Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-15345-2018
https://doi.org/10.5194/acp-18-15345-2018
Research article
 | 
25 Oct 2018
Research article |  | 25 Oct 2018

Peroxy acetyl nitrate (PAN) measurements at northern midlatitude mountain sites in April: a constraint on continental source–receptor relationships

Arlene M. Fiore, Emily V. Fischer, George P. Milly, Shubha Pandey Deolal, Oliver Wild, Daniel A. Jaffe, Johannes Staehelin, Olivia E. Clifton, Dan Bergmann, William Collins, Frank Dentener, Ruth M. Doherty, Bryan N. Duncan, Bernd Fischer, Stefan Gilge, Peter G. Hess, Larry W. Horowitz, Alexandru Lupu, Ian A. MacKenzie, Rokjin Park, Ludwig Ries, Michael G. Sanderson, Martin G. Schultz, Drew T. Shindell, Martin Steinbacher, David S. Stevenson, Sophie Szopa, Christoph Zellweger, and Guang Zeng

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Cited articles

Arnold, S. R., Emmons, L. K., Monks, S. A., Law, K. S., Ridley, D. A., Turquety, S., Tilmes, S., Thomas, J. L., Bouarar, I., Flemming, J., Huijnen, V., Mao, J., Duncan, B. N., Steenrod, S., Yoshida, Y., Langner, J., and Long, Y.: Biomass burning influence on high-latitude tropospheric ozone and reactive nitrogen in summer 2008: a multi-model analysis based on POLMIP simulations, Atmos. Chem. Phys., 15, 6047–6068, https://doi.org/10.5194/acp-15-6047-2015, 2015. 
Balzani Lööv, J. M., Henne, S., Legreid, G., Staehelin, J., Reimann, S., Prévôt, A. S. H., Steinbacher, M., and Vollmer, M. K.: Estimation of background concentrations of trace gases at the Swiss Alpine site Jungfraujoch (3580 m asl), J. Geophys. Res., 113, D22305, https://doi.org/10.1029/2007JD009751, 2008. 
Borodina, A., Fischer, E. M., and Knutti, R.: Emergent Constraints in Climate Projections: A Case Study of Changes in High-Latitude Temperature Variability, J. Climate, 30, 3655–3670, https://doi.org/10.1175/JCLI-D-16-0662.1, 2017. 
Bottenheim, J. W., Sirois, A., Brice, K. A., and Gallant, A. J.: Five years of continuous observations of PAN and ozone at a rural location in eastern Canada, J. Geophys. Res.-Atmos., 99, 5333–5352, 10.1029/93JD02716, 1994. 
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Short summary
We demonstrate a proof-of-concept approach for applying northern midlatitude mountaintop peroxy acetyl nitrate (PAN) measurements and a multi-model ensemble during April to constrain the influence of continental-scale anthropogenic precursor emissions on PAN. Our findings imply a role for carefully coordinated multi-model ensembles in helping identify observations for discriminating among widely varying (and poorly constrained) model responses of atmospheric constituents to changes in emissions.
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