Articles | Volume 15, issue 12
https://doi.org/10.5194/acp-15-6745-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-6745-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes – deduced from structure–product relationships
Institut für Energie- und Klimaforschung, IEK-8, Forschungszentrum Jülich, Jülich, Germany
M. Springer
Institut für Energie- und Klimaforschung, IEK-8, Forschungszentrum Jülich, Jülich, Germany
Institut für Energie- und Klimaforschung, IEK-8, Forschungszentrum Jülich, Jülich, Germany
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
E. Kleist
Institut für Bio- und Geowissenschaften, IBG-2, Forschungszentrum Jülich, Jülich, Germany
I. Pullinen
Institut für Energie- und Klimaforschung, IEK-8, Forschungszentrum Jülich, Jülich, Germany
T. Kurtén
Department of Chemistry, University of Helsinki, 00014 Helsinki, Finland
M. Rissanen
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
A. Wahner
Institut für Energie- und Klimaforschung, IEK-8, Forschungszentrum Jülich, Jülich, Germany
J. Wildt
Institut für Bio- und Geowissenschaften, IBG-2, Forschungszentrum Jülich, Jülich, Germany
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- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
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- Synthesis, Electronic Spectroscopy, and Photochemistry of Methacrolein Oxide: A Four-Carbon Unsaturated Criegee Intermediate from Isoprene Ozonolysis M. Vansco et al. 10.1021/jacs.9b05193
- Highly Oxygenated Multifunctional Compounds in α-Pinene Secondary Organic Aerosol X. Zhang et al. 10.1021/acs.est.6b06588
- Speciated Monitoring of Gas-Phase Organic Peroxy Radicals by Chemical Ionization Mass Spectrometry: Cross-Reactions between CH3O2, CH3(CO)O2, (CH3)3CO2, and c-C6H11O2 B. Nozière & D. Hanson 10.1021/acs.jpca.7b06456
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Functional Group Composition of Secondary Organic Aerosol Formed from Ozonolysis of α-Pinene Under High VOC and Autoxidation Conditions M. Claflin et al. 10.1021/acsearthspacechem.8b00117
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- PTR3: An Instrument for Studying the Lifecycle of Reactive Organic Carbon in the Atmosphere M. Breitenlechner et al. 10.1021/acs.analchem.6b05110
- The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system P. Roldin et al. 10.1038/s41467-019-12338-8
- Experimental and computational investigation of vinoxy and 1-methylvinoxy radicals from the unimolecular decay of alkyl-substituted Criegee intermediates V. Barber et al. 10.1016/j.cplett.2020.137478
- Detection of RO2 radicals and other products from cyclohexene ozonolysis with NH4+ and acetate chemical ionization mass spectrometry A. Hansel et al. 10.1016/j.atmosenv.2018.04.023
- An aldehyde as a rapid source of secondary aerosol precursors: theoretical and experimental study of hexanal autoxidation S. Barua et al. 10.5194/acp-23-10517-2023
- Effect of Ozone Concentration and Relative Humidity on the Heterogeneous Oxidation of Linoleic Acid Particles by Ozone: An Insight into the Interchangeability of Ozone Concentration and Time Y. Chu et al. 10.1021/acsearthspacechem.9b00002
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Four-Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production V. Barber et al. 10.1021/jacs.8b06010
- New particle formation in the free troposphere: A question of chemistry and timing F. Bianchi et al. 10.1126/science.aad5456
- Decrease in radiative forcing by organic aerosol nucleation, climate, and land use change J. Zhu et al. 10.1038/s41467-019-08407-7
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Additional chain-branching pathways in the low-temperature oxidation of branched alkanes Z. Wang et al. 10.1016/j.combustflame.2015.11.035
- Molecular corridors and parameterizations of volatility in the chemical evolution of organic aerosols Y. Li et al. 10.5194/acp-16-3327-2016
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
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- Accurate identification of dimers from α‐pinene oxidation using high‐resolution collision‐induced dissociation mass spectrometry K. Sekimoto et al. 10.1002/jms.4508
- Biogenic secondary organic aerosols: A review on formation mechanism, analytical challenges and environmental impacts M. Mahilang et al. 10.1016/j.chemosphere.2020.127771
- Control of ozonolysis kinetics and aerosol yield by nuances in the molecular structure of volatile organic compounds R. Harvey & G. Petrucci 10.1016/j.atmosenv.2015.09.038
- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Primary Formation of Highly Oxidized Multifunctional Products in the OH-Initiated Oxidation of Isoprene: A Combined Theoretical and Experimental Study S. Wang et al. 10.1021/acs.est.8b02783
- Impact of NO<sub><i>x</i></sub> on secondary organic aerosol (SOA) formation from <i>α</i>-pinene and <i>β</i>-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
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- Estimation of rate coefficients and branching ratios for gas-phase reactions of OH with aliphatic organic compounds for use in automated mechanism construction M. Jenkin et al. 10.5194/acp-18-9297-2018
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- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
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- Molecular mechanisms and atmospheric implications of the simplest criegee intermediate and hydrochloric acid chemistry in the gas phase and at the aqueous interfaces C. Ding et al. 10.1016/j.atmosenv.2024.120558
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- Estimation of rate coefficients and branching ratios for reactions of organic peroxy radicals for use in automated mechanism construction M. Jenkin et al. 10.5194/acp-19-7691-2019
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- CH Stretch Activation of CH3CHOO: Deep Tunneling to Hydroxyl Radical Products V. Barber et al. 10.1021/acs.jpca.8b12324
- Potential factors and mechanism of particulate matters explosive increase induced by free radicals oxidation G. Wang et al. 10.1016/j.jes.2019.01.011
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene S. Richters et al. 10.5194/acp-16-9831-2016
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- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Direct probing of acylperoxy radicals during ozonolysis of α-pinene: constraints on radical chemistry and production of highly oxygenated organic molecules H. Zang et al. 10.5194/acp-23-12691-2023
- Computational Study of Hydrogen Shifts and Ring-Opening Mechanisms in α-Pinene Ozonolysis Products T. Kurtén et al. 10.1021/acs.jpca.5b08948
- Reaction between Peroxy and Alkoxy Radicals Can Form Stable Adducts S. Iyer et al. 10.1021/acs.jpclett.9b00405
- Experimental investigation into the volatilities of highly oxygenated organic molecules (HOMs) O. Peräkylä et al. 10.5194/acp-20-649-2020
- Alkenyl and Aryl Peroxides M. Klussmann 10.1002/chem.201703775
- A detailed MSn study for the molecular identification of a dimer formed from oxidation of pinene M. Beck & T. Hoffmann 10.1016/j.atmosenv.2015.09.012
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Unimolecular HO2 Loss from Peroxy Radicals Formed in Autoxidation Is Unlikely under Atmospheric Conditions N. Hyttinen et al. 10.1021/acs.jpca.6b02281
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- Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact T. Stephenson & M. Lester 10.1080/0144235X.2020.1688530
- Atmospheric Oxidation Mechanism of Sabinene Initiated by the Hydroxyl Radicals L. Wang & L. Wang 10.1021/acs.jpca.8b06381
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- Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: An Experimental and Theoretical Study B. Nozière & L. Vereecken 10.1002/anie.201907981
- Hydroxyl radical-induced formation of highly oxidized organic compounds T. Berndt et al. 10.1038/ncomms13677
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- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- α-Pinene Autoxidation Products May Not Have Extremely Low Saturation Vapor Pressures Despite High O:C Ratios T. Kurtén et al. 10.1021/acs.jpca.6b02196
- Ozonolysis Chemistry and Phase Behavior of 1-Octen-3-ol-Derived Secondary Organic Aerosol K. Fischer et al. 10.1021/acsearthspacechem.0c00092
- Theoretical kinetics studies on the temperature and pressure dependence of the reaction of ammonia with the Criegee intermediate CH2OO A. Nazari & V. Saheb 10.1007/s00214-022-02930-5
- Synthesis and characterisation of peroxypinic acids as proxies for highly oxygenated molecules (HOMs) in secondary organic aerosol S. Steimer et al. 10.5194/acp-18-10973-2018
- Online Quantification of Criegee Intermediates of α-Pinene Ozonolysis by Stabilization with Spin Traps and Proton-Transfer Reaction Mass Spectrometry Detection C. Giorio et al. 10.1021/jacs.6b10981
- Vertical characterization of highly oxygenated molecules (HOMs) below and above a boreal forest canopy Q. Zha et al. 10.5194/acp-18-17437-2018
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- SOA and gas phase organic acid yields from the sequential photooxidation of seven monoterpenes B. Friedman & D. Farmer 10.1016/j.atmosenv.2018.06.003
- Molecular identification of organic vapors driving atmospheric nanoparticle growth C. Mohr et al. 10.1038/s41467-019-12473-2
- Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes M. Riva et al. 10.5194/acp-16-11001-2016
- Formation of Highly Oxygenated Organic Molecules from α-Pinene Ozonolysis: Chemical Characteristics, Mechanism, and Kinetic Model Development U. Molteni et al. 10.1021/acsearthspacechem.9b00035
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- Accretion Product Formation from Self‐ and Cross‐Reactions of RO2 Radicals in the Atmosphere T. Berndt et al. 10.1002/anie.201710989
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
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- Size-dependent influence of NO x on the growth rates of organic aerosol particles C. Yan et al. 10.1126/sciadv.aay4945
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics O. Garmash et al. 10.5194/acp-20-515-2020
- SOA formation from the photooxidation of <i>α</i>-pinene: systematic exploration of the simulation of chamber data R. McVay et al. 10.5194/acp-16-2785-2016
- Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals E. Praske et al. 10.1021/acs.jpca.8b09745
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- Characterization and Quantification of Particle-Bound Criegee Intermediates in Secondary Organic Aerosol S. Campbell et al. 10.1021/acs.est.2c04101
- The pinene scaffold: its occurrence, chemistry, synthetic utility, and pharmacological importance R. Nyamwihura & I. Ogungbe 10.1039/D2RA00423B
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Ambient observations of dimers from terpene oxidation in the gas phase: Implications for new particle formation and growth C. Mohr et al. 10.1002/2017GL072718
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: An Experimental and Theoretical Study B. Nozière & L. Vereecken 10.1002/ange.201907981
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- Current state of aerosol nucleation parameterizations for air-quality and climate modeling K. Semeniuk & A. Dastoor 10.1016/j.atmosenv.2018.01.039
- Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene Y. Wang et al. 10.5194/acp-20-5145-2020
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- Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry C. Faxon et al. 10.5194/acp-18-5467-2018
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- Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds Q. He et al. 10.1021/acs.est.0c06838
- Relationship between chemical composition and oxidative potential of secondary organic aerosol from polycyclic aromatic hydrocarbons S. Wang et al. 10.5194/acp-18-3987-2018
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Characterization of Highly Oxidized Molecules in Fresh and Aged Biogenic Secondary Organic Aerosol P. Tu et al. 10.1021/acs.analchem.6b00378
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- Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes M. Dam et al. 10.5194/acp-22-9017-2022
- Global simulations of monoterpene-derived peroxy radical fates and the distributions of highly oxygenated organic molecules (HOMs) and accretion products R. Xu et al. 10.5194/acp-22-5477-2022
- Particle size dependence of biogenic secondary organic aerosol molecular composition P. Tu & M. Johnston 10.5194/acp-17-7593-2017
- Nanoparticle growth by particle-phase chemistry M. Apsokardu & M. Johnston 10.5194/acp-18-1895-2018
- Ambient Measurements of Highly Oxidized Gas-Phase Molecules during the Southern Oxidant and Aerosol Study (SOAS) 2013 P. Massoli et al. 10.1021/acsearthspacechem.8b00028
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- Unimolecular Decay of Criegee Intermediates to OH Radical Products: Prompt and Thermal Decay Processes M. Lester & S. Klippenstein 10.1021/acs.accounts.8b00077
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- The bimolecular catalytic transformation of methyl vinyl ketone oxide: A DFT study I. Elayan et al. 10.1016/j.chemphys.2019.110649
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- NO2 Suppression of Autoxidation–Inhibition of Gas-Phase Highly Oxidized Dimer Product Formation M. Rissanen 10.1021/acsearthspacechem.8b00123
147 citations as recorded by crossref.
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis L. Quéléver et al. 10.5194/acp-19-7609-2019
- Synthesis, Electronic Spectroscopy, and Photochemistry of Methacrolein Oxide: A Four-Carbon Unsaturated Criegee Intermediate from Isoprene Ozonolysis M. Vansco et al. 10.1021/jacs.9b05193
- Highly Oxygenated Multifunctional Compounds in α-Pinene Secondary Organic Aerosol X. Zhang et al. 10.1021/acs.est.6b06588
- Speciated Monitoring of Gas-Phase Organic Peroxy Radicals by Chemical Ionization Mass Spectrometry: Cross-Reactions between CH3O2, CH3(CO)O2, (CH3)3CO2, and c-C6H11O2 B. Nozière & D. Hanson 10.1021/acs.jpca.7b06456
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Functional Group Composition of Secondary Organic Aerosol Formed from Ozonolysis of α-Pinene Under High VOC and Autoxidation Conditions M. Claflin et al. 10.1021/acsearthspacechem.8b00117
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- PTR3: An Instrument for Studying the Lifecycle of Reactive Organic Carbon in the Atmosphere M. Breitenlechner et al. 10.1021/acs.analchem.6b05110
- The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system P. Roldin et al. 10.1038/s41467-019-12338-8
- Experimental and computational investigation of vinoxy and 1-methylvinoxy radicals from the unimolecular decay of alkyl-substituted Criegee intermediates V. Barber et al. 10.1016/j.cplett.2020.137478
- Detection of RO2 radicals and other products from cyclohexene ozonolysis with NH4+ and acetate chemical ionization mass spectrometry A. Hansel et al. 10.1016/j.atmosenv.2018.04.023
- An aldehyde as a rapid source of secondary aerosol precursors: theoretical and experimental study of hexanal autoxidation S. Barua et al. 10.5194/acp-23-10517-2023
- Effect of Ozone Concentration and Relative Humidity on the Heterogeneous Oxidation of Linoleic Acid Particles by Ozone: An Insight into the Interchangeability of Ozone Concentration and Time Y. Chu et al. 10.1021/acsearthspacechem.9b00002
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Four-Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production V. Barber et al. 10.1021/jacs.8b06010
- New particle formation in the free troposphere: A question of chemistry and timing F. Bianchi et al. 10.1126/science.aad5456
- Decrease in radiative forcing by organic aerosol nucleation, climate, and land use change J. Zhu et al. 10.1038/s41467-019-08407-7
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Additional chain-branching pathways in the low-temperature oxidation of branched alkanes Z. Wang et al. 10.1016/j.combustflame.2015.11.035
- Molecular corridors and parameterizations of volatility in the chemical evolution of organic aerosols Y. Li et al. 10.5194/acp-16-3327-2016
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Formation of Highly Oxidized Organic Compounds and Secondary Organic Aerosol from α-Thujene Ozonolysis M. Dam et al. 10.1021/acs.jpca.3c02584
- OH Roaming during the Ozonolysis of α-Pinene: A New Route to Highly Oxygenated Molecules? S. Klippenstein & S. Elliott 10.1021/acs.jpca.3c05179
- Highly Oxidized RO2Radicals and Consecutive Products from the Ozonolysis of Three Sesquiterpenes S. Richters et al. 10.1021/acs.est.5b05321
- Secondary Ion Chemistry Mediated by Ozone and Acidic Organic Molecules in Iodide-Adduct Chemical Ionization Mass Spectrometry W. Zhang & H. Zhang 10.1021/acs.analchem.1c01486
- Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene T. Berndt et al. 10.1021/acs.est.8b02210
- Secondary Organic Aerosol Formation from Healthy and Aphid-Stressed Scots Pine Emissions C. Faiola et al. 10.1021/acsearthspacechem.9b00118
- Formation of Highly Oxidized Radicals and Multifunctional Products from the Atmospheric Oxidation of Alkylbenzenes S. Wang et al. 10.1021/acs.est.7b02374
- Accurate identification of dimers from α‐pinene oxidation using high‐resolution collision‐induced dissociation mass spectrometry K. Sekimoto et al. 10.1002/jms.4508
- Biogenic secondary organic aerosols: A review on formation mechanism, analytical challenges and environmental impacts M. Mahilang et al. 10.1016/j.chemosphere.2020.127771
- Control of ozonolysis kinetics and aerosol yield by nuances in the molecular structure of volatile organic compounds R. Harvey & G. Petrucci 10.1016/j.atmosenv.2015.09.038
- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
- Primary Formation of Highly Oxidized Multifunctional Products in the OH-Initiated Oxidation of Isoprene: A Combined Theoretical and Experimental Study S. Wang et al. 10.1021/acs.est.8b02783
- Impact of NO<sub><i>x</i></sub> on secondary organic aerosol (SOA) formation from <i>α</i>-pinene and <i>β</i>-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Electronic spectroscopy of methyl vinyl ketone oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis M. Vansco et al. 10.1063/1.5064716
- Ozonation of Oilsands Bitumen S. Hendessi & A. de Klerk 10.1021/acs.energyfuels.6b01344
- Estimation of rate coefficients and branching ratios for gas-phase reactions of OH with aliphatic organic compounds for use in automated mechanism construction M. Jenkin et al. 10.5194/acp-18-9297-2018
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Atmospheric autoxidation is increasingly important in urban and suburban North America E. Praske et al. 10.1073/pnas.1715540115
- Anthropogenic enhancements to production of highly oxygenated molecules from autoxidation H. Pye et al. 10.1073/pnas.1810774116
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- Degradation of Carbonyl Hydroperoxides in the Atmosphere and in Combustion L. Xing et al. 10.1021/jacs.7b08297
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Review of technologies and their applications for the speciated detection of RO2 radicals Y. Gao et al. 10.1016/j.jes.2022.09.028
- Atmospheric photochemistry and secondary aerosol formation of urban air in Lyon, France S. Sbai et al. 10.1016/j.jes.2020.06.037
- Molecular mechanisms and atmospheric implications of the simplest criegee intermediate and hydrochloric acid chemistry in the gas phase and at the aqueous interfaces C. Ding et al. 10.1016/j.atmosenv.2024.120558
- Bildung von Aufbauprodukten aus den Selbst‐ und Kreuzreaktionen von RO2‐Radikalen in der Atmosphäre T. Berndt et al. 10.1002/ange.201710989
- Impact of NO<sub><i>x</i></sub> and OH on secondary organic aerosol formation from <i>β</i>-pinene photooxidation M. Sarrafzadeh et al. 10.5194/acp-16-11237-2016
- Molecular Composition of Oxygenated Organic Molecules and Their Contributions to Organic Aerosol in Beijing Y. Wang et al. 10.1021/acs.est.1c05191
- The role of low-volatility organic compounds in initial particle growth in the atmosphere J. Tröstl et al. 10.1038/nature18271
- Estimation of rate coefficients and branching ratios for reactions of organic peroxy radicals for use in automated mechanism construction M. Jenkin et al. 10.5194/acp-19-7691-2019
- Hydroxyl radicals from secondary organic aerosol decomposition in water H. Tong et al. 10.5194/acp-16-1761-2016
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- CH Stretch Activation of CH3CHOO: Deep Tunneling to Hydroxyl Radical Products V. Barber et al. 10.1021/acs.jpca.8b12324
- Potential factors and mechanism of particulate matters explosive increase induced by free radicals oxidation G. Wang et al. 10.1016/j.jes.2019.01.011
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene S. Richters et al. 10.5194/acp-16-9831-2016
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. 10.5194/acp-24-7961-2024
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Direct probing of acylperoxy radicals during ozonolysis of α-pinene: constraints on radical chemistry and production of highly oxygenated organic molecules H. Zang et al. 10.5194/acp-23-12691-2023
- Computational Study of Hydrogen Shifts and Ring-Opening Mechanisms in α-Pinene Ozonolysis Products T. Kurtén et al. 10.1021/acs.jpca.5b08948
- Reaction between Peroxy and Alkoxy Radicals Can Form Stable Adducts S. Iyer et al. 10.1021/acs.jpclett.9b00405
- Experimental investigation into the volatilities of highly oxygenated organic molecules (HOMs) O. Peräkylä et al. 10.5194/acp-20-649-2020
- Alkenyl and Aryl Peroxides M. Klussmann 10.1002/chem.201703775
- A detailed MSn study for the molecular identification of a dimer formed from oxidation of pinene M. Beck & T. Hoffmann 10.1016/j.atmosenv.2015.09.012
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Unimolecular HO2 Loss from Peroxy Radicals Formed in Autoxidation Is Unlikely under Atmospheric Conditions N. Hyttinen et al. 10.1021/acs.jpca.6b02281
- Detection and identification of Criegee intermediates from the ozonolysis of biogenic and anthropogenic VOCs: comparison between experimental measurements and theoretical calculations C. Giorio et al. 10.1039/C7FD00025A
- Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact T. Stephenson & M. Lester 10.1080/0144235X.2020.1688530
- Atmospheric Oxidation Mechanism of Sabinene Initiated by the Hydroxyl Radicals L. Wang & L. Wang 10.1021/acs.jpca.8b06381
- Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate S. Wang et al. 10.1021/acs.est.9b02591
- Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: An Experimental and Theoretical Study B. Nozière & L. Vereecken 10.1002/anie.201907981
- Hydroxyl radical-induced formation of highly oxidized organic compounds T. Berndt et al. 10.1038/ncomms13677
- Ion mobility spectrometry–mass spectrometry (IMS–MS) for on- and offline analysis of atmospheric gas and aerosol species J. Krechmer et al. 10.5194/amt-9-3245-2016
- Lowering of Reaction Rates by Energetically Favorable Hydrogen Bonding in the Transition State. Degradation of Biofuel Ketohydroperoxides by OH L. Xing et al. 10.1021/jacs.2c06124
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- α-Pinene Autoxidation Products May Not Have Extremely Low Saturation Vapor Pressures Despite High O:C Ratios T. Kurtén et al. 10.1021/acs.jpca.6b02196
- Ozonolysis Chemistry and Phase Behavior of 1-Octen-3-ol-Derived Secondary Organic Aerosol K. Fischer et al. 10.1021/acsearthspacechem.0c00092
- Theoretical kinetics studies on the temperature and pressure dependence of the reaction of ammonia with the Criegee intermediate CH2OO A. Nazari & V. Saheb 10.1007/s00214-022-02930-5
- Synthesis and characterisation of peroxypinic acids as proxies for highly oxygenated molecules (HOMs) in secondary organic aerosol S. Steimer et al. 10.5194/acp-18-10973-2018
- Online Quantification of Criegee Intermediates of α-Pinene Ozonolysis by Stabilization with Spin Traps and Proton-Transfer Reaction Mass Spectrometry Detection C. Giorio et al. 10.1021/jacs.6b10981
- Vertical characterization of highly oxygenated molecules (HOMs) below and above a boreal forest canopy Q. Zha et al. 10.5194/acp-18-17437-2018
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- SOA and gas phase organic acid yields from the sequential photooxidation of seven monoterpenes B. Friedman & D. Farmer 10.1016/j.atmosenv.2018.06.003
- Molecular identification of organic vapors driving atmospheric nanoparticle growth C. Mohr et al. 10.1038/s41467-019-12473-2
- Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes M. Riva et al. 10.5194/acp-16-11001-2016
- Formation of Highly Oxygenated Organic Molecules from α-Pinene Ozonolysis: Chemical Characteristics, Mechanism, and Kinetic Model Development U. Molteni et al. 10.1021/acsearthspacechem.9b00035
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- Accretion Product Formation from Self‐ and Cross‐Reactions of RO2 Radicals in the Atmosphere T. Berndt et al. 10.1002/anie.201710989
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
- Correct Symmetry Treatment for X + X Reactions Prevents Large Errors in Predicted Isotope Enrichment M. Goldman et al. 10.1021/acs.jpca.8b09024
- Size-dependent influence of NO x on the growth rates of organic aerosol particles C. Yan et al. 10.1126/sciadv.aay4945
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics O. Garmash et al. 10.5194/acp-20-515-2020
- SOA formation from the photooxidation of <i>α</i>-pinene: systematic exploration of the simulation of chamber data R. McVay et al. 10.5194/acp-16-2785-2016
- Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals E. Praske et al. 10.1021/acs.jpca.8b09745
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- Characterization and Quantification of Particle-Bound Criegee Intermediates in Secondary Organic Aerosol S. Campbell et al. 10.1021/acs.est.2c04101
- The pinene scaffold: its occurrence, chemistry, synthetic utility, and pharmacological importance R. Nyamwihura & I. Ogungbe 10.1039/D2RA00423B
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Ambient observations of dimers from terpene oxidation in the gas phase: Implications for new particle formation and growth C. Mohr et al. 10.1002/2017GL072718
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Direct Observation of Aliphatic Peroxy Radical Autoxidation and Water Effects: An Experimental and Theoretical Study B. Nozière & L. Vereecken 10.1002/ange.201907981
- Organic Nitrate Contribution to New Particle Formation and Growth in Secondary Organic Aerosols from α-Pinene Ozonolysis T. Berkemeier et al. 10.1021/acs.est.6b00961
- Current state of aerosol nucleation parameterizations for air-quality and climate modeling K. Semeniuk & A. Dastoor 10.1016/j.atmosenv.2018.01.039
- Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene Y. Wang et al. 10.5194/acp-20-5145-2020
- Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors Y. Shao et al. 10.5194/acp-22-9799-2022
- Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry C. Faxon et al. 10.5194/acp-18-5467-2018
- Quantification of Particle-Bound Organic Radicals in Secondary Organic Aerosol S. Campbell et al. 10.1021/acs.est.9b00825
- Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds Q. He et al. 10.1021/acs.est.0c06838
- Relationship between chemical composition and oxidative potential of secondary organic aerosol from polycyclic aromatic hydrocarbons S. Wang et al. 10.5194/acp-18-3987-2018
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Characterization of Highly Oxidized Molecules in Fresh and Aged Biogenic Secondary Organic Aerosol P. Tu et al. 10.1021/acs.analchem.6b00378
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Observations of gas-phase products from the nitrate-radical-initiated oxidation of four monoterpenes M. Dam et al. 10.5194/acp-22-9017-2022
- Global simulations of monoterpene-derived peroxy radical fates and the distributions of highly oxygenated organic molecules (HOMs) and accretion products R. Xu et al. 10.5194/acp-22-5477-2022
- Particle size dependence of biogenic secondary organic aerosol molecular composition P. Tu & M. Johnston 10.5194/acp-17-7593-2017
- Nanoparticle growth by particle-phase chemistry M. Apsokardu & M. Johnston 10.5194/acp-18-1895-2018
- Ambient Measurements of Highly Oxidized Gas-Phase Molecules during the Southern Oxidant and Aerosol Study (SOAS) 2013 P. Massoli et al. 10.1021/acsearthspacechem.8b00028
- Kinetic modeling studies of SOA formation from <i>α</i>-pinene ozonolysis K. Gatzsche et al. 10.5194/acp-17-13187-2017
- Computational Comparison of Acetate and Nitrate Chemical Ionization of Highly Oxidized Cyclohexene Ozonolysis Intermediates and Products N. Hyttinen et al. 10.1021/acs.jpca.6b12654
- Efficient alkane oxidation under combustion engine and atmospheric conditions Z. Wang et al. 10.1038/s42004-020-00445-3
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al. 10.1039/C9CP06306D
- Theoretical kinetic study of the formic acid catalyzed Criegee intermediate isomerization: multistructural anharmonicity and atmospheric implications M. Monge-Palacios et al. 10.1039/C7CP08538A
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Multi-scheme chemical ionization inlet (MION) for fast switching of reagent ion chemistry in atmospheric pressure chemical ionization mass spectrometry (CIMS) applications M. Rissanen et al. 10.5194/amt-12-6635-2019
- Autoxidation of glycols used in inhalable daily products: implications for the use of artificial fogs and e-cigarettes X. Guo et al. 10.1039/D3EM00214D
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Effect of NO<sub><i>x</i></sub> on 1,3,5-trimethylbenzene (TMB) oxidation product distribution and particle formation E. Tsiligiannis et al. 10.5194/acp-19-15073-2019
- Quantitative kinetics reveal that reactions of HO2 are a significant sink for aldehydes in the atmosphere and may initiate the formation of highly oxygenated molecules via autoxidation Q. Gao et al. 10.1039/D4CP00693C
- Highly Oxygenated Molecules from Atmospheric Autoxidation of Hydrocarbons: A Prominent Challenge for Chemical Kinetics Studies M. Ehn et al. 10.1002/kin.21130
- Predicting Aerosol Reactivity Across Scales: from the Laboratory to the Atmosphere F. Houle et al. 10.1021/acs.est.8b04688
- Computational Investigation of RO2 + HO2 and RO2 + RO2 Reactions of Monoterpene Derived First-Generation Peroxy Radicals Leading to Radical Recycling S. Iyer et al. 10.1021/acs.jpca.8b09241
- Unimolecular Decay of Criegee Intermediates to OH Radical Products: Prompt and Thermal Decay Processes M. Lester & S. Klippenstein 10.1021/acs.accounts.8b00077
- Ultrahigh-Resolution Mass Spectrometry in Real Time: Atmospheric Pressure Chemical Ionization Orbitrap Mass Spectrometry of Atmospheric Organic Aerosol C. Zuth et al. 10.1021/acs.analchem.8b00671
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Experimental and theoretical studies of the doubly substituted methyl-ethyl Criegee intermediate: Infrared action spectroscopy and unimolecular decay to OH radical products V. Barber et al. 10.1063/5.0002422
- The bimolecular catalytic transformation of methyl vinyl ketone oxide: A DFT study I. Elayan et al. 10.1016/j.chemphys.2019.110649
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
5 citations as recorded by crossref.
- Investigation of the formation of benzoyl peroxide, benzoic anhydride, and other potential aerosol products from gas–phase reactions of benzoylperoxy radicals C. Strollo & P. Ziemann 10.1016/j.atmosenv.2016.01.011
- Gas-Phase Ozonolysis of Cycloalkenes: Formation of Highly Oxidized RO2Radicals and Their Reactions with NO, NO2, SO2, and Other RO2Radicals T. Berndt et al. 10.1021/acs.jpca.5b07295
- Highly Oxidized Multifunctional Organic Compounds Observed in Tropospheric Particles: A Field and Laboratory Study A. Mutzel et al. 10.1021/acs.est.5b00885
- Investigating the evolution of summertime secondary atmospheric pollutants in urban Beijing D. Ji et al. 10.1016/j.scitotenv.2016.07.153
- NO2 Suppression of Autoxidation–Inhibition of Gas-Phase Highly Oxidized Dimer Product Formation M. Rissanen 10.1021/acsearthspacechem.8b00123
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Short summary
We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the structural pre-requisites and chemical pathways to the recently discovered class of highly oxidized molecules ELVOC (Ehn et al., Nature, 2014). ELVOC may totally change the view on (parts of) the mechanism of SOA formation. We present results which support recent observations of H shifts from C-H to peroxy radicals, highlighting the pivotal role of peroxyradicals in organic atmospheric chemistry.
We studied a series of cycloalkenes and methyl-substituted alkenes in order to elucidate the...
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