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Articles | Volume 13, issue 15
Atmos. Chem. Phys., 13, 7343–7358, 2013
https://doi.org/10.5194/acp-13-7343-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue: Megapoli-Paris 2009/2010 campaign
Atmos. Chem. Phys., 13, 7343–7358, 2013
https://doi.org/10.5194/acp-13-7343-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article 01 Aug 2013
Research article | 01 Aug 2013
CO, NOx and 13CO2 as tracers for fossil fuel CO2: results from a pilot study in Paris during winter 2010
M. Lopez et al.
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Atmos. Chem. Phys., 13, 7115–7132, https://doi.org/10.5194/acp-13-7115-2013, https://doi.org/10.5194/acp-13-7115-2013, 2013
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Bert Verreyken, Crist Amelynck, Jérôme Brioude, Jean-François Müller, Niels Schoon, Nicolas Kumps, Aurélie Colomb, Jean-Marc Metzger, Christopher F. Lee, Theodore K. Koenig, Rainer Volkamer, and Trissevgeni Stavrakou
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Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 20, 13011–13022, https://doi.org/10.5194/acp-20-13011-2020, https://doi.org/10.5194/acp-20-13011-2020, 2020
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Decadal trends and variations in OH are critical for understanding atmospheric CH4 evolution. We quantify the impacts of OH trends and variations on the CH4 budget by conducting CH4 inversions on a decadal scale with an ensemble of OH fields. We find the negative OH anomalies due to enhanced fires can reduce the optimized CH4 emissions by up to 10 Tg yr−1 during El Niño years and the positive OH trend from 1986 to 2010 results in a ∼ 23 Tg yr−1 additional increase in optimized CH4 emissions.
Vincent Michoud, Elise Hallemans, Laura Chiappini, Eva Leoz-Garziandia, Aurélie Colomb, Sébastien Dusanter, Isabelle Fronval, François Gheusi, Jean-Luc Jaffrezo, Thierry Léonardis, Nadine Locoge, Nicolas Marchand, Stéphane Sauvage, Jean Sciare, and Jean-François Doussin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1051, https://doi.org/10.5194/acp-2020-1051, 2020
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Alkuin Maximilian Koenig, Olivier Magand, Paolo Laj, Marcos Andrade, Isabel Moreno, Fernando Velarde, Grover Salvatierra, René Gutierrez, Luis Blacutt, Diego Aliaga, Thomas Reichler, Karine Sellegri, Olivier Laurent, Michel Ramonet, and Aurélien Dommergue
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The environmental cycling of atmospheric mercury, a harmful global contaminant, is still not sufficiently constrained, partly due to missing data in remote regions. Here, we address this issue by presenting 20 months of atmospheric mercury measurements, sampled in the Bolivian Andes. We observe a significant seasonal pattern, whose key features we explore. Moreover, we deduce ratios to constrain South American biomass burning mercury emissions and the mercury uptake by the Amazon rainforest.
Haeyoung Lee, Edward J. Dlugokencky, Jocelyn C. Turnbull, Sepyo Lee, Scott J. Lehman, John B. Miller, Gabrielle Pétron, Jeong-Sik Lim, Gang-Woong Lee, Sang-Sam Lee, and Young-San Park
Atmos. Chem. Phys., 20, 12033–12045, https://doi.org/10.5194/acp-20-12033-2020, https://doi.org/10.5194/acp-20-12033-2020, 2020
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To understand South Korea's CO2 emissions and sinks as well as those of the surrounding region, we used flask-air samples collected for 2 years at Anmyeondo (36.53° N, 126.32° E; 46 m a.s.l.), South Korea, for analysis of observed 14C in atmospheric CO2 as a tracer of fossil fuel CO2 contribution (Cff). Here, we showed our observation result of 14C and Cff. SF6 and CO can be good proxies of Cff in this study, and the ratio of CO to Cff was compared to a bottom-up inventory.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
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Atmos. Chem. Phys., 20, 11161–11180, https://doi.org/10.5194/acp-20-11161-2020, https://doi.org/10.5194/acp-20-11161-2020, 2020
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Clémence Rose, Matti P. Rissanen, Siddharth Iyer, Jonathan Duplissy, Chao Yan, John B. Nowak, Aurélie Colomb, Régis Dupuy, Xu-Cheng He, Janne Lampilahti, Yee Jun Tham, Daniela Wimmer, Jean-Marc Metzger, Pierre Tulet, Jérôme Brioude, Céline Planche, Markku Kulmala, and Karine Sellegri
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Sulfuric acid (H2SO4) is commonly accepted as a key precursor for atmospheric new particle formation. However, direct measurements of [H2SO4] remain challenging, thus motivating the development of proxies. Using data collected in two different volcanic plumes, we show, in these specific conditions, the good performance of a proxy from the literature and highlight as well the benefit of the newly developed proxies for the prediction of the highest [H2SO4] concentrations.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Edward J. Dlugokencky, Ray L. Langenfelds, Michel Ramonet, Doug Worthy, and Bo Zheng
Atmos. Chem. Phys., 20, 9525–9546, https://doi.org/10.5194/acp-20-9525-2020, https://doi.org/10.5194/acp-20-9525-2020, 2020
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The hydroxyl radical (OH), which is the dominant sink of methane (CH4), plays a key role in closing the global methane budget. This study quantifies how uncertainties in the hydroxyl radical can influence top-down estimates of CH4 emissions based on 4D Bayesian inversions with different OH fields and the same surface observations. We show that uncertainties in CH4 emissions driven by different OH fields are comparable to the uncertainties given by current bottom-up and top-down estimations.
Marielle Saunois, Ann R. Stavert, Ben Poulter, Philippe Bousquet, Josep G. Canadell, Robert B. Jackson, Peter A. Raymond, Edward J. Dlugokencky, Sander Houweling, Prabir K. Patra, Philippe Ciais, Vivek K. Arora, David Bastviken, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Kimberly M. Carlson, Mark Carrol, Simona Castaldi, Naveen Chandra, Cyril Crevoisier, Patrick M. Crill, Kristofer Covey, Charles L. Curry, Giuseppe Etiope, Christian Frankenberg, Nicola Gedney, Michaela I. Hegglin, Lena Höglund-Isaksson, Gustaf Hugelius, Misa Ishizawa, Akihiko Ito, Greet Janssens-Maenhout, Katherine M. Jensen, Fortunat Joos, Thomas Kleinen, Paul B. Krummel, Ray L. Langenfelds, Goulven G. Laruelle, Licheng Liu, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Joe McNorton, Paul A. Miller, Joe R. Melton, Isamu Morino, Jurek Müller, Fabiola Murguia-Flores, Vaishali Naik, Yosuke Niwa, Sergio Noce, Simon O'Doherty, Robert J. Parker, Changhui Peng, Shushi Peng, Glen P. Peters, Catherine Prigent, Ronald Prinn, Michel Ramonet, Pierre Regnier, William J. Riley, Judith A. Rosentreter, Arjo Segers, Isobel J. Simpson, Hao Shi, Steven J. Smith, L. Paul Steele, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Francesco N. Tubiello, Aki Tsuruta, Nicolas Viovy, Apostolos Voulgarakis, Thomas S. Weber, Michiel van Weele, Guido R. van der Werf, Ray F. Weiss, Doug Worthy, Debra Wunch, Yi Yin, Yukio Yoshida, Wenxin Zhang, Zhen Zhang, Yuanhong Zhao, Bo Zheng, Qing Zhu, Qiuan Zhu, and Qianlai Zhuang
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Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. We have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. This is the second version of the review dedicated to the decadal methane budget, integrating results of top-down and bottom-up estimates.
Yi Yin, Frederic Chevallier, Philippe Ciais, Philippe Bousquet, Marielle Saunois, Bo Zheng, John Worden, A. Anthony Bloom, Robert Parker, Daniel Jacob, Edward J. Dlugokencky, and Christian Frankenberg
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-649, https://doi.org/10.5194/acp-2020-649, 2020
Preprint under review for ACP
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The growth of methane, the second most important anthropogenic greenhouse gas after carbon dioxide, has been accelerating in the atmosphere in recent years. Using an ensemble of multi-tracer atmospheric inversions constrained by surface or satellite observations, we show that global methane emissions increased by nearly 1 % per year over 2010–2017, with leading contributions from the tropics and East Asia.
Jinghui Lian, François-Marie Bréon, Grégoire Broquet, Bo Zheng, Michel Ramonet, and Philippe Ciais
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-540, https://doi.org/10.5194/acp-2020-540, 2020
Revised manuscript has not been submitted
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Currently there is a growing interest in monitoring city-scale CO2 emissions based on atmospheric CO2 measurements, atmospheric transport modeling and inversion technique. We analyze the various sources of uncertainty that impact the atmospheric CO2 modeling and that may compromise the potential of this method for the monitoring of CO2 emission over Paris. Results suggest selection criteria for the assimilation of CO2 measurements into the inversion system that aims at retrieving city emissions.
Franz Slemr, Lynwill Martin, Casper Labuschagne, Thumeka Mkololo, Hélène Angot, Olivier Magand, Aurélien Dommergue, Philippe Garat, Michel Ramonet, and Johannes Bieser
Atmos. Chem. Phys., 20, 7683–7692, https://doi.org/10.5194/acp-20-7683-2020, https://doi.org/10.5194/acp-20-7683-2020, 2020
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Monitoring of atmospheric mercury (Hg) concentrations is an important part of the effectiveness evaluation of the Minamata Convention on Hg. Hg concentrations in 2012–2017 at Cape Point, South Africa, and at Amsterdam Island in the remote Indian Ocean are comparable, and no trend or a slightly downward trend was observed at both stations. Over the 2007–2017 period an upward trend was observed at CPT which was driven mainly by the 2007–2014 data. The trend and its change are discussed.
Jean-Luc Baray, Laurent Deguillaume, Aurélie Colomb, Karine Sellegri, Evelyn Freney, Clémence Rose, Joël Van Baelen, Jean-Marc Pichon, David Picard, Patrick Fréville, Laëtitia Bouvier, Mickaël Ribeiro, Pierre Amato, Sandra Banson, Angelica Bianco, Agnès Borbon, Lauréline Bourcier, Yannick Bras, Marcello Brigante, Philippe Cacault, Aurélien Chauvigné, Tiffany Charbouillot, Nadine Chaumerliac, Anne-Marie Delort, Marc Delmotte, Régis Dupuy, Antoine Farah, Guy Febvre, Andrea Flossmann, Christophe Gourbeyre, Claude Hervier, Maxime Hervo, Nathalie Huret, Muriel Joly, Victor Kazan, Morgan Lopez, Gilles Mailhot, Angela Marinoni, Olivier Masson, Nadège Montoux, Marius Parazols, Frédéric Peyrin, Yves Pointin, Michel Ramonet, Manon Rocco, Martine Sancelme, Stéphane Sauvage, Martina Schmidt, Emmanuel Tison, Mickaël Vaïtilingom, Paolo Villani, Miao Wang, Camille Yver-Kwok, and Paolo Laj
Atmos. Meas. Tech., 13, 3413–3445, https://doi.org/10.5194/amt-13-3413-2020, https://doi.org/10.5194/amt-13-3413-2020, 2020
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CO-PDD (Cézeaux-Aulnat-Opme-puy de Dôme) is a fully instrumented platform for atmospheric research. The four sites located at different altitudes from 330 to 1465 m around Clermont-Ferrand (France) host in situ and remote sensing instruments to measure atmospheric composition, including long-term trends and variability, to study interconnected processes (microphysical, chemical, biological, chemical, and dynamical) and to provide a reference point for climate models.
Pramod Kumar, Grégoire Broquet, Camille Yver-Kwok, Olivier Laurent, Susan Gichuki, Christopher Caldow, Ford Cropley, Thomas Lauvaux, Michel Ramonet, Guillaume Berthe, Frédéric Martin, Olivier Duclaux, Catherine Juery, Caroline Bouchet, and Philippe Ciais
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2020-226, https://doi.org/10.5194/amt-2020-226, 2020
Preprint under review for AMT
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This study presents a simple atmospheric inversion modeling framework for the localization and quantification of unknown CH4 and CO2 emissions from point sources based on near-surface mobile concentration measurements and a Gaussian plume dispersion model. It is applied for the estimate of a series of brief controlled releases of CH4 and CO2 with a wide range of rates during the TOTAL's TADI-2018 experiment. Results indicate a 20–30 % average error on the estimate of the release rates.
Katixa Lajaunie-Salla, Frédéric Diaz, Cathy Wimart-Rousseau, Thibaut Wagener, Dominique Lefèvre, Christophe Yohia, Irène Xueref-Remy, Brian Nathan, Alexandre Armengaud, and Christel Pinazo
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2020-41, https://doi.org/10.5194/gmd-2020-41, 2020
Revised manuscript accepted for GMD
Claudia Grossi, Scott D. Chambers, Olivier Llido, Felix R. Vogel, Victor Kazan, Alessandro Capuana, Sylvester Werczynski, Roger Curcoll, Marc Delmotte, Arturo Vargas, Josep-Anton Morguí, Ingeborg Levin, and Michel Ramonet
Atmos. Meas. Tech., 13, 2241–2255, https://doi.org/10.5194/amt-13-2241-2020, https://doi.org/10.5194/amt-13-2241-2020, 2020
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The sustainable support of radon metrology at the environmental level offers new scientific possibilities for the quantification of greenhouse gas (GHG) emissions and the determination of their source terms as well as for the identification of radioactive sources for the assessment of radiation exposure. This study helps to harmonize the techniques commonly used for atmospheric radon and radon progeny activity concentration measurements.
Cyrielle Denjean, Thierry Bourrianne, Frederic Burnet, Marc Mallet, Nicolas Maury, Aurélie Colomb, Pamela Dominutti, Joel Brito, Régis Dupuy, Karine Sellegri, Alfons Schwarzenboeck, Cyrille Flamant, and Peter Knippertz
Atmos. Chem. Phys., 20, 4735–4756, https://doi.org/10.5194/acp-20-4735-2020, https://doi.org/10.5194/acp-20-4735-2020, 2020
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This paper presents aircraft measurements of aerosol optical properties over southern West Africa. We show that aerosol optical properties in the boundary layer were dominated by a persistent biomass burning loading from the Southern Hemisphere. Biomass burning aerosols were more light absorbing that those previously measured in other areas (Amazonia, North America). Our study suggests that lens-coated black carbon particles were the dominant absorber for these biomass burning aerosols.
Antoine Berchet, Isabelle Pison, Patrick M. Crill, Brett Thornton, Philippe Bousquet, Thibaud Thonat, Thomas Hocking, Joël Thanwerdas, Jean-Daniel Paris, and Marielle Saunois
Atmos. Chem. Phys., 20, 3987–3998, https://doi.org/10.5194/acp-20-3987-2020, https://doi.org/10.5194/acp-20-3987-2020, 2020
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Methane isotopes in the atmosphere can help us differentiate between emission processes. A large variety of natural and anthropogenic emission types are active in the Arctic and are unsatisfactorily understood and documented up to now. A ship-based campaign was carried out in summer 2014, providing a unique dataset of isotopic measurements in the Arctic Ocean. Using a chemistry-transport model, we link these measurements to circumpolar emissions and retrieve information about their signature.
Shamil Maksyutov, Tomohiro Oda, Makoto Saito, Rajesh Janardanan, Dmitry Belikov, Johannes W. Kaiser, Ruslan Zhuravlev, Alexander Ganshin, Vinu K. Valsala, Arlyn Andrews, Lukasz Chmura, Edward Dlugokencky, László Haszpra, Ray L. Langenfelds, Toshinobu Machida, Takakiyo Nakazawa, Michel Ramonet, Colm Sweeney, and Douglas Worthy
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-251, https://doi.org/10.5194/acp-2020-251, 2020
Revised manuscript accepted for ACP
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In order to improve the top-down estimation of the anthropogenic greenhouse gas emissions, a high-resolution inverse modeling technique was developed for applications to global transport modeling of carbon dioxide and other greenhouse gases. A coupled Eulerian-Lagrangian transport model and its adjoint are combined with surface fluxes at 0.1-degree resolution to provide high-resolution forward simulation and inverse modeling of surface fluxes accounting for signals from emission hotspots.
Sébastien Conil, Julie Helle, Laurent Langrene, Olivier Laurent, Marc Delmotte, and Michel Ramonet
Atmos. Meas. Tech., 12, 6361–6383, https://doi.org/10.5194/amt-12-6361-2019, https://doi.org/10.5194/amt-12-6361-2019, 2019
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Continuous measurements of greenhouse gases using high-precision spectrometers started in 2011 on a tall tower with three sampling inlets at 10 m, 50 m and 120 m above the ground at the OPE station, in the eastern part of France. The measurement strategy for carbon dioxide (CO2), methane (CH4) and carbon monoxide (CO) follows the ICOS recommendations. Over the 2011–2018 period, the CO2 and CH4 data show trends with annual growth rates of 2.4 ppm yr−1 and 8.8 ppb yr−1 at the 120 m level.
Minqiang Zhou, Bavo Langerock, Mahesh Kumar Sha, Nicolas Kumps, Christian Hermans, Christof Petri, Thorsten Warneke, Huilin Chen, Jean-Marc Metzger, Rigel Kivi, Pauli Heikkinen, Michel Ramonet, and Martine De Mazière
Atmos. Meas. Tech., 12, 6125–6141, https://doi.org/10.5194/amt-12-6125-2019, https://doi.org/10.5194/amt-12-6125-2019, 2019
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In this study, CH4 vertical profile is retrieved by SFIT4 code from FTIR NIR spectra based on six sites during 2016–2017. The degree of freedom for signal of the SFIT4NIR retrieval is about 2.4, with two distinct species of information in the troposphere and in the stratosphere. By comparison against other measurements, e.g. TCCON standard products, satellite observations and AirCore measurements, the uncertainties of the SFIT4NIR total column and partial columns are estimated and discussed.
Jinghui Lian, François-Marie Bréon, Grégoire Broquet, T. Scott Zaccheo, Jeremy Dobler, Michel Ramonet, Johannes Staufer, Diego Santaren, Irène Xueref-Remy, and Philippe Ciais
Atmos. Chem. Phys., 19, 13809–13825, https://doi.org/10.5194/acp-19-13809-2019, https://doi.org/10.5194/acp-19-13809-2019, 2019
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CO2 emissions within urban areas impact nearby and downwind concentrations. A different system, based on bi-wavelength laser measurements, has been deployed over Paris. It samples CO2 concentrations along horizontal lines, between a transceiver and a reflector. In this paper, we analyze the measurements provided by this system, together with the more classical in situ sampling and high-resolution modeling. We focus on the temporal and spatial variability of atmospheric CO2 concentrations.
Minqiang Zhou, Bavo Langerock, Corinne Vigouroux, Mahesh Kumar Sha, Christian Hermans, Jean-Marc Metzger, Huilin Chen, Michel Ramonet, Rigel Kivi, Pauli Heikkinen, Dan Smale, David F. Pollard, Nicholas Jones, Voltaire A. Velazco, Omaira E. García, Matthias Schneider, Mathias Palm, Thorsten Warneke, and Martine De Mazière
Atmos. Meas. Tech., 12, 5979–5995, https://doi.org/10.5194/amt-12-5979-2019, https://doi.org/10.5194/amt-12-5979-2019, 2019
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The differences between the TCCON and NDACC XCO measurements are investigated and discussed based on six NDACC–TCCON sites (Ny-Ålesund, Bremen, Izaña, Saint-Denis, Wollongong and Lauder) using data over the period 2007–2017. The smoothing errors from both TCCON and NDACC measurements are estimated. In addition, the scaling factor of the TCCON XCO data is reassessed by comparing with the AirCore measurements at Sodankylä and Orléans.
Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Didier A. Hauglustaine, Sophie Szopa, Ann R. Stavert, Nathan Luke Abraham, Alex T. Archibald, Slimane Bekki, Makoto Deushi, Patrick Jöckel, Béatrice Josse, Douglas Kinnison, Ole Kirner, Virginie Marécal, Fiona M. O'Connor, David A. Plummer, Laura E. Revell, Eugene Rozanov, Andrea Stenke, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
Atmos. Chem. Phys., 19, 13701–13723, https://doi.org/10.5194/acp-19-13701-2019, https://doi.org/10.5194/acp-19-13701-2019, 2019
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The role of hydroxyl radical changes in methane trends is debated, hindering our understanding of the methane cycle. This study quantifies how uncertainties in the hydroxyl radical may influence methane abundance in the atmosphere based on the inter-model comparison of hydroxyl radical fields and model simulations of CH4 abundance with different hydroxyl radical scenarios during 2000–2016. We show that hydroxyl radical changes could contribute up to 54 % of model-simulated methane biases.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, Didier Hauglustaine, Michel Ramonet, Cyril Crevoisier, Bianca Baier, Colm Sweeney, and Philippe Bousquet
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-925, https://doi.org/10.5194/acp-2019-925, 2019
Revised manuscript not accepted
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Oxidation by the hydroxyl radical (OH) is the dominant atmospheric sink for methane, contributing to approximately 90 % of the total methane loss. Chemical losses by reaction with atomic oxygen (O1D) and chlorine radicals (Cl) in the stratosphere are other sinks, contributing about 3 % to the total methane destruction. We assess here the impact of atomic Cl on atmospheric methane mixing ratios, methane atmospheric loss and atmospheric isotopic δ13C-CH4 values.
Clémence Rose, Brice Foucart, David Picard, Aurélie Colomb, Jean-Marc Metzger, Pierre Tulet, and Karine Sellegri
Atmos. Chem. Phys., 19, 13243–13265, https://doi.org/10.5194/acp-19-13243-2019, https://doi.org/10.5194/acp-19-13243-2019, 2019
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New particle formation (NPF) is a significant climate-relevant source of aerosols in the atmosphere. We show that during the eruptive periods of the Piton de la Fournaise in 2015, NPF was favoured compared to regular days. Using the largest dataset ever reported in volcanic plume conditions, we quantify the emission rates of particles over a broad size range and provide a new statistically robust parameterization to take into account this important source of atmospheric particles in models.
Thibaud Thonat, Marielle Saunois, Isabelle Pison, Antoine Berchet, Thomas Hocking, Brett F. Thornton, Patrick M. Crill, and Philippe Bousquet
Atmos. Chem. Phys., 19, 12141–12161, https://doi.org/10.5194/acp-19-12141-2019, https://doi.org/10.5194/acp-19-12141-2019, 2019
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This paper discusses the methane isotopic signals that could be detected at instrumental surface sites in the northern high latitudes using a 3–D chemistry transport model. Isotopic signals may be used in atmospheric inverse systems to better characterize methane emissions and changes. We show that depending on the source magnitude and the location of the site, detecting isotopic signals of specific individual sources may be challenging for the new generation of methane isotope instruments.
Pamela Dominutti, Sekou Keita, Julien Bahino, Aurélie Colomb, Cathy Liousse, Véronique Yoboué, Corinne Galy-Lacaux, Eleanor Morris, Laëtitia Bouvier, Stéphane Sauvage, and Agnès Borbon
Atmos. Chem. Phys., 19, 11721–11741, https://doi.org/10.5194/acp-19-11721-2019, https://doi.org/10.5194/acp-19-11721-2019, 2019
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Several field campaigns were performed in southern West Africa in the framework of the DACCIWA project with the purpose of measuring a broad range of atmospheric constituents. Our study presents the analysis of a comprehensive dataset which integrates up to 56 species of VOCs measured at different ambient sites and emission sources. Our detailed VOC estimation for Cote d'Ivoire is 3 to 6 times higher than the whole of Europe, transportation being the dominant source of VOCs.
Valentin Duflot, Pierre Tulet, Olivier Flores, Christelle Barthe, Aurélie Colomb, Laurent Deguillaume, Mickael Vaïtilingom, Anne Perring, Alex Huffman, Mark T. Hernandez, Karine Sellegri, Ellis Robinson, David J. O'Connor, Odessa M. Gomez, Frédéric Burnet, Thierry Bourrianne, Dominique Strasberg, Manon Rocco, Allan K. Bertram, Patrick Chazette, Julien Totems, Jacques Fournel, Pierre Stamenoff, Jean-Marc Metzger, Mathilde Chabasset, Clothilde Rousseau, Eric Bourrianne, Martine Sancelme, Anne-Marie Delort, Rachel E. Wegener, Cedric Chou, and Pablo Elizondo
Atmos. Chem. Phys., 19, 10591–10618, https://doi.org/10.5194/acp-19-10591-2019, https://doi.org/10.5194/acp-19-10591-2019, 2019
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The Forests gAses aeRosols Clouds Exploratory (FARCE) campaign was conducted in March–April 2015 on the tropical island of La Réunion. For the first time, several scientific teams from different disciplines collaborated to provide reference measurements and characterization of La Réunion vegetation, volatile organic compounds (VOCs), biogenic VOCs (BVOCs), (bio)aerosols and composition of clouds, with a strong focus on the Maïdo mount slope area.
Anna Agustí-Panareda, Michail Diamantakis, Sébastien Massart, Frédéric Chevallier, Joaquín Muñoz-Sabater, Jérôme Barré, Roger Curcoll, Richard Engelen, Bavo Langerock, Rachel M. Law, Zoë Loh, Josep Anton Morguí, Mark Parrington, Vincent-Henri Peuch, Michel Ramonet, Coleen Roehl, Alex T. Vermeulen, Thorsten Warneke, and Debra Wunch
Atmos. Chem. Phys., 19, 7347–7376, https://doi.org/10.5194/acp-19-7347-2019, https://doi.org/10.5194/acp-19-7347-2019, 2019
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This paper demonstrates the benefits of using global models with high horizontal resolution to represent atmospheric CO2 patterns associated with evolving weather. The modelling of CO2 weather is crucial to interpret the variability from ground-based and satellite CO2 observations, which can then be used to infer CO2 fluxes in atmospheric inversions. The benefits of high resolution come from an improved representation of the topography, winds, tracer transport and CO2 flux distribution.
Emmanuel Arzoumanian, Felix R. Vogel, Ana Bastos, Bakhram Gaynullin, Olivier Laurent, Michel Ramonet, and Philippe Ciais
Atmos. Meas. Tech., 12, 2665–2677, https://doi.org/10.5194/amt-12-2665-2019, https://doi.org/10.5194/amt-12-2665-2019, 2019
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We tested commercial lower-cost CO2 sensors in laboratory and field studies to see if they can measure atmospheric CO2 mole fractions with less than 1 ppm bias (with monthly calibration), to allow continuous urban CO2 monitoring.
We find that the sensors' CO2 readings are influenced by temperature, atmospheric pressure and water vapour content, but this can be corrected for by adding sensors (T, p, RH) and carefully calibrating each sensor against a high-precision instrument.
Emily D. White, Matthew Rigby, Mark F. Lunt, T. Luke Smallman, Edward Comyn-Platt, Alistair J. Manning, Anita L. Ganesan, Simon O'Doherty, Ann R. Stavert, Kieran Stanley, Mathew Williams, Peter Levy, Michel Ramonet, Grant L. Forster, Andrew C. Manning, and Paul I. Palmer
Atmos. Chem. Phys., 19, 4345–4365, https://doi.org/10.5194/acp-19-4345-2019, https://doi.org/10.5194/acp-19-4345-2019, 2019
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Understanding carbon dioxide (CO2) fluxes from the terrestrial biosphere on a national scale is important for evaluating land use strategies to mitigate climate change. We estimate emissions of CO2 from the UK biosphere using atmospheric data in a top-down approach. Our findings show that bottom-up estimates from models of biospheric fluxes overestimate the amount of CO2 uptake in summer. This suggests these models wrongly estimate or omit key processes, e.g. land disturbance due to harvest.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Carole Helfter, Neil Mullinger, Massimo Vieno, Simon O'Doherty, Michel Ramonet, Paul I. Palmer, and Eiko Nemitz
Atmos. Chem. Phys., 19, 3043–3063, https://doi.org/10.5194/acp-19-3043-2019, https://doi.org/10.5194/acp-19-3043-2019, 2019
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We present a novel approach to estimate the annual budgets of carbon dioxide (881.0 ± 128.5 Tg) and methane (2.55 ± 0.48 Tg) of the British Isles from shipborne measurements taken over a 3-year period (2015–2017). This study brings independent verification of the emission budgets estimated using alternative products and investigates the seasonality of these emissions, which is usually not possible.
Marine Remaud, Frédéric Chevallier, Anne Cozic, Xin Lin, and Philippe Bousquet
Geosci. Model Dev., 11, 4489–4513, https://doi.org/10.5194/gmd-11-4489-2018, https://doi.org/10.5194/gmd-11-4489-2018, 2018
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We compare several versions of a global atmospheric transport model for the simulation of CO2. The representation of subgrid-scale processes modulates the interhemispheric gradient and the amplitude of the seasonal cycle in the Northern Hemisphere. It has the largest impact over Brazil. Refining the horizontal resolution improves the simulation near emission hotspots or along the coastlines. The sensitivities to the land surface model and to the increase in vertical resolution are marginal.
Minqiang Zhou, Bavo Langerock, Corinne Vigouroux, Mahesh Kumar Sha, Michel Ramonet, Marc Delmotte, Emmanuel Mahieu, Whitney Bader, Christian Hermans, Nicolas Kumps, Jean-Marc Metzger, Valentin Duflot, Zhiting Wang, Mathias Palm, and Martine De Mazière
Atmos. Chem. Phys., 18, 13881–13901, https://doi.org/10.5194/acp-18-13881-2018, https://doi.org/10.5194/acp-18-13881-2018, 2018
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This study focuses on atmospheric CO and CH4 time series and seasonal variations on Reunion Island based on in situ and FTIR measurements from two sites, Saint Denis and Maido. Ground-based in situ and FTIR (NDACC and TCCON) measurements are used to show their complementarity with regards to obtaining the CO and CH4 concentrations at the surface and in the troposphere and stratosphere. FLEXPART and GEOS-Chem models are applied to understand the seasonal variations of CO and CH4 at this site.
Cyrille Flamant, Adrien Deroubaix, Patrick Chazette, Joel Brito, Marco Gaetani, Peter Knippertz, Andreas H. Fink, Gaëlle de Coetlogon, Laurent Menut, Aurélie Colomb, Cyrielle Denjean, Rémi Meynadier, Philip Rosenberg, Regis Dupuy, Pamela Dominutti, Jonathan Duplissy, Thierry Bourrianne, Alfons Schwarzenboeck, Michel Ramonet, and Julien Totems
Atmos. Chem. Phys., 18, 12363–12389, https://doi.org/10.5194/acp-18-12363-2018, https://doi.org/10.5194/acp-18-12363-2018, 2018
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This work sheds light on the complex mechanisms by which coastal shallow circulations distribute atmospheric pollutants over the densely populated southern West African region. Pollutants of concern are anthropogenic emissions from coastal cities, as well as biomass burning aerosol and dust associated with long-range transport. The complex vertical distribution of aerosols over coastal southern West Africa is investigated using airborne observations and numerical simulations.
Maarten Krol, Marco de Bruine, Lars Killaars, Huug Ouwersloot, Andrea Pozzer, Yi Yin, Frederic Chevallier, Philippe Bousquet, Prabir Patra, Dmitry Belikov, Shamil Maksyutov, Sandip Dhomse, Wuhu Feng, and Martyn P. Chipperfield
Geosci. Model Dev., 11, 3109–3130, https://doi.org/10.5194/gmd-11-3109-2018, https://doi.org/10.5194/gmd-11-3109-2018, 2018
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The TransCom inter-comparison project regularly carries out studies to quantify errors in simulated atmospheric transport. This paper presents the first results of an age of air (AoA) inter-comparison of six global transport models. Following a protocol, six models simulated five tracers from which atmospheric transport times can easily be deduced. Results highlight that inter-model differences associated with atmospheric transport are still large and require further analysis.
Xin Lin, Philippe Ciais, Philippe Bousquet, Michel Ramonet, Yi Yin, Yves Balkanski, Anne Cozic, Marc Delmotte, Nikolaos Evangeliou, Nuggehalli K. Indira, Robin Locatelli, Shushi Peng, Shilong Piao, Marielle Saunois, Panangady S. Swathi, Rong Wang, Camille Yver-Kwok, Yogesh K. Tiwari, and Lingxi Zhou
Atmos. Chem. Phys., 18, 9475–9497, https://doi.org/10.5194/acp-18-9475-2018, https://doi.org/10.5194/acp-18-9475-2018, 2018
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We simulate CH4 and CO2 using a zoomed global transport model with a horizontal resolution of ~50 km over South and East Asia, as well as a standard model version for comparison. Model performance is evaluated for both gases and versions at multiple timescales against a new collection of surface stations over this key GHG-emitting region. The evaluation at different timescales and comparisons between gases and model versions have implications for possible model improvements and inversions.
Sekou Keita, Cathy Liousse, Véronique Yoboué, Pamela Dominutti, Benjamin Guinot, Eric-Michel Assamoi, Agnès Borbon, Sophie L. Haslett, Laetitia Bouvier, Aurélie Colomb, Hugh Coe, Aristide Akpo, Jacques Adon, Julien Bahino, Madina Doumbia, Julien Djossou, Corinne Galy-Lacaux, Eric Gardrat, Sylvain Gnamien, Jean F. Léon, Money Ossohou, E. Touré N'Datchoh, and Laurent Roblou
Atmos. Chem. Phys., 18, 7691–7708, https://doi.org/10.5194/acp-18-7691-2018, https://doi.org/10.5194/acp-18-7691-2018, 2018
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This study provides emission factor (EF) data for elemental and organic carbon, total particulate matter and 58 volatile organic compound species for combustion sources specific to Africa to establish emission inventories with less uncertainty. EFs obtained in this study are generally higher than those in the literature whose values are used in emissions inventories for Africa. This shows that particles and VOC emissions were sometimes underestimated and underlines this study's importance.
Arineh Cholakian, Matthias Beekmann, Augustin Colette, Isabelle Coll, Guillaume Siour, Jean Sciare, Nicolas Marchand, Florian Couvidat, Jorge Pey, Valerie Gros, Stéphane Sauvage, Vincent Michoud, Karine Sellegri, Aurélie Colomb, Karine Sartelet, Helen Langley DeWitt, Miriam Elser, André S. H. Prévot, Sonke Szidat, and François Dulac
Atmos. Chem. Phys., 18, 7287–7312, https://doi.org/10.5194/acp-18-7287-2018, https://doi.org/10.5194/acp-18-7287-2018, 2018
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In this work, four schemes for the simulation of organic aerosols in the western Mediterranean basin are added to the CHIMERE chemistry–transport model; the resulting simulations are then compared to measurements obtained from ChArMEx. It is concluded that the scheme taking into account the fragmentation and the formation of nonvolatile organic aerosols corresponds better to measurements; the major source of this aerosol in the western Mediterranean is found to be of biogenic origin.
Evelyn Freney, Karine Sellegri, Mounir Chrit, Kouji Adachi, Joel Brito, Antoine Waked, Agnès Borbon, Aurélie Colomb, Régis Dupuy, Jean-Marc Pichon, Laetitia Bouvier, Claire Delon, Corinne Jambert, Pierre Durand, Thierry Bourianne, Cécile Gaimoz, Sylvain Triquet, Anaïs Féron, Matthias Beekmann, François Dulac, and Karine Sartelet
Atmos. Chem. Phys., 18, 7041–7056, https://doi.org/10.5194/acp-18-7041-2018, https://doi.org/10.5194/acp-18-7041-2018, 2018
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The focus of these experiments, within the ChArMEx project, were to better understand the chemical properties of ambient aerosols over the Mediterranean region. A series of airborne measurements were performed aboard the French research aircraft, the ATR42, during the summer period. Aerosol and gas-phase chemical mass spectrometry allowed us to understand the sources and formation of organic aerosols. Numerical models were incorporated into this study to help interpret our observations.
Abdelhadi El Yazidi, Michel Ramonet, Philippe Ciais, Gregoire Broquet, Isabelle Pison, Amara Abbaris, Dominik Brunner, Sebastien Conil, Marc Delmotte, Francois Gheusi, Frederic Guerin, Lynn Hazan, Nesrine Kachroudi, Giorgos Kouvarakis, Nikolaos Mihalopoulos, Leonard Rivier, and Dominique Serça
Atmos. Meas. Tech., 11, 1599–1614, https://doi.org/10.5194/amt-11-1599-2018, https://doi.org/10.5194/amt-11-1599-2018, 2018
Isabelle Pison, Antoine Berchet, Marielle Saunois, Philippe Bousquet, Grégoire Broquet, Sébastien Conil, Marc Delmotte, Anita Ganesan, Olivier Laurent, Damien Martin, Simon O'Doherty, Michel Ramonet, T. Gerard Spain, Alex Vermeulen, and Camille Yver Kwok
Atmos. Chem. Phys., 18, 3779–3798, https://doi.org/10.5194/acp-18-3779-2018, https://doi.org/10.5194/acp-18-3779-2018, 2018
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Methane emissions on the national scale in France in 2012 are inferred by assimilating continuous atmospheric mixing ratio measurements from nine stations of the European network ICOS. Two complementary inversion set-ups are computed and analysed: (i) a regional run correcting for the spatial distribution of fluxes in France and (ii) a sectorial run correcting fluxes for activity sectors on the national scale. The results are compared with existing inventories and other regional inversions.
Magnus Gålfalk, Martin Karlson, Patrick Crill, Philippe Bousquet, and David Bastviken
Biogeosciences, 15, 1549–1557, https://doi.org/10.5194/bg-15-1549-2018, https://doi.org/10.5194/bg-15-1549-2018, 2018
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We describe a quick in situ method for mapping ground surface cover, calculating areas of each surface type in a 10 x 10 m plot for each measurement. The method is robust, weather-independent, easily carried out, and uses wide-field imaging with a standard remote-controlled camera mounted on a very long extendible monopod from a height of 3–4.5 m. The method enables collection of detailed field reference data, critical in many remote sensing applications, such as wetland mapping.
Irène Xueref-Remy, Elsa Dieudonné, Cyrille Vuillemin, Morgan Lopez, Christine Lac, Martina Schmidt, Marc Delmotte, Frédéric Chevallier, François Ravetta, Olivier Perrussel, Philippe Ciais, François-Marie Bréon, Grégoire Broquet, Michel Ramonet, T. Gerard Spain, and Christophe Ampe
Atmos. Chem. Phys., 18, 3335–3362, https://doi.org/10.5194/acp-18-3335-2018, https://doi.org/10.5194/acp-18-3335-2018, 2018
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Urbanized and industrialized areas are the largest source of fossil CO2. This work analyses the atmospheric CO2 variability observed from the first in situ network deployed in the Paris megacity area. Gradients of several ppm are found between the rural, peri-urban and urban sites at the diurnal to the seasonal scales. Wind direction and speed as well as boundary layer dynamics, correlated to highly variable urban emissions, are shown to be key regulator factors of the observed CO2 records.
Peter Bergamaschi, Ute Karstens, Alistair J. Manning, Marielle Saunois, Aki Tsuruta, Antoine Berchet, Alexander T. Vermeulen, Tim Arnold, Greet Janssens-Maenhout, Samuel Hammer, Ingeborg Levin, Martina Schmidt, Michel Ramonet, Morgan Lopez, Jost Lavric, Tuula Aalto, Huilin Chen, Dietrich G. Feist, Christoph Gerbig, László Haszpra, Ove Hermansen, Giovanni Manca, John Moncrieff, Frank Meinhardt, Jaroslaw Necki, Michal Galkowski, Simon O'Doherty, Nina Paramonova, Hubertus A. Scheeren, Martin Steinbacher, and Ed Dlugokencky
Atmos. Chem. Phys., 18, 901–920, https://doi.org/10.5194/acp-18-901-2018, https://doi.org/10.5194/acp-18-901-2018, 2018
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European methane (CH4) emissions are estimated for 2006–2012 using atmospheric in situ measurements from 18 European monitoring stations and 7 different inverse models. Our analysis highlights the potential significant contribution of natural emissions from wetlands (including peatlands and wet soils) to the total European emissions. The top-down estimates of total EU-28 CH4 emissions are broadly consistent with the sum of reported anthropogenic CH4 emissions and the estimated natural emissions.
Joel Brito, Evelyn Freney, Pamela Dominutti, Agnes Borbon, Sophie L. Haslett, Anneke M. Batenburg, Aurelie Colomb, Regis Dupuy, Cyrielle Denjean, Frederic Burnet, Thierry Bourriane, Adrien Deroubaix, Karine Sellegri, Stephan Borrmann, Hugh Coe, Cyrille Flamant, Peter Knippertz, and Alfons Schwarzenboeck
Atmos. Chem. Phys., 18, 757–772, https://doi.org/10.5194/acp-18-757-2018, https://doi.org/10.5194/acp-18-757-2018, 2018
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This work focuses on sources of submicron aerosol particles over southern West Africa (SWA). Results have shown that isoprene, a gas-phase compound of biogenic origin, is responsible for roughly 25 % of the organic aerosol (OA) loading, under most background or urban plumes alike. This fraction represents a lower estimate from the biogenic contribution in this fairly polluted region. This work sheds light upon the role of anthropogenic and biogenic emissions on the pollution burden over SWA.
Sébastien Ars, Grégoire Broquet, Camille Yver Kwok, Yelva Roustan, Lin Wu, Emmanuel Arzoumanian, and Philippe Bousquet
Atmos. Meas. Tech., 10, 5017–5037, https://doi.org/10.5194/amt-10-5017-2017, https://doi.org/10.5194/amt-10-5017-2017, 2017
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This study presents a new concept for estimating the pollutant emission rates of a site combining the tracer release method, local-scale atmospheric transport modelling and a statistical atmospheric inversion approach. The potential of this new concept is evaluated with a practical implementation based on a series of inversions of controlled methane and tracer point sources in different spatial configurations to assess the efficiency of the method in comparison with the classic tracer method.
Zhiting Wang, Thorsten Warneke, Nicholas M. Deutscher, Justus Notholt, Ute Karstens, Marielle Saunois, Matthias Schneider, Ralf Sussmann, Harjinder Sembhi, David W. T. Griffith, Dave F. Pollard, Rigel Kivi, Christof Petri, Voltaire A. Velazco, Michel Ramonet, and Huilin Chen
Atmos. Chem. Phys., 17, 13283–13295, https://doi.org/10.5194/acp-17-13283-2017, https://doi.org/10.5194/acp-17-13283-2017, 2017
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In this paper we separate the biases of atmospheric methane models into stratospheric and tropospheric parts. It is observed in other studies that simulated total columns of atmospheric methane present a latitudinal bias compared to measurements. The latitudinal gradients are considered to be from the stratosphere. However, our results show that the latitudinal biases could come from the troposphere in two of three models evaluated in this study.
Nora Zannoni, Valerie Gros, Roland Sarda Esteve, Cerise Kalogridis, Vincent Michoud, Sebastien Dusanter, Stephane Sauvage, Nadine Locoge, Aurelie Colomb, and Bernard Bonsang
Atmos. Chem. Phys., 17, 12645–12658, https://doi.org/10.5194/acp-17-12645-2017, https://doi.org/10.5194/acp-17-12645-2017, 2017
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Our paper presents results of hydroxyl radical (OH) reactivity from a field study conducted during summer 2013 in a western Mediterranean coastal site (Corsica, France). Here, the total OH reactivity, measured with the comparative reactivity method, is compared with the summed OH reactivity from the reactive gases measured with a multitude of different technologies. Our results demonstrate the relatively high observed reactivity and the large impact of biogenic compounds.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Ray Weiss, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Atmos. Chem. Phys., 17, 11135–11161, https://doi.org/10.5194/acp-17-11135-2017, https://doi.org/10.5194/acp-17-11135-2017, 2017
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Following the Global Methane Budget 2000–2012 published in Saunois et al. (2016), we use the same dataset of bottom-up and top-down approaches to discuss the variations in methane emissions over the period 2000–2012. The changes in emissions are discussed both in terms of trends and quasi-decadal changes. The ensemble gathered here allows us to synthesise the robust changes in terms of regional and sectorial contributions to the increasing methane emissions.
Vincent Michoud, Jean Sciare, Stéphane Sauvage, Sébastien Dusanter, Thierry Léonardis, Valérie Gros, Cerise Kalogridis, Nora Zannoni, Anaïs Féron, Jean-Eudes Petit, Vincent Crenn, Dominique Baisnée, Roland Sarda-Estève, Nicolas Bonnaire, Nicolas Marchand, H. Langley DeWitt, Jorge Pey, Aurélie Colomb, François Gheusi, Sonke Szidat, Iasonas Stavroulas, Agnès Borbon, and Nadine Locoge
Atmos. Chem. Phys., 17, 8837–8865, https://doi.org/10.5194/acp-17-8837-2017, https://doi.org/10.5194/acp-17-8837-2017, 2017
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The ChArMEx SOP2 field campaign took place from 15 July to 5 August 2013 in the western Mediterranean Basin at Ersa, a remote site in Cape Corse. Exhaustive descriptions of the chemical composition of air masses in gas and aerosol phase were performed. An analysis of these measurements was performed using various source-receptor approaches. This led to the identification of several factors linked to primary sources but also to secondary processes of both biogenic and anthropogenic origin.
Thibaud Thonat, Marielle Saunois, Philippe Bousquet, Isabelle Pison, Zeli Tan, Qianlai Zhuang, Patrick M. Crill, Brett F. Thornton, David Bastviken, Ed J. Dlugokencky, Nikita Zimov, Tuomas Laurila, Juha Hatakka, Ove Hermansen, and Doug E. J. Worthy
Atmos. Chem. Phys., 17, 8371–8394, https://doi.org/10.5194/acp-17-8371-2017, https://doi.org/10.5194/acp-17-8371-2017, 2017
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Atmospheric methane simulations in the Arctic have been made for 2012 and compared to continuous observations at six measurement sites. All methane sources significantly affect the measurements at all stations, at least at the synoptic scale, except for biomass burning. An appropriate modelling framework combined with continuous observations of atmospheric methane enables us to gain knowledge on regional methane sources, including those which are usually poorly represented, such as freshwater.
Irène Ventrillard, Irène Xueref-Remy, Martina Schmidt, Camille Yver Kwok, Xavier Faïn, and Daniele Romanini
Atmos. Meas. Tech., 10, 1803–1812, https://doi.org/10.5194/amt-10-1803-2017, https://doi.org/10.5194/amt-10-1803-2017, 2017
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We present a comparison of CO measurements performed with a portable OF-CEAS laser spectrometer against a high-performance gas chromatograph. For both surface and airborne measurements, the instruments show an excellent agreement very close to the 2 ppb World Meteorological Organization recommendation for CO inter-laboratory comparison. This work establishes that this laser technique allows for the development of sensitive, compact, robust and reliable instruments for in situ trace-gas analysis.
Pierre Tulet, Andréa Di Muro, Aurélie Colomb, Cyrielle Denjean, Valentin Duflot, Santiago Arellano, Brice Foucart, Jérome Brioude, Karine Sellegri, Aline Peltier, Alessandro Aiuppa, Christelle Barthe, Chatrapatty Bhugwant, Soline Bielli, Patrice Boissier, Guillaume Boudoire, Thierry Bourrianne, Christophe Brunet, Fréderic Burnet, Jean-Pierre Cammas, Franck Gabarrot, Bo Galle, Gaetano Giudice, Christian Guadagno, Fréderic Jeamblu, Philippe Kowalski, Jimmy Leclair de Bellevue, Nicolas Marquestaut, Dominique Mékies, Jean-Marc Metzger, Joris Pianezze, Thierry Portafaix, Jean Sciare, Arnaud Tournigand, and Nicolas Villeneuve
Atmos. Chem. Phys., 17, 5355–5378, https://doi.org/10.5194/acp-17-5355-2017, https://doi.org/10.5194/acp-17-5355-2017, 2017
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The STRAP campaign was conducted in 2015 to investigate the volcanic plumes of Piton de La Fournaise (La Réunion, France). For the first time, measurements were conducted at the local (near the vent) and regional scales around the island. The STRAP 2015 campaign gave a unique set of multi-disciplinary data that can now be used by modellers to improve the numerical parameterisations of the physical and chemical evolution of the volcanic plumes.
Dominik Schmithüsen, Scott Chambers, Bernd Fischer, Stefan Gilge, Juha Hatakka, Victor Kazan, Rolf Neubert, Jussi Paatero, Michel Ramonet, Clemens Schlosser, Sabine Schmid, Alex Vermeulen, and Ingeborg Levin
Atmos. Meas. Tech., 10, 1299–1312, https://doi.org/10.5194/amt-10-1299-2017, https://doi.org/10.5194/amt-10-1299-2017, 2017
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A European-wide 222radon/222radon progeny comparison study has been conducted at nine measurement stations in order to determine differences between existing 222radon instrumentation and atmospheric data sets, respectively. Mean differences up to 45 % were found between monitors. These differences need to be taken into account if the data shall serve for quantitative regional atmospheric transport model validation.
Clémence Rose, Karine Sellegri, Isabel Moreno, Fernando Velarde, Michel Ramonet, Kay Weinhold, Radovan Krejci, Marcos Andrade, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 17, 1529–1541, https://doi.org/10.5194/acp-17-1529-2017, https://doi.org/10.5194/acp-17-1529-2017, 2017
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Using an indirect method based on particle size distribution measurements, we show that new particle formation (NPF) is responsible for a large contribution to the cloud condensation nuclei concentration at the highest observatory in the world (Bolivia, 5240 m a.s.l.) as expected from some global model predictions. We also provide unique results related to the influence of the boundary layer on the NPF process, showing direct evidence for the important NPF frequency in the free troposphere.
Lamia Ammoura, Irène Xueref-Remy, Felix Vogel, Valérie Gros, Alexia Baudic, Bernard Bonsang, Marc Delmotte, Yao Té, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 15653–15664, https://doi.org/10.5194/acp-16-15653-2016, https://doi.org/10.5194/acp-16-15653-2016, 2016
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We propose a new approach to estimate urban emission ratios that takes advantage of the enhanced local urban signal in the atmosphere at low wind speed. We apply it to estimate monthly ratios between CO2, CO and some VOCs from atmospheric measurement datasets acquired in the centre of Paris between 2010 and 2014. We find that this approach is little sensitive to the regional background level definition. With this new method, we may reveal spatial and seasonal variability in the ratios in Paris.
Marielle Saunois, Philippe Bousquet, Ben Poulter, Anna Peregon, Philippe Ciais, Josep G. Canadell, Edward J. Dlugokencky, Giuseppe Etiope, David Bastviken, Sander Houweling, Greet Janssens-Maenhout, Francesco N. Tubiello, Simona Castaldi, Robert B. Jackson, Mihai Alexe, Vivek K. Arora, David J. Beerling, Peter Bergamaschi, Donald R. Blake, Gordon Brailsford, Victor Brovkin, Lori Bruhwiler, Cyril Crevoisier, Patrick Crill, Kristofer Covey, Charles Curry, Christian Frankenberg, Nicola Gedney, Lena Höglund-Isaksson, Misa Ishizawa, Akihiko Ito, Fortunat Joos, Heon-Sook Kim, Thomas Kleinen, Paul Krummel, Jean-François Lamarque, Ray Langenfelds, Robin Locatelli, Toshinobu Machida, Shamil Maksyutov, Kyle C. McDonald, Julia Marshall, Joe R. Melton, Isamu Morino, Vaishali Naik, Simon O'Doherty, Frans-Jan W. Parmentier, Prabir K. Patra, Changhui Peng, Shushi Peng, Glen P. Peters, Isabelle Pison, Catherine Prigent, Ronald Prinn, Michel Ramonet, William J. Riley, Makoto Saito, Monia Santini, Ronny Schroeder, Isobel J. Simpson, Renato Spahni, Paul Steele, Atsushi Takizawa, Brett F. Thornton, Hanqin Tian, Yasunori Tohjima, Nicolas Viovy, Apostolos Voulgarakis, Michiel van Weele, Guido R. van der Werf, Ray Weiss, Christine Wiedinmyer, David J. Wilton, Andy Wiltshire, Doug Worthy, Debra Wunch, Xiyan Xu, Yukio Yoshida, Bowen Zhang, Zhen Zhang, and Qiuan Zhu
Earth Syst. Sci. Data, 8, 697–751, https://doi.org/10.5194/essd-8-697-2016, https://doi.org/10.5194/essd-8-697-2016, 2016
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An accurate assessment of the methane budget is important to understand the atmospheric methane concentrations and trends and to provide realistic pathways for climate change mitigation. The various and diffuse sources of methane as well and its oxidation by a very short lifetime radical challenge this assessment. We quantify the methane sources and sinks as well as their uncertainties based on both bottom-up and top-down approaches provided by a broad international scientific community.
Sauveur Belviso, Ilja Marco Reiter, Benjamin Loubet, Valérie Gros, Juliette Lathière, David Montagne, Marc Delmotte, Michel Ramonet, Cerise Kalogridis, Benjamin Lebegue, Nicolas Bonnaire, Victor Kazan, Thierry Gauquelin, Catherine Fernandez, and Bernard Genty
Atmos. Chem. Phys., 16, 14909–14923, https://doi.org/10.5194/acp-16-14909-2016, https://doi.org/10.5194/acp-16-14909-2016, 2016
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The role that soil, foliage, and atmospheric dynamics have on surface OCS exchange in a Mediterranean forest ecosystem in southern France (O3HP) was investigated in June of 2012 and 2013 with essentially a top-down approach. Atmospheric data suggest that the site is appropriate for estimating GPP directly from eddy covariance measurements of OCS fluxes, but it is less adequate for scaling NEE to GPP from observations of vertical gradients of OCS relative to CO2 during the daytime.
Johannes Staufer, Grégoire Broquet, François-Marie Bréon, Vincent Puygrenier, Frédéric Chevallier, Irène Xueref-Rémy, Elsa Dieudonné, Morgan Lopez, Martina Schmidt, Michel Ramonet, Olivier Perrussel, Christine Lac, Lin Wu, and Philippe Ciais
Atmos. Chem. Phys., 16, 14703–14726, https://doi.org/10.5194/acp-16-14703-2016, https://doi.org/10.5194/acp-16-14703-2016, 2016
Shushi Peng, Shilong Piao, Philippe Bousquet, Philippe Ciais, Bengang Li, Xin Lin, Shu Tao, Zhiping Wang, Yuan Zhang, and Feng Zhou
Atmos. Chem. Phys., 16, 14545–14562, https://doi.org/10.5194/acp-16-14545-2016, https://doi.org/10.5194/acp-16-14545-2016, 2016
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Methane is an important greenhouse gas, which accounts for about 20 % of the warming induced by long-lived greenhouse gases since 1750. Anthropogenic methane emissions from China may have been growing rapidly in the past decades because of increased coal mining and fast growing livestock. A good long-term methane emissions dataset is still lacking. Here, we produced a detailed bottom-up inventory of anthropogenic methane emissions from the eight major source sectors in China during 1980–2010.
Andreas Ostler, Ralf Sussmann, Prabir K. Patra, Sander Houweling, Marko De Bruine, Gabriele P. Stiller, Florian J. Haenel, Johannes Plieninger, Philippe Bousquet, Yi Yin, Marielle Saunois, Kaley A. Walker, Nicholas M. Deutscher, David W. T. Griffith, Thomas Blumenstock, Frank Hase, Thorsten Warneke, Zhiting Wang, Rigel Kivi, and John Robinson
Atmos. Meas. Tech., 9, 4843–4859, https://doi.org/10.5194/amt-9-4843-2016, https://doi.org/10.5194/amt-9-4843-2016, 2016
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Our evaluation of column-averaged methane (XCH4) in models and TCCON reveals latitudinal biases between 0.4 % and 2.1 % originating from an inter-model spread in stratospheric CH4. Substituting model stratospheric CH4 fields by satellite data significantly reduces the large XCH4 bias observed for one model. For other models, showing only minor biases, the impact is ambiguous; i.e., the satellite uncertainty range hinders a more accurate model evaluation needed to improve inverse modeling.
Lynn Hazan, Jérôme Tarniewicz, Michel Ramonet, Olivier Laurent, and Amara Abbaris
Atmos. Meas. Tech., 9, 4719–4736, https://doi.org/10.5194/amt-9-4719-2016, https://doi.org/10.5194/amt-9-4719-2016, 2016
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The ATC automatically processes atmospheric greenhouse gases mole fractions of data sent daily by the ICOS network, this includes calibration and water vapor corrections. Data are stored in a database which has been developed with an emphasis on traceability. Instrument calibration and manual quality control lead to automatic revaluation of the mole fractions calculated in near-real time. Calibration corrections avoid artificial gradients between sites that could lead to error in flux estimates.
E. N. Koffi, P. Bergamaschi, U. Karstens, M. Krol, A. Segers, M. Schmidt, I. Levin, A. T. Vermeulen, R. E. Fisher, V. Kazan, H. Klein Baltink, D. Lowry, G. Manca, H. A. J. Meijer, J. Moncrieff, S. Pal, M. Ramonet, H. A. Scheeren, and A. G. Williams
Geosci. Model Dev., 9, 3137–3160, https://doi.org/10.5194/gmd-9-3137-2016, https://doi.org/10.5194/gmd-9-3137-2016, 2016
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We evaluate the capability of the TM5 model to reproduce observations of the boundary layer dynamics and the associated variability of trace gases close to the surface, using 222Rn. Focusing on the European scale, we compare the TM5 boundary layer heights with observations from radiosondes, lidar, and ceilometer. Furthermore, we compare TM5 simulations of 222Rn activity concentrations, using a novel, process-based 222Rn flux map over Europe, with 222Rn harmonized measurements from 10 stations.
Cindy Cressot, Isabelle Pison, Peter J. Rayner, Philippe Bousquet, Audrey Fortems-Cheiney, and Frédéric Chevallier
Atmos. Chem. Phys., 16, 9089–9108, https://doi.org/10.5194/acp-16-9089-2016, https://doi.org/10.5194/acp-16-9089-2016, 2016
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Several hypothesis have been made to attribute current trends in atmospheric methane to particular regions. In this context, this work aims at evaluating how well anomalies in methane emissions can be detected at the regional scale with currently available observing systems: two space-borne instruments and a surface network. Our results show that inter-annual analyses of methane emissions inferred by atmospheric inversions should always include an uncertainty assessment.
Lin Wu, Grégoire Broquet, Philippe Ciais, Valentin Bellassen, Felix Vogel, Frédéric Chevallier, Irène Xueref-Remy, and Yilong Wang
Atmos. Chem. Phys., 16, 7743–7771, https://doi.org/10.5194/acp-16-7743-2016, https://doi.org/10.5194/acp-16-7743-2016, 2016
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This paper advances atmospheric inversion of city CO2 emissions as follows: (1) illustrate how inversion methodology can be tailored to deal with very large urban networks of sensors measuring CO2 concentrations; (2) demonstrate that atmospheric inversion could be a relevant tool of Monitoring, Reporting and Verification (MRV) of city CO2 emissions; (3) clarify the theoretical potential of inversion for reducing uncertainties in the estimates of citywide total and sectoral CO2 emissions.
Alex Boon, Grégoire Broquet, Deborah J. Clifford, Frédéric Chevallier, David M. Butterfield, Isabelle Pison, Michel Ramonet, Jean-Daniel Paris, and Philippe Ciais
Atmos. Chem. Phys., 16, 6735–6756, https://doi.org/10.5194/acp-16-6735-2016, https://doi.org/10.5194/acp-16-6735-2016, 2016
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We measured carbon dioxide and methane concentrations at four near-ground sites located in London, 2012. We investigated the potential for using these measurements, alongside numerical modelling, to help us to understand urban greenhouse gas emissions. Low-level sites were highly sensitive to local emissions, which questions our ability to use measurements from near-ground sites in cities in some modelling applications. A gradient approach was found to be beneficial to reduce model–data errors.
Sourish Basu, John Bharat Miller, and Scott Lehman
Atmos. Chem. Phys., 16, 5665–5683, https://doi.org/10.5194/acp-16-5665-2016, https://doi.org/10.5194/acp-16-5665-2016, 2016
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We present a dual tracer atmospheric inversion technique to separately estimate biospheric and fossil fuel CO2 fluxes from atmospheric measurements of CO2 and 14CO2. In addition to estimating monthly regional fossil fuel fluxes of CO2, this system can also reduce biases in biospheric fluxes that arise in a traditional CO2 inversion from prescribing a fixed but inaccurate fossil fuel flux.
Antoine Berchet, Philippe Bousquet, Isabelle Pison, Robin Locatelli, Frédéric Chevallier, Jean-Daniel Paris, Ed J. Dlugokencky, Tuomas Laurila, Juha Hatakka, Yrjo Viisanen, Doug E. J. Worthy, Euan Nisbet, Rebecca Fisher, James France, David Lowry, Viktor Ivakhov, and Ove Hermansen
Atmos. Chem. Phys., 16, 4147–4157, https://doi.org/10.5194/acp-16-4147-2016, https://doi.org/10.5194/acp-16-4147-2016, 2016
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We propose insights based on atmospheric observations around the Arctic circle to evaluate estimates of methane emissions to the atmosphere from the East Siberian Arctic Shelf. Based on a comprehensive statistical analysis of the observations and of high-resolution transport simulations, annual methane emissions from ESAS are estimated to range from 0.0 to 4.5 TgCH4 yr−1, with a maximum in summer and very low emissions in winter.
Benjamin Lebegue, Martina Schmidt, Michel Ramonet, Benoit Wastine, Camille Yver Kwok, Olivier Laurent, Sauveur Belviso, Ali Guemri, Carole Philippon, Jeremiah Smith, and Sebastien Conil
Atmos. Meas. Tech., 9, 1221–1238, https://doi.org/10.5194/amt-9-1221-2016, https://doi.org/10.5194/amt-9-1221-2016, 2016
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In this study, we tested seven N2O analyzers from five different companies and compared the results with established techniques. The test protocols included the characterization of the short-term and long-term repeatability, drift, temperature dependence, linearity and sensitivity to water vapor. All of the analyzers showed a standard deviation better than 0.1 ppb for the 10-min averages. Some analyzers would benefit from improvements in temperature stability and water vapour correction.
Q. J. Zhang, M. Beekmann, E. Freney, K. Sellegri, J. M. Pichon, A. Schwarzenboeck, A. Colomb, T. Bourrianne, V. Michoud, and A. Borbon
Atmos. Chem. Phys., 15, 13973–13992, https://doi.org/10.5194/acp-15-13973-2015, https://doi.org/10.5194/acp-15-13973-2015, 2015
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Secondary organic aerosol (SOA) is an important pollutant formed from megacity emissions at a regional scale. An original method based on ratios of different pollutants is used to specifically validate the aerosol scheme (the volatility basis set approach) within a CTM. The method is applied to airborne measurements performed within the Paris plume during the MEGAPOLI summer campaign. Simulations indicate that SOA of anthropogenic origin has a significant impact on regional air quality.
M. Lopez, M. Schmidt, M. Ramonet, J.-L. Bonne, A. Colomb, V. Kazan, P. Laj, and J.-M. Pichon
Atmos. Meas. Tech., 8, 3941–3958, https://doi.org/10.5194/amt-8-3941-2015, https://doi.org/10.5194/amt-8-3941-2015, 2015
C. Yver Kwok, O. Laurent, A. Guemri, C. Philippon, B. Wastine, C. W. Rella, C. Vuillemin, F. Truong, M. Delmotte, V. Kazan, M. Darding, B. Lebègue, C. Kaiser, I. Xueref-Rémy, and M. Ramonet
Atmos. Meas. Tech., 8, 3867–3892, https://doi.org/10.5194/amt-8-3867-2015, https://doi.org/10.5194/amt-8-3867-2015, 2015
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We present the results of tests of CRDS instruments in the laboratory (47 instruments) and in the field (15 instruments). We demonstrate that, thanks to rigorous testing, newer models generally perform better than older models, especially in terms of reproducibility between instruments. In the field, we see the importance of individual diagnostics during the installation phase, and we show the value of calibration and target gases that assess the quality of the data.
A. Berchet, I. Pison, F. Chevallier, J.-D. Paris, P. Bousquet, J.-L. Bonne, M. Y. Arshinov, B. D. Belan, C. Cressot, D. K. Davydov, E. J. Dlugokencky, A. V. Fofonov, A. Galanin, J. Lavrič, T. Machida, R. Parker, M. Sasakawa, R. Spahni, B. D. Stocker, and J. Winderlich
Biogeosciences, 12, 5393–5414, https://doi.org/10.5194/bg-12-5393-2015, https://doi.org/10.5194/bg-12-5393-2015, 2015
C. Rose, K. Sellegri, E. Freney, R. Dupuy, A. Colomb, J.-M. Pichon, M. Ribeiro, T. Bourianne, F. Burnet, and A. Schwarzenboeck
Atmos. Chem. Phys., 15, 10203–10218, https://doi.org/10.5194/acp-15-10203-2015, https://doi.org/10.5194/acp-15-10203-2015, 2015
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In the present paper we report airborne measurements of new particle formation (NPF) above the Mediterranean Sea (HYMEX campaign). We show that NPF occurs over large areas above the sea, but the process is clearly promoted at high altitude, above 1000m, i.e. frequently in the free troposphere. NPF also seems to be mainly influenced by local processes occurring above the sea. After their formation, particles slowly grow at high altitude while not being greatly depleted or affected by coagulation.
R. Locatelli, P. Bousquet, M. Saunois, F. Chevallier, and C. Cressot
Atmos. Chem. Phys., 15, 9765–9780, https://doi.org/10.5194/acp-15-9765-2015, https://doi.org/10.5194/acp-15-9765-2015, 2015
H. Petetin, M. Beekmann, A. Colomb, H. A. C. Denier van der Gon, J.-C. Dupont, C. Honoré, V. Michoud, Y. Morille, O. Perrussel, A. Schwarzenboeck, J. Sciare, A. Wiedensohler, and Q. J. Zhang
Atmos. Chem. Phys., 15, 9799–9818, https://doi.org/10.5194/acp-15-9799-2015, https://doi.org/10.5194/acp-15-9799-2015, 2015
X. Lin, N. K. Indira, M. Ramonet, M. Delmotte, P. Ciais, B. C. Bhatt, M. V. Reddy, D. Angchuk, S. Balakrishnan, S. Jorphail, T. Dorjai, T. T. Mahey, S. Patnaik, M. Begum, C. Brenninkmeijer, S. Durairaj, R. Kirubagaran, M. Schmidt, P. S. Swathi, N. V. Vinithkumar, C. Yver Kwok, and V. K. Gaur
Atmos. Chem. Phys., 15, 9819–9849, https://doi.org/10.5194/acp-15-9819-2015, https://doi.org/10.5194/acp-15-9819-2015, 2015
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We present 5-year flask measurements (2007–2011) of greenhouse gases (GHGs) at three atmospheric stations in India. The results suggest significant sources of CO2, CH4, N2O, CO, and H2 over S and NE India, while SF6 sources are weak. The seasonal cycles for each species reflect the seasonality of sources/sinks and influences of the Indian monsoon circulations. The data show potential to infer regional patterns of GHG fluxes and atmospheric transport over this under-documented region.
L. Molina, G. Broquet, P. Imbach, F. Chevallier, B. Poulter, D. Bonal, B. Burban, M. Ramonet, L. V. Gatti, S. C. Wofsy, J. W. Munger, E. Dlugokencky, and P. Ciais
Atmos. Chem. Phys., 15, 8423–8438, https://doi.org/10.5194/acp-15-8423-2015, https://doi.org/10.5194/acp-15-8423-2015, 2015
C. E. Yver Kwok, D. Müller, C. Caldow, B. Lebègue, J. G. Mønster, C. W. Rella, C. Scheutz, M. Schmidt, M. Ramonet, T. Warneke, G. Broquet, and P. Ciais
Atmos. Meas. Tech., 8, 2853–2867, https://doi.org/10.5194/amt-8-2853-2015, https://doi.org/10.5194/amt-8-2853-2015, 2015
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This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. We show that the tracer release method is suitable to quantify facility emissions, while the chamber measurements, provide insights into individual processes. We confirm that the open basins are not a major source of CH4 on the WWTP but that the pretreatment and sludge treatment are the main emitters.
K. Markakis, M. Valari, O. Perrussel, O. Sanchez, and C. Honore
Atmos. Chem. Phys., 15, 7703–7723, https://doi.org/10.5194/acp-15-7703-2015, https://doi.org/10.5194/acp-15-7703-2015, 2015
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The efficacy of emission policies is explored by coarse resolution modeling applications. These were shown to be biased, overestimating that efficacy indicated in simulations with refined resolution. In order to improve our assessments, we need to quantify those biases. In this study we show that the ozone bias of the coarse run is reduced by 40% by adopting higher resolution emissions. For PM2.5, the coarse run cannot selectively incorporate local scale features in order to reduce model error.
C. C. Hoerger, A. Claude, C. Plass-Duelmer, S. Reimann, E. Eckart, R. Steinbrecher, J. Aalto, J. Arduini, N. Bonnaire, J. N. Cape, A. Colomb, R. Connolly, J. Diskova, P. Dumitrean, C. Ehlers, V. Gros, H. Hakola, M. Hill, J. R. Hopkins, J. Jäger, R. Junek, M. K. Kajos, D. Klemp, M. Leuchner, A. C. Lewis, N. Locoge, M. Maione, D. Martin, K. Michl, E. Nemitz, S. O'Doherty, P. Pérez Ballesta, T. M. Ruuskanen, S. Sauvage, N. Schmidbauer, T. G. Spain, E. Straube, M. Vana, M. K. Vollmer, R. Wegener, and A. Wenger
Atmos. Meas. Tech., 8, 2715–2736, https://doi.org/10.5194/amt-8-2715-2015, https://doi.org/10.5194/amt-8-2715-2015, 2015
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The performance of 20 European laboratories involved in long-term non-methane hydrocarbon (NMHC) measurements was assessed with respect to ACTRIS and GAW data quality objectives. The participants were asked to measure both a 30-component NMHC mixture in nitrogen and whole air. The NMHCs were analysed either by GC-FID or GC-MS. Most systems performed well for the NMHC in nitrogen, whereas in air more scatter was observed. Reasons for this are explained in the paper.
C. Barbet, L. Deguillaume, N. Chaumerliac, M. Leriche, A. Berger, E. Freney, A. Colomb, K. Sellegri, L. Patryl, and P. Armand
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-13395-2015, https://doi.org/10.5194/acpd-15-13395-2015, 2015
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C. Rose, K. Sellegri, E. Asmi, M. Hervo, E. Freney, A. Colomb, H. Junninen, J. Duplissy, M. Sipilä, J. Kontkanen, K. Lehtipalo, and M. Kulmala
Atmos. Chem. Phys., 15, 3413–3428, https://doi.org/10.5194/acp-15-3413-2015, https://doi.org/10.5194/acp-15-3413-2015, 2015
F. M. Bréon, G. Broquet, V. Puygrenier, F. Chevallier, I. Xueref-Remy, M. Ramonet, E. Dieudonné, M. Lopez, M. Schmidt, O. Perrussel, and P. Ciais
Atmos. Chem. Phys., 15, 1707–1724, https://doi.org/10.5194/acp-15-1707-2015, https://doi.org/10.5194/acp-15-1707-2015, 2015
R. Locatelli, P. Bousquet, F. Hourdin, M. Saunois, A. Cozic, F. Couvreux, J.-Y. Grandpeix, M.-P. Lefebvre, C. Rio, P. Bergamaschi, S. D. Chambers, U. Karstens, V. Kazan, S. van der Laan, H. A. J. Meijer, J. Moncrieff, M. Ramonet, H. A. Scheeren, C. Schlosser, M. Schmidt, A. Vermeulen, and A. G. Williams
Geosci. Model Dev., 8, 129–150, https://doi.org/10.5194/gmd-8-129-2015, https://doi.org/10.5194/gmd-8-129-2015, 2015
P. Bergamaschi, M. Corazza, U. Karstens, M. Athanassiadou, R. L. Thompson, I. Pison, A. J. Manning, P. Bousquet, A. Segers, A. T. Vermeulen, G. Janssens-Maenhout, M. Schmidt, M. Ramonet, F. Meinhardt, T. Aalto, L. Haszpra, J. Moncrieff, M. E. Popa, D. Lowry, M. Steinbacher, A. Jordan, S. O'Doherty, S. Piacentino, and E. Dlugokencky
Atmos. Chem. Phys., 15, 715–736, https://doi.org/10.5194/acp-15-715-2015, https://doi.org/10.5194/acp-15-715-2015, 2015
L. Ammoura, I. Xueref-Remy, V. Gros, A. Baudic, B. Bonsang, J.-E. Petit, O. Perrussel, N. Bonnaire, J. Sciare, and F. Chevallier
Atmos. Chem. Phys., 14, 12871–12882, https://doi.org/10.5194/acp-14-12871-2014, https://doi.org/10.5194/acp-14-12871-2014, 2014
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We present the first study of CO2, VOCs and NOx measured all together in a road tunnel around the Paris megacity with the aim to quantify the ratios of these species co-emitted within traffic emissions. It allows us to independently assess some of the ratios provided in the latest Paris emission inventory. It also reveals a large variability of the ratios to CO2, implying that traffic does not have a unique imprint in the urban plume, but rather leaves various signatures.
H. Angot, M. Barret, O. Magand, M. Ramonet, and A. Dommergue
Atmos. Chem. Phys., 14, 11461–11473, https://doi.org/10.5194/acp-14-11461-2014, https://doi.org/10.5194/acp-14-11461-2014, 2014
Z. Wang, N. M. Deutscher, T. Warneke, J. Notholt, B. Dils, D. W. T. Griffith, M. Schmidt, M. Ramonet, and C. Gerbig
Atmos. Meas. Tech., 7, 3295–3305, https://doi.org/10.5194/amt-7-3295-2014, https://doi.org/10.5194/amt-7-3295-2014, 2014
W. Ait-Helal, A. Borbon, S. Sauvage, J. A. de Gouw, A. Colomb, V. Gros, F. Freutel, M. Crippa, C. Afif, U. Baltensperger, M. Beekmann, J.-F. Doussin, R. Durand-Jolibois, I. Fronval, N. Grand, T. Leonardis, M. Lopez, V. Michoud, K. Miet, S. Perrier, A. S. H. Prévôt, J. Schneider, G. Siour, P. Zapf, and N. Locoge
Atmos. Chem. Phys., 14, 10439–10464, https://doi.org/10.5194/acp-14-10439-2014, https://doi.org/10.5194/acp-14-10439-2014, 2014
M. Schmidt, M. Lopez, C. Yver Kwok, C. Messager, M. Ramonet, B. Wastine, C. Vuillemin, F. Truong, B. Gal, E. Parmentier, O. Cloué, and P. Ciais
Atmos. Meas. Tech., 7, 2283–2296, https://doi.org/10.5194/amt-7-2283-2014, https://doi.org/10.5194/amt-7-2283-2014, 2014
K. Markakis, M. Valari, A. Colette, O. Sanchez, O. Perrussel, C. Honore, R. Vautard, Z. Klimont, and S. Rao
Atmos. Chem. Phys., 14, 7323–7340, https://doi.org/10.5194/acp-14-7323-2014, https://doi.org/10.5194/acp-14-7323-2014, 2014
R. L. Thompson, K. Ishijima, E. Saikawa, M. Corazza, U. Karstens, P. K. Patra, P. Bergamaschi, F. Chevallier, E. Dlugokencky, R. G. Prinn, R. F. Weiss, S. O'Doherty, P. J. Fraser, L. P. Steele, P. B. Krummel, A. Vermeulen, Y. Tohjima, A. Jordan, L. Haszpra, M. Steinbacher, S. Van der Laan, T. Aalto, F. Meinhardt, M. E. Popa, J. Moncrieff, and P. Bousquet
Atmos. Chem. Phys., 14, 6177–6194, https://doi.org/10.5194/acp-14-6177-2014, https://doi.org/10.5194/acp-14-6177-2014, 2014
J.-L. Bonne, V. Masson-Delmotte, O. Cattani, M. Delmotte, C. Risi, H. Sodemann, and H. C. Steen-Larsen
Atmos. Chem. Phys., 14, 4419–4439, https://doi.org/10.5194/acp-14-4419-2014, https://doi.org/10.5194/acp-14-4419-2014, 2014
R. L. Thompson, P. K. Patra, K. Ishijima, E. Saikawa, M. Corazza, U. Karstens, C. Wilson, P. Bergamaschi, E. Dlugokencky, C. Sweeney, R. G. Prinn, R. F. Weiss, S. O'Doherty, P. J. Fraser, L. P. Steele, P. B. Krummel, M. Saunois, M. Chipperfield, and P. Bousquet
Atmos. Chem. Phys., 14, 4349–4368, https://doi.org/10.5194/acp-14-4349-2014, https://doi.org/10.5194/acp-14-4349-2014, 2014
V. Michoud, A. Colomb, A. Borbon, K. Miet, M. Beekmann, M. Camredon, B. Aumont, S. Perrier, P. Zapf, G. Siour, W. Ait-Helal, C. Afif, A. Kukui, M. Furger, J. C. Dupont, M. Haeffelin, and J. F. Doussin
Atmos. Chem. Phys., 14, 2805–2822, https://doi.org/10.5194/acp-14-2805-2014, https://doi.org/10.5194/acp-14-2805-2014, 2014
L. Deguillaume, T. Charbouillot, M. Joly, M. Vaïtilingom, M. Parazols, A. Marinoni, P. Amato, A.-M. Delort, V. Vinatier, A. Flossmann, N. Chaumerliac, J. M. Pichon, S. Houdier, P. Laj, K. Sellegri, A. Colomb, M. Brigante, and G. Mailhot
Atmos. Chem. Phys., 14, 1485–1506, https://doi.org/10.5194/acp-14-1485-2014, https://doi.org/10.5194/acp-14-1485-2014, 2014
E. J. Freney, K. Sellegri, F. Canonaco, A. Colomb, A. Borbon, V. Michoud, J.-F. Doussin, S. Crumeyrolle, N. Amarouche, J.-M. Pichon, T. Bourianne, L. Gomes, A. S. H. Prevot, M. Beekmann, and A. Schwarzenböeck
Atmos. Chem. Phys., 14, 1397–1412, https://doi.org/10.5194/acp-14-1397-2014, https://doi.org/10.5194/acp-14-1397-2014, 2014
C. Cressot, F. Chevallier, P. Bousquet, C. Crevoisier, E. J. Dlugokencky, A. Fortems-Cheiney, C. Frankenberg, R. Parker, I. Pison, R. A. Scheepmaker, S. A. Montzka, P. B. Krummel, L. P. Steele, and R. L. Langenfelds
Atmos. Chem. Phys., 14, 577–592, https://doi.org/10.5194/acp-14-577-2014, https://doi.org/10.5194/acp-14-577-2014, 2014
I. Pison, B. Ringeval, P. Bousquet, C. Prigent, and F. Papa
Atmos. Chem. Phys., 13, 11609–11623, https://doi.org/10.5194/acp-13-11609-2013, https://doi.org/10.5194/acp-13-11609-2013, 2013
C. Rose, J. Boulon, M. Hervo, H. Holmgren, E. Asmi, M. Ramonet, P. Laj, and K. Sellegri
Atmos. Chem. Phys., 13, 11573–11594, https://doi.org/10.5194/acp-13-11573-2013, https://doi.org/10.5194/acp-13-11573-2013, 2013
B. W. LaFranchi, G. Pétron, J. B. Miller, S. J. Lehman, A. E. Andrews, E. J. Dlugokencky, B. Hall, B. R. Miller, S. A. Montzka, W. Neff, P. C. Novelli, C. Sweeney, J. C. Turnbull, D. E. Wolfe, P. P. Tans, K. R. Gurney, and T. P. Guilderson
Atmos. Chem. Phys., 13, 11101–11120, https://doi.org/10.5194/acp-13-11101-2013, https://doi.org/10.5194/acp-13-11101-2013, 2013
V. V. S. S. Sarma, A. Lenton, R. M. Law, N. Metzl, P. K. Patra, S. Doney, I. D. Lima, E. Dlugokencky, M. Ramonet, and V. Valsala
Biogeosciences, 10, 7035–7052, https://doi.org/10.5194/bg-10-7035-2013, https://doi.org/10.5194/bg-10-7035-2013, 2013
J.-L. Baray, Y. Courcoux, P. Keckhut, T. Portafaix, P. Tulet, J.-P. Cammas, A. Hauchecorne, S. Godin Beekmann, M. De Mazière, C. Hermans, F. Desmet, K. Sellegri, A. Colomb, M. Ramonet, J. Sciare, C. Vuillemin, C. Hoareau, D. Dionisi, V. Duflot, H. Vérèmes, J. Porteneuve, F. Gabarrot, T. Gaudo, J.-M. Metzger, G. Payen, J. Leclair de Bellevue, C. Barthe, F. Posny, P. Ricaud, A. Abchiche, and R. Delmas
Atmos. Meas. Tech., 6, 2865–2877, https://doi.org/10.5194/amt-6-2865-2013, https://doi.org/10.5194/amt-6-2865-2013, 2013
C. E. Yver-Kwok, D. Müller, C. Caldow, B. Lebegue, J. G. Mønster, C. W. Rella, C. Scheutz, M. Schmidt, M. Ramonet, T. Warneke, G. Broquet, and P. Ciais
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amtd-6-9181-2013, https://doi.org/10.5194/amtd-6-9181-2013, 2013
Revised manuscript not accepted
R. Locatelli, P. Bousquet, F. Chevallier, A. Fortems-Cheney, S. Szopa, M. Saunois, A. Agusti-Panareda, D. Bergmann, H. Bian, P. Cameron-Smith, M. P. Chipperfield, E. Gloor, S. Houweling, S. R. Kawa, M. Krol, P. K. Patra, R. G. Prinn, M. Rigby, R. Saito, and C. Wilson
Atmos. Chem. Phys., 13, 9917–9937, https://doi.org/10.5194/acp-13-9917-2013, https://doi.org/10.5194/acp-13-9917-2013, 2013
G. Broquet, F. Chevallier, F.-M. Bréon, N. Kadygrov, M. Alemanno, F. Apadula, S. Hammer, L. Haszpra, F. Meinhardt, J. A. Morguí, J. Necki, S. Piacentino, M. Ramonet, M. Schmidt, R. L. Thompson, A. T. Vermeulen, C. Yver, and P. Ciais
Atmos. Chem. Phys., 13, 9039–9056, https://doi.org/10.5194/acp-13-9039-2013, https://doi.org/10.5194/acp-13-9039-2013, 2013
A. Berchet, I. Pison, F. Chevallier, P. Bousquet, S. Conil, M. Geever, T. Laurila, J. Lavrič, M. Lopez, J. Moncrieff, J. Necki, M. Ramonet, M. Schmidt, M. Steinbacher, and J. Tarniewicz
Atmos. Chem. Phys., 13, 7115–7132, https://doi.org/10.5194/acp-13-7115-2013, https://doi.org/10.5194/acp-13-7115-2013, 2013
Q. J. Zhang, M. Beekmann, F. Drewnick, F. Freutel, J. Schneider, M. Crippa, A. S. H. Prevot, U. Baltensperger, L. Poulain, A. Wiedensohler, J. Sciare, V. Gros, A. Borbon, A. Colomb, V. Michoud, J.-F. Doussin, H. A. C. Denier van der Gon, M. Haeffelin, J.-C. Dupont, G. Siour, H. Petetin, B. Bessagnet, S. N. Pandis, A. Hodzic, O. Sanchez, C. Honoré, and O. Perrussel
Atmos. Chem. Phys., 13, 5767–5790, https://doi.org/10.5194/acp-13-5767-2013, https://doi.org/10.5194/acp-13-5767-2013, 2013
C. Lac, R. P. Donnelly, V. Masson, S. Pal, S. Riette, S. Donier, S. Queguiner, G. Tanguy, L. Ammoura, and I. Xueref-Remy
Atmos. Chem. Phys., 13, 4941–4961, https://doi.org/10.5194/acp-13-4941-2013, https://doi.org/10.5194/acp-13-4941-2013, 2013
S. Hammer, G. Konrad, A. T. Vermeulen, O. Laurent, M. Delmotte, A. Jordan, L. Hazan, S. Conil, and I. Levin
Atmos. Meas. Tech., 6, 1201–1216, https://doi.org/10.5194/amt-6-1201-2013, https://doi.org/10.5194/amt-6-1201-2013, 2013
F. Freutel, J. Schneider, F. Drewnick, S.-L. von der Weiden-Reinmüller, M. Crippa, A. S. H. Prévôt, U. Baltensperger, L. Poulain, A. Wiedensohler, J. Sciare, R. Sarda-Estève, J. F. Burkhart, S. Eckhardt, A. Stohl, V. Gros, A. Colomb, V. Michoud, J. F. Doussin, A. Borbon, M. Haeffelin, Y. Morille, M. Beekmann, and S. Borrmann
Atmos. Chem. Phys., 13, 933–959, https://doi.org/10.5194/acp-13-933-2013, https://doi.org/10.5194/acp-13-933-2013, 2013
V. Michoud, A. Kukui, M. Camredon, A. Colomb, A. Borbon, K. Miet, B. Aumont, M. Beekmann, R. Durand-Jolibois, S. Perrier, P. Zapf, G. Siour, W. Ait-Helal, N. Locoge, S. Sauvage, C. Afif, V. Gros, M. Furger, G. Ancellet, and J. F. Doussin
Atmos. Chem. Phys., 12, 11951–11974, https://doi.org/10.5194/acp-12-11951-2012, https://doi.org/10.5194/acp-12-11951-2012, 2012
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
A mass-weighted isentropic coordinate for mapping chemical tracers and computing atmospheric inventories
Methane mapping, emission quantification, and attribution in two European cities: Utrecht (NL) and Hamburg (DE)
Ozone affected by a succession of four landfall typhoons in the Yangtze River Delta, China: major processes and health impacts
4D dispersion of total gaseous mercury derived from a mining source: identification of criteria to assess risks related to high concentrations of atmospheric mercury
Estimating CH4, CO2 and CO emissions from coal mining and industrial activities in the Upper Silesian Coal Basin using an aircraft-based mass balance approach
Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes
Measurement report: Leaf-scale gas exchange of atmospheric reactive trace species (NO2, NO, O3) at a northern hardwood forest in Michigan
A dedicated flask sampling strategy developed for Integrated Carbon Observation System (ICOS) stations based on CO2 and CO measurements and Stochastic Time-Inverted Lagrangian Transport (STILT) footprint modelling
The increasing atmospheric burden of the greenhouse gas sulfur hexafluoride (SF6)
Understanding nighttime methane signals at the Amazon Tall Tower Observatory (ATTO)
Background heterogeneity and other uncertainties in estimating urban methane flux: results from the Indianapolis Flux Experiment (INFLUX)
Methane emissions from the Munich Oktoberfest
A study of the influence of tropospheric subsidence on spring and summer surface ozone concentrations at the JRC Ispra station in northern Italy
Local and synoptic meteorological influences on daily variability in summertime surface ozone in eastern China
Variability in a four-network composite of atmospheric CO2 differences between three primary baseline sites
Quantifying the impact of synoptic circulation patterns on ozone variability in northern China from April to October 2013–2017
Multivariate statistical air mass classification for the high-alpine observatory at the Zugspitze Mountain, Germany
Evolution of anthropogenic air pollutant emissions in Guangdong Province, China, from 2006 to 2015
Speciated atmospheric mercury and sea–air exchange of gaseous mercury in the South China Sea
Methane emissions from oil and gas platforms in the North Sea
Assessing London CO2, CH4 and CO emissions using aircraft measurements and dispersion modelling
2005–2017 ozone trends and potential benefits of local measures as deduced from air quality measurements in the north of the Barcelona metropolitan area
Country-scale greenhouse gas budgets using shipborne measurements: a case study for the UK and Ireland
Intercomparison of midlatitude tropospheric and lower-stratospheric water vapor measurements and comparison to ECMWF humidity data
Eddy flux measurements of sulfur dioxide deposition to the sea surface
Quantifying uncertainties from mobile-laboratory-derived emissions of well pads using inverse Gaussian methods
Observing local CO2 sources using low-cost, near-surface urban monitors
Spatiotemporal variability of NO2 and PM2.5 over Eastern China: observational and model analyses with a novel statistical method
Spatial–temporal patterns of inorganic nitrogen air concentrations and deposition in eastern China
Phenomenology of summer ozone episodes over the Madrid Metropolitan Area, central Spain
Ship-based MAX-DOAS measurements of tropospheric NO2, SO2, and HCHO distribution along the Yangtze River
Gradient flux measurements of sea–air DMS transfer during the Surface Ocean Aerosol Production (SOAP) experiment
Measurements of atmospheric ethene by solar absorption FTIR spectrometry
Ozone pollution around a coastal region of South China Sea: interaction between marine and continental air
Abundance and sources of atmospheric halocarbons in the Eastern Mediterranean
Diurnal, synoptic and seasonal variability of atmospheric CO2 in the Paris megacity area
Atmospheric carbonyl sulfide (OCS) measured remotely by FTIR solar absorption spectrometry
Temporal variation of VOC fluxes measured with PTR-TOF above a boreal forest
Long-term trends of surface ozone and its influencing factors at the Mt Waliguan GAW station, China – Part 2: The roles of anthropogenic emissions and climate variability
Gaseous elemental mercury (GEM) fluxes over canopy of two typical subtropical forests in south China
Observations of ozone depletion events in a Finnish boreal forest
Mobile measurement of methane emissions from natural gas developments in northeastern British Columbia, Canada
Impacts of large-scale circulation on urban ambient concentrations of gaseous elemental mercury in New York, USA
Surface ozone at Nam Co in the inland Tibetan Plateau: variation, synthesis comparison and regional representativeness
Trends and annual cycles in soundings of Arctic tropospheric ozone
Estimation of bubble-mediated air–sea gas exchange from concurrent DMS and CO2 transfer velocities at intermediate–high wind speeds
Estimating the size of a methane emission point source at different scales: from local to landscape
Genesis of diamond dust, ice fog and thick cloud episodes observed and modelled above Dome C, Antarctica
Impact of typhoons on the composition of the upper troposphere within the Asian summer monsoon anticyclone: the SWOP campaign in Lhasa 2013
An investigation on the origin of regional springtime ozone episodes in the western Mediterranean
Yuming Jin, Ralph F. Keeling, Eric J. Morgan, Eric Ray, Nicholas C. Parazoo, and Britton B. Stephens
Atmos. Chem. Phys., 21, 217–238, https://doi.org/10.5194/acp-21-217-2021, https://doi.org/10.5194/acp-21-217-2021, 2021
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We propose a new atmospheric coordinate (Mθe) based on equivalent potential temperature (θe) but with mass as the unit. This coordinate is useful in studying the spatial and temporal distribution of long-lived chemical tracers (CO2, CH4, O2 / N2, etc.) from sparse data, like airborne observation. Using this coordinate and sparse airborne observation (HIPPO and ATom), we resolve the Northern Hemisphere mass-weighted average CO2 seasonal cycle with high accuracy.
Hossein Maazallahi, Julianne M. Fernandez, Malika Menoud, Daniel Zavala-Araiza, Zachary D. Weller, Stefan Schwietzke, Joseph C. von Fischer, Hugo Denier van der Gon, and Thomas Röckmann
Atmos. Chem. Phys., 20, 14717–14740, https://doi.org/10.5194/acp-20-14717-2020, https://doi.org/10.5194/acp-20-14717-2020, 2020
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Methane accounts for ∼ 25 % of current climate warming. The current lack of methane measurements is a barrier for tracking major sources, which are key for near-term climate mitigation. We use mobile measurements to identify and quantify methane emission sources in Utrecht (NL) and Hamburg (DE) with a focus on natural gas pipeline leaks. The measurements resulted in fixing the major leaks by the local utility, but coordinated efforts are needed at national levels for further emission reductions.
Chenchao Zhan, Min Xie, Chongwu Huang, Jane Liu, Tijian Wang, Meng Xu, Chaoqun Ma, Jianwei Yu, Yumeng Jiao, Mengmeng Li, Shu Li, Bingliang Zhuang, Ming Zhao, and Dongyang Nie
Atmos. Chem. Phys., 20, 13781–13799, https://doi.org/10.5194/acp-20-13781-2020, https://doi.org/10.5194/acp-20-13781-2020, 2020
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The Yangtze River Delta (YRD) region has been suffering from severe ozone (O3) pollution in recent years. Synoptic systems, like typhoons, can have a significant effect on O3 episodes. However, research on landfall typhoons affecting O3 in the YRD is limited. This work aims to reveal the main processes of landfall typhoons affecting surface O3 and estimate health impacts of O3 during the study period in the YRD, which can be useful for taking reasonable pollution control measures in this area.
José M. Esbrí, Pablo L. Higueras, Alba Martínez-Coronado, and Rocío Naharro
Atmos. Chem. Phys., 20, 12995–13010, https://doi.org/10.5194/acp-20-12995-2020, https://doi.org/10.5194/acp-20-12995-2020, 2020
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The aim of this work was to identify criteria to obtain the minimum amount of data with the maximum meaning and representativeness in order to delimit risk areas, both in a spatial and temporal respect. We have constructed a model of vertical mercury movements which could be used to predict the location and timing of mercury inhalation risk. Also, we have designed a monitoring strategy to identify the relevant criteria, which involved the measurement of gaseous mercury in a vertical section.
Alina Fiehn, Julian Kostinek, Maximilian Eckl, Theresa Klausner, Michał Gałkowski, Jinxuan Chen, Christoph Gerbig, Thomas Röckmann, Hossein Maazallahi, Martina Schmidt, Piotr Korbeń, Jarosław Neçki, Pawel Jagoda, Norman Wildmann, Christian Mallaun, Rostyslav Bun, Anna-Leah Nickl, Patrick Jöckel, Andreas Fix, and Anke Roiger
Atmos. Chem. Phys., 20, 12675–12695, https://doi.org/10.5194/acp-20-12675-2020, https://doi.org/10.5194/acp-20-12675-2020, 2020
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A severe reduction of greenhouse gas emissions is necessary to fulfill the Paris Agreement. We use aircraft- and ground-based in situ observations of trace gases and wind speed from two flights over the Upper Silesian Coal Basin, Poland, for independent emission estimation. The derived methane emission estimates are within the range of emission inventories, carbon dioxide estimates are in the lower range and carbon monoxide emission estimates are slightly higher than emission inventory values.
Flora Kluge, Tilman Hüneke, Matthias Knecht, Michael Lichtenstern, Meike Rotermund, Hans Schlager, Benjamin Schreiner, and Klaus Pfeilsticker
Atmos. Chem. Phys., 20, 12363–12389, https://doi.org/10.5194/acp-20-12363-2020, https://doi.org/10.5194/acp-20-12363-2020, 2020
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The presented study reports on airborne measurements of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon basin and lays a special focus on the influence of biomass burning emissions on the atmospheric profiles of these carbonyl compounds within the planetary boundary layer as well as in the free and upper troposphere.
Wei Wang, Laurens Ganzeveld, Samuel Rossabi, Jacques Hueber, and Detlev Helmig
Atmos. Chem. Phys., 20, 11287–11304, https://doi.org/10.5194/acp-20-11287-2020, https://doi.org/10.5194/acp-20-11287-2020, 2020
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Trees exchange with the atmosphere nitrogen oxides and ozone, affecting the tropospheric composition and consequently air quality and ecosystem health. We examined the leaf-level gas exchanges for four typical tree species (pine, maple, oak, aspen) found in northern Michigan, US. The leaves largely absorb the gases, showing little evidence of emission. We measured the uptake rates that can be used to improve model studies of the source and sink processes controlling these gases in forests.
Ingeborg Levin, Ute Karstens, Markus Eritt, Fabian Maier, Sabrina Arnold, Daniel Rzesanke, Samuel Hammer, Michel Ramonet, Gabriela Vítková, Sebastien Conil, Michal Heliasz, Dagmar Kubistin, and Matthias Lindauer
Atmos. Chem. Phys., 20, 11161–11180, https://doi.org/10.5194/acp-20-11161-2020, https://doi.org/10.5194/acp-20-11161-2020, 2020
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Based on observations and Stochastic Time-Inverted Lagrangian Transport (STILT) footprint modelling, a sampling strategy has been developed for tall tower stations of the Integrated Carbon Observation System (ICOS) research infrastructure atmospheric station network. This strategy allows independent quality control of in situ measurements, provides representative coverage of the influence area of the sites, and is capable of automated targeted sampling of fossil fuel CO2 emission hotspots.
Peter G. Simmonds, Matthew Rigby, Alistair J. Manning, Sunyoung Park, Kieran M. Stanley, Archie McCulloch, Stephan Henne, Francesco Graziosi, Michela Maione, Jgor Arduini, Stefan Reimann, Martin K. Vollmer, Jens Mühle, Simon O'Doherty, Dickon Young, Paul B. Krummel, Paul J. Fraser, Ray F. Weiss, Peter K. Salameh, Christina M. Harth, Mi-Kyung Park, Hyeri Park, Tim Arnold, Chris Rennick, L. Paul Steele, Blagoj Mitrevski, Ray H. J. Wang, and Ronald G. Prinn
Atmos. Chem. Phys., 20, 7271–7290, https://doi.org/10.5194/acp-20-7271-2020, https://doi.org/10.5194/acp-20-7271-2020, 2020
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Sulfur hexafluoride (SF6) is a potent greenhouse gas which is regulated under the Kyoto Protocol. From a 40-year record of measurements, collected at five global monitoring sites and archived air samples, we show that its concentration in the atmosphere has steadily increased. Using modelling techniques, we estimate that global emissions have increased by about 24 % over the past decade. We find that this increase is driven by the demand for SF6-insulated switchgear in developing countries.
Santiago Botía, Christoph Gerbig, Julia Marshall, Jost V. Lavric, David Walter, Christopher Pöhlker, Bruna Holanda, Gilberto Fisch, Alessandro Carioca de Araújo, Marta O. Sá, Paulo R. Teixeira, Angélica F. Resende, Cleo Q. Dias-Junior, Hella van Asperen, Pablo S. Oliveira, Michel Stefanello, and Otávio C. Acevedo
Atmos. Chem. Phys., 20, 6583–6606, https://doi.org/10.5194/acp-20-6583-2020, https://doi.org/10.5194/acp-20-6583-2020, 2020
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A long record of atmospheric methane concentrations in central Amazonia was analyzed. We describe events in which concentrations at 79 m are higher than at 4 m. These events are more frequent during the nighttime of dry season, but we found no association with fire signals. Instead, we suggest that a combination of nighttime transport and a nearby source could explain such events. Our research gives insights into how methane is transported in the complex nocturnal atmosphere in Amazonia.
Nikolay V. Balashov, Kenneth J. Davis, Natasha L. Miles, Thomas Lauvaux, Scott J. Richardson, Zachary R. Barkley, and Timothy A. Bonin
Atmos. Chem. Phys., 20, 4545–4559, https://doi.org/10.5194/acp-20-4545-2020, https://doi.org/10.5194/acp-20-4545-2020, 2020
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An accurate independent verification methodology to estimate methane (a powerful greenhouse gas) emissions is essential for the effective implementation of policies that aim to reduce the impacts of climate change. In this paper, four uncertainties that complicate the independent estimation of urban methane emissions are identified: the definition of urban domain, background heterogeneity, emissions temporal variability, and missing sources. Ways to improve emission estimates are suggested.
Jia Chen, Florian Dietrich, Hossein Maazallahi, Andreas Forstmaier, Dominik Winkler, Magdalena E. G. Hofmann, Hugo Denier van der Gon, and Thomas Röckmann
Atmos. Chem. Phys., 20, 3683–3696, https://doi.org/10.5194/acp-20-3683-2020, https://doi.org/10.5194/acp-20-3683-2020, 2020
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We demonstrate for the first time that large festivals can be significant methane sources, though they are not included in emission inventories. We combined in situ measurements with a Gaussian plume model to determine the Oktoberfest emissions and show that they are not due solely to human biogenic emissions, but are instead primarily fossil fuel related. Our study provides the foundation to develop reduction policies for such events and new pathways to mitigate fossil fuel methane emissions.
Pavlos Kalabokas, Niels Roland Jensen, Mauro Roveri, Jens Hjorth, Maxim Eremenko, Juan Cuesta, Gaëlle Dufour, Gilles Foret, and Matthias Beekmann
Atmos. Chem. Phys., 20, 1861–1885, https://doi.org/10.5194/acp-20-1861-2020, https://doi.org/10.5194/acp-20-1861-2020, 2020
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The influence of tropospheric ozone on the surface measurements at a regional air pollution station in the pre-Alpine area of northern Italy is investigated. During such episodes the local air pollution parameters show generally very low values, while the ozone levels reach high values, occasionally exceeding the ozone air quality standards. Better understanding of ozone variability over the examined region will help in the formulation of more effective policies for the environment and climate.
Han Han, Jane Liu, Lei Shu, Tijian Wang, and Huiling Yuan
Atmos. Chem. Phys., 20, 203–222, https://doi.org/10.5194/acp-20-203-2020, https://doi.org/10.5194/acp-20-203-2020, 2020
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We statistically assessed the impacts of local and synoptic meteorology on daily surface ozone in eastern China in summer during 2013–2018. The results show that the meteorology described by a multiple linear regression model explains 43 % of variations in surface ozone. The most important local meteorological factors vary with location in eastern China. The maximum impact of the predominant synoptic pattern on surface ozone can reach ± 8 µg m-3 or ± 16 % of the daily mean over some regions.
Roger J. Francey, Jorgen S. Frederiksen, L. Paul Steele, and Ray L. Langenfelds
Atmos. Chem. Phys., 19, 14741–14754, https://doi.org/10.5194/acp-19-14741-2019, https://doi.org/10.5194/acp-19-14741-2019, 2019
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25-year composites of interhemispheric baseline CO2 differences demonstrate close agreement between 4 monitoring networks. Variability from monthly to multiyear time frames mostly reflects variability in upper troposphere dynamical indices chosen to represent eddy and mean transport interhemispheric exchange. Monthly interhemispheric atmospheric fluxes are much larger than air–surface terrestrial exchanges. The composite differences offer unusual constraints on transport in global carbon models.
Jingda Liu, Lili Wang, Mingge Li, Zhiheng Liao, Yang Sun, Tao Song, Wenkang Gao, Yonghong Wang, Yan Li, Dongsheng Ji, Bo Hu, Veli-Matti Kerminen, Yuesi Wang, and Markku Kulmala
Atmos. Chem. Phys., 19, 14477–14492, https://doi.org/10.5194/acp-19-14477-2019, https://doi.org/10.5194/acp-19-14477-2019, 2019
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We analyzed the surface ozone variation characteristics and quantified the impact of synoptic and local meteorological factors on northern China during the warm season based on multi-city, in situ ozone and meteorological data, as well as meteorological reanalysis. The results of quantitative exploration on synoptic and local meteorological factors influencing both interannual and day-to-day ozone variations will provide the scientific basis for evaluating emission reduction measures.
Armin Sigmund, Korbinian Freier, Till Rehm, Ludwig Ries, Christian Schunk, Anette Menzel, and Christoph K. Thomas
Atmos. Chem. Phys., 19, 12477–12494, https://doi.org/10.5194/acp-19-12477-2019, https://doi.org/10.5194/acp-19-12477-2019, 2019
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Air masses at the Schneefernerhaus mountain site at Zugspitze Mountain, Germany, were classified with respect to the atmospheric layer from which they originated and their degree of pollution. Measurements of several gases, particulate matter, and standard meteorological quantities indicated that polluted air was lifted to the site in 31 % of cases and clean air descended to the site in approximately 14 % cases while most of the remaining cases were ambiguous.
Yahui Bian, Zhijiong Huang, Jiamin Ou, Zhuangmin Zhong, Yuanqian Xu, Zhiwei Zhang, Xiao Xiao, Xiao Ye, Yuqi Wu, Xiaohong Yin, Cheng Li, Liangfu Chen, Min Shao, and Junyu Zheng
Atmos. Chem. Phys., 19, 11701–11719, https://doi.org/10.5194/acp-19-11701-2019, https://doi.org/10.5194/acp-19-11701-2019, 2019
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During 2006–2015, emissions of SO2, NOx, PM2.5 and PM10 saw an obvious downtrend. However, most emissions still have large reduction potential. On-road mobile sources and solvent use are the two key sources that should receive more effective control measures in GD. Also, controls measures on VOC and NH3 should be weighted since they still increased in 2006–2015. Since most control measures focused on PRD rather than non-PRD in GD, emissions in non-PRD were increasingly important.
Chunjie Wang, Zhangwei Wang, Fan Hui, and Xiaoshan Zhang
Atmos. Chem. Phys., 19, 10111–10127, https://doi.org/10.5194/acp-19-10111-2019, https://doi.org/10.5194/acp-19-10111-2019, 2019
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A low GEM level indicated that the SCS suffered less anthropogenic influence. There was no significant difference in GEM and HgP2.5 values between day and night, but the RGM level was higher in daytime than in nighttime. The size distribution of HgP in PM10 was observed to be bi-modal, but the coarse modal was the dominant size. The annual emission flux of Hg0 from the SCS was estimated to be 159 ton yr-1. The dry deposition was an important pathway for the input of atmospheric Hg to the SCS.
Stuart N. Riddick, Denise L. Mauzerall, Michael Celia, Neil R. P. Harris, Grant Allen, Joseph Pitt, John Staunton-Sykes, Grant L. Forster, Mary Kang, David Lowry, Euan G. Nisbet, and Alistair J. Manning
Atmos. Chem. Phys., 19, 9787–9796, https://doi.org/10.5194/acp-19-9787-2019, https://doi.org/10.5194/acp-19-9787-2019, 2019
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Currently, bottom-up methods estimate that 0.13 % of methane produced by UK North Sea oil and gas installations is lost. Here we measure emissions from eight platforms in the North Sea and, when considered collectively, the methane loss is estimated at 0.19 % of gas production. As this ambient loss is not explicitly accounted for in the bottom-up approach, these measured emissions represent significant additional emissions above previous estimates.
Joseph R. Pitt, Grant Allen, Stéphane J.-B. Bauguitte, Martin W. Gallagher, James D. Lee, Will Drysdale, Beth Nelson, Alistair J. Manning, and Paul I. Palmer
Atmos. Chem. Phys., 19, 8931–8945, https://doi.org/10.5194/acp-19-8931-2019, https://doi.org/10.5194/acp-19-8931-2019, 2019
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This paper presents a new method to assess inventory estimates of greenhouse gas and air pollutant emissions for large cities and their surrounding regions. A case study using data sampled by a research aircraft around London was used to test the method. We found that the UK national inventory agrees with our observations for CO but needed lower emissions for CH4 to agree with the measured data. Repeated studies could help determine how these emissions vary on different timescales.
Jordi Massagué, Cristina Carnerero, Miguel Escudero, José María Baldasano, Andrés Alastuey, and Xavier Querol
Atmos. Chem. Phys., 19, 7445–7465, https://doi.org/10.5194/acp-19-7445-2019, https://doi.org/10.5194/acp-19-7445-2019, 2019
Carole Helfter, Neil Mullinger, Massimo Vieno, Simon O'Doherty, Michel Ramonet, Paul I. Palmer, and Eiko Nemitz
Atmos. Chem. Phys., 19, 3043–3063, https://doi.org/10.5194/acp-19-3043-2019, https://doi.org/10.5194/acp-19-3043-2019, 2019
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We present a novel approach to estimate the annual budgets of carbon dioxide (881.0 ± 128.5 Tg) and methane (2.55 ± 0.48 Tg) of the British Isles from shipborne measurements taken over a 3-year period (2015–2017). This study brings independent verification of the emission budgets estimated using alternative products and investigates the seasonality of these emissions, which is usually not possible.
Stefan Kaufmann, Christiane Voigt, Romy Heller, Tina Jurkat-Witschas, Martina Krämer, Christian Rolf, Martin Zöger, Andreas Giez, Bernhard Buchholz, Volker Ebert, Troy Thornberry, and Ulrich Schumann
Atmos. Chem. Phys., 18, 16729–16745, https://doi.org/10.5194/acp-18-16729-2018, https://doi.org/10.5194/acp-18-16729-2018, 2018
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We present an intercomparison of the airborne water vapor measurements during the ML-CIRRUS mission. Although the agreement of the hygrometers significantly improved compared to studies from recent decades, systematic differences remain under specific meteorological conditions. We compare the measurements to model data, where we observe a model wet bias in the lower stratosphere close to the tropopause, likely caused by a blurred humidity gradient in the model tropopause.
Jack G. Porter, Warren De Bruyn, and Eric S. Saltzman
Atmos. Chem. Phys., 18, 15291–15305, https://doi.org/10.5194/acp-18-15291-2018, https://doi.org/10.5194/acp-18-15291-2018, 2018
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Deposition to the sea surface is a major loss pathway for highly soluble atmospheric trace gases. These fluxes are important to biogeochemical cycles, climate, and air quality. Here we report measurements of air–sea fluxes of sulfur dioxide, sensible heat, and momentum to coastal waters. Transfer velocities derived from the data show a dependence on molecular diffusivity, demonstrating the importance of diffusion in the interfacial layer on the atmospheric side of the air–sea interface.
Dana R. Caulton, Qi Li, Elie Bou-Zeid, Jeffrey P. Fitts, Levi M. Golston, Da Pan, Jessica Lu, Haley M. Lane, Bernhard Buchholz, Xuehui Guo, James McSpiritt, Lars Wendt, and Mark A. Zondlo
Atmos. Chem. Phys., 18, 15145–15168, https://doi.org/10.5194/acp-18-15145-2018, https://doi.org/10.5194/acp-18-15145-2018, 2018
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Mobile laboratory measurements have been widely used to quantify methane emissions from point sources such as oil and gas wells, but the emission uncertainties are poorly constrained. We designed a hierarchical measurement strategy to sample natural gas emissions in the Marcellus Shale play based upon high-resolution modeling of select sites. Our study quantifies the largest sources of error with this approach and provides guidance on how to best implement mobile laboratory sampling protocols.
Alexis A. Shusterman, Jinsol Kim, Kaitlyn J. Lieschke, Catherine Newman, Paul J. Wooldridge, and Ronald C. Cohen
Atmos. Chem. Phys., 18, 13773–13785, https://doi.org/10.5194/acp-18-13773-2018, https://doi.org/10.5194/acp-18-13773-2018, 2018
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We describe the diversity and heterogeneity of urban CO2 levels observed using the BErkeley Atmospheric CO2 Observation Network, a distributed instrument of > 50 CO2 sensors stationed every ~ 2 km across the San Francisco Bay Area. We demonstrate that relatively simple mathematical techniques, applied to these observations, can be used to detect the small changes in highway CO2 emissions expected to result from upcoming fuel economy regulations, affirming the policy relevance of low-cost sensors.
Mengyao Liu, Jintai Lin, Yuchen Wang, Yang Sun, Bo Zheng, Jingyuan Shao, Lulu Chen, Yixuan Zheng, Jinxuan Chen, Tzung-May Fu, Yingying Yan, Qiang Zhang, and Zhaohua Wu
Atmos. Chem. Phys., 18, 12933–12952, https://doi.org/10.5194/acp-18-12933-2018, https://doi.org/10.5194/acp-18-12933-2018, 2018
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Eastern China is heavily polluted by NO2, PM2.5, and other air pollutants. Our study uses EOF–EEMD to analyze the spatiotemporal variability of ground-level NO2, PM2.5, and their associations with meteorological processes. Their regular diurnal cycles are mainly affected by human activities, while irregular day-to-day variations are dominated by weather processes representing synchronous variation or north–south opposing changes over Eastern China.
Wen Xu, Lei Liu, Miaomiao Cheng, Yuanhong Zhao, Lin Zhang, Yuepeng Pan, Xiuming Zhang, Baojing Gu, Yi Li, Xiuying Zhang, Jianlin Shen, Li Lu, Xiaosheng Luo, Yu Zhao, Zhaozhong Feng, Jeffrey L. Collett Jr., Fusuo Zhang, and Xuejun Liu
Atmos. Chem. Phys., 18, 10931–10954, https://doi.org/10.5194/acp-18-10931-2018, https://doi.org/10.5194/acp-18-10931-2018, 2018
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Our main results demonstrate that atmospheric Nr pollution in eastern China is more serious in the northern region than in the southern region. Any effects of current emission controls are not yet apparent in Nr pollution. NH3 emissions from fertilizer use were the largest contributor (36 %) to total inorganic Nr deposition. Our results provide useful information for policy-makers that mitigation of NH3 emissions should be a priority to tackle serious N deposition.
Xavier Querol, Andrés Alastuey, Gotzon Gangoiti, Noemí Perez, Hong K. Lee, Heeram R. Eun, Yonghee Park, Enrique Mantilla, Miguel Escudero, Gloria Titos, Lucio Alonso, Brice Temime-Roussel, Nicolas Marchand, Juan R. Moreta, M. Arantxa Revuelta, Pedro Salvador, Begoña Artíñano, Saúl García dos Santos, Mónica Anguas, Alberto Notario, Alfonso Saiz-Lopez, Roy M. Harrison, Millán Millán, and Kang-Ho Ahn
Atmos. Chem. Phys., 18, 6511–6533, https://doi.org/10.5194/acp-18-6511-2018, https://doi.org/10.5194/acp-18-6511-2018, 2018
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We show the main drivers of high O3 episodes in and around Madrid. High levels of ultrafine particles (UFPs) are evidenced, but we demonstrate that most O3 arises from the fumigation of high atmospheric layers, whereas UFPs are generated inside the PBL. O3 contributions from the fumigation of the vertical recirculation of regional air masses, hemispheric transport, and horizontally from direct urban plume transport are shown. Complexity arises from the need to quantify them to abate surface O3.
Qianqian Hong, Cheng Liu, Ka Lok Chan, Qihou Hu, Zhouqing Xie, Haoran Liu, Fuqi Si, and Jianguo Liu
Atmos. Chem. Phys., 18, 5931–5951, https://doi.org/10.5194/acp-18-5931-2018, https://doi.org/10.5194/acp-18-5931-2018, 2018
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We presented ship-based MAX-DOAS measurements of tropospheric trace gases' distribution along the eastern part of the Yangtze River during winter 2015. Tropospheric VCDs of NO2, SO2, and HCHO were retrieved from MAX-DOAS measurement spectra. Enhanced tropospheric NO2 and SO2 VCDs were detected over downwind areas of industrial zones over the Yangtze River. Our results indicate that different pollution control strategies should be applied in different provinces.
Murray J. Smith, Carolyn F. Walker, Thomas G. Bell, Mike J. Harvey, Eric S. Saltzman, and Cliff S. Law
Atmos. Chem. Phys., 18, 5861–5877, https://doi.org/10.5194/acp-18-5861-2018, https://doi.org/10.5194/acp-18-5861-2018, 2018
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The transfer of gases across the air–sea interface has a significant influence on climate. During a research voyage in the South Pacific we measured the transfer rate of the biogenic gas dimethyl sulfide (DMS) from the ocean using two independent methods. The agreement between the techniques provides confidence in their use in compilations of global gas transfer. We also identified physical conditions under which the observations are not well predicted by a standard gas transfer model.
Geoffrey C. Toon, Jean-Francois L. Blavier, and Keeyoon Sung
Atmos. Chem. Phys., 18, 5075–5088, https://doi.org/10.5194/acp-18-5075-2018, https://doi.org/10.5194/acp-18-5075-2018, 2018
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Remote sensing measurements of ethene have been made from the ground and from balloons. Ethene can be measured at low altitudes in polluted regions, such as the Los Angeles basin. Here ethene amounts have decreased by a factor of 3 over the past 25 years due to increasingly strict emission control regulations (e.g., on vehicle exhaust).
Hao Wang, Xiaopu Lyu, Hai Guo, Yu Wang, Shichun Zou, Zhenhao Ling, Xinming Wang, Fei Jiang, Yangzong Zeren, Wenzhuo Pan, Xiaobo Huang, and Jin Shen
Atmos. Chem. Phys., 18, 4277–4295, https://doi.org/10.5194/acp-18-4277-2018, https://doi.org/10.5194/acp-18-4277-2018, 2018
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While oceanic air is generally thought to be clean, the air pollution over waters in proximity to the coasts is not well recognized. This research indicated that ozone was higher over South China Sea (SCS) than that in the adjacent continental area, while continental anticyclone, tropical cyclone and land breeze favored O3 formation over SCS. In addition, weaker NO titration and stronger atmospheric oxidative capacity led to higher O3 production efficiency over SCS.
Fabian Schoenenberger, Stephan Henne, Matthias Hill, Martin K. Vollmer, Giorgos Kouvarakis, Nikolaos Mihalopoulos, Simon O'Doherty, Michela Maione, Lukas Emmenegger, Thomas Peter, and Stefan Reimann
Atmos. Chem. Phys., 18, 4069–4092, https://doi.org/10.5194/acp-18-4069-2018, https://doi.org/10.5194/acp-18-4069-2018, 2018
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Anthropogenic halocarbon emissions contribute to stratospheric ozone depletion and global warming. We measured atmospheric halocarbons for 6 months on Crete to extend the coverage of the existing observation network to the Eastern Mediterranean. The derived emission estimates showed a contribution of 16.8 % (13.6–23.3 %) and 53.2 % (38.1–84.2 %) of this region to the total HFC and HCFC emissions of the analyzed European domain and a reduction of the underlying uncertainties by 40–80 %.
Irène Xueref-Remy, Elsa Dieudonné, Cyrille Vuillemin, Morgan Lopez, Christine Lac, Martina Schmidt, Marc Delmotte, Frédéric Chevallier, François Ravetta, Olivier Perrussel, Philippe Ciais, François-Marie Bréon, Grégoire Broquet, Michel Ramonet, T. Gerard Spain, and Christophe Ampe
Atmos. Chem. Phys., 18, 3335–3362, https://doi.org/10.5194/acp-18-3335-2018, https://doi.org/10.5194/acp-18-3335-2018, 2018
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Urbanized and industrialized areas are the largest source of fossil CO2. This work analyses the atmospheric CO2 variability observed from the first in situ network deployed in the Paris megacity area. Gradients of several ppm are found between the rural, peri-urban and urban sites at the diurnal to the seasonal scales. Wind direction and speed as well as boundary layer dynamics, correlated to highly variable urban emissions, are shown to be key regulator factors of the observed CO2 records.
Geoffrey C. Toon, Jean-Francois L. Blavier, and Keeyoon Sung
Atmos. Chem. Phys., 18, 1923–1944, https://doi.org/10.5194/acp-18-1923-2018, https://doi.org/10.5194/acp-18-1923-2018, 2018
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OCS is the main form of atmospheric sulfur. It is produced near the earth's surface and destroyed primarily in the stratosphere, where it is converted to stratospheric sulfate aerosol (SSA). SSA plays an important role in atmospheric chemistry and transport and so it is important to better understand the factors that regulate OCS and hence SSA. Ground-based and balloon-borne infrared spectra observed over the past 30 years are analyzed to provide an improved OCS dataset.
Simon Schallhart, Pekka Rantala, Maija K. Kajos, Juho Aalto, Ivan Mammarella, Taina M. Ruuskanen, and Markku Kulmala
Atmos. Chem. Phys., 18, 815–832, https://doi.org/10.5194/acp-18-815-2018, https://doi.org/10.5194/acp-18-815-2018, 2018
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Emissions of volatile organic compounds (VOCs) have impact to air quality, human health and climate. We investigated the development of VOC exchange in a boreal forest between April and June 2013. VOC exchange and diversity increased towards summer, but over 75 % of the biogenic net exchange was driven by methanol, monoterpenes and acetone only. The boreal forest emitted less than 0.2 % carbon in form of VOCs in relation to the carbon uptake.
Wanyun Xu, Xiaobin Xu, Meiyun Lin, Weili Lin, David Tarasick, Jie Tang, Jianzhong Ma, and Xiangdong Zheng
Atmos. Chem. Phys., 18, 773–798, https://doi.org/10.5194/acp-18-773-2018, https://doi.org/10.5194/acp-18-773-2018, 2018
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The impact of anthropogenic emissions and climate variability on the long-term trends and periodicity of surface ozone measured at Mt Waliguan (WLG) for the period of 1994–2013 is studied. STT ozone and rising emissions in eastern China contribute to spring and autumnal increasing trends, respectively. The 2–3-, 3–7-, and 11-year periodicities in the ozone data are linked to the QBO, EASMI, and sunspot cycle, respectively. An empirical model is obtained for normalised monthly ozone at WLG.
Qian Yu, Yao Luo, Shuxiao Wang, Zhiqi Wang, Jiming Hao, and Lei Duan
Atmos. Chem. Phys., 18, 495–509, https://doi.org/10.5194/acp-18-495-2018, https://doi.org/10.5194/acp-18-495-2018, 2018
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This study provides high-quality direct observation data of a clean and a contaminated site in subtropical south China and quantifies the natural forest Hg emission. We find that clean and contaminated forests present a net GEM source with annual average values of 6.67 and 0.30 ng m-2 h-1, respectively; daily variations of GEM fluxes showed a source in the daytime with a peak at 13:00, and as a sink or balance at night; and higher atmospheric GEM concentration restricted the forest GEM emission.
Xuemeng Chen, Lauriane L. J. Quéléver, Pak L. Fung, Jutta Kesti, Matti P. Rissanen, Jaana Bäck, Petri Keronen, Heikki Junninen, Tuukka Petäjä, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 18, 49–63, https://doi.org/10.5194/acp-18-49-2018, https://doi.org/10.5194/acp-18-49-2018, 2018
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We analysed a 20-year-long dataset collected in a Finnish boreal forest at SMEAR II station to investigate the frequency and strength of ozone depletion events. We could identify a number of ozone depletion events that lasted for more than 3 h, mainly in the autumn and winter months. Their occurrence was likely related to the formation of a low mixing layer under the conditions of low temperatures, low wind speeds, high relative humidities and limited intensity of solar radiation.
Emmaline Atherton, David Risk, Chelsea Fougère, Martin Lavoie, Alex Marshall, John Werring, James P. Williams, and Christina Minions
Atmos. Chem. Phys., 17, 12405–12420, https://doi.org/10.5194/acp-17-12405-2017, https://doi.org/10.5194/acp-17-12405-2017, 2017
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Methane is a potent greenhouse gas, and leaks from natural gas infrastructure are thought to be a significant emission source. We used a mobile survey method to measure GHGs near Canadian infrastructure. Our results show that ~ 47 % of active wells were emitting. Abandoned and aging wells were also associated with emissions. We estimate methane emissions from this development are just over 111 Mt year−1, which is more than previous government estimates, but less than similar studies in the US.
Huiting Mao, Dolly Hall, Zhuyun Ye, Ying Zhou, Dirk Felton, and Leiming Zhang
Atmos. Chem. Phys., 17, 11655–11671, https://doi.org/10.5194/acp-17-11655-2017, https://doi.org/10.5194/acp-17-11655-2017, 2017
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Mercury (Hg) is a global pollutant hazardous to human and ecosystem health, and its emission control is imperative. Anthropogenic mercury emissions have been reduced by 78 % in the United States from 1990 to 2014. However, no clearly defined trend was observed in Hg concentrations at urban locations such as the one in this study. This indicates that other factors may have dominated over anthropogenic emission control. The implications of this study could hence be highly policy relevant.
Xiufeng Yin, Shichang Kang, Benjamin de Foy, Zhiyuan Cong, Jiali Luo, Lang Zhang, Yaoming Ma, Guoshuai Zhang, Dipesh Rupakheti, and Qianggong Zhang
Atmos. Chem. Phys., 17, 11293–11311, https://doi.org/10.5194/acp-17-11293-2017, https://doi.org/10.5194/acp-17-11293-2017, 2017
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We presented 5-year surface ozone measurements at Nam Co in the inland Tibetan Plateau and made a synthesis comparison of diurnal and seasonal patterns on regional and hemispheric scales. Surface ozone at Nam Co is mainly dominated by natural processes and is less influenced by stratospheric intrusions and human activities than on the rim of the Tibetan Plateau. Ozone at Nam Co is representative of background that is valuable for studying ozone-related effects on large scales.
Bo Christiansen, Nis Jepsen, Rigel Kivi, Georg Hansen, Niels Larsen, and Ulrik Smith Korsholm
Atmos. Chem. Phys., 17, 9347–9364, https://doi.org/10.5194/acp-17-9347-2017, https://doi.org/10.5194/acp-17-9347-2017, 2017
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Ozone soundings in the troposphere from nine Arctic stations covering the period 1984–2014 have been analyzed. Stations with the best data coverage show a consistent and significant temporal variation with a maximum near 2005 followed by a decrease. Some significant changes are found in the annual cycle in agreement with the notion that the ozone summer maximum is appearing earlier in the year. Such changes in Arctic ozone in the free troposphere have not been reported before.
Thomas G. Bell, Sebastian Landwehr, Scott D. Miller, Warren J. de Bruyn, Adrian H. Callaghan, Brian Scanlon, Brian Ward, Mingxi Yang, and Eric S. Saltzman
Atmos. Chem. Phys., 17, 9019–9033, https://doi.org/10.5194/acp-17-9019-2017, https://doi.org/10.5194/acp-17-9019-2017, 2017
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The mechanisms that determine the air–sea exchange of gases such as carbon dioxide are not well understood. During a research cruise in the North Atlantic, we simultaneously measured the air–sea transfer of two gases with contrasting solubility over a range in wind and wave conditions. We compare the transfer of these gases to improve understanding of how bubbles from breaking waves may mediate air–sea gas fluxes.
Stuart N. Riddick, Sarah Connors, Andrew D. Robinson, Alistair J. Manning, Pippa S. D. Jones, David Lowry, Euan Nisbet, Robert L. Skelton, Grant Allen, Joseph Pitt, and Neil R. P. Harris
Atmos. Chem. Phys., 17, 7839–7851, https://doi.org/10.5194/acp-17-7839-2017, https://doi.org/10.5194/acp-17-7839-2017, 2017
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High methane mixing ratios occurred at our long-term measurement site. Isotopic measurements show the source is a landfill 7 km away; the emissions were estimated using three different approaches. The emission estimates made by near-source and middle-distance methods agree well for a period of intense observation. The estimate of the inverse modelling is similar to the labour-intensive middle-distance approach, which shows it can be used to identify point sources within an emission landscape.
Philippe Ricaud, Eric Bazile, Massimo del Guasta, Christian Lanconelli, Paolo Grigioni, and Achraf Mahjoub
Atmos. Chem. Phys., 17, 5221–5237, https://doi.org/10.5194/acp-17-5221-2017, https://doi.org/10.5194/acp-17-5221-2017, 2017
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The novelty of the paper is to combine a large set of measurements and meteorological models to study the genesis of thick cloud and diamond dust/ice fog (ice crystals) episodes above Dome C, Antarctica. The originality of the work is to attribute the presence of thick cloud and diamond dust/ice fog to advection and microphysical processes with oceanic and continental origin of air masses, respectively. Thick cloud episodes are reproduced by the models but not diamond dust/ice fog episode.
Dan Li, Bärbel Vogel, Jianchun Bian, Rolf Müller, Laura L. Pan, Gebhard Günther, Zhixuan Bai, Qian Li, Jinqiang Zhang, Qiujun Fan, and Holger Vömel
Atmos. Chem. Phys., 17, 4657–4672, https://doi.org/10.5194/acp-17-4657-2017, https://doi.org/10.5194/acp-17-4657-2017, 2017
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High-resolution ozone and water vapour profiles over Lhasa, China, were measured in August 2013. The correlations between ozone and water vapour profiles show a strong variability in the upper troposphere. These relationships were investigated using CLaMS trajectory calculations. The model results demonstrate that three tropical cyclones (Jebi, Utor, and Trami), occurring over the western Pacific, had a strong impact on the vertical structure of ozone and water vapour profiles.
Pavlos Kalabokas, Jens Hjorth, Gilles Foret, Gaëlle Dufour, Maxim Eremenko, Guillaume Siour, Juan Cuesta, and Matthias Beekmann
Atmos. Chem. Phys., 17, 3905–3928, https://doi.org/10.5194/acp-17-3905-2017, https://doi.org/10.5194/acp-17-3905-2017, 2017
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The main atmospheric mechanisms linked with spring surface ozone episodes over the western Mediterranean are examined. It comes out that high surface midday ozone values are usually linked with regional ozone episodes, which are strongly influenced by some specific meteorological conditions. The better understanding of the ozone variability in the lower troposphere and the boundary layer over the examined regions will help in the formulation of more effective policies in environment and climate.
Cited articles
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