Preprints
https://doi.org/10.5194/acp-2022-478
https://doi.org/10.5194/acp-2022-478
 
28 Jul 2022
28 Jul 2022
Status: this preprint is currently under review for the journal ACP.

High variations of BVOC emissions from Norway spruce in boreal forests

Hannele Hakola1, Ditte Taipale2,3, Arnaud Praplan1, Simon Schallhart1, Steven Thomas1, Toni Tykkä1, Aku Helin4, Jaana Bäck5, and Heidi Hellén1 Hannele Hakola et al.
  • 1Atmospheric Composition Research, Finnish Meteorological Institute, FI-00101 Helsinki, Finland
  • 2Kilpisjärvi Biological Station, Faculty of Biological and Environmental Sciences, Käsivarrentie 14622, 99490 Kilpisjärvi, Finland
  • 3Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
  • 4Finnish Institute of Occupational Health, P.O. Box 40, FI-00032 Työterveyslaitos, Finland
  • 5Institute for Atmospheric and Earth System Research/Faculty of Agriculture and Forestry, University of Helsinki, PO Box 27, 00014, Helsinki, Finland

Abstract. The biogenic volatile organic compound (BVOC) emission rates of Norway spruces published vary a lot. In this study we combined published Norway spruce emission rates measured in boreal forests (Meeningen et al., 2017; Bourtsoukidis et al., 2014a, 2014b; Hakola et al., (2003, 2019)) and added our new, unpublished emission data from southern (SF) and northern Finland (NF). Standardized summer monthly mean emission potentials of isoprene vary from below detection limit to 7 µg g-1(dw) h-1, and monoterpene (MT) and sesquiterpene (SQT) emission potentials 0.01–3 µg g-1(dw) h-1 and 0.03–2.7 µg g-1(dw) h-1, respectively. In this study, we found much higher SQT emissions from Norway spruces than measured before and on average SQTs had higher emission potentials than isoprene or MTs. The highest monthly mean SQT emission potential 13.6 µg g-1(dw) h-1 was observed in September in southern Finland.

We found that none of the younger (33–40 years) trees in Hyytiälä, southern Finland, emitted isoprene, while one 50-year-old tree was a strong isoprene emitter. However, this could not be confirmed at other sites since all measured small trees were growing in Hyytiälä, so this could also be due to the same genetic origin. On average, older trees (>80 years) emitted about ten times more isoprene and MTs than younger ones (<80 years), but no clear difference was seen in SQT emissions. SQT emissions can be more related to stress effects.

As shown here for Norway spruce, it is possible that the emission factor of SQTs is significantly higher than what is currently used in models, which may have significant effects on the prediction of formation and growht of new particles, since the secondary organic aerosol (SOA) formation potential of SQTs is high and this may have significant effects on the formation and growth of new particles. Due to high secondary organic aerosol (SOA) formation potentials of SQTs the impact on SOA formation and mass could be even higher.

Hannele Hakola et al.

Status: open (until 08 Sep 2022)

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Hannele Hakola et al.

Hannele Hakola et al.

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Short summary
Norway spruce is one of the main tree species growing in the boreal area. We show that volatile organic compound emission potentials and compound composition vary a lot. We have investigated if e.g. growing location or age of a tree could explain the variations. Recognizing this observed large variability in spruce BVOC emissions (precursors for new particle formation processes), we also tested the consequences of this variability in simulations of aerosol formation.
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