Articles | Volume 21, issue 11
https://doi.org/10.5194/acp-21-8479-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-8479-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Jun 2021
Research article |
| 04 Jun 2021
| 04 Jun 2021
Importance of secondary organic aerosol formation of α-pinene, limonene, and m-cresol comparing day- and nighttime radical chemistry
Anke Mutzel
CORRESPONDING AUTHOR
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
now at: Eurofins Institute Dr. Appelt Leipzig, Täubchenweg 28,
04318 Leipzig
Yanli Zhang
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Protection and Resources Utilization, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640,
China
Olaf Böge
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
Maria Rodigast
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
now at: Indulor Chemie GmbH & Co. KG Produktionsgesellschaft
Bitterfeld, 06749 Bitterfeld-Wolfen, Germany
Agata Kolodziejczyk
Institute of Physical Chemistry of the Polish Academy of Sciences,
Kasprzaka 44/52, 01-224 Warsaw, Poland
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
Xinming Wang
State Key Laboratory of Organic Geochemistry and Guangdong Key
Laboratory of Environmental Protection and Resources Utilization, Guangzhou
Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640,
China
Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric
Chemistry Department (ACD), Permoserstr. 15, 04318 Leipzig, Germany
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Tianle Pan, Andrew T. Lambe, Weiwei Hu, Yicong He, Minghao Hu, Huaishan Zhou, Xinming Wang, Qingqing Hu, Hui Chen, Yue Zhao, Yuanlong Huang, Doug R. Worsnop, Zhe Peng, Melissa A. Morris, Douglas A. Day, Pedro Campuzano-Jost, Jose-Luis Jimenez, and Shantanu H. Jathar
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Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
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Juanjuan Qin, Leiming Zhang, Yuanyuan Qin, Shaoxuan Shi, Jingnan Li, Zhao Shu, Yuwei Gao, Ting Qi, Jihua Tan, and Xinming Wang
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Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
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Ping Liu, Xiang Ding, Bo-Xuan Li, Yu-Qing Zhang, Daniel J. Bryant, and Xin-Ming Wang
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In this paper, we further optimize the measurement of atmospheric organosulfates by hydrophilic interaction liquid chromatography (HILIC), offering an improved method for quantifying and speciating atmospheric organosulfates. These efforts will contribute to a deeper understanding of secondary organic aerosol precursors, formation mechanisms, and the contribution of organosulfate to atmospheric aerosols, ultimately guiding research in the field of air pollution prevention and control.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
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Anil Kumar Mandariya, Junteng Wu, Anne Monod, Paola Formenti, Bénédicte Picquet-Varrault, Mathieu Cazaunau, Stephan Mertes, Laurent Poulain, Antonin Berge, Edouard Pangui, Andreas Tilgner, Thomas Schaefer, Liang Wen, Hartmut Herrmann, and Jean-François Doussin
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Publication in AMT not foreseen
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An optimized and controlled protocol for generating quasi-adiabatic expansion clouds under simulated dark and light conditions was presented. The irradiated clouds clearly showed a gradual activation of seed particles into droplets. In contrast, non-irradiated clouds faced a flash activation. This paper will lay the foundation for multiphase photochemical studies implying water-soluble volatile organic compounds and particulate matter formation during cloud formation-evaporation cycles.
Andrea Cuesta-Mosquera, Kristina Glojek, Griša Močnik, Luka Drinovec, Asta Gregorič, Martin Rigler, Matej Ogrin, Baseerat Romshoo, Kay Weinhold, Maik Merkel, Dominik van Pinxteren, Hartmut Herrmann, Alfred Wiedensohler, Mira Pöhlker, and Thomas Müller
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This study evaluated the air pollution and climate impacts of residential-wood-burning particle emissions from a rural European site. The authors investigate the optical and physical properties that connect the aerosol emissions with climate by evaluating atmospheric radiative impacts via simple-forcing calculations. The study contributes to reducing the lack of information on the understanding of the optical properties of air pollution from anthropogenic sources.
Hua Fang, Ting Wu, Shutan Ma, Qina Jia, Fengyu Zan, Juan Zhao, Jintao Zhang, Zhi Yang, Hongling Xu, Yuzhe Huang, and Xinming Wang
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Preprint archived
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Using in situ VOC flux measurements, we reveal that the freshwater wetland is a potential source of atmospheric VOCs and that litter decomposition enhances net VOC emission. Ambient temperature is the key factor driving the seasonal variation of net VOC flux. Notably, the release or uptake of VOCs varies depending on chemical groups and is jointly controlled by biotic and abiotic processes.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 15561–15587, https://doi.org/10.5194/acp-23-15561-2023, https://doi.org/10.5194/acp-23-15561-2023, 2023
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Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles, and potentially contribute to the formation of fog and clouds. Here, we present the results of a sea–air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Bojiang Su, Xinhui Bi, Zhou Zhang, Yue Liang, Congbo Song, Tao Wang, Yaohao Hu, Lei Li, Zhen Zhou, Jinpei Yan, Xinming Wang, and Guohua Zhang
Atmos. Chem. Phys., 23, 10697–10711, https://doi.org/10.5194/acp-23-10697-2023, https://doi.org/10.5194/acp-23-10697-2023, 2023
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During the R/V Xuelong cruise observation over the Ross Sea, Antarctica, the mass concentrations of water-soluble Ca2+ and the mass spectra of individual calcareous particles were measured. Our results indicated that lower temperature, lower wind speed, and the presence of sea ice may facilitate Ca2+ enrichment in sea spray aerosols and highlighted the potential contribution of organically complexed calcium to calcium enrichment, which is inaccurate based solely on water-soluble Ca2+ estimation.
Jean-Philippe Putaud, Enrico Pisoni, Alexander Mangold, Christoph Hueglin, Jean Sciare, Michael Pikridas, Chrysanthos Savvides, Jakub Ondracek, Saliou Mbengue, Alfred Wiedensohler, Kay Weinhold, Maik Merkel, Laurent Poulain, Dominik van Pinxteren, Hartmut Herrmann, Andreas Massling, Claus Nordstroem, Andrés Alastuey, Cristina Reche, Noemí Pérez, Sonia Castillo, Mar Sorribas, Jose Antonio Adame, Tuukka Petaja, Katrianne Lehtipalo, Jarkko Niemi, Véronique Riffault, Joel F. de Brito, Augustin Colette, Olivier Favez, Jean-Eudes Petit, Valérie Gros, Maria I. Gini, Stergios Vratolis, Konstantinos Eleftheriadis, Evangelia Diapouli, Hugo Denier van der Gon, Karl Espen Yttri, and Wenche Aas
Atmos. Chem. Phys., 23, 10145–10161, https://doi.org/10.5194/acp-23-10145-2023, https://doi.org/10.5194/acp-23-10145-2023, 2023
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Many European people are still exposed to levels of air pollution that can affect their health. COVID-19 lockdowns in 2020 were used to assess the impact of the reduction in human mobility on air pollution across Europe by comparing measurement data with values that would be expected if no lockdown had occurred. We show that lockdown measures did not lead to consistent decreases in the concentrations of fine particulate matter suspended in the air, and we investigate why.
Yiyu Cai, Chenshuo Ye, Wei Chen, Weiwei Hu, Wei Song, Yuwen Peng, Shan Huang, Jipeng Qi, Sihang Wang, Chaomin Wang, Caihong Wu, Zelong Wang, Baolin Wang, Xiaofeng Huang, Lingyan He, Sasho Gligorovski, Bin Yuan, Min Shao, and Xinming Wang
Atmos. Chem. Phys., 23, 8855–8877, https://doi.org/10.5194/acp-23-8855-2023, https://doi.org/10.5194/acp-23-8855-2023, 2023
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We studied the variability and molecular composition of ambient oxidized organic nitrogen (OON) in both gas and particle phases using a state-of-the-art online mass spectrometer in urban air. Biomass burning and secondary formation were found to be the two major sources of OON. Daytime nitrate radical chemistry for OON formation was more important than previously thought. Our results improved the understanding of the sources and molecular composition of OON in the polluted urban atmosphere.
Samira Atabakhsh, Laurent Poulain, Gang Chen, Francesco Canonaco, André S. H. Prévôt, Mira Pöhlker, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 6963–6988, https://doi.org/10.5194/acp-23-6963-2023, https://doi.org/10.5194/acp-23-6963-2023, 2023
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The study focuses on the aerosol chemical variations found in the rural-background station of Melpitz based on ACSM and MAAP measurements. Source apportionment on both organic aerosol (OA) and black carbon (eBC) was performed, and source seasonality was also linked to air mass trajectories. Overall, three anthropogenic sources were identified in OA and eBC plus two additional aged OA. Our results demonstrate the influence of transported coal-combustion-related OA even during summer time.
Manuela van Pinxteren, Sebastian Zeppenfeld, Khanneh Wadinga Fomba, Nadja Triesch, Sanja Frka, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 6571–6590, https://doi.org/10.5194/acp-23-6571-2023, https://doi.org/10.5194/acp-23-6571-2023, 2023
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Important marine organic carbon compounds were identified in the Atlantic Ocean and marine aerosol particles. These compounds were strongly enriched in the atmosphere. Their enrichment was, however, not solely explained via sea-to-air transfer but also via atmospheric in situ formation. The identified compounds constituted about 50 % of the organic carbon on the aerosol particles, and a pronounced coupling between ocean and atmosphere for this oligotrophic region could be concluded.
Joanna E. Dyson, Lisa K. Whalley, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Stephen D. Worrall, Asan Bacak, Archit Mehra, Thomas J. Bannan, Hugh Coe, Carl J. Percival, Bin Ouyang, C. Nicholas Hewitt, Roderic L. Jones, Leigh R. Crilley, Louisa J. Kramer, W. Joe F. Acton, William J. Bloss, Supattarachai Saksakulkrai, Jingsha Xu, Zongbo Shi, Roy M. Harrison, Simone Kotthaus, Sue Grimmond, Yele Sun, Weiqi Xu, Siyao Yue, Lianfang Wei, Pingqing Fu, Xinming Wang, Stephen R. Arnold, and Dwayne E. Heard
Atmos. Chem. Phys., 23, 5679–5697, https://doi.org/10.5194/acp-23-5679-2023, https://doi.org/10.5194/acp-23-5679-2023, 2023
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The hydroxyl (OH) and closely coupled hydroperoxyl (HO2) radicals are vital for their role in the removal of atmospheric pollutants. In less polluted regions, atmospheric models over-predict HO2 concentrations. In this modelling study, the impact of heterogeneous uptake of HO2 onto aerosol surfaces on radical concentrations and the ozone production regime in Beijing in the summertime is investigated, and the implications for emissions policies across China are considered.
Huanhuan Zhang, Rui Li, Chengpeng Huang, Xiaofei Li, Shuwei Dong, Fu Wang, Tingting Li, Yizhu Chen, Guohua Zhang, Yan Ren, Qingcai Chen, Ru-jin Huang, Siyu Chen, Tao Xue, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 23, 3543–3559, https://doi.org/10.5194/acp-23-3543-2023, https://doi.org/10.5194/acp-23-3543-2023, 2023
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This work investigated the seasonal variation of aerosol Fe solubility for coarse and fine particles in Xi’an, a megacity in northwestern China severely affected by anthropogenic emission and desert dust aerosol. In addition, we discussed in depth what controlled aerosol Fe solubility at different seasons for coarse and fine particles.
Peng Wang, Ruhan Zhang, Shida Sun, Meng Gao, Bo Zheng, Dan Zhang, Yanli Zhang, Gregory R. Carmichael, and Hongliang Zhang
Atmos. Chem. Phys., 23, 2983–2996, https://doi.org/10.5194/acp-23-2983-2023, https://doi.org/10.5194/acp-23-2983-2023, 2023
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In China, the number of vehicles has jumped significantly in the last decade. This caused severe traffic congestion and aggravated air pollution. In this study, we developed a new temporal allocation approach to quantify the impacts of traffic congestion. We found that traffic congestion worsens air quality and the health burden across China, especially in the urban clusters. More effective and comprehensive vehicle emission control policies should be implemented to improve air quality in China.
Tingting Feng, Yingkun Wang, Weiwei Hu, Ming Zhu, Wei Song, Wei Chen, Yanyan Sang, Zheng Fang, Wei Deng, Hua Fang, Xu Yu, Cheng Wu, Bin Yuan, Shan Huang, Min Shao, Xiaofeng Huang, Lingyan He, Young Ro Lee, Lewis Gregory Huey, Francesco Canonaco, Andre S. H. Prevot, and Xinming Wang
Atmos. Chem. Phys., 23, 611–636, https://doi.org/10.5194/acp-23-611-2023, https://doi.org/10.5194/acp-23-611-2023, 2023
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To investigate the impact of aging processes on organic aerosols (OA), we conducted a comprehensive field study at a continental remote site using an on-line mass spectrometer. The results show that OA in the Chinese outflows were strongly influenced by upwind anthropogenic emissions. The aging processes can significantly decrease the OA volatility and result in a varied viscosity of OA under different circumstances, signifying the complex physiochemical properties of OA in aged plumes.
Yuan Wang, Silvia Henning, Laurent Poulain, Chunsong Lu, Frank Stratmann, Yuying Wang, Shengjie Niu, Mira L. Pöhlker, Hartmut Herrmann, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 15943–15962, https://doi.org/10.5194/acp-22-15943-2022, https://doi.org/10.5194/acp-22-15943-2022, 2022
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Aerosol particle activation affects cloud, precipitation, radiation, and thus the global climate. Its long-term measurements are important but still scarce. In this study, more than 4 years of measurements at a central European station were analyzed. The overall characteristics and seasonal changes of aerosol particle activation are summarized. The power-law fit between particle hygroscopicity factor and diameter was recommended for predicting cloud
condensation nuclei number concentration.
Xueyin Ruan, Chun Zhao, Rahul A. Zaveri, Pengzhen He, Xinming Wang, Jingyuan Shao, and Lei Geng
Geosci. Model Dev., 15, 6143–6164, https://doi.org/10.5194/gmd-15-6143-2022, https://doi.org/10.5194/gmd-15-6143-2022, 2022
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Accurate prediction of aerosol pH in chemical transport models is essential to aerosol modeling. This study examines the performance of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) on aerosol pH predictions and the sensitivities to emissions of nonvolatile cations and NH3, aerosol-phase state assumption, and heterogeneous sulfate production. Temporal evolution of aerosol pH during haze cycles in Beijing and the driving factors are also presented and discussed.
Guohua Zhang, Xiaodong Hu, Wei Sun, Yuxiang Yang, Ziyong Guo, Yuzhen Fu, Haichao Wang, Shengzhen Zhou, Lei Li, Mingjin Tang, Zongbo Shi, Duohong Chen, Xinhui Bi, and Xinming Wang
Atmos. Chem. Phys., 22, 9571–9582, https://doi.org/10.5194/acp-22-9571-2022, https://doi.org/10.5194/acp-22-9571-2022, 2022
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We show a significant enhancement of nitrate mass fraction in cloud water and relative intensity of nitrate in the cloud residual particles and highlight that hydrolysis of N2O5 serves as the critical route for the in-cloud formation of nitrate, even during the daytime. Given that N2O5 hydrolysis acts as a major sink of NOx in the atmosphere, further model updates may improve our understanding about the processes contributing to nitrate production in cloud and the cycling of odd nitrogen.
Yihang Yu, Peng Cheng, Huirong Li, Wenda Yang, Baobin Han, Wei Song, Weiwei Hu, Xinming Wang, Bin Yuan, Min Shao, Zhijiong Huang, Zhen Li, Junyu Zheng, Haichao Wang, and Xiaofang Yu
Atmos. Chem. Phys., 22, 8951–8971, https://doi.org/10.5194/acp-22-8951-2022, https://doi.org/10.5194/acp-22-8951-2022, 2022
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We have investigated the budget of HONO at an urban site in Guangzhou. Budget and comprehensive uncertainty analysis suggest that at such locations as ours, HONO direct emissions and NO + OH can become comparable or even surpass other HONO sources that typically receive greater attention and interest, such as the NO2 heterogeneous source and the unknown daytime photolytic source. Our findings emphasize the need to reduce the uncertainties of both conventional and novel HONO sources and sinks.
Lady Mateus-Fontecha, Angela Vargas-Burbano, Rodrigo Jimenez, Nestor Y. Rojas, German Rueda-Saa, Dominik van Pinxteren, Manuela van Pinxteren, Khanneh Wadinga Fomba, and Hartmut Herrmann
Atmos. Chem. Phys., 22, 8473–8495, https://doi.org/10.5194/acp-22-8473-2022, https://doi.org/10.5194/acp-22-8473-2022, 2022
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This study reports the chemical composition of regionally representative PM2.5 in an area densely populated and substantially industrialized, located in the inter-Andean valley, with the highest sugarcane yield in the world and where sugarcane is burned and harvested year round. We found that sugarcane burning is not portrayed as a distinguishable sample composition component. Instead, the composition analysis revealed multiple associations among sugarcane burning components and other sources.
Lu Chen, Fang Zhang, Dongmei Zhang, Xinming Wang, Wei Song, Jieyao Liu, Jingye Ren, Sihui Jiang, Xue Li, and Zhanqing Li
Atmos. Chem. Phys., 22, 6773–6786, https://doi.org/10.5194/acp-22-6773-2022, https://doi.org/10.5194/acp-22-6773-2022, 2022
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Aerosol hygroscopicity is critical when evaluating its effect on visibility and climate. Here, the size-resolved particle hygroscopicity at five sites in China is characterized using field measurements. We show the distinct behavior of hygroscopic particles during pollution evolution among the five sites. Moreover, different hygroscopic behavior during NPF events were also observed. The dataset is helpful for understanding the spatial variability in particle composition and formation mechanisms.
Manuela van Pinxteren, Tiera-Brandy Robinson, Sebastian Zeppenfeld, Xianda Gong, Enno Bahlmann, Khanneh Wadinga Fomba, Nadja Triesch, Frank Stratmann, Oliver Wurl, Anja Engel, Heike Wex, and Hartmut Herrmann
Atmos. Chem. Phys., 22, 5725–5742, https://doi.org/10.5194/acp-22-5725-2022, https://doi.org/10.5194/acp-22-5725-2022, 2022
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A class of marine particles (transparent exopolymer particles, TEPs) that is ubiquitously found in the world oceans was measured for the first time in ambient marine aerosol particles and marine cloud waters in the tropical Atlantic Ocean. TEPs are likely to have good properties for influencing clouds. We show that TEPs are transferred from the ocean to the marine atmosphere via sea-spray formation and our results suggest that they can also form directly in aerosol particles and in cloud water.
Kristina Glojek, Griša Močnik, Honey Dawn C. Alas, Andrea Cuesta-Mosquera, Luka Drinovec, Asta Gregorič, Matej Ogrin, Kay Weinhold, Irena Ježek, Thomas Müller, Martin Rigler, Maja Remškar, Dominik van Pinxteren, Hartmut Herrmann, Martina Ristorini, Maik Merkel, Miha Markelj, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 5577–5601, https://doi.org/10.5194/acp-22-5577-2022, https://doi.org/10.5194/acp-22-5577-2022, 2022
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A pilot study to determine the emissions of wood burning under
real-world laboratoryconditions was conducted. We found that measured black carbon (eBC) and particulate matter (PM) in rural shallow terrain depressions with residential wood burning could be much greater than predicted by models. The exceeding levels are a cause for concern since similar conditions can be expected in numerous hilly and mountainous regions across Europe, where approximately 20 % of the total population lives.
Ziyong Guo, Yuxiang Yang, Xiaodong Hu, Xiaocong Peng, Yuzhen Fu, Wei Sun, Guohua Zhang, Duohong Chen, Xinhui Bi, Xinming Wang, and Ping'an Peng
Atmos. Chem. Phys., 22, 4827–4839, https://doi.org/10.5194/acp-22-4827-2022, https://doi.org/10.5194/acp-22-4827-2022, 2022
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We show that in-cloud aqueous processing facilitates the formation of brown carbon (BrC), based on the simultaneous measurements of the light-absorption properties of the cloud residuals, cloud interstitial, and cloud-free particles. While extensive laboratory evidence indicated the formation of BrC in aqueous phase, our study represents the first attempt to show the possibility in real clouds, which would have potential implications in the atmospheric evolution and radiation forcing of BrC.
Suxia Yang, Bin Yuan, Yuwen Peng, Shan Huang, Wei Chen, Weiwei Hu, Chenglei Pei, Jun Zhou, David D. Parrish, Wenjie Wang, Xianjun He, Chunlei Cheng, Xiao-Bing Li, Xiaoyun Yang, Yu Song, Haichao Wang, Jipeng Qi, Baolin Wang, Chen Wang, Chaomin Wang, Zelong Wang, Tiange Li, E Zheng, Sihang Wang, Caihong Wu, Mingfu Cai, Chenshuo Ye, Wei Song, Peng Cheng, Duohong Chen, Xinming Wang, Zhanyi Zhang, Xuemei Wang, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4539–4556, https://doi.org/10.5194/acp-22-4539-2022, https://doi.org/10.5194/acp-22-4539-2022, 2022
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We use a model constrained using observations to study the formation of nitrate aerosol in and downwind of a representative megacity. We found different contributions of various chemical reactions to ground-level nitrate concentrations between urban and suburban regions. We also show that controlling VOC emissions are effective for decreasing nitrate formation in both urban and regional environments, although VOCs are not direct precursors of nitrate aerosol.
Wenjie Wang, Bin Yuan, Yuwen Peng, Hang Su, Yafang Cheng, Suxia Yang, Caihong Wu, Jipeng Qi, Fengxia Bao, Yibo Huangfu, Chaomin Wang, Chenshuo Ye, Zelong Wang, Baolin Wang, Xinming Wang, Wei Song, Weiwei Hu, Peng Cheng, Manni Zhu, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4117–4128, https://doi.org/10.5194/acp-22-4117-2022, https://doi.org/10.5194/acp-22-4117-2022, 2022
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From thorough measurements of numerous oxygenated volatile organic compounds, we show that their photodissociation can be important for radical production and ozone formation in the atmosphere. This effect was underestimated in previous studies, as measurements of them were lacking.
Haichao Wang, Chao Peng, Xuan Wang, Shengrong Lou, Keding Lu, Guicheng Gan, Xiaohong Jia, Xiaorui Chen, Jun Chen, Hongli Wang, Shaojia Fan, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 22, 1845–1859, https://doi.org/10.5194/acp-22-1845-2022, https://doi.org/10.5194/acp-22-1845-2022, 2022
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Via combining laboratory and modeling work, we found that heterogeneous reaction of N2O5 with saline mineral dust aerosol could be an important source of tropospheric ClNO2 in inland regions.
Juanjuan Qin, Jihua Tan, Xueming Zhou, Yanrong Yang, Yuanyuan Qin, Xiaobo Wang, Shaoxuan Shi, Kang Xiao, and Xinming Wang
Atmos. Chem. Phys., 22, 465–479, https://doi.org/10.5194/acp-22-465-2022, https://doi.org/10.5194/acp-22-465-2022, 2022
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Water-soluble organic compounds (WSOCs) play important roles in atmospheric particle formation, migration, and transformation processes. In this work, size-segregated atmospheric particles were collected in a rural area of Beijing, and 3D fluorescence spectroscopy was used to investigate the optical properties of WSOCs as a means of inferring information about their atmospheric sources. It was found that these data could efficiently reveal the secondary transformation processes of WSOCs.
Jianqiang Zeng, Yanli Zhang, Huina Zhang, Wei Song, Zhenfeng Wu, and Xinming Wang
Atmos. Meas. Tech., 15, 79–93, https://doi.org/10.5194/amt-15-79-2022, https://doi.org/10.5194/amt-15-79-2022, 2022
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The emission of biogenic volatile organic compounds (BVOCs) from plant leaves is an essential part of biosphere–atmosphere interactions. Here we demonstrate how a dynamic chamber for measuring branch-scale BVOC emissions could be characterized both in the lab for adsorptive losses and in the field for ambient–enclosure environmental differences. The results also imply emission factors for terpenes might be underestimated if measured using dynamic chambers without certified transfer efficiencies.
Nabil Deabji, Khanneh Wadinga Fomba, Souad El Hajjaji, Abdelwahid Mellouki, Laurent Poulain, Sebastian Zeppenfeld, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 18147–18174, https://doi.org/10.5194/acp-21-18147-2021, https://doi.org/10.5194/acp-21-18147-2021, 2021
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Mountain and high-altitude sites provide representative data for the lower free troposphere, various pathways for aerosol interactions, and changing boundary layer heights useful in understanding atmospheric composition. However, only few studies exist in African regions despite diversity in both natural and anthropogenic emissions. This study provides detailed atmospheric studies in the northern African high-altitude region.
Wei Sun, Yuzhen Fu, Guohua Zhang, Yuxiang Yang, Feng Jiang, Xiufeng Lian, Bin Jiang, Yuhong Liao, Xinhui Bi, Duohong Chen, Jianmin Chen, Xinming Wang, Jie Ou, Ping'an Peng, and Guoying Sheng
Atmos. Chem. Phys., 21, 16631–16644, https://doi.org/10.5194/acp-21-16631-2021, https://doi.org/10.5194/acp-21-16631-2021, 2021
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We sampled cloud water at a remote mountain site and investigated the molecular characteristics. CHON and CHO are dominant in cloud water. No statistical difference in the oxidation state is observed between cloud water and interstitial PM2.5. Most of the formulas are aliphatic and olefinic species. CHON, with aromatic structures and organosulfates, are abundant, especially in nighttime samples. The in-cloud and multi-phase dark reactions likely contribute significantly.
Andreas Tilgner, Thomas Schaefer, Becky Alexander, Mary Barth, Jeffrey L. Collett Jr., Kathleen M. Fahey, Athanasios Nenes, Havala O. T. Pye, Hartmut Herrmann, and V. Faye McNeill
Atmos. Chem. Phys., 21, 13483–13536, https://doi.org/10.5194/acp-21-13483-2021, https://doi.org/10.5194/acp-21-13483-2021, 2021
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Feedbacks of acidity and atmospheric multiphase chemistry in deliquesced particles and clouds are crucial for the tropospheric composition, depositions, climate, and human health. This review synthesizes the current scientific knowledge on these feedbacks using both inorganic and organic aqueous-phase chemistry. Finally, this review outlines atmospheric implications and highlights the need for future investigations with respect to reducing emissions of key acid precursors in a changing world.
R. Anthony Cox, Markus Ammann, John N. Crowley, Paul T. Griffiths, Hartmut Herrmann, Erik H. Hoffmann, Michael E. Jenkin, V. Faye McNeill, Abdelwahid Mellouki, Christopher J. Penkett, Andreas Tilgner, and Timothy J. Wallington
Atmos. Chem. Phys., 21, 13011–13018, https://doi.org/10.5194/acp-21-13011-2021, https://doi.org/10.5194/acp-21-13011-2021, 2021
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The term open-air factor was coined in the 1960s, establishing that rural air had powerful germicidal properties possibly resulting from immediate products of the reaction of ozone with alkenes, unsaturated compounds ubiquitously present in natural and polluted environments. We have re-evaluated those early experiments, applying the recently substantially improved knowledge, and put them into the context of the lifetime of aerosol-borne pathogens that are so important in the Covid-19 pandemic.
Markus Hartmann, Xianda Gong, Simonas Kecorius, Manuela van Pinxteren, Teresa Vogl, André Welti, Heike Wex, Sebastian Zeppenfeld, Hartmut Herrmann, Alfred Wiedensohler, and Frank Stratmann
Atmos. Chem. Phys., 21, 11613–11636, https://doi.org/10.5194/acp-21-11613-2021, https://doi.org/10.5194/acp-21-11613-2021, 2021
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Ice-nucleating particles (INPs) are not well characterized in the Arctic despite their importance for the Arctic energy budget. Little is known about their nature (mineral or biological) and sources (terrestrial or marine, long-range transport or local). We find indications that, at the beginning of the melt season, a local, biogenic, probably marine source is likely, but significant enrichment of INPs has to take place from the ocean to the aerosol phase.
Peng Wang, Juanyong Shen, Men Xia, Shida Sun, Yanli Zhang, Hongliang Zhang, and Xinming Wang
Atmos. Chem. Phys., 21, 10347–10356, https://doi.org/10.5194/acp-21-10347-2021, https://doi.org/10.5194/acp-21-10347-2021, 2021
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Ozone (O3) pollution has received extensive attention due to worsening air quality and rising health risks. The Chinese National Day holiday (CNDH), which is associated with intensive commercial and tourist activities, serves as a valuable experiment to evaluate the O3 response during the holiday. We find sharply increasing trends of observed O3 concentrations throughout China during the CNDH, leading to 33 % additional total daily deaths.
Hua Fang, Xiaoqing Huang, Yanli Zhang, Chenglei Pei, Zuzhao Huang, Yujun Wang, Yanning Chen, Jianhong Yan, Jianqiang Zeng, Shaoxuan Xiao, Shilu Luo, Sheng Li, Jun Wang, Ming Zhu, Xuewei Fu, Zhenfeng Wu, Runqi Zhang, Wei Song, Guohua Zhang, Weiwei Hu, Mingjin Tang, Xiang Ding, Xinhui Bi, and Xinming Wang
Atmos. Chem. Phys., 21, 10005–10013, https://doi.org/10.5194/acp-21-10005-2021, https://doi.org/10.5194/acp-21-10005-2021, 2021
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A tunnel test was initiated to measure the vehicular IVOC emissions under real-world driving conditions. Higher SOA formation estimated from vehicular IVOCs compared to those from traditional VOCs emphasized the greater importance of IVOCs in modulating urban SOA. The results also revealed that non-road diesel-fueled engines greatly contributed to IVOCs in China.
Chenshuo Ye, Bin Yuan, Yi Lin, Zelong Wang, Weiwei Hu, Tiange Li, Wei Chen, Caihong Wu, Chaomin Wang, Shan Huang, Jipeng Qi, Baolin Wang, Chen Wang, Wei Song, Xinming Wang, E Zheng, Jordan E. Krechmer, Penglin Ye, Zhanyi Zhang, Xuemei Wang, Douglas R. Worsnop, and Min Shao
Atmos. Chem. Phys., 21, 8455–8478, https://doi.org/10.5194/acp-21-8455-2021, https://doi.org/10.5194/acp-21-8455-2021, 2021
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We performed measurements of gaseous and particulate organic compounds using a state-of-the-art online mass spectrometer in urban air. Using the dataset, we provide a holistic chemical characterization of oxygenated organic compounds in the polluted urban atmosphere, which can serve as a reference for the future field measurements of organic compounds in cities.
Jingsha Xu, Di Liu, Xuefang Wu, Tuan V. Vu, Yanli Zhang, Pingqing Fu, Yele Sun, Weiqi Xu, Bo Zheng, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 7321–7341, https://doi.org/10.5194/acp-21-7321-2021, https://doi.org/10.5194/acp-21-7321-2021, 2021
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Source apportionment of fine aerosols in an urban site of Beijing used a chemical mass balance (CMB) model. Seven primary sources (industrial/residential coal burning, biomass burning, gasoline/diesel vehicles, cooking and vegetative detritus) explained an average of 75.7 % and 56.1 % of fine OC in winter and summer, respectively. CMB was found to resolve more primary OA sources than AMS-PMF, but the latter apportioned more secondary OA sources.
Chao Peng, Patricia N. Razafindrambinina, Kotiba A. Malek, Lanxiadi Chen, Weigang Wang, Ru-Jin Huang, Yuqing Zhang, Xiang Ding, Maofa Ge, Xinming Wang, Akua A. Asa-Awuku, and Mingjin Tang
Atmos. Chem. Phys., 21, 7135–7148, https://doi.org/10.5194/acp-21-7135-2021, https://doi.org/10.5194/acp-21-7135-2021, 2021
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Organosulfates are important constituents in tropospheric aerosol particles, but their hygroscopic properties and cloud condensation nuclei activities are not well understood. In our work, three complementary techniques were employed to investigate the interactions of 11 organosulfates with water vapor under sub- and supersaturated conditions.
Claire E. Reeves, Graham P. Mills, Lisa K. Whalley, W. Joe F. Acton, William J. Bloss, Leigh R. Crilley, Sue Grimmond, Dwayne E. Heard, C. Nicholas Hewitt, James R. Hopkins, Simone Kotthaus, Louisa J. Kramer, Roderic L. Jones, James D. Lee, Yanhui Liu, Bin Ouyang, Eloise Slater, Freya Squires, Xinming Wang, Robert Woodward-Massey, and Chunxiang Ye
Atmos. Chem. Phys., 21, 6315–6330, https://doi.org/10.5194/acp-21-6315-2021, https://doi.org/10.5194/acp-21-6315-2021, 2021
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The impact of isoprene on atmospheric chemistry is dependent on how its oxidation products interact with other pollutants, specifically nitrogen oxides. Such interactions can lead to isoprene nitrates. We made measurements of the concentrations of individual isoprene nitrate isomers in Beijing and used a model to test current understanding of their chemistry. We highlight areas of uncertainty in understanding, in particular the chemistry following oxidation of isoprene by the nitrate radical.
Long Peng, Lei Li, Guohua Zhang, Xubing Du, Xinming Wang, Ping'an Peng, Guoying Sheng, and Xinhui Bi
Atmos. Chem. Phys., 21, 5605–5613, https://doi.org/10.5194/acp-21-5605-2021, https://doi.org/10.5194/acp-21-5605-2021, 2021
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We build a novel system that utilizes an aerodynamic aerosol classifier (AAC) combined with a single-particle aerosol mass spectrometry (SPAMS) to simultaneously characterize the volume equivalent diameter (Dve), chemical compositions, and effective density (ρe) of individual particles in real time. A test of the AAC-SPAMS with both spherical and aspherical particles shows that the deviations between the measured and theoretical values are less than 6 %.
Abdelwahid Mellouki, Markus Ammann, R. Anthony Cox, John N. Crowley, Hartmut Herrmann, Michael E. Jenkin, V. Faye McNeill, Jürgen Troe, and Timothy J. Wallington
Atmos. Chem. Phys., 21, 4797–4808, https://doi.org/10.5194/acp-21-4797-2021, https://doi.org/10.5194/acp-21-4797-2021, 2021
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Volatile organic compounds play an important role in atmospheric chemistry. This article, the eighth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the gas-phase reactions of organic species with four, or more, carbon atoms (≥ C4) including thermal reactions of closed-shell organic species with HO and NO3 radicals and their photolysis. These data are important for atmospheric models.
Nadja Triesch, Manuela van Pinxteren, Sanja Frka, Christian Stolle, Tobias Spranger, Erik Hans Hoffmann, Xianda Gong, Heike Wex, Detlef Schulz-Bull, Blaženka Gašparović, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 4267–4283, https://doi.org/10.5194/acp-21-4267-2021, https://doi.org/10.5194/acp-21-4267-2021, 2021
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To investigate the source of lipids and their representatives in the marine atmosphere, concerted measurements of seawater and submicrometer aerosol particle sampling were carried out on the Cabo Verde islands. This field study describes the biogenic sources of lipids, their selective transfer from the ocean into the atmosphere and their enrichment as part of organic matter. A strong enrichment of the studied representatives of the lipid classes on submicrometer aerosol particles was observed.
Laurent Poulain, Benjamin Fahlbusch, Gerald Spindler, Konrad Müller, Dominik van Pinxteren, Zhijun Wu, Yoshiteru Iinuma, Wolfram Birmili, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 3667–3684, https://doi.org/10.5194/acp-21-3667-2021, https://doi.org/10.5194/acp-21-3667-2021, 2021
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We present results from source apportionment analysis on the carbonaceous aerosol particles, including organic aerosol (OA) and equivalent black carbon (eBC), allowing us to distinguish local emissions from long-range transport for OA and eBC sources. By merging online chemical measurements and considering particle number size distribution, the different air masses reaching the sampling place were described and discussed, based on their respective chemical composition and size distribution.
Lisa K. Whalley, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Archit Mehra, Stephen D. Worrall, Asan Bacak, Thomas J. Bannan, Hugh Coe, Carl J. Percival, Bin Ouyang, Roderic L. Jones, Leigh R. Crilley, Louisa J. Kramer, William J. Bloss, Tuan Vu, Simone Kotthaus, Sue Grimmond, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 21, 2125–2147, https://doi.org/10.5194/acp-21-2125-2021, https://doi.org/10.5194/acp-21-2125-2021, 2021
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To understand how emission controls will impact ozone, an understanding of the sources and sinks of OH and the chemical cycling between peroxy radicals is needed. This paper presents measurements of OH, HO2 and total RO2 taken in central Beijing. The radical observations are compared to a detailed chemistry model, which shows that under low NO conditions, there is a missing OH source. Under high NOx conditions, the model under-predicts RO2 and impacts our ability to model ozone.
Mike J. Newland, Daniel J. Bryant, Rachel E. Dunmore, Thomas J. Bannan, W. Joe F. Acton, Ben Langford, James R. Hopkins, Freya A. Squires, William Dixon, William S. Drysdale, Peter D. Ivatt, Mathew J. Evans, Peter M. Edwards, Lisa K. Whalley, Dwayne E. Heard, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, Archit Mehra, Stephen D. Worrall, Asan Bacak, Hugh Coe, Carl J. Percival, C. Nicholas Hewitt, James D. Lee, Tianqu Cui, Jason D. Surratt, Xinming Wang, Alastair C. Lewis, Andrew R. Rickard, and Jacqueline F. Hamilton
Atmos. Chem. Phys., 21, 1613–1625, https://doi.org/10.5194/acp-21-1613-2021, https://doi.org/10.5194/acp-21-1613-2021, 2021
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We report the formation of secondary pollutants in the urban megacity of Beijing that are typically associated with remote regions such as rainforests. This is caused by extremely low levels of nitric oxide (NO), typically expected to be high in urban areas, observed in the afternoon. This work has significant implications for how we understand atmospheric chemistry in the urban environment and thus for how to implement effective policies to improve urban air quality.
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys., 21, 315–338, https://doi.org/10.5194/acp-21-315-2021, https://doi.org/10.5194/acp-21-315-2021, 2021
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Photochemistry of iron(III) complexes plays an important role in aerosol aging, especially in the lower troposphere. Ensuing radical chemistry leads to decarboxylation, and the production of peroxides, and oxygenated volatile compounds, resulting in particle mass loss due to release of the volatile products to the gas phase. We investigated kinetic transport limitations due to high particle viscosity under low relative humidity conditions. For quantification a numerical model was developed.
Nadja Triesch, Manuela van Pinxteren, Anja Engel, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 163–181, https://doi.org/10.5194/acp-21-163-2021, https://doi.org/10.5194/acp-21-163-2021, 2021
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To investigate the sources of free amino acids (FAAs) in the marine atmosphere, concerted measurements (the simultaneous investigation of seawater, size-segregated aerosol particles and cloud water) were performed at the Cabo Verde islands. This study describes the transfer of FAAs as part of organic matter from the ocean into the atmosphere on a molecular level. In the investigated marine environment, a high enrichment of FAAs in submicron aerosol particles and in cloud droplets was observed.
W. Joe F. Acton, Zhonghui Huang, Brian Davison, Will S. Drysdale, Pingqing Fu, Michael Hollaway, Ben Langford, James Lee, Yanhui Liu, Stefan Metzger, Neil Mullinger, Eiko Nemitz, Claire E. Reeves, Freya A. Squires, Adam R. Vaughan, Xinming Wang, Zhaoyi Wang, Oliver Wild, Qiang Zhang, Yanli Zhang, and C. Nicholas Hewitt
Atmos. Chem. Phys., 20, 15101–15125, https://doi.org/10.5194/acp-20-15101-2020, https://doi.org/10.5194/acp-20-15101-2020, 2020
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Air quality in Beijing is of concern to both policy makers and the general public. In order to address concerns about air quality it is vital that the sources of atmospheric pollutants are understood. This work presents the first top-down measurement of volatile organic compound (VOC) emissions in Beijing. These measurements are used to evaluate the emissions inventory and assess the impact of VOC emission from the city centre on atmospheric chemistry.
Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Bin Yuan, Jipeng Qi, Baolin Wang, Hongli Wang, Chen Wang, Wei Song, Xinming Wang, Weiwei Hu, Shengrong Lou, Chenshuo Ye, Yuwen Peng, Zelong Wang, Yibo Huangfu, Yan Xie, Manni Zhu, Junyu Zheng, Xuemei Wang, Bin Jiang, Zhanyi Zhang, and Min Shao
Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, https://doi.org/10.5194/acp-20-14769-2020, 2020
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Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Eloise J. Slater, Lisa K. Whalley, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Leigh R. Crilley, Louisa Kramer, William Bloss, Tuan Vu, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 20, 14847–14871, https://doi.org/10.5194/acp-20-14847-2020, https://doi.org/10.5194/acp-20-14847-2020, 2020
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The paper details atmospheric chemistry in a megacity (Beijing), focussing on radicals which mediate the formation of secondary pollutants such as ozone and particles. Highly polluted conditions were experienced, including the highest ever levels of nitric oxide (NO), with simultaneous radical measurements. Radical concentrations were large during "haze" events, demonstrating active photochemistry. Modelling showed that our understanding of the chemistry at high NOx levels is incomplete.
Qingqing Yu, Xiang Ding, Quanfu He, Weiqiang Yang, Ming Zhu, Sheng Li, Runqi Zhang, Ruqin Shen, Yanli Zhang, Xinhui Bi, Yuesi Wang, Ping'an Peng, and Xinming Wang
Atmos. Chem. Phys., 20, 14581–14595, https://doi.org/10.5194/acp-20-14581-2020, https://doi.org/10.5194/acp-20-14581-2020, 2020
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We carried out a 1-year PM concurrent observation at 12 sites across six regions of China, and size-segregated PAHs were measured. We found both PAHs and BaPeq were concentrated in PM1.1, and northern China had higher PAHs' pollution and inhalation cancer risk than southern China. Nationwide increases in both PAH levels and inhalation cancer risk occurred in winter. We suggest reducing coal and biofuel consumption in the residential sector is an important option to mitigate PAHs' health risks.
Cited articles
Atkinson, R., Aschmann, S. M., Winer, A. M., and Pitts, J. N.: Kinetics of
the gas-phase reactions of NO3 radicals with a series of dialkenes,
cycloalkenes, and monoterpenes at 295
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic
volatile organic compounds: a review, Atmos. Environ., 37, S197–S219, https://doi.org/10.1016/s1352-2310(03)00391-1, 2003.
Ayres, J. G., Borm, P., Cassee, F. R., Castranova, V., Donaldson, K., Ghio,
A., Harrison, R. M., Hider, R., Kelly, F., Kooter, I. M., Marano, F.,
Maynard, R. L., Mudway, I., Nel, A., Sioutas, C., Smith, S., Baeza-Squiban,
A., Cho, A., Duggan, S., and Froines, J.: Evaluating the toxicity of
airborne particulate matter and nanoparticles by measuring oxidative stress
potential – A workshop report and consensus statement, Inhal.
Toxicol., 20, 75–99, https://doi.org/10.1080/08958370701665517, 2008.
Barmet, P., Dommen, J., DeCarlo, P. F., Tritscher, T., Praplan, A. P., Platt, S. M., Prévôt, A. S. H., Donahue, N. M., and Baltensperger, U.: OH clock determination by proton transfer reaction mass spectrometry at an environmental chamber, Atmos. Meas. Tech., 5, 647–656, https://doi.org/10.5194/amt-5-647-2012, 2012.
Barnes, I., Bastian, V., Becker, K. H., and Tong, Z.: Kinetics and Products
of the reactions of NO3 with monoalkene, dialkenes and monoterpenes,
J. Phys. Chem., 94, 2413–2419, https://doi.org/10.1021/j100369a041, 1990.
Bonn, B. and Moorgat, G. K.: New particle formation during a- and b-pinene oxidation by O3, OH and NO3, and the influence of water vapour: particle size distribution studies, Atmos. Chem. Phys., 2, 183–196, https://doi.org/10.5194/acp-2-183-2002, 2002.
Boyd, C. M., Sanchez, J., Xu, L., Eugene, A. J., Nah, T., Tuet, W. Y., Guzman, M. I., and Ng, N. L.: Secondary organic aerosol formation from the β-pinene+NO3 system: effect of humidity and peroxy radical fate, Atmos. Chem. Phys., 15, 7497–7522, https://doi.org/10.5194/acp-15-7497-2015, 2015.
Brown, S. S. and Stutz, J.: Nighttime radical observations and chemistry,
Chem. Soc. Rev., 41, 6405–6447, https://doi.org/10.1039/c2cs35181a, 2012.
Carter, W. P. L., Winer, A. M., and Pitts, J. N.: Major atmospheric sink for
phenol and the cresols. Reaction with the nitrate radical, Environ. Sci. Technol., 15, 829–831, https://doi.org/10.1021/es00089a009, 1981.
Chen, Q., Liu, Y., Donahue, N. M., Shilling, J. E., and Martin, S. T.:
Particle-phase chemistry of secondary Organic material: modeled compared to
measured O : C and H : C elemental ratios provide constraints, Environ. Sci. Technol., 45, 4763–4770, https://doi.org/10.1021/es104398s, 2011.
Chen, X. and Hopke, P. K.: A chamber study of secondary organic aerosol
formation by limonene ozonolysis, Indoor Air, 20, 320–328, https://doi.org/10.1111/j.1600-0668.2010.00656.x, 2010.
Chung, C. E., Ramanathan, V., and Decremer, D.: Observationally constrained
estimates of carbonaceous aerosol radiative forcing, P. Natl. Acad. Sci. USA, 109, 11624–11629, https://doi.org/10.1073/pnas.1203707109, 2012.
Claeys, M., Iinuma, Y., Szmigielski, R., Surratt, J. D., Blockhuys, F., Van
Alsenoy, C., Böge, O., Sierau, B., Gómez-González, Y.,
Vermeylen, R., Van der Veken, P., Shahgholi, M., Chan, A. W. H., Herrmann,
H., Seinfeld, J. H., and Maenhaut, W.: Terpenylic acid and related compounds
from the oxidation of α-pinene: implications for new particle
formation and growth above forests, Environ. Sci. Technol.,
43, 6976–6982, https://doi.org/10.1021/es9007596, 2009.
Clegg, S. L., Brimblecombe, P., and Wexler, A. S.: Thermodynamic model of
the system
H
Cocker, D. R., Clegg, S. L., Flagan, R. C., and Seinfeld, J. H.: The effect
of water on gas–particle partitioning of secondary organic aerosol. Part I:
α-pinene/ozone system, Atmos. Environ., 35, 6049–6072,
https://doi.org/10.1016/S1352-2310(01)00404-6, 2001.
Coeur-Tourneur, C., Henry, F., Janquin, M.-A., and Brutier, L.: Gas-phase
reaction of hydroxyl radicals with m-, o- and p-cresol, Int.
J. Chem. Kin., 38, 553–562, https://doi.org/10.1002/kin.20186, 2006.
Darer, A. I., Cole-Filipiak, N. C., O'Connor, A. E., and Elrod, M. J.:
Formation and stability of atmospherically relevant isoprene-derived
organosulfates and organonitrates, Environ. Sci. Technol.,
45, 1895–1902, https://doi.org/10.1021/es103797z, 2011.
Day, D. A., Liu, S., Russell, L. M., and Ziemann, P. J.: Organonitrate group
concentrations in submicron particles with high nitrate and organic
fractions in coastal southern California, Atmos. Environ., 44, 1970–1979, https://doi.org/10.1016/j.atmosenv.2010.02.045, 2010.
Dlugokencky, E. J. and Howard, C. J.: Studies of NO3 radical reacions
with some atmospheric organic-compounds at low pressures, J. Phys.
Chem., 93, 1091–1096, https://doi.org/10.1021/j100340a015, 1989.
Docherty, K. S., Wu, W., Lim, Y. B., and Ziemann, P. J.: Contributions of
organic peroxides to secondary aerosol formed from reactions of monoterpenes
with O3, Environ. Sci. Technol., 39, 4049–4059, https://doi.org/10.1021/es050228s, 2005.
Emanuelsson, E. U., Hallquist, M., Kristensen, K., Glasius, M., Bohn, B., Fuchs, H., Kammer, B., Kiendler-Scharr, A., Nehr, S., Rubach, F., Tillmann, R., Wahner, A., Wu, H.-C., and Mentel, Th. F.: Formation of anthropogenic secondary organic aerosol (SOA) and its influence on biogenic SOA properties, Atmos. Chem. Phys., 13, 2837–2855, https://doi.org/10.5194/acp-13-2837-2013, 2013.
Epstein, S. A., Blair, S. L., and Nizkorodov, S. A.: Direct photolysis of
α-pinene ozonolysis secondary organic aerosol: effect on particle
mass and peroxide content, Environ. Sci. Technol., 48,
11251–11258, https://doi.org/10.1021/es502350u, 2014.
Friedmann, B. and Farmer, D. K.: SOA and gas phase organic yields from the
sequential photooxidation of seven monoterpenes, Atmos. Environ., 187, 335–345,
2018.
Fry, J. L., Kiendler-Scharr, A., Rollins, A. W., Wooldridge, P. J., Brown, S. S., Fuchs, H., Dubé, W., Mensah, A., dal Maso, M., Tillmann, R., Dorn, H.-P., Brauers, T., and Cohen, R. C.: Organic nitrate and secondary organic aerosol yield from NO3 oxidation of β-pinene evaluated using a gas-phase kinetics/aerosol partitioning model, Atmos. Chem. Phys., 9, 1431–1449, https://doi.org/10.5194/acp-9-1431-2009, 2009.
Fry, J. L., Kiendler-Scharr, A., Rollins, A. W., Brauers, T., Brown, S. S., Dorn, H.-P., Dubé, W. P., Fuchs, H., Mensah, A., Rohrer, F., Tillmann, R., Wahner, A., Wooldridge, P. J., and Cohen, R. C.: SOA from limonene: role of NO3 in its generation and degradation, Atmos. Chem. Phys., 11, 3879–3894, https://doi.org/10.5194/acp-11-3879-2011, 2011.
Fry, J. L., Draper, D. C., Barsanti, K. C., Smith, J. N., Ortega, J.,
Winkle, P. M., Lawler, M. J., Brown, S. S., Edwards, P. M., Cohen, R. C.,
and Lee, L.: Secondary organic aerosol formation and organic nitrate yield
from NO3 oxidation of biogenic hydrocarbons, Environ. Sci. Technol., 48, 11944–11953, https://doi.org/10.1021/es502204x, 2014.
Fry, J. L., Brown, S. S., Middlebrook, A. M., Edwards, P. M., Campuzano-Jost, P., Day, D. A., Jimenez, J. L., Allen, H. M., Ryerson, T. B., Pollack, I., Graus, M., Warneke, C., de Gouw, J. A., Brock, C. A., Gilman, J., Lerner, B. M., Dubé, W. P., Liao, J., and Welti, A.: Secondary organic aerosol (SOA) yields from NO3 radical + isoprene based on nighttime aircraft power plant plume transects, Atmos. Chem. Phys., 18, 11663–11682, https://doi.org/10.5194/acp-18-11663-2018, 2018.
Gao, S., Ng, N. L., Keywood, M., Varutbangkul, V., Bahreini, R., Nenes, A.,
He, J., Yoo, K. Y., Beauchamp, J. L., Hodyss, R. P., Flagan, R. C., and
Seinfeld, J. H.: Particle phase acidity and oligomer formation in secondary
organic aerosol, Environ. Sci. Technol., 38, 6582–6589, https://doi.org/10.1021/es049125k, 2004.
Geyer, A., Alicke, B., Konrad, S., Schmitz, T., Stutz, J., and Platt, U.:
Chemistry and oxidation capacity of the nitrate radical in the continental
boundary layer near Berlin, J. Geophys. Res.-Atmos., 106, 8013–8025, https://doi.org/10.1029/2000jd900681, 2001.
Glasius, M. and Goldstein, A. H.: Recent discoveries and future challenges
in atmospheric organic chemistry, Environ. Sci. Technol., 50,
2754–2764, https://doi.org/10.1021/acs.est.5b05105, 2016.
Goldstein, A. H. and Galbally, I. E.: Known and Unexplored Organic Constituents in the Earth’s Atmosphere, Environ. Sci. Technol., 41, 1514–1521, https://doi.org/10.1021/es072476p, 2007.
Gong, Y., Chen, Z., and Li, H.: The oxidation regime and SOA composition in limonene ozonolysis: roles of different double bonds, radicals, and water, Atmos. Chem. Phys., 18, 15105–15123, https://doi.org/10.5194/acp-18-15105-2018, 2018.
Hallquist, M., Wangberg, I., Ljungstrom, E., Barnes, I., and Becker, K. H.:
Aerosol and product yields from NO3 radical-initiated oxidation of
selected monoterpenes, Environ. Sci. Technol., 33, 553–559, https://doi.org/10.1021/es980292s, 1999.
Hallquist, M., Wenger, J. C., Baltensperger, U., Rudich, Y., Simpson, D., Claeys, M., Dommen, J., Donahue, N. M., George, C., Goldstein, A. H., Hamilton, J. F., Herrmann, H., Hoffmann, T., Iinuma, Y., Jang, M., Jenkin, M. E., Jimenez, J. L., Kiendler-Scharr, A., Maenhaut, W., McFiggans, G., Mentel, Th. F., Monod, A., Prévôt, A. S. H., Seinfeld, J. H., Surratt, J. D., Szmigielski, R., and Wildt, J.: The formation, properties and impact of secondary organic aerosol: current and emerging issues, Atmos. Chem. Phys., 9, 5155–5236, https://doi.org/10.5194/acp-9-5155-2009, 2009.
Heald, C. L., Henze, D. K., Horowitz, L. W., Feddema, J., Lamarque, J.-F.,
Guenther, A., Hess, P. G., Vitt, F., Seinfeld, J. H., Goldstein, A. H., and
Fung, I.: Predicted change in global secondary organic aerosol
concentrations in response to future climate, emissions, and land use
change, J. Geophys. Res.-Atmos., 113, D05211, https://doi.org/10.1029/2007jd009092, 2008.
Healy, R. M., Temime, B., Kuprovskyte, K., and Wenger, J. C.: Effect of
relative humidity on gas/particle partitioning and aerosol mass yield in the
photooxidation of p-xylene, Environ. Sci. Technol., 43,
1884–1889, https://doi.org/10.1021/es802404z, 2009.
Herrmann, H.: Database of atmospheric simulation chamber studies, available at: https://data.eurochamp.org/data-access/chamber-experiments/#/, last access: 24 January 2020.
Herrmann, H., Ervens, B., Nowacki, P., Wolke, R., and Zellner, R.: A
chemical aqueous phase radical mechanism for tropospheric chemistry,
Chemosphere, 38, 1223-1232, https://doi.org/10.1016/S0045-6535(98)00520-7,
1999.
Hildebrandt, L., Donahue, N. M., and Pandis, S. N.: High formation of secondary organic aerosol from the photo-oxidation of toluene, Atmos. Chem. Phys., 9, 2973–2986, https://doi.org/10.5194/acp-9-2973-2009, 2009.
Hoffmann, D., Iinuma, Y., and Herrmann, H.: Development of a method for fast
analysis of phenolic molecular markers in biomass burning particles using
high performance liquid chromatography/atmospheric pressure chemical
ionisation mass spectrometry, J. Chromatogr.A, 1143, 168–175,
https://doi.org/10.1016/j.chroma.2007.01.035, 2007.
Horowitz, L. W., Fiore, A. M., Milly, G. P., Cohen, R. C., Perring, A.,
Wooldridge, P. J., Hess, P. G., Emmons, L. K., and Lamarque, J.-F.:
Observational constraints on the chemistry of isoprene nitrates over the
eastern United States, J. Geophys. Res.-Atmos., 112, D12S08, https://doi.org/10.1029/2006jd007747,
2007.
Hoyle, C. R., Berntsen, T., Myhre, G., and Isaksen, I. S. A.: Secondary organic aerosol in the global aerosol – chemical transport model Oslo CTM2, Atmos. Chem. Phys., 7, 5675–5694, https://doi.org/10.5194/acp-7-5675-2007, 2007.
Hu, K. S., Darer, A. I., and Elrod, M. J.: Thermodynamics and kinetics of the hydrolysis of atmospherically relevant organonitrates and organosulfates, Atmos. Chem. Phys., 11, 8307–8320, https://doi.org/10.5194/acp-11-8307-2011, 2011.
Iinuma, Y., Böge, O., Keywood, M., Gnauk, T., and Herrmann, H.:
Diaterebic acid acetate and diaterpenylic acid acetate: atmospheric tracers
for secondary organic aerosol formation from 1,8-cineole oxidation,
Environ. Sci. Technol., 43, 280–285, https://doi.org/10.1021/es802141v, 2009.
Iinuma, Y., Böge, O., Gräfe, R., and Herrmann, H.:
Methyl-nitrocatechols: atmospheric tracer compounds for biomass burning
secondary organic aerosols, Environ. Sci. Technol., 44,
8453–8459, https://doi.org/10.1021/es102938a, 2010.
Izumi, K. and Fukuyama, T.: Photochemical aerosol formation from aromatic
hydrocarbons in the presence of NOx, Atmos. Environ. A, 24, 1433–1441, https://doi.org/10.1016/0960-1686(90)90052-O,
1990.
Jacobs, M. I., Burke, W. J., and Elrod, M. J.: Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis, Atmos. Chem. Phys., 14, 8933–8946, https://doi.org/10.5194/acp-14-8933-2014, 2014.
Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric
degradation of volatile organic compounds: a protocol for mechanism
development, Atmos. Environ., 31, 81–104,
https://doi.org/10.1016/S1352-2310(96)00105-7, 1997.
Jiang, L., Wang, W., and Xu, Y.-S.: Theoretical investigation of the
NO3 radical addition to double bonds of limonene, Int. J. Mol. Sci., 10,
3743–3754, https://doi.org/10.3390/ijms10093743, 2009.
Joo, T., Rivera-Rios, J. C., Takeuchi, M., Alvarado, M. J., and Ng, N. L.:
Secondary organic aerosol formation from reaction of 3-methylfuran with
nitrate radicals, ACS Earth Space Chem., 3, 922–934, https://doi.org/10.1021/acsearthspacechem.9b00068, 2019.
Kiendler-Scharr, A., Mensah, A. A., Friese, E., Topping, D., Nemitz, E.,
Prevot, A. S. H., Aijala, M., Allan, J., Canonaco, F., Canagaratna, M.,
Carbone, S., Crippa, M., Dall Osto, M., Day, D. A., De Carlo, P., Di Marco,
C. F., Elbern, H., Eriksson, A., Freney, E., Hao, L., Herrmann, H.,
Hildebrandt, L., Hillamo, R., Jimenez, J. L., Laaksonen, A., McFiggans, G.,
Mohr, C., O'Dowd, C., Otjes, R., Ovadnevaite, J., Pandis, S. N., Poulain,
L., Schlag, P., Sellegri, K., Swietlicki, E., Tiitta, P., Vermeulen, A.,
Wahner, A., Worsnop, D., and Wu, H. C.: Ubiquity of organic nitrates from
nighttime chemistry in the European submicron aerosol, Geophys. Res.
Lett., 43, 7735–7744, https://doi.org/10.1002/2016gl069239, 2016.
Kind, I., Berndt, T., and Böge, O.: Gas-phase rate constants for the
reaction of NO3 radicals with a series of cyclic alkenes,
2-ethyl-1-butene and 2,3-dimethyl-1,3-butadiene, Chem. Phys. Lett.,
288, 111–118, https://doi.org/10.1016/s0009-2614(98)00254-1, 1998.
Krapf, M., El Haddad, I., Bruns, Emily A., Molteni, U., Daellenbach,
Kaspar R., Prévôt, André S. H., Baltensperger, U., and Dommen,
J.: Labile peroxides in secondary organic aerosol, Chem, 1, 603–616,
https://doi.org/10.1016/j.chempr.2016.09.007, 2016.
Kurtenbach, R., Ackermann, R., Becker, K. H., Geyer, A., Gomes, J. A. G.,
Lorzer, J. C., Platt, U., and Wiesen, P.: Verification of the contribution
of vehicular traffic to the total NMVOC emissions in Germany and the
importance of the NO3 chemistry in the city air, J. Atmos. Chem., 42,
395–411, https://doi.org/10.1023/a:1015778616796, 2002.
Kwan, A. J., Chan, A. W. H., Ng, N. L., Kjaergaard, H. G., Seinfeld, J. H., and Wennberg, P. O.: Peroxy radical chemistry and OH radical production during the NO3-initiated oxidation of isoprene, Atmos. Chem. Phys., 12, 7499–7515, https://doi.org/10.5194/acp-12-7499-2012, 2012.
Larsen, B. R., Di Bella, D., Glasius, M., Winterhalter, R., Jensen, N. R.,
and Hjorth, J.: Gas-phase OH oxidation of monoterpenes: gaseous and
particulate products, J. Atmos. Chem., 38, 231–276, https://doi.org/10.1023/A:1006487530903,
2001.
Lathière, J., Hauglustaine, D. A., De Noblet-Ducoudré, N., Krinner,
G., and Folberth, G. A.: Past and future changes in biogenic volatile
organic compound emissions simulated with a global dynamic vegetation model,
Geophys. Res. Lett., 32, L20818, https://doi.org/10.1029/2005gl024164, 2005.
Liebmann, J., Karu, E., Sobanski, N., Schuladen, J., Ehn, M., Schallhart, S., Quéléver, L., Hellen, H., Hakola, H., Hoffmann, T., Williams, J., Fischer, H., Lelieveld, J., and Crowley, J. N.: Direct measurement of NO3 radical reactivity in a boreal forest, Atmos. Chem. Phys., 18, 3799–3815, https://doi.org/10.5194/acp-18-3799-2018, 2018a.
Liebmann, J. M., Muller, J. B. A., Kubistin, D., Claude, A., Holla, R., Plass-Dülmer, C., Lelieveld, J., and Crowley, J. N.: Direct measurements of NO3 reactivity in and above the boundary layer of a mountaintop site: identification of reactive trace gases and comparison with OH reactivity, Atmos. Chem. Phys., 18, 12045–12059, https://doi.org/10.5194/acp-18-12045-2018, 2018b.
Lightfoot, P. D., Cox, R. A., Crowley, J. N., Destriau, M., Hayman, G. D.,
Jenkin, M. E., Moortgat, G. K., and Zabel, F.: Organic peroxy radicals:
kinetics, spectroscopy and tropospheric chemistry, Atmos. Environ.
Pt. A, 26, 1805–1961,
https://doi.org/10.1016/0960-1686(92)90423-I, 1992.
Lindinger, W., Hansel, A., and Jordan, A.: On-line monitoring of volatile
organic compounds at pptv levels by means of proton-transfer-reaction mass
spectrometry (PTR-MS) medical applications, food control and environmental
research, Int. J. Mass Spectrom., 173,
191–241, https://doi.org/10.1016/S0168-1176(97)00281-4, 1998.
Ma, Y., Willcox, T. R., Russell, A. T., and Marston, G.: Pinic and pinonic
acid formation in the reaction of ozone with α-pinene, Chem.
Commun., 1328–1330, https://doi.org/10.1039/B617130C, 2007.
Martinez, E., Cabanas, B., Aranda, A., and Martin, P.: Kinetics of the
reactions of NO3 radical with selected monoterpenes: A temperature
dependence study, Environ. Sci. Technol., 32, 3730–3734, https://doi.org/10.1021/es970899t, 1998.
Martinez, E., Cabanas, B., Aranda, A., Martin, P., and Salgado, S.: Absolute
rate coefficients for the gas-phase reactions of NO3 radical with a series
of monoterpenes at T= 298 to 433 K, J. Atmos. Chem., 33, 265–282, https://doi.org/10.1023/a:1006178530211, 1999.
McMurry, P. H. and Grosjean, D.: Gas and Aerosol Wall Losses in Teflon Film
Smog Chamber, Environ. Sci. Technol., 19, 1176–1182, 1985.
McLaren, R., Wojtal, P., Majonis, D., McCourt, J., Halla, J. D., and Brook, J.: NO3 radical measurements in a polluted marine environment: links to ozone formation, Atmos. Chem. Phys., 10, 4187–4206, https://doi.org/10.5194/acp-10-4187-2010, 2010.
Mertes, P., Pfaffenberger, L., Dommen, J., Kalberer, M., and Baltensperger, U.: Development of a sensitive long path absorption photometer to quantify peroxides in aerosol particles (Peroxide-LOPAP), Atmos. Meas. Tech., 5, 2339–2348, https://doi.org/10.5194/amt-5-2339-2012, 2012.
Moldanova, J. and Ljungstrom, E.: Modelling of particle formation from
NO3 oxidation of selected monoterpenes, J. Aerosol Sci.,
31, 1317–1333, https://doi.org/10.1016/s0021-8502(00)00041-0, 2000.
Moortgat, G. K., Veyret, B., and Lesclaux, R.: Kinetics of the reaction of
HO2 with CH3C(O)O2 in the temperature range 253–368 K,
Chem. Phys. Lett., 160, 443–447,
https://doi.org/10.1016/0009-2614(89)87624-9, 1989.
Müller, L., Reinnig, M.-C., Warnke, J., and Hoffmann, Th.: Unambiguous identification of esters as oligomers in secondary organic aerosol formed from cyclohexene and cyclohexene/α-pinene ozonolysis, Atmos. Chem. Phys., 8, 1423–1433, https://doi.org/10.5194/acp-8-1423-2008, 2008.
Mutzel, A., Rodigast, M., Iinuma, Y., Böge, O., and Herrmann, H.: An
improved method for the quantification of SOA bound peroxides, Atmos.
Environ., 67, 365–369, https://doi.org/10.1016/j.atmosenv.2012.11.012, 2013.
Mutzel, A., Poulain, L., Berndt, T., Iinuma, Y., Rodigast, M., Böge, O.,
Richters, S., Spindler, G., Sipilä, M., Jokinen, T., Kulmala, M., and
Herrmann, H.: Highly oxidized multifunctional organic compounds observed in
tropospheric particles: A field and laboratory study, Environ. Sci. Technol., 49, 7754–7761, https://doi.org/10.1021/acs.est.5b00885, 2015.
Mutzel, A., Rodigast, M., Iinuma, Y., Böge, O., and Herrmann, H.:
Monoterpene SOA – Contribution of first-generation oxidation products to
formation and chemical composition, Atmos. Environ., 130, 136–144,
https://doi.org/10.1016/j.atmosenv.2015.10.080, 2016.
Nah, T., Sanchez, J., Boyd, C. M., and Ng, N. L.: Photochemical aging of
alpha-pinene and beta-pinene secondary organic aerosol formed from nitrate
radical oxidation, Environ. Sci. Technol., 50, 222–231, https://doi.org/10.1021/acs.est.5b04594, 2016.
Nakao, S., Clark, C., Tang, P., Sato, K., and Cocker III, D.: Secondary organic aerosol formation from phenolic compounds in the absence of NOx, Atmos. Chem. Phys., 11, 10649–10660, https://doi.org/10.5194/acp-11-10649-2011, 2011.
Neusüß, C., Gnauk, T., Plewka, A., Herrmann, H., and Quinn, P. K.:
Carbonaceous aerosol over the Indian Ocean: OC
Ng, N. L., Kroll, J. H., Keywood, M. D., Bahreini, R., Varutbangkul, V.,
Flagan, R. C., Seinfeld, J. H., Lee, A., and Goldstein, A. H.: Contribution
of First- versus Second-Generation Products to Secondary Organic Aerosols
Formed in the Oxidation of Biogenic Hydrocarbons, Environ. Sci. Technol., 40, 2283–2297, https://doi.org/10.1021/es052269u, 2006.
Ng, N. L., Chhabra, P. S., Chan, A. W. H., Surratt, J. D., Kroll, J. H., Kwan, A. J., McCabe, D. C., Wennberg, P. O., Sorooshian, A., Murphy, S. M., Dalleska, N. F., Flagan, R. C., and Seinfeld, J. H.: Effect of NOx level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes, Atmos. Chem. Phys., 7, 5159–5174, https://doi.org/10.5194/acp-7-5159-2007, 2007.
Ng, N. L., Brown, S. S., Archibald, A. T., Atlas, E., Cohen, R. C., Crowley, J. N., Day, D. A., Donahue, N. M., Fry, J. L., Fuchs, H., Griffin, R. J., Guzman, M. I., Herrmann, H., Hodzic, A., Iinuma, Y., Jimenez, J. L., Kiendler-Scharr, A., Lee, B. H., Luecken, D. J., Mao, J., McLaren, R., Mutzel, A., Osthoff, H. D., Ouyang, B., Picquet-Varrault, B., Platt, U., Pye, H. O. T., Rudich, Y., Schwantes, R. H., Shiraiwa, M., Stutz, J., Thornton, J. A., Tilgner, A., Williams, B. J., and Zaveri, R. A.: Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol, Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, 2017.
Niki, H., Maker, P. D., Savage, C. M., and Breitenbach, L. P.: FTIR study of
the kinetics and mechanism for chlorine-atom-initiated reactions of
acetaldehyde, J. Phys. Chem., 89, 588–591, https://doi.org/10.1021/j100250a008, 1985.
Northcross, A. L. and Jang, M.: Heterogeneous SOA yield from ozonolysis of
monoterpenes in the presence of inorganic acid, Atmos. Environ., 41,
1483–1493, https://doi.org/10.1016/j.atmosenv.2006.10.009, 2007.
Odum, J. R., Hoffmann, T., Bowman, F., Collins, D., Flagan, R. C., and
Seinfeld, J. H.: Gas/particle partitioning and secondary organic aerosol
yields, Environ. Sci. Technol., 30, 2580–2585, https://doi.org/10.1021/es950943+, 1996.
Perraud, V., Bruns, E. A., Ezell, M. J., Johnson, S. N., Greaves, J., and
Finlayson-Pitts, B. J.: Identification of organic nitrates in the NO3
radical initiated oxidation of alpha-pinene by atmospheric pressure chemical
ionization mass spectrometry, Environ. Sci. Technol., 44,
5887–5893, https://doi.org/10.1021/es1005658, 2010.
Presto, A. A., Huff Hartz, K. E., and Donahue, N. M.: Secondary organic
aerosol production from terpene ozonolysis. 2. Effect of NOx
concentration, Environ. Sci. Technol., 39, 7046–7054, https://doi.org/10.1021/es050400s, 2005.
Pye, H. O. T., Chan, A. W. H., Barkley, M. P., and Seinfeld, J. H.: Global modeling of organic aerosol: the importance of reactive nitrogen (NOx and NO3), Atmos. Chem. Phys., 10, 11261–11276, https://doi.org/10.5194/acp-10-11261-2010, 2010.
Qin, M. M., Hu, Y. T., Wang, X. S., Vasilakos, P., Boyd, C. M., Xu, L.,
Song, Y., Ng, N. L., Nenes, A., and Russell, A. G.: Modeling biogenic
secondary organic aerosol (BSOA) formation from monoterpene reactions with
NO3: A case study of the SOAS campaign using CMAQ, Atmos. Environ.,
184, 146–155, https://doi.org/10.1016/j.atmosenv.2018.03.042, 2018.
Ramasamy, S., Nakayama, T., Imamura, T., Morino, Y., Kajii, Y., and Sato, K.: Investigation of dark condition nitrate radical-and ozone-initiated aging of toluene secondary organic aerosol: Importance of nitrate radical reactions with phenolic products, Atmos. Environ., 219, 117049, https://doi.org/10.1016/j.atmosenv.2019.117049, 2019.
Rindelaub, J. D., McAvey, K. M., and Shepson, P. B.: The photochemical
production of organic nitrates from alpha-pinene and loss via acid-dependent
particle phase hydrolysis, Atmos. Environ., 100, 193–201, https://doi.org/10.1016/j.atmosenv.2014.11.010, 2015.
Rollins, A. W., Smith, J. D., Wilson, K. R., and Cohen, R. C.: Real time in
situ detection of organic nitrates in atmospheric aerosols, Environ. Sci. Technol., 44, 5540–5545, https://doi.org/10.1021/es100926x, 2010.
Romano, A. and Hanna, G. B.: Identification and quantification of VOCs by
proton transfer reaction time of flight mass spectrometry: An experimental
workflow for the optimization of specificity, sensitivity, and accuracy, J.
Mass Spectrom., 53, 287–295, https://doi.org/10.1002/jms.4063, 2018.
Sanderson, M. G., Jones, C. D., Collins, W. J., Johnson, C. E., and Derwent,
R. G.: Effect of climate change on isoprene emissions and surface ozone
levels, Geophys. Res. Lett., 30, 1936, https://doi.org/10.1029/2003gl017642, 2003.
Saunders, S. M., Jenkin, M. E., Derwent, R. G., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 161–180, https://doi.org/10.5194/acp-3-161-2003, 2003.
Schwantes, R. H., Teng, A. P., Nguyen, T. B., Coggon, M. M., Crounse, J. D.,
St Clair, J. M., Zhang, X., Schilling, K. A., Seinfeld, J. H., and Wennberg,
P. O.: Isoprene NO3 oxidation products from the RO2 + HO2 pathway, J. Phys. Chem. A, 119, 10158–10171, https://doi.org/10.1021/acs.jpca.5b06355, 2015.
Schwartz, J., Laden, F., and Zanobetti, A.: The concentration-response
relation between PM2.5 and daily deaths, Environ. Health Persp., 110, 1025–1029, https://doi.org/10.1289/ehp.021101025, 2002.
Seinfeld, J., Erdakos, G., Asher, W., and Pankow, J.: Modeling the formation
of secondary organic aerosol (SOA). 2. The predicted effects of relative
humidity on aerosol formation in the alpha-pinene-, beta-pinene-, sabinene-,
delta 3-carene-, and cyclohexene-ozone systems, Environ. Sci.
Technol., 35, 1806–1817, 2001.
Shrivastava, M., Cappa, C. D., Fan, J., Goldstein, A. H., Guenther, A. B.,
Jimenez, J. L., Kuang, C., Laskin, A., Martin, S. T., Ng, N. L., Petaja, T.,
Pierce, J. R., Rasch, P. J., Roldin, P., Seinfeld, J. H., Shilling, J.,
Smith, J. N., Thornton, J. A., Volkamer, R., Wang, J., Worsnop, D. R.,
Zaveri, R. A., Zelenyuk, A., and Zhang, Q.: Recent advances in understanding
secondary organic aerosol: Implications for global climate forcing, Rev.
Geophys. 55, 509–559, https://doi.org/10.1002/2016rg000540, 2017.
Slade, J. H. and Knopf, D. A.: Multiphase OH oxidation kinetics of organic
aerosol: The role of particle phase state and relative humidity, Geophys.
Res. Lett., 41, 5297–5306, https://doi.org/10.1002/2014gl060582, 2014.
Spindler, G., Müller, K., Brüggemann, E., Gnauk, T., and Herrmann,
H.: Long-term size-segregated characterization of PM10, PM2.5,
and PM1 at the IfT research station Melpitz downwind of Leipzig
(Germany) using high and low-volume filter samplers, Atmos. Environ., 38,
5333–5347, https://doi.org/10.1016/j.atmosenv.2003.12.047, 2004.
Spittler, M., Barnes, I., Bejan, I., Brockmann, K. J., Benter, T., and
Wirtz, K.: Reactions of NO3 radicals with limonene and alpha-pinene:
Product and SOA formation, Atmos. Environ., 40, S116–S127, https://doi.org/10.1016/j.atmosenv.2005.09.093, 2006.
Squadrito, G. L., Cueto, R., Dellinger, B., and Pryor, W. A.: Quinoid redox
cycling as a mechanism for sustained free radical generation by inhaled
airborne particulate matter, Free Radical Bio. Med., 31,
1132–1138, https://doi.org/10.1016/S0891-5849(01)00703-1, 2001.
Stewart, D. J., Almabrok, S. H., Lockhart, J. P., Mohamed, O. M., Nutt, D.
R., Pfrang, C., and Marston, G.: The kinetics of the gas-phase reactions of
selected monoterpenes and cyclo-alkenes with ozone and the NO3 radical,
Atmos. Environ., 70, 227–235, https://doi.org/10.1016/j.atmosenv.2013.01.036, 2013.
Szmigielski, R., Surratt, J., Gomez-Gonzalez, Y., Veken, P., Kourtchev, I.,
Vermeylen, R., Blockhuys, F., Jaoui, M., Kleindienst, T., Lewandowski, M.,
Offenberg, J., Edney, E., Seinfeld, J., Maenhaut, W., and Claeys, M.:
3-Methyl-1,2,3-butanetricarboxylic acid: An atmospheric tracer for terpene
secondary organic aerosol, Geophys. Res. Lett., 34, L24811, https://doi.org/10.1029/2007gl031338, 2007.
Timonen, H., Aurela, M., Carbone, S., Saarnio, K., Saarikoski, S., Mäkelä, T., Kulmala, M., Kerminen, V.-M., Worsnop, D. R., and Hillamo, R.: High time-resolution chemical characterization of the water-soluble fraction of ambient aerosols with PILS-TOC-IC and AMS, Atmos. Meas. Tech., 3, 1063–1074, https://doi.org/10.5194/amt-3-1063-2010, 2010.
Tolocka, M. P., Jang, M., Ginter, J. M., Cox, F. J., Kamens, R. M., and
Johnston, M. V.: Formation of oligomers in secondary organic aerosol,
Environ. Sci. Technol., 38, 1428–1434, https://doi.org/10.1021/es035030r,
2004.
van Pinxteren, D., Brüggemann, E., Gnauk, T., Iinuma, Y., Müller,
K., Nowak, A., Achtert, P., Wiedensohler, A., and Herrmann, H.: Size- and
time-resolved chemical particle characterization during CAREBeijing-2006:
Different pollution regimes and diurnal profiles, J. Geophys.
Res.-Atmos., 114, D00G09, https://doi.org/10.1029/2008jd010890, 2009.
Vöhringer-Martinez, E., Hansmann, B., Hernandez, H., Francisco, J. S.,
Troe, J., and Abel, B.: Water catalysis of a radical-molecule gas-phase
reaction, Science, 315, 497–501, https://doi.org/10.1126/science.1134494, 2007.
von Kuhlmann, R., Lawrence, M. G., Pöschl, U., and Crutzen, P. J.: Sensitivities in global scale modeling of isoprene, Atmos. Chem. Phys., 4, 1–17, https://doi.org/10.5194/acp-4-1-2004, 2004.
Wang, Y., Kim, H., and Paulson, S. E.: Hydrogen peroxide generation from
α- and β-pinene and toluene secondary organic aerosols,
Atmos. Environ., 45, 3149–3156,
https://doi.org/10.1016/j.atmosenv.2011.02.060, 2011.
Wayne, R. P., Barnes, I., Biggs, P., Burrows, J. P., Canosa-Mas, C. E.,
Hjorth, J., Lebras, G., Moortgat, G. K., Perner, D., Poulet, G., Restelli,
G., and Sidebottom, H.: The nitrate radical – physics, chemistry, and the
atmosphere, Atmos. Environ. Pt. A, 25, 1–203, https://doi.org/10.1016/0960-1686(91)90192-a, 1991.
Wiedensohler, A., Birmili, W., Nowak, A., Sonntag, A., Weinhold, K., Merkel, M., Wehner, B., Tuch, T., Pfeifer, S., Fiebig, M., Fjäraa, A. M., Asmi, E., Sellegri, K., Depuy, R., Venzac, H., Villani, P., Laj, P., Aalto, P., Ogren, J. A., Swietlicki, E., Williams, P., Roldin, P., Quincey, P., Hüglin, C., Fierz-Schmidhauser, R., Gysel, M., Weingartner, E., Riccobono, F., Santos, S., Grüning, C., Faloon, K., Beddows, D., Harrison, R., Monahan, C., Jennings, S. G., O'Dowd, C. D., Marinoni, A., Horn, H.-G., Keck, L., Jiang, J., Scheckman, J., McMurry, P. H., Deng, Z., Zhao, C. S., Moerman, M., Henzing, B., de Leeuw, G., Löschau, G., and Bastian, S.: Mobility particle size spectrometers: harmonization of technical standards and data structure to facilitate high quality long-term observations of atmospheric particle number size distributions, Atmos. Meas. Tech., 5, 657–685, https://doi.org/10.5194/amt-5-657-2012, 2012.
Xiao, G. G., Wang, M. Y., Li, N., Loo, J. A., and Nel, A. E.: Use of
proteomics to demonstrate a hierarchical oxidative stress response to diesel
exhaust particle chemicals in a macrophage cell line, J. Biol. Chem., 278,
50781–50790, https://doi.org/10.1074/jbc.M306423200, 2003.
Xu, L., Guo, H., Boyd, C. M., Klein, M., Bougiatioti, A., Cerully, K. M.,
Hite, J. R., Isaacman-Van Wertz, G., Kreisberg, N. M., Knote, C., Olson, K.,
Koss, A., Goldstein, A. H., Hering, S. V., de Gouw, J., Baumann, K., Lee,
S.-H., Nenes, A., Weber, R. J., and Ng, N. L.: Effects of anthropogenic
emissions on aerosol formation from isoprene and monoterpenes in the
southeastern United States, P. Natl. Acad. Sci. USA, 112, 37–42, https://doi.org/10.1073/pnas.1417609112, 2015.
Yasmeen, F., Vermeylen, R., Szmigielski, R., Iinuma, Y., Böge, O., Herrmann, H., Maenhaut, W., and Claeys, M.: Terpenylic acid and related compounds: precursors for dimers in secondary organic aerosol from the ozonolysis of α- and β-pinene, Atmos. Chem. Phys., 10, 9383–9392, https://doi.org/10.5194/acp-10-9383-2010, 2010.
Zaveri, R. A., Berkowitz, C. M., Brechtel, F. J., Gilles, M. K., Hubbe, J.
M., Jayne, J. T., Kleinman, L. I., Laskin, A., Madronich, S., Onasch, T. B.,
Pekour, M. S., Springston, S. R., Thornton, J. A., Tivanski, A. V., and
Worsnop, D. R.: Nighttime chemical evolution of aerosol and trace gases in a
power plant plume: Implications for secondary organic nitrate and
organosulfate aerosol formation, NO3 radical chemistry, and
N2O5 heterogeneous hydrolysis, J. Geophys. Res.-Atmos., 115, D12304, https://doi.org/10.1029/2009jd013250, 2010.
Zhao, D., Schmitt, S. H., Wang, M., Acir, I.-H., Tillmann, R., Tan, Z., Novelli, A., Fuchs, H., Pullinen, I., Wegener, R., Rohrer, F., Wildt, J., Kiendler-Scharr, A., Wahner, A., and Mentel, T. F.: Effects of NOx and SO2 on the secondary organic aerosol formation from photooxidation of α-pinene and limonene, Atmos. Chem. Phys., 18, 1611–1628, https://doi.org/10.5194/acp-18-1611-2018, 2018.
Short summary
This study investigates secondary organic aerosol (SOA) formation and particle growth from α-pinene, limonene, and m-cresol oxidation through NO3 and OH radicals and the effect of relative humidity. The formed SOA is comprehensively characterized with respect to the content of OC / EC, WSOC, SOA-bound peroxides, and SOA marker compounds. The findings present new insights and implications of nighttime chemistry, which can form SOA more efficiently than OH radical reaction during daytime.
This study investigates secondary organic aerosol (SOA) formation and particle growth from...
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