Articles | Volume 19, issue 23
https://doi.org/10.5194/acp-19-14431-2019
https://doi.org/10.5194/acp-19-14431-2019
Research article
 | 
29 Nov 2019
Research article |  | 29 Nov 2019

Long-term total OH reactivity measurements in a boreal forest

Arnaud P. Praplan, Toni Tykkä, Dean Chen, Michael Boy, Ditte Taipale, Ville Vakkari, Putian Zhou, Tuukka Petäjä, and Heidi Hellén

Related authors

Undetected biogenic volatile organic compounds from Norway spruce drive total ozone reactivity measurements
Steven Job Thomas, Toni Tykkä, Heidi Hellén, Federico Bianchi, and Arnaud P. Praplan
Atmos. Chem. Phys., 23, 14627–14642, https://doi.org/10.5194/acp-23-14627-2023,https://doi.org/10.5194/acp-23-14627-2023, 2023
Short summary
Characterization of volatile organic compounds and submicron organic aerosol in a traffic environment
Sanna Saarikoski, Heidi Hellén, Arnaud P. Praplan, Simon Schallhart, Petri Clusius, Jarkko V. Niemi, Anu Kousa, Toni Tykkä, Rostislav Kouznetsov, Minna Aurela, Laura Salo, Topi Rönkkö, Luis M. F. Barreira, Liisa Pirjola, and Hilkka Timonen
Atmos. Chem. Phys., 23, 2963–2982, https://doi.org/10.5194/acp-23-2963-2023,https://doi.org/10.5194/acp-23-2963-2023, 2023
Short summary
Ozone reactivity measurement of biogenic volatile organic compound emissions
Detlev Helmig, Alex Guenther, Jacques Hueber, Ryan Daly, Wei Wang, Jeong-Hoo Park, Anssi Liikanen, and Arnaud P. Praplan
Atmos. Meas. Tech., 15, 5439–5454, https://doi.org/10.5194/amt-15-5439-2022,https://doi.org/10.5194/amt-15-5439-2022, 2022
Short summary
High variations of BVOC emissions from Norway spruce in boreal forests
Hannele Hakola, Ditte Taipale, Arnaud Praplan, Simon Schallhart, Steven Thomas, Toni Tykkä, Aku Helin, Jaana Bäck, and Heidi Hellén
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-478,https://doi.org/10.5194/acp-2022-478, 2022
Revised manuscript not accepted
Short summary
Oxidation product characterization from ozonolysis of the diterpene ent-kaurene
Yuanyuan Luo, Olga Garmash, Haiyan Li, Frans Graeffe, Arnaud P. Praplan, Anssi Liikanen, Yanjun Zhang, Melissa Meder, Otso Peräkylä, Josep Peñuelas, Ana María Yáñez-Serrano, and Mikael Ehn
Atmos. Chem. Phys., 22, 5619–5637, https://doi.org/10.5194/acp-22-5619-2022,https://doi.org/10.5194/acp-22-5619-2022, 2022
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion)
Romain Salignat, Matti Rissanen, Siddharth Iyer, Jean-Luc Baray, Pierre Tulet, Jean-Marc Metzger, Jérôme Brioude, Karine Sellegri, and Clémence Rose
Atmos. Chem. Phys., 24, 3785–3812, https://doi.org/10.5194/acp-24-3785-2024,https://doi.org/10.5194/acp-24-3785-2024, 2024
Short summary
Production of oxygenated volatile organic compounds from the ozonolysis of coastal seawater
Delaney B. Kilgour, Gordon A. Novak, Megan S. Claflin, Brian M. Lerner, and Timothy H. Bertram
Atmos. Chem. Phys., 24, 3729–3742, https://doi.org/10.5194/acp-24-3729-2024,https://doi.org/10.5194/acp-24-3729-2024, 2024
Short summary
Comment on “Transport of substantial stratospheric ozone to the surface by a dying typhoon and shallow convection” by Chen et al. (2022)
Xiangdong Zheng, Wen Yang, Yuting Sun, Chunmei Geng, Yingying Liu, and Xiaobin Xu
Atmos. Chem. Phys., 24, 3759–3768, https://doi.org/10.5194/acp-24-3759-2024,https://doi.org/10.5194/acp-24-3759-2024, 2024
Short summary
Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O3 destruction
James M. Roberts, Siyuan Wang, Patrick R. Veres, J. Andrew Neuman, Michael A. Robinson, Ilann Bourgeois, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Hannah M. Allen, John D. Crounse, Paul O. Wennberg, Samuel R. Hall, Kirk Ullmann, Simone Meinardi, Isobel J. Simpson, and Donald Blake
Atmos. Chem. Phys., 24, 3421–3443, https://doi.org/10.5194/acp-24-3421-2024,https://doi.org/10.5194/acp-24-3421-2024, 2024
Short summary
Individual coal mine methane emissions constrained by eddy covariance measurements: low bias and missing sources
Kai Qin, Wei Hu, Qin He, Fan Lu, and Jason Blake Cohen
Atmos. Chem. Phys., 24, 3009–3028, https://doi.org/10.5194/acp-24-3009-2024,https://doi.org/10.5194/acp-24-3009-2024, 2024
Short summary

Cited articles

Aaltonen, H., Pumpanen, J., Pihlatie, M., Hakola, H., Hellén, H., Kulmala, L., Vesala, T., and Bäck, J.: Boreal pine forest floor biogenic volatile organic compound emissions peak in early summer and autumn, Agr. Forest Meteorol., 151, 682–691, https://doi.org/10.1016/j.agrformet.2010.12.010, 2011. a
Atkinson, R., Aschmann, S. M., Winer, A. M., and Carter, W. P. L.: Rate constants for the gas-phase reactions of nitrate radicals with furan, thiophene, and pyrrole at 295 ± 1 K and atmospheric pressure, Environ. Sci. Technol., 19, 87–90, https://doi.org/10.1021/es00131a010, 1985. a
Atkinson, R., Baulch, D. L., Cox, R. A., Hampson, R. F., Kerr, J. A., and Troe, J.: Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement IV, IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry, J. Phys. Chem. Ref. Data, 21, 1125–1568, https://doi.org/10.1063/1.555918, 1992. a
Bloss, C., Wagner, V., Jenkin, M. E., Volkamer, R., Bloss, W. J., Lee, J. D., Heard, D. E., Wirtz, K., Martin-Reviejo, M., Rea, G., Wenger, J. C., and Pilling, M. J.: Development of a detailed chemical mechanism (MCMv3.1) for the atmospheric oxidation of aromatic hydrocarbons, Atmos. Chem. Phys., 5, 641–664, https://doi.org/10.5194/acp-5-641-2005, 2005. a
Bourtsoukidis, E., Behrendt, T., Yañez-Serrano, A. M., Hellén, H., Diamantopoulos, E., Catão, E., Ashworth, K., Pozzer, A., Quesada, C. A., Martins, D. L., Sá, M., Araujo, A., Brito, J., Artaxo, P., Kesselmeier, J., Lelieveld, J., and Williams, J.: Strong sesquiterpene emissions from Amazonian soils, Nat. Commun., 9, 2226, https://doi.org/10.1038/s41467-018-04658-y, 2018. a
Download

The requested paper has a corresponding corrigendum published. Please read the corrigendum first before downloading the article.

Short summary
Our study shows that, despite our best efforts and recent progress, our knowledge of the chemical composition of the air under the canopy of a boreal forest still cannot be fully characterized. The discrepancy between the measured total reactivity of the air and the reactivity derived from the known chemical composition highlights the need to better understand the emissions from vegetation, but also other sources, such as the forest soil.
Altmetrics
Final-revised paper
Preprint