Articles | Volume 15, issue 24
https://doi.org/10.5194/acp-15-14071-2015
https://doi.org/10.5194/acp-15-14071-2015
Research article
 | 
21 Dec 2015
Research article |  | 21 Dec 2015

Hygroscopic properties and cloud condensation nuclei activation of limonene-derived organosulfates and their mixtures with ammonium sulfate

A. M. K. Hansen, J. Hong, T. Raatikainen, K. Kristensen, A. Ylisirniö, A. Virtanen, T. Petäjä, M. Glasius, and N. L. Prisle

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Cited articles

Asa-Awuku, A., Engelhart, G. J., Lee, B. H., Pandis, S. N., and Nenes, A.: Relating CCN activity, volatility, and droplet growth kinetics of β-caryophyllene secondary organic aerosol, Atmos. Chem. Phys., 9, 795–812, https://doi.org/10.5194/acp-9-795-2009, 2009.
Carrico, C. M., Petters, M. D., Kreidenweis, S. M., Collett, J. L., Engling, G., and Malm, W. C.: Aerosol hygroscopicity and cloud droplet activation of extracts of filters from biomass burning experiments, J. Geophys. Res.-Atmos., 113, D08206, https://doi.org/10.1029/2007jd009274, 2008.
Cavdar, H. and Saraçoğlu, N.: Ring opening of epoxides with NaHSO4: isolation of beta-hydroxy sulfate esters and an effective synthesis for trans-diols, Tetrahedron, 65, 985–989, https://doi.org/10.1016/j.tet.2008.11.092, 2009.
Cerully, K. M., Raatikainen, T., Lance, S., Tkacik, D., Tiitta, P., Petäjä, T., Ehn, M., Kulmala, M., Worsnop, D. R., Laaksonen, A., Smith, J. N., and Nenes, A.: Aerosol hygroscopicity and CCN activation kinetics in a boreal forest environment during the 2007 EUCAARI campaign, Atmos. Chem. Phys., 11, 12369–12386, https://doi.org/10.5194/acp-11-12369-2011, 2011
Chan, M. N., Kreidenweis, S. M., and Chan, C. K.: Measurements of the hygroscopic and deliquescence properties of organic compounds of different solubilities in water and their relationship with cloud condensation nuclei activities, Environ. Sci. Technol., 42, 3602–3608, https://doi.org/10.1021/es7023252, 2008.
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This paper presents the first study of the hygroscopic properties of limonene derived organosulfates (L-OS 250). The results showed that L-OS 250 particles are weakly hygroscopic and able to activate into cloud droplets. Particles of L-OS 250 mixed with ammonium sulfate were much more hygroscopic than expected from model parametrizations and the ZSR mixing rule, indicating that solubility and non-ideal droplet interactions could be important for the hygroscopic properties of the mixed particles.
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