Articles | Volume 23, issue 5
https://doi.org/10.5194/acp-23-3233-2023
https://doi.org/10.5194/acp-23-3233-2023
Research article
 | 
13 Mar 2023
Research article |  | 13 Mar 2023

Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity

Yiqun Lu, Yingge Ma, Dan Dan Huang, Shengrong Lou, Sheng'ao Jing, Yaqin Gao, Hongli Wang, Yanjun Zhang, Hui Chen, Yunhua Chang, Naiqiang Yan, Jianmin Chen, Christian George, Matthieu Riva, and Cheng Huang

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N-containing oxygenated organic molecules have been identified as important precursors of aerosol particles. We used an ultra-high-resolution mass spectrometer coupled with an online sample inlet to accurately measure their molecular composition, concentration level and variation patterns. We show their formation process and influencing factors in a Chinese megacity involving various volatile organic compound precursors and atmospheric oxidants, and we highlight the influence of PM2.5 episodes.
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