Articles | Volume 19, issue 10
https://doi.org/10.5194/acp-19-6737-2019
https://doi.org/10.5194/acp-19-6737-2019
Research article
 | 
21 May 2019
Research article |  | 21 May 2019

Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China

Xionghui Qiu, Qi Ying, Shuxiao Wang, Lei Duan, Jian Zhao, Jia Xing, Dian Ding, Yele Sun, Baoxian Liu, Aijun Shi, Xiao Yan, Qingcheng Xu, and Jiming Hao

Related authors

Tracking County-level Cooking Emissions and Their Drivers in China from 1990 to 2021 by Ensemble Machine Learning
Zeqi Li, Bin Zhao, Shengyue Li, Zhezhe Shi, Dejia Yin, Qingru Wu, Fenfen Zhang, Xiao Yun, Guanghan Huang, Yun Zhu, and Shuxiao Wang
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-104,https://doi.org/10.5194/essd-2025-104, 2025
Preprint under review for ESSD
Short summary
Effectiveness of Emission Controls on Atmospheric Oxidation and Air Pollutant Concentrations: Uncertainties due to Chemical Mechanisms and Inventories
Mingjie Kang, Hongliang Zhang, and Qi Ying
EGUsphere, https://doi.org/10.5194/egusphere-2025-255,https://doi.org/10.5194/egusphere-2025-255, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Accounting for the black carbon aging process in a two-way coupled meteorology–air quality model
Yuzhi Jin, Jiandong Wang, Chao Liu, David C. Wong, Golam Sarwar, Kathleen M. Fahey, Shang Wu, Jiaping Wang, Jing Cai, Zeyuan Tian, Zhouyang Zhang, Jia Xing, Aijun Ding, and Shuxiao Wang
Atmos. Chem. Phys., 25, 2613–2630, https://doi.org/10.5194/acp-25-2613-2025,https://doi.org/10.5194/acp-25-2613-2025, 2025
Short summary
Steady-state mixing state of black carbon aerosols from a particle-resolved model
Zhouyang Zhang, Jiandong Wang, Jiaping Wang, Nicole Riemer, Chao Liu, Yuzhi Jin, Zeyuan Tian, Jing Cai, Yueyue Cheng, Ganzhen Chen, Bin Wang, Shuxiao Wang, and Aijun Ding
Atmos. Chem. Phys., 25, 1869–1881, https://doi.org/10.5194/acp-25-1869-2025,https://doi.org/10.5194/acp-25-1869-2025, 2025
Short summary
Carbon reduction requires attention to the contribution of natural gas use: Combustion and leakage
Haoyuan Chen, Tao Song, Xiaodong Chen, Yinghong Wang, Mengtian Cheng, Kai Wang, Fuxin Liu, Baoxian Liu, Guiqian Tang, and Yuesi Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3931,https://doi.org/10.5194/egusphere-2024-3931, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary

Related subject area

Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations
Ursula A. Jongebloed, Jacob I. Chalif, Linia Tashmim, William C. Porter, Kelvin H. Bates, Qianjie Chen, Erich C. Osterberg, Bess G. Koffman, Jihong Cole-Dai, Dominic A. Winski, David G. Ferris, Karl J. Kreutz, Cameron P. Wake, and Becky Alexander
Atmos. Chem. Phys., 25, 4083–4106, https://doi.org/10.5194/acp-25-4083-2025,https://doi.org/10.5194/acp-25-4083-2025, 2025
Short summary
Driving factors of aerosol acidity: a new hierarchical quantitative analysis framework and its application in Changzhou, China
Xiaolin Duan, Guangjie Zheng, Chuchu Chen, Qiang Zhang, and Kebin He
Atmos. Chem. Phys., 25, 3919–3928, https://doi.org/10.5194/acp-25-3919-2025,https://doi.org/10.5194/acp-25-3919-2025, 2025
Short summary
Understanding the long-term trend of organic aerosol and the influences from anthropogenic emission and regional climate change in China
Wenxin Zhang, Yaman Liu, Man Yue, Xinyi Dong, Kan Huang, and Minghuai Wang
Atmos. Chem. Phys., 25, 3857–3872, https://doi.org/10.5194/acp-25-3857-2025,https://doi.org/10.5194/acp-25-3857-2025, 2025
Short summary
Population exposure to outdoor NO2, black carbon, and ultrafine and fine particles over Paris with multi-scale modelling down to the street scale
Soo-Jin Park, Lya Lugon, Oscar Jacquot, Youngseob Kim, Alexia Baudic, Barbara D'Anna, Ludovico Di Antonio, Claudia Di Biagio, Fabrice Dugay, Olivier Favez, Véronique Ghersi, Aline Gratien, Julien Kammer, Jean-Eudes Petit, Olivier Sanchez, Myrto Valari, Jérémy Vigneron, and Karine Sartelet
Atmos. Chem. Phys., 25, 3363–3387, https://doi.org/10.5194/acp-25-3363-2025,https://doi.org/10.5194/acp-25-3363-2025, 2025
Short summary
Predicted impacts of heterogeneous chemical pathways on particulate sulfur over Fairbanks (Alaska), the Northern Hemisphere, and the Contiguous United States
Sara L. Farrell, Havala O. T. Pye, Robert Gilliam, George Pouliot, Deanna Huff, Golam Sarwar, William Vizuete, Nicole Briggs, Fengkui Duan, Tao Ma, Shuping Zhang, and Kathleen Fahey
Atmos. Chem. Phys., 25, 3287–3312, https://doi.org/10.5194/acp-25-3287-2025,https://doi.org/10.5194/acp-25-3287-2025, 2025
Short summary

Cited articles

Abbatt, J. P. D. and Waschewsky, G. C.G.: Heterogeneous interactions of HOBr, HNO3, O3, and NO2 with deliquescent NaCl aerosols at room temperature, J. Phys. Chem A., 102, 3719–3725, 1998. 
Bertram, T. H. and Thornton, J. A.: Toward a general parameterization of N2O5 reactivity on aqueous particles: the competing effects of particle liquid water, nitrate and chloride, Atmos. Chem. Phys., 9, 8351–8363, https://doi.org/10.5194/acp-9-8351-2009, 2009. 
Brown, S. S. and Stutz, J.: Nighttime radical observations and chemistry, Chem. Soc. Rev., 41, 6405–6447, 2012. 
Carter, W. P. and Heo, G.: Development of revised SAPRC aromatics mechanisms, Atmos. Environ., 77, 404–414, 2013. 
Chang, X., Wang, S., Zhao, B., Cai, S., and Hao, J.: Assessment of inter-city transport of particulate matter in the Beijing–Tianjin–Hebei region, Atmos. Chem. Phys., 18, 4843–4858, https://doi.org/10.5194/acp-18-4843-2018, 2018. 
Download
Short summary
Current chemical transport models cannot capture the diurnal and nocturnal variation in atmospheric nitrate, which may be relative to the missing atmospheric chlorine chemistry. In this work, the Community Multiscale Air Quality (CMAQ) model with improved chlorine heterogeneous chemistry is applied to simulate the impact of chlorine chemistry on summer nitrate concentrations in Beijing. The results of this work can improve our understanding of nitrate formation.
Share
Altmetrics
Final-revised paper
Preprint