Articles | Volume 20, issue 24
https://doi.org/10.5194/acp-20-15835-2020
https://doi.org/10.5194/acp-20-15835-2020
Research article
 | 
19 Dec 2020
Research article |  | 19 Dec 2020

Influence of aerosol copper on HO2 uptake: a novel parameterized equation

Huan Song, Xiaorui Chen, Keding Lu, Qi Zou, Zhaofeng Tan, Hendrik Fuchs, Alfred Wiedensohler, Daniel R. Moon, Dwayne E. Heard, María-Teresa Baeza-Romero, Mei Zheng, Andreas Wahner, Astrid Kiendler-Scharr, and Yuanhang Zhang

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Cited articles

Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013. 
Berkemeier, T., Steimer, S. S., Krieger, U. K., Peter, T., Pöschl, U., Ammann, M., and Shiraiwa, M.: Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry, Phys. Chem. Chem. Phys., 18, 12662–12674, 2016. 
Bian, Y. X., Zhao, C. S., Ma, N., Chen, J., and Xu, W. Y.: A study of aerosol liquid water content based on hygroscopicity measurements at high relative humidity in the North China Plain, Atmos. Chem. Phys., 14, 6417–6426, https://doi.org/10.5194/acp-14-6417-2014, 2014. 
Bielski, B. H., Cabelli, D. E., Arudi, R. L., and Ross, A. B.: Reactivity of HO2/O2- radicals in aqueous solution, Journal of physical and chemical reference data, 14, 1041–1100, 1985. 
Capps, S. L., Henze, D. K., Hakami, A., Russell, A. G., and Nenes, A.: ANISORROPIA: the adjoint of the aerosol thermodynamic model ISORROPIA, Atmos. Chem. Phys., 12, 527–543, https://doi.org/10.5194/acp-12-527-2012, 2012. 
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Accurate calculation of the HO2 uptake coefficient is one of the key parameters to quantify the co-reduction of both aerosol and ozone pollution. We modelled various lab measurements of γHO2 based on a gas-liquid phase kinetic model and developed a state-of-the-art parameterized equation. Based on a dataset from a comprehensive field campaign in the North China Plain, we proposed that the determination of the heterogeneous uptake process for HO2 should be included in future field campaigns.
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