Articles | Volume 21, issue 11
https://doi.org/10.5194/acp-21-8961-2021
https://doi.org/10.5194/acp-21-8961-2021
Measurement report
 | 
14 Jun 2021
Measurement report |  | 14 Jun 2021

Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules

Wei Huang, Haiyan Li, Nina Sarnela, Liine Heikkinen, Yee Jun Tham, Jyri Mikkilä, Steven J. Thomas, Neil M. Donahue, Markku Kulmala, and Federico Bianchi

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Cited articles

Äijälä, M., Heikkinen, L., Fröhlich, R., Canonaco, F., Prévôt, A. S. H., Junninen, H., Petäjä, T., Kulmala, M., Worsnop, D., and Ehn, M.: Resolving anthropogenic aerosol pollution types – deconvolution and exploratory classification of pollution events, Atmos. Chem. Phys., 17, 3165–3197, https://doi.org/10.5194/acp-17-3165-2017, 2017. 
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003. 
Barreira, L. M. F., Duporte, G., Parshintsev, J., Hartonen, K., Jussila, M., Aalto, J., Back, J., Kulmala, M., and Riekkola, M. L.: Emissions of biogenic volatile organic compounds from the boreal forest floor and understory: a study by solid-phase microextraction and portable gas chromatography-mass spectrometry, Boreal Environ. Res., 22, 393–413, 2017. 
Baumbach, G. and Vogt, U.: Influence of inversion layers on the distribution of air pollutants in urban areas, Water Air Soil Poll.: Focus, 3, 67–78, https://doi.org/10.1023/A:1026098305581, 2003. 
Berresheim, H., Elste, T., Plass-Dülmer, C., Eisele, F. L., and Tanner, D. J.: Chemical ionization mass spectrometer for long-term measurements of atmospheric OH and H2SO4, Int. J. Mass Spectrom., 202, 91–109, https://doi.org/10.1016/S1387-3806(00)00233-5, 2000. 
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We show full characterization of gaseous organic compounds in a boreal forest. Molecular composition and volatility of gaseous organic compounds with different oxidation extents (from volatile organic compounds to highly oxygenated organic molecules) were investigated and discussed. We provide a more comprehensive understanding of atmospheric organic compounds in this boreal forest and new insights into interpreting ambient measurements or testing and improving parameterizations in models.
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