Articles | Volume 19, issue 10
https://doi.org/10.5194/acp-19-6737-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-6737-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 May 2019
Research article |
| 21 May 2019
Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China
Xionghui Qiu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
Qi Ying
CORRESPONDING AUTHOR
Zachry Department of Civil Engineering, Texas A&M University, College Station, Texas 77843-3138, USA
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
Lei Duan
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
Jian Zhao
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
Jia Xing
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
Dian Ding
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
Baoxian Liu
Beijing Environmental Monitoring Center, Beijing 100048, China
Aijun Shi
Beijing Municipal Research Institute of Environmental Protection, Beijing 100037, China
Xiao Yan
Beijing Municipal Research Institute of Environmental Protection, Beijing 100037, China
Qingcheng Xu
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
Jiming Hao
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, School of Environment, Tsinghua University, Beijing 100084, China
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- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
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- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Transport Pathways of Nitrate Formed from Nocturnal N2O5 Hydrolysis Aloft to the Ground Level in Winter North China Plain X. Zhao et al. 10.1021/acs.est.3c00086
- Insights into source origins and formation mechanisms of nitrate during winter haze episodes in the Yangtze River Delta J. Shen et al. 10.1016/j.scitotenv.2020.140187
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Real‐Time Characterization of Aerosol Compositions, Sources, and Aging Processes in Guangzhou During PRIDE‐GBA 2018 Campaign W. Chen et al. 10.1029/2021JD035114
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- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
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- Significant Impact of Reactive Chlorine on Complex Air Pollution Over the Yangtze River Delta Region, China X. Yi et al. 10.1029/2023JD038898
- Vertical distribution of PM10 and PM2.5 emission sources and chemical composition during winter period in Delhi city R. Shanmuga Priyan et al. 10.1007/s11869-021-01092-w
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- An Updated Anthropogenic Emission Inventory of Reactive Chlorine Precursors in China S. Yin et al. 10.1021/acsearthspacechem.2c00096
- Tracking Daily Concentrations of PM2.5 Chemical Composition in China since 2000 S. Liu et al. 10.1021/acs.est.2c06510
- The role of anthropogenic chlorine emission in surface ozone formation during different seasons over eastern China Y. Hong et al. 10.1016/j.scitotenv.2020.137697
- Dominant physical and chemical processes impacting nitrate in Shandong of the North China Plain during winter haze events J. Yang et al. 10.1016/j.scitotenv.2023.169065
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- Gaseous and Particulate Chlorine Emissions From Typical Iron and Steel Industry in China X. Ding et al. 10.1029/2020JD032729
- Elucidate the formation mechanism of particulate nitrate based on direct radical observations in the Yangtze River Delta summer 2019 T. Zhai et al. 10.5194/acp-23-2379-2023
- The Occurrence of Heavy Air Pollution during the COVID-19 Outbreak in Beijing, China: Roles of Emission Reduction, Meteorological Conditions, and Regional Transport X. Yan et al. 10.3390/su132112312
28 citations as recorded by crossref.
- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
- Impacts of the differences in PM2.5 air quality improvement on regional transport and health risk in Beijing–Tianjin–Hebei region during 2013–2017 J. Cao et al. 10.1016/j.chemosphere.2022.134179
- Modeled changes in source contributions of particulate matter during the COVID-19 pandemic in the Yangtze River Delta, China J. Ma et al. 10.5194/acp-21-7343-2021
- Important contribution of N2O5 hydrolysis to the daytime nitrate in Xi'an, China during haze periods: Isotopic analysis and WRF-Chem model simulation C. Wu et al. 10.1016/j.envpol.2021.117712
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Modeling particulate nitrate in China: Current findings and future directions X. Xie et al. 10.1016/j.envint.2022.107369
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Transport Pathways of Nitrate Formed from Nocturnal N2O5 Hydrolysis Aloft to the Ground Level in Winter North China Plain X. Zhao et al. 10.1021/acs.est.3c00086
- Insights into source origins and formation mechanisms of nitrate during winter haze episodes in the Yangtze River Delta J. Shen et al. 10.1016/j.scitotenv.2020.140187
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Real‐Time Characterization of Aerosol Compositions, Sources, and Aging Processes in Guangzhou During PRIDE‐GBA 2018 Campaign W. Chen et al. 10.1029/2021JD035114
- An emission inventory for Cl2 and HOCl in Shanghai, 2017 L. Li et al. 10.1016/j.atmosenv.2019.117220
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- A clear north-to-south spatial gradience of chloride in marine aerosol in Chinese seas under the influence of East Asian Winter Monsoon J. Liu et al. 10.1016/j.scitotenv.2022.154929
- Significant production of ClNO<sub>2</sub> and possible source of Cl<sub>2</sub> from N<sub>2</sub>O<sub>5</sub> uptake at a suburban site in eastern China M. Xia et al. 10.5194/acp-20-6147-2020
- Significant Impact of Reactive Chlorine on Complex Air Pollution Over the Yangtze River Delta Region, China X. Yi et al. 10.1029/2023JD038898
- Vertical distribution of PM10 and PM2.5 emission sources and chemical composition during winter period in Delhi city R. Shanmuga Priyan et al. 10.1007/s11869-021-01092-w
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- An Updated Anthropogenic Emission Inventory of Reactive Chlorine Precursors in China S. Yin et al. 10.1021/acsearthspacechem.2c00096
- Tracking Daily Concentrations of PM2.5 Chemical Composition in China since 2000 S. Liu et al. 10.1021/acs.est.2c06510
- The role of anthropogenic chlorine emission in surface ozone formation during different seasons over eastern China Y. Hong et al. 10.1016/j.scitotenv.2020.137697
- Dominant physical and chemical processes impacting nitrate in Shandong of the North China Plain during winter haze events J. Yang et al. 10.1016/j.scitotenv.2023.169065
- Comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA: implications for atmospheric oxidative capacity M. Soni et al. 10.5194/acp-23-15165-2023
- Gaseous and Particulate Chlorine Emissions From Typical Iron and Steel Industry in China X. Ding et al. 10.1029/2020JD032729
- Elucidate the formation mechanism of particulate nitrate based on direct radical observations in the Yangtze River Delta summer 2019 T. Zhai et al. 10.5194/acp-23-2379-2023
- The Occurrence of Heavy Air Pollution during the COVID-19 Outbreak in Beijing, China: Roles of Emission Reduction, Meteorological Conditions, and Regional Transport X. Yan et al. 10.3390/su132112312
Latest update: 25 Apr 2024
Short summary
Current chemical transport models cannot capture the diurnal and nocturnal variation in atmospheric nitrate, which may be relative to the missing atmospheric chlorine chemistry. In this work, the Community Multiscale Air Quality (CMAQ) model with improved chlorine heterogeneous chemistry is applied to simulate the impact of chlorine chemistry on summer nitrate concentrations in Beijing. The results of this work can improve our understanding of nitrate formation.
Current chemical transport models cannot capture the diurnal and nocturnal variation in...
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