Articles | Volume 17, issue 17
https://doi.org/10.5194/acp-17-10565-2017
https://doi.org/10.5194/acp-17-10565-2017
Research article
 | 
08 Sep 2017
Research article |  | 08 Sep 2017

Chemical processes related to net ozone tendencies in the free troposphere

Heiko Bozem, Tim M. Butler, Mark G. Lawrence, Hartwig Harder, Monica Martinez, Dagmar Kubistin, Jos Lelieveld, and Horst Fischer

Related authors

Overview: quasi-Lagrangian observations of Arctic air mass transformations – introduction and initial results of the HALO–(𝒜 𝒞)3 aircraft campaign
Manfred Wendisch, Susanne Crewell, André Ehrlich, Andreas Herber, Benjamin Kirbus, Christof Lüpkes, Mario Mech, Steven J. Abel, Elisa F. Akansu, Felix Ament, Clémantyne Aubry, Sebastian Becker, Stephan Borrmann, Heiko Bozem, Marlen Brückner, Hans-Christian Clemen, Sandro Dahlke, Georgios Dekoutsidis, Julien Delanoë, Elena De La Torre Castro, Henning Dorff, Regis Dupuy, Oliver Eppers, Florian Ewald, Geet George, Irina V. Gorodetskaya, Sarah Grawe, Silke Groß, Jörg Hartmann, Silvia Henning, Lutz Hirsch, Evelyn Jäkel, Philipp Joppe, Olivier Jourdan, Zsofia Jurányi, Michail Karalis, Mona Kellermann, Marcus Klingebiel, Michael Lonardi, Johannes Lucke, Anna E. Luebke, Maximilian Maahn, Nina Maherndl, Marion Maturilli, Bernhard Mayer, Johanna Mayer, Stephan Mertes, Janosch Michaelis, Michel Michalkov, Guillaume Mioche, Manuel Moser, Hanno Müller, Roel Neggers, Davide Ori, Daria Paul, Fiona M. Paulus, Christian Pilz, Felix Pithan, Mira Pöhlker, Veronika Pörtge, Maximilian Ringel, Nils Risse, Gregory C. Roberts, Sophie Rosenburg, Johannes Röttenbacher, Janna Rückert, Michael Schäfer, Jonas Schaefer, Vera Schemann, Imke Schirmacher, Jörg Schmidt, Sebastian Schmidt, Johannes Schneider, Sabrina Schnitt, Anja Schwarz, Holger Siebert, Harald Sodemann, Tim Sperzel, Gunnar Spreen, Bjorn Stevens, Frank Stratmann, Gunilla Svensson, Christian Tatzelt, Thomas Tuch, Timo Vihma, Christiane Voigt, Lea Volkmer, Andreas Walbröl, Anna Weber, Birgit Wehner, Bruno Wetzel, Martin Wirth, and Tobias Zinner
Atmos. Chem. Phys., 24, 8865–8892, https://doi.org/10.5194/acp-24-8865-2024,https://doi.org/10.5194/acp-24-8865-2024, 2024
Short summary
A comprehensive in-situ and remote sensing data set collected during the HALO–(AC)3 aircraft campaign
André Ehrlich, Susanne Crewell, Andreas Herber, Marcus Klingebiel, Christof Lüpkes, Mario Mech, Sebastian Becker, Stephan Borrmann, Heiko Bozem, Matthias Buschmann, Hans-Christian Clemen, Elena De La Torre Castro, Henning Dorff, Regis Dupuy, Oliver Eppers, Florian Ewald, Geet George, Andreas Giez, Sarah Grawe, Christophe Gourbeyre, Jörg Hartmann, Evelyn Jäkel, Philipp Joppe, Olivier Jourdan, Zsófia Jurányi, Benjamin Kirbus, Johannes Lucke, Anna E. Luebke, Maximilian Maahn, Nina Maherndl, Christian Mallaun, Johanna Mayer, Stephan Mertes, Guillaume Mioche, Manuel Moser, Hanno Müller, Veronika Pörtge, Nils Risse, Greg Roberts, Sophie Rosenburg, Johannes Röttenbacher, Michael Schäfer, Jonas Schaefer, Andreas Schäfler, Imke Schirmacher, Johannes Schneider, Sabrina Schnitt, Frank Stratmann, Christian Tatzelt, Christiane Voigt, Andreas Walbröl, Anna Weber, Bruno Wetzel, Martin Wirth, and Manfred Wendisch
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-281,https://doi.org/10.5194/essd-2024-281, 2024
Preprint under review for ESSD
Short summary
Preparation of low-concentration H2 test gas mixtures in ambient air for calibration of H2 sensors
Niklas Karbach, Lisa Höhler, Peter Hoor, Heiko Bozem, Nicole Bobrowski, and Thorsten Hoffmann
Atmos. Meas. Tech., 17, 4081–4086, https://doi.org/10.5194/amt-17-4081-2024,https://doi.org/10.5194/amt-17-4081-2024, 2024
Short summary
Possible controls on Arctic clouds by natural aerosols from long-range transport of biogenic emissions and ozone depletion events
Rupert Holzinger, Oliver Eppers, Kouji Adachi, Heiko Bozem, Markus Hartmann, Andreas Herber, Makoto Koike, Dylan B. Millet, Nobuhiro Moteki, Sho Ohata, Frank Stratmann, and Atsushi Yoshida
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-95,https://doi.org/10.5194/acp-2022-95, 2022
Revised manuscript not accepted
Short summary
Comparison of inorganic chlorine in the Antarctic and Arctic lowermost stratosphere by separate late winter aircraft measurements
Markus Jesswein, Heiko Bozem, Hans-Christoph Lachnitt, Peter Hoor, Thomas Wagenhäuser, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 21, 17225–17241, https://doi.org/10.5194/acp-21-17225-2021,https://doi.org/10.5194/acp-21-17225-2021, 2021
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024,https://doi.org/10.5194/acp-24-11927-2024, 2024
Short summary
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024,https://doi.org/10.5194/acp-24-11823-2024, 2024
Short summary
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024,https://doi.org/10.5194/acp-24-11883-2024, 2024
Short summary
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024,https://doi.org/10.5194/acp-24-11807-2024, 2024
Short summary
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024,https://doi.org/10.5194/acp-24-11603-2024, 2024
Short summary

Cited articles

Bozem, H., Fischer, H., Gurk, C., Schiller, C. L., Parchatka, U., Koenigstedt, R., Stickler, A., Martinez, M., Harder, H., Kubistin, D., Williams, J., Eerdekens, G., and Lelieveld, J.: Influence of corona discharge on the ozone budget in the tropical free troposphere: a case study of deep convection during GABRIEL, Atmos. Chem. Phys., 14, 8917–8931, https://doi.org/10.5194/acp-14-8917-2014, 2014.
Bozem, H., Pozzer, A., Harder, H., Martinez, M., Williams, J., Lelieveld, J., and Fischer, H.: The influence of deep convection on HCHO and H2O2 in the upper troposphere over Europe, Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-154, in review, 2017.
Brunner, D., Staehelin, J., Jeker, D., Wernli, H., and Schumann, U.: Nitrogen oxides and ozone in the tropopause region of the northern hemisphere: Measurements from commercial aircraft in 1995/1996 and 1997, J. Geophys. Res., 106, 27673–27699, https://doi.org/10.1029/2001JD900239, 2001.
Cantrell, C. A., Shetter, R. E., Gilpin, T. M., and Calvert, J. G.: Peroxy radicals measured during Mauna Loa Observatory Photochemistry Experiment 2: The data and first analysis, J. Geophys. Res., 101, 14643–14652, https://doi.org/10.1029/95JD01698, 1996.
Download
Short summary
We present airborne measurements and model simulations in the tropics and mid-latitudes during GABRIEL and HOOVER, respectively. Based only on in situ data net ozone formation/destruction tendencies (NOPR) are calculated and compared to a 3-D chemistry transport model. The NOPR is positive in the continental boundary layer and the upper troposphere above 6 km. In the marine boundary layer and the middle troposphere ozone destruction prevails. Fresh convection shows strong net ozone formation.
Altmetrics
Final-revised paper
Preprint