Articles | Volume 22, issue 6
https://doi.org/10.5194/acp-22-4253-2022
https://doi.org/10.5194/acp-22-4253-2022
Research article
 | 
01 Apr 2022
Research article |  | 01 Apr 2022

Photochemical evolution of the 2013 California Rim Fire: synergistic impacts of reactive hydrocarbons and enhanced oxidants

Glenn M. Wolfe, Thomas F. Hanisco, Heather L. Arkinson, Donald R. Blake, Armin Wisthaler, Tomas Mikoviny, Thomas B. Ryerson, Ilana Pollack, Jeff Peischl, Paul O. Wennberg, John D. Crounse, Jason M. St. Clair, Alex Teng, L. Gregory Huey, Xiaoxi Liu, Alan Fried, Petter Weibring, Dirk Richter, James Walega, Samuel R. Hall, Kirk Ullmann, Jose L. Jimenez, Pedro Campuzano-Jost, T. Paul Bui, Glenn Diskin, James R. Podolske, Glen Sachse, and Ronald C. Cohen

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Adler, G., Wagner, N. L., Lamb, K. D., Manfred, K. M., Schwarz, J. P., Franchin, A., Middlebrook, A. M., Washenfelder, R. A., Womack, C. C., Yokelson, R. J., and Murphy, D. M.: Evidence in biomass burning smoke for a light-absorbing aerosol with properties intermediate between brown and black carbon, AEROSOL Sci. Technol., 53, 976–989, https://doi.org/10.1080/02786826.2019.1617832, 2019. 
Akagi, S. K., Yokelson, R. J., Wiedinmyer, C., Alvarado, M. J., Reid, J. S., Karl, T., Crounse, J. D., and Wennberg, P. O.: Emission factors for open and domestic biomass burning for use in atmospheric models, Atmos. Chem. Phys., 11, 4039–4072, https://doi.org/10.5194/acp-11-4039-2011, 2011. 
Akagi, S. K., Craven, J. S., Taylor, J. W., Mcmeeking, G. R., Yokelson, R. J., Burling, I. R., Urbanski, S. P., Wold, C. E., Seinfeld, J. H., Coe, H., Alvarado, M. J., and Weise, D. R.: Evolution of trace gases and particles emitted by a chaparral fire in California, Atmos. Chem. Phys., 12, 1397–1421, https://doi.org/10.5194/acp-12-1397-2012, 2012. 
Akagi, S. K., Yokelson, R. J., Burling, I. R., Meinardi, S., Simpson, I., Blake, D. R., McMeeking, G. R., Sullivan, A., Lee, T., Kreidenweis, S., Urbanski, S., Reardon, J., Griffith, D. W. T., Johnson, T. J., and Weise, D. R.: Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes, Atmos. Chem. Phys., 13, 1141–1165, https://doi.org/10.5194/acp-13-1141-2013, 2013. 
Allen, H. M., Crounse, J. D., Bates, K. H., Teng, A. P., Krawiec-thayer, M. P., Rivera-rios, J. C., Keutsch, F. N., Clair, J. M. S., Hanisco, T. F., Møller, K. H., Kjaergaard, H. G., and Wennberg, P. O.: Kinetics and Product Yields of the OH Initiated Oxidation of Hydroxymethyl Hydroperoxide, J. Phys. Chem. A, 122, 6292–6302, https://doi.org/10.1021/acs.jpca.8b04577, 2018. 
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Short summary
Smoke plumes are chemically complex. This work combines airborne observations of smoke plume composition with a photochemical model to probe the production of ozone and the fate of reactive gases in the outflow of a large wildfire. Model–measurement comparisons illustrate how uncertain emissions and chemical processes propagate into simulated chemical evolution. Results provide insight into how this system responds to perturbations, which can help guide future observation and modeling efforts.
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