HR-AMS in examining the concentration and chemistry of atmospheric ON compounds, thereby offering insights into their sources and environmental impacts.
Mutong Niu, Shu Huang, Wei Hu, Yajie Wang, Wanyun Xu, Wan Wei, Qiang Zhang, Zihan Wang, Donghuan Zhang, Rui Jin, Libin Wu, Junjun Deng, Fangxia Shen, and Pingqing Fu
Biogeosciences, 20, 4915–4930, https://doi.org/10.5194/bg-20-4915-2023, https://doi.org/10.5194/bg-20-4915-2023, 2023
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Sugar compounds in air can trace the source of bioaerosols that affect public health and climate. In rural north China, we observed increased fungal activity at night and less variable bacterial community diversity. Certain night-increasing sugar compounds were more closely related to fungi than bacteria. The fungal community greatly influenced sugar compounds, while bacteria played a limited role. Caution is advised when using sugar compounds to trace airborne microbes, particularly bacteria.
Lehui Cui, Yunting Xiao, Wei Hu, Lei Song, Yujue Wang, Chao Zhang, Pingqing Fu, and Jialei Zhu
Earth Syst. Sci. Data, 15, 5403–5425, https://doi.org/10.5194/essd-15-5403-2023, https://doi.org/10.5194/essd-15-5403-2023, 2023
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Isoprene is a crucial non-methane biogenic volatile organic compound with the largest global emissions, which has high chemical reactivity and serves as the primary source of natural secondary organic aerosols. This study built a module to present a 20-year global hourly dataset of marine phytoplankton-generated biological and photochemistry-generated isoprene emissions in the sea microlayers based on the latest advancements in biological, physical, and chemical processes.
Xuelian Zhong, Hengqing Shen, Min Zhao, Ji Zhang, Yue Sun, Yuhong Liu, Yingnan Zhang, Ye Shan, Hongyong Li, Jiangshan Mu, Yu Yang, Yanqiu Nie, Jinghao Tang, Can Dong, Xinfeng Wang, Yujiao Zhu, Mingzhi Guo, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 23, 14761–14778, https://doi.org/10.5194/acp-23-14761-2023, https://doi.org/10.5194/acp-23-14761-2023, 2023
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Nitrous acid (HONO) is vital for atmospheric oxidation. In research at Mount Lao, China, models revealed a significant unidentified marine HONO source. Overlooking this could skew our understanding of air quality and climate change. This finding emphasizes HONO’s importance in the coastal atmosphere, uncovering previously unnoticed interactions.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
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This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Wenxing Jia, Xiaoye Zhang, Hong Wang, Yaqiang Wang, Deying Wang, Junting Zhong, Wenjie Zhang, Lei Zhang, Lifeng Guo, Yadong Lei, Jizhi Wang, Yuanqin Yang, and Yi Lin
Geosci. Model Dev., 16, 6833–6856, https://doi.org/10.5194/gmd-16-6833-2023, https://doi.org/10.5194/gmd-16-6833-2023, 2023
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In addition to the dominant role of the PBL scheme on the results of the meteorological field, many factors in the model are influenced by large uncertainties. This study focuses on the uncertainties that influence numerical simulation results (including horizontal resolution, vertical resolution, near-surface scheme, initial and boundary conditions, underlying surface update, and update of model version), hoping to provide a reference for scholars conducting research on the model.
Wenxing Jia, Xiaoye Zhang, Hong Wang, Yaqiang Wang, Deying Wang, Junting Zhong, Wenjie Zhang, Lei Zhang, Lifeng Guo, Yadong Lei, Jizhi Wang, Yuanqin Yang, and Yi Lin
Geosci. Model Dev., 16, 6635–6670, https://doi.org/10.5194/gmd-16-6635-2023, https://doi.org/10.5194/gmd-16-6635-2023, 2023
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Most current studies on planetary boundary layer (PBL) parameterization schemes are relatively fragmented and lack systematic in-depth analysis and discussion. In this study, we comprehensively evaluate the performance capability of the PBL scheme in five typical regions of China in different seasons from the mechanism of the scheme and the effects of PBL schemes on the near-surface meteorological parameters, vertical structures of the PBL, PBL height, and turbulent diffusion.
Aodong Du, Jiaxing Sun, Hang Liu, Weiqi Xu, Wei Zhou, Yuting Zhang, Lei Li, Xubing Du, Yan Li, Xiaole Pan, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 23, 13597–13611, https://doi.org/10.5194/acp-23-13597-2023, https://doi.org/10.5194/acp-23-13597-2023, 2023
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We characterized the impacts of emission controls on particle mixing state and density during the Beijing Olympic Winter Games using a SPAMS in tandem with a DMA and an AAC. OC and sulfate-containing particles increased, while those from primary emissions decreased. The effective particle densities increased and varied largely for different particles, highlighting the impacts of aging and formation processes on the changes of particle density and mixing state.
Qianqian Gao, Shengqiang Zhu, Kaili Zhou, Jinghao Zhai, Shaodong Chen, Qihuang Wang, Shurong Wang, Jin Han, Xiaohui Lu, Hong Chen, Liwu Zhang, Lin Wang, Zimeng Wang, Xin Yang, Qi Ying, Hongliang Zhang, Jianmin Chen, and Xiaofei Wang
Atmos. Chem. Phys., 23, 13049–13060, https://doi.org/10.5194/acp-23-13049-2023, https://doi.org/10.5194/acp-23-13049-2023, 2023
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Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Dust aerosols are mainly generated by wind erosion, which may have some chemical selectivity. Mn, Cd and Pb were found to be highly enriched in fine-dust (PM2.5) aerosols. In addition, estimation of heavy metal emissions from dust generation by air quality models may have errors without using proper dust profiles.
Tao Wang, Hang Liu, Jie Li, Shuai Wang, Youngseob Kim, Yele Sun, Wenyi Yang, Huiyun Du, Zhe Wang, and Zifa Wang
Geosci. Model Dev., 16, 5585–5599, https://doi.org/10.5194/gmd-16-5585-2023, https://doi.org/10.5194/gmd-16-5585-2023, 2023
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This paper developed a two-way coupled module in a new version of a regional urban–street network model, IAQMS-street v2.0, in which the mass flux from streets to background is considered. Test cases are defined to evaluate the performance of IAQMS-street v2.0 in Beijing by comparing it with that simulated by IAQMS-street v1.0 and a regional model. The contribution of local emissions and the influence of on-road vehicle control measures on air quality are evaluated by using IAQMS-street v2.0.
Li Wu, Hyo-Jin Eom, Hanjin Yoo, Dhrubajyoti Gupta, Hye-Rin Cho, Pingqing Fu, and Chul-Un Ro
Atmos. Chem. Phys., 23, 12571–12588, https://doi.org/10.5194/acp-23-12571-2023, https://doi.org/10.5194/acp-23-12571-2023, 2023
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Hygroscopicity of ambient marine aerosols is of critical relevance to investigate their atmospheric impacts, which, however, remain uncertain due to their complex compositions and mixing states. Therefore, a study on the hygroscopic behavior of ambient marine aerosols for understanding the phase states when interacting with water vapor at different RH levels and their subsequent impacts on the heterogeneous chemical reactions, atmospheric environment, and human health is of vital importance.
Xi Chen, Ting Yang, Zifa Wang, Futing Wang, and Haibo Wang
Atmos. Meas. Tech., 16, 4289–4302, https://doi.org/10.5194/amt-16-4289-2023, https://doi.org/10.5194/amt-16-4289-2023, 2023
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Uncertainties remain great in the planetary boundary layer height (PBLH) determination from radiosonde, especially during the transition period of different PBL regimes. We combine seven existing methods along with statistical modification on gradient-based methods. We find that the ensemble method can eliminate the overestimation of PBLH and reduce the inconsistency between individual methods. The ensemble method improves the effectiveness of PBLH determination to 62.6 %.
Yong Zhang, Jie Tian, Qiyuan Wang, Lu Qi, Manousos Ioannis Manousakas, Yuemei Han, Weikang Ran, Yele Sun, Huikun Liu, Renjian Zhang, Yunfei Wu, Tianqu Cui, Kaspar Rudolf Daellenbach, Jay Gates Slowik, André S. H. Prévôt, and Junji Cao
Atmos. Chem. Phys., 23, 9455–9471, https://doi.org/10.5194/acp-23-9455-2023, https://doi.org/10.5194/acp-23-9455-2023, 2023
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PM2.5 pollution still frequently occurs in northern China during winter, and it is necessary to figure out the causes of air pollution based on intensive real-time measurement. The findings elaborate the chemical characteristics and source contributions of PM2.5 in three pilot cities, reveal potential formation mechanisms of secondary aerosols, and highlight the importance of controlling biomass burning and inhibiting generation of secondary aerosol for air quality improvement.
Qi Yuan, Yuanyuan Wang, Yixin Chen, Siyao Yue, Jian Zhang, Yinxiao Zhang, Liang Xu, Wei Hu, Dantong Liu, Pingqing Fu, Huiwang Gao, and Weijun Li
Atmos. Chem. Phys., 23, 9385–9399, https://doi.org/10.5194/acp-23-9385-2023, https://doi.org/10.5194/acp-23-9385-2023, 2023
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This study for the first time found large amounts of liquid–liquid phase separation particles with soot redistributing in organic coatings instead of sulfate cores in the eastern Tibetan Plateau atmosphere. The particle size and the ratio of the organic matter coating thickness to soot size are two of the major possible factors that likely affect the soot redistribution process. The soot redistribution process promoted the morphological compaction of soot particles.
Dandan Liu, Yun Zhang, Shujun Zhong, Shuang Chen, Qiaorong Xie, Donghuan Zhang, Qiang Zhang, Wei Hu, Junjun Deng, Libin Wu, Chao Ma, Haijie Tong, and Pingqing Fu
Atmos. Chem. Phys., 23, 8383–8402, https://doi.org/10.5194/acp-23-8383-2023, https://doi.org/10.5194/acp-23-8383-2023, 2023
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Based on ultra-high-resolution mass spectrometry analysis, we found that β-pinene oxidation-derived highly oxygenated organic molecules (HOMs) exhibit higher yield at high ozone concentration, while limonene oxidation-derived HOMs exhibit higher yield at moderate ozone concentration. The distinct molecular response of HOMs and low-volatile species in different biogenic secondary organic aerosols to ozone concentrations provides a new clue for more accurate air quality prediction and management.
Yue Peng, Hong Wang, Xiaoye Zhang, Zhaodong Liu, Wenjie Zhang, Siting Li, Chen Han, and Huizheng Che
Atmos. Chem. Phys., 23, 8325–8339, https://doi.org/10.5194/acp-23-8325-2023, https://doi.org/10.5194/acp-23-8325-2023, 2023
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This study demonstrates a strong link between local circulation, aerosol–radiation interaction (ARI), and haze pollution. Under the weak weather-scale systems, the typical local circulation driven by mountainous topography is the main cause of pollutant distribution in the Beijing–Tianjin–Hebei region, and the ARI mechanism amplifies this influence of local circulation on pollutants, making haze pollution aggravated by the superposition of both.
Siting Li, Ping Wang, Hong Wang, Yue Peng, Zhaodong Liu, Wenjie Zhang, Hongli Liu, Yaqiang Wang, Huizheng Che, and Xiaoye Zhang
Geosci. Model Dev., 16, 4171–4191, https://doi.org/10.5194/gmd-16-4171-2023, https://doi.org/10.5194/gmd-16-4171-2023, 2023
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Optimizing the initial state of atmospheric chemistry model input is one of the most essential methods to improve forecast accuracy. Considering the large computational load of the model, we introduce an ensemble optimal interpolation scheme (EnOI) for operational use and efficient updating of the initial fields of chemical components. The results suggest that EnOI provides a practical and cost-effective technique for improving the accuracy of chemical weather numerical forecasts.
Xiaojing Shen, Junying Sun, Huizheng Che, Yangmei Zhang, Chunhong Zhou, Ke Gui, Wanyun Xu, Quan Liu, Junting Zhong, Can Xia, Xinyao Hu, Sinan Zhang, Jialing Wang, Shuo Liu, Jiayuan Lu, Aoyuan Yu, and Xiaoye Zhang
Atmos. Chem. Phys., 23, 8241–8257, https://doi.org/10.5194/acp-23-8241-2023, https://doi.org/10.5194/acp-23-8241-2023, 2023
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New particle formation (NPF) events occur when the dust episodes' fade is analysed based on long-term measurement of particle number size distribution. Analysis shows that the observed formation and growth rates are approximately 50 % of and 30 % lower than those of other NPF events. As a consequence of the uptake of precursor gases on mineral dust, the physical and chemical properties of submicron particles, as well as the ability to be cloud condensation nuclei, can be changed.
Jianyan Lu, Sunling Gong, Jian Zhang, Jianmin Chen, Lei Zhang, and Chunhong Zhou
Atmos. Chem. Phys., 23, 8021–8037, https://doi.org/10.5194/acp-23-8021-2023, https://doi.org/10.5194/acp-23-8021-2023, 2023
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WRF/CUACE was used to assess the cloud chemistry contribution in China. Firstly, the CUACE cloud chemistry scheme was found to reproduce well the cloud processing and consumption of H2O2, O3, and SO2, as well as the increase of sulfate. Secondly, during cloud availability in December under a heavy pollution episode, sulfate production increased 60–95 % and SO2 was reduced by over 80 %. This study provides a way to analyze the phenomenon of overestimation of SO2 in many chemical transport models.
Lichao Yang, Wansuo Duan, and Zifa Wang
Geosci. Model Dev., 16, 3827–3848, https://doi.org/10.5194/gmd-16-3827-2023, https://doi.org/10.5194/gmd-16-3827-2023, 2023
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An approach is proposed to refine a ground meteorological observation network to improve the PM2.5 forecasts in the Beijing–Tianjin–Hebei region. A cost-effective observation network is obtained and makes the relevant PM2.5 forecasts assimilate fewer observations but achieve the forecasting skill comparable to or higher than that obtained by assimilating all ground station observations, suggesting that many of the current ground stations can be greatly scattered to avoid much unnecessary work.
Hang Liu, Xiaole Pan, Shandong Lei, Yuting Zhang, Aodong Du, Weijie Yao, Guiqian Tang, Tao Wang, Jinyuan Xin, Jie Li, Yele Sun, Junji Cao, and Zifa Wang
Atmos. Chem. Phys., 23, 7225–7239, https://doi.org/10.5194/acp-23-7225-2023, https://doi.org/10.5194/acp-23-7225-2023, 2023
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We provide the average vertical profiles of black carbon (BC) concentration, size distribution and coating thickness at different times of the day in an urban area based on 112 vertical profiles. In addition, it is found that BC in the residual layer generally has a thicker coating, higher absorption enhancement and hygroscopicity than on the surface. Such aged BC could enter into the boundary layer and influence the BC properties in the early morning.
Wen Lu, Bin Zhu, Shuqi Yan, Jie Li, and Zifa Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-1089, https://doi.org/10.5194/egusphere-2023-1089, 2023
Preprint archived
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Parameterized the minimum turbulent diffusivity (Kzmin) by sensible heat flux and latent heat flux and embedded it into the WRF-Chem model. New scheme improved the underestimation of turbulence diffusion underestimation and overestimation of surface PM2.5 under stable boundary layer simulation over eastern China. The physical relationship between Kzmin and two factors was discussed. Process analysis showed that vertical mixing is the key process to improve surface PM2.5 simulations.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Yele Sun, Pingqing Fu, Meng Gao, Huangjian Wu, Miaomiao Lu, Qian Wu, Shuyuan Huang, Wenxuan Sui, Jie Li, Xiaole Pan, Lin Wu, Hajime Akimoto, and Gregory R. Carmichael
Atmos. Chem. Phys., 23, 6217–6240, https://doi.org/10.5194/acp-23-6217-2023, https://doi.org/10.5194/acp-23-6217-2023, 2023
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A multi-air-pollutant inversion system has been developed in this study to estimate emission changes in China during COVID-19 lockdown. The results demonstrate that the lockdown is largely a nationwide road traffic control measure with NOx emissions decreasing by ~40 %. Emissions of other species only decreased by ~10 % due to smaller effects of lockdown on other sectors. Assessment results further indicate that the lockdown only had limited effects on the control of PM2.5 and O3 in China.
Joanna E. Dyson, Lisa K. Whalley, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Stephen D. Worrall, Asan Bacak, Archit Mehra, Thomas J. Bannan, Hugh Coe, Carl J. Percival, Bin Ouyang, C. Nicholas Hewitt, Roderic L. Jones, Leigh R. Crilley, Louisa J. Kramer, W. Joe F. Acton, William J. Bloss, Supattarachai Saksakulkrai, Jingsha Xu, Zongbo Shi, Roy M. Harrison, Simone Kotthaus, Sue Grimmond, Yele Sun, Weiqi Xu, Siyao Yue, Lianfang Wei, Pingqing Fu, Xinming Wang, Stephen R. Arnold, and Dwayne E. Heard
Atmos. Chem. Phys., 23, 5679–5697, https://doi.org/10.5194/acp-23-5679-2023, https://doi.org/10.5194/acp-23-5679-2023, 2023
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The hydroxyl (OH) and closely coupled hydroperoxyl (HO2) radicals are vital for their role in the removal of atmospheric pollutants. In less polluted regions, atmospheric models over-predict HO2 concentrations. In this modelling study, the impact of heterogeneous uptake of HO2 onto aerosol surfaces on radical concentrations and the ozone production regime in Beijing in the summertime is investigated, and the implications for emissions policies across China are considered.
Xinyao Hu, Junying Sun, Can Xia, Xiaojing Shen, Yangmei Zhang, Quan Liu, Zhaodong Liu, Sinan Zhang, Jialing Wang, Aoyuan Yu, Jiayuan Lu, Shuo Liu, and Xiaoye Zhang
Atmos. Chem. Phys., 23, 5517–5531, https://doi.org/10.5194/acp-23-5517-2023, https://doi.org/10.5194/acp-23-5517-2023, 2023
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The simultaneous measurements under dry conditions of aerosol optical properties were conducted at three wavelengths for PM1 and PM10 in urban Beijing from 2018 to 2021. Considerable reductions in aerosol absorption coefficient and increased single scattering albedo demonstrated that absorbing aerosols were more effectively controlled than scattering aerosols due to pollution control measures. The aerosol radiative effect and the transport's impact on aerosol optical properties were analysed.
Junhua Wang, Baozhu Ge, Xueshun Chen, Jie Li, Keding Lu, Yayuan Dong, Lei Kong, Zifa Wang, and Yuanhang Zhang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-22, https://doi.org/10.5194/gmd-2023-22, 2023
Revised manuscript not accepted
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We developed a quantitative decoupling analysis (QDA) method to quantify the contributions of emissions, meteorology, chemical reactions, and their nonlinear interactions on PM2.5. We found the effects of adverse meteorological conditions and the importance of nonlinear interactions. This method can provide valuable information for understanding of key factors to heavy pollution, but also help the modelers to find out the sources of uncertainties in numerical models.
Jinlong Ma, Shengqiang Zhu, Siyu Wang, Peng Wang, Jianmin Chen, and Hongliang Zhang
Atmos. Chem. Phys., 23, 4311–4325, https://doi.org/10.5194/acp-23-4311-2023, https://doi.org/10.5194/acp-23-4311-2023, 2023
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An updated version of the CMAQ model with biogenic volatile organic compound (BVOC) emissions from MEGAN was applied to study the impacts of different land cover inputs on O3 and secondary organic aerosol (SOA) in China. The estimated BVOC emissions ranged from 25.42 to 37.39 Tg using different leaf area index (LAI) and land cover (LC) inputs. Those differences further induced differences of 4.8–6.9 ppb in O3 concentrations and differences of 5.3–8.4 µg m−3 in SOA concentrations in China.
Shixian Zhai, Daniel J. Jacob, Drew C. Pendergrass, Nadia K. Colombi, Viral Shah, Laura Hyesung Yang, Qiang Zhang, Shuxiao Wang, Hwajin Kim, Yele Sun, Jin-Soo Choi, Jin-Soo Park, Gan Luo, Fangqun Yu, Jung-Hun Woo, Younha Kim, Jack E. Dibb, Taehyoung Lee, Jin-Seok Han, Bruce E. Anderson, Ke Li, and Hong Liao
Atmos. Chem. Phys., 23, 4271–4281, https://doi.org/10.5194/acp-23-4271-2023, https://doi.org/10.5194/acp-23-4271-2023, 2023
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Anthropogenic fugitive dust in East Asia not only causes severe coarse particulate matter air pollution problems, but also affects fine particulate nitrate. Due to emission control efforts, coarse PM decreased steadily. We find that the decrease of coarse PM is a major driver for a lack of decrease of fine particulate nitrate, as it allows more nitric acid to form fine particulate nitrate. The continuing decrease of coarse PM requires more stringent ammonia and nitrogen oxides emission controls.
Yiqun Lu, Yingge Ma, Dan Dan Huang, Shengrong Lou, Sheng'ao Jing, Yaqin Gao, Hongli Wang, Yanjun Zhang, Hui Chen, Yunhua Chang, Naiqiang Yan, Jianmin Chen, Christian George, Matthieu Riva, and Cheng Huang
Atmos. Chem. Phys., 23, 3233–3245, https://doi.org/10.5194/acp-23-3233-2023, https://doi.org/10.5194/acp-23-3233-2023, 2023
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N-containing oxygenated organic molecules have been identified as important precursors of aerosol particles. We used an ultra-high-resolution mass spectrometer coupled with an online sample inlet to accurately measure their molecular composition, concentration level and variation patterns. We show their formation process and influencing factors in a Chinese megacity involving various volatile organic compound precursors and atmospheric oxidants, and we highlight the influence of PM2.5 episodes.
Yu Han, Tao Wang, Rui Li, Hongbo Fu, Yusen Duan, Song Gao, Liwu Zhang, and Jianmin Chen
Atmos. Chem. Phys., 23, 2877–2900, https://doi.org/10.5194/acp-23-2877-2023, https://doi.org/10.5194/acp-23-2877-2023, 2023
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Limited knowledge is available on volatile organic compound (VOC) multi-site research of different land-use types at city level. This study performed a concurrent multi-site observation campaign on the three typical land-use types of Shanghai, East China. The results showed that concentrations, sources and ozone and secondary organic aerosol formation potentials of VOCs varied with the land-use types.
Yingfang Li, Zhili Wang, Yadong Lei, Huizheng Che, and Xiaoye Zhang
Atmos. Chem. Phys., 23, 2499–2523, https://doi.org/10.5194/acp-23-2499-2023, https://doi.org/10.5194/acp-23-2499-2023, 2023
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Since few studies have assessed the impacts of future combined reductions in aerosols, ozone, and their precursors on future climate change, we use models with an interactive representation of tropospheric aerosols and atmospheric chemistry schemes to quantify the impact of their reductions on the Asian climate. Our results suggest that their reductions will exacerbate the warming effect caused by greenhouse gases, increasing future climate extremes and associated population exposure risk.
Zhichao Dong, Chandra Mouli Pavuluri, Zhanjie Xu, Yu Wang, Peisen Li, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 23, 2119–2143, https://doi.org/10.5194/acp-23-2119-2023, https://doi.org/10.5194/acp-23-2119-2023, 2023
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This study has provided comprehensive baseline data of carbonaceous and inorganic aerosols as well as their isotope ratios in the Tianjin region, North China, found that Tianjin aerosols were derived from coal combustion, biomass burning and photochemical reactions of VOCs, and also implied that the Tianjin aerosols were more aged during long-range atmospheric transport in summer via carbonaceous and isotope data analysis.
Shujun Zhong, Shuang Chen, Junjun Deng, Yanbing Fan, Qiang Zhang, Qiaorong Xie, Yulin Qi, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Jialei Zhu, Xin Wang, Di Liu, Xiaole Pan, Yele Sun, Zifa Wang, Yisheng Xu, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 2061–2077, https://doi.org/10.5194/acp-23-2061-2023, https://doi.org/10.5194/acp-23-2061-2023, 2023
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This study investigated the role of the secondary organic aerosol (SOA) loading on the molecular composition of wintertime urban aerosols by ultrahigh-resolution mass spectrometry. Results demonstrate that the SOA loading is an important factor associated with the oxidation degree, nitrate group content, and chemodiversity of nitrooxy–organosulfates. Our study also found that the hydrolysis of nitrooxy–organosulfates is a possible pathway for the formation of organosulfates.
Wenjie Zhang, Hong Wang, Xiaoye Zhang, Liping Huang, Yue Peng, Zhaodong Liu, Xiao Zhang, and Huizheng Che
Atmos. Chem. Phys., 22, 15207–15221, https://doi.org/10.5194/acp-22-15207-2022, https://doi.org/10.5194/acp-22-15207-2022, 2022
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Aerosol–cloud interaction (ACI) is first implemented in the atmospheric chemistry system GRAPES_Meso5.1/CUACE. ACI can improve the simulated cloud, temperature, and precipitation under haze pollution conditions in Jing-Jin-Ji in China. This paper demonstrates the critical role of ACI in current numerical weather prediction over the severely polluted region.
Yuying Wang, Rong Hu, Qiuyan Wang, Zhanqing Li, Maureen Cribb, Yele Sun, Xiaorui Song, Yi Shang, Yixuan Wu, Xin Huang, and Yuxiang Wang
Atmos. Chem. Phys., 22, 14133–14146, https://doi.org/10.5194/acp-22-14133-2022, https://doi.org/10.5194/acp-22-14133-2022, 2022
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The mixing state of size-resolved soot particles and their influencing factors were investigated. The results suggest anthropogenic emissions and aging processes have diverse impacts on the mixing state of soot particles in different modes. Considering that the mixing state of soot particles is crucial to model aerosol absorption, this finding is important to study particle growth and the warming effect of black carbon aerosols.
Xiaoying Niu, Wei Pu, Pingqing Fu, Yang Chen, Yuxuan Xing, Dongyou Wu, Ziqi Chen, Tenglong Shi, Yue Zhou, Hui Wen, and Xin Wang
Atmos. Chem. Phys., 22, 14075–14094, https://doi.org/10.5194/acp-22-14075-2022, https://doi.org/10.5194/acp-22-14075-2022, 2022
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In this study, we do the first investigation of WSOC in seasonal snow of northeastern China. The results revealed the regional-specific compositions and sources of WSOC due to different natural environments and anthropogenic activities. The abundant concentrations of WSOC and its absorption properties contributed to a crucial impact on the snow albedo and radiative effect. We established that our study could raise awareness of carbon cycling processes, hydrological processes, and climate change.
Jian-yan Lu, Sunling Gong, Chun-hong Zhou, Jian Zhang, Jian-min Chen, and Lei Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-716, https://doi.org/10.5194/acp-2022-716, 2022
Revised manuscript not accepted
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A regional online chemical weather model WRF/ CUACE was used to assess the contributions of cloud chemistry to the SO2 and sulfate levels in typical regions in China. The cloud chemistry scheme in CUACE was evaluated, and well reproduces the cloud chemistry processes. During cloud availability in a heavy pollution episode, the sulfate production increases 40–80 % and SO2 reduces over 80 %. This study provides a way to analyze the over-estimate phenomenon of SO2 in many chemical transport models.
Futing Wang, Ting Yang, Zifa Wang, Haibo Wang, Xi Chen, Yele Sun, Jianjun Li, Guigang Tang, and Wenxuan Chai
Atmos. Meas. Tech., 15, 6127–6144, https://doi.org/10.5194/amt-15-6127-2022, https://doi.org/10.5194/amt-15-6127-2022, 2022
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We develop a new algorithm to get the vertical mass concentration profiles of fine aerosol components based on the synergy of ground-based remote sensing for the first time. The comparisons with in situ observations and chemistry transport models validate the performance of the algorithm. Uncertainties caused by input parameters are also assessed in this paper. We expected that the algorithm can provide a new idea for lidar inversion and promote the development of aerosol component profiles.
Tao Wang, Yangyang Liu, Hanyun Cheng, Zhenzhen Wang, Hongbo Fu, Jianmin Chen, and Liwu Zhang
Atmos. Chem. Phys., 22, 13467–13493, https://doi.org/10.5194/acp-22-13467-2022, https://doi.org/10.5194/acp-22-13467-2022, 2022
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This study compared the gas-phase, aqueous-phase, and heterogeneous SO2 oxidation pathways by combining laboratory work with a modelling study. The heterogeneous oxidation, particularly that induced by the dust surface drivers, presents positive implications for the removal of airborne SO2 and formation of sulfate aerosols. This work highlighted the atmospheric significance of heterogeneous oxidation and suggested a comparison model to evaluate the following heterogeneous laboratory research.
Chao Yan, Yicheng Shen, Dominik Stolzenburg, Lubna Dada, Ximeng Qi, Simo Hakala, Anu-Maija Sundström, Yishuo Guo, Antti Lipponen, Tom V. Kokkonen, Jenni Kontkanen, Runlong Cai, Jing Cai, Tommy Chan, Liangduo Chen, Biwu Chu, Chenjuan Deng, Wei Du, Xiaolong Fan, Xu-Cheng He, Juha Kangasluoma, Joni Kujansuu, Mona Kurppa, Chang Li, Yiran Li, Zhuohui Lin, Yiliang Liu, Yuliang Liu, Yiqun Lu, Wei Nie, Jouni Pulliainen, Xiaohui Qiao, Yonghong Wang, Yifan Wen, Ye Wu, Gan Yang, Lei Yao, Rujing Yin, Gen Zhang, Shaojun Zhang, Feixue Zheng, Ying Zhou, Antti Arola, Johanna Tamminen, Pauli Paasonen, Yele Sun, Lin Wang, Neil M. Donahue, Yongchun Liu, Federico Bianchi, Kaspar R. Daellenbach, Douglas R. Worsnop, Veli-Matti Kerminen, Tuukka Petäjä, Aijun Ding, Jingkun Jiang, and Markku Kulmala
Atmos. Chem. Phys., 22, 12207–12220, https://doi.org/10.5194/acp-22-12207-2022, https://doi.org/10.5194/acp-22-12207-2022, 2022
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Atmospheric new particle formation (NPF) is a dominant source of atmospheric ultrafine particles. In urban environments, traffic emissions are a major source of primary pollutants, but their contribution to NPF remains under debate. During the COVID-19 lockdown, traffic emissions were significantly reduced, providing a unique chance to examine their relevance to NPF. Based on our comprehensive measurements, we demonstrate that traffic emissions alone are not able to explain the NPF in Beijing.
Mengying Li, Shaocai Yu, Xue Chen, Zhen Li, Yibo Zhang, Zhe Song, Weiping Liu, Pengfei Li, Xiaoye Zhang, Meigen Zhang, Yele Sun, Zirui Liu, Caiping Sun, Jingkun Jiang, Shuxiao Wang, Benjamin N. Murphy, Kiran Alapaty, Rohit Mathur, Daniel Rosenfeld, and John H. Seinfeld
Atmos. Chem. Phys., 22, 11845–11866, https://doi.org/10.5194/acp-22-11845-2022, https://doi.org/10.5194/acp-22-11845-2022, 2022
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This study constructed an emission inventory of condensable particulate matter (CPM) in China with a focus on organic aerosols (OAs), based on collected CPM emission information. The results show that OA emissions are enhanced twofold for the years 2014 and 2017 after the inclusion of CPM in the new inventory. Sensitivity cases demonstrated the significant contributions of CPM emissions from stationary combustion and mobile sources to primary, secondary, and total OA concentrations.
Lichao Yang, Wansuo Duan, Zifa Wang, and Wenyi Yang
Atmos. Chem. Phys., 22, 11429–11453, https://doi.org/10.5194/acp-22-11429-2022, https://doi.org/10.5194/acp-22-11429-2022, 2022
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The initial meteorological state has a great impact on PM2.5 forecasts. Assimilating additional observations is an effective way to improve the accuracy of the initial meteorological state. Here we used an advanced optimization approach to identify where we should preferentially place the meteorological observations associated with PM2.5 forecasts in the Beijing–Tianjin–Hebei region of China. We provide evidence that the target observation strategy is effective for improving PM2.5 forecasts.
Zhiqiang Zhang, Yele Sun, Chun Chen, Bo You, Aodong Du, Weiqi Xu, Yan Li, Zhijie Li, Lu Lei, Wei Zhou, Jiaxing Sun, Yanmei Qiu, Lianfang Wei, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 22, 10409–10423, https://doi.org/10.5194/acp-22-10409-2022, https://doi.org/10.5194/acp-22-10409-2022, 2022
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We present a comprehensive characterization of water-soluble organic aerosol and the first mass spectral characterization of water-insoluble organic aerosol in the cold season in Beijing by integrating online and offline aerosol mass spectrometer measurements. WSOA comprised dominantly secondary OA and showed large changes during the transition season from autumn to winter. WIOA was characterized by prominent hydrocarbon ions series, low oxidation states, and significant day–night differences.
Lei Li, Yevgeny Derimian, Cheng Chen, Xindan Zhang, Huizheng Che, Gregory L. Schuster, David Fuertes, Pavel Litvinov, Tatyana Lapyonok, Anton Lopatin, Christian Matar, Fabrice Ducos, Yana Karol, Benjamin Torres, Ke Gui, Yu Zheng, Yuanxin Liang, Yadong Lei, Jibiao Zhu, Lei Zhang, Junting Zhong, Xiaoye Zhang, and Oleg Dubovik
Earth Syst. Sci. Data, 14, 3439–3469, https://doi.org/10.5194/essd-14-3439-2022, https://doi.org/10.5194/essd-14-3439-2022, 2022
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A climatology of aerosol composition concentration derived from POLDER-3 observations using GRASP/Component is presented. The conceptual specifics of the GRASP/Component approach are in the direct retrieval of aerosol speciation without intermediate retrievals of aerosol optical characteristics. The dataset of satellite-derived components represents scarce but imperative information for validation and potential adjustment of chemical transport models.
Junting Zhong, Xiaoye Zhang, Ke Gui, Jie Liao, Ye Fei, Lipeng Jiang, Lifeng Guo, Liangke Liu, Huizheng Che, Yaqiang Wang, Deying Wang, and Zijiang Zhou
Earth Syst. Sci. Data, 14, 3197–3211, https://doi.org/10.5194/essd-14-3197-2022, https://doi.org/10.5194/essd-14-3197-2022, 2022
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Historical long-term PM2.5 records with high temporal resolution are essential but lacking for research and environmental management. Here, we reconstruct site-based and gridded PM2.5 datasets at 6-hour intervals from 1960 to 2020 that combine visibility, meteorological data, and emissions based on a machine learning model with extracted spatial features. These two PM2.5 datasets will lay the foundation of research studies associated with air pollution, climate change, and aerosol reanalysis.
Haochi Che, Michal Segal-Rozenhaimer, Lu Zhang, Caroline Dang, Paquita Zuidema, Arthur J. Sedlacek III, Xiaoye Zhang, and Connor Flynn
Atmos. Chem. Phys., 22, 8767–8785, https://doi.org/10.5194/acp-22-8767-2022, https://doi.org/10.5194/acp-22-8767-2022, 2022
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A 17-month in situ study on Ascension Island found low single-scattering albedo and strong absorption enhancement of the marine boundary layer aerosols during biomass burnings on the African continent, along with apparent patterns of regular monthly variability. We further discuss the characteristics and drivers behind these changes and find that biomass burning conditions in Africa may be the main factor influencing the optical properties of marine boundary aerosols.
Ke Gui, Wenrui Yao, Huizheng Che, Linchang An, Yu Zheng, Lei Li, Hujia Zhao, Lei Zhang, Junting Zhong, Yaqiang Wang, and Xiaoye Zhang
Atmos. Chem. Phys., 22, 7905–7932, https://doi.org/10.5194/acp-22-7905-2022, https://doi.org/10.5194/acp-22-7905-2022, 2022
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This study investigates the aerosol optical and radiative properties and meteorological drivers during two mega SDS events over Northern China in March 2021. The MODIS-retrieved DOD data registered these two events as the most intense episode in the same period in history over the past 20 years. These two extreme SDS events were associated with both atmospheric circulation extremes and local meteorological anomalies that favor enhanced dust emissions in the Gobi Desert.
Jiaxing Sun, Yele Sun, Conghui Xie, Weiqi Xu, Chun Chen, Zhe Wang, Lei Li, Xubing Du, Fugui Huang, Yan Li, Zhijie Li, Xiaole Pan, Nan Ma, Wanyun Xu, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 22, 7619–7630, https://doi.org/10.5194/acp-22-7619-2022, https://doi.org/10.5194/acp-22-7619-2022, 2022
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We analyzed the chemical composition and mixing state of BC-containing particles at urban and rural sites in winter in the North China Plain and evaluated their impact on light absorption enhancement. BC was dominantly mixed with organic carbon, nitrate, and sulfate, and the mixing state evolved significantly as a function of relative humidity (RH) at both sites. The absorption enhancement depended strongly on coated secondary inorganic aerosol and was up to ~1.3–1.4 during aging processes.
Junjun Deng, Hao Ma, Xinfeng Wang, Shujun Zhong, Zhimin Zhang, Jialei Zhu, Yanbing Fan, Wei Hu, Libin Wu, Xiaodong Li, Lujie Ren, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 22, 6449–6470, https://doi.org/10.5194/acp-22-6449-2022, https://doi.org/10.5194/acp-22-6449-2022, 2022
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Light-absorbing brown carbon (BrC) plays an important role in climate change and atmospheric chemistry. Here we investigated the seasonal and diurnal variations in water-soluble BrC in PM2.5 in the megacity Tianjin in coastal China. Results of the source apportionments from the combination with organic molecular compositions and optical properties of water-soluble BrC reveal a large contribution from primary bioaerosol particles to BrC in the urban atmosphere.
Clarissa Baldo, Akinori Ito, Michael D. Krom, Weijun Li, Tim Jones, Nick Drake, Konstantin Ignatyev, Nicholas Davidson, and Zongbo Shi
Atmos. Chem. Phys., 22, 6045–6066, https://doi.org/10.5194/acp-22-6045-2022, https://doi.org/10.5194/acp-22-6045-2022, 2022
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High ionic strength relevant to the aerosol-water enhanced proton-promoted dissolution of iron in coal fly ash (up to 7 times) but suppressed oxalate-promoted dissolution at low pH (< 3). Fe in coal fly ash dissolved up to 7 times faster than in Saharan dust at low pH. A global model with the updated dissolution rates of iron in coal fly ash suggested a larger contribution of pyrogenic dissolved Fe over regions with a strong impact from fossil fuel combustions.
Haibo Wang, Ting Yang, Zifa Wang, Jianjun Li, Wenxuan Chai, Guigang Tang, Lei Kong, and Xueshun Chen
Geosci. Model Dev., 15, 3555–3585, https://doi.org/10.5194/gmd-15-3555-2022, https://doi.org/10.5194/gmd-15-3555-2022, 2022
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In this paper, we develop an online data coupled assimilation system (NAQPMS-PDAF) with the Eulerian atmospheric chemistry-transport model. NAQPMS-PDAF allows efficient use of large computational resources. The application and performance of the system are investigated by assimilating 1 month of vertical aerosol observations. The results show that NAQPMS-PDAF can significantly improve the performance of aerosol vertical structure simulation and reduce the uncertainty to a large extent.
Yu Zheng, Huizheng Che, Yupeng Wang, Xiangao Xia, Xiuqing Hu, Xiaochun Zhang, Jun Zhu, Jibiao Zhu, Hujia Zhao, Lei Li, Ke Gui, and Xiaoye Zhang
Atmos. Meas. Tech., 15, 2139–2158, https://doi.org/10.5194/amt-15-2139-2022, https://doi.org/10.5194/amt-15-2139-2022, 2022
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Ground-based observations of aerosols and aerosol data verification is important for satellite and climate model modification. Here we present an evaluation of aerosol microphysical, optical and radiative properties measured using a multiwavelength photometer with a highly integrated design and smart control performance. The validation of this product is discussed in detail using AERONET as a reference. This work contributes to reducing AOD uncertainties in China and combating climate change.
Jingnan Shi, Juan Hong, Nan Ma, Qingwei Luo, Yao He, Hanbing Xu, Haobo Tan, Qiaoqiao Wang, Jiangchuan Tao, Yaqing Zhou, Shuang Han, Long Peng, Linhong Xie, Guangsheng Zhou, Wanyun Xu, Yele Sun, Yafang Cheng, and Hang Su
Atmos. Chem. Phys., 22, 4599–4613, https://doi.org/10.5194/acp-22-4599-2022, https://doi.org/10.5194/acp-22-4599-2022, 2022
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In this study, we investigated the hygroscopicity of submicron aerosols at a rural site in the North China Plain during the winter of 2018, using a HTDMA and a CV-ToF-ACSM. We observed differences in aerosol hygroscopicity during two distinct episodes with different primary emissions and secondary aerosol formation processes. These results provide an improved understanding of the complex influence of sources and aerosol evolution processes on their hygroscopicity.
Chaoyang Xue, Can Ye, Jörg Kleffmann, Chenglong Zhang, Valéry Catoire, Fengxia Bao, Abdelwahid Mellouki, Likun Xue, Jianmin Chen, Keding Lu, Yong Zhao, Hengde Liu, Zhaoxin Guo, and Yujing Mu
Atmos. Chem. Phys., 22, 3149–3167, https://doi.org/10.5194/acp-22-3149-2022, https://doi.org/10.5194/acp-22-3149-2022, 2022
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Summertime measurements of nitrous acid (HONO) and related parameters were conducted at the foot and the summit of Mt. Tai (1534 m above sea level). We proposed a rapid vertical air mass exchange between the foot and the summit level, which enhances the role of HONO in the oxidizing capacity of the upper boundary layer. Kinetics for aerosol-derived HONO sources were constrained. HONO formation from different paths was quantified and discussed.
Yanhong Zhu, Weijun Li, Yue Wang, Jian Zhang, Lei Liu, Liang Xu, Jingsha Xu, Jinhui Shi, Longyi Shao, Pingqing Fu, Daizhou Zhang, and Zongbo Shi
Atmos. Chem. Phys., 22, 2191–2202, https://doi.org/10.5194/acp-22-2191-2022, https://doi.org/10.5194/acp-22-2191-2022, 2022
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The solubilities of iron in fine particles in a megacity in Eastern China were studied under haze, fog, dust, clear, and rain weather conditions. For the first time, a receptor model was used to quantify the sources of dissolved and total iron aerosol. Microscopic analysis further confirmed the aging of iron aerosol during haze and fog conditions that facilitated dissolution of insoluble iron.
Yaqing Zhou, Nan Ma, Qiaoqiao Wang, Zhibin Wang, Chunrong Chen, Jiangchuan Tao, Juan Hong, Long Peng, Yao He, Linhong Xie, Shaowen Zhu, Yuxuan Zhang, Guo Li, Wanyun Xu, Peng Cheng, Uwe Kuhn, Guangsheng Zhou, Pingqing Fu, Qiang Zhang, Hang Su, and Yafang Cheng
Atmos. Chem. Phys., 22, 2029–2047, https://doi.org/10.5194/acp-22-2029-2022, https://doi.org/10.5194/acp-22-2029-2022, 2022
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This study characterizes size-resolved particle effective densities and their evolution associated with emissions and aging processes in a rural area of the North China Plain. Particle effective density exhibits a high-frequency bimodal distribution, and two density modes exhibit opposite trends with increasing particle size. SIA and BC mass fractions are key factors of particle effective density, and a value of 0.6 g cm−3 is appropriate to represent BC effective density in bulk particles.
Jing Cai, Cheng Wu, Jiandong Wang, Wei Du, Feixue Zheng, Simo Hakala, Xiaolong Fan, Biwu Chu, Lei Yao, Zemin Feng, Yongchun Liu, Yele Sun, Jun Zheng, Chao Yan, Federico Bianchi, Markku Kulmala, Claudia Mohr, and Kaspar R. Daellenbach
Atmos. Chem. Phys., 22, 1251–1269, https://doi.org/10.5194/acp-22-1251-2022, https://doi.org/10.5194/acp-22-1251-2022, 2022
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This study investigates the connection between organic aerosol (OA) molecular composition and particle absorptive properties in autumn in Beijing. We find that the molecular properties of OA compounds in different episodes influence particle light absorption properties differently: the light absorption enhancement of black carbon and light absorption coefficient of brown carbon were mostly related to more oxygenated OA (low C number and four O atoms) and aromatics/nitro-aromatics, respectively.
Jiaxing Sun, Zhe Wang, Wei Zhou, Conghui Xie, Cheng Wu, Chun Chen, Tingting Han, Qingqing Wang, Zhijie Li, Jie Li, Pingqing Fu, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 22, 561–575, https://doi.org/10.5194/acp-22-561-2022, https://doi.org/10.5194/acp-22-561-2022, 2022
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We analyzed 9-year measurements of BC and aerosol optical properties from 2012 to 2020 in Beijing, China. Our results showed large reductions in BC and light extinction coefficient due to the Clean Air Action Plan. As a response, both SSA and mass extinction efficiency (MEE) showed considerable increases, demonstrating a future challenge in visibility improvement. The primary and secondary BrC was also separated and quantified, and the changes in radiative forcing of BC and BrC were estimated.
Qian Ye, Jie Li, Xueshun Chen, Huansheng Chen, Wenyi Yang, Huiyun Du, Xiaole Pan, Xiao Tang, Wei Wang, Lili Zhu, Jianjun Li, Zhe Wang, and Zifa Wang
Geosci. Model Dev., 14, 7573–7604, https://doi.org/10.5194/gmd-14-7573-2021, https://doi.org/10.5194/gmd-14-7573-2021, 2021
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We developed a global tropospheric atmospheric chemistry source–receptor model. This model can quantify the contributions of multiple air pollutants from various source regions in one simulation without introducing the nonlinear error of atmospheric chemistry. The S-R relationships of PM2.5 and O3 from a global high-resolution (0.5° × 0.5°) simulation were given and compared with previous studies. This model will be useful for creating a link between the scientific community and policymakers.
Yuting Zhang, Hang Liu, Shandong Lei, Wanyun Xu, Yu Tian, Weijie Yao, Xiaoyong Liu, Qi Liao, Jie Li, Chun Chen, Yele Sun, Pingqing Fu, Jinyuan Xin, Junji Cao, Xiaole Pan, and Zifa Wang
Atmos. Chem. Phys., 21, 17631–17648, https://doi.org/10.5194/acp-21-17631-2021, https://doi.org/10.5194/acp-21-17631-2021, 2021
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In this study, the authors used a single-particle soot photometer (SP2) to characterize the particle size, mixing state, and optical properties of black carbon aerosols in rural areas of the North China Plain in winter. Relatively warm and high-RH environments (RH > 50 %, −4° < T < 4 °) were more favorable to rBC aging than dry and cold environments (RH < 60 %, T < −8°). The paper emphasizes the importance of meteorological parameters in the mixing state of black carbon.
Liang Xu, Xiaohuan Liu, Huiwang Gao, Xiaohong Yao, Daizhou Zhang, Lei Bi, Lei Liu, Jian Zhang, Yinxiao Zhang, Yuanyuan Wang, Qi Yuan, and Weijun Li
Atmos. Chem. Phys., 21, 17715–17726, https://doi.org/10.5194/acp-21-17715-2021, https://doi.org/10.5194/acp-21-17715-2021, 2021
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We quantified different types of marine aerosols and explored the Cl depletion of sea salt aerosol (SSA) in the eastern China seas and the northwestern Pacific Ocean. We found that anthropogenic acidic gases in the troposphere were transported longer distances compared to the anthropogenic aerosols and could significantly impact remote marine aerosols. Meanwhile, variations of chloride depletion in SSA can serve as a potential indicator for anthropogenic gaseous pollutants in remote marine air.
Wenxing Jia and Xiaoye Zhang
Atmos. Chem. Phys., 21, 16827–16841, https://doi.org/10.5194/acp-21-16827-2021, https://doi.org/10.5194/acp-21-16827-2021, 2021
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Heavy aerosol pollution incidents have attracted much attention since 2013, but the temporal and spatial limitations of observations and the inaccuracy of simulation are a stumbling block to assessing pollution mechanisms. The correct simulation of boundary layer mixing process of pollutant is a challenge for mesoscale numerical models. We add the turbulent diffusion term of aerosol to the WRF-Chem model to prove the impact of turbulent diffusion on pollutant concentration.
Wei Sun, Yuzhen Fu, Guohua Zhang, Yuxiang Yang, Feng Jiang, Xiufeng Lian, Bin Jiang, Yuhong Liao, Xinhui Bi, Duohong Chen, Jianmin Chen, Xinming Wang, Jie Ou, Ping'an Peng, and Guoying Sheng
Atmos. Chem. Phys., 21, 16631–16644, https://doi.org/10.5194/acp-21-16631-2021, https://doi.org/10.5194/acp-21-16631-2021, 2021
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We sampled cloud water at a remote mountain site and investigated the molecular characteristics. CHON and CHO are dominant in cloud water. No statistical difference in the oxidation state is observed between cloud water and interstitial PM2.5. Most of the formulas are aliphatic and olefinic species. CHON, with aromatic structures and organosulfates, are abundant, especially in nighttime samples. The in-cloud and multi-phase dark reactions likely contribute significantly.
Men Xia, Xiang Peng, Weihao Wang, Chuan Yu, Zhe Wang, Yee Jun Tham, Jianmin Chen, Hui Chen, Yujing Mu, Chenglong Zhang, Pengfei Liu, Likun Xue, Xinfeng Wang, Jian Gao, Hong Li, and Tao Wang
Atmos. Chem. Phys., 21, 15985–16000, https://doi.org/10.5194/acp-21-15985-2021, https://doi.org/10.5194/acp-21-15985-2021, 2021
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ClNO2 is an important precursor of chlorine radical that affects photochemistry. However, its production and impact are not well understood. Our study presents field observations of ClNO2 at three sites in northern China. These observations provide new insights into nighttime processes that produce ClNO2 and the significant impact of ClNO2 on secondary pollutions during daytime. The results improve the understanding of photochemical pollution in the lower part of the atmosphere.
Ke Gui, Huizheng Che, Yu Zheng, Hujia Zhao, Wenrui Yao, Lei Li, Lei Zhang, Hong Wang, Yaqiang Wang, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 15309–15336, https://doi.org/10.5194/acp-21-15309-2021, https://doi.org/10.5194/acp-21-15309-2021, 2021
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This study utilized the globally gridded aerosol extinction data from CALIOP during 2007–2019 to investigate the 3D climatology, trends, and meteorological drivers of tropospheric type-dependent aerosols. Results revealed that the planetary boundary layer (PBL) and the free troposphere contribute 62.08 % and 37.92 %, respectively, of the global tropospheric TAOD. Trends in
CALIOP-derived aerosol loading, in particular those partitioned in the PBL, can be explained to a large extent by meteorology.
Deepchandra Srivastava, Jingsha Xu, Tuan V. Vu, Di Liu, Linjie Li, Pingqing Fu, Siqi Hou, Natalia Moreno Palmerola, Zongbo Shi, and Roy M. Harrison
Atmos. Chem. Phys., 21, 14703–14724, https://doi.org/10.5194/acp-21-14703-2021, https://doi.org/10.5194/acp-21-14703-2021, 2021
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This study presents the source apportionment of PM2.5 performed by positive matrix factorization (PMF) at urban and rural sites in Beijing. These factors are interpreted as traffic emissions, biomass burning, road and soil dust, coal and oil combustion, and secondary inorganics. PMF failed to resolve some sources identified by CMB and AMS and appears to overestimate the dust sources. Comparison with earlier PMF studies from the Beijing area highlights inconsistent findings using this method.
Sihui Jiang, Fang Zhang, Jingye Ren, Lu Chen, Xing Yan, Jieyao Liu, Yele Sun, and Zhanqing Li
Atmos. Chem. Phys., 21, 14293–14308, https://doi.org/10.5194/acp-21-14293-2021, https://doi.org/10.5194/acp-21-14293-2021, 2021
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New particle formation (NPF) can be a large source of CCN and affect weather and climate. Here we show that the NPF contributes largely to cloud droplet number concentration (Nd) but is suppressed at high particle number concentrations in Beijing due to water vapor competition. We also reveal a considerable impact of primary sources on the evaluation in the urban atmosphere. Our study has great significance for assessing NPF-associated effects on climate in polluted regions.
Michael Biggart, Jenny Stocker, Ruth M. Doherty, Oliver Wild, David Carruthers, Sue Grimmond, Yiqun Han, Pingqing Fu, and Simone Kotthaus
Atmos. Chem. Phys., 21, 13687–13711, https://doi.org/10.5194/acp-21-13687-2021, https://doi.org/10.5194/acp-21-13687-2021, 2021
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Heat-related illnesses are of increasing concern in China given its rapid urbanisation and our ever-warming climate. We examine the relative impacts that land surface properties and anthropogenic heat have on the urban heat island (UHI) in Beijing using ADMS-Urban. Air temperature measurements and satellite-derived land surface temperatures provide valuable means of evaluating modelled spatiotemporal variations. This work provides critical information for urban planners and UHI mitigation.
Huan Song, Keding Lu, Can Ye, Huabin Dong, Shule Li, Shiyi Chen, Zhijun Wu, Mei Zheng, Limin Zeng, Min Hu, and Yuanhang Zhang
Atmos. Chem. Phys., 21, 13713–13727, https://doi.org/10.5194/acp-21-13713-2021, https://doi.org/10.5194/acp-21-13713-2021, 2021
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Secondary sulfate aerosols are an important component of fine particles in severe air pollution events. We calculated the sulfate formation rates via a state-of-the-art multiphase model constrained to the observed values. We showed that transition metals in urban aerosols contribute significantly to sulfate formation during haze periods and thus play an important role in mitigation strategies and public health measures in megacities worldwide.
Hong Ren, Wei Hu, Lianfang Wei, Siyao Yue, Jian Zhao, Linjie Li, Libin Wu, Wanyu Zhao, Lujie Ren, Mingjie Kang, Qiaorong Xie, Sihui Su, Xiaole Pan, Zifa Wang, Yele Sun, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 21, 12949–12963, https://doi.org/10.5194/acp-21-12949-2021, https://doi.org/10.5194/acp-21-12949-2021, 2021
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This study presents vertical profiles of biogenic and anthropogenic secondary organic aerosols (SOAs) in the urban boundary layer based on a 325 m tower in Beijing in late summer. The increases in the isoprene and toluene SOAs with height were found to be more related to regional transport, whereas the decrease in those from monoterpenes and sesquiterpene were more subject to local emissions. Such complicated vertical distributions of SOA should be considered in future modeling work.
Junhua Wang, Baozhu Ge, Xueshun Chen, Jie Li, Keding Lu, Yayuan Dong, Lei Kong, Zifa Wang, and Yuanhang Zhang
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2021-259, https://doi.org/10.5194/gmd-2021-259, 2021
Revised manuscript not accepted
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This paper developed a novel quantitative decoupling analysis (QDA) method to quantify the contributions of emission, meteorology, chemical reaction, and their nonlinear interactions on PM2.5 and applied it to a pollution episode in Beijing. This method can provides the researchers and policy makers with valuable information for understanding of key factors to heavy pollution, but also help the modelers to find out the sources of uncertainties among numerical models.
Letizia Abis, Carmen Kalalian, Bastien Lunardelli, Tao Wang, Liwu Zhang, Jianmin Chen, Sébastien Perrier, Benjamin Loubet, Raluca Ciuraru, and Christian George
Atmos. Chem. Phys., 21, 12613–12629, https://doi.org/10.5194/acp-21-12613-2021, https://doi.org/10.5194/acp-21-12613-2021, 2021
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Biogenic volatile organic compound (BVOC) emissions from rapeseed leaf litter have been investigated by means of a controlled atmospheric simulation chamber. The diversity of emitted VOCs increased also in the presence of UV light irradiation. SOA formation was observed when leaf litter was exposed to both UV light and ozone, indicating a potential contribution to particle formation or growth at local scales.
Zhenzhen Wang, Di Wu, Zhuoyu Li, Xiaona Shang, Qing Li, Xiang Li, Renjie Chen, Haidong Kan, Huiling Ouyang, Xu Tang, and Jianmin Chen
Atmos. Chem. Phys., 21, 12227–12241, https://doi.org/10.5194/acp-21-12227-2021, https://doi.org/10.5194/acp-21-12227-2021, 2021
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This study firstly investigates the composition of sugars in the fine fraction of aerosol over three sites in southwest China. The result suggested no significant reduction in biomass burning emissions in southwest Yunnan Province to some extent. The result shown sheds light on the contributions of biomass burning and the characteristics of biogenic saccharides in these regions, which could be further applied to regional source apportionment models and global climate models.
Yang Yang, Minqiang Zhou, Ting Wang, Bo Yao, Pengfei Han, Denghui Ji, Wei Zhou, Yele Sun, Gengchen Wang, and Pucai Wang
Atmos. Chem. Phys., 21, 11741–11757, https://doi.org/10.5194/acp-21-11741-2021, https://doi.org/10.5194/acp-21-11741-2021, 2021
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This study introduces the in situ CO2 measurement system installed in Beijing (urban), Xianghe (suburban), and Xinglong (rural) in North China for the first time. The spatial and temporal variations in CO2 mole fractions at the three sites between June 2018 and April 2020 are discussed on both seasonal and diurnal scales.
Qiaorong Xie, Sihui Su, Jing Chen, Yuqing Dai, Siyao Yue, Hang Su, Haijie Tong, Wanyu Zhao, Lujie Ren, Yisheng Xu, Dong Cao, Ying Li, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, Guibin Jiang, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 21, 11453–11465, https://doi.org/10.5194/acp-21-11453-2021, https://doi.org/10.5194/acp-21-11453-2021, 2021
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This study investigated the role of nighttime chemistry during Chinese New Year's Eve that enhances the formation of nitrooxy organosulfates in the aerosol phase. Results show that anthropogenic precursors, together with biogenic ones, considerably contribute to the formation of low-volatility nitrooxy OSs. Our study provides detailed molecular composition of firework-related aerosols, which gives new insights into the physicochemical properties and potential health effects of urban aerosols.
Yingnan Zhang, Likun Xue, William P. L. Carter, Chenglei Pei, Tianshu Chen, Jiangshan Mu, Yujun Wang, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 21, 11053–11068, https://doi.org/10.5194/acp-21-11053-2021, https://doi.org/10.5194/acp-21-11053-2021, 2021
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We developed the localized incremental reactivity (IR) for VOCs in a Chinese megacity and elucidated their applications in calculating the ozone formation potential (OFP). The IR scales showed a strong dependence on chemical mechanisms. Both emission- and observation-based inputs are suitable for the MIR calculation but not the case under mixed-limited or NOx-limited O3 formation regimes. We provide suggestions for the application of IR and OFP scales to aid in VOC control in China.
Ying Wei, Xueshun Chen, Huansheng Chen, Yele Sun, Wenyi Yang, Huiyun Du, Qizhong Wu, Dan Chen, Xiujuan Zhao, Jie Li, and Zifa Wang
Geosci. Model Dev., 14, 4411–4428, https://doi.org/10.5194/gmd-14-4411-2021, https://doi.org/10.5194/gmd-14-4411-2021, 2021
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The sub-grid particle formation (SGPF) in plumes plays an important role in air pollution and climate. We coupled an SGPF scheme to a chemical transport model with an aerosol microphysics module and applied it to investigate the SGPF impact over China. The scheme clearly improved the model performance in simulating aerosol components and particle number at typical sites influenced by point sources. The results indicate the significant effects of SGPF on aerosol particles in industrial areas.
Haijie Tong, Fobang Liu, Alexander Filippi, Jake Wilson, Andrea M. Arangio, Yun Zhang, Siyao Yue, Steven Lelieveld, Fangxia Shen, Helmi-Marja K. Keskinen, Jing Li, Haoxuan Chen, Ting Zhang, Thorsten Hoffmann, Pingqing Fu, William H. Brune, Tuukka Petäjä, Markku Kulmala, Maosheng Yao, Thomas Berkemeier, Manabu Shiraiwa, and Ulrich Pöschl
Atmos. Chem. Phys., 21, 10439–10455, https://doi.org/10.5194/acp-21-10439-2021, https://doi.org/10.5194/acp-21-10439-2021, 2021
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We measured radical yields of aqueous PM2.5 extracts and found lower yields at higher concentrations of PM2.5. Abundances of water-soluble transition metals and aromatics in PM2.5 were positively correlated with the relative fraction of •OH but negatively correlated with the relative fraction of C-centered radicals among detected radicals. Composition-dependent reactive species yields may explain differences in the reactivity and health effects of PM2.5 in clean versus polluted air.
Qingyang Xiao, Yixuan Zheng, Guannan Geng, Cuihong Chen, Xiaomeng Huang, Huizheng Che, Xiaoye Zhang, Kebin He, and Qiang Zhang
Atmos. Chem. Phys., 21, 9475–9496, https://doi.org/10.5194/acp-21-9475-2021, https://doi.org/10.5194/acp-21-9475-2021, 2021
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We used both statistical methods and a chemical transport model to assess the contribution of meteorology and emissions to PM2.5 during 2000–2018. Both methods revealed that emissions dominated the long-term PM2.5 trend with notable meteorological effects ranged up to 37.9 % of regional annual average PM2.5. The meteorological contribution became more beneficial to PM2.5 control in southern China but more unfavorable in northern China during the studied period.
Baozhu Ge, Danhui Xu, Oliver Wild, Xuefeng Yao, Junhua Wang, Xueshun Chen, Qixin Tan, Xiaole Pan, and Zifa Wang
Atmos. Chem. Phys., 21, 9441–9454, https://doi.org/10.5194/acp-21-9441-2021, https://doi.org/10.5194/acp-21-9441-2021, 2021
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In this study, an improved sequential sampling method is developed and implemented to estimate the contribution of below-cloud and in-cloud wet deposition over four years of measurements in Beijing. We find that the contribution of below-cloud scavenging for Ca2+, SO4 2–, and NH4+ decreases from above 50 % in 2014 to below 40 % in 2017. This suggests that the Action Plan has mitigated particulate matter pollution in the surface layer and hence decreased scavenging due to the washout process.
Xueshun Chen, Fangqun Yu, Wenyi Yang, Yele Sun, Huansheng Chen, Wei Du, Jian Zhao, Ying Wei, Lianfang Wei, Huiyun Du, Zhe Wang, Qizhong Wu, Jie Li, Junling An, and Zifa Wang
Atmos. Chem. Phys., 21, 9343–9366, https://doi.org/10.5194/acp-21-9343-2021, https://doi.org/10.5194/acp-21-9343-2021, 2021
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Atmospheric aerosol particles have significant climate and health effects that depend on aerosol size, composition, and mixing state. A new global-regional nested aerosol model with an advanced particle microphysics module and a volatility basis set organic aerosol module was developed to simulate aerosol microphysical processes. Simulations strongly suggest the important role of anthropogenic organic species in particle formation over the areas influenced by anthropogenic sources.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Zhe Wang, Junichi Kurokawa, Jiani Tan, Kan Huang, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 21, 8709–8734, https://doi.org/10.5194/acp-21-8709-2021, https://doi.org/10.5194/acp-21-8709-2021, 2021
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This study presents the detailed analysis of acid deposition over southeast Asia based on the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Simulated wet deposition is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The difficulties of models to capture observations are related to the model performance on precipitation. The precipitation-adjusted approach was applied, and the distribution of wet deposition was successfully revised.
Rui Li, Yilong Zhao, Hongbo Fu, Jianmin Chen, Meng Peng, and Chunying Wang
Atmos. Chem. Phys., 21, 8677–8692, https://doi.org/10.5194/acp-21-8677-2021, https://doi.org/10.5194/acp-21-8677-2021, 2021
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Based on a random forest model, the strict lockdown measures significantly decreased primary components such as Cr (−67 %) and Fe (−61 %) in PM2.5 (p < 0.01), whereas the higher relative humidity (RH) and NH3 level and the lower air temperature (T) remarkably enhanced the production of secondary aerosol including SO42− (29 %), NO3− (29 %), and NH4+ (21 %) (p < 0.05). The natural experiment suggested that the NH3 emission should be strictly controlled.
Siqi Hou, Di Liu, Jingsha Xu, Tuan V. Vu, Xuefang Wu, Deepchandra Srivastava, Pingqing Fu, Linjie Li, Yele Sun, Athanasia Vlachou, Vaios Moschos, Gary Salazar, Sönke Szidat, André S. H. Prévôt, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 8273–8292, https://doi.org/10.5194/acp-21-8273-2021, https://doi.org/10.5194/acp-21-8273-2021, 2021
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This study provides a newly developed method which combines radiocarbon (14C) with organic tracers to enable source apportionment of primary and secondary fossil vs. non-fossil sources of carbonaceous aerosols at an urban and a rural site of Beijing. The source apportionment results were compared with those by chemical mass balance and AMS/ACSM-PMF methods. Correlations of WINSOC and WSOC with different sources of OC were also performed to elucidate the formation mechanisms of SOC.
Weiqi Xu, Masayuki Takeuchi, Chun Chen, Yanmei Qiu, Conghui Xie, Wanyun Xu, Nan Ma, Douglas R. Worsnop, Nga Lee Ng, and Yele Sun
Atmos. Meas. Tech., 14, 3693–3705, https://doi.org/10.5194/amt-14-3693-2021, https://doi.org/10.5194/amt-14-3693-2021, 2021
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Here we developed a method for estimation of particulate organic nitrates (pON) from the measurements of a high-resolution aerosol mass spectrometer coupled with a thermodenuder based on the volatility differences between inorganic nitrate and pON. The results generally had improvements in reducing negative values due to the influences of a high concentration of inorganic nitrate and a constant ratio of NO+ to NO2+ of organic nitrates (RON).
Jiangchuan Tao, Ye Kuang, Nan Ma, Juan Hong, Yele Sun, Wanyun Xu, Yanyan Zhang, Yao He, Qingwei Luo, Linhong Xie, Hang Su, and Yafang Cheng
Atmos. Chem. Phys., 21, 7409–7427, https://doi.org/10.5194/acp-21-7409-2021, https://doi.org/10.5194/acp-21-7409-2021, 2021
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The mechanism of secondary aerosol (SA) formation can be affected by relative humidity (RH) and has different influences on the particle CCN activity under different RH conditions. In the North China Plain, we find different responses of CCN activity and enhancements of CCN number concentration to SA formation under different RH conditions. In addition, variations of aerosol mixing state due to SA formation contribute some of the largest uncertainties in predicting CCN number concentration.
Jinlong Ma, Juanyong Shen, Peng Wang, Shengqiang Zhu, Yu Wang, Pengfei Wang, Gehui Wang, Jianmin Chen, and Hongliang Zhang
Atmos. Chem. Phys., 21, 7343–7355, https://doi.org/10.5194/acp-21-7343-2021, https://doi.org/10.5194/acp-21-7343-2021, 2021
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Due to the reduced anthropogenic emissions during the COVID-19 lockdown, mainly from the transportation and industrial sectors, PM2.5 decreased significantly in the whole Yangtze River Delta (YRD) and its major cities. However, the contributions and relative importance of different source sectors and regions changed differently, indicating that control strategies should be adjusted accordingly for further pollution control.
Jingsha Xu, Di Liu, Xuefang Wu, Tuan V. Vu, Yanli Zhang, Pingqing Fu, Yele Sun, Weiqi Xu, Bo Zheng, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 7321–7341, https://doi.org/10.5194/acp-21-7321-2021, https://doi.org/10.5194/acp-21-7321-2021, 2021
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Source apportionment of fine aerosols in an urban site of Beijing used a chemical mass balance (CMB) model. Seven primary sources (industrial/residential coal burning, biomass burning, gasoline/diesel vehicles, cooking and vegetative detritus) explained an average of 75.7 % and 56.1 % of fine OC in winter and summer, respectively. CMB was found to resolve more primary OA sources than AMS-PMF, but the latter apportioned more secondary OA sources.
Xiaojing Shen, Junying Sun, Fangqun Yu, Ying Wang, Junting Zhong, Yangmei Zhang, Xinyao Hu, Can Xia, Sinan Zhang, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 7039–7052, https://doi.org/10.5194/acp-21-7039-2021, https://doi.org/10.5194/acp-21-7039-2021, 2021
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In this work, we revealed the changes of PNSD and NPF events during the COVID-19 lockdown period in Beijing, China, to illustrate the impact of reduced primary emission and elavated atmospheric oxidized capicity on the nucleation and growth processes. The subsequent growth of nucleated particles and their contribution to the aerosol pollution formation were also explored, to highlight the necessity of controlling the nanoparticles in the future air quality management.
Philippe Massicotte, Rainer M. W. Amon, David Antoine, Philippe Archambault, Sergio Balzano, Simon Bélanger, Ronald Benner, Dominique Boeuf, Annick Bricaud, Flavienne Bruyant, Gwenaëlle Chaillou, Malik Chami, Bruno Charrière, Jing Chen, Hervé Claustre, Pierre Coupel, Nicole Delsaut, David Doxaran, Jens Ehn, Cédric Fichot, Marie-Hélène Forget, Pingqing Fu, Jonathan Gagnon, Nicole Garcia, Beat Gasser, Jean-François Ghiglione, Gaby Gorsky, Michel Gosselin, Priscillia Gourvil, Yves Gratton, Pascal Guillot, Hermann J. Heipieper, Serge Heussner, Stanford B. Hooker, Yannick Huot, Christian Jeanthon, Wade Jeffrey, Fabien Joux, Kimitaka Kawamura, Bruno Lansard, Edouard Leymarie, Heike Link, Connie Lovejoy, Claudie Marec, Dominique Marie, Johannie Martin, Jacobo Martín, Guillaume Massé, Atsushi Matsuoka, Vanessa McKague, Alexandre Mignot, William L. Miller, Juan-Carlos Miquel, Alfonso Mucci, Kaori Ono, Eva Ortega-Retuerta, Christos Panagiotopoulos, Tim Papakyriakou, Marc Picheral, Louis Prieur, Patrick Raimbault, Joséphine Ras, Rick A. Reynolds, André Rochon, Jean-François Rontani, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Yuan Shen, Guisheng Song, Dariusz Stramski, Eri Tachibana, Alexandre Thirouard, Imma Tolosa, Jean-Éric Tremblay, Mickael Vaïtilingom, Daniel Vaulot, Frédéric Vaultier, John K. Volkman, Huixiang Xie, Guangming Zheng, and Marcel Babin
Earth Syst. Sci. Data, 13, 1561–1592, https://doi.org/10.5194/essd-13-1561-2021, https://doi.org/10.5194/essd-13-1561-2021, 2021
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The MALINA oceanographic expedition was conducted in the Mackenzie River and the Beaufort Sea systems. The sampling was performed across seven shelf–basin transects to capture the meridional gradient between the estuary and the open ocean. The main goal of this research program was to better understand how processes such as primary production are influencing the fate of organic matter originating from the surrounding terrestrial landscape during its transition toward the Arctic Ocean.
Steven J. Campbell, Kate Wolfer, Battist Utinger, Joe Westwood, Zhi-Hui Zhang, Nicolas Bukowiecki, Sarah S. Steimer, Tuan V. Vu, Jingsha Xu, Nicholas Straw, Steven Thomson, Atallah Elzein, Yele Sun, Di Liu, Linjie Li, Pingqing Fu, Alastair C. Lewis, Roy M. Harrison, William J. Bloss, Miranda Loh, Mark R. Miller, Zongbo Shi, and Markus Kalberer
Atmos. Chem. Phys., 21, 5549–5573, https://doi.org/10.5194/acp-21-5549-2021, https://doi.org/10.5194/acp-21-5549-2021, 2021
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In this study, we quantify PM2.5 oxidative potential (OP), a metric widely suggested as a potential measure of particle toxicity, in Beijing in summer and winter using four acellular assays. We correlate PM2.5 OP with a comprehensive range of atmospheric and particle composition measurements, demonstrating inter-assay differences and seasonal variation of PM2.5 OP. Using multivariate statistical analysis, we highlight specific particle chemical components and sources that influence OP.
Weiqi Xu, Chun Chen, Yanmei Qiu, Ying Li, Zhiqiang Zhang, Eleni Karnezi, Spyros N. Pandis, Conghui Xie, Zhijie Li, Jiaxing Sun, Nan Ma, Wanyun Xu, Pingqing Fu, Zifa Wang, Jiang Zhu, Douglas R. Worsnop, Nga Lee Ng, and Yele Sun
Atmos. Chem. Phys., 21, 5463–5476, https://doi.org/10.5194/acp-21-5463-2021, https://doi.org/10.5194/acp-21-5463-2021, 2021
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Here aerosol volatility and viscosity at a rural site (Gucheng) and an urban site (Beijing) in the North China Plain (NCP) were investigated in summer and winter. Our results showed that organic aerosol (OA) in winter in the NCP is more volatile than that in summer due to enhanced primary emissions from coal combustion and biomass burning. We also found that OA existed mainly as a solid in winter in Beijing but as semisolids in Beijing in summer and Gucheng in winter.
Santosh Kumar Verma, Kimitaka Kawamura, Fei Yang, Pingqing Fu, Yugo Kanaya, and Zifa Wang
Atmos. Chem. Phys., 21, 4959–4978, https://doi.org/10.5194/acp-21-4959-2021, https://doi.org/10.5194/acp-21-4959-2021, 2021
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We studied aerosol samples collected in autumn 2007 with day and night intervals in a rural site of Mangshan, north of Beijing, for sugar compounds (SCs) that are abundant organic aerosol components and can influence the air quality and climate. We found higher concentrations of biomass burning (BB) products at nighttime than daytime, whereas pollen tracers and other SCs showed an opposite diurnal trend, because this site is meteorologically characterized by a mountain/valley breeze.
Tabish Umar Ansari, Oliver Wild, Edmund Ryan, Ying Chen, Jie Li, and Zifa Wang
Atmos. Chem. Phys., 21, 4471–4485, https://doi.org/10.5194/acp-21-4471-2021, https://doi.org/10.5194/acp-21-4471-2021, 2021
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We use novel modelling approaches to quantify the lingering effects of 1 d local and regional emission controls on subsequent days, the effects of longer continuous emission controls of individual sectors over different regions, and the effects of combined emission controls of multiple sectors and regions on air quality in Beijing under varying weather conditions to inform precise short-term emission control policies for avoiding heavy haze pollution in Beijing.
Linlin Liang, Guenter Engling, Chang Liu, Wanyun Xu, Xuyan Liu, Yuan Cheng, Zhenyu Du, Gen Zhang, Junying Sun, and Xiaoye Zhang
Atmos. Chem. Phys., 21, 3181–3192, https://doi.org/10.5194/acp-21-3181-2021, https://doi.org/10.5194/acp-21-3181-2021, 2021
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A unique episode with extreme biomass burning (BB) impact, with daily concentration of levoglucosan as high as 4.37 µg m-3, was captured at an area upwind of Beijing. How this extreme BB pollution event was generated and what were the chemical properties of PM2.5 under this kind severe BB pollution level in the real atmospheric environment were both presented in this measurement report. Moreover, the variation of the ratios of BB tracers during different BB pollution periods was also exhibited.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Jianjun Li, Huangjian Wu, Qizhong Wu, Huansheng Chen, Lili Zhu, Wei Wang, Bing Liu, Qian Wang, Duohong Chen, Yuepeng Pan, Tao Song, Fei Li, Haitao Zheng, Guanglin Jia, Miaomiao Lu, Lin Wu, and Gregory R. Carmichael
Earth Syst. Sci. Data, 13, 529–570, https://doi.org/10.5194/essd-13-529-2021, https://doi.org/10.5194/essd-13-529-2021, 2021
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China's air pollution has changed substantially since 2013. Here we have developed a 6-year-long high-resolution air quality reanalysis dataset over China from 2013 to 2018 to illustrate such changes and to provide a basic dataset for relevant studies. Surface fields of PM2.5, PM10, SO2, NO2, CO, and O3 concentrations are provided, and the evaluation results indicate that the reanalysis dataset has excellent performance in reproducing the magnitude and variation of air pollution in China.
Lei Liu, Jian Zhang, Yinxiao Zhang, Yuanyuan Wang, Liang Xu, Qi Yuan, Dantong Liu, Yele Sun, Pingqing Fu, Zongbo Shi, and Weijun Li
Atmos. Chem. Phys., 21, 2251–2265, https://doi.org/10.5194/acp-21-2251-2021, https://doi.org/10.5194/acp-21-2251-2021, 2021
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We found that large numbers of light-absorbing primary organic particles with high viscosity, especially tarballs, from domestic coal and biomass burning occurred in rural and even urban hazes in the winter of North China. For the first time, we characterized the atmospheric aging process of these burning-related primary organic particles by microscopic analysis and further evaluated their light absorption enhancement resulting from the “lensing effect” of secondary inorganic coatings.
Lisa K. Whalley, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Archit Mehra, Stephen D. Worrall, Asan Bacak, Thomas J. Bannan, Hugh Coe, Carl J. Percival, Bin Ouyang, Roderic L. Jones, Leigh R. Crilley, Louisa J. Kramer, William J. Bloss, Tuan Vu, Simone Kotthaus, Sue Grimmond, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 21, 2125–2147, https://doi.org/10.5194/acp-21-2125-2021, https://doi.org/10.5194/acp-21-2125-2021, 2021
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To understand how emission controls will impact ozone, an understanding of the sources and sinks of OH and the chemical cycling between peroxy radicals is needed. This paper presents measurements of OH, HO2 and total RO2 taken in central Beijing. The radical observations are compared to a detailed chemistry model, which shows that under low NO conditions, there is a missing OH source. Under high NOx conditions, the model under-predicts RO2 and impacts our ability to model ozone.
Xiaona Shang, Ling Li, Xinlian Zhang, Huihui Kang, Guodong Sui, Gehui Wang, Xingnan Ye, Hang Xiao, and Jianmin Chen
Atmos. Meas. Tech., 14, 1037–1045, https://doi.org/10.5194/amt-14-1037-2021, https://doi.org/10.5194/amt-14-1037-2021, 2021
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Oxidative stress can be used to evaluate not only adverse health effects but also adverse ecological effects. However, little research uses eco-toxicological assay to assess the risks posed by particle matter to non-human biomes. One important reason might be that the concentration of toxic components of atmospheric particles is far below the high detection limit of eco-toxic measurement. To solve the rapid detection problem, we extended a VACES for ecotoxicity aerosol measurement.
Lei Zhang, Sunling Gong, Tianliang Zhao, Chunhong Zhou, Yuesi Wang, Jiawei Li, Dongsheng Ji, Jianjun He, Hongli Liu, Ke Gui, Xiaomei Guo, Jinhui Gao, Yunpeng Shan, Hong Wang, Yaqiang Wang, Huizheng Che, and Xiaoye Zhang
Geosci. Model Dev., 14, 703–718, https://doi.org/10.5194/gmd-14-703-2021, https://doi.org/10.5194/gmd-14-703-2021, 2021
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Development of chemical transport models with advanced physics and chemical schemes is important for improving air-quality forecasts. This study develops the chemical module CUACE by updating with a new particle dry deposition scheme and adding heterogenous chemical reactions and couples it with the WRF model. The coupled model (WRF/CUACE) was able to capture well the variations of PM2.5, O3, NO2, and secondary inorganic aerosols in eastern China.
Yujiao Zhu, Likun Xue, Jian Gao, Jianmin Chen, Hongyong Li, Yong Zhao, Zhaoxin Guo, Tianshu Chen, Liang Wen, Penggang Zheng, Ye Shan, Xinfeng Wang, Tao Wang, Xiaohong Yao, and Wenxing Wang
Atmos. Chem. Phys., 21, 1305–1323, https://doi.org/10.5194/acp-21-1305-2021, https://doi.org/10.5194/acp-21-1305-2021, 2021
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This work investigates the long-term changes in new particle formation (NPF) events under reduced SO2 emissions at the summit of Mt. Tai during seven campaigns from 2007 to 2018. We found the NPF intensity increased 2- to 3-fold in 2018 compared to 2007. In contrast, the probability of new particles growing to CCN size largely decreased. Changes to biogenic VOCs and anthropogenic emissions are proposed to explain the distinct NPF characteristics.
Liya Ma, Yujiao Zhu, Mei Zheng, Yele Sun, Lei Huang, Xiaohuan Liu, Yang Gao, Yanjie Shen, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 21, 183–200, https://doi.org/10.5194/acp-21-183-2021, https://doi.org/10.5194/acp-21-183-2021, 2021
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In this study, we investigate three patterns of new particles growing to CCN (cloud condensation nuclei) size, i.e., one-stage growth and two-stage growth-A and growth-B patterns. Combining the observations of gaseous pollutants and measured or modeled particulate chemical species, the three growth patterns were discussed regarding the spatial heterogeneity, formation of secondary aerosols, and evaporation of semivolatile particulates as was the survival probability of new particles to CCN size.
Rutambhara Joshi, Dantong Liu, Eiko Nemitz, Ben Langford, Neil Mullinger, Freya Squires, James Lee, Yunfei Wu, Xiaole Pan, Pingqing Fu, Simone Kotthaus, Sue Grimmond, Qiang Zhang, Ruili Wu, Oliver Wild, Michael Flynn, Hugh Coe, and James Allan
Atmos. Chem. Phys., 21, 147–162, https://doi.org/10.5194/acp-21-147-2021, https://doi.org/10.5194/acp-21-147-2021, 2021
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Black carbon (BC) is a component of particulate matter which has significant effects on climate and human health. Sources of BC include biomass burning, transport, industry and domestic cooking and heating. In this study, we measured BC emissions in Beijing, finding a dominance of traffic emissions over all other sources. The quantitative method presented here has benefits for revising widely used emissions inventories and for understanding BC sources with impacts on air quality and climate.
Huan Song, Xiaorui Chen, Keding Lu, Qi Zou, Zhaofeng Tan, Hendrik Fuchs, Alfred Wiedensohler, Daniel R. Moon, Dwayne E. Heard, María-Teresa Baeza-Romero, Mei Zheng, Andreas Wahner, Astrid Kiendler-Scharr, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 15835–15850, https://doi.org/10.5194/acp-20-15835-2020, https://doi.org/10.5194/acp-20-15835-2020, 2020
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Accurate calculation of the HO2 uptake coefficient is one of the key parameters to quantify the co-reduction of both aerosol and ozone pollution. We modelled various lab measurements of γHO2 based on a gas-liquid phase kinetic model and developed a state-of-the-art parameterized equation. Based on a dataset from a comprehensive field campaign in the North China Plain, we proposed that the determination of the heterogeneous uptake process for HO2 should be included in future field campaigns.
W. Joe F. Acton, Zhonghui Huang, Brian Davison, Will S. Drysdale, Pingqing Fu, Michael Hollaway, Ben Langford, James Lee, Yanhui Liu, Stefan Metzger, Neil Mullinger, Eiko Nemitz, Claire E. Reeves, Freya A. Squires, Adam R. Vaughan, Xinming Wang, Zhaoyi Wang, Oliver Wild, Qiang Zhang, Yanli Zhang, and C. Nicholas Hewitt
Atmos. Chem. Phys., 20, 15101–15125, https://doi.org/10.5194/acp-20-15101-2020, https://doi.org/10.5194/acp-20-15101-2020, 2020
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Air quality in Beijing is of concern to both policy makers and the general public. In order to address concerns about air quality it is vital that the sources of atmospheric pollutants are understood. This work presents the first top-down measurement of volatile organic compound (VOC) emissions in Beijing. These measurements are used to evaluate the emissions inventory and assess the impact of VOC emission from the city centre on atmospheric chemistry.
Hajime Akimoto, Tatsuya Nagashima, Natsumi Kawano, Li Jie, Joshua S. Fu, and Zifa Wang
Atmos. Chem. Phys., 20, 15003–15014, https://doi.org/10.5194/acp-20-15003-2020, https://doi.org/10.5194/acp-20-15003-2020, 2020
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In order to perform proper model simulation of ozone near the ground in the coastal area of northeastern Asia, it has been found that it is very important to select appropriate dry deposition velocities of ozone on the oceanic water of specific area of the northwestern Pacific. Empirical measurement of the mixing ratios and dry deposition flux of ozone over the ocean in this area is highly recommended.
Eloise J. Slater, Lisa K. Whalley, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Leigh R. Crilley, Louisa Kramer, William Bloss, Tuan Vu, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 20, 14847–14871, https://doi.org/10.5194/acp-20-14847-2020, https://doi.org/10.5194/acp-20-14847-2020, 2020
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The paper details atmospheric chemistry in a megacity (Beijing), focussing on radicals which mediate the formation of secondary pollutants such as ozone and particles. Highly polluted conditions were experienced, including the highest ever levels of nitric oxide (NO), with simultaneous radical measurements. Radical concentrations were large during "haze" events, demonstrating active photochemistry. Modelling showed that our understanding of the chemistry at high NOx levels is incomplete.
Junjun Deng, Hao Guo, Hongliang Zhang, Jialei Zhu, Xin Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 14419–14435, https://doi.org/10.5194/acp-20-14419-2020, https://doi.org/10.5194/acp-20-14419-2020, 2020
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One-year source apportionment of BC aerosols in a coastal city in China was conducted with the light-absorption observation-based method and source-oriented model. Source contributions identified by the two source apportionment methods were compared. Temporal variability, potential sources and transport pathways of BC from fossil fuel and biomass burning were characterized. Significant influence of biomass burning in North and East–Central China on BC in the region was highlighted.
Jingsha Xu, Shaojie Song, Roy M. Harrison, Congbo Song, Lianfang Wei, Qiang Zhang, Yele Sun, Lu Lei, Chao Zhang, Xiaohong Yao, Dihui Chen, Weijun Li, Miaomiao Wu, Hezhong Tian, Lining Luo, Shengrui Tong, Weiran Li, Junling Wang, Guoliang Shi, Yanqi Huangfu, Yingze Tian, Baozhu Ge, Shaoli Su, Chao Peng, Yang Chen, Fumo Yang, Aleksandra Mihajlidi-Zelić, Dragana Đorđević, Stefan J. Swift, Imogen Andrews, Jacqueline F. Hamilton, Ye Sun, Agung Kramawijaya, Jinxiu Han, Supattarachai Saksakulkrai, Clarissa Baldo, Siqi Hou, Feixue Zheng, Kaspar R. Daellenbach, Chao Yan, Yongchun Liu, Markku Kulmala, Pingqing Fu, and Zongbo Shi
Atmos. Meas. Tech., 13, 6325–6341, https://doi.org/10.5194/amt-13-6325-2020, https://doi.org/10.5194/amt-13-6325-2020, 2020
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An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
Liang Xu, Satoshi Fukushima, Sophie Sobanska, Kotaro Murata, Ayumi Naganuma, Lei Liu, Yuanyuan Wang, Hongya Niu, Zongbo Shi, Tomoko Kojima, Daizhou Zhang, and Weijun Li
Atmos. Chem. Phys., 20, 14321–14332, https://doi.org/10.5194/acp-20-14321-2020, https://doi.org/10.5194/acp-20-14321-2020, 2020
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We quantified the mixing structures of soot particles and found that the dominant mixing structure changed from fresh to partially embedded to fully embedded along the pathway of an Asian dust storm from eastern China to Japan. Soot particles became more compact following transport. Our findings not only provide direct evidence for soot aging during regional transport but also help us understand how their morphology changes in different air environments.
Chaomin Wang, Bin Yuan, Caihong Wu, Sihang Wang, Jipeng Qi, Baolin Wang, Zelong Wang, Weiwei Hu, Wei Chen, Chenshuo Ye, Wenjie Wang, Yele Sun, Chen Wang, Shan Huang, Wei Song, Xinming Wang, Suxia Yang, Shenyang Zhang, Wanyun Xu, Nan Ma, Zhanyi Zhang, Bin Jiang, Hang Su, Yafang Cheng, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, https://doi.org/10.5194/acp-20-14123-2020, 2020
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We utilized a novel online mass spectrometry method to measure the total concentration of higher alkanes at each carbon number at two different sites in China, allowing us to take into account SOA contributions from all isomers for higher alkanes. We found that higher alkanes account for significant fractions of SOA formation at the two sites. The contributions are comparable to or even higher than single-ring aromatics, the most-recognized SOA precursors in urban air.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
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We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
Jiarong Li, Chao Zhu, Hui Chen, Defeng Zhao, Likun Xue, Xinfeng Wang, Hongyong Li, Pengfei Liu, Junfeng Liu, Chenglong Zhang, Yujing Mu, Wenjin Zhang, Luming Zhang, Hartmut Herrmann, Kai Li, Min Liu, and Jianmin Chen
Atmos. Chem. Phys., 20, 13735–13751, https://doi.org/10.5194/acp-20-13735-2020, https://doi.org/10.5194/acp-20-13735-2020, 2020
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Based on a field study at Mt. Tai, China, the simultaneous variations of cloud microphysics, aerosol microphysics and their potential interactions during cloud life cycles were discussed. Results demonstrated that clouds on clean days were more susceptible to the concentrations of particle number, while clouds formed on polluted days might be more sensitive to meteorological parameters. Particles larger than 150 nm played important roles in forming cloud droplets with sizes of 5–10 μm.
Jing Cai, Biwu Chu, Lei Yao, Chao Yan, Liine M. Heikkinen, Feixue Zheng, Chang Li, Xiaolong Fan, Shaojun Zhang, Daoyuan Yang, Yonghong Wang, Tom V. Kokkonen, Tommy Chan, Ying Zhou, Lubna Dada, Yongchun Liu, Hong He, Pauli Paasonen, Joni T. Kujansuu, Tuukka Petäjä, Claudia Mohr, Juha Kangasluoma, Federico Bianchi, Yele Sun, Philip L. Croteau, Douglas R. Worsnop, Veli-Matti Kerminen, Wei Du, Markku Kulmala, and Kaspar R. Daellenbach
Atmos. Chem. Phys., 20, 12721–12740, https://doi.org/10.5194/acp-20-12721-2020, https://doi.org/10.5194/acp-20-12721-2020, 2020
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By applying both OA PMF and size PMF at the same urban measurement site in Beijing, similar particle source types, including vehicular emissions, cooking emissions and secondary formation-related sources, were resolved by both frameworks and agreed well. It is also found that in the absence of new particle formation, vehicular and cooking emissions dominate the particle number concentration, while secondary particulate matter governed PM2.5 mass during spring and summer in Beijing.
Ruqian Miao, Qi Chen, Yan Zheng, Xi Cheng, Yele Sun, Paul I. Palmer, Manish Shrivastava, Jianping Guo, Qiang Zhang, Yuhan Liu, Zhaofeng Tan, Xuefei Ma, Shiyi Chen, Limin Zeng, Keding Lu, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 12265–12284, https://doi.org/10.5194/acp-20-12265-2020, https://doi.org/10.5194/acp-20-12265-2020, 2020
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In this study we evaluated the model performances for simulating secondary inorganic aerosol (SIA) and organic aerosol (OA) in PM2.5 in China against comprehensive datasets. The potential biases from factors related to meteorology, emission, chemistry, and atmospheric removal are systematically investigated. This study provides a comprehensive understanding of modeling PM2.5, which is important for studies on the effectiveness of emission control strategies.
Jiawei Li, Zhiwei Han, Pingqing Fu, and Xiaohong Yao
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1016, https://doi.org/10.5194/acp-2020-1016, 2020
Revised manuscript not accepted
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Organic aerosols of marine origin are so far poorly understood. An on-line coupled regional chemistry-climate model is developed to firstly explore and characterize the seasonality and annual feature of emission, distribution and radiative effects of marine organic aerosols specifically for the western Pacific over East Asia. This study reveals an important role of marine organic aerosols in radiation and cloud and would be valuable for climate research at both regional and global scales.
Ying Jiang, Likun Xue, Rongrong Gu, Mengwei Jia, Yingnan Zhang, Liang Wen, Penggang Zheng, Tianshu Chen, Hongyong Li, Ye Shan, Yong Zhao, Zhaoxin Guo, Yujian Bi, Hengde Liu, Aijun Ding, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 20, 12115–12131, https://doi.org/10.5194/acp-20-12115-2020, https://doi.org/10.5194/acp-20-12115-2020, 2020
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We analyzed the characteristics and sources of HONO in the upper boundary layer and lower free troposphere in the North China Plain, based on the field measurements at Mount Tai. Higher-than-expected levels and broad daytime peaks of HONO were observed. Without presence of ground surfaces, aerosol surface plays a key role in the heterogeneous HONO formation at high altitudes. Models without additional HONO sources largely
underestimatedthe oxidation processes in the elevation atmospheres.
Hwajin Kim, Qi Zhang, and Yele Sun
Atmos. Chem. Phys., 20, 11527–11550, https://doi.org/10.5194/acp-20-11527-2020, https://doi.org/10.5194/acp-20-11527-2020, 2020
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Severe spring haze and influences of long-range transport in the Seoul metropolitan area (SMA) in March 2019 were investigated. Simultaneous downwind (SMA) and upwind (Beijing) measurements using AMS and ACSM over the same period showed that PM species can be transported in approximately 2 d. Nitrate was the most responsible, and sulfate and two regional-transport-influenced SOAs also contributed. Enhancement of Pb also showed that the haze in the SMA was influenced by the regional transport.
Baozhu Ge, Syuichi Itahashi, Keiichi Sato, Danhui Xu, Junhua Wang, Fan Fan, Qixin Tan, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Jung-Hun Woo, Junichi Kurokawa, Yuepeng Pan, Qizhong Wu, Xuejun Liu, and Zifa Wang
Atmos. Chem. Phys., 20, 10587–10610, https://doi.org/10.5194/acp-20-10587-2020, https://doi.org/10.5194/acp-20-10587-2020, 2020
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Performances of the simulated deposition for different reduced N (Nr) species in China were conducted with the Model Inter-Comparison Study for Asia. Results showed that simulated wet deposition of oxidized N was overestimated in northeastern China and underestimated in south China, but Nr was underpredicted in all regions by all models. Oxidized N has larger uncertainties than Nr, indicating that the chemical reaction process is one of the most importance factors affecting model performance.
Wei Hu, Kotaro Murata, Chunlan Fan, Shu Huang, Hiromi Matsusaki, Pingqing Fu, and Daizhou Zhang
Biogeosciences, 17, 4477–4487, https://doi.org/10.5194/bg-17-4477-2020, https://doi.org/10.5194/bg-17-4477-2020, 2020
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This paper reports the first estimate of the status of bacteria in long-distance-transported Asian dust, demonstrating that airborne dust, which can carry viable and nonviable bacteria on particle surfaces, is an efficient medium for constantly spreading bacteria at regional and even global scales. Such data are essential to better model and understand the roles and activities of bioaerosols in environmental evolution and climate change and the potential risks of bioaerosols to human health.
Wanyu Zhao, Hong Ren, Kimitaka Kawamura, Huiyun Du, Xueshun Chen, Siyao Yue, Qiaorong Xie, Lianfang Wei, Ping Li, Xin Zeng, Shaofei Kong, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 10331–10350, https://doi.org/10.5194/acp-20-10331-2020, https://doi.org/10.5194/acp-20-10331-2020, 2020
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Our observations provide detailed information on the abundance and vertical distribution of dicarboxylic acids, oxoacids and α-dicarbonyls in PM2.5 collected at three heights based on a 325 m meteorological tower in Beijing in summer. Our results demonstrate that organic acids at the ground surface are largely associated with local traffic emissions, while long-range atmospheric transport followed by photochemical ageing contributes more in the urban boundary layer than the ground surface.
Yuwei Wang, Archit Mehra, Jordan E. Krechmer, Gan Yang, Xiaoyu Hu, Yiqun Lu, Andrew Lambe, Manjula Canagaratna, Jianmin Chen, Douglas Worsnop, Hugh Coe, and Lin Wang
Atmos. Chem. Phys., 20, 9563–9579, https://doi.org/10.5194/acp-20-9563-2020, https://doi.org/10.5194/acp-20-9563-2020, 2020
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A series of OH-initiated oxidation experiments of trimethylbenzene were investigated in the absence and presence of NOx. Many C9 products with 1–11 oxygen atoms and C18 products presumably formed from dimerization of C9 peroxy radicals were observed, hinting at the extensive existence of autoxidation and accretion reaction pathways. The presence of NOx would suppress the formation of highly oxygenated C18 molecules and enhance the formation of organonitrates and even dinitrate compounds.
Yang Chen, Jing Cai, Zhichao Wang, Chao Peng, Xiaojiang Yao, Mi Tian, Yiqun Han, Guangming Shi, Zongbo Shi, Yue Liu, Xi Yang, Mei Zheng, Tong Zhu, Kebin He, Qiang Zhang, and Fumo Yang
Atmos. Chem. Phys., 20, 9231–9247, https://doi.org/10.5194/acp-20-9231-2020, https://doi.org/10.5194/acp-20-9231-2020, 2020
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Patterns of particle transport, accumulation, and evolution in both urban and rural areas of Beijing are investigated. The two sites shared 17 common particle types in different stages of atmospheric processing.
Yang Chen, Guangming Shi, Jing Cai, Zongbo Shi, Zhichao Wang, Xiaojiang Yao, Mi Tian, Chao Peng, Yiqun Han, Tong Zhu, Yue Liu, Xi Yang, Mei Zheng, Fumo Yang, Qiang Zhang, and Kebin He
Atmos. Chem. Phys., 20, 9249–9263, https://doi.org/10.5194/acp-20-9249-2020, https://doi.org/10.5194/acp-20-9249-2020, 2020
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Individual particles were observed in two field studies during winter 2016 in the urban and rural areas of Beijing. An online single-particle chemical composition analysis was used as a tracing system to investigate the impact of heating activities and the formation of haze events. During the pollution events, a pattern of transport and accumulation was found with evidence of single particles. The transport from Pinggu to Peking University was significant but PKU to PG occurred occasionally.
Shengqiang Zhu, Lei Li, Shurong Wang, Mei Li, Yaxi Liu, Xiaohui Lu, Hong Chen, Lin Wang, Jianmin Chen, Zhen Zhou, Xin Yang, and Xiaofei Wang
Atmos. Meas. Tech., 13, 4111–4121, https://doi.org/10.5194/amt-13-4111-2020, https://doi.org/10.5194/amt-13-4111-2020, 2020
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Single-particle aerosol mass spectrometry (SPAMS) is widely used to detect chemical compositions and sizes of individual aerosol particles. However, it has a major issue: the mass accuracy of high-resolution SPAMS is relatively low. Here we developed an automatic linear calibration method to greatly improve the mass accuracy of SPAMS spectra so that the elemental compositions of organic peaks, such as Cx, CxHy, CxHyOz and CxHyNO peaks, can be directly identified just based on their m / z values.
Freya A. Squires, Eiko Nemitz, Ben Langford, Oliver Wild, Will S. Drysdale, W. Joe F. Acton, Pingqing Fu, C. Sue B. Grimmond, Jacqueline F. Hamilton, C. Nicholas Hewitt, Michael Hollaway, Simone Kotthaus, James Lee, Stefan Metzger, Natchaya Pingintha-Durden, Marvin Shaw, Adam R. Vaughan, Xinming Wang, Ruili Wu, Qiang Zhang, and Yanli Zhang
Atmos. Chem. Phys., 20, 8737–8761, https://doi.org/10.5194/acp-20-8737-2020, https://doi.org/10.5194/acp-20-8737-2020, 2020
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Significant air quality problems exist in megacities like Beijing, China. To manage air pollution, legislators need a clear understanding of pollutant emissions. However, emissions inventories have large uncertainties, and reliable field measurements of pollutant emissions are required to constrain them. This work presents the first measurements of traffic-dominated emissions in Beijing which suggest that inventories overestimate these emissions in the region during both winter and summer.
Junchen Guo, Shengzhen Zhou, Mingfu Cai, Jun Zhao, Wei Song, Weixiong Zhao, Weiwei Hu, Yele Sun, Yao He, Chengqiang Yang, Xuezhe Xu, Zhisheng Zhang, Peng Cheng, Qi Fan, Jian Hang, Shaojia Fan, Xinming Wang, and Xuemei Wang
Atmos. Chem. Phys., 20, 7595–7615, https://doi.org/10.5194/acp-20-7595-2020, https://doi.org/10.5194/acp-20-7595-2020, 2020
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We characterized non-refractory submicron particulate matter (PM1.0) during winter in Guangzhou, south China. Chemical composition and key sources of ambient PM1.0 are revealed, highlighting the significant role of SOA. The relationship with SOA and peroxy radicals indicated gas-phase oxidation contributed predominantly to SOA formation during non-pollution periods, while heterogeneous/multiphase reactions played more important roles in SOA formation during pollution periods.
Jiani Tan, Joshua S. Fu, Gregory R. Carmichael, Syuichi Itahashi, Zhining Tao, Kan Huang, Xinyi Dong, Kazuyo Yamaji, Tatsuya Nagashima, Xuemei Wang, Yiming Liu, Hyo-Jung Lee, Chuan-Yao Lin, Baozhu Ge, Mizuo Kajino, Jia Zhu, Meigen Zhang, Hong Liao, and Zifa Wang
Atmos. Chem. Phys., 20, 7393–7410, https://doi.org/10.5194/acp-20-7393-2020, https://doi.org/10.5194/acp-20-7393-2020, 2020
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This study evaluated the performance of 12 chemical transport models from MICS-Asia III for predicting the particulate matter (PM) over East Asia. Four model processes were investigated as the possible reasons for model bias with measurements and the factors causing inconsistent predictions of PM from different models: (1) model inputs, (2) gas–particle conversion, (3) dust emission modules and (4) removal mechanisms (wet and dry depositions). The influence of each process was discussed.
Jingyi Li, Haowen Zhang, Qi Ying, Zhijun Wu, Yanli Zhang, Xinming Wang, Xinghua Li, Yele Sun, Min Hu, Yuanhang Zhang, and Jianlin Hu
Atmos. Chem. Phys., 20, 7291–7306, https://doi.org/10.5194/acp-20-7291-2020, https://doi.org/10.5194/acp-20-7291-2020, 2020
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Large gaps still exist in modeled and observed secondary organic aerosol (SOA) mass loading and properties. Here we investigated the impacts of water partitioning into organic aerosol and nonideality of the organic–water mixture on SOA over eastern China using a regional 3D model. SOA is increased more significantly in humid and hot environments. Increases in SOA further cause an enhancement of the cooling effects of aerosols. It is crucial to consider the above processes in modeling SOA.
Jian Xu, Jia Chen, Na Zhao, Guochen Wang, Guangyuan Yu, Hao Li, Juntao Huo, Yanfen Lin, Qingyan Fu, Hongyu Guo, Congrui Deng, Shan-Hu Lee, Jianmin Chen, and Kan Huang
Atmos. Chem. Phys., 20, 7259–7269, https://doi.org/10.5194/acp-20-7259-2020, https://doi.org/10.5194/acp-20-7259-2020, 2020
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This study provided evidence that gas-particle partitioning of ammonia, as opposed to ammonia concentration, plays a critical role in the haze formation. A reduction in ammonia emissions alone may not reduce air pollution effectively, at least at rural agricultural sites in China.
Weiqi Xu, Yao He, Yanmei Qiu, Chun Chen, Conghui Xie, Lu Lei, Zhijie Li, Jiaxing Sun, Junyao Li, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Meas. Tech., 13, 3205–3219, https://doi.org/10.5194/amt-13-3205-2020, https://doi.org/10.5194/amt-13-3205-2020, 2020
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We characterized mass spectral features of organic aerosol (OA) and water-soluble OA (WSOA) from 21 cooking, crop straw, wood, and coal burning experiments using aerosol mass spectrometers with standard and capture vaporizers, and we demonstrated the applications of source spectral profiles in improving source apportionment of ambient OA at a highly polluted rural site in the North China Plain in winter.
Tianshu Chen, Likun Xue, Penggang Zheng, Yingnan Zhang, Yuhong Liu, Jingjing Sun, Guangxuan Han, Hongyong Li, Xin Zhang, Yunfeng Li, Hong Li, Can Dong, Fei Xu, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 20, 7069–7086, https://doi.org/10.5194/acp-20-7069-2020, https://doi.org/10.5194/acp-20-7069-2020, 2020
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Oil production is a significant source of ambient VOCs, but its impact on air quality has long been overlooked in China. We addressed this gap by conducting field campaigns in an oil field region followed by chemical modeling analyses. The VOC speciation profiles from the oil field emissions were directly measured for the first time in China. This study emphasizes the importance of oil extraction to photochemical pollution and atmospheric chemistry in the oil production regions of China.
Manuela van Pinxteren, Khanneh Wadinga Fomba, Nadja Triesch, Christian Stolle, Oliver Wurl, Enno Bahlmann, Xianda Gong, Jens Voigtländer, Heike Wex, Tiera-Brandy Robinson, Stefan Barthel, Sebastian Zeppenfeld, Erik Hans Hoffmann, Marie Roveretto, Chunlin Li, Benoit Grosselin, Veronique Daële, Fabian Senf, Dominik van Pinxteren, Malena Manzi, Nicolás Zabalegui, Sanja Frka, Blaženka Gašparović, Ryan Pereira, Tao Li, Liang Wen, Jiarong Li, Chao Zhu, Hui Chen, Jianmin Chen, Björn Fiedler, Wolf von Tümpling, Katie Alana Read, Shalini Punjabi, Alastair Charles Lewis, James Roland Hopkins, Lucy Jane Carpenter, Ilka Peeken, Tim Rixen, Detlef Schulz-Bull, María Eugenia Monge, Abdelwahid Mellouki, Christian George, Frank Stratmann, and Hartmut Herrmann
Atmos. Chem. Phys., 20, 6921–6951, https://doi.org/10.5194/acp-20-6921-2020, https://doi.org/10.5194/acp-20-6921-2020, 2020
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An introduction to a comprehensive field campaign performed at the Cape Verde Atmospheric Observatory regarding ocean–atmosphere interactions is given. Chemical, physical, biological and meteorological techniques were applied, and measurements of bulk water, the sea surface microlayer, cloud water and ambient aerosol particles took place. Oceanic compounds were found to be transferred to atmospheric aerosol and to the cloud level; however, sea spray contributions to CCN and INPs were limited.
Jing Yang, Wanyu Zhao, Lianfang Wei, Qiang Zhang, Yue Zhao, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 20, 6841–6860, https://doi.org/10.5194/acp-20-6841-2020, https://doi.org/10.5194/acp-20-6841-2020, 2020
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Our observations provide novel detailed information on the atmospheric abundances and spatial distributions of dicarboxylic acids, oxoacids, and α-dicarbonyls in marine aerosols collected from the South China Sea to the East Indian Ocean. Our results demonstrate that the continental outflow of both biogenic and anthropogenic precursors followed by photochemical aging is one of the main sources and formation processes of marine organic aerosols over the tropical oceanic regions.
Qiaorong Xie, Sihui Su, Shuang Chen, Yisheng Xu, Dong Cao, Jing Chen, Lujie Ren, Siyao Yue, Wanyu Zhao, Yele Sun, Zifa Wang, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, Guibin Jiang, Cong-Qiang Liu, and Pingqing Fu
Atmos. Chem. Phys., 20, 6803–6820, https://doi.org/10.5194/acp-20-6803-2020, https://doi.org/10.5194/acp-20-6803-2020, 2020
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Current knowledge on firework-related organic aerosols is very limited. Here the detailed molecular composition of organics in urban aerosols was characterized using ultrahigh-resolution FT-ICR mass spectrometry. Our findings highlight that firework emission leads to a sharp increase in CHO, CHNO, and CHOS containing high-molecular-weight species, particularly aromatic-like substances, which affect the physicochemical properties such as the light absorption and health effects of urban aerosols.
Yanhong Zhu, Andreas Tilgner, Erik Hans Hoffmann, Hartmut Herrmann, Kimitaka Kawamura, Lingxiao Yang, Likun Xue, and Wenxing Wang
Atmos. Chem. Phys., 20, 6725–6747, https://doi.org/10.5194/acp-20-6725-2020, https://doi.org/10.5194/acp-20-6725-2020, 2020
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The formation and processing of secondary inorganic and organic compounds at Mt. Tai, the highest mountain on the North China Plain, are modeled using a multiphase chemical model. The concentrations of key radical and non-radical oxidations in the formation processes are investigated. Sensitivity tests assess the impacts of emission data and glyoxal partitioning constants on modeled results. The key precursors of secondary organic compounds are also identified.
Shengzhen Zhou, Luolin Wu, Junchen Guo, Weihua Chen, Xuemei Wang, Jun Zhao, Yafang Cheng, Zuzhao Huang, Jinpu Zhang, Yele Sun, Pingqing Fu, Shiguo Jia, Jun Tao, Yanning Chen, and Junxia Kuang
Atmos. Chem. Phys., 20, 6435–6453, https://doi.org/10.5194/acp-20-6435-2020, https://doi.org/10.5194/acp-20-6435-2020, 2020
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In this work, measurements of size-segregated aerosols were conducted at three altitudes (ground level, 118 m, and 488 m) on the 610 m high Canton Tower in southern China. Vertical variations of PM and size-segregated chemical compositions were investigated. The results indicated that meteorological parameters and atmospheric aqueous and heterogeneous reactions together led to aerosol formation and haze episodes in the Pearl River Delta region during the measurement periods.
Xinning Wang, Xingnan Ye, Jianmin Chen, Xiaofei Wang, Xin Yang, Tzung-May Fu, Lei Zhu, and Chongxuan Liu
Atmos. Chem. Phys., 20, 6273–6290, https://doi.org/10.5194/acp-20-6273-2020, https://doi.org/10.5194/acp-20-6273-2020, 2020
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Hygroscopicity plays several key roles in determining aerosol optical properties and aging processes in the atmosphere. However, it is quite difficult to study aerosol hygroscopicity at the single-particle level. In this study, we built a comprehensive database linking hygroscopicities and mass spectra of individual particles. Based on the measured hygroscopicity–composition relations, we developed a statistical method to estimate ambient particle hygroscopicity just from their mass spectra.
Yucong Miao, Huizheng Che, Xiaoye Zhang, and Shuhua Liu
Atmos. Chem. Phys., 20, 5899–5909, https://doi.org/10.5194/acp-20-5899-2020, https://doi.org/10.5194/acp-20-5899-2020, 2020
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By combining long-term observational data analyses, synoptic classifications, and meteorology–chemistry coupled simulations, the complicated impacts of large-scale synoptic forcing and local boundary layer processes on the aerosol pollution in the Beijing–Tianjin–Hebei region have been investigated. The influences of the aerosol radiative effect on boundary layer structure and pollution were also examined. This study has important implications for better understanding pollution in China.
Hang Liu, Xiaole Pan, Dantong Liu, Xiaoyong Liu, Xueshun Chen, Yu Tian, Yele Sun, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 20, 5771–5785, https://doi.org/10.5194/acp-20-5771-2020, https://doi.org/10.5194/acp-20-5771-2020, 2020
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The bare black carbon (BC) was in a fractal structure. With coating thickness increasing, BC changed from a fractal structure to a core–shell structure. In the ambient atmosphere, plenty of BC particles were not in a perfect core–shell structure. This study brought attention to the combined effects of morphology and coating thickness on the absorption enhancement of BC-containing particles, which is helpful for determining the climatic effects of BC.
Jian Zhang, Lei Liu, Liang Xu, Qiuhan Lin, Hujia Zhao, Zhibin Wang, Song Guo, Min Hu, Dantong Liu, Zongbo Shi, Dao Huang, and Weijun Li
Atmos. Chem. Phys., 20, 5355–5372, https://doi.org/10.5194/acp-20-5355-2020, https://doi.org/10.5194/acp-20-5355-2020, 2020
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Northeast China faces severe air pollution in regional haze in wintertime. In this study, we revealed a contrasting formation mechanism of two typical haze events: Haze-I was induced by adverse meteorological conditions together with residential coal burning emissions; Haze-II was caused by agricultural biomass waste burning. In particular, we observed large numbers of tar balls as the primary brown carbon in northeast China.
Fanhao Meng, Min Qin, Ke Tang, Jun Duan, Wu Fang, Shuaixi Liang, Kaidi Ye, Pinhua Xie, Yele Sun, Conghui Xie, Chunxiang Ye, Pingqing Fu, Jianguo Liu, and Wenqing Liu
Atmos. Chem. Phys., 20, 5071–5092, https://doi.org/10.5194/acp-20-5071-2020, https://doi.org/10.5194/acp-20-5071-2020, 2020
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Nitrous acid (HONO), a major precursor of the OH radical, plays a key role in atmospheric chemistry, but its sources are still debated. The first high-resolution vertical measurements of HONO and NO2 were conducted in Beijing to investigate the nocturnal sources of HONO at different stages of pollution. The ground surface dominated HONO production by heterogeneous conversion of NO2 during clean episodes, but the aerosol production was an important nighttime HONO source during haze episodes.
Yuning Xie, Gehui Wang, Xinpei Wang, Jianmin Chen, Yubao Chen, Guiqian Tang, Lili Wang, Shuangshuang Ge, Guoyan Xue, Yuesi Wang, and Jian Gao
Atmos. Chem. Phys., 20, 5019–5033, https://doi.org/10.5194/acp-20-5019-2020, https://doi.org/10.5194/acp-20-5019-2020, 2020
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As a result of strict emission control, nitrate-dominated PM2.5 in pollution episodes was observed in urban Beijing during the winter of 2017–2018. With the help of sufficient ammonia, particle pH could increase to near neutral (5.4) as particulate nitrate fraction increases. Further tests imply that airborne particle hygroscopicity would be enhanced at moderate RH in nitrate-dominated particles, and pH elevation will be accelerated when ammonia and particulate nitrate both increase.
Chuan Yu, Zhe Wang, Men Xia, Xiao Fu, Weihao Wang, Yee Jun Tham, Tianshu Chen, Penggang Zheng, Hongyong Li, Ye Shan, Xinfeng Wang, Likun Xue, Yan Zhou, Dingli Yue, Yubo Ou, Jian Gao, Keding Lu, Steven S. Brown, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 20, 4367–4378, https://doi.org/10.5194/acp-20-4367-2020, https://doi.org/10.5194/acp-20-4367-2020, 2020
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This study provides a holistic picture of N2O5 heterogeneous uptake on ambient aerosols and the influencing factors under various climatic and chemical conditions in China, and it proposes an observation-based empirical parameterization. The empirical parameterization can be used in air quality models to improve the prediction of PM2.5 and photochemical pollution in China and similar polluted regions of the world.
Chenjie Yu, Dantong Liu, Kurtis Broda, Rutambhara Joshi, Jason Olfert, Yele Sun, Pingqing Fu, Hugh Coe, and James D. Allan
Atmos. Chem. Phys., 20, 3645–3661, https://doi.org/10.5194/acp-20-3645-2020, https://doi.org/10.5194/acp-20-3645-2020, 2020
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This study presents the first atmospheric application of a new morphology-independent measurement for the quantification of the mixing state of rBC-containing particles in urban Beijing as part of the UK–China APHH campaign. An inversion method has been applied for better quantification of rBC mixing state. The mass-resolved rBC mixing state information presented here has implications for detailed models of BC, its optical properties and its atmospheric life cycle.
Shaofeng Xu, Lujie Ren, Yunchao Lang, Shengjie Hou, Hong Ren, Lianfang Wei, Libin Wu, Junjun Deng, Wei Hu, Xiaole Pan, Yele Sun, Zifa Wang, Hang Su, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 20, 3623–3644, https://doi.org/10.5194/acp-20-3623-2020, https://doi.org/10.5194/acp-20-3623-2020, 2020
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Current knowledge on the size distribution of biogenic primary organic aerosols in urban regions with heavy haze pollution is very limited. Here we performed a year-round study focusing on the organic molecular composition of size-segregated aerosol samples collected in urban Beijing during haze and non-haze days to elucidate the seasonal contributions of biomass burning, fungal spores, and plant debris to organic carbon as well as the influences from local emissions and long-range transport.
Leigh R. Crilley, Ajit Singh, Louisa J. Kramer, Marvin D. Shaw, Mohammed S. Alam, Joshua S. Apte, William J. Bloss, Lea Hildebrandt Ruiz, Pingqing Fu, Weiqi Fu, Shahzad Gani, Michael Gatari, Evgenia Ilyinskaya, Alastair C. Lewis, David Ng'ang'a, Yele Sun, Rachel C. W. Whitty, Siyao Yue, Stuart Young, and Francis D. Pope
Atmos. Meas. Tech., 13, 1181–1193, https://doi.org/10.5194/amt-13-1181-2020, https://doi.org/10.5194/amt-13-1181-2020, 2020
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There is considerable interest in using low-cost optical particle counters (OPCs) for particle mass measurements; however, there is no agreed upon method with respect to calibration. Here we exploit a number of datasets globally to demonstrate that particle composition and relative humidity are the key factors affecting measured concentrations from a low-cost OPC, and we present a simple correction methodology that corrects for this influence.
Lu Lei, Conghui Xie, Dawei Wang, Yao He, Qingqing Wang, Wei Zhou, Wei Hu, Pingqing Fu, Yong Chen, Xiaole Pan, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 20, 2877–2890, https://doi.org/10.5194/acp-20-2877-2020, https://doi.org/10.5194/acp-20-2877-2020, 2020
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We characterized aerosol composition and sources near two steel plants in a coastal region in fall and spring seasons. Our results showed substantially different aerosol composition and sources between the two seasons. We observed significant impacts of steel plant emissions on aerosol chemistry nearby, and we found that aerosol particles emitted from the steel plants were dominated by ammonium sulfate/bisulfate; NOx/CO and NOx/SO2 were distinct from those in the absence of industrial plumes.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Junichi Kurokawa, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 20, 2667–2693, https://doi.org/10.5194/acp-20-2667-2020, https://doi.org/10.5194/acp-20-2667-2020, 2020
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This study gives an overview of acid deposition from the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Wet deposition simulated by a total of nine models is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The total deposition maps comparing to emissions over Asia are presented. To seek a way to improve the model performance, ensemble approaches and the precipitation-adjusted method are discussed.
Zhining Tao, Mian Chin, Meng Gao, Tom Kucsera, Dongchul Kim, Huisheng Bian, Jun-ichi Kurokawa, Yuesi Wang, Zirui Liu, Gregory R. Carmichael, Zifa Wang, and Hajime Akimoto
Atmos. Chem. Phys., 20, 2319–2339, https://doi.org/10.5194/acp-20-2319-2020, https://doi.org/10.5194/acp-20-2319-2020, 2020
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One goal of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III is to identify strengths and weaknesses of current air quality models to provide insights into reducing uncertainties. This study identified that a 15 km grid would be the optimal horizontal resolution in terms of performance and resource usage to capture average and extreme air quality over East Asia and is thus suggested for use in future MICS-Asia modeling activities if the investigation domain remains the same.
Can Wu, Gehui Wang, Jin Li, Jianjun Li, Cong Cao, Shuangshuang Ge, Yuning Xie, Jianmin Chen, Xingru Li, Guoyan Xue, Xinpei Wang, Zhuyu Zhao, and Fang Cao
Atmos. Chem. Phys., 20, 2017–2030, https://doi.org/10.5194/acp-20-2017-2020, https://doi.org/10.5194/acp-20-2017-2020, 2020
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Brown carbon (BrC), as an important component of aerosol, has attracted wide attention in recent years, yet very limited information on size differences is available. This paper reveals that BrC presented a bimodal pattern and was mainly derived from biomass burning in an interior city of China. Our results are very helpful for readers to comprehensively understand the features of brown carbon in China.
Meng Gao, Zirui Liu, Bo Zheng, Dongsheng Ji, Peter Sherman, Shaojie Song, Jinyuan Xin, Cheng Liu, Yuesi Wang, Qiang Zhang, Jia Xing, Jingkun Jiang, Zifa Wang, Gregory R. Carmichael, and Michael B. McElroy
Atmos. Chem. Phys., 20, 1497–1505, https://doi.org/10.5194/acp-20-1497-2020, https://doi.org/10.5194/acp-20-1497-2020, 2020
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We quantified the relative influences of anthropogenic emissions and meteorological conditions on PM2.5 concentrations in Beijing over the winters of 2002–2016. Meteorological conditions over the study period would have led to an increase of haze in Beijing, but the strict emission control measures have suppressed the unfavorable influences of the recent climate.
Fan Zhang, Hai Guo, Yingjun Chen, Volker Matthias, Yan Zhang, Xin Yang, and Jianmin Chen
Atmos. Chem. Phys., 20, 1549–1564, https://doi.org/10.5194/acp-20-1549-2020, https://doi.org/10.5194/acp-20-1549-2020, 2020
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Particulate matter (PM) emitted from ships has gained more attention in recent decades. Organic matter, elemental carbon, water-soluble ions and heavy metals in PM and particle numbers are the main points. However, studies of detailed chemical compositions in particles with different size ranges emitted from ships are in shortage. This study could bring new and detailed measurement data into the field of size-segregated particles from ships and be of great source emission interest.
Linlin Liang, Guenter Engling, Chang Liu, Wanyun Xu, Xuyan Liu, Yuan Cheng, Zhenyu Du, Gen Zhang, Junying Sun, and Xiaoye Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-19, https://doi.org/10.5194/acp-2020-19, 2020
Revised manuscript not accepted
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Our study captured an episode with extreme biomass burning tracer level at an agricultural site in North China, with concentrations of levoglucosan as high as 4.37 μg m−3. Based on comparison of the chemical composition between different biomass burning periods, it appeared that biomass burning can obviously elevate the levels of organic components, but seems to have no significant effect on the production of secondary inorganic ions, although their precursors increased during the episode.
Meng Gao, Zhiwei Han, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Meng Li, Jung-Hun Woo, Qiang Zhang, Yafang Cheng, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 1147–1161, https://doi.org/10.5194/acp-20-1147-2020, https://doi.org/10.5194/acp-20-1147-2020, 2020
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Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative feedbacks. This paper discusses the estimates of aerosol radiative forcing, aerosol feedbacks, and possible causes for the differences among the models.
Xinxin Fan, Jieyao Liu, Fang Zhang, Lu Chen, Don Collins, Weiqi Xu, Xiaoai Jin, Jingye Ren, Yuying Wang, Hao Wu, Shangze Li, Yele Sun, and Zhanqing Li
Atmos. Chem. Phys., 20, 915–929, https://doi.org/10.5194/acp-20-915-2020, https://doi.org/10.5194/acp-20-915-2020, 2020
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Aerosol effects on visibility and climate are influenced by their hygroscopicity. By contrasting data from two techniques between summer and winter in Beijing, we investigate the effect of aerosol aging, mixing state, and local sources on its hygroscopicity. We revealed that inappropriate use of the density of BC and organics results in large uncertainty in calculating aerosols hygroscopicity. Our results are helpful for parameterization in models.
Xiaoai Jin, Yuying Wang, Zhanqing Li, Fang Zhang, Weiqi Xu, Yele Sun, Xinxin Fan, Guangyu Chen, Hao Wu, Jingye Ren, Qiuyan Wang, and Maureen Cribb
Atmos. Chem. Phys., 20, 901–914, https://doi.org/10.5194/acp-20-901-2020, https://doi.org/10.5194/acp-20-901-2020, 2020
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In this study the aerosol liquid water content (ALWC) is determined from aerosol hygroscopic growth factor (GF) measurement (ALWCHTDMA) and also simulated by the ISORROPIA II thermodynamic model (ALWCISO). We found that ALWC contributed by organics (ALWCOrg) accounts for 30 % ± 22 % of the total ALWC in winter in Beijing. A case study reveals that ALWCOrg plays an important role in the formation of secondary aerosols through multiphase reactions at the initial stage of a heavy-haze episode.
Ye Kuang, Yao He, Wanyun Xu, Pusheng Zhao, Yafang Cheng, Gang Zhao, Jiangchuan Tao, Nan Ma, Hang Su, Yanyan Zhang, Jiayin Sun, Peng Cheng, Wenda Yang, Shaobin Zhang, Cheng Wu, Yele Sun, and Chunsheng Zhao
Atmos. Chem. Phys., 20, 865–880, https://doi.org/10.5194/acp-20-865-2020, https://doi.org/10.5194/acp-20-865-2020, 2020
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A new method was developed to calculate hygroscopicity parameter κ of organic aerosols (κOA) based on aerosol light-scattering measurements and bulk aerosol chemical-composition measurements. Derived high-time-resolution κOA varied in a wide range (near 0 to 0.25), and the organic aerosol oxidation degree significantly impacts variations in κOA. Distinct diurnal variation in κOA is found, and its relationship with oxygenated organic aerosol is discussed.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Joshua S. Fu, Xuemei Wang, Syuichi Itahashi, Kazuyo Yamaji, Tatsuya Nagashima, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Lei Chen, Meigen Zhang, Zhining Tao, Jie Li, Mizuo Kajino, Hong Liao, Zhe Wang, Kengo Sudo, Yuesi Wang, Yuepeng Pan, Guiqian Tang, Meng Li, Qizhong Wu, Baozhu Ge, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 181–202, https://doi.org/10.5194/acp-20-181-2020, https://doi.org/10.5194/acp-20-181-2020, 2020
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Evaluation and uncertainty investigation of NO2, CO and NH3 modeling over China were conducted in this study using 14 chemical transport model results from MICS-Asia III. All models largely underestimated CO concentrations and showed very poor performance in reproducing the observed monthly variations of NH3 concentrations. Potential factors related to such deficiencies are investigated and discussed in this paper.
Yanbing Fan, Cong-Qiang Liu, Linjie Li, Lujie Ren, Hong Ren, Zhimin Zhang, Qinkai Li, Shuang Wang, Wei Hu, Junjun Deng, Libin Wu, Shujun Zhong, Yue Zhao, Chandra Mouli Pavuluri, Xiaodong Li, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, Zongbo Shi, and Pingqing Fu
Atmos. Chem. Phys., 20, 117–137, https://doi.org/10.5194/acp-20-117-2020, https://doi.org/10.5194/acp-20-117-2020, 2020
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This study provides useful knowledge on the abundance, sources, and formation processes of organic aerosols in the coastal megacity of Tianjin, North China, based on the investigation of the molecular composition, diurnal variation, and winter/summer differences under the influence of land/sea breezes and the Asian summer monsoon.
Danhui Xu, Baozhu Ge, Xueshun Chen, Yele Sun, Nianliang Cheng, Mei Li, Xiaole Pan, Zhiqiang Ma, Yuepeng Pan, and Zifa Wang
Atmos. Chem. Phys., 19, 15569–15581, https://doi.org/10.5194/acp-19-15569-2019, https://doi.org/10.5194/acp-19-15569-2019, 2019
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Wet deposition is one of the most important and efficient removal mechanisms in the evolution of the air pollution. Due to the lack of a localized parameterization scheme and some mechanisms being neglected in theoretical estimations and modeling calculations, below-cloud wet scavenging coefficients (BWSC) have large uncertainties. We compare the BWSCs under the same conditions to perform a multi-method evaluation in order to describe their characteristics.
Hang Liu, Xiaole Pan, Yu Wu, Dawei Wang, Yu Tian, Xiaoyong Liu, Lu Lei, Yele Sun, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 19, 14791–14804, https://doi.org/10.5194/acp-19-14791-2019, https://doi.org/10.5194/acp-19-14791-2019, 2019
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The relationship among the effective density, rBC's coating thickness, and rBC's morphology was investigated. rBC with larger effective density adopted a more regular shape due to more coating thickness. The effective density distribution of ambient rBC was also measured. From the information of effective density, the ambient rBC mainly adopts an irregular shape, which can cause large uncertainties in the rBC's optical properties.
Min Cui, Cheng Li, Yingjun Chen, Fan Zhang, Jun Li, Bin Jiang, Yangzhi Mo, Jia Li, Caiqing Yan, Mei Zheng, Zhiyong Xie, Gan Zhang, and Junyu Zheng
Atmos. Chem. Phys., 19, 13945–13956, https://doi.org/10.5194/acp-19-13945-2019, https://doi.org/10.5194/acp-19-13945-2019, 2019
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Refined source apportionment is urgently needed but hard to achieve due to a lack of specific biomarkers. Recently, Fourier transform ion cyclotron resonance mass spectrometry has been used to analyse the probable chemical structure of polar organic matter emitted from off-road engines. We found more condensed aromatic rings in S-containing compounds for HFO-fueled vessels, while more abundant aliphatic chains were observed in emissions from diesel equipment.
Jie Li, Tatsuya Nagashima, Lei Kong, Baozhu Ge, Kazuyo Yamaji, Joshua S. Fu, Xuemei Wang, Qi Fan, Syuichi Itahashi, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Meigen Zhang, Zhining Tao, Mizuo Kajino, Hong Liao, Meng Li, Jung-Hun Woo, Jun-ichi Kurokawa, Zhe Wang, Qizhong Wu, Hajime Akimoto, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 19, 12993–13015, https://doi.org/10.5194/acp-19-12993-2019, https://doi.org/10.5194/acp-19-12993-2019, 2019
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This study evaluated and intercompared 14 CTMs with ozone observations in East Asia, within the framework of the Model Inter-Comparison Study for ASIA Phase III (MICS-Asia III). Potential causes of the discrepancies between model results and observation were investigated by assessing the planetary boundary layer heights, emission fluxes, dry deposition, chemistry and vertical transport among models. Finally, a multi-model estimate of pollution distributions was provided.
Renmin Yuan, Xiaoye Zhang, Hao Liu, Yu Gui, Bohao Shao, Xiaoping Tao, Yaqiang Wang, Junting Zhong, Yubin Li, and Zhiqiu Gao
Atmos. Chem. Phys., 19, 12857–12874, https://doi.org/10.5194/acp-19-12857-2019, https://doi.org/10.5194/acp-19-12857-2019, 2019
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To understand the contribution of ground emission during heavy pollution in Beijing, Tianjin and Hebei, aerosol fluxes were estimated in Beijing and Gucheng areas. The results show that in the three stages of a heavy pollution process (transport, accumulative and removal stages: TS, AS and RS), the ground emissions in the TS and RS stages are stronger, while the ground discharge in the AS stage is weak. The weakened mass flux indicates that the already weak turbulence would be further weakened.
Zhenzhen Wang, Tao Wang, Hongbo Fu, Liwu Zhang, Mingjin Tang, Christian George, Vicki H. Grassian, and Jianmin Chen
Atmos. Chem. Phys., 19, 12569–12585, https://doi.org/10.5194/acp-19-12569-2019, https://doi.org/10.5194/acp-19-12569-2019, 2019
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This study confirmed that SO2 uptake on mineral particles could be greatly enhanced during cloud processing. The large pH fluctuations between the cloud-aerosol modes could significantly modify the microphysical properties of particles, and triggered the formation of reactive Fe particles to accelerate sulfate formation via a self-amplifying process. Results of this study could partly explain the missing source of sulfate and improve agreement between models and field observations.
Yunhua Chang, Yan-Lin Zhang, Jiarong Li, Chongguo Tian, Linlin Song, Xiaoyao Zhai, Wenqi Zhang, Tong Huang, Yu-Chi Lin, Chao Zhu, Yunting Fang, Moritz F. Lehmann, and Jianmin Chen
Atmos. Chem. Phys., 19, 12221–12234, https://doi.org/10.5194/acp-19-12221-2019, https://doi.org/10.5194/acp-19-12221-2019, 2019
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The present work underscores the value of cloud water dissolved inorganic nitrogen isotopes as carriers of quantitative information on regional NOx and NH3 emissions. It sheds light on the origin and production pathways of nitrogenous species in clouds and emphasizes the importance of biomass-burning-derived nitrogenous species as cloud condensation nuclei in China’s troposphere. Moreover, it highlights the rapid evolution of NOx emissions in China.
Jun Zhang, Xinfeng Wang, Rui Li, Shuwei Dong, Yingnan Zhang, Penggang Zheng, Min Li, Tianshu Chen, Yuhong Liu, Likun Xue, Wei Nie, Aijun Ding, Mingjin Tang, Xuehua Zhou, Lin Du, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-757, https://doi.org/10.5194/acp-2019-757, 2019
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This study presents the concentrations, variation characteristics, and key influencing factors of particulate organic nitrates at four urban and rural sites in eastern China. The effects of anthropogenic activities (i.e. biomass burning and coal combustion) and meteorological conditions (in particular the humidity) on the secondary formation of organic nitrates have been investigated. The results highlight the greater role of SO2 in organic nitrate chemistry than previously assumed.
Lei Chen, Yi Gao, Meigen Zhang, Joshua S. Fu, Jia Zhu, Hong Liao, Jialin Li, Kan Huang, Baozhu Ge, Xuemei Wang, Yun Fat Lam, Chuan-Yao Lin, Syuichi Itahashi, Tatsuya Nagashima, Mizuo Kajino, Kazuyo Yamaji, Zifa Wang, and Jun-ichi Kurokawa
Atmos. Chem. Phys., 19, 11911–11937, https://doi.org/10.5194/acp-19-11911-2019, https://doi.org/10.5194/acp-19-11911-2019, 2019
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Simulated aerosol concentrations from 14 CTMs within the framework of MICS-Asia III are detailedly evaluated with an extensive set of measurements in East Asia. Similarities and differences among model performances are also analyzed. Although more considerable capacities for reproducing the aerosol concentrations and their variations are shown in current CTMs than those in MICS-Asia II, more efforts are needed to reduce diversities of simulated aerosol concentrations among air quality models.
Huizheng Che, Xiangao Xia, Hujia Zhao, Oleg Dubovik, Brent N. Holben, Philippe Goloub, Emilio Cuevas-Agulló, Victor Estelles, Yaqiang Wang, Jun Zhu, Bing Qi, Wei Gong, Honglong Yang, Renjian Zhang, Leiku Yang, Jing Chen, Hong Wang, Yu Zheng, Ke Gui, Xiaochun Zhang, and Xiaoye Zhang
Atmos. Chem. Phys., 19, 11843–11864, https://doi.org/10.5194/acp-19-11843-2019, https://doi.org/10.5194/acp-19-11843-2019, 2019
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A full-scale description of ground-based aerosol microphysical and optical properties over China is presented. Moreover, the results have also provided significant information about optical and radiative aerosol properties for different types of sites covering a broad expanse of China. The results have considerable value for ground-truthing satellite observations and validating aerosol models.
Xianyi Yang, Huizheng Che, Hitoshi Irie, Quanliang Chen, Ke Gui, Ying Cai, Yu Zheng, Linchang An, Hujia Zhao, Lei Li, Yuanxin Liang, Yaqiang Wang, Hong Wang, and Xiaoye Zhang
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-339, https://doi.org/10.5194/amt-2019-339, 2019
Preprint withdrawn
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This study assesses the performance of SKYNET in comparison to AERONET (Aerosol Robotic Network) for retrieving aerosol optical properties (AOPs) in Beijing, China. SKYNET data retrieved by SR-CEReS analysis package are used to analyze a serious pollution event in winter over Beijing. The AOPs under three weather conditions (clean, dusty, haze) in Beijing are discussed. Measurements from the SKYNET skyradiometer can be used to analyze the AOPs over Beijing reasonably.
Ruihe Lyu, Zongbo Shi, Mohammed Salim Alam, Xuefang Wu, Di Liu, Tuan V. Vu, Christopher Stark, Pingqing Fu, Yinchang Feng, and Roy M. Harrison
Atmos. Chem. Phys., 19, 10865–10881, https://doi.org/10.5194/acp-19-10865-2019, https://doi.org/10.5194/acp-19-10865-2019, 2019
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Severe pollution of the Beijing atmosphere is a frequent occurrence. The airborne particles which characterize the episodes of haze contain a wide range of chemical constituents but organic compounds make up a substantial proportion. In this study individual compounds are analysed under both haze and non-haze conditions, and the measurements are compared with samples collected in London, where the air pollution climate and sources are very different.
Huizheng Che, Ke Gui, Xiangao Xia, Yaqiang Wang, Brent N. Holben, Philippe Goloub, Emilio Cuevas-Agulló, Hong Wang, Yu Zheng, Hujia Zhao, and Xiaoye Zhang
Atmos. Chem. Phys., 19, 10497–10523, https://doi.org/10.5194/acp-19-10497-2019, https://doi.org/10.5194/acp-19-10497-2019, 2019
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A comprehensive assessment of the global and regional AOD trends over the past 37 years (1980–2016) is presented. AOD observations from both AERONET and CARSNET were used for the first time to assess the performance of the MERRA-2 AOD dataset on a global scale. Based on statistical models, we found the meteorological parameters explained a larger proportion of the regional AOD variability (20.4 %–2.8 %) when compared with emission factors (0 %%–56 %).
Hua Yu, Weijun Li, Yangmei Zhang, Peter Tunved, Manuel Dall'Osto, Xiaojing Shen, Junying Sun, Xiaoye Zhang, Jianchao Zhang, and Zongbo Shi
Atmos. Chem. Phys., 19, 10433–10446, https://doi.org/10.5194/acp-19-10433-2019, https://doi.org/10.5194/acp-19-10433-2019, 2019
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Interaction of anthropogenic particles with radiation and clouds plays an important role in Arctic climate change. The mixing state of different aerosols is a key parameter influencing such interactions. However, little is known of this parameter, preventing an accurate representation of this information in global models. Multi-microscopic techniques were used to find one general core–shell structure in which secondary sulfate particles were covered by organic coating in the Arctic atmosphere.
Weiqi Xu, Conghui Xie, Eleni Karnezi, Qi Zhang, Junfeng Wang, Spyros N. Pandis, Xinlei Ge, Jingwei Zhang, Junling An, Qingqing Wang, Jian Zhao, Wei Du, Yanmei Qiu, Wei Zhou, Yao He, Ying Li, Jie Li, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 19, 10205–10216, https://doi.org/10.5194/acp-19-10205-2019, https://doi.org/10.5194/acp-19-10205-2019, 2019
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We present the first aerosol volatility measurements in Beijing in summer using a thermodenuder coupled with aerosol mass spectrometers. Our results showed that organic aerosol (OA) comprised mainly semi-volatile organic compounds in summer, and the freshly oxidized secondary OA was the most volatile component. We also found quite different volatility distributions in black-carbon-containing primary and secondary OA, ambient OA, ambient secondary OA and the WRF-Chem model.
Siyang Li, Xiaotong Jiang, Marie Roveretto, Christian George, Ling Liu, Wei Jiang, Qingzhu Zhang, Wenxing Wang, Maofa Ge, and Lin Du
Atmos. Chem. Phys., 19, 9887–9902, https://doi.org/10.5194/acp-19-9887-2019, https://doi.org/10.5194/acp-19-9887-2019, 2019
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We stimulated the photochemical aging of organic film coated on aqueous aerosol in the presence of imidazole-2-carboxaldehyde, humic acid, an atmospheric PM2.5 sample, and a secondary organic aerosol sample from the lab. The unsaturated lipid mixed with photosensitizer under UV irradiation produced hydroperoxides, leading to surface area increase in organic film. Our results reveal the modification of organic film on aqueous aerosol has potential influence on the hygroscopic growth of droplets.
Michael Hollaway, Oliver Wild, Ting Yang, Yele Sun, Weiqi Xu, Conghui Xie, Lisa Whalley, Eloise Slater, Dwayne Heard, and Dantong Liu
Atmos. Chem. Phys., 19, 9699–9714, https://doi.org/10.5194/acp-19-9699-2019, https://doi.org/10.5194/acp-19-9699-2019, 2019
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This study, for the first time, uses combinations of aerosol and lidar data to drive an offline photolysis scheme. Absorbing species are shown to have the greatest impact on photolysis rate constants in the winter and scattering aerosol are shown to dominate responses in the summer. During haze episodes, aerosols are shown to produce a greater impact than cloud cover. The findings demonstrate the potential photochemical impacts of haze pollution in a highly polluted urban environment.
Huiyun Du, Jie Li, Xueshun Chen, Zifa Wang, Yele Sun, Pingqing Fu, Jianjun Li, Jian Gao, and Ying Wei
Atmos. Chem. Phys., 19, 9351–9370, https://doi.org/10.5194/acp-19-9351-2019, https://doi.org/10.5194/acp-19-9351-2019, 2019
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Regional transport and heterogeneous reactions play crucial roles in haze formation. Using a chemical transport model, we found that chemical transformation of SO2 along the transport pathway from source regions to Beijing was the major source of sulfate. Heterogeneous chemistry had a stronger effect under high humidity and high pollution levels. Aerosols underwent aging during transport which altered the aerosol size and the degree of aging.
Tabish Umar Ansari, Oliver Wild, Jie Li, Ting Yang, Weiqi Xu, Yele Sun, and Zifa Wang
Atmos. Chem. Phys., 19, 8651–8668, https://doi.org/10.5194/acp-19-8651-2019, https://doi.org/10.5194/acp-19-8651-2019, 2019
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We explore the effectiveness of short-term emission controls on haze events in Beijing in October–November 2014 with high-resolution model studies. The model captures observed hourly variation in key pollutants well, but representation of boundary layer processes remains a key constraint. The controls contributed to improved air quality in early November but would not have been sufficient had the meteorology been less favourable. We quantify the much more stringent controls needed in that case.
Xiaole Pan, Hang Liu, Yu Wu, Yu Tian, Yele Sun, Conghui Xie, Xiaoyong Liu, Tianhai Cheng, and Zifa Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-433, https://doi.org/10.5194/acp-2019-433, 2019
Revised manuscript not accepted
Ying Wei, Xueshun Chen, Huansheng Chen, Jie Li, Zifa Wang, Wenyi Yang, Baozhu Ge, Huiyun Du, Jianqi Hao, Wei Wang, Jianjun Li, Yele Sun, and Huili Huang
Atmos. Chem. Phys., 19, 8269–8296, https://doi.org/10.5194/acp-19-8269-2019, https://doi.org/10.5194/acp-19-8269-2019, 2019
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This study presents a full description and evaluation of a global–regional nested aerosol and atmospheric chemistry model (IAP-AACM). The simulation for 2014 is evaluated against model datasets and a range of observational datasets. The results show that IAP-AACM is within the range of other models, and reproduces both spatial and seasonal variation of trace gases and aerosols over most areas well. In future, we recommend improving the model's ability to capture high spatial variation of PM2.5.
Weijun Li, Lei Liu, Qi Yuan, Liang Xu, Yanhong Zhu, Bingbing Wang, Hua Yu, Xiaokun Ding, Jian Zhang, Dao Huang, Dantong Liu, Wei Hu, Daizhou Zhang, Pingqing Fu, Maosheng Yao, Min Hu, Xiaoye Zhang, and Zongbo Shi
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-539, https://doi.org/10.5194/acp-2019-539, 2019
Preprint withdrawn
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The real state of individual primary biological aerosol particles (PBAPs) derived from natural sources is under mystery, although many studies well evaluate the morphology, mixing state, and elemental composition of anthropogenic particles. It induces that some studies mislead some anthropogenic particles into biological particles through electron microscopy. Here we firstly estimate the full database of individual PBAPs through two microscopic instruments. The database is good for research.
Zongbo Shi, Tuan Vu, Simone Kotthaus, Roy M. Harrison, Sue Grimmond, Siyao Yue, Tong Zhu, James Lee, Yiqun Han, Matthias Demuzere, Rachel E. Dunmore, Lujie Ren, Di Liu, Yuanlin Wang, Oliver Wild, James Allan, W. Joe Acton, Janet Barlow, Benjamin Barratt, David Beddows, William J. Bloss, Giulia Calzolai, David Carruthers, David C. Carslaw, Queenie Chan, Lia Chatzidiakou, Yang Chen, Leigh Crilley, Hugh Coe, Tie Dai, Ruth Doherty, Fengkui Duan, Pingqing Fu, Baozhu Ge, Maofa Ge, Daobo Guan, Jacqueline F. Hamilton, Kebin He, Mathew Heal, Dwayne Heard, C. Nicholas Hewitt, Michael Hollaway, Min Hu, Dongsheng Ji, Xujiang Jiang, Rod Jones, Markus Kalberer, Frank J. Kelly, Louisa Kramer, Ben Langford, Chun Lin, Alastair C. Lewis, Jie Li, Weijun Li, Huan Liu, Junfeng Liu, Miranda Loh, Keding Lu, Franco Lucarelli, Graham Mann, Gordon McFiggans, Mark R. Miller, Graham Mills, Paul Monk, Eiko Nemitz, Fionna O'Connor, Bin Ouyang, Paul I. Palmer, Carl Percival, Olalekan Popoola, Claire Reeves, Andrew R. Rickard, Longyi Shao, Guangyu Shi, Dominick Spracklen, David Stevenson, Yele Sun, Zhiwei Sun, Shu Tao, Shengrui Tong, Qingqing Wang, Wenhua Wang, Xinming Wang, Xuejun Wang, Zifang Wang, Lianfang Wei, Lisa Whalley, Xuefang Wu, Zhijun Wu, Pinhua Xie, Fumo Yang, Qiang Zhang, Yanli Zhang, Yuanhang Zhang, and Mei Zheng
Atmos. Chem. Phys., 19, 7519–7546, https://doi.org/10.5194/acp-19-7519-2019, https://doi.org/10.5194/acp-19-7519-2019, 2019
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APHH-Beijing is a collaborative international research programme to study the sources, processes and health effects of air pollution in Beijing. This introduction to the special issue provides an overview of (i) the APHH-Beijing programme, (ii) the measurement and modelling activities performed as part of it and (iii) the air quality and meteorological conditions during joint intensive field campaigns as a core activity within APHH-Beijing.
Linlin Wang, Junkai Liu, Zhiqiu Gao, Yubin Li, Meng Huang, Sihui Fan, Xiaoye Zhang, Yuanjian Yang, Shiguang Miao, Han Zou, Yele Sun, Yong Chen, and Ting Yang
Atmos. Chem. Phys., 19, 6949–6967, https://doi.org/10.5194/acp-19-6949-2019, https://doi.org/10.5194/acp-19-6949-2019, 2019
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Urban boundary layer (UBL) affects the physical and chemical processes of the pollutants, and UBL structure can also be altered by pollutants. This paper presents the interactions between air pollution and the UBL structure by using the field data mainly collected from a 325 m meteorology tower, as well as from a Doppler wind lidar, during a severe heavy pollution event that occurred during 1–4 December 2016 in Beijing.
Dantong Liu, Rutambhara Joshi, Junfeng Wang, Chenjie Yu, James D. Allan, Hugh Coe, Michael J. Flynn, Conghui Xie, James Lee, Freya Squires, Simone Kotthaus, Sue Grimmond, Xinlei Ge, Yele Sun, and Pingqing Fu
Atmos. Chem. Phys., 19, 6749–6769, https://doi.org/10.5194/acp-19-6749-2019, https://doi.org/10.5194/acp-19-6749-2019, 2019
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This study provides source attribution and characterization of BC in the Beijing urban environment in both winter and summer. For the first time, the physically and chemically based source apportionments are compared to evaluate the primary source contribution and secondary processing of BC-containing particles. A method is proposed to isolate the BC from the transportation sector and coal combustion sources.
Xionghui Qiu, Qi Ying, Shuxiao Wang, Lei Duan, Jian Zhao, Jia Xing, Dian Ding, Yele Sun, Baoxian Liu, Aijun Shi, Xiao Yan, Qingcheng Xu, and Jiming Hao
Atmos. Chem. Phys., 19, 6737–6747, https://doi.org/10.5194/acp-19-6737-2019, https://doi.org/10.5194/acp-19-6737-2019, 2019
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Current chemical transport models cannot capture the diurnal and nocturnal variation in atmospheric nitrate, which may be relative to the missing atmospheric chlorine chemistry. In this work, the Community Multiscale Air Quality (CMAQ) model with improved chlorine heterogeneous chemistry is applied to simulate the impact of chlorine chemistry on summer nitrate concentrations in Beijing. The results of this work can improve our understanding of nitrate formation.
Yue Liu, Mei Zheng, Mingyuan Yu, Xuhui Cai, Huiyun Du, Jie Li, Tian Zhou, Caiqing Yan, Xuesong Wang, Zongbo Shi, Roy M. Harrison, Qiang Zhang, and Kebin He
Atmos. Chem. Phys., 19, 6595–6609, https://doi.org/10.5194/acp-19-6595-2019, https://doi.org/10.5194/acp-19-6595-2019, 2019
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This study is part of the UK–China APHH campaign. To identify both source types and source regions at the same time, this study developed a combined method including receptor model, footprint model, and air quality model for the first time to investigate sources of PM2.5 during haze episodes in Beijing. It is an expansion of the application of the receptor model and is helpful for formulating effective control strategies to improve air quality in this region.
Jialin Li, Meigen Zhang, Guiqian Tang, Yele Sun, Fangkun Wu, and Yongfu Xu
Atmos. Chem. Phys., 19, 6481–6495, https://doi.org/10.5194/acp-19-6481-2019, https://doi.org/10.5194/acp-19-6481-2019, 2019
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There are large uncertainties in the sources of secondary organic aerosol (SOA). Simulations of SOA concentrations in China with aqueous SOA formation pathway updated and glyoxal simulation improved reveal that dicarbonyl-derived SOA (AAQ) can explain a significant fraction of the unaccounted SOA sources. The mean AAQ can contribute 60.6 % and 64.5 % to the total concentration of SOA in summer and fall, respectively.
Tao Wang, Yangyang Liu, Yue Deng, Hanyun Cheng, Yang Yang, Yiqing Feng, Muhammad Ali Tahir, Xiaozhong Fang, Xu Dong, Kejian Li, Saira Ajmal, Aziz-Ur-Rahim Bacha, Iqra Nabi, Hongbo Fu, Liwu Zhang, and Jianmin Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-315, https://doi.org/10.5194/acp-2019-315, 2019
Revised manuscript not accepted
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We studied the heterogeneous formation of nitrate and nitrite aerosols by in-situ laboratory tests and field observations. Sunlight becomes the protagonist under weak illumination, while a costar under strong irradiation, attributing to the balance between NO2 adsorption and the formation of photoinduced active species. Meanwhile, sunlight determines the association between atmospheric nitrate and nitrite. We hope this work offer more suggestions for modelling studies.
Jingyuan Shao, Qianjie Chen, Yuxuan Wang, Xiao Lu, Pengzhen He, Yele Sun, Viral Shah, Randall V. Martin, Sajeev Philip, Shaojie Song, Yue Zhao, Zhouqing Xie, Lin Zhang, and Becky Alexander
Atmos. Chem. Phys., 19, 6107–6123, https://doi.org/10.5194/acp-19-6107-2019, https://doi.org/10.5194/acp-19-6107-2019, 2019
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Sulfate is a key species contributing to particle formation and growth during wintertime Chinese haze events. This study combines observations and modeling of oxygen isotope signatures in sulfate aerosol to investigate its formation mechanisms, with a focus on heterogeneous production on aerosol surface via H2O2, O3, and NO2 and trace metal catalyzed oxidation. Contributions from different formation pathways are presented.
Zhenying Xu, Mingxu Liu, Minsi Zhang, Yu Song, Shuxiao Wang, Lin Zhang, Tingting Xu, Tiantian Wang, Caiqing Yan, Tian Zhou, Yele Sun, Yuepeng Pan, Min Hu, Mei Zheng, and Tong Zhu
Atmos. Chem. Phys., 19, 5605–5613, https://doi.org/10.5194/acp-19-5605-2019, https://doi.org/10.5194/acp-19-5605-2019, 2019
Junting Zhong, Xiaoye Zhang, Yaqiang Wang, Jizhi Wang, Xiaojing Shen, Hongsheng Zhang, Tijian Wang, Zhouqing Xie, Cheng Liu, Hengde Zhang, Tianliang Zhao, Junying Sun, Shaojia Fan, Zhiqiu Gao, Yubin Li, and Linlin Wang
Atmos. Chem. Phys., 19, 3287–3306, https://doi.org/10.5194/acp-19-3287-2019, https://doi.org/10.5194/acp-19-3287-2019, 2019
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In various haze regions in China, including the Guanzhong Plain, the middle and lower reaches of the Yangtze River, the Pearl River Delta, the Sichuan Basin, and the Northeast China Plain, heavy aerosol pollution episodes include inter-/trans-regional transport stages and cumulative stages (CSs). During CSs a two-way feedback mechanism exists between unfavorable meteorological conditions and cumulative aerosol pollution. This two-way feedback is further quantified and its magnitude is compared.
Kate R. Smith, Peter M. Edwards, Peter D. Ivatt, James D. Lee, Freya Squires, Chengliang Dai, Richard E. Peltier, Mat J. Evans, Yele Sun, and Alastair C. Lewis
Atmos. Meas. Tech., 12, 1325–1336, https://doi.org/10.5194/amt-12-1325-2019, https://doi.org/10.5194/amt-12-1325-2019, 2019
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Clusters of low-cost, low-power atmospheric gas sensors were built into a sensor instrument to monitor NO2 and O3 in Beijing, alongside reference instruments, aiming to improve the reliability of sensor measurements. Clustering identical sensors and using the median sensor signal was used to minimize drift over short and medium timescales. Three different machine learning techniques were used for all the sensor data in an attempt to correct for cross-interferences, which worked to some degree.
Hui Wang, Junmin Lin, Qizhong Wu, Huansheng Chen, Xiao Tang, Zifa Wang, Xueshun Chen, Huaqiong Cheng, and Lanning Wang
Geosci. Model Dev., 12, 749–764, https://doi.org/10.5194/gmd-12-749-2019, https://doi.org/10.5194/gmd-12-749-2019, 2019
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A new framework was designed for the widely used Carbon Bond Mechanism Z (CBM-Z) gas-phase chemical kinetics kernel to adapt the single-instruction, multiple-data (SIMD) technology in next-generation processors like Knights Landing (KNL) to improve their calculation performance. The optimization is aimed at implementing the fine-grain level parallelization of CBM-Z. The test results showed significant acceleration with our optimization on both CPU and KNL platforms.
Lei Sun, Likun Xue, Yuhang Wang, Longlei Li, Jintai Lin, Ruijing Ni, Yingying Yan, Lulu Chen, Juan Li, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 19, 1455–1469, https://doi.org/10.5194/acp-19-1455-2019, https://doi.org/10.5194/acp-19-1455-2019, 2019
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We quantified the detailed impacts of meteorology and anthropogenic emissions on surface O3 increase in central eastern China between 2003 and 2015 using GEOS-Chem. The emission change plays a more important role than the meteorological change, while the regions with a larger O3 increase are more sensitive to meteorology. NMVOC emission change dominated the O3 increase in eastern CEC, while NOx emission change led to an O3 increase in western and central CEC and O3 decrease in urban areas.
Zhijian Li, Sergey A. Nizkorodov, Hong Chen, Xiaohui Lu, Xin Yang, and Jianmin Chen
Atmos. Chem. Phys., 19, 1343–1356, https://doi.org/10.5194/acp-19-1343-2019, https://doi.org/10.5194/acp-19-1343-2019, 2019
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In this work, we found that acrolein, the smallest α,β-unsaturated aldehyde, has the potential to form light-absorbing heterocyclic secondary organic aerosol. In the gaseous phase, acrolein can react with gaseous ammonia, forming 3-picoline. In the liquid phase, the dissolved acrolein can react with ammonium to form higher molecular-weight pyridinium compounds. All the pyridinium compounds can increase the light absorptivity of aerosol particles.
Shaojie Song, Meng Gao, Weiqi Xu, Yele Sun, Douglas R. Worsnop, John T. Jayne, Yuzhong Zhang, Lei Zhu, Mei Li, Zhen Zhou, Chunlei Cheng, Yibing Lv, Ying Wang, Wei Peng, Xiaobin Xu, Nan Lin, Yuxuan Wang, Shuxiao Wang, J. William Munger, Daniel J. Jacob, and Michael B. McElroy
Atmos. Chem. Phys., 19, 1357–1371, https://doi.org/10.5194/acp-19-1357-2019, https://doi.org/10.5194/acp-19-1357-2019, 2019
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Chemistry responsible for sulfate production in northern China winter haze remains mysterious. We propose a potentially key pathway through the reaction of formaldehyde and sulfur dioxide that has not been accounted for in previous studies. The special atmospheric conditions favor the formation and existence of their complex, hydroxymethanesulfonate (HMS).
Jun Chen, Zhanqing Li, Min Lv, Yuying Wang, Wei Wang, Yingjie Zhang, Haofei Wang, Xing Yan, Yele Sun, and Maureen Cribb
Atmos. Chem. Phys., 19, 1327–1342, https://doi.org/10.5194/acp-19-1327-2019, https://doi.org/10.5194/acp-19-1327-2019, 2019
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The hygroscopic growth function of aerosol particles is derived from Raman lidar, whose dependence on aerosol chemical composition is investigated using data from an aerosol chemical speciation monitor (ACSM) and a hygroscopic tandem differential mobility analyzer (H-TDMA) deployed in China. Two distinct cases were chosen with marked differences in their hygroscopic growth, which was fitted by the Kasten model. The differences were attributed to different amounts of chemical species.
Angela Benedetti, Francesca Di Giuseppe, Luke Jones, Vincent-Henri Peuch, Samuel Rémy, and Xiaoye Zhang
Atmos. Chem. Phys., 19, 987–998, https://doi.org/10.5194/acp-19-987-2019, https://doi.org/10.5194/acp-19-987-2019, 2019
Hajime Akimoto, Tatsuya Nagashima, Jie Li, Joshua S. Fu, Dongsheng Ji, Jiani Tan, and Zifa Wang
Atmos. Chem. Phys., 19, 603–615, https://doi.org/10.5194/acp-19-603-2019, https://doi.org/10.5194/acp-19-603-2019, 2019
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The regional model intercomparison study called MICS-Asia III revealed that substantial discrepancy still exists for surface ozone simulation in East Asia, even though common emissions, meteorological field, and boundary conditions have been used among the models. Three factors have been identified as possible causes of such discrepancy, (1) chemistry sub-models, (2) heterogeneous reactions, and (3) vertical transport parameters, and each component has been discussed.
Junfeng Wang, Dantong Liu, Xinlei Ge, Yangzhou Wu, Fuzhen Shen, Mindong Chen, Jian Zhao, Conghui Xie, Qingqing Wang, Weiqi Xu, Jie Zhang, Jianlin Hu, James Allan, Rutambhara Joshi, Pingqing Fu, Hugh Coe, and Yele Sun
Atmos. Chem. Phys., 19, 447–458, https://doi.org/10.5194/acp-19-447-2019, https://doi.org/10.5194/acp-19-447-2019, 2019
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This work is part of the UK-China APHH campaign. We used a laser-only Aerodyne soot particle aerosol mass spectrometer, for the first time, to investigate the concentrations, size distributions and chemical compositions for those ambient submicron aerosol particles only with black carbon as cores. Our findings are valuable to understand the BC properties and processes in the densely populated megacities.
Qiang Huang, Jiubin Chen, Weilin Huang, John R. Reinfelder, Pingqing Fu, Shengliu Yuan, Zhongwei Wang, Wei Yuan, Hongming Cai, Hong Ren, Yele Sun, and Li He
Atmos. Chem. Phys., 19, 315–325, https://doi.org/10.5194/acp-19-315-2019, https://doi.org/10.5194/acp-19-315-2019, 2019
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Although the specific reactions and mechanisms in fine aerosols could not be explicitly determined from this field study, our results provide isotopic evidence that local daily photochemical reduction of divalent Hg is of critical importance to the fate of PM2.5-Hg in urban atmospheres and that, in addition to variation in sources, photochemical reduction appears to be an important process that affects both the particle mass-specific abundance and isotopic composition of PM2.5-Hg.
Xiaole Pan, Baozhu Ge, Zhe Wang, Yu Tian, Hang Liu, Lianfang Wei, Siyao Yue, Itsushi Uno, Hiroshi Kobayashi, Tomoaki Nishizawa, Atsushi Shimizu, Pingqing Fu, and Zifa Wang
Atmos. Chem. Phys., 19, 219–232, https://doi.org/10.5194/acp-19-219-2019, https://doi.org/10.5194/acp-19-219-2019, 2019
Conghui Xie, Weiqi Xu, Junfeng Wang, Qingqing Wang, Dantong Liu, Guiqian Tang, Ping Chen, Wei Du, Jian Zhao, Yingjie Zhang, Wei Zhou, Tingting Han, Qingyun Bian, Jie Li, Pingqing Fu, Zifa Wang, Xinlei Ge, James Allan, Hugh Coe, and Yele Sun
Atmos. Chem. Phys., 19, 165–179, https://doi.org/10.5194/acp-19-165-2019, https://doi.org/10.5194/acp-19-165-2019, 2019
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We present the first simultaneous real-time online measurements of aerosol optical properties at ground level and at 260 m on a meteorological tower in urban Beijing in winter. The vertical similarities and differences in scattering and absorption coefficients were characterized. The increases in MAC of BC were mainly associated with the coating materials on rBC. Coal combustion was the dominant source contribution of brown carbon followed by biomass burning and SOA in winter in Beijing.
Yu Tian, Xiaole Pan, Tomoaki Nishizawa, Hiroshi Kobayashi, Itsushi Uno, Xiquan Wang, Atsushi Shimizu, and Zifa Wang
Atmos. Chem. Phys., 18, 18203–18217, https://doi.org/10.5194/acp-18-18203-2018, https://doi.org/10.5194/acp-18-18203-2018, 2018
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East Asia is characterized by severe anthropogenic pollution and dust storms due to fuel consumption and the downwind location of dust sources. We studied the mixing states of dust and pollutants using an optical particle counter equipped with a polarization detection module, providing a deeper understanding of possible mechanisms of aerosols’ morphological change. In Beijing, the heterogeneous processes in the mixture of dust and emitted pollutants have a great influence on smog formation.
Hong Wang, Yue Peng, Xiaoye Zhang, Hongli Liu, Meng Zhang, Huizheng Che, Yanli Cheng, and Yu Zheng
Atmos. Chem. Phys., 18, 17717–17733, https://doi.org/10.5194/acp-18-17717-2018, https://doi.org/10.5194/acp-18-17717-2018, 2018
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The explosive growth (EG) of PM2.5 resulted in a PM2.5 maximum, which was generally underestimated by atmospheric chemical models due to the deficient description of the local
turbulence intermittent. The aerosol–radiation feedback (AF) and decrease in turbulence diffusion (DTD) may reduce the underestimation of PM2.5 EG by 20–25% and 14–20%, respectively. The modeled EG stage PM2.5 error was decreased from −40 to −51% to −11 to 2% by the combined effects of AF and DTD in Jing–Jin–Ji.
Yue Peng, Hong Wang, Yubin Li, Changwei Liu, Tianliang Zhao, Xiaoye Zhang, Zhiqiu Gao, Tong Jiang, Huizheng Che, and Meng Zhang
Atmos. Chem. Phys., 18, 17421–17435, https://doi.org/10.5194/acp-18-17421-2018, https://doi.org/10.5194/acp-18-17421-2018, 2018
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Two surface layer schemes are evaluated in eastern China based on observational flux data. The results indicate that the Li scheme better describes regional atmosphere stratification compared with the MM5 scheme, especially for the transition stage from unstable to stable atmosphere conditions, corresponding to PM2.5 accumulation. Our research suggests the potential improved possibilities for severe haze prediction in eastern China by coupling Li online into atmosphere chemical models.
Yangyang Zhang, Aohan Tang, Dandan Wang, Qingqing Wang, Katie Benedict, Lin Zhang, Duanyang Liu, Yi Li, Jeffrey L. Collett Jr., Yele Sun, and Xuejun Liu
Atmos. Chem. Phys., 18, 16385–16398, https://doi.org/10.5194/acp-18-16385-2018, https://doi.org/10.5194/acp-18-16385-2018, 2018
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Our study is the first to continually monitor the vertical concentration profile of NH3 in urban Beijing. Weekly concentrations averaged 13.3 ± 4.8 μg m−3. The highest NH3 concentrations were always observed between 32 and 63 m, decreasing toward the surface and toward higher altitudes. Our results demonstrate a NH3 rich atmosphere in urban Beijing, from the ground to at least 320 m. Regional transport from the south (intensive agricultural regions) contributed high NH3 concentrations in Beijing.
Kangning Li, Xingnan Ye, Hongwei Pang, Xiaohui Lu, Hong Chen, Xiaofei Wang, Xin Yang, Jianmin Chen, and Yingjun Chen
Atmos. Chem. Phys., 18, 15201–15218, https://doi.org/10.5194/acp-18-15201-2018, https://doi.org/10.5194/acp-18-15201-2018, 2018
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Temporal variation in the hygroscopicity and its correlation with the mixing state of ambient BC particles were studied using a HTDMA–SP2 system. Secondary organic carbon formation and condensation of nitrates were mainly responsible for the changes of hygroscopicity of BC particles during daytime and nighttime, respectively. Different atmospheric aging processes led to the change of BC particles' mixing states, which play a fundamental role in determining their hygroscopicity.
Yingjie Zhang, Wei Du, Yuying Wang, Qingqing Wang, Haofei Wang, Haitao Zheng, Fang Zhang, Hongrong Shi, Yuxuan Bian, Yongxiang Han, Pingqing Fu, Francesco Canonaco, André S. H. Prévôt, Tong Zhu, Pucai Wang, Zhanqing Li, and Yele Sun
Atmos. Chem. Phys., 18, 14637–14651, https://doi.org/10.5194/acp-18-14637-2018, https://doi.org/10.5194/acp-18-14637-2018, 2018
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We have a comprehensive characterization of aerosol chemistry and particle growth events at a downwind site of a highly polluted city in the North China Plain. Aerosol particles at the urban downwind site were highly aged and mainly from secondary formation. New particle growth events were also frequently observed on both clean and polluted days. While both sulfate and SOA played important roles in particle growth during clean periods, SOA was more important than sulfate during polluted events.
Lei Liu, Jian Zhang, Liang Xu, Qi Yuan, Dao Huang, Jianmin Chen, Zongbo Shi, Yele Sun, Pingqing Fu, Zifa Wang, Daizhou Zhang, and Weijun Li
Atmos. Chem. Phys., 18, 14681–14693, https://doi.org/10.5194/acp-18-14681-2018, https://doi.org/10.5194/acp-18-14681-2018, 2018
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Using transmission electron microscopy, we studied individual cloud droplet residual and interstitial particles collected in cloud events at Mt. Tai in the polluted North China region. We found that individual cloud droplets were an extremely complicated mixture containing abundant refractory soot (i.e., black carbon), fly ash, and metals. The complicated cloud droplets have not been reported in clean continental or marine air before.
Zhong Li, Chunlin Li, Xingnan Ye, Hongbo Fu, Lin Wang, Xin Yang, Xinke Wang, Zhuohui Zhao, Haidong Kan, Abdelwahid Mellouki, and Jianmin Chen
Atmos. Chem. Phys., 18, 14445–14464, https://doi.org/10.5194/acp-18-14445-2018, https://doi.org/10.5194/acp-18-14445-2018, 2018
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Air quality over the Yangtze River is important as it may significantly influence aquatic ecosystems, public health, and coastal areas. A comprehensive 15-day cruise campaign, TEMP, was performed in the mid–lower reaches of the Yangtze River in winter of 2015. Based on the filter samples, the chemical composition of PM2.5 greatly varied or fluctuated.
Mingjie Kang, Pingqing Fu, Kimitaka Kawamura, Fan Yang, Hongliang Zhang, Zhengchen Zang, Hong Ren, Lujie Ren, Ye Zhao, Yele Sun, and Zifa Wang
Atmos. Chem. Phys., 18, 13947–13967, https://doi.org/10.5194/acp-18-13947-2018, https://doi.org/10.5194/acp-18-13947-2018, 2018
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Molecular characterization and spatial distribution of biogenic primary organic aerosol (POA) and secondary organic aerosol (SOA) in the marine atmosphere are not well known. Here, we analysed the organic molecular composition of marine aerosols collected during a marine cruise in the East China Sea during May–June 2014. Our results suggest that the Asian continent can be a natural emitter of biogenic POA and SOA, which can be transported to the downwind marine atmosphere.
Ying Ji, Xiaofei Qin, Bo Wang, Jian Xu, Jiandong Shen, Jianmin Chen, Kan Huang, Congrui Deng, Renchang Yan, Kaier Xu, and Tian Zhang
Atmos. Chem. Phys., 18, 13581–13600, https://doi.org/10.5194/acp-18-13581-2018, https://doi.org/10.5194/acp-18-13581-2018, 2018
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Large-scale joint emission control measures were carried out in the Yangtze River Delta during the Hangzhou G20 Summit in 2016. The extent of secondary inorganic aerosol formation was found to be significantly enhanced under transport conditions from northern China. However, the formation of secondary organic aerosols was also greatly suppressed due to the emission control measures. Overall, it was found that regional/long-range transport could have offset part of the emission control efforts.
Yee Jun Tham, Zhe Wang, Qinyi Li, Weihao Wang, Xinfeng Wang, Keding Lu, Nan Ma, Chao Yan, Simonas Kecorius, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 18, 13155–13171, https://doi.org/10.5194/acp-18-13155-2018, https://doi.org/10.5194/acp-18-13155-2018, 2018
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This study addresses the limited understanding of heterogeneous N2O5 uptake and ClNO2 production in the polluted environment of China. The results showed that N2O5 uptake and ClNO2 yield cannot be well explained by previous parameterizations and were largely influenced by factors like aerosol water content and biomass burning emission. Our findings illuminate the need to realistically parameterize these heterogeneous processes for better simulation of photochemical and haze pollution in China.
Yuying Wang, Zhanqing Li, Yingjie Zhang, Wei Du, Fang Zhang, Haobo Tan, Hanbing Xu, Tianyi Fan, Xiaoai Jin, Xinxin Fan, Zipeng Dong, Qiuyan Wang, and Yele Sun
Atmos. Chem. Phys., 18, 11739–11752, https://doi.org/10.5194/acp-18-11739-2018, https://doi.org/10.5194/acp-18-11739-2018, 2018
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Very different aerosol hygroscopicities and mixing states were found at these sites in the North China Plain. The PDF for 40–200 nm particles showed the particles were highly aged and internally mixed at Xingtai because of high pollution and strong photochemical reactions. A good proxy for the chemical comical composition (kappa = 0.31) in calculating CCN concentration was found. Importantly, our study investigated the influence of industrial emissions on the aerosol properties.
Wei Zhou, Jian Zhao, Bin Ouyang, Archit Mehra, Weiqi Xu, Yuying Wang, Thomas J. Bannan, Stephen D. Worrall, Michael Priestley, Asan Bacak, Qi Chen, Conghui Xie, Qingqing Wang, Junfeng Wang, Wei Du, Yingjie Zhang, Xinlei Ge, Penglin Ye, James D. Lee, Pingqing Fu, Zifa Wang, Douglas Worsnop, Roderic Jones, Carl J. Percival, Hugh Coe, and Yele Sun
Atmos. Chem. Phys., 18, 11581–11597, https://doi.org/10.5194/acp-18-11581-2018, https://doi.org/10.5194/acp-18-11581-2018, 2018
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We present measurements of gas-phase N2O5 and ClNO2 by ToF-CIMS during summer in urban Beijing as part of the APHH campaign. High reactivity of N2O5 indicative of active nocturnal chemistry was observed. The lifetime of N2O5 as a function of aerosol surface area and relative humidity was characterized, and N2O5 uptake coefficients were estimated. We also found that the N2O5 loss in this study is mainly attributed to its indirect loss via reactions of NO3 with VOCs and NO.
Liang Wen, Likun Xue, Xinfeng Wang, Caihong Xu, Tianshu Chen, Lingxiao Yang, Tao Wang, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 18, 11261–11275, https://doi.org/10.5194/acp-18-11261-2018, https://doi.org/10.5194/acp-18-11261-2018, 2018
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We present the first piece of observational evidence of the increasing trend of fine nitrate aerosol in the North China Plain (NCP) during 2005–2015. The summertime nitrate formation mechanism is dissected with a multiphase chemical box model based on observations at three different sites. The nitrate formation is most sensitive to NO2 and to a lesser extent to O3. NH3 plays a significant role in prompting the nitrate formation, but it is usually in excess in summer in the NCP region.
Yanhong Zhu, Lingxiao Yang, Jianmin Chen, Kimitaka Kawamura, Mamiko Sato, Andreas Tilgner, Dominik van Pinxteren, Ying Chen, Likun Xue, Xinfeng Wang, Isobel J. Simpson, Hartmut Herrmann, Donald R. Blake, and Wenxing Wang
Atmos. Chem. Phys., 18, 10741–10758, https://doi.org/10.5194/acp-18-10741-2018, https://doi.org/10.5194/acp-18-10741-2018, 2018
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Molecular distributions of dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls in the free troposphere are identified, and their concentration variations between 2014 and 2006 are presented. High nighttime concentrations were probably due to precursor emissions and aqueous-phase oxidation. Biomass burning was significant, but its tracer levoglucosan in 2014 was 5 times lower than 2006 concentrations. Finally, regional emission from anthropogenic activities was identified as a major source.
Yele Sun, Weiqi Xu, Qi Zhang, Qi Jiang, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Jie Li, John Jayne, Douglas R. Worsnop, and Zifa Wang
Atmos. Chem. Phys., 18, 8469–8489, https://doi.org/10.5194/acp-18-8469-2018, https://doi.org/10.5194/acp-18-8469-2018, 2018
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We present a 2–year analysis of organic aerosol (OA) from highly time–resolved measurements by an aerosol chemical speciation monitor in the megacity of Beijing. The sources of OA were analyzed with the advanced factor analysis of a multilinear engine (ME-2). Our results showed very different seasonal patterns, relative humidity and temperature dependence, and sources regions among different OA factors. The sources and processes of OA factors, and their roles in haze pollution are elucidated.
Xiao-Xiao Zhang, Brenton Sharratt, Lian-You Liu, Zi-Fa Wang, Xiao-Le Pan, Jia-Qiang Lei, Shi-Xin Wu, Shuang-Yan Huang, Yu-Hong Guo, Jie Li, Xiao Tang, Ting Yang, Yu Tian, Xue-Shun Chen, Jian-Qi Hao, Hai-Tao Zheng, Yan-Yan Yang, and Yan-Li Lyu
Atmos. Chem. Phys., 18, 8353–8371, https://doi.org/10.5194/acp-18-8353-2018, https://doi.org/10.5194/acp-18-8353-2018, 2018
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The impact of a strong East Asian dust event during 2–7 May 2017 was quantified and assessed based upon environmental observations, lidar measurements, and satellite products along with simulation techniques. This dust storm impacted a wide area of China and other Asian nations and reached North America within 1 week. Dust storms are a significant contributor to the global dust budget. Asian dust storms such as that observed in early May 2017 may lead to wider climate forcing on a global scale.
Jie Zhang, Sara Lance, Jeffrey M. Freedman, Yele Sun, Brian A. Crandall, Xiuli Wei, and James J. Schwab
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-529, https://doi.org/10.5194/acp-2018-529, 2018
Preprint retracted
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The impact of fireworks (FW) events on air quality was studied using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and collocated instruments during the Independence Day (July 4) holiday. The Independence Day FW events resulted in significant increases in both organic and inorganic (potassium, sulfate, chloride) chemical components, and the contribution from different aerosol sources was discussed.
Shaojie Song, Meng Gao, Weiqi Xu, Jingyuan Shao, Guoliang Shi, Shuxiao Wang, Yuxuan Wang, Yele Sun, and Michael B. McElroy
Atmos. Chem. Phys., 18, 7423–7438, https://doi.org/10.5194/acp-18-7423-2018, https://doi.org/10.5194/acp-18-7423-2018, 2018
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Severe haze events occur frequently over northern China, especially in winter. Acidity plays a critical role in the formation of secondary PM2.5 and its toxicity. Using field measurements of gases and particles to critically evaluate two thermodynamic models routinely employed to determine particle acidity, we found that China's winter haze particles are generally within a moderately acidic range (pH 4–5) and not highly acidic (0) or neutral (7) as has been previously reported in the literature.
Jingye Ren, Fang Zhang, Yuying Wang, Don Collins, Xinxin Fan, Xiaoai Jin, Weiqi Xu, Yele Sun, Maureen Cribb, and Zhanqing Li
Atmos. Chem. Phys., 18, 6907–6921, https://doi.org/10.5194/acp-18-6907-2018, https://doi.org/10.5194/acp-18-6907-2018, 2018
Xiaoye Zhang, Junting Zhong, Jizhi Wang, Yaqiang Wang, and Yanju Liu
Atmos. Chem. Phys., 18, 5991–5999, https://doi.org/10.5194/acp-18-5991-2018, https://doi.org/10.5194/acp-18-5991-2018, 2018
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The relation between interdecadal changes in weather conditions and climate warming is uncertain. Here, the decadal worsening of meteorological conditions since the 1960s in the Beijing area was found to be partly attributed to climate warming, which is defined by more warming in the higher layers of the boundary layer (BL) than the lower layers. This worsening may also partly be related to the impact on the increasing aerosol pollution (particularly after 2010).
Di Liu, Matthias Vonwiller, Jun Li, Junwen Liu, Sönke Szidat, Yanlin Zhang, Chongguo Tian, Yinjun Chen, Zhineng Cheng, Guangcai Zhong, Pingqing Fu, and Gan Zhang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-295, https://doi.org/10.5194/acp-2018-295, 2018
Revised manuscript not accepted
Meng Gao, Zhiwei Han, Zirui Liu, Meng Li, Jinyuan Xin, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Yafang Cheng, Yuesi Wang, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Jung-Hun Woo, Qiang Zhang, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 18, 4859–4884, https://doi.org/10.5194/acp-18-4859-2018, https://doi.org/10.5194/acp-18-4859-2018, 2018
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Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative and microphysical feedbacks. A comprehensive overview of the MICS-ASIA III Topic 3 study design is presented.
Liwei Wang, Xinfeng Wang, Rongrong Gu, Hao Wang, Lan Yao, Liang Wen, Fanping Zhu, Weihao Wang, Likun Xue, Lingxiao Yang, Keding Lu, Jianmin Chen, Tao Wang, Yuanghang Zhang, and Wenxing Wang
Atmos. Chem. Phys., 18, 4349–4359, https://doi.org/10.5194/acp-18-4349-2018, https://doi.org/10.5194/acp-18-4349-2018, 2018
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This study presents concentrations, variation characteristics, sources and secondary formations of nitrated phenols, a major component of brown carbon, in typical seasons at four sites in northern China. The results highlight the strong influences and contributions of anthropogenic activities, in particular coal combustion and the aging processes, to the atmospheric nitrated phenols in this region.
Wei Zhou, Qingqing Wang, Xiujuan Zhao, Weiqi Xu, Chen Chen, Wei Du, Jian Zhao, Francesco Canonaco, André S. H. Prévôt, Pingqing Fu, Zifa Wang, Douglas R. Worsnop, and Yele Sun
Atmos. Chem. Phys., 18, 3951–3968, https://doi.org/10.5194/acp-18-3951-2018, https://doi.org/10.5194/acp-18-3951-2018, 2018
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We present a 3-month analysis of submicron aerosols that were measured at 260 m on a meteorological tower in Beijing, China. The sources of organic aerosol (OA) were analyzed by using a multi-linear engine (ME-2). Our results showed significant changes in both primary and secondary OA composition from the non-heating season to the heating season. We also observed a considerable contribution (10–13%) of cooking OA at 260 m and very different OA composition between ground level and 260 m.
Tianze Sun, Huizheng Che, Bing Qi, Yaqiang Wang, Yunsheng Dong, Xiangao Xia, Hong Wang, Ke Gui, Yu Zheng, Hujia Zhao, Qianli Ma, Rongguang Du, and Xiaoye Zhang
Atmos. Chem. Phys., 18, 2949–2971, https://doi.org/10.5194/acp-18-2949-2018, https://doi.org/10.5194/acp-18-2949-2018, 2018
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The Yangtze River Delta (YRD) region is a key hub in China with air pollution problems. We applied various data from observations and satellites, finding particles in summer prefer hygroscopic growth leading to high scatter. Transported scatter particles lead to a cooling effect which lowers the boundary layer, creating positive feedback. Transported pollutants over YRD are from the North China Plain, northwestern deserts, and southern biomass burning. This finding helps air quality control.
Wanyu Zhao, Kimitaka Kawamura, Siyao Yue, Lianfang Wei, Hong Ren, Yu Yan, Mingjie Kang, Linjie Li, Lujie Ren, Senchao Lai, Jie Li, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 18, 2749–2767, https://doi.org/10.5194/acp-18-2749-2018, https://doi.org/10.5194/acp-18-2749-2018, 2018
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In this paper, we investigate the seasonal trends in concentrations and compound-specific stable carbon isotope ratios of low molecular weight dicarboxylic acids (C2–C12) and related compounds in fine aerosols (PM2.5) in Beijing. Our study demonstrates that, in addition to the production via photo-oxidation, high abundances of diacids and related compounds in Beijing are largely associated with anthropogenic primary emissions such as biomass burning, fossil fuel combustion and plastic burning.
Qingqing Wang, Yele Sun, Weiqi Xu, Wei Du, Libo Zhou, Guiqian Tang, Chen Chen, Xueling Cheng, Xiujuan Zhao, Dongsheng Ji, Tingting Han, Zhe Wang, Jie Li, and Zifa Wang
Atmos. Chem. Phys., 18, 2495–2509, https://doi.org/10.5194/acp-18-2495-2018, https://doi.org/10.5194/acp-18-2495-2018, 2018
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We conducted the first real-time continuous vertical measurements of particle extinction, NO2, and BC from ground level to 260 m during two severe winter haze episodes in urban Beijing, China. Our results show very complex and dynamic vertical profiles that interact closely with boundary layer and meteorological conditions. Further analysis demonstrate that vertical convection, temperature inversion, and local emissions are three major factors affecting the changes in vertical profiles.
Ganglin Lv, Xiao Sui, Jianmin Chen, Rohan Jayaratne, and Abdelwahid Mellouki
Atmos. Chem. Phys., 18, 2243–2258, https://doi.org/10.5194/acp-18-2243-2018, https://doi.org/10.5194/acp-18-2243-2018, 2018
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We conducted an investigation of new particle formation (NPF) at the summit of Mt. Tai, eastern China, based on simultaneous measurements of particle size distribution, meteorological parameters, gaseous species, mass concentration, and chemical composition of PM2.5. The general characteristics, favorable conditions, and potential precursor species of NPF events are discussed. An in-depth study of NPF on Mt. Tai is important for understanding the effect of particles on air quality.
Xiaojing Shen, Junying Sun, Niku Kivekäs, Adam Kristensson, Xiaoye Zhang, Yangmei Zhang, Lu Zhang, Ruxia Fan, Xuefei Qi, Qianli Ma, and Huaigang Zhou
Atmos. Chem. Phys., 18, 587–599, https://doi.org/10.5194/acp-18-587-2018, https://doi.org/10.5194/acp-18-587-2018, 2018
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In this study we used the NanoMap method by applying back trajectories and particle number size distribution in different rural sites in China to evaluate the spatial distribution of NPF events and their occurrence probability. We found difference in the horizontal spatial distribution of new particle source areas was connected to typical meteorological conditions. The horizontal extent of NPF reached to larger than 500 km at two sites, favoured by the fast transport of northwesterly air masses.
Huizheng Che, Bing Qi, Hujia Zhao, Xiangao Xia, Thomas F. Eck, Philippe Goloub, Oleg Dubovik, Victor Estelles, Emilio Cuevas-Agulló, Luc Blarel, Yunfei Wu, Jun Zhu, Rongguang Du, Yaqiang Wang, Hong Wang, Ke Gui, Jie Yu, Yu Zheng, Tianze Sun, Quanliang Chen, Guangyu Shi, and Xiaoye Zhang
Atmos. Chem. Phys., 18, 405–425, https://doi.org/10.5194/acp-18-405-2018, https://doi.org/10.5194/acp-18-405-2018, 2018
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Sun photometer measurements from seven sites in the Yangtze River Delta (YRD) from 2011 to 2015 were used to characterize the climatology of aerosol microphysical and optical properties, calculate direct aerosol radiative forcing (DARF) and classify aerosols based on size and absorption. This study contributes to our understanding of aerosols and regional climate/air quality, and the results will be useful for validating satellite retrievals and for improving climate models and remote sensing.
Junting Zhong, Xiaoye Zhang, Yunsheng Dong, Yaqiang Wang, Cheng Liu, Jizhi Wang, Yangmei Zhang, and Haochi Che
Atmos. Chem. Phys., 18, 247–258, https://doi.org/10.5194/acp-18-247-2018, https://doi.org/10.5194/acp-18-247-2018, 2018
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Beijing heavy pollution episodes are characterized by the transport stage (TS) and the cumulative stage (CS). PM2.5 pollution formation in the TS is primarily caused by pollutants transported from the south of Beijing. PM2.5 cumulative explosive growth in the CS is dominated by stable atmospheric stratification due to the interaction of particulate matter (PM) and meteorological factors. The positive meteorological feedback on PM2.5 mass noted explains over 70% of cumulative explosive growth.
Santosh Kumar Verma, Kimitaka Kawamura, Jing Chen, and Pingqing Fu
Atmos. Chem. Phys., 18, 81–101, https://doi.org/10.5194/acp-18-81-2018, https://doi.org/10.5194/acp-18-81-2018, 2018
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East Asia has experienced rapid economic development in the last several decades, of which activities emit bioaerosols. The atmospheric particles are transported to downwind regions in the Pacific. To understand the atmospheric transport of bioaerosols, we conducted long-term observations of sugar components over Chichijima Island from 2001 to 2013. We found that atmospheric circulations significantly affect the seasonal variation of bioaerosol distributions over the western North Pacific.
Zheng Fang, Wei Deng, Yanli Zhang, Xiang Ding, Mingjin Tang, Tengyu Liu, Qihou Hu, Ming Zhu, Zhaoyi Wang, Weiqiang Yang, Zhonghui Huang, Wei Song, Xinhui Bi, Jianmin Chen, Yele Sun, Christian George, and Xinming Wang
Atmos. Chem. Phys., 17, 14821–14839, https://doi.org/10.5194/acp-17-14821-2017, https://doi.org/10.5194/acp-17-14821-2017, 2017
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Primary emissions and aging of open straw burning plumes were characterized in ambient dilution conditions in a chamber. Rich in alkenes, the plumes have high O3 formation potential. The emissions of specific particulate and gaseous compounds were less when the straws were fully burned. Organic aerosol (OA) mass increased by a factor of 2–8 with 3–9 h photo-oxidation, yet > 70 % of the mass cannot be explained by the known precursors. OA gained more O- and N-containing compounds during aging.
Yunjiang Zhang, Lili Tang, Philip L. Croteau, Olivier Favez, Yele Sun, Manjula R. Canagaratna, Zhuang Wang, Florian Couvidat, Alexandre Albinet, Hongliang Zhang, Jean Sciare, André S. H. Prévôt, John T. Jayne, and Douglas R. Worsnop
Atmos. Chem. Phys., 17, 14501–14517, https://doi.org/10.5194/acp-17-14501-2017, https://doi.org/10.5194/acp-17-14501-2017, 2017
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We conducted the first field measurements of non-refractory fine aerosols (NR-PM2.5) in a megacity of eastern China using a PM2.5-ACSM along with a PM1-ACSM measurement. Inter-comparisons demonstrated that the NR-PM2.5 components can be characterized. Substantial mass fractions of aerosol species were observed in the size range of 1–2.5 μm, with sulfate and SOA being the two largest contributors. The impacts of aerosol water driven by secondary inorganic aerosols on SOA formation were explored.
Xiaole Pan, Yugo Kanaya, Fumikazu Taketani, Takuma Miyakawa, Satoshi Inomata, Yuichi Komazaki, Hiroshi Tanimoto, Zhe Wang, Itsushi Uno, and Zifa Wang
Atmos. Chem. Phys., 17, 13001–13016, https://doi.org/10.5194/acp-17-13001-2017, https://doi.org/10.5194/acp-17-13001-2017, 2017
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Characteristics of refractory black carbon (rBC) from open biomass burning (OBB) have a great impact on regional pollution and climate, in particular in East Asia. However, experimental study on characteristics of rBC from agricultural residue burning in East China was limited. This study performed laboratory experiments: we found that emission of rBC is highly related to flaming burning, and non-rBC to smoldering burning. Rapid condensation of semi-volatile organics resulted in coated rBC.
Zhe Wang, Weihao Wang, Yee Jun Tham, Qinyi Li, Hao Wang, Liang Wen, Xinfeng Wang, and Tao Wang
Atmos. Chem. Phys., 17, 12361–12378, https://doi.org/10.5194/acp-17-12361-2017, https://doi.org/10.5194/acp-17-12361-2017, 2017
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This work addresses unclear roles of heterogeneous N2O5 reactions and chlorine activation processes in the polluted residual layer from a mountaintop measurement in northern China. The results revealed efficient ClNO2 production in the coal-fired plumes in this region, having large impacts on next-morning photochemistry. Fast heterogeneous N2O5 reactions dominate the nocturnal NOx loss and contribute to substantial nitrate formation, which may boost the haze pollution in northern China.
Chaoliu Li, Fangping Yan, Shichang Kang, Pengfei Chen, Xiaowen Han, Zhaofu Hu, Guoshuai Zhang, Ye Hong, Shaopeng Gao, Bin Qu, Zhejing Zhu, Jiwei Li, Bing Chen, and Mika Sillanpää
Atmos. Chem. Phys., 17, 11899–11912, https://doi.org/10.5194/acp-17-11899-2017, https://doi.org/10.5194/acp-17-11899-2017, 2017
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In this study, we found, due to contribution of carbonates, previously reported BC concentration in atmosphere of the Himalayas and Tibetan Plateau (HTP) were overestimated by around 39–52 %. Meanwhile, we found BC deposition of lake cores overestimated the atmospheric deposition of BC in the HTP; BC depositions of glacier region reflected actual values of 17.9 ± 5.3 mg m−2 a−1. The above results are critical for studying atmospheric distribution and chemical transport of BC in and around the HTP.
Caihong Xu, Min Wei, Jianmin Chen, Chao Zhu, Jiarong Li, Ganglin Lv, Xianmang Xu, Lulu Zheng, Guodong Sui, Weijun Li, Bing Chen, Wenxing Wang, Qingzhu Zhang, Aijun Ding, and Abdelwahid Mellouki
Atmos. Chem. Phys., 17, 11247–11260, https://doi.org/10.5194/acp-17-11247-2017, https://doi.org/10.5194/acp-17-11247-2017, 2017
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Fungi are ubiquitous throughout the near-surface atmosphere, where they represent an important component of primary biological aerosol particles. The diversity and composition of the fungal communities varied over the different seasons between the fine (PM2.5) and submicron (PM1) particles at the summit of Mt. Tai located in the North China Plain, China. This work may serve as an important reference for the fungal contribution to primary biological aerosol particles.
Jiarong Li, Xinfeng Wang, Jianmin Chen, Chao Zhu, Weijun Li, Chengbao Li, Lu Liu, Caihong Xu, Liang Wen, Likun Xue, Wenxing Wang, Aijun Ding, and Hartmut Herrmann
Atmos. Chem. Phys., 17, 9885–9896, https://doi.org/10.5194/acp-17-9885-2017, https://doi.org/10.5194/acp-17-9885-2017, 2017
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Cloud events at Mt. Tai were investigated for the chemical composition and size distribution of cloud droplets. An obvious rise in pH was found for elevated NH+4 during the last decade. Higher PM2.5 levels resulted in higher concentrations of water-soluble ions, smaller sizes and higher numbers of cloud droplets. The mechanism of cloud-droplet formation and the mass transfer between aerosol–gas–cloud phases were summarized to enrich the knowledge of cloud chemical and microphysical properties.
Yujiao Zhu, Caiqing Yan, Renyi Zhang, Zifa Wang, Mei Zheng, Huiwang Gao, Yang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 17, 9469–9484, https://doi.org/10.5194/acp-17-9469-2017, https://doi.org/10.5194/acp-17-9469-2017, 2017
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This study reports the distinct effects of street canyons on new particle formation (NPF) under warm or cold ambient temperature conditions because of on-road vehicle emissions; i.e., stronger condensation sinks are responsible for the reduced NPF in the springtime, but efficient nucleation and partitioning of gaseous species contribute to the enhanced NPF in the wintertime. The oxidization of biogenic organics is suggested to play an important role in growing new particles.
Hui Wang, Huansheng Chen, Qizhong Wu, Junmin Lin, Xueshun Chen, Xinwei Xie, Rongrong Wang, Xiao Tang, and Zifa Wang
Geosci. Model Dev., 10, 2891–2904, https://doi.org/10.5194/gmd-10-2891-2017, https://doi.org/10.5194/gmd-10-2891-2017, 2017
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We introduced some methods to port our Global Nested Air Quality Prediction Modeling System (GNAQPMS) model on Intel Knight Landing (KNL). In this paper, we introduced both common and specific methods to accelerate out model better. With the guidance of the resources material on Intel Websites (http://www.intel.com/content/www/us/en/products/processors/xeon-phi.html) and relative books, this paper could be an example for the model developers to take advantage of KNL for their model.
Jinghao Zhai, Xiaohui Lu, Ling Li, Qi Zhang, Ci Zhang, Hong Chen, Xin Yang, and Jianmin Chen
Atmos. Chem. Phys., 17, 7481–7493, https://doi.org/10.5194/acp-17-7481-2017, https://doi.org/10.5194/acp-17-7481-2017, 2017
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The effective density, chemical composition, and optical properties of particles produced by burning rice straw were measured. Density distribution and single-particle mass spectrometry showed the size-dependent external mixing of black carbon, organic carbon, and potassium salts in biomass burning particles. Optical measurements indicated the significant presence of brown carbon in all particles. Though freshly emitted, light absorption enhancement was observed for particles larger than 200 nm.
Yuanyuan Xie, Xingnan Ye, Zhen Ma, Ye Tao, Ruyu Wang, Ci Zhang, Xin Yang, Jianmin Chen, and Hong Chen
Atmos. Chem. Phys., 17, 7277–7290, https://doi.org/10.5194/acp-17-7277-2017, https://doi.org/10.5194/acp-17-7277-2017, 2017
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Urban air pollution is one of the greatest environmental concern in 21st century. In this paper, we trace temporal evolutions of aerosol hygroscopicity and effective density during a representative particulate matter episode, which provide a strong support on that severe haze pollution can be formed in highly polluted areas by the initial accumulation of gas-phase and particulate pollutants under stagnant meteorological conditions and subsequent rapid particle growth by secondary processes.
Wei Du, Jian Zhao, Yuying Wang, Yingjie Zhang, Qingqing Wang, Weiqi Xu, Chen Chen, Tingting Han, Fang Zhang, Zhanqing Li, Pingqing Fu, Jie Li, Zifa Wang, and Yele Sun
Atmos. Chem. Phys., 17, 6797–6811, https://doi.org/10.5194/acp-17-6797-2017, https://doi.org/10.5194/acp-17-6797-2017, 2017
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We conducted the first simultaneous measurements of size-resolved particle number concentrations at ground level and 260 m in urban Beijing. The vertical differences strongly depend on particle sizes, with accumulation-mode particles being highly correlated at the two heights. We further demonstrated that regional emission controls have a dominant impact on accumulation-mode particles, while the influences on Aitken particles were much smaller due to the enhanced NPF events.
Ting Yang, Zifa Wang, Wei Zhang, Alex Gbaguidi, Nobuo Sugimoto, Xiquan Wang, Ichiro Matsui, and Yele Sun
Atmos. Chem. Phys., 17, 6215–6225, https://doi.org/10.5194/acp-17-6215-2017, https://doi.org/10.5194/acp-17-6215-2017, 2017
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Predicting air pollution events over megacities requires, notably, continuous and accurate determination of the boundary layer height (BLH). Based on gravity wave theory, a new approach (CRGM) is developed to overcome existing algorithms' weakness in order to accurately reproduce the fluctuations of the BLH under various atmospheric pollution conditions from lidar observation. Comprehensive evaluation highlights strong effectiveness of this new method.
Min Wei, Caihong Xu, Jianmin Chen, Chao Zhu, Jiarong Li, and Ganglin Lv
Atmos. Chem. Phys., 17, 5253–5270, https://doi.org/10.5194/acp-17-5253-2017, https://doi.org/10.5194/acp-17-5253-2017, 2017
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Bacterial communities in cloud water collected at the summit of Mt Tai from 24 July to 23 August 2014 were investigated. A highly diverse bacterial community was retrieved. Community function prediction suggested that pathways related to metabolism and disease infections were significantly correlated with the predominant genera. Potential pathogens were enriched in the polluted cloud samples, whereas the diverse ecological function groups were significant in the non-polluted samples.
Yuying Wang, Fang Zhang, Zhanqing Li, Haobo Tan, Hanbing Xu, Jingye Ren, Jian Zhao, Wei Du, and Yele Sun
Atmos. Chem. Phys., 17, 5239–5251, https://doi.org/10.5194/acp-17-5239-2017, https://doi.org/10.5194/acp-17-5239-2017, 2017
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A series of strict emission control measures were implemented in Beijing and the surrounding seven provinces to ensure good air quality during the 2015 China Victory Day parade, rendering a unique opportunity to investigate anthropogenic impact of aerosol properties. Submicron aerosol hygroscopicity and volatility were measured during and after the control period. By comparison we found aerosol particles became more hydrophobic and volatile due to the emission control measures.
Rui Li, Yunjie Hu, Ling Li, Hongbo Fu, and Jianmin Chen
Atmos. Chem. Phys., 17, 5079–5093, https://doi.org/10.5194/acp-17-5079-2017, https://doi.org/10.5194/acp-17-5079-2017, 2017
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Five episodes were divided based on meteorological conditions and chemical composition. The clear episodes (EP-2 and EP-4) featured low light extinction with fewer pollutants, which are mostly externally mixed. In contrast, EP-1 and EP-5 were impacted by the industrial activities and biomass burning through the southern air mass, respectively. Soot at the fog period detected in EP-3 was mostly internally mixed with sulfates and nitrates.
Chunlin Li, Yunjie Hu, Fei Zhang, Jianmin Chen, Zhen Ma, Xingnan Ye, Xin Yang, Lin Wang, Xingfu Tang, Renhe Zhang, Mu Mu, Guihua Wang, Haidong Kan, Xinming Wang, and Abdelwahid Mellouki
Atmos. Chem. Phys., 17, 4957–4988, https://doi.org/10.5194/acp-17-4957-2017, https://doi.org/10.5194/acp-17-4957-2017, 2017
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Detailed emission factors for smoke particulate species in PM2.5 and PM1.0 were derived from laboratory simulation of crop straw burning using aerosol chamber systems. Based on this, emissions for crop residue field burning in China were calculated and characterized with respect to five different burning scenarios. Moreover, health effects and health-related economic loss from smoke particle exposure were assessed; a practical emission control policy for agricultural field burning was proposed.
Jian Zhao, Wei Du, Yingjie Zhang, Qingqing Wang, Chen Chen, Weiqi Xu, Tingting Han, Yuying Wang, Pingqing Fu, Zifa Wang, Zhanqing Li, and Yele Sun
Atmos. Chem. Phys., 17, 3215–3232, https://doi.org/10.5194/acp-17-3215-2017, https://doi.org/10.5194/acp-17-3215-2017, 2017
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We conducted aerosol particle composition measurements at ground level and 260 m with two aerosol mass spectrometers in Beijing during the 2015 China Victory Day parade. Our results showed a stronger impact of emission controls on inorganic aerosol than OA. A larger decrease in more oxidized SOA than the less oxidized one during the control period was also observed. Our results indicate that emission controls and the changes in meteorological conditions have affected SOA formation mechanisms.
Xiao-Xiao Zhang, Brenton Sharratt, Xi Chen, Zi-Fa Wang, Lian-You Liu, Yu-Hong Guo, Jie Li, Huan-Sheng Chen, and Wen-Yi Yang
Atmos. Chem. Phys., 17, 1699–1711, https://doi.org/10.5194/acp-17-1699-2017, https://doi.org/10.5194/acp-17-1699-2017, 2017
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To improve our understanding of the fate and transport of airborne dust, there is a need for long-term records of dust deposition and concentration. This study characterized the spatial and temporal distribution in dust deposition and concentration in central Asia. The occurrence of high dust deposition and concentration suggests this region is a potential contributor to the global dust budget. This work will strengthen our comprehension of aerosol transport in global desertification regions.
Chen Xu, Junyan Duan, Yanyu Wang, Yifan Wang, Hailin Zhu, Xiang Li, Lingdong Kong, Qianshan He, Tiantao Cheng, and Jianmin Chen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-968, https://doi.org/10.5194/acp-2016-968, 2016
Revised manuscript not accepted
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We intensively examined the influence of polluted aerosol on cloud and precipitation on different underlying surfaces and evaluated relationship between aerosol types and physical properties of clouds under different atmospheric conditions over the YRD. Aerosol plays an important role in cloud evolution in the low layers of troposphere (below 5 km) in the case of the stable atmosphere in wintertime.The results are helpful to in-depth understanding of aerosol indirect effects in Asian.
Yee Jun Tham, Zhe Wang, Qinyi Li, Hui Yun, Weihao Wang, Xinfeng Wang, Likun Xue, Keding Lu, Nan Ma, Birger Bohn, Xin Li, Simonas Kecorius, Johannes Größ, Min Shao, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 16, 14959–14977, https://doi.org/10.5194/acp-16-14959-2016, https://doi.org/10.5194/acp-16-14959-2016, 2016
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This work addresses the unclear global significance of chlorine activation processes in the troposphere. The first high-quality measurement data set of ClNO2 in northern China revealed strong ClNO2 production in the residual layers, and demonstrated its significant effects on radical budget and ozone production. Our findings imply the widespread effects of ClNO2 over the polluted regions of northern China, which may increase photochemical and haze pollution.
Lei Yao, Ming-Yi Wang, Xin-Ke Wang, Yi-Jun Liu, Hang-Fei Chen, Jun Zheng, Wei Nie, Ai-Jun Ding, Fu-Hai Geng, Dong-Fang Wang, Jian-Min Chen, Douglas R. Worsnop, and Lin Wang
Atmos. Chem. Phys., 16, 14527–14543, https://doi.org/10.5194/acp-16-14527-2016, https://doi.org/10.5194/acp-16-14527-2016, 2016
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We present the development of a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) method, utilizing protonated ethanol as reagent ions to simultaneously detect atmospheric gaseous amines (C1 to C6) and amides (C1 to C6). Deployment of this ethanol HR-ToF-CIMS has been demonstrated in a field campaign in urban Shanghai, China, detecting amines (from a few pptv to hundreds of pptv) and amides (from tens of pptv to a few ppbv).
Biwu Chu, Xiao Zhang, Yongchun Liu, Hong He, Yele Sun, Jingkun Jiang, Junhua Li, and Jiming Hao
Atmos. Chem. Phys., 16, 14219–14230, https://doi.org/10.5194/acp-16-14219-2016, https://doi.org/10.5194/acp-16-14219-2016, 2016
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The interactive effects between inorganic and organic species under highly complex pollution conditions remain uncertain and were studied in a smog chamber. This study indicated that the synergistic formation of secondary inorganic and organic aerosol might increase the secondary aerosol load in the atmosphere and contribute haze pollution in eastern China. These synergistic effects were related to the heterogeneous process on aerosol surface and need to be considered in air quality models.
Yi Zhu, Jiping Zhang, Junxia Wang, Wenyuan Chen, Yiqun Han, Chunxiang Ye, Yingruo Li, Jun Liu, Limin Zeng, Yusheng Wu, Xinfeng Wang, Wenxing Wang, Jianmin Chen, and Tong Zhu
Atmos. Chem. Phys., 16, 12551–12565, https://doi.org/10.5194/acp-16-12551-2016, https://doi.org/10.5194/acp-16-12551-2016, 2016
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With five repeated experiments using a mobile laboratory, we obtained the spatial distribution of major air pollutants over the surface of the North China Plain (NCP). All the pollutants were at high levels, with pollutant peak values in nearby major cities and along transport routes. With simulated wind fields, we identified the prevalent transport routes of air pollutants on different parts of the NCP, reflecting the transport of air pollution between megacities and surrounding regions.
Meng Gao, Gregory R. Carmichael, Pablo E. Saide, Zifeng Lu, Man Yu, David G. Streets, and Zifa Wang
Atmos. Chem. Phys., 16, 11837–11851, https://doi.org/10.5194/acp-16-11837-2016, https://doi.org/10.5194/acp-16-11837-2016, 2016
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The WRF-Chem model was used to examine how the winter PM2.5 concentrations change in response to changes in emissions and meteorology in North China from 1960 to 2010. The discussions in this study indicate that dramatic changes in emissions are the main cause of increasing haze events in North China, and long-term trends in atmospheric circulations maybe another important cause. We also found aerosol feedbacks have been significantly enhanced from 1960 to 2010, due to higher aerosol loadings.
Qiang Huang, Jiubin Chen, Weilin Huang, Pingqing Fu, Benjamin Guinot, Xinbin Feng, Lihai Shang, Zhuhong Wang, Zhongwei Wang, Shengliu Yuan, Hongming Cai, Lianfang Wei, and Ben Yu
Atmos. Chem. Phys., 16, 11773–11786, https://doi.org/10.5194/acp-16-11773-2016, https://doi.org/10.5194/acp-16-11773-2016, 2016
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Atmospheric airborne mercury is of particular concern because, once inhaled, both Hg and its vectors might have adverse effects on human beings. In this study, we attempted to identify the sources of PM2.5-Hg in Beijing, China, using Hg isotopic composition. Large range and seasonal variations in both mass-dependent and mass-independent fractionations of Hg isotopes in haze particles demonstrate the usefulness of Hg isotopes for directly tracing the sources and its vectors in the atmosphere.
Lei Sun, Likun Xue, Tao Wang, Jian Gao, Aijun Ding, Owen R. Cooper, Meiyun Lin, Pengju Xu, Zhe Wang, Xinfeng Wang, Liang Wen, Yanhong Zhu, Tianshu Chen, Lingxiao Yang, Yan Wang, Jianmin Chen, and Wenxing Wang
Atmos. Chem. Phys., 16, 10637–10650, https://doi.org/10.5194/acp-16-10637-2016, https://doi.org/10.5194/acp-16-10637-2016, 2016
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We compiled the available observations of surface O3 at Mt. Tai – the highest mountain in the North China Plain, and found a significant increase of O3 concenrations from 2003 to 2015. The observed O3 increase was mainly due to the increase of O3 precursors, especially VOCs. Our analysis shows that controlling NOx alone, in the absence of VOC controls, is not sufficient to reduce regional O3 levels in North China in a short period.
Likun Xue, Rongrong Gu, Tao Wang, Xinfeng Wang, Sandra Saunders, Donald Blake, Peter K. K. Louie, Connie W. Y. Luk, Isobel Simpson, Zheng Xu, Zhe Wang, Yuan Gao, Shuncheng Lee, Abdelwahid Mellouki, and Wenxing Wang
Atmos. Chem. Phys., 16, 9891–9903, https://doi.org/10.5194/acp-16-9891-2016, https://doi.org/10.5194/acp-16-9891-2016, 2016
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The chemical budgets and principal sources of ROx and NO3 radicals during a multi-day photochemical smog episode in Hong Kong are elucidated by an observation-constrained MCM model. NO3 was shown to be an important oxidant even during daytime in a pollution case when high aerosol loading attenuated the solar irradiation. This study suggests the potential important role of daytime NO3 chemistry in polluted atmospheres under conditions with the co-existence of abundant O3, NO2, VOCs, and aerosols.
Xiaole Pan, Itsushi Uno, Yukari Hara, Kazuo Osada, Shigekazu Yamamoto, Zhe Wang, Nobuo Sugimoto, Hiroshi Kobayashi, and Zifa Wang
Atmos. Chem. Phys., 16, 9863–9873, https://doi.org/10.5194/acp-16-9863-2016, https://doi.org/10.5194/acp-16-9863-2016, 2016
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Polarization properties of aerosol particles at a suburban site in the western Japan was studied on the basis of long-term observation and trajectory analysis. This study provides the detailed information on the polarization characteristics of particles from different origins, and proposed a reliable criterion to classify spherical and non-spherical particles. This study introduced a new method to investigate the mixed state of dust particle with anthropogenic pollutant.
Chunpeng Leng, Junyan Duan, Chen Xu, Hefeng Zhang, Yifan Wang, Yanyu Wang, Xiang Li, Lingdong Kong, Jun Tao, Renjian Zhang, Tiantao Cheng, Shuping Zha, and Xingna Yu
Atmos. Chem. Phys., 16, 9221–9234, https://doi.org/10.5194/acp-16-9221-2016, https://doi.org/10.5194/acp-16-9221-2016, 2016
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Meteorological conditions, local anthropogenic emissions and aerosol properties played major roles in this historic winter haze weather formation. Aerosols the size of 600–1400 nm are mostly responsible for the impairment of atmospheric visibility. This study was performed by combining many on-line measurement techniques which were calibrated regularly to ensure reliability, and can act as a reference for forecasting and eliminating the occurrences of regional atmospheric pollutions in China.
Junfeng Wang, Xinlei Ge, Yanfang Chen, Yafei Shen, Qi Zhang, Yele Sun, Jianzhong Xu, Shun Ge, Huan Yu, and Mindong Chen
Atmos. Chem. Phys., 16, 9109–9127, https://doi.org/10.5194/acp-16-9109-2016, https://doi.org/10.5194/acp-16-9109-2016, 2016
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Highly time- and chemically resolved submicron aerosol properties were characterized online for the first time during springtime in Nanjing by using the Aerodyne SP-AMS. Both chemical and size information of black carbon together with other aerosol species were simultaneously determined. An in-depth analysis of the data elucidates the sources and evolution processes of the fine aerosols in the YRD region. Our findings are valuable for air quality remediation in the densely populated regions.
Yele Sun, Wei Du, Pingqing Fu, Qingqing Wang, Jie Li, Xinlei Ge, Qi Zhang, Chunmao Zhu, Lujie Ren, Weiqi Xu, Jian Zhao, Tingting Han, Douglas R. Worsnop, and Zifa Wang
Atmos. Chem. Phys., 16, 8309–8329, https://doi.org/10.5194/acp-16-8309-2016, https://doi.org/10.5194/acp-16-8309-2016, 2016
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We have a comprehensive characterization of the sources, variations and processes of submicron aerosols in Beijing in winter using HR-AMS and GC/MS measurements. The primary sources including traffic, cooking, biomass burning and coal combustion emissions, and secondary components were separated and quantified with PMF. Our results elucidated the important roles of primary emissions, particularly coal combustion, and aqueous-phase processing in the formation of severe air pollution in winter.
Xuezhe Xu, Weixiong Zhao, Qilei Zhang, Shuo Wang, Bo Fang, Weidong Chen, Dean S. Venables, Xinfeng Wang, Wei Pu, Xin Wang, Xiaoming Gao, and Weijun Zhang
Atmos. Chem. Phys., 16, 6421–6439, https://doi.org/10.5194/acp-16-6421-2016, https://doi.org/10.5194/acp-16-6421-2016, 2016
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We report on the field measurement of the optical properties and chemical composition of PM1.0 particles in a suburban environment in Beijing during the winter coal heating season. Organic mass was the largest contributor to the total extinction of PM1.0, while EC, owing to its high absorption efficiency, contributed appreciably to PM1.0 extinction and should be a key target to air quality controls. Non-BC absorption from secondary organic aerosol also contributes to particle absorption.
Xiao Tang, Jiang Zhu, ZiFa Wang, Alex Gbaguidi, CaiYan Lin, JinYuan Xin, Tao Song, and Bo Hu
Atmos. Chem. Phys., 16, 6395–6405, https://doi.org/10.5194/acp-16-6395-2016, https://doi.org/10.5194/acp-16-6395-2016, 2016
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Chemical data assimilation through adjusting precursor emissions has brought out notable impacts on improving ozone forecasts in previous studies. This paper, from another point of view, investigated in detail the impacts of adjusting nitrogen oxide emissions on the forecasts of nitrogen dioxide through assimilating ozone observations. Limitations of the existing chemical data assimilation methods in a highly nonlinear system were identified and highlighted.
Yan-Lin Zhang, Kimitaka Kawamura, Ping Qing Fu, Suresh K. R. Boreddy, Tomomi Watanabe, Shiro Hatakeyama, Akinori Takami, and Wei Wang
Atmos. Chem. Phys., 16, 6407–6419, https://doi.org/10.5194/acp-16-6407-2016, https://doi.org/10.5194/acp-16-6407-2016, 2016
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Here, based on three aircraft measurements over East Asia, we demonstrate an aqueous-phase mechanism for enhanced SOA production in the troposphere following correlation analysis of oxalic acid in tropospheric aerosols with other measured chemical variables including its precursors and its intermediate as well as biogenic-derived SOA from isoprene, monoterpenes and β-caryophyllene.
Fang Zhang, Zhanqing Li, Yanan Li, Yele Sun, Zhenzhu Wang, Ping Li, Li Sun, Pucai Wang, Maureen Cribb, Chuanfeng Zhao, Tianyi Fan, Xin Yang, and Qingqing Wang
Atmos. Chem. Phys., 16, 5413–5425, https://doi.org/10.5194/acp-16-5413-2016, https://doi.org/10.5194/acp-16-5413-2016, 2016
Xianda Gong, Ci Zhang, Hong Chen, Sergey A. Nizkorodov, Jianmin Chen, and Xin Yang
Atmos. Chem. Phys., 16, 5399–5411, https://doi.org/10.5194/acp-16-5399-2016, https://doi.org/10.5194/acp-16-5399-2016, 2016
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In this study, we used a Single Particle Aerosol Mass Spectrometer and a Single Particle Soot Photometer to investigate the chemical and physical properties of black carbon (BC) aerosols during a regional air pollution episode in urban Shanghai. BC containing particles were mainly attributed to biomass burning and traffic emissions. We observed a group of highly aged traffic emitted particles with a relatively small BC core (~ 60–80 nm) and a very thick absolute coating thickness (~ 130–300 nm).
Yan Lyu, Tingting Xu, Xiang Li, Tiantao Cheng, Xin Yang, Xiaomin Sun, and Jianmin Chen
Atmos. Meas. Tech., 9, 1025–1037, https://doi.org/10.5194/amt-9-1025-2016, https://doi.org/10.5194/amt-9-1025-2016, 2016
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This study presents the particle size distribution of PBDEs in the atmosphere of a megacity and evaluates the contribution of size-fractionated PBDEs' deposition in the human respiratory tract.
Yan Lv, Xiang Li, Ting Ting Xu, Tian Tao Cheng, Xin Yang, Jian Min Chen, Yoshiteru Iinuma, and Hartmut Herrmann
Atmos. Chem. Phys., 16, 2971–2983, https://doi.org/10.5194/acp-16-2971-2016, https://doi.org/10.5194/acp-16-2971-2016, 2016
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The study focused on size-resolved PAHs in urban aerosols at a megacity Shanghai site. The results provide us with a mechanistic understanding of the particle size distribution of PAHs and their transport in the human respiratory system; this can help develop better source control strategies.
Wei Deng, Qihou Hu, Tengyu Liu, Xinming Wang, Yanli Zhang, Xiang Ding, Yele Sun, Xinhui Bi, Jianzhen Yu, Weiqiang Yang, Xinyu Huang, Zhou Zhang, Zhonghui Huang, Quanfu He, A. Mellouki, and Christian George
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-50, https://doi.org/10.5194/acp-2016-50, 2016
Revised manuscript not accepted
Xin Ke Wang, Stéphanie Rossignol, Ye Ma, Lei Yao, Ming Yi Wang, Jian Min Chen, Christian George, and Lin Wang
Atmos. Chem. Phys., 16, 2285–2298, https://doi.org/10.5194/acp-16-2285-2016, https://doi.org/10.5194/acp-16-2285-2016, 2016
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PM2.5 filter samples have been collected in three megacities at the middle and lower reaches of the Yangtze River: Wuhan, Nanjing, and Shanghai. The samples were analyzed using ultra-high-performance liquid chromatography coupled with Orbitrap mass spectrometry, which allowed for detection of about 200 formulas of particulate organosulfates, including dozens of formulas of nitrooxy-organosulfates, with various numbers of isomers for each tentatively determined formula at each location.
M. Gao, G. R. Carmichael, Y. Wang, P. E. Saide, M. Yu, J. Xin, Z. Liu, and Z. Wang
Atmos. Chem. Phys., 16, 1673–1691, https://doi.org/10.5194/acp-16-1673-2016, https://doi.org/10.5194/acp-16-1673-2016, 2016
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The WRF-Chem model was applied to study the 2010 winter haze in North China. Air pollutants outside Beijing contributed about 64.5 % to the PM2.5 levels in Beijing during this haze event, and most of them are from south Hebei, Tianjin city, Shandong and Henan provinces. In addition, aerosol feedback has important impacts on surface temperature, Relative Humidity (RH) and wind speeds, and these meteorological variables affect aerosol distribution and formation in turn.
Y. Q. Yang, J. Z. Wang, S. L. Gong, X. Y. Zhang, H. Wang, Y. Q. Wang, J. Wang, D. Li, and J. P. Guo
Atmos. Chem. Phys., 16, 1353–1364, https://doi.org/10.5194/acp-16-1353-2016, https://doi.org/10.5194/acp-16-1353-2016, 2016
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A new model, PLAM/h, has been developed and used in near-real-time air quality forecasts by considering both meteorology and pollutant emissions, based on the two-dimensional probability density function diagnosis model for emissions. The results show that combining the influence of regular meteorological conditions and emission factors together in the PLAM/h parameterization scheme is very effective in improving the forecasting ability for fog-haze weather in North China.
P. Wang, H. Wang, Y. Q. Wang, X. Y. Zhang, S. L. Gong, M. Xue, C. H. Zhou, H. L. Liu, X. Q. An, T. Niu, and Y. L. Cheng
Atmos. Chem. Phys., 16, 989–1002, https://doi.org/10.5194/acp-16-989-2016, https://doi.org/10.5194/acp-16-989-2016, 2016
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An ensemble optimal interpolation (EnOI) data assimilation technique is used to investigate the possibility of optimally recovering the spatially resolved emissions bias of BC. The inversed emission over China in January is 240.1 Gg, and annual emission is about 2539 Gg. Even though only monthly mean BC measurements are employed to inverse the emissions, the accuracy of the daily model simulation improves. We finds that EnOI is a useful and computation-free method to make top-down estimation.
T. Liu, X. Wang, Q. Hu, W. Deng, Y. Zhang, X. Ding, X. Fu, F. Bernard, Z. Zhang, S. Lü, Q. He, X. Bi, J. Chen, Y. Sun, J. Yu, P. Peng, G. Sheng, and J. Fu
Atmos. Chem. Phys., 16, 675–689, https://doi.org/10.5194/acp-16-675-2016, https://doi.org/10.5194/acp-16-675-2016, 2016
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The formation of SOA and sulfate aerosols from the photooxidation of gasoline vehicle exhaust (GVE) when mixing with SO2 was investigated in a smog chamber. We found that the presence of GVE enhanced the conversion of SO2 to sulfate predominantly through reactions with stabilized Criegee intermediates. On the other hand, the elevated particle acidity enhanced the SOA production from GVE. This study indicated that SO2 and GVE could enhance each other in forming secondary aerosols.
S. Kundu, K. Kawamura, M. Kobayashi, E. Tachibana, M. Lee, P. Q. Fu, and J. Jung
Atmos. Chem. Phys., 16, 585–596, https://doi.org/10.5194/acp-16-585-2016, https://doi.org/10.5194/acp-16-585-2016, 2016
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Chemistry-transport models have predicted a change in secondary organic aerosols (SOA) in the future atmosphere with a large uncertainty. This study measures diacids, major water-soluble surrogates of SOA, on a sub-decadal scale in atmospheric aerosols in eastern Asia. Diacids are observed to increase by 3.9–47.4 % per year. The increases in the water-soluble organic acid fraction could modify the aerosol organic composition and its sensitivity to climate-relevant physical properties.
C. Zhou, X. Zhang, S. Gong, Y. Wang, and M. Xue
Atmos. Chem. Phys., 16, 145–160, https://doi.org/10.5194/acp-16-145-2016, https://doi.org/10.5194/acp-16-145-2016, 2016
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A comprehensive aerosol-cloud-precipitation interaction (ACI) scheme from emissions to precipitation has been developed under the CMA chemical weather modeling system GRAPES/CUACE. The ACI for January 2013 has been studied using this model. The interactive microphysical properties of clouds improve the precipitation, showing 24 to 48 % enhancements of threat score for 6 h precipitation in all regions and reduction of the regional mean bias of temperature by 3 °C in certain precipitation events.
W. Q. Xu, Y. L. Sun, C. Chen, W. Du, T. T. Han, Q. Q. Wang, P. Q. Fu, Z. F. Wang, X. J. Zhao, L. B. Zhou, D. S. Ji, P. C. Wang, and D. R. Worsnop
Atmos. Chem. Phys., 15, 13681–13698, https://doi.org/10.5194/acp-15-13681-2015, https://doi.org/10.5194/acp-15-13681-2015, 2015
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We have investigated the response of aerosol composition, size distributions, and oxidation properties to emission controls during the 2014 Asia- Pacific Economic Cooperation (APEC) summit in Beijing. Our results showed substantial changes of aerosol bulk composition during APEC with the most reductions in secondary aerosols in large accumulation modes, demonstrating that that emission controls over regional scales can substantially reduce secondary particulates.
Y. Q. Wang, X. Y. Zhang, J. Y. Sun, X. C. Zhang, H. Z. Che, and Y. Li
Atmos. Chem. Phys., 15, 13585–13598, https://doi.org/10.5194/acp-15-13585-2015, https://doi.org/10.5194/acp-15-13585-2015, 2015
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Concentrations of PM10, PM2.5 and PM1 were monitored at 24 stations of CAWNET from 2006 to 2014. The average levels of particulate matter (PM) concentrations and relationships were investigated. Seasonal, interannual and diurnal variations of the PM were revealed. The effects of meteorological factors on the PM were discussed. The highest PM concentrations were observed at the stations of Xian, Zhengzhou and Gucheng, in Guanzhong and the Huabei Plain.
W. J. Li, S. R. Chen, Y. S. Xu, X. C. Guo, Y. L. Sun, X. Y. Yang, Z. F. Wang, X. D. Zhao, J. M. Chen, and W. X. Wang
Atmos. Chem. Phys., 15, 13365–13376, https://doi.org/10.5194/acp-15-13365-2015, https://doi.org/10.5194/acp-15-13365-2015, 2015
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We found that anthropogenic soot, fly ash, and visible organic particles likely adhere to the surface of secondary inorganic particles larger than 200nm due to coagulation. Biomass burning and coal combustion both constantly contribute to anthropogenic particles in the Qinghai-Tibet Plateau (QTP) background atmosphere. Organic coating and soot on the surface of the aged particles could have different impacts on their hygroscopic and optical properties in the QTP compared to the urban aerosols.
X. Y. Zhang, J. Z. Wang, Y. Q. Wang, H. L. Liu, J. Y. Sun, and Y. M. Zhang
Atmos. Chem. Phys., 15, 12935–12952, https://doi.org/10.5194/acp-15-12935-2015, https://doi.org/10.5194/acp-15-12935-2015, 2015
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No obvious changes were found in annual mean concentrations of major chemical components and PM10 in 2013, relative to 2012. But wintertime mass were quite different; approximately 60% of the winter mass increase from 2012 to 2013 can be attributed to severe meteorological conditions in the HBP area, and mass of chemical components exhibited a decline during 2006 to 2010, and then a rise till 2013. Coal-combustion was still the largest anthropogenic source of aerosol pollution in 2013 in China.
C. Chen, Y. L. Sun, W. Q. Xu, W. Du, L. B. Zhou, T. T. Han, Q. Q. Wang, P. Q. Fu, Z. F. Wang, Z. Q. Gao, Q. Zhang, and D. R. Worsnop
Atmos. Chem. Phys., 15, 12879–12895, https://doi.org/10.5194/acp-15-12879-2015, https://doi.org/10.5194/acp-15-12879-2015, 2015
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A comprehensive characterization of submicron aerosol composition and sources at 260m in urban Beijing during APEC 2014 is presented. Aerosol species were shown to decrease substantially by 40–80% during APEC, whereas the bulk composition was relatively similar to the result of synergetic controls of secondary precursors. Our results elucidated that the good air quality during APEC was the combined result of emission controls and meteorological effects, with the former playing the dominant role.
J. Zheng, J. Zhu, Z. Wang, F. Fang, C. C. Pain, and J. Xiang
Geosci. Model Dev., 8, 3421–3440, https://doi.org/10.5194/gmd-8-3421-2015, https://doi.org/10.5194/gmd-8-3421-2015, 2015
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A new anisotropic hr-adaptive mesh technique has been applied to modelling of multiscale transport phenomena. Over existing air quality models typically based on static-structured grids using a locally nesting technique, the advantage of the anisotropic hr-adaptive model has the ability to adapt the mesh according to the evolving pollutant distribution and flow features. To illustrate its capability, comparisons have been made between the results obtained using adaptive and uniform meshes.
J. W. Chi, W. J. Li, D. Z. Zhang, J. C. Zhang, Y. T. Lin, X. J. Shen, J. Y. Sun, J. M. Chen, X. Y. Zhang, Y. M. Zhang, and W. X. Wang
Atmos. Chem. Phys., 15, 11341–11353, https://doi.org/10.5194/acp-15-11341-2015, https://doi.org/10.5194/acp-15-11341-2015, 2015
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Sea salt aerosols (SSA) are dominant particles in the Arctic atmosphere. Our result suggests that the hydrophilic MgCl2 coating in fresh SSA likely intrigued the heterogeneous reactions at the beginning of SSA and acidic gases in the Arctic. The content of organic matter increased in the aged SSA compared with the fresh SSA, which suggests organic acids (beside inorganic acids) participate in the ageing of SSA in the Arctic.
L. K. Xue, S. M. Saunders, T. Wang, R. Gao, X. F. Wang, Q. Z. Zhang, and W. X. Wang
Geosci. Model Dev., 8, 3151–3162, https://doi.org/10.5194/gmd-8-3151-2015, https://doi.org/10.5194/gmd-8-3151-2015, 2015
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A detailed chemical mechanism including 205 reactions is developed for use in the Master Chemical Mechanism. With this new chlorine mechanism, it was found that the nocturnal formation of ClNO2 has high potential to perturb the next day's atmospheric photochemistry, by enhancing the radical production and cycling, VOC oxidation and O3 formation, in the polluted coastal environments.
W. Du, Y. L. Sun, Y. S. Xu, Q. Jiang, Q. Q. Wang, W. Yang, F. Wang, Z. P. Bai, X. D. Zhao, and Y. C. Yang
Atmos. Chem. Phys., 15, 10811–10824, https://doi.org/10.5194/acp-15-10811-2015, https://doi.org/10.5194/acp-15-10811-2015, 2015
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A fall field campaign was conducted at a national background site (3295m a.s.l.) over the Tibetan Plateau. The submicron aerosol was dominated by organics (43%) and sulfate (28%). Secondary organic aerosol (SOA) dominated OA (85%), 17% of which being aged biomass burning OA. New particle formation and growth events were frequently observed, with an average particle growth rate of 2.0nm per hour. The important role of organics in particle growth in the Tibetan Plateau was also demonstrated.
H. S. Chen, Z. F. Wang, J. Li, X. Tang, B. Z. Ge, X. L. Wu, O. Wild, and G. R. Carmichael
Geosci. Model Dev., 8, 2857–2876, https://doi.org/10.5194/gmd-8-2857-2015, https://doi.org/10.5194/gmd-8-2857-2015, 2015
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A new global nested atmospheric mercury transport model was developed and introduced. Model performance was found significantly better in North America and Europe than in East Asia. Nested simulation has been conducted in East Asia and shows improved skill at capturing the high spatial variability of Hg concentrations and deposition. The trans-boundary transport of Chinese primary anthropogenic mercury emissions was quantified for the first time.
Y. L. Sun, Z. F. Wang, W. Du, Q. Zhang, Q. Q. Wang, P. Q. Fu, X. L. Pan, J. Li, J. Jayne, and D. R. Worsnop
Atmos. Chem. Phys., 15, 10149–10165, https://doi.org/10.5194/acp-15-10149-2015, https://doi.org/10.5194/acp-15-10149-2015, 2015
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We conducted the first long-term real-time measurement of submicron aerosol composition in Beijing using an ACSM for 1 year. The seasonal variations of mass concentrations and chemical composition of submicron aerosol were investigated in detail, and the meteorological effects on aerosol chemistry, particularly temperature and relative humidity, were elucidated. Finally, the potential source areas of aerosol species during four seasons were identified.
C. M. Pavuluri, K. Kawamura, and P. Q. Fu
Atmos. Chem. Phys., 15, 9883–9896, https://doi.org/10.5194/acp-15-9883-2015, https://doi.org/10.5194/acp-15-9883-2015, 2015
T. Liu, X. Wang, W. Deng, Q. Hu, X. Ding, Y. Zhang, Q. He, Z. Zhang, S. Lü, X. Bi, J. Chen, and J. Yu
Atmos. Chem. Phys., 15, 9049–9062, https://doi.org/10.5194/acp-15-9049-2015, https://doi.org/10.5194/acp-15-9049-2015, 2015
T. Li, Y. Wang, W. J. Li, J. M. Chen, T. Wang, and W. X. Wang
Atmos. Chem. Phys., 15, 8987–9002, https://doi.org/10.5194/acp-15-8987-2015, https://doi.org/10.5194/acp-15-8987-2015, 2015
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Twelve trace elements in fine particles and clouds at a mountain site in southern China were investigated.
Long-range transport contributed the most to element concentrations, whereas the YRD and the area around Mt. Lushan exhibited the highest element solubility.
We demonstrated that cloud processing can enhance aerosol element solubility and increase sulfate concentration correspondingly, by irreversibly altering the morphology of metal particles in cloud droplet residues.
L. Zhang, J. Y. Sun, X. J. Shen, Y. M. Zhang, H. Che, Q. L. Ma, Y. W. Zhang, X. Y. Zhang, and J. A. Ogren
Atmos. Chem. Phys., 15, 8439–8454, https://doi.org/10.5194/acp-15-8439-2015, https://doi.org/10.5194/acp-15-8439-2015, 2015
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The aerosol hygroscopic properties at a rural background site in the Yangtze River delta of China was discussed. The results show the scattering coefficient and backscattering coefficient increased by 58 and 25% as relative humidity (RH) increased from 40 to 85%, while the hemispheric backscatter fraction decreased by 21%. Aerosol hygroscopic growth caused a 47% increase in calculated aerosol direct radiative forcing at 85% RH compared to the forcing at 40% RH. Nitrate played a vital role.
Y. R. Yang, X. G. Liu, Y. Qu, J. L. An, R. Jiang, Y. H. Zhang, Y. L. Sun, Z. J. Wu, F. Zhang, W. Q. Xu, and Q. X. Ma
Atmos. Chem. Phys., 15, 8165–8178, https://doi.org/10.5194/acp-15-8165-2015, https://doi.org/10.5194/acp-15-8165-2015, 2015
H. Che, X.-Y. Zhang, X. Xia, P. Goloub, B. Holben, H. Zhao, Y. Wang, X.-C. Zhang, H. Wang, L. Blarel, B. Damiri, R. Zhang, X. Deng, Y. Ma, T. Wang, F. Geng, B. Qi, J. Zhu, J. Yu, Q. Chen, and G. Shi
Atmos. Chem. Phys., 15, 7619–7652, https://doi.org/10.5194/acp-15-7619-2015, https://doi.org/10.5194/acp-15-7619-2015, 2015
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This work studied more than 10 years of measurements of aerosol optical depths (AODs) made for 50 sites of CARSNET compiled into a climatology of aerosol optical properties for China. It lets us see a detailed full-scale description of AOD observations over China. The results would benefit us a lot in comprehending the temporal and special distribution aerosol optical property over China. Also the data would be valuable to communities of aerosol satellite retrieval, modelling, etc.
X. Pan, Y. Kanaya, H. Tanimoto, S. Inomata, Z. Wang, S. Kudo, and I. Uno
Atmos. Chem. Phys., 15, 6101–6111, https://doi.org/10.5194/acp-15-6101-2015, https://doi.org/10.5194/acp-15-6101-2015, 2015
Q. Jiang, Y. L. Sun, Z. Wang, and Y. Yin
Atmos. Chem. Phys., 15, 6023–6034, https://doi.org/10.5194/acp-15-6023-2015, https://doi.org/10.5194/acp-15-6023-2015, 2015
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Aerosol composition and sources during the Chinese spring festival are characterized in detail. The roles of fireworks and secondary aerosol in fine particle pollution were elucidated. We observed large reductions of primary species, whereas changes of secondary aerosol during the holiday period were minor. This has significant implications; reducing primary emissions on a local scale during severe haze episodes might have a limited effect on improving air quality in megacities.
Z. L. Wang, H. Zhang, and X. Y. Zhang
Atmos. Chem. Phys., 15, 3671–3685, https://doi.org/10.5194/acp-15-3671-2015, https://doi.org/10.5194/acp-15-3671-2015, 2015
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This study highlights that there are no effective ways to remove the black carbon exclusively without influencing the other co-emitted components, our results therefore indicate that a reduction in BC emission can lead to an unexpected warming on the Earth’s climate system in the future.
H. Wang, M. Xue, X. Y. Zhang, H. L. Liu, C. H. Zhou, S. C. Tan, H. Z. Che, B. Chen, and T. Li
Atmos. Chem. Phys., 15, 3257–3275, https://doi.org/10.5194/acp-15-3257-2015, https://doi.org/10.5194/acp-15-3257-2015, 2015
S. Xiao, M. Y. Wang, L. Yao, M. Kulmala, B. Zhou, X. Yang, J. M. Chen, D. F. Wang, Q. Y. Fu, D. R. Worsnop, and L. Wang
Atmos. Chem. Phys., 15, 1769–1781, https://doi.org/10.5194/acp-15-1769-2015, https://doi.org/10.5194/acp-15-1769-2015, 2015
Z. Cong, S. Kang, K. Kawamura, B. Liu, X. Wan, Z. Wang, S. Gao, and P. Fu
Atmos. Chem. Phys., 15, 1573–1584, https://doi.org/10.5194/acp-15-1573-2015, https://doi.org/10.5194/acp-15-1573-2015, 2015
Y. J. Zhang, L. L. Tang, Z. Wang, H. X. Yu, Y. L. Sun, D. Liu, W. Qin, F. Canonaco, A. S. H. Prévôt, H. L. Zhang, and H. C. Zhou
Atmos. Chem. Phys., 15, 1331–1349, https://doi.org/10.5194/acp-15-1331-2015, https://doi.org/10.5194/acp-15-1331-2015, 2015
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The chemical composition, sources, and evolution processes of PM1 were investigated with an Aerodyne ACSM during harvest seasons in the Yangtze River delta, China. Two biomass burning organic aerosol (BBOA) factors derived from PMF model were assessed. The oxidized BBOA contributes ~80% of the total BBOA loadings in the BB plumes. Evidence that BBOA may be oxidized to more aged and less volatile organics during the aging process was suggested.
L. K. Xue, T. Wang, J. Gao, A. J. Ding, X. H. Zhou, D. R. Blake, X. F. Wang, S. M. Saunders, S. J. Fan, H. C. Zuo, Q. Z. Zhang, and W. X. Wang
Atmos. Chem. Phys., 14, 13175–13188, https://doi.org/10.5194/acp-14-13175-2014, https://doi.org/10.5194/acp-14-13175-2014, 2014
C. Leng, Q. Zhang, D. Zhang, C. Xu, T. Cheng, R. Zhang, J. Tao, J. Chen, S. Zha, Y. Zhang, X. Li, L. Kong, and W. Gao
Atmos. Chem. Phys., 14, 12499–12512, https://doi.org/10.5194/acp-14-12499-2014, https://doi.org/10.5194/acp-14-12499-2014, 2014
Y. M. Zhang, X. Y. Zhang, J. Y. Sun, G. Y. Hu, X. J. Shen, Y. Q. Wang, T. T. Wang, D. Z. Wang, and Y. Zhao
Atmos. Chem. Phys., 14, 12237–12249, https://doi.org/10.5194/acp-14-12237-2014, https://doi.org/10.5194/acp-14-12237-2014, 2014
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An AMS was employed to measure the mass and size distributions of PM1 at an elevated site. Features of PM1 at four seasons, during different kinds of episodes including NPF, polluted, PBL, LFT and in-cloud, were discussed. The characterizations of PM1 at seven clusters of air masses were also analyzed. BBOA, CCOA and oxidized organic aerosols were resolved by AMS-PMF (positive matrix function). Almost half of OA were oxidized, and BBOA is 34% of OA in summer; CCOA is 22% of OA in winter as well.
C. Leng, Q. Zhang, J. Tao, H. Zhang, D. Zhang, C. Xu, X. Li, L. Kong, T. Cheng, R. Zhang, X. Yang, J. Chen, L. Qiao, S. Lou, H. Wang, and C. Chen
Atmos. Chem. Phys., 14, 11353–11365, https://doi.org/10.5194/acp-14-11353-2014, https://doi.org/10.5194/acp-14-11353-2014, 2014
K. Tsigaridis, N. Daskalakis, M. Kanakidou, P. J. Adams, P. Artaxo, R. Bahadur, Y. Balkanski, S. E. Bauer, N. Bellouin, A. Benedetti, T. Bergman, T. K. Berntsen, J. P. Beukes, H. Bian, K. S. Carslaw, M. Chin, G. Curci, T. Diehl, R. C. Easter, S. J. Ghan, S. L. Gong, A. Hodzic, C. R. Hoyle, T. Iversen, S. Jathar, J. L. Jimenez, J. W. Kaiser, A. Kirkevåg, D. Koch, H. Kokkola, Y. H Lee, G. Lin, X. Liu, G. Luo, X. Ma, G. W. Mann, N. Mihalopoulos, J.-J. Morcrette, J.-F. Müller, G. Myhre, S. Myriokefalitakis, N. L. Ng, D. O'Donnell, J. E. Penner, L. Pozzoli, K. J. Pringle, L. M. Russell, M. Schulz, J. Sciare, Ø. Seland, D. T. Shindell, S. Sillman, R. B. Skeie, D. Spracklen, T. Stavrakou, S. D. Steenrod, T. Takemura, P. Tiitta, S. Tilmes, H. Tost, T. van Noije, P. G. van Zyl, K. von Salzen, F. Yu, Z. Wang, Z. Wang, R. A. Zaveri, H. Zhang, K. Zhang, Q. Zhang, and X. Zhang
Atmos. Chem. Phys., 14, 10845–10895, https://doi.org/10.5194/acp-14-10845-2014, https://doi.org/10.5194/acp-14-10845-2014, 2014
Q. Z. Wu, W. S. Xu, A. J. Shi, Y. T. Li, X. J. Zhao, Z. F. Wang, J. X. Li, and L. N. Wang
Geosci. Model Dev., 7, 2243–2259, https://doi.org/10.5194/gmd-7-2243-2014, https://doi.org/10.5194/gmd-7-2243-2014, 2014
L. D. Kong, X. Zhao, Z. Y. Sun, Y. W. Yang, H. B. Fu, S. C. Zhang, T. T. Cheng, X. Yang, L. Wang, and J. M. Chen
Atmos. Chem. Phys., 14, 9451–9467, https://doi.org/10.5194/acp-14-9451-2014, https://doi.org/10.5194/acp-14-9451-2014, 2014
X. H. Liu, Y. J. Zhu, M. Zheng, H. W. Gao, and X. H. Yao
Atmos. Chem. Phys., 14, 7941–7951, https://doi.org/10.5194/acp-14-7941-2014, https://doi.org/10.5194/acp-14-7941-2014, 2014
P. Q. Fu, K. Kawamura, Y. F. Cheng, S. Hatakeyama, A. Takami, H. Li, and W. Wang
Atmos. Chem. Phys., 14, 4185–4199, https://doi.org/10.5194/acp-14-4185-2014, https://doi.org/10.5194/acp-14-4185-2014, 2014
H. Che, X. Xia, J. Zhu, Z. Li, O. Dubovik, B. Holben, P. Goloub, H. Chen, V. Estelles, E. Cuevas-Agulló, L. Blarel, H. Wang, H. Zhao, X. Zhang, Y. Wang, J. Sun, R. Tao, X. Zhang, and G. Shi
Atmos. Chem. Phys., 14, 2125–2138, https://doi.org/10.5194/acp-14-2125-2014, https://doi.org/10.5194/acp-14-2125-2014, 2014
X. Wang, T. Wang, C. Yan, Y. J. Tham, L. Xue, Z. Xu, and Q. Zha
Atmos. Meas. Tech., 7, 1–12, https://doi.org/10.5194/amt-7-1-2014, https://doi.org/10.5194/amt-7-1-2014, 2014
L. K. Xue, T. Wang, J. Gao, A. J. Ding, X. H. Zhou, D. R. Blake, X. F. Wang, S. M. Saunders, S. J. Fan, H. C. Zuo, Q. Z. Zhang, and W. X. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-27243-2013, https://doi.org/10.5194/acpd-13-27243-2013, 2013
Revised manuscript not accepted
Y. Kanaya, H. Akimoto, Z.-F. Wang, P. Pochanart, K. Kawamura, Y. Liu, J. Li, Y. Komazaki, H. Irie, X.-L. Pan, F. Taketani, K. Yamaji, H. Tanimoto, S. Inomata, S. Kato, J. Suthawaree, K. Okuzawa, G. Wang, S. G. Aggarwal, P. Q. Fu, T. Wang, J. Gao, Y. Wang, and G. Zhuang
Atmos. Chem. Phys., 13, 8265–8283, https://doi.org/10.5194/acp-13-8265-2013, https://doi.org/10.5194/acp-13-8265-2013, 2013
K. Kawamura, E. Tachibana, K. Okuzawa, S. G. Aggarwal, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys., 13, 8285–8302, https://doi.org/10.5194/acp-13-8285-2013, https://doi.org/10.5194/acp-13-8285-2013, 2013
A. Petzold, J. A. Ogren, M. Fiebig, P. Laj, S.-M. Li, U. Baltensperger, T. Holzer-Popp, S. Kinne, G. Pappalardo, N. Sugimoto, C. Wehrli, A. Wiedensohler, and X.-Y. Zhang
Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, https://doi.org/10.5194/acp-13-8365-2013, 2013
H. Jiang, H. Liao, H. O. T. Pye, S. Wu, L. J. Mickley, J. H. Seinfeld, and X. Y. Zhang
Atmos. Chem. Phys., 13, 7937–7960, https://doi.org/10.5194/acp-13-7937-2013, https://doi.org/10.5194/acp-13-7937-2013, 2013
Y. Cheng, G. Engling, K.-B. He, F.-K. Duan, Y.-L. Ma, Z.-Y. Du, J.-M. Liu, M. Zheng, and R. J. Weber
Atmos. Chem. Phys., 13, 7765–7781, https://doi.org/10.5194/acp-13-7765-2013, https://doi.org/10.5194/acp-13-7765-2013, 2013
Y. Zhang, K. Sartelet, S. Zhu, W. Wang, S.-Y. Wu, X. Zhang, K. Wang, P. Tran, C. Seigneur, and Z.-F. Wang
Atmos. Chem. Phys., 13, 6845–6875, https://doi.org/10.5194/acp-13-6845-2013, https://doi.org/10.5194/acp-13-6845-2013, 2013
N. He, K. Kawamura, K. Okuzawa, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-16699-2013, https://doi.org/10.5194/acpd-13-16699-2013, 2013
Revised manuscript not accepted
K. Kawamura, K. Okuzawa, S. G. Aggarwal, H. Irie, Y. Kanaya, and Z. Wang
Atmos. Chem. Phys., 13, 5369–5380, https://doi.org/10.5194/acp-13-5369-2013, https://doi.org/10.5194/acp-13-5369-2013, 2013
Y. L. Sun, Z. F. Wang, P. Q. Fu, T. Yang, Q. Jiang, H. B. Dong, J. Li, and J. J. Jia
Atmos. Chem. Phys., 13, 4577–4592, https://doi.org/10.5194/acp-13-4577-2013, https://doi.org/10.5194/acp-13-4577-2013, 2013
Y. Huang, L. Li, J. Li, X. Wang, H. Chen, J. Chen, X. Yang, D. S. Gross, H. Wang, L. Qiao, and C. Chen
Atmos. Chem. Phys., 13, 3931–3944, https://doi.org/10.5194/acp-13-3931-2013, https://doi.org/10.5194/acp-13-3931-2013, 2013
C. M. Pavuluri, K. Kawamura, N. Mihalopoulos, and P. Fu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-6589-2013, https://doi.org/10.5194/acpd-13-6589-2013, 2013
Revised manuscript not accepted
P. Q. Fu, K. Kawamura, J. Chen, B. Charrière, and R. Sempéré
Biogeosciences, 10, 653–667, https://doi.org/10.5194/bg-10-653-2013, https://doi.org/10.5194/bg-10-653-2013, 2013
G. H. Wang, B. H. Zhou, C. L. Cheng, J. J. Cao, J. J. Li, J. J. Meng, J. Tao, R. J. Zhang, and P. Q. Fu
Atmos. Chem. Phys., 13, 819–835, https://doi.org/10.5194/acp-13-819-2013, https://doi.org/10.5194/acp-13-819-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Influence of terrestrial and marine air mass on the constituents and intermixing of bioaerosols over a coastal atmosphere
A multi-site passive approach to studying the emissions and evolution of smoke from prescribed fires
The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition
Opinion: How will advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution?
Measurement report: Intra-annual variability of black carbon and brown carbon and their interrelation with meteorological conditions over Gangtok, Sikkim
Long-range transport of air pollutants increases the concentration of hazardous components of PM2.5 in northern South America
Dominant influence of biomass combustion and cross-border transport on nitrogen-containing organic compound levels in the southeastern Tibetan Plateau
Impacts of elevated anthropogenic emissions on physicochemical characteristics of black-carbon-containing particles over the Tibetan Plateau
Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses
Atmospheric evolution of environmentally persistent free radicals in the rural North China Plain: effects on water solubility and PM2.5 oxidative potential
Two distinct ship emission profiles for organic-sulfate source apportionment of PM in sulfur emission control areas
Automated compound speciation, cluster analysis, and quantification of organic vapors and aerosols using comprehensive two-dimensional gas chromatography and mass spectrometry
Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints
Bridging gas and aerosol properties between the northeastern US and Bermuda: analysis of eight transit flights
The behaviour of charged particles (ions) during new particle formation events in urban Leipzig, Germany
Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China
Measurement report: Characteristics of airborne black-carbon-containing particles during the 2021 summer COVID-19 lockdown in a typical Yangtze River Delta city, China
Aerosol optical properties within the atmospheric boundary layer predicted from ground-based observations compared to Raman lidar retrievals during RITA-2021
Hygroscopic growth and activation changed submicron aerosol composition and properties in the North China Plain
Measurement report: Formation of tropospheric brown carbon in a lifting air mass
Vertical variability of aerosol properties and trace gases over a remote marine region: a case study over Bermuda
Differences in aerosol and cloud properties along the central California coast when winds change from northerly to southerly
International airport emissions and their impact on local air quality: chemical speciation of ambient aerosols at Madrid–Barajas Airport during the AVIATOR campaign
Significant role of biomass burning in heavy haze formation in a megacity: Molecular-level insights from intensive PM2.5 sampling on winter hazy days
The local ship speed reduction effect on black carbon emissions measured at a remote marine station
High-altitude aerosol chemical characterization and source identification: insights from the CALISHTO campaign
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – a short-term case study in Beijing
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Impact of cloud processes on secondary organic aerosols at a forested mountain site in southeastern China
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Seasonal Investigation of Ultrafine Particle Composition in an Eastern Amazonian Rainforest
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic in Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Technical note: Quantified organic aerosol subsaturated hygroscopicity by a simple optical scatter monitor system through field measurements
Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean
The water-insoluble organic carbon in PM2.5 of typical Chinese urban areas: light-absorbing properties, potential sources, radiative forcing effects, and a possible light-absorbing continuum
Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
Non-sea-salt aerosols that contain trace bromine and iodine are widespread in the remote troposphere
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
High-resolution analyses of concentrations and sizes of black carbon particles deposited on northwest Greenland over the past 350 years – Part 2: Seasonal and temporal trends in black carbon originated from fossil fuel combustion and biomass burning
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Formation and chemical evolution of SOA in two different environments: A dual chamber study
Enhanced daytime secondary aerosol formation driven by gas-particle partitioning in downwind urban plumes
Qun He, Zhaowen Wang, Houfeng Liu, Pengju Xu, Rongbao Duan, Caihong Xu, Jianmin Chen, and Min Wei
Atmos. Chem. Phys., 24, 12775–12792, https://doi.org/10.5194/acp-24-12775-2024, https://doi.org/10.5194/acp-24-12775-2024, 2024
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Coastal environments provide an ideal setting for investigating the intermixing of terrestrial and marine aerosols. Terrestrial air mass constituted a larger number of microbes from anthropogenic and soil emissions, whereas saprophytic and gut microbes were predominant in marine samples. Mixed air masses indicated a fusion of marine and terrestrial aerosols, characterized by alterations in the ratio of pathogenic and saprophytic microbes when compared to either terrestrial or marine samples.
Rime El Asmar, Zongrun Li, David J. Tanner, Yongtao Hu, Susan O'Neill, L. Gregory Huey, M. Talat Odman, and Rodney J. Weber
Atmos. Chem. Phys., 24, 12749–12773, https://doi.org/10.5194/acp-24-12749-2024, https://doi.org/10.5194/acp-24-12749-2024, 2024
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Prescribed burning is an important method for managing ecosystems and preventing wildfires. However, smoke from prescribed fires can have a significant impact on air quality. Here, using a network of fixed sites and sampling throughout an extended prescribed burning period in 2 different years, we characterize emissions and evolutions of up to 8 h of PM2.5 mass, black carbon (BC), and brown carbon (BrC) in smoke from burning of forested lands in the southeastern USA.
Matthew Boyer, Diego Aliaga, Lauriane L. J. Quéléver, Silvia Bucci, Hélène Angot, Lubna Dada, Benjamin Heutte, Lisa Beck, Marina Duetsch, Andreas Stohl, Ivo Beck, Tiia Laurila, Nina Sarnela, Roseline C. Thakur, Branka Miljevic, Markku Kulmala, Tuukka Petäjä, Mikko Sipilä, Julia Schmale, and Tuija Jokinen
Atmos. Chem. Phys., 24, 12595–12621, https://doi.org/10.5194/acp-24-12595-2024, https://doi.org/10.5194/acp-24-12595-2024, 2024
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We analyze the seasonal cycle and sources of gases that are relevant for the formation of aerosol particles in the central Arctic. Since theses gases can form new particles, they can influence Arctic climate. We show that the sources of these gases are associated with changes in the Arctic environment during the year, especially with respect to sea ice. Therefore, the concentration of these gases will likely change in the future as the Arctic continues to warm.
Imad El Haddad, Danielle Vienneau, Kaspar R. Daellenbach, Robin Modini, Jay G. Slowik, Abhishek Upadhyay, Petros N. Vasilakos, David Bell, Kees de Hoogh, and Andre S. H. Prevot
Atmos. Chem. Phys., 24, 11981–12011, https://doi.org/10.5194/acp-24-11981-2024, https://doi.org/10.5194/acp-24-11981-2024, 2024
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This opinion paper explores how advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution. We advocate for a shift in the way we target PM pollution, focusing on the most harmful anthropogenic emissions. We highlight key observations, modelling developments, and emission measurements needed to achieve this shift.
Pramod Kumar, Khushboo Sharma, Ankita Malu, Rajeev Rajak, Aparna Gupta, Bidyutjyoti Baruah, Shailesh Yadav, Thupstan Angchuk, Jayant Sharma, Rakesh Kumar Ranjan, Anil Kumar Misra, and Nishchal Wanjari
Atmos. Chem. Phys., 24, 11585–11601, https://doi.org/10.5194/acp-24-11585-2024, https://doi.org/10.5194/acp-24-11585-2024, 2024
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This work monitors and assesses air pollution, especially black and brown carbon, its controlling factor, and its effect on the environment of Sikkim Himalayan region. The huge urban sprawl in recent decades has led to regional human-induced air pollution in the region. Black carbon was highest in April 2021 and March 2022, exceeding the WHO limit. The monsoon season causes huge rainfall over the region, which reduces the pollutants by scavenging (rainout and washout).
Maria P. Velásquez-García, K. Santiago Hernández, James A. Vergara-Correa, Richard J. Pope, Miriam Gómez-Marín, and Angela M. Rendón
Atmos. Chem. Phys., 24, 11497–11520, https://doi.org/10.5194/acp-24-11497-2024, https://doi.org/10.5194/acp-24-11497-2024, 2024
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In the Aburrá Valley, northern South America, local emissions determine air quality conditions. However, we found that external sources, such as regional fires, Saharan dust, and volcanic emissions, increase particulate concentrations and worsen chemical composition by introducing elements like heavy metals. Dry winds and source variability contribute to seasonal influences on these events. This study assesses the air quality risks posed by such events, which can affect broad regions worldwide.
Meng Wang, Qiyuan Wang, Steven Sai Hang Ho, Jie Tian, Yong Zhang, Shun-cheng Lee, and Junji Cao
Atmos. Chem. Phys., 24, 11175–11189, https://doi.org/10.5194/acp-24-11175-2024, https://doi.org/10.5194/acp-24-11175-2024, 2024
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We studied nitrogen-containing organic compounds (NOCs) in particulate matter <2.5 µm particles on the southeastern Tibetan Plateau. We found that biomass burning and transboundary transport are the main sources of NOCs in the high-altitude area. Understanding these aerosol sources informs how they add to regional and potentially global climate changes. Our findings could help shape effective environmental policies to enhance air quality and address climate impacts in this sensitive region.
Jinbo Wang, Jiaping Wang, Yuxuan Zhang, Tengyu Liu, Xuguang Chi, Xin Huang, Dafeng Ge, Shiyi Lai, Caijun Zhu, Lei Wang, Qiaozhi Zha, Ximeng Qi, Wei Nie, Congbin Fu, and Aijun Ding
Atmos. Chem. Phys., 24, 11063–11080, https://doi.org/10.5194/acp-24-11063-2024, https://doi.org/10.5194/acp-24-11063-2024, 2024
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In this study, we found large spatial discrepancies in the physical and chemical properties of black carbon over the Tibetan Plateau (TP). Elevated anthropogenic emissions from low-altitude regions can significantly change the mass concentration, mixing state and chemical composition of black-carbon-containing aerosol in the TP region, further altering its light absorption ability. Our study emphasizes the vulnerability of remote plateau regions to intense anthropogenic influences.
Liyuan Zhou, Qianyun Liu, Christian M. Salvador, Michael Le Breton, Mattias Hallquist, Jian Zhen Yu, Chak K. Chan, and Åsa M. Hallquist
Atmos. Chem. Phys., 24, 11045–11061, https://doi.org/10.5194/acp-24-11045-2024, https://doi.org/10.5194/acp-24-11045-2024, 2024
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Our research on city bus emissions reveals that alternative fuels (compressed natural gas and biofuels) reduce fresh particle emissions compared to diesel. However, all fuels lead to secondary air pollution. Aiming at guiding better environmental policies, we studied 76 buses using advanced emission measurement techniques. This work sheds light on the complex effects of bus fuels on urban air quality, emphasizing the need for comprehensive evaluations of future transportation technologies.
Xu Yang, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi He, and Haijie Tong
Atmos. Chem. Phys., 24, 11029–11043, https://doi.org/10.5194/acp-24-11029-2024, https://doi.org/10.5194/acp-24-11029-2024, 2024
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A study in the rural North China Plain showed environmentally persistent free radicals (EPFRs) in atmospheric particulate matter (PM), with a notable water-soluble fraction likely from atmospheric oxidation during transport. Significant positive correlations between EPFRs and the water-soluble oxidative potential of PM2.5 were found, primarily attributable to the water-soluble fractions of EPFRs. These findings emphasize understanding EPFRs' atmospheric evolution for climate and health impacts.
Kirsten N. Fossum, Chunshui Lin, Niall O'Sullivan, Lu Lei, Stig Hellebust, Darius Ceburnis, Aqeel Afzal, Anja Tremper, David Green, Srishti Jain, Steigvilė Byčenkienė, Colin O'Dowd, John Wenger, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 24, 10815–10831, https://doi.org/10.5194/acp-24-10815-2024, https://doi.org/10.5194/acp-24-10815-2024, 2024
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The chemical composition and sources of submicron aerosol in the Dublin Port area were investigated over a month-long campaign. Two distinct types of ship emissions were identified and characterised: sulfate-rich plumes from the use of heavy fuel oil with scrubbers and organic-rich plumes from the use of low-sulfur fuels. The latter were more frequent, emitting double the particle number and having a typical V / Ni ratio for ship emission.
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
Atmos. Chem. Phys., 24, 10655–10666, https://doi.org/10.5194/acp-24-10655-2024, https://doi.org/10.5194/acp-24-10655-2024, 2024
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This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Yu Xu, Tang Liu, Yi-Jia Ma, Qi-Bin Sun, Hong-Wei Xiao, Hao Xiao, Hua-Yun Xiao, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, https://doi.org/10.5194/acp-24-10531-2024, 2024
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This study investigates the characteristics of aminiums and ammonium in PM2.5 on clean and polluted winter days in 11 Chinese cities, highlighting the possibility of the competitive uptake of ammonia versus amines on acidic aerosols or the displacement of aminiums by ammonia under high-ammonia conditions. The overall results deepen the understanding of the spatiotemporal differences in aminium characteristics and formation in China.
Cassidy Soloff, Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Francesca Gallo, Johnathan W. Hair, Miguel Ricardo A. Hilario, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 10385–10408, https://doi.org/10.5194/acp-24-10385-2024, https://doi.org/10.5194/acp-24-10385-2024, 2024
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Using aircraft measurements over the northwestern Atlantic between the US East Coast and Bermuda and trajectory modeling of continental outflow, we identify trace gas and particle properties that exhibit gradients with offshore distance and quantify these changes with high-resolution measurements of concentrations and particle chemistry, size, and scattering properties. This work furthers our understanding of the complex interactions between continental and marine environments.
Alex Rowell, James Brean, David C. S. Beddows, Zongbo Shi, Avinash Kumar, Matti Rissanen, Miikka Dal Maso, Peter Mettke, Kay Weinhold, Maik Merkel, and Roy M. Harrison
Atmos. Chem. Phys., 24, 10349–10361, https://doi.org/10.5194/acp-24-10349-2024, https://doi.org/10.5194/acp-24-10349-2024, 2024
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Ions enhance the formation and growth rates of new particles, affecting the Earth's radiation budget. Despite these effects, there is little published data exploring the sources of ions in the urban environment and their role in new particle formation (NPF). Here we show that natural ion sources dominate in urban environments, while traffic is a secondary source. Ions contribute up to 12.7 % of the formation rate of particles, indicating that they are important for forming urban PM.
Yuan Cheng, Xu-bing Cao, Sheng-qiang Zhu, Zhi-qing Zhang, Jiu-meng Liu, Hong-liang Zhang, Qiang Zhang, and Ke-bin He
Atmos. Chem. Phys., 24, 9869–9883, https://doi.org/10.5194/acp-24-9869-2024, https://doi.org/10.5194/acp-24-9869-2024, 2024
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The agreement between observational and modeling results is essential for the development of efficient air pollution control strategies. Here we constrained the modeling results of carbonaceous aerosols by field observation in Northeast China, a historically overlooked but recently targeted region of national clean-air actions. Our study suggested that the simulation of agricultural fire emissions and secondary organic aerosols remains challenging.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
Atmos. Chem. Phys., 24, 9733–9748, https://doi.org/10.5194/acp-24-9733-2024, https://doi.org/10.5194/acp-24-9733-2024, 2024
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Short-term strict emission control can improve air quality, but its effectiveness needs assessment. During the 2021 summer COVID-19 lockdown in Yangzhou, we found that PM2.5 levels did not decrease despite reduced primary emissions. Aged black-carbon particles increased substantially due to higher O3 levels and transported pollutants. High humidity and low wind also played key roles. The results highlight the importance of a regionally balanced control strategy for future air quality management.
Xinya Liu, Diego Alves Gouveia, Bas Henzing, Arnoud Apituley, Arjan Hensen, Danielle van Dinther, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 9597–9614, https://doi.org/10.5194/acp-24-9597-2024, https://doi.org/10.5194/acp-24-9597-2024, 2024
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The vertical distribution of aerosol optical properties is important for their effect on climate. This is usually measured by lidar, which has limitations, most notably the assumption of a lidar ratio. Our study shows that routine surface-level aerosol measurements are able to predict this lidar ratio reasonably well within the lower layers of the atmosphere and thus provide a relatively simple and cost-effective method to improve lidar measurements.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
Atmos. Chem. Phys., 24, 9387–9399, https://doi.org/10.5194/acp-24-9387-2024, https://doi.org/10.5194/acp-24-9387-2024, 2024
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We deployed an advanced aerosol–fog sampling system at a rural site in the North China Plain to investigate impacts of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient relative humidity (RH) conditions and that RH levels significantly impact aerosol sampling through the aerosol swelling effect.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 9263–9275, https://doi.org/10.5194/acp-24-9263-2024, https://doi.org/10.5194/acp-24-9263-2024, 2024
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Brown carbon (BrC) is prevalent in the troposphere and can efficiently absorb solar and terrestrial radiation. Our observations show that the enhanced light absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Johnathan W. Hair, Miguel Ricardo A. Hilario, Chris A. Hostetler, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Cassidy Soloff, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9197–9218, https://doi.org/10.5194/acp-24-9197-2024, https://doi.org/10.5194/acp-24-9197-2024, 2024
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This study uses airborne data to examine vertical profiles of trace gases, aerosol particles, and meteorological variables over a remote marine area (Bermuda). Results show distinct differences based on both air mass source region (North America, Ocean, Caribbean/North Africa) and altitude for a given air mass type. This work highlights the sensitivity of remote marine areas to long-range transport and the importance of considering the vertical dependence of trace gas and aerosol properties.
Kira Zeider, Grace Betito, Anthony Bucholtz, Peng Xian, Annette Walker, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9059–9083, https://doi.org/10.5194/acp-24-9059-2024, https://doi.org/10.5194/acp-24-9059-2024, 2024
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The predominant wind direction along the California coast (northerly) reverses several times during the summer (to southerly). The effects of these wind reversals on aerosol and cloud characteristics are not well understood. Using data from multiple datasets we found that southerly flow periods had enhanced signatures of anthropogenic emissions due to shipping and continental sources, and clouds had more but smaller droplets.
Saleh Alzahrani, Doğuşhan Kılıç, Michael Flynn, Paul I. Williams, and James Allan
Atmos. Chem. Phys., 24, 9045–9058, https://doi.org/10.5194/acp-24-9045-2024, https://doi.org/10.5194/acp-24-9045-2024, 2024
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This paper investigates emissions from aviation activities at an international airport to evaluate their impact on local air quality. The study provides detailed insights into the chemical composition of aerosols and key pollutants in the airport environment. Source apportionment analysis using positive matrix factorisation (PMF) identified three significant sources: less oxidised oxygenated organic aerosol, alkane organic aerosol, and more oxidised oxygenated organic aerosol.
Mingjie Kang, Mengying Bao, Wenhuai Song, Aduburexiati Abulimiti, Fang Cao, Sönke Szidat, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2098, https://doi.org/10.5194/egusphere-2024-2098, 2024
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Reports on the molecular level knowledge of high temporal resolution PM2.5 components on hazy days are still limited. This study investigated many individual PM2.5 species and sources. The results show biomass burning (BB) was the main source of organic carbon. Moreover, BB enhanced fungal spore emissions and secondary aerosol formation. The contribution of non-fossils increased with increasing haze pollution. These findings suggest BB may be an important driver of haze events in winter.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
Atmos. Chem. Phys., 24, 8927–8941, https://doi.org/10.5194/acp-24-8927-2024, https://doi.org/10.5194/acp-24-8927-2024, 2024
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Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams per kilogram of fuel. Ships with an exhaust gas cleaning system (EGCS) were found to have median BC emissions per fuel consumed 5 times lower than ships without an EGCS. However, this might be because of non-EGCS ships running at low engine loads rather than the EGCS itself. A local speed restriction would increase BC emissions of ships.
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 24, 8911–8926, https://doi.org/10.5194/acp-24-8911-2024, https://doi.org/10.5194/acp-24-8911-2024, 2024
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Characterization of PM1 and positive matrix factorization (PMF) source apportionment of organic and inorganic fractions were conducted at the high-altitude station (HAC)2. Cloud presence reduced PM1, affecting sulfate more than organics. Free-troposphere (FT) conditions showed more black carbon (eBC) than planetary boundary layer (PBL) conditions.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
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Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROSs) play an active role in the atmosphere. Despite control measures having effectively reduced their emissions, reductions were less than in PM2.5. Emission control measures performed well in achieving Parade Blue, but reducing the impact of the atmosphere on human health remains challenging. Thus, there is a need to reassess emission control measures to better address the challenges posed by EPFRs and ROSs.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 24, 8507–8518, https://doi.org/10.5194/acp-24-8507-2024, https://doi.org/10.5194/acp-24-8507-2024, 2024
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The water solubility of secondary organic aerosols (SOAs) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOAs with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyan Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
Atmos. Chem. Phys., 24, 8473–8488, https://doi.org/10.5194/acp-24-8473-2024, https://doi.org/10.5194/acp-24-8473-2024, 2024
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We investigated aerosol composition and sources and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more oxidized SOA; however, cloud evaporation leads to the production of less oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
Atmos. Chem. Phys., 24, 8397–8411, https://doi.org/10.5194/acp-24-8397-2024, https://doi.org/10.5194/acp-24-8397-2024, 2024
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Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
EGUsphere, https://doi.org/10.5194/egusphere-2024-2230, https://doi.org/10.5194/egusphere-2024-2230, 2024
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We present measurements of the composition of ultrafine particles collected from the eastern Amazon, a relatively understudied region that is subjected to increasing human influence. We find that while isoprene chemistry is likely significant to ultrafine particle growth throughout the year, compounds related to other sources such as biological spore emissions and biomass burning exhibit striking seasonal differences, implying an extensive variation in regional ultrafine particle sources.
Maya Abou-Ghanem, Daniel M. Murphy, Gregory P. Schill, Michael J. Lawler, and Karl D. Froyd
Atmos. Chem. Phys., 24, 8263–8275, https://doi.org/10.5194/acp-24-8263-2024, https://doi.org/10.5194/acp-24-8263-2024, 2024
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Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
Atmos. Chem. Phys., 24, 8049–8066, https://doi.org/10.5194/acp-24-8049-2024, https://doi.org/10.5194/acp-24-8049-2024, 2024
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To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate in Barbados and compared them to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable, except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions in sulfur dioxide (SO2) in the US and Europe; then it increased in the 2000s, likely due to anthropogenic emissions from Africa.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
EGUsphere, https://doi.org/10.5194/egusphere-2024-1390, https://doi.org/10.5194/egusphere-2024-1390, 2024
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This study shows the derived organic aerosol hygroscopicity under high humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), after knowing the aerosol chemical composition.
Jiao Xue, Tian Zhang, Keyhong Park, Jinpei Yan, Young Jun Yoon, Jiyeon Park, and Bingbing Wang
Atmos. Chem. Phys., 24, 7731–7754, https://doi.org/10.5194/acp-24-7731-2024, https://doi.org/10.5194/acp-24-7731-2024, 2024
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Ice formation by particles is an important way of making mixed-phase and ice clouds. We found that particles collected in the marine atmosphere exhibit diverse ice nucleation abilities and mixing states. Sea salt mixed-sulfate particles were enriched in ice-nucleating particles. Selective aging on sea salt particles made particle populations more externally mixed. Characterizations of particles and their mixing state are needed for a better understanding of aerosol–cloud interactions.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 24, 7755–7772, https://doi.org/10.5194/acp-24-7755-2024, https://doi.org/10.5194/acp-24-7755-2024, 2024
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In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %) were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibiting the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O'Dowd
Atmos. Chem. Phys., 24, 7687–7698, https://doi.org/10.5194/acp-24-7687-2024, https://doi.org/10.5194/acp-24-7687-2024, 2024
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The chemical composition of atmospheric particles has shown significant changes in recent years. We investigated the potential effects of changes in inorganics on aerosol water uptake and, thus, secondary organic aerosol formation in wintertime haze based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, northwestern China. We highlight the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
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Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
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The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
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The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
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We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
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Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Tomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
EGUsphere, https://doi.org/10.5194/egusphere-2024-1399, https://doi.org/10.5194/egusphere-2024-1399, 2024
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Using single-particle mass spectrometry, we show that trace concentrations of bromine and iodine are ubiquitous in remote tropospheric aerosol, and suggest that aerosols are an important part of the global reactive iodine budget. Comparisons to a global climate model with detailed iodine chemistry are favorable in the background atmosphere; however, the model cannot replicate our measurements near the ocean surface, in biomass burning plumes, and in the stratosphere.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
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Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, and Teruo Aoki
EGUsphere, https://doi.org/10.5194/egusphere-2024-1498, https://doi.org/10.5194/egusphere-2024-1498, 2024
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Monthly records spanning 350 years from a Greenland ice core reveal trends in black carbon (BC) concentrations and sizes. BC concentrations have risen since the late 19th century due to the inflow of anthropogenic BC, with these particles being larger than those from biomass burning (BB). High BB BC concentration peaks in summer originating from BB could reduce albedo. However, BB BC showed no upward trend until the early 2000s. Our findings are crucial for validating aerosol and climate models.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Andreas Aktypis, Dontavious Sippial, Christina Vasilakopoulou, Angeliki Matrali, Christos Kaltsonoudis, Andrea Simonati, Marco Paglione, Matteo Rinaldi, Stefano Decesari, and Spyros Pandis
EGUsphere, https://doi.org/10.5194/egusphere-2024-1317, https://doi.org/10.5194/egusphere-2024-1317, 2024
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A dual chamber system was deployed in two different environments (Po Valley, Italy and Pertouli forest, Greece) to study the potential of ambient air directly injected into the chambers, to form secondary aerosol. In the Po Valley, the system reacts rapidly forming large amounts of SOA, while in Pertouli the corresponding SOA formation chemistry appears to have been practically terminated before the beginning of most experiments, so there is little additional SOA formation potential left.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
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This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
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Kulmala, M., Kerminen, V.-M., Anttila, T., Laaksonen, A., and O'Dowd, C. D.: Organic aerosol formation via sulphate cluster activation, J. Geophys. Res.-Atmos., 109, D04205, https://doi.org/10.1029/2003JD003961, 2004.
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Zhu, J., Crozier, P. A., and Anderson, J. R.: Characterization of light-absorbing carbon particles at three altitudes in East Asian outflow by transmission electron microscopy, Atmos. Chem. Phys., 13, 6359–6371, https://doi.org/10.5194/acp-13-6359-2013, 2013.
Short summary
Many studies have focused on the unusually severe hazes instead of the more frequent light and moderate hazes (22–63 %) in winter in the North China Plain (NCP). The morphology, mixing state, and size of organic aerosols in the L & M hazes were characterized. We conclude that the direct emissions from residential coal stoves without any pollution controls in rural and urban outskirts contribute large amounts of primary OM particles to the regional L & M hazes in winter in the NCP.
Many studies have focused on the unusually severe hazes instead of the more frequent light and...
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