Articles | Volume 18, issue 4
Atmos. Chem. Phys., 18, 2461–2480, 2018
Atmos. Chem. Phys., 18, 2461–2480, 2018

Research article 19 Feb 2018

Research article | 19 Feb 2018

Molecular composition of particulate matter emissions from dung and brushwood burning household cookstoves in Haryana, India

Lauren T. Fleming1, Peng Lin2, Alexander Laskin2, Julia Laskin2, Robert Weltman3, Rufus D. Edwards3, Narendra K. Arora4, Ankit Yadav4, Simone Meinardi1, Donald R. Blake1, Ajay Pillarisetti5, Kirk R. Smith5, and Sergey A. Nizkorodov1 Lauren T. Fleming et al.
  • 1Department of Chemistry, University of California, Irvine, CA 92617, USA
  • 2Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA
  • 3Department of Epidemiology, University of California, Irvine, CA, 92617, USA
  • 4The Inclen Trust, Okhla Industrial Area, Phase-I, New Delhi-110020, India
  • 5School of Public Health, University of California, Berkeley, CA 94720, USA

Abstract. Emissions of airborne particles from biomass burning are a significant source of black carbon (BC) and brown carbon (BrC) in rural areas of developing countries where biomass is the predominant energy source for cooking and heating. This study explores the molecular composition of organic aerosols from household cooking emissions with a focus on identifying fuel-specific compounds and BrC chromophores. Traditional meals were prepared by a local cook with dung and brushwood-fueled cookstoves in a village in Palwal district, Haryana, India. Cooking was done in a village kitchen while controlling for variables including stove type, fuel moisture, and meal. Fine particulate matter (PM2.5) emissions were collected on filters, and then analyzed via nanospray desorption electrospray ionization–high-resolution mass spectrometry (nano-DESI-HRMS) and high-performance liquid chromatography–photodiode array–high-resolution mass spectrometry (HPLC-PDA-HRMS) techniques. The nano-DESI-HRMS analysis provided an inventory of numerous compounds present in the particle phase. Although several compounds observed in this study have been previously characterized using gas chromatography methods a majority of the species in the nano-DESI spectra were newly observed biomass burning compounds. Both the stove (chulha or angithi) and the fuel (brushwood or dung) affected the composition of organic aerosols. The geometric mean of the PM2.5 emission factor and the observed molecular complexity increased in the following order: brushwood–chulha (7.3 ± 1.8 g kg−1 dry fuel, 93 compounds), dung–chulha (21.1 ± 4.2 g kg−1 dry fuel, 212 compounds), and dung–angithi (29.8 ± 11.5 g kg−1 dry fuel, 262 compounds). The mass-normalized absorption coefficient (MACbulk) for the organic-solvent extractable material for brushwood PM2.5 was 3.7 ± 1.5 and 1.9 ± 0.8 m2 g−1 at 360 and 405 nm, respectively, which was approximately a factor of two higher than that for dung PM2.5. The HPLC-PDA-HRMS analysis showed that, regardless of fuel type, the main chromophores were CxHyOz lignin fragments. The main chromophores accounting for the higher MACbulk values of brushwood PM2.5 were C8H10O3 (tentatively assigned to syringol), nitrophenols C8H9NO4, and C10H10O3 (tentatively assigned to methoxycinnamic acid).

Short summary
Household cooking emissions in India, which rely on traditional meal preparation with dung- and brushwood-fueled cookstoves, produce copious amounts of particulate matter. Detailed chemical analysis of the compounds found in this particulate matter detected a large number of previously unidentified nitrogen-containing organic compounds, originating from dung-fueled cookstoves.
Final-revised paper