Articles | Volume 16, issue 5
https://doi.org/10.5194/acp-16-2747-2016
https://doi.org/10.5194/acp-16-2747-2016
Research article
 | 
04 Mar 2016
Research article |  | 04 Mar 2016

Detailed budget analysis of HONO in central London reveals a missing daytime source

J. D. Lee, L. K. Whalley, D. E. Heard, D. Stone, R. E. Dunmore, J. F. Hamilton, D. E. Young, J. D. Allan, S. Laufs, and J. Kleffmann

Related authors

Data supporting the North Atlantic Climate System: Integrated Studies (ACSIS) programme, including atmospheric composition, oceanographic and sea ice observations (2016–2022) and output from ocean, atmosphere, land and sea-ice models (1950–2050)
Alexander T. Archibald, Bablu Sinha, Maria Russo, Emily Matthews, Freya Squires, N. Luke Abraham, Stephane Bauguitte, Thomas Bannan, Thomas Bell, David Berry, Lucy Carpenter, Hugh Coe, Andrew Coward, Peter Edwards, Daniel Feltham, Dwayne Heard, Jim Hopkins, James Keeble, Elizabeth C. Kent, Brian King, Isobel R. Lawrence, James Lee, Claire R. Macintosh, Alex Megann, Ben I. Moat, Katie Read, Chris Reed, Malcolm Roberts, Reinhard Schiemann, David Schroeder, Tim Smyth, Loren Temple, Navaneeth Thamban, Lisa Whalley, Simon Williams, Huihui Wu, and Ming-Xi Yang
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-405,https://doi.org/10.5194/essd-2023-405, 2024
Preprint under review for ESSD
Short summary
The effect of different Climate and Air Quality policies in China on in situ Ozone production in Beijing
Beth S. Nelson, Zhenze Liu, Freya A. Squires, Marvin Shaw, James R. Hopkins, Jacqueline F. Hamilton, Andrew R. Rickard, Alastair C. Lewis, Zongbo Shi, and James D. Lee
EGUsphere, https://doi.org/10.5194/egusphere-2023-2910,https://doi.org/10.5194/egusphere-2023-2910, 2024
Short summary
Aircraft-based mass balance estimate of methane emissions from offshore gas facilities in the southern North Sea
Magdalena Pühl, Anke Roiger, Alina Fiehn, Alan M. Gorchov Negron, Eric A. Kort, Stefan Schwietzke, Ignacio Pisso, Amy Foulds, James Lee, James L. France, Anna E. Jones, Dave Lowry, Rebecca E. Fisher, Langwen Huang, Jacob Shaw, Prudence Bateson, Stephen Andrews, Stuart Young, Pamela Dominutti, Tom Lachlan-Cope, Alexandra Weiss, and Grant Allen
Atmos. Chem. Phys., 24, 1005–1024, https://doi.org/10.5194/acp-24-1005-2024,https://doi.org/10.5194/acp-24-1005-2024, 2024
Short summary
Future tropospheric ozone budget and distribution over east Asia under a net-zero scenario
Xuewei Hou, Oliver Wild, Bin Zhu, and James Lee
Atmos. Chem. Phys., 23, 15395–15411, https://doi.org/10.5194/acp-23-15395-2023,https://doi.org/10.5194/acp-23-15395-2023, 2023
Short summary
Radical chemistry and ozone production at a UK coastal receptor site
Robert Woodward-Massey, Roberto Sommariva, Lisa K. Whalley, Danny R. Cryer, Trevor Ingham, William J. Bloss, Stephen M. Ball, Sam Cox, James D. Lee, Chris P. Reed, Leigh R. Crilley, Louisa J. Kramer, Brian J. Bandy, Grant L. Forster, Claire E. Reeves, Paul S. Monks, and Dwayne E. Heard
Atmos. Chem. Phys., 23, 14393–14424, https://doi.org/10.5194/acp-23-14393-2023,https://doi.org/10.5194/acp-23-14393-2023, 2023
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
Arianna Peron, Martin Graus, Marcus Striednig, Christian Lamprecht, Georg Wohlfahrt, and Thomas Karl
Atmos. Chem. Phys., 24, 7063–7083, https://doi.org/10.5194/acp-24-7063-2024,https://doi.org/10.5194/acp-24-7063-2024, 2024
Short summary
Emission characteristics of reactive organic gases (ROGs) from industrial volatile chemical products (VCPs) in the Pearl River Delta (PRD), China
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024,https://doi.org/10.5194/acp-24-7101-2024, 2024
Short summary
Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024,https://doi.org/10.5194/acp-24-6865-2024, 2024
Short summary
Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany
Junwei Song, Harald Saathoff, Feng Jiang, Linyu Gao, Hengheng Zhang, and Thomas Leisner
Atmos. Chem. Phys., 24, 6699–6717, https://doi.org/10.5194/acp-24-6699-2024,https://doi.org/10.5194/acp-24-6699-2024, 2024
Short summary
Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry
Xin Yang, Kimberly Strong, Alison S. Criscitiello, Marta Santos-Garcia, Kristof Bognar, Xiaoyi Zhao, Pierre Fogal, Kaley A. Walker, Sara M. Morris, and Peter Effertz
Atmos. Chem. Phys., 24, 5863–5886, https://doi.org/10.5194/acp-24-5863-2024,https://doi.org/10.5194/acp-24-5863-2024, 2024
Short summary

Cited articles

Acker, K., Möller, D., Wieprecht, W., Meixner, F. X., Bohn, B., Gilge, S., Plass-Dülmer, C., and Berresheim, H.: Strong daytime production of OH from HNO2 at a rural mountain site, Geophys. Res. Lett., 33, L02809, https://doi.org/10.1029/2005gl024643, 2006.
Alicke, B., Platt, U., and Stutz, J.: Impact of nitrous acid photolysis on the total hydroxyl radical budget during the Limitation of Oxidant Production/Pianura Padana Produzione di Ozono study in Milan, J. Geophys. Res., 107, 8196, https://doi.org/10.1029/2000jd000075, 2002.
Arens, F., Gutzwiller, L., Baltensperger, U., Gäggeler, H. W., and Ammann, M.: Heterogeneous Reaction of NO2 on Diesel Soot Particles, Environ. Sci. Technol., 35, 2191–2199, 2001.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Barlow, J. F., Dunbar, T. M., Nemitz, E. G., Wood, C. R., Gallagher, M. W., Davies, F., O'Connor, E., and Harrison, R. M.: Boundary layer dynamics over London, UK, as observed using Doppler lidar during REPARTEE-II, Atmos. Chem. Phys., 11, 2111–2125, https://doi.org/10.5194/acp-11-2111-2011, 2011.
Download
Short summary
This paper presents field measurements of HONO and a range of other gas phase and particulate species from an urban background site in London. The measured daytime HONO cannot be reproduced with a simple box model and thus a significant daytime missing source of HONO is present. We show that this missing source could be responsible for 40 % of the OH radical source and 57 % of the OH initiation; hence its potential importance for atmospheric oxidation and ozone production.
Altmetrics
Final-revised paper
Preprint