Articles | Volume 15, issue 12
Atmos. Chem. Phys., 15, 6745–6765, 2015
https://doi.org/10.5194/acp-15-6745-2015

Special issue: The Pan European Gas-Aerosols Climate Interaction Study...

Atmos. Chem. Phys., 15, 6745–6765, 2015
https://doi.org/10.5194/acp-15-6745-2015

Research article 18 Jun 2015

Research article | 18 Jun 2015

Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes – deduced from structure–product relationships

T. F. Mentel et al.

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Cited articles

Berndt, T., Böge, O., Stratmann, F., Heintzenberg, J., and Kulmala, M.: Rapid formation of sulfuric acid particles at near-atmospheric conditions, Science, 307, 698–700, https://doi.org/10.1126/science.1104054, 2005.
Bzdek, B. R., Horan, A. J., Pennington, M. R., DePalma, J. W., Zhao, J., Jen, C. N., Hanson, D. R., Smith, J. N., McMurry, P. H., and Johnston, M. V.: Quantitative and time-resolved nanoparticle composition measurements during new particle formation, Farad. Discuss., 165, 25–43, https://doi.org/10.1039/c3fd00039g, 2013.
Cox, R. A. and Cole, J. A.: Chemical aspects of the autoignition of hydrocarbon-air mixtures, Combustion Flame, 60, 109–123, https://doi.org/10.1016/0010-2180(85)90001-x, 1985.
Crounse, J. D., Paulot, F., Kjaergaard, H. G., and Wennberg, P. O.: Peroxy radical isomerization in the oxidation of isoprene, Phys. Chem. Chem. Phys., 13, 13607–13613, https://doi.org/10.1039/c1cp21330j, 2011.
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We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the structural pre-requisites and chemical pathways to the recently discovered class of highly oxidized molecules ELVOC (Ehn et al., Nature, 2014). ELVOC may totally change the view on (parts of) the mechanism of SOA formation. We present results which support recent observations of H shifts from C-H to peroxy radicals, highlighting the pivotal role of peroxyradicals in organic atmospheric chemistry.
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