Articles | Volume 18, issue 17
https://doi.org/10.5194/acp-18-13013-2018
https://doi.org/10.5194/acp-18-13013-2018
Research article
 | 
11 Sep 2018
Research article |  | 11 Sep 2018

Chlorine oxidation of VOCs at a semi-rural site in Beijing: significant chlorine liberation from ClNO2 and subsequent gas- and particle-phase Cl–VOC production

Michael Le Breton, Åsa M. Hallquist, Ravi Kant Pathak, David Simpson, Yujue Wang, John Johansson, Jing Zheng, Yudong Yang, Dongjie Shang, Haichao Wang, Qianyun Liu, Chak Chan, Tao Wang, Thomas J. Bannan, Michael Priestley, Carl J. Percival, Dudley E. Shallcross, Keding Lu, Song Guo, Min Hu, and Mattias Hallquist

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Cited articles

Allan, W., Struthers, H., and Lowe, D. C.: Methane carbon isotope effects caused by atomic chlorine in the marine boundary layer: Global model results compared with southern hemisphere measurements, J. Geophys. Res., 112, https://doi.org/10.1029/2006JD007369, 2007.
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Bannan, T. J., Bacak, A., Le Breton, M., Ouyang, B., Flynn, M., McLeod, M., Jones, R., Malkin, T. L., Whalley, L. K., Heard, D. E., Bandy, B., Khan, A., Shallcross, D. E., and Percival, C. J.: Ground and airborne U.K. measurements of nitryl chloride, an investigation of the role of Cl atom oxidation at Weybourne Atmospheric Observatory, J. Geophys. Res.-Atmos., 122, 11154–11165, https://doi.org/10.1002/2017JD026624, 2017.
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We apply state-of-the-art chemical characterization to determine the chloride radical production in Beijing via measurement of inorganic halogens at a semi-rural site. The high concentration of inorganic halogens, namely nitryl chloride, enables the production of chlorinated volatile organic compounds which are measured in both the gas and particle phases simultaneously. This enables the secondary production of aerosols via chlorine oxidation to be directly observed in ambient air.
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