Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

IF value: 5.414
IF5.414
IF 5-year value: 5.958
IF 5-year
5.958
CiteScore value: 9.7
CiteScore
9.7
SNIP value: 1.517
SNIP1.517
IPP value: 5.61
IPP5.61
SJR value: 2.601
SJR2.601
Scimago H <br class='widget-line-break'>index value: 191
Scimago H
index
191
h5-index value: 89
h5-index89
Volume 18, issue 4
Atmos. Chem. Phys., 18, 2381–2394, 2018
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 2381–2394, 2018
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 19 Feb 2018

Research article | 19 Feb 2018

Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO3

Katrin Dulitz et al.

Related authors

Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene
Terry J. Dillon, Katrin Dulitz, Christoph B. M. Groß, and John N. Crowley
Atmos. Chem. Phys., 17, 15137–15150, https://doi.org/10.5194/acp-17-15137-2017,https://doi.org/10.5194/acp-17-15137-2017, 2017
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR
Michael Rolletter, Marion Blocquet, Martin Kaminski, Birger Bohn, Hans-Peter Dorn, Andreas Hofzumahaus, Frank Holland, Xin Li, Franz Rohrer, Ralf Tillmann, Robert Wegener, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 20, 13701–13719, https://doi.org/10.5194/acp-20-13701-2020,https://doi.org/10.5194/acp-20-13701-2020, 2020
Short summary
Reaction between CH3C(O)OOH (peracetic acid) and OH in the gas phase: a combined experimental and theoretical study of the kinetics and mechanism
Matias Berasategui, Damien Amedro, Luc Vereecken, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 13541–13555, https://doi.org/10.5194/acp-20-13541-2020,https://doi.org/10.5194/acp-20-13541-2020, 2020
Short summary
Snow heterogeneous reactivity of bromide with ozone lost during snow metamorphism
Jacinta Edebeli, Jürg C. Trachsel, Sven E. Avak, Markus Ammann, Martin Schneebeli, Anja Eichler, and Thorsten Bartels-Rausch
Atmos. Chem. Phys., 20, 13443–13454, https://doi.org/10.5194/acp-20-13443-2020,https://doi.org/10.5194/acp-20-13443-2020, 2020
Short summary
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates
R. Anthony Cox, Markus Ammann, John N. Crowley, Hartmut Herrmann, Michael E. Jenkin, V. Faye McNeill, Abdelwahid Mellouki, Jürgen Troe, and Timothy J. Wallington
Atmos. Chem. Phys., 20, 13497–13519, https://doi.org/10.5194/acp-20-13497-2020,https://doi.org/10.5194/acp-20-13497-2020, 2020
Short summary
Technical Note: Effect of varying the λ = 185 and 254 nm photon flux ratio on radical generation in oxidation flow reactors
Jake P. Rowe, Andrew T. Lambe, and William H. Brune
Atmos. Chem. Phys., 20, 13417–13424, https://doi.org/10.5194/acp-20-13417-2020,https://doi.org/10.5194/acp-20-13417-2020, 2020
Short summary

Cited articles

Aloisio, S. and Francisco, J. S.: Structure and energetics of hydrogen bonded HOX-HNO3 complexes, J. Phys. Chem. A, 103, 6049–6053, 1999.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: volume I – gas phase reactions of Ox, HOx, NOxand SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Biaume, F.: Nitric acid vapour absorption cross-section spectrum and its photodissociation in the stratosphere, J. Photochem., 2, 139–149, 1973–1974.
Bogumil, K., Orphal, J., Homann, T., Voigt, S., Spietz, P., Fleischmann, O. C., Vogel, A., Hartmann, M., Kromminga, H., Bovensmann, H., Frerick, J., and Burrows, J. P.: Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230–2380 nm region, J. Photochem. Photobiol. A, 157, 167–184, https://doi.org/10.1016/s1010-6030(03)00062-5, 2003.
Brown, S. S., Talukdar, R. K., and Ravishankara, A. R.: Reconsideration of the rate constant for the reaction of hydroxyl radicals with nitric acid, J. Phys. Chem.-US, 103, 3031–3037, 1999.
Publications Copernicus
Download
Short summary
The reaction between the OH radical and HNO3 represents an important route for the release of NOx (NO and NO2) from HNO3, the most important NOx reservoir in many parts of the atmosphere. In our laboratory study, we have generated an extensive, high-quality set of rate coefficients for this reaction at different temperatures and pressures and used these to derive a new parameterisation of the rate coefficient for atmospheric modelling.
The reaction between the OH radical and HNO3 represents an important route for the release of...
Citation
Altmetrics
Final-revised paper
Preprint