Articles | Volume 17, issue 9
https://doi.org/10.5194/acp-17-5703-2017
https://doi.org/10.5194/acp-17-5703-2017
Research article
 | 
08 May 2017
Research article |  | 08 May 2017

Fine particle pH and gas–particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign

Hongyu Guo, Jiumeng Liu, Karl D. Froyd, James M. Roberts, Patrick R. Veres, Patrick L. Hayes, Jose L. Jimenez, Athanasios Nenes, and Rodney J. Weber

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Ansari, A. S. and Pandis, S. N.: The effect of metastable equilibrium states on the partitioning of nitrate between the gas and aerosol phases, Atmos. Environ., 34, 157–168, https://doi.org/10.1016/s1352-2310(99)00242-3, 2000.
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Short summary
Fine particle pH is linked to many environmental impacts by affecting particle concentration and composition. Predicted Pasadena, CA (CalNex campaign), PM1 pH is 1.9 and PM2.5 pH 2.7, the latter higher due to sea salts. The model predicted gas–particle partitionings of HNO3–NO3, NH3–NH4+, and HCl–Cl are in good agreement, verifying the model predictions. A summary of contrasting locations in the US and eastern Mediterranean shows fine particles are generally highly acidic, with pH below 3.
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