Articles | Volume 15, issue 24
https://doi.org/10.5194/acp-15-14071-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-14071-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Hygroscopic properties and cloud condensation nuclei activation of limonene-derived organosulfates and their mixtures with ammonium sulfate
A. M. K. Hansen
Department of Chemistry and iNANO, Aarhus University, Aarhus, Denmark
J. Hong
Department of Physics, University of Helsinki, Helsinki, Finland
T. Raatikainen
Finnish Meteorological Institute, Helsinki, Finland
K. Kristensen
Department of Chemistry and iNANO, Aarhus University, Aarhus, Denmark
A. Ylisirniö
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
A. Virtanen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
T. Petäjä
Department of Physics, University of Helsinki, Helsinki, Finland
M. Glasius
Department of Chemistry and iNANO, Aarhus University, Aarhus, Denmark
N. L. Prisle
CORRESPONDING AUTHOR
Department of Physics, University of Helsinki, Helsinki, Finland
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77 citations as recorded by crossref.
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- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
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- Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong Y. Wang et al. 10.1016/j.scitotenv.2023.166851
- Comprehensive characterization of hygroscopic properties of methanesulfonates L. Guo et al. 10.1016/j.atmosenv.2020.117349
- Virtual Special Issue: New Advances in Organic Aerosol Chemistry V. McNeill 10.1021/acsearthspacechem.0c00052
- Impact of acidity and surface-modulated acid dissociation on cloud response to organic aerosol G. Sengupta et al. 10.5194/acp-24-1467-2024
- Mechanistic insight into the formation of aromatic organosulfates and sulfonates through sulfoxy-radical-initiated reactions in the atmospheric aqueous phase G. Lv et al. 10.1016/j.atmosenv.2024.120701
- Measurement report: Distinct size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei activity at a rural site in the Pearl River Delta (PRD) region, China M. Cai et al. 10.5194/acp-22-8117-2022
- Urban organic aerosol composition in eastern China differs from north to south: molecular insight from a liquid chromatography–mass spectrometry (Orbitrap) study K. Wang et al. 10.5194/acp-21-9089-2021
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- Significant Climate Impact of Highly Hygroscopic Atmospheric Aerosols in Delhi, India Y. Wang & Y. Chen 10.1029/2019GL082339
- Hygroscopicity of aerosol particles composed of surfactant SDS and its internal mixture with ammonium sulfate at relative humidities up to 99.9% C. Zhang et al. 10.1016/j.atmosenv.2023.119625
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- Hygroscopic growth of aerosol particles consisted of oxalic acid and its internal mixture with ammonium sulfate for the relative humidity ranging from 80% to 99.5% C. Zhang et al. 10.1016/j.atmosenv.2021.118318
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- Water uptake of subpollen aerosol particles: hygroscopic growth, cloud condensation nuclei activation, and liquid–liquid phase separation E. Mikhailov et al. 10.5194/acp-21-6999-2021
- A predictive thermodynamic framework of cloud droplet activation for chemically unresolved aerosol mixtures, including surface tension, non-ideality, and bulk–surface partitioning N. Prisle 10.5194/acp-21-16387-2021
- Formation of Inorganic Sulfate and Volatile Nonsulfated Products from Heterogeneous Hydroxyl Radical Oxidation of 2-Methyltetrol Sulfate Aerosols: Mechanisms and Atmospheric Implications R. Xu et al. 10.1021/acs.estlett.4c00451
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- Insight into the formation of organosulfur compounds from the reaction of methyl vinyl ketone with sulfite radical in atmospheric aqueous phase G. Lv et al. 10.1016/j.scitotenv.2021.145817
- Thermodynamic properties of isoprene- and monoterpene-derived organosulfates estimated with COSMO<i>therm</i> N. Hyttinen et al. 10.5194/acp-20-5679-2020
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- A thermodynamic framework for bulk–surface partitioning in finite-volume mixed organic–inorganic aerosol particles and cloud droplets R. Schmedding & A. Zuend 10.5194/acp-23-7741-2023
- Competing esterification and oligomerization reactions of typical long-chain alcohols to secondary organic aerosol formation J. Wang et al. 10.1016/j.jes.2022.02.030
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- Cloud droplet activation of organic–salt mixtures predicted from two model treatments of the droplet surface J. Lin et al. 10.1039/C8EM00345A
- Effects of surface tension time-evolution for CCN activation of a complex organic surfactant J. Lin et al. 10.1039/C9EM00426B
- Interactions between the atmosphere, cryosphere, and ecosystems at northern high latitudes M. Boy et al. 10.5194/acp-19-2015-2019
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- The impact of aerosol size-dependent hygroscopicity and mixing state on the cloud condensation nuclei potential over the north-east Atlantic W. Xu et al. 10.5194/acp-21-8655-2021
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Interactions of organosulfates with water vapor under sub- and supersaturated conditions C. Peng et al. 10.5194/acp-21-7135-2021
- Water Uptake and Hygroscopic Growth of Organosulfate Aerosol A. Estillore et al. 10.1021/acs.est.5b05014
- A method for the direct measurement of surface tension of collected atmospherically relevant aerosol particles using atomic force microscopy A. Hritz et al. 10.5194/acp-16-9761-2016
- Effects of chemical composition and mixing state on size‐resolved hygroscopicity and cloud condensation nuclei activity of submicron aerosols at a suburban site in northern Japan in summer A. Müller et al. 10.1002/2017JD027286
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- SO<sub>2</sub> and NH<sub>3</sub> emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al. 10.5194/acp-21-7963-2021
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
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Latest update: 23 Nov 2024
Short summary
This paper presents the first study of the hygroscopic properties of limonene derived organosulfates (L-OS 250). The results showed that L-OS 250 particles are weakly hygroscopic and able to activate into cloud droplets. Particles of L-OS 250 mixed with ammonium sulfate were much more hygroscopic than expected from model parametrizations and the ZSR mixing rule, indicating that solubility and non-ideal droplet interactions could be important for the hygroscopic properties of the mixed particles.
This paper presents the first study of the hygroscopic properties of limonene derived...
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