Articles | Volume 18, issue 14
https://doi.org/10.5194/acp-18-10355-2018
https://doi.org/10.5194/acp-18-10355-2018
Research article
 | 
19 Jul 2018
Research article |  | 19 Jul 2018

Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS

Michael Le Breton, Yujue Wang, Åsa M. Hallquist, Ravi Kant Pathak, Jing Zheng, Yudong Yang, Dongjie Shang, Marianne Glasius, Thomas J. Bannan, Qianyun Liu, Chak K. Chan, Carl J. Percival, Wenfei Zhu, Shengrong Lou, David Topping, Yuchen Wang, Jianzhen Yu, Keding Lu, Song Guo, Min Hu, and Mattias Hallquist

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Cited articles

Bannan, T. J., Booth, A. M., Jones, B. T., O'Meara, S., Barley, M. H., Riipinen, I., Percival, C. J., and Topping, D.: Measured saturation vapor pressures of phenolic and nitro-aromatic compounds, Environ. Sci. Technol., 51, 3922–3928, 2017. 
Booth, A. M., Markus, T., McFiggans, G., Percival, C. J., Mcgillen, M. R., and Topping, D. O.: Design and construction of a simple Knudsen Effusion Mass Spectrometer (KEMS) system for vapour pressure measurements of low volatility organics, Atmos. Meas. Tech., 2, 355–361, https://doi.org/10.5194/amt-2-355-2009, 2009. 
Booth, A. M., Barley, M. H., Topping, D. O., McFiggans, G., Garforth, A., and Percival, C. J.: Solid state and sub-cooled liquid vapour pressures of substituted dicarboxylic acids using Knudsen Effusion Mass Spectrometry (KEMS) and Differential Scanning Calorimetry, Atmos. Chem. Phys., 10, 4879–4892, https://doi.org/10.5194/acp-10-4879-2010, 2010. 
Booth, A. M., Bannan, T., Barley, M. H., Topping, D. O., McFiggans, G., and Percival, C. J.: The role of ortho, meta, para isomerism in measured solid state and derived sub-cooled liquid vapour pressures of substituted benzoic acids, Roy. Soc. Chem., 2, 4430–4443, 2012. 
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This paper utilizes a chemical ionisation mass spectrometer measuring gas and particle-phase organosulfates (OS) simultaneously during a field campaign in Beijing, China, and highlights how high time frequency online measurements enable a detailed analysis of dominant production mechanisms. We find that high aerosol acidity, organic precursor concentration and relative humidity promote the production of OS. The thermogram desorption reveals the potential for semi-volatile gas-phase OS.
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