Articles | Volume 18, issue 5
https://doi.org/10.5194/acp-18-3799-2018
https://doi.org/10.5194/acp-18-3799-2018
Research article
 | 
15 Mar 2018
Research article |  | 15 Mar 2018

Direct measurement of NO3 radical reactivity in a boreal forest

Jonathan Liebmann, Einar Karu, Nicolas Sobanski, Jan Schuladen, Mikael Ehn, Simon Schallhart, Lauriane Quéléver, Heidi Hellen, Hannele Hakola, Thorsten Hoffmann, Jonathan Williams, Horst Fischer, Jos Lelieveld, and John N. Crowley

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Cited articles

Aaltonen, H., Pumpanen, J., Pihlatie, M., Hakola, H., Hellén, H., Kulmala, L., Vesala, T., and Bäck, J.: Boreal pine forest floor biogenic volatile organic compound emissions peak in early summer and autumn, Agr. Forest Meteorol., 151, 682–691, doi:https://doi.org/10.1016/j.agrformet.2010.12.010, 2011. 
Aldener, M., Brown, S. S., Stark, H., Williams, E. J., Lerner, B. M., Kuster, W. C., Goldan, P. D., Quinn, P. K., Bates, T. S., Fehsenfeld, F. C., and Ravishankara, A. R.: Reactivity and loss mechanisms of NO3 and N2O5 in a polluted marine environment: Results from in situ measurements during New England Air Quality Study 2002, J. Geophys. Res.-Atmos., 111, D23S73, https://doi.org/10.1029/2006JD007252, 2006. 
Aliwell, S. R. and Jones, R. L.: Measurements of tropospheric NO3 at midlatitude, J. Geophys. Res.-Atmos., 103, 5719–5727, 1998. 
Allan, B. J., Carslaw, N., Coe, H., Burgess, R. A., and Plane, J. M. C.: Observations of the nitrate radical in the marine boundary layer, J. Atmos. Chem., 33, 129–154, 1999. 
Allan, B. J., Plane, J. M. C., Coe, H., and Shillito, J.: Observations of NO3 concentration profiles in the troposphere, J. Geophys. Res.-Atmos., 107, 4588, https://doi.org/10.1029/2002jd002112, 2002. 
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Short summary
Using a newly developed experimental setup, we have made the first direct measurements (during autumn 2016) of NO3 reactivity in the Finnish boreal forest. The NO3 reactivity was generally very high (maximum value of 0.94/s) so that daytime reaction with organics was a substantial fraction of the NO3 loss. Observations of biogenic hydrocarbons (BVOCs) suggested a dominant role for monoterpenes in determining the NO3 reactivity, which displayed a strong vertical gradient between 8.5 and 25 m.
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