Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

IF value: 5.414
IF5.414
IF 5-year value: 5.958
IF 5-year
5.958
CiteScore value: 9.7
CiteScore
9.7
SNIP value: 1.517
SNIP1.517
IPP value: 5.61
IPP5.61
SJR value: 2.601
SJR2.601
Scimago H <br class='widget-line-break'>index value: 191
Scimago H
index
191
h5-index value: 89
h5-index89
Volume 15, issue 12
Atmos. Chem. Phys., 15, 6745–6765, 2015
https://doi.org/10.5194/acp-15-6745-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: The Pan European Gas-Aerosols Climate Interaction Study...

Atmos. Chem. Phys., 15, 6745–6765, 2015
https://doi.org/10.5194/acp-15-6745-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 18 Jun 2015

Research article | 18 Jun 2015

Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes – deduced from structure–product relationships

T. F. Mentel et al.

Related authors

Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates
Iida Pullinen, Sebastian Schmitt, Sungah Kang, Mehrnaz Sarrafzadeh, Patrick Schlag, Stefanie Andres, Einhard Kleist, Thomas F. Mentel, Franz Rohrer, Monika Springer, Ralf Tillmann, Jürgen Wildt, Cheng Wu, Defeng Zhao, Andreas Wahner, and Astrid Kiendler-Scharr
Atmos. Chem. Phys., 20, 10125–10147, https://doi.org/10.5194/acp-20-10125-2020,https://doi.org/10.5194/acp-20-10125-2020, 2020
Short summary
Chemical characterisation of benzene oxidation products under high and low NOx conditions using chemical ionisation mass spectrometry
Michael Priestley, Thomas J. Bannan, Michael Le Breton, Stephen D. Worrall, Sungah Kang, Iida Pullinen, Sebastian Schmitt, Ralf Tillmann, Einhard Kleist, Defeng Zhao, Jürgen Wildt, Olga Garmash, Archit Mehra, Asan Bacak, Dudley E. Shallcross, Åsa Halquist, Mikael Ehn, Astrid Kiendler-Scharr, Thomas F. Mentel, Gordon McFiggans, Mattias Halquist, Hugh Coe, and Carl J. Percival
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-819,https://doi.org/10.5194/acp-2020-819, 2020
Preprint under review for ACP
Short summary
Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics
Olga Garmash, Matti P. Rissanen, Iida Pullinen, Sebastian Schmitt, Oskari Kausiala, Ralf Tillmann, Defeng Zhao, Carl Percival, Thomas J. Bannan, Michael Priestley, Åsa M. Hallquist, Einhard Kleist, Astrid Kiendler-Scharr, Mattias Hallquist, Torsten Berndt, Gordon McFiggans, Jürgen Wildt, Thomas F. Mentel, and Mikael Ehn
Atmos. Chem. Phys., 20, 515–537, https://doi.org/10.5194/acp-20-515-2020,https://doi.org/10.5194/acp-20-515-2020, 2020
Short summary
Effect of NOx on 1,3,5-trimethylbenzene (TMB) oxidation product distribution and particle formation
Epameinondas Tsiligiannis, Julia Hammes, Christian Mark Salvador, Thomas F. Mentel, and Mattias Hallquist
Atmos. Chem. Phys., 19, 15073–15086, https://doi.org/10.5194/acp-19-15073-2019,https://doi.org/10.5194/acp-19-15073-2019, 2019
Short summary
Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS
Julia Hammes, Anna Lutz, Thomas Mentel, Cameron Faxon, and Mattias Hallquist
Atmos. Chem. Phys., 19, 13037–13052, https://doi.org/10.5194/acp-19-13037-2019,https://doi.org/10.5194/acp-19-13037-2019, 2019
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Determination of the absorption cross sections of higher-order iodine oxides at 355 and 532 nm
Thomas R. Lewis, Juan Carlos Gómez Martín, Mark A. Blitz, Carlos A. Cuevas, John M. C. Plane, and Alfonso Saiz-Lopez
Atmos. Chem. Phys., 20, 10865–10887, https://doi.org/10.5194/acp-20-10865-2020,https://doi.org/10.5194/acp-20-10865-2020, 2020
Short summary
Evolution of NO3 reactivity during the oxidation of isoprene
Patrick Dewald, Jonathan M. Liebmann, Nils Friedrich, Justin Shenolikar, Jan Schuladen, Franz Rohrer, David Reimer, Ralf Tillmann, Anna Novelli, Changmin Cho, Kangming Xu, Rupert Holzinger, François Bernard, Li Zhou, Wahid Mellouki, Steven S. Brown, Hendrik Fuchs, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 10459–10475, https://doi.org/10.5194/acp-20-10459-2020,https://doi.org/10.5194/acp-20-10459-2020, 2020
Short summary
Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique
Jacob T. Shaw, Andrew R. Rickard, Mike J. Newland, and Terry J. Dillon
Atmos. Chem. Phys., 20, 9725–9736, https://doi.org/10.5194/acp-20-9725-2020,https://doi.org/10.5194/acp-20-9725-2020, 2020
Short summary
Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and (1E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen
Atmos. Chem. Phys., 20, 8939–8951, https://doi.org/10.5194/acp-20-8939-2020,https://doi.org/10.5194/acp-20-8939-2020, 2020
Short summary
The nitrogen budget of laboratory-simulated western US wildfires during the FIREX 2016 Fire Lab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys., 20, 8807–8826, https://doi.org/10.5194/acp-20-8807-2020,https://doi.org/10.5194/acp-20-8807-2020, 2020
Short summary

Cited articles

Berndt, T., Böge, O., Stratmann, F., Heintzenberg, J., and Kulmala, M.: Rapid formation of sulfuric acid particles at near-atmospheric conditions, Science, 307, 698–700, https://doi.org/10.1126/science.1104054, 2005.
Bzdek, B. R., Horan, A. J., Pennington, M. R., DePalma, J. W., Zhao, J., Jen, C. N., Hanson, D. R., Smith, J. N., McMurry, P. H., and Johnston, M. V.: Quantitative and time-resolved nanoparticle composition measurements during new particle formation, Farad. Discuss., 165, 25–43, https://doi.org/10.1039/c3fd00039g, 2013.
Cox, R. A. and Cole, J. A.: Chemical aspects of the autoignition of hydrocarbon-air mixtures, Combustion Flame, 60, 109–123, https://doi.org/10.1016/0010-2180(85)90001-x, 1985.
Crounse, J. D., Paulot, F., Kjaergaard, H. G., and Wennberg, P. O.: Peroxy radical isomerization in the oxidation of isoprene, Phys. Chem. Chem. Phys., 13, 13607–13613, https://doi.org/10.1039/c1cp21330j, 2011.
Publications Copernicus
Download
Short summary
We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the structural pre-requisites and chemical pathways to the recently discovered class of highly oxidized molecules ELVOC (Ehn et al., Nature, 2014). ELVOC may totally change the view on (parts of) the mechanism of SOA formation. We present results which support recent observations of H shifts from C-H to peroxy radicals, highlighting the pivotal role of peroxyradicals in organic atmospheric chemistry.
We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the...
Citation
Altmetrics
Final-revised paper
Preprint