Articles | Volume 16, issue 8
https://doi.org/10.5194/acp-16-4867-2016
https://doi.org/10.5194/acp-16-4867-2016
Research article
 | 
20 Apr 2016
Research article |  | 20 Apr 2016

Chemical and meteorological influences on the lifetime of NO3 at a semi-rural mountain site during PARADE

N. Sobanski, M. J. Tang, J. Thieser, G. Schuster, D. Pöhler, H. Fischer, W. Song, C. Sauvage, J. Williams, J. Fachinger, F. Berkes, P. Hoor, U. Platt, J. Lelieveld, and J. N. Crowley

Related authors

Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results
Philipp G. Eger, Luc Vereecken, Rolf Sander, Jan Schuladen, Nicolas Sobanski, Horst Fischer, Einar Karu, Jonathan Williams, Ville Vakkari, Tuukka Petäjä, Jos Lelieveld, Andrea Pozzer, and John N. Crowley
Atmos. Chem. Phys., 21, 14333–14349, https://doi.org/10.5194/acp-21-14333-2021,https://doi.org/10.5194/acp-21-14333-2021, 2021
Short summary
Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry
Philipp G. Eger, Jan Schuladen, Nicolas Sobanski, Horst Fischer, Einar Karu, Jonathan Williams, Matthieu Riva, Qiaozhi Zha, Mikael Ehn, Lauriane L. J. Quéléver, Simon Schallhart, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 3697–3711, https://doi.org/10.5194/acp-20-3697-2020,https://doi.org/10.5194/acp-20-3697-2020, 2020
Short summary
Direct measurement of NO3 radical reactivity in a boreal forest
Jonathan Liebmann, Einar Karu, Nicolas Sobanski, Jan Schuladen, Mikael Ehn, Simon Schallhart, Lauriane Quéléver, Heidi Hellen, Hannele Hakola, Thorsten Hoffmann, Jonathan Williams, Horst Fischer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 18, 3799–3815, https://doi.org/10.5194/acp-18-3799-2018,https://doi.org/10.5194/acp-18-3799-2018, 2018
Short summary
Measurement of ambient NO3 reactivity: design, characterization and first deployment of a new instrument
Jonathan M. Liebmann, Gerhard Schuster, Jan B. Schuladen, Nicolas Sobanski, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 10, 1241–1258, https://doi.org/10.5194/amt-10-1241-2017,https://doi.org/10.5194/amt-10-1241-2017, 2017
Short summary
Day and night-time formation of organic nitrates at a forested mountain site in south-west Germany
Nicolas Sobanski, Jim Thieser, Jan Schuladen, Carina Sauvage, Wei Song, Jonathan Williams, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 17, 4115–4130, https://doi.org/10.5194/acp-17-4115-2017,https://doi.org/10.5194/acp-17-4115-2017, 2017
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Observation and modeling of atmospheric OH and HO2 radicals at a subtropical rural site and implications for secondary pollutants
Zhouxing Zou, Tianshu Chen, Qianjie Chen, Weihang Sun, Shichun Han, Zhuoyue Ren, Xinyi Li, Wei Song, Aoqi Ge, Qi Wang, Xiao Tian, Chenglei Pei, Xinming Wang, Yanli Zhang, and Tao Wang
Atmos. Chem. Phys., 25, 8147–8161, https://doi.org/10.5194/acp-25-8147-2025,https://doi.org/10.5194/acp-25-8147-2025, 2025
Short summary
Tracing elevated abundance of CH2Cl2 in the subarctic upper troposphere to the Asian Summer Monsoon
Markus Jesswein, Valentin Lauther, Nicolas Emig, Peter Hoor, Timo Keber, Hans-Christoph Lachnitt, Linda Ort, Tanja Schuck, Johannes Strobel, Ronja Van Luijt, C. Michael Volk, Franziska Weyland, and Andreas Engel
Atmos. Chem. Phys., 25, 8107–8126, https://doi.org/10.5194/acp-25-8107-2025,https://doi.org/10.5194/acp-25-8107-2025, 2025
Short summary
Carbonyl compounds from typical combustion sources: emission characteristics, influencing factors, and their contribution to ozone formation
Yanjie Lu, Xinxin Feng, Yanli Feng, Minjun Jiang, Yu Peng, Tian Chen, and Yingjun Chen
Atmos. Chem. Phys., 25, 8043–8059, https://doi.org/10.5194/acp-25-8043-2025,https://doi.org/10.5194/acp-25-8043-2025, 2025
Short summary
Formation drivers and photochemical effects of ClNO2 in a coastal city of Southeast China
Gaojie Chen, Xiaolong Fan, Haichao Wang, Yee Jun Tham, Ziyi Lin, Xiaoting Ji, Lingling Xu, Baoye Hu, and Jinsheng Chen
Atmos. Chem. Phys., 25, 7815–7828, https://doi.org/10.5194/acp-25-7815-2025,https://doi.org/10.5194/acp-25-7815-2025, 2025
Short summary
Significant influence of oxygenated volatile organic compounds on atmospheric chemistry: a case study in a typical industrial city in China
Jingwen Dai, Kun Zhang, Yanli Feng, Xin Yi, Rui Li, Jin Xue, Qing Li, Lishu Shi, Jiaqiang Liao, Yanan Yi, Fangting Wang, Liumei Yang, Hui Chen, Ling Huang, Jiani Tan, Yangjun Wang, and Li Li
Atmos. Chem. Phys., 25, 7467–7484, https://doi.org/10.5194/acp-25-7467-2025,https://doi.org/10.5194/acp-25-7467-2025, 2025
Short summary

Cited articles

Allan, B. J., Carslaw, N., Coe, H., Burgess, R. A., and Plane, J. M. C.: Observations of the nitrate radical in the marine boundary layer, J. Atmos. Chem., 33, 129–154, 1999.
Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013.
Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: IUPAC: Task Group on Atmospheric Chemical Kinetic Data Evaluation, available at: http://iupac.pole-ether.fr/index.html, last access: February 2016.
Asaf, D., Pedersen, D., Matveev, V., Peleg, M., Kern, C., Zingler, J., Platt, U., and Luria, M.: Long-term measurements of NO3 radical at a semiarid, urban Site: 1. Extreme concentration events and their oxidation capacity, Environ. Sci. Technol., 43, 9117–9123, https://doi.org/10.1021/es900798b, 2009.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Download
Short summary
The nitrate radical (NO3) is an important nocturnal oxidant. By measuring NO3, its precursors (nitrogen dioxide and ozone) and several trace gases with which it reacts, we examined the chemical and meteorological factors influencing the lifetime of NO3 at a semi-rural mountain site. Unexpectedly long lifetimes, approaching 1 h, were observed on several nights and were associated with a low-lying residual layer. We discuss the role of other reactions that convert NO2 to NO3.
Share
Altmetrics
Final-revised paper
Preprint