Articles | Volume 14, issue 17
Atmos. Chem. Phys., 14, 9233–9247, 2014
https://doi.org/10.5194/acp-14-9233-2014
Atmos. Chem. Phys., 14, 9233–9247, 2014
https://doi.org/10.5194/acp-14-9233-2014

Review article 08 Sep 2014

Review article | 08 Sep 2014

Compilation and evaluation of gas phase diffusion coefficients of reactive trace gases in the atmosphere: volume 1. Inorganic compounds

M. J. Tang1,2, R. A. Cox1, and M. Kalberer1 M. J. Tang et al.
  • 1Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
  • 2School of Earth Sciences, University of Bristol, Bristol BS8 1RJ, UK

Abstract. Diffusion of gas molecules to the surface is the first step for all gas–surface reactions. Gas phase diffusion can influence and sometimes even limit the overall rates of these reactions; however, there is no database of the gas phase diffusion coefficients of atmospheric reactive trace gases. Here we compile and evaluate, for the first time, the diffusivities (pressure-independent diffusion coefficients) of atmospheric inorganic reactive trace gases reported in the literature. The measured diffusivities are then compared with estimated values using a semi-empirical method developed by Fuller et al. (1966). The diffusivities estimated using Fuller's method are typically found to be in good agreement with the measured values within ±30%, and therefore Fuller's method can be used to estimate the diffusivities of trace gases for which experimental data are not available. The two experimental methods used in the atmospheric chemistry community to measure the gas phase diffusion coefficients are also discussed. A different version of this compilation/evaluation, which will be updated when new data become available, is uploaded online (https://sites.google.com/site/mingjintang/home/diffusion).

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