Articles | Volume 23, issue 19
https://doi.org/10.5194/acp-23-12651-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-12651-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Oct 2023
Research article |
| 11 Oct 2023
| 11 Oct 2023
What controls ozone sensitivity in the upper tropical troposphere?
Clara M. Nussbaumer
CORRESPONDING AUTHOR
Department of Atmospheric Chemistry, Max Planck Institute for Chemistry, Mainz, Germany
Horst Fischer
Department of Atmospheric Chemistry, Max Planck Institute for Chemistry, Mainz, Germany
Jos Lelieveld
Department of Atmospheric Chemistry, Max Planck Institute for Chemistry, Mainz, Germany
Climate and Atmosphere Research Center, The Cyprus Institute, Nicosia, Cyprus
Andrea Pozzer
Department of Atmospheric Chemistry, Max Planck Institute for Chemistry, Mainz, Germany
Climate and Atmosphere Research Center, The Cyprus Institute, Nicosia, Cyprus
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Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-314, https://doi.org/10.5194/essd-2024-314, 2024
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Atmos. Meas. Tech., 17, 3553–3565, https://doi.org/10.5194/amt-17-3553-2024, https://doi.org/10.5194/amt-17-3553-2024, 2024
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Airborne in situ measurements are of great importance to collect valuable data to improve our knowledge of the atmosphere but also present challenges which demand specific designs. This study presents an IR spectrometer for airborne trace-gas measurements with high data efficiency and a simple, compact design. Its in-flight performance is characterized with the help of a test flight and a comparison with another spectrometer. Moreover, results from its first campaign highlight its benefits.
Simone Rodrigues, Glauber Cirino, Demerval Moreira, Andrea Pozzer, Rafael Palácios, Sung-Ching Lee, Breno Imbiriba, José Nogueira, Maria Isabel Vitorino, and George Vourlitis
Biogeosciences, 21, 843–868, https://doi.org/10.5194/bg-21-843-2024, https://doi.org/10.5194/bg-21-843-2024, 2024
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The radiative effects of atmospheric particles are still unknown for a wide variety of species and types of vegetation present in Amazonian biomes. We examined the effects of aerosols on solar radiation and their impacts on photosynthesis in an area of semideciduous forest in the southern Amazon Basin. Under highly smoky-sky conditions, our results show substantial photosynthetic interruption (20–70 %), attributed specifically to the decrease in solar radiation and leaf canopy temperature.
Imran A. Girach, Narendra Ojha, Prabha R. Nair, Kandula V. Subrahmanyam, Neelakantan Koushik, Mohammed M. Nazeer, Nadimpally Kiran Kumar, Surendran Nair Suresh Babu, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 24, 1979–1995, https://doi.org/10.5194/acp-24-1979-2024, https://doi.org/10.5194/acp-24-1979-2024, 2024
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We investigate surface ozone variability in East Antarctica based on measurements and EMAC global model simulations during austral summer. Nearly half of the surface ozone is found to be of stratospheric origin. The east coast of Antarctica acts as a stronger sink of ozone than surrounding regions. Photochemical loss of ozone is counterbalanced by downward transport of ozone. The study highlights the intertwined role of chemistry and dynamics in governing ozone variations over East Antarctica.
Leon Kuhn, Steffen Beirle, Vinod Kumar, Sergey Osipov, Andrea Pozzer, Tim Bösch, Rajesh Kumar, and Thomas Wagner
Atmos. Chem. Phys., 24, 185–217, https://doi.org/10.5194/acp-24-185-2024, https://doi.org/10.5194/acp-24-185-2024, 2024
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NO₂ is an important air pollutant. It was observed that the WRF-Chem model shows significant deviations in NO₂ abundance when compared to measurements. We use a 1-month simulation over central Europe to show that these deviations can be mostly resolved by reparameterization of the vertical mixing routine. In order to validate our results, they are compared to in situ, satellite, and MAX-DOAS measurements.
Meghna Soni, Rolf Sander, Lokesh K. Sahu, Domenico Taraborrelli, Pengfei Liu, Ankit Patel, Imran A. Girach, Andrea Pozzer, Sachin S. Gunthe, and Narendra Ojha
Atmos. Chem. Phys., 23, 15165–15180, https://doi.org/10.5194/acp-23-15165-2023, https://doi.org/10.5194/acp-23-15165-2023, 2023
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The study presents the implementation of comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA. Simulations for contrasting urban environments of Asia and Europe highlight the significant impacts of chlorine on atmospheric oxidation capacity and composition. Chemical processes governing the production and loss of chlorine-containing species has been discussed. The updated chemical mechanism will be useful to interpret field measurements and for future air quality studies.
Ryan Vella, Andrea Pozzer, Matthew Forrest, Jos Lelieveld, Thomas Hickler, and Holger Tost
Biogeosciences, 20, 4391–4412, https://doi.org/10.5194/bg-20-4391-2023, https://doi.org/10.5194/bg-20-4391-2023, 2023
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We investigated the effect of the El Niño–Southern Oscillation (ENSO) on biogenic volatile organic compound (BVOC) emissions from plants. ENSO events can cause a significant increase in these emissions, which have a long-term impact on the Earth's atmosphere. Persistent ENSO conditions can cause long-term changes in vegetation, resulting in even higher BVOC emissions. We link ENSO-induced emission anomalies with driving atmospheric and vegetational variables.
Susanna Strada, Andrea Pozzer, Graziano Giuliani, Erika Coppola, Fabien Solmon, Xiaoyan Jiang, Alex Guenther, Efstratios Bourtsoukidis, Dominique Serça, Jonathan Williams, and Filippo Giorgi
Atmos. Chem. Phys., 23, 13301–13327, https://doi.org/10.5194/acp-23-13301-2023, https://doi.org/10.5194/acp-23-13301-2023, 2023
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Water deficit modifies emissions of isoprene, an aromatic compound released by plants that influences the production of an air pollutant such as ozone. Numerical modelling shows that, during the warmest and driest summers, isoprene decreases between −20 and −60 % over the Euro-Mediterranean region, while near-surface ozone only diminishes by a few percent. Decreases in isoprene emissions not only happen under dry conditions, but also could occur after prolonged or repeated water deficits.
Zaneta Hamryszczak, Antonia Hartmann, Dirk Dienhart, Sascha Hafermann, Bettina Brendel, Rainer Königstedt, Uwe Parchatka, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 4741–4756, https://doi.org/10.5194/amt-16-4741-2023, https://doi.org/10.5194/amt-16-4741-2023, 2023
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Hydroperoxide measurements improve the understanding of atmospheric oxidation processes. We introduce an instrumental setup for airborne measurements. The aim of the work is the characterization of the measurement method with emphasis on interferences impacting instrumental uncertainty. Technical and physical challenges do not critically impact the instrumental performance. The instrument resolves dynamic processes, such as convective transport, as shown based on the CAFE-Brazil campaign.
Matthias Kohl, Jos Lelieveld, Sourangsu Chowdhury, Sebastian Ehrhart, Disha Sharma, Yafang Cheng, Sachchida Nand Tripathi, Mathew Sebastian, Govindan Pandithurai, Hongli Wang, and Andrea Pozzer
Atmos. Chem. Phys., 23, 13191–13215, https://doi.org/10.5194/acp-23-13191-2023, https://doi.org/10.5194/acp-23-13191-2023, 2023
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Knowledge on atmospheric ultrafine particles (UFPs) with a diameter smaller than 100 nm is crucial for public health and the hydrological cycle. We present a new global dataset of UFP concentrations at the Earth's surface derived with a comprehensive chemistry–climate model and evaluated with ground-based observations. The evaluation results are combined with high-resolution primary emissions to downscale UFP concentrations to an unprecedented horizontal resolution of 0.1° × 0.1°.
Clara M. Nussbaumer, Bryan K. Place, Qindan Zhu, Eva Y. Pfannerstill, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Ryan Ward, Anthony Bucholtz, John H. Seinfeld, Allen H. Goldstein, and Ronald C. Cohen
Atmos. Chem. Phys., 23, 13015–13028, https://doi.org/10.5194/acp-23-13015-2023, https://doi.org/10.5194/acp-23-13015-2023, 2023
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NOx is a precursor to hazardous tropospheric ozone and can be emitted from various anthropogenic sources. It is important to quantify NOx emissions in urban environments to improve the local air quality, which still remains a challenge, as sources are heterogeneous in space and time. In this study, we calculate NOx emissions over Los Angeles, based on aircraft measurements in June 2021, and compare them to a local emission inventory, which we find mostly overpredicts the measured values.
Qindan Zhu, Bryan Place, Eva Y. Pfannerstill, Sha Tong, Huanxin Zhang, Jun Wang, Clara M. Nussbaumer, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Anthony Bucholtz, John H. Seinfeld, Allen H. Goldstein, and Ronald C. Cohen
Atmos. Chem. Phys., 23, 9669–9683, https://doi.org/10.5194/acp-23-9669-2023, https://doi.org/10.5194/acp-23-9669-2023, 2023
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Nitrogen oxide (NOx) is a hazardous air pollutant, and it is the precursor of short-lived climate forcers like tropospheric ozone and aerosol particles. While NOx emissions from transportation has been strictly regulated, soil NOx emissions are overlooked. We use the airborne flux measurements to observe NOx emissions from highways and urban and cultivated soil land cover types. We show non-negligible soil NOx emissions, which are significantly underestimated in current model simulations.
Seyed Omid Nabavi, Theodoros Christoudias, Yiannis Proestos, Christos Fountoukis, Huda Al-Sulaiti, and Jos Lelieveld
Atmos. Chem. Phys., 23, 7719–7739, https://doi.org/10.5194/acp-23-7719-2023, https://doi.org/10.5194/acp-23-7719-2023, 2023
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The objective of our study is to comprehensively assess the timing of radioactive material transportation and deposition, along with the associated population exposure in the designated region. We employed diverse meteorological inputs, emission specifics, and simulation codes, aiming to quantify the level of uncertainty.
Klaus Klingmüller and Jos Lelieveld
Geosci. Model Dev., 16, 3013–3028, https://doi.org/10.5194/gmd-16-3013-2023, https://doi.org/10.5194/gmd-16-3013-2023, 2023
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Desert dust has significant impacts on climate, public health, infrastructure and ecosystems. An impact assessment requires numerical predictions, which are challenging because the dust emissions are not well known. We present a novel approach using satellite observations and machine learning to more accurately estimate the emissions and to improve the model simulations.
Zaneta Hamryszczak, Dirk Dienhart, Bettina Brendel, Roland Rohloff, Daniel Marno, Monica Martinez, Hartwig Harder, Andrea Pozzer, Birger Bohn, Martin Zöger, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 23, 5929–5943, https://doi.org/10.5194/acp-23-5929-2023, https://doi.org/10.5194/acp-23-5929-2023, 2023
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Hydrogen peroxide is a key contributor to the oxidative chemistry of the atmosphere through its link to the most prominent oxidants controlling its self-cleansing capacity, HOx. During the CAFE-Africa campaign, H2O2 was measured over the Atlantic Ocean and western Africa in August/September 2018. The study gives an overview of the distribution of H2O2 in the upper tropical troposphere and investigates the impact of convective processes in the Intertropical Convergence Zone on the budget of H2O2.
Lenard L. Röder, Patrick Dewald, Clara M. Nussbaumer, Jan Schuladen, John N. Crowley, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 16, 1167–1178, https://doi.org/10.5194/amt-16-1167-2023, https://doi.org/10.5194/amt-16-1167-2023, 2023
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Field experiments in atmospheric chemistry provide insights into chemical interactions of our atmosphere. However, high data coverage and accuracy are needed to enable further analysis. In this study, we explore a statistical method that combines knowledge about the chemical reactions with information from measurements to increase the quality of field experiment datasets. We test the algorithm for several applications and discuss limitations that depend on the specific variable and the dynamics.
Ryan Vella, Matthew Forrest, Jos Lelieveld, and Holger Tost
Geosci. Model Dev., 16, 885–906, https://doi.org/10.5194/gmd-16-885-2023, https://doi.org/10.5194/gmd-16-885-2023, 2023
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Biogenic volatile organic compounds (BVOCs) are released by vegetation and have a major impact on atmospheric chemistry and aerosol formation. Non-interacting vegetation constrains the majority of numerical models used to estimate global BVOC emissions, and thus, the effects of changing vegetation on emissions are not addressed. In this work, we replace the offline vegetation with dynamic vegetation states by linking a chemistry–climate model with a global dynamic vegetation model.
Jennifer Schallock, Christoph Brühl, Christine Bingen, Michael Höpfner, Landon Rieger, and Jos Lelieveld
Atmos. Chem. Phys., 23, 1169–1207, https://doi.org/10.5194/acp-23-1169-2023, https://doi.org/10.5194/acp-23-1169-2023, 2023
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We characterized the influence of volcanic aerosols for the period 1990–2019 and established a volcanic SO2 emission inventory that includes more than 500 eruptions. From limb-based satellite observations of SO2 and extinction, we derive 3D plumes of SO2 perturbations and injected mass by a novel method. We calculate instantaneous radiative forcing with a comprehensive chemisty climate model. Our results show that smaller eruptions can also contribute to the stratospheric aerosol forcing.
Mohamed Abdelkader, Georgiy Stenchikov, Andrea Pozzer, Holger Tost, and Jos Lelieveld
Atmos. Chem. Phys., 23, 471–500, https://doi.org/10.5194/acp-23-471-2023, https://doi.org/10.5194/acp-23-471-2023, 2023
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We study the effect of injected volcanic ash, water vapor, and SO2 on the development of the volcanic cloud and the stratospheric aerosol optical depth (AOD). Both are sensitive to the initial injection height and to the aging of the volcanic ash shaped by heterogeneous chemistry coupled with the ozone cycle. The paper explains the large differences in AOD for different injection scenarios, which could improve the estimate of the radiative forcing of volcanic eruptions.
Dirk Dienhart, Bettina Brendel, John N. Crowley, Philipp G. Eger, Hartwig Harder, Monica Martinez, Andrea Pozzer, Roland Rohloff, Jan Schuladen, Sebastian Tauer, David Walter, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 23, 119–142, https://doi.org/10.5194/acp-23-119-2023, https://doi.org/10.5194/acp-23-119-2023, 2023
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Formaldehyde and hydroperoxide measurements were performed in the marine boundary layer around the Arabian Peninsula and highlight the Suez Canal and Arabian (Persian) Gulf as a hotspot of photochemical air pollution. A comparison with the EMAC model shows that the formaldehyde results match within a factor of 2, while hydrogen peroxide was overestimated by more than a factor of 5, which revealed enhanced HOx (OH+HO2) radicals in the simulation and an underestimation of dry deposition velocites.
Laura Tomsche, Andreas Marsing, Tina Jurkat-Witschas, Johannes Lucke, Stefan Kaufmann, Katharina Kaiser, Johannes Schneider, Monika Scheibe, Hans Schlager, Lenard Röder, Horst Fischer, Florian Obersteiner, Andreas Zahn, Martin Zöger, Jos Lelieveld, and Christiane Voigt
Atmos. Chem. Phys., 22, 15135–15151, https://doi.org/10.5194/acp-22-15135-2022, https://doi.org/10.5194/acp-22-15135-2022, 2022
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The detection of sulfur compounds in the upper troposphere (UT) and lower stratosphere (LS) is a challenge. In-flight measurements of SO2 and sulfate aerosol were performed during the BLUESKY mission in spring 2020 under exceptional atmospheric conditions. Reduced sinks in the dry UTLS and lower but still significant air traffic influenced the enhanced SO2 in the UT, and aged volcanic plumes enhanced the LS sulfate aerosol impacting the atmospheric radiation budget and global climate.
Charlotte M. Beall, Thomas C. J. Hill, Paul J. DeMott, Tobias Köneman, Michael Pikridas, Frank Drewnick, Hartwig Harder, Christopher Pöhlker, Jos Lelieveld, Bettina Weber, Minas Iakovides, Roman Prokeš, Jean Sciare, Meinrat O. Andreae, M. Dale Stokes, and Kimberly A. Prather
Atmos. Chem. Phys., 22, 12607–12627, https://doi.org/10.5194/acp-22-12607-2022, https://doi.org/10.5194/acp-22-12607-2022, 2022
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Ice-nucleating particles (INPs) are rare aerosols that can trigger ice formation in clouds and affect climate-relevant cloud properties such as phase, reflectivity and lifetime. Dust is the dominant INP source, yet few measurements have been reported near major dust sources. We report INP observations within hundreds of kilometers of the biggest dust source regions globally: the Sahara and the Arabian Peninsula. Results show that at temperatures > −15 °C, INPs are dominated by organics.
Mengze Li, Andrea Pozzer, Jos Lelieveld, and Jonathan Williams
Earth Syst. Sci. Data, 14, 4351–4364, https://doi.org/10.5194/essd-14-4351-2022, https://doi.org/10.5194/essd-14-4351-2022, 2022
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We present a northern hemispheric airborne measurement dataset of atmospheric ethane, propane and methane and temporal trends for the time period 2006–2016 in the upper troposphere and lower stratosphere. The growth rates of ethane, methane, and propane in the upper troposphere are -2.24, 0.33, and -0.78 % yr-1, respectively, and in the lower stratosphere they are -3.27, 0.26, and -4.91 % yr-1, respectively, in 2006–2016.
Simon F. Reifenberg, Anna Martin, Matthias Kohl, Sara Bacer, Zaneta Hamryszczak, Ivan Tadic, Lenard Röder, Daniel J. Crowley, Horst Fischer, Katharina Kaiser, Johannes Schneider, Raphael Dörich, John N. Crowley, Laura Tomsche, Andreas Marsing, Christiane Voigt, Andreas Zahn, Christopher Pöhlker, Bruna A. Holanda, Ovid Krüger, Ulrich Pöschl, Mira Pöhlker, Patrick Jöckel, Marcel Dorf, Ulrich Schumann, Jonathan Williams, Birger Bohn, Joachim Curtius, Hardwig Harder, Hans Schlager, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 22, 10901–10917, https://doi.org/10.5194/acp-22-10901-2022, https://doi.org/10.5194/acp-22-10901-2022, 2022
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In this work we use a combination of observational data from an aircraft campaign and model results to investigate the effect of the European lockdown due to COVID-19 in spring 2020. Using model results, we show that the largest relative changes to the atmospheric composition caused by the reduced emissions are located in the upper troposphere around aircraft cruise altitude, while the largest absolute changes are present at the surface.
Zaneta T. Hamryszczak, Andrea Pozzer, Florian Obersteiner, Birger Bohn, Benedikt Steil, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 22, 9483–9497, https://doi.org/10.5194/acp-22-9483-2022, https://doi.org/10.5194/acp-22-9483-2022, 2022
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Hydrogen peroxide plays a pivotal role in the chemistry of the atmosphere. Together with organic hydroperoxides, it forms a reservoir for peroxy radicals, which are known to be the key contributors to the self-cleaning processes of the atmosphere. Hydroperoxides were measured over Europe during the BLUESKY campaign in May–June 2020. The paper gives an overview of the distribution of the species in the troposphere and investigates the impact of wet scavenging and deposition on the budget of H2O2.
Marco Wietzoreck, Marios Kyprianou, Benjamin A. Musa Bandowe, Siddika Celik, John N. Crowley, Frank Drewnick, Philipp Eger, Nils Friedrich, Minas Iakovides, Petr Kukučka, Jan Kuta, Barbora Nežiková, Petra Pokorná, Petra Přibylová, Roman Prokeš, Roland Rohloff, Ivan Tadic, Sebastian Tauer, Jake Wilson, Hartwig Harder, Jos Lelieveld, Ulrich Pöschl, Euripides G. Stephanou, and Gerhard Lammel
Atmos. Chem. Phys., 22, 8739–8766, https://doi.org/10.5194/acp-22-8739-2022, https://doi.org/10.5194/acp-22-8739-2022, 2022
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A unique dataset of concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) and their alkylated, oxygenated and nitrated derivatives, in total 74 individual species, in the marine atmosphere is presented. Exposure to these substances poses a major health risk. We found very low concentrations over the Arabian Sea, while both local and long-range-transported pollution caused elevated levels over the Mediterranean Sea and the Arabian Gulf.
Ovid O. Krüger, Bruna A. Holanda, Sourangsu Chowdhury, Andrea Pozzer, David Walter, Christopher Pöhlker, Maria Dolores Andrés Hernández, John P. Burrows, Christiane Voigt, Jos Lelieveld, Johannes Quaas, Ulrich Pöschl, and Mira L. Pöhlker
Atmos. Chem. Phys., 22, 8683–8699, https://doi.org/10.5194/acp-22-8683-2022, https://doi.org/10.5194/acp-22-8683-2022, 2022
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The abrupt reduction in human activities during the first COVID-19 lockdown created unprecedented atmospheric conditions. We took the opportunity to quantify changes in black carbon (BC) as a major anthropogenic air pollutant. Therefore, we measured BC on board a research aircraft over Europe during the lockdown and compared the results to measurements from 2017. With model simulations we account for different weather conditions and find a lockdown-related decrease in BC of 41 %.
Patrick Dewald, Clara M. Nussbaumer, Jan Schuladen, Akima Ringsdorf, Achim Edtbauer, Horst Fischer, Jonathan Williams, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 22, 7051–7069, https://doi.org/10.5194/acp-22-7051-2022, https://doi.org/10.5194/acp-22-7051-2022, 2022
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We measured the gas-phase reactivity of the NO3 radical on the summit (825 m a.s.l.) of a semi-rural mountain in southwestern Germany in July 2021. The impact of VOC-induced NO3 losses (mostly monoterpenes) competing with a loss by reaction with NO and photolysis throughout the diel cycle was estimated. Besides chemistry, boundary layer dynamics and plant-physiological processes presumably have a great impact on our observations, which were compared to previous NO3 measurements at the same site.
George K. Georgiou, Theodoros Christoudias, Yiannis Proestos, Jonilda Kushta, Michael Pikridas, Jean Sciare, Chrysanthos Savvides, and Jos Lelieveld
Geosci. Model Dev., 15, 4129–4146, https://doi.org/10.5194/gmd-15-4129-2022, https://doi.org/10.5194/gmd-15-4129-2022, 2022
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We evaluate the skill of the WRF-Chem model to perform high-resolution air quality forecasts (including ozone, nitrogen dioxide, and fine particulate matter) over the Eastern Mediterranean, during winter and summer. We compare the forecast output to observational data from background and urban locations and the forecast output from CAMS. WRF-Chem was found to forecast the concentrations and diurnal profiles of gas-phase pollutants in urban areas with higher accuracy.
Dimitris Akritidis, Andrea Pozzer, Johannes Flemming, Antje Inness, Philippe Nédélec, and Prodromos Zanis
Atmos. Chem. Phys., 22, 6275–6289, https://doi.org/10.5194/acp-22-6275-2022, https://doi.org/10.5194/acp-22-6275-2022, 2022
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We perform a process-oriented evaluation of Copernicus Atmosphere Monitoring Service (CAMS) reanalysis (CAMSRA) O3 over Europe using WOUDC (World Ozone and Ultraviolet Radiation Data Centre) ozonesondes and IAGOS (In-service Aircraft for a Global Observing System) aircraft measurements. Chemical data assimilation assists CAMSRA to reproduce the observed O3 increases in the troposphere during the examined folding events, but it mostly results in O3 overestimation in the upper troposphere.
Clara M. Nussbaumer, Andrea Pozzer, Ivan Tadic, Lenard Röder, Florian Obersteiner, Hartwig Harder, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 22, 6151–6165, https://doi.org/10.5194/acp-22-6151-2022, https://doi.org/10.5194/acp-22-6151-2022, 2022
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The European COVID-19 lockdowns have significantly reduced the emission of primary pollutants such as NOx, which impacts the tropospheric photochemical processes and the abundance of O3. In this study, we present how the lockdowns have affected tropospheric trace gases and ozone production based on in situ observations and modeling simulations. We additionally show that the chemical regime shifted from a transition point to a NOx limitation in the upper troposphere.
Wenyu Sun, Matias Berasategui, Andrea Pozzer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 22, 4969–4984, https://doi.org/10.5194/acp-22-4969-2022, https://doi.org/10.5194/acp-22-4969-2022, 2022
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The reaction between OH and SO2 is a termolecular process that in the atmosphere results in the formation of H2SO4 and thus aerosols. We present the first temperature- and pressure-dependent measurements of the rate coefficients in N2. This is also the first study to examine the effects of water vapour on the kinetics of this reaction. Our results indicate the rate coefficient is larger than that recommended by evaluation panels, with deviations of up to 30 % in some parts of the atmosphere.
Andrea Pozzer, Simon F. Reifenberg, Vinod Kumar, Bruno Franco, Matthias Kohl, Domenico Taraborrelli, Sergey Gromov, Sebastian Ehrhart, Patrick Jöckel, Rolf Sander, Veronica Fall, Simon Rosanka, Vlassis Karydis, Dimitris Akritidis, Tamara Emmerichs, Monica Crippa, Diego Guizzardi, Johannes W. Kaiser, Lieven Clarisse, Astrid Kiendler-Scharr, Holger Tost, and Alexandra Tsimpidi
Geosci. Model Dev., 15, 2673–2710, https://doi.org/10.5194/gmd-15-2673-2022, https://doi.org/10.5194/gmd-15-2673-2022, 2022
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A newly developed setup of the chemistry general circulation model EMAC (ECHAM5/MESSy for Atmospheric Chemistry) is evaluated here. A comprehensive organic degradation mechanism is used and coupled with a volatility base model.
The results show that the model reproduces most of the tracers and aerosols satisfactorily but shows discrepancies for oxygenated organic gases. It is also shown that this model configuration can be used for further research in atmospheric chemistry.
Guangjie Zheng, Hang Su, Siwen Wang, Andrea Pozzer, and Yafang Cheng
Atmos. Chem. Phys., 22, 47–63, https://doi.org/10.5194/acp-22-47-2022, https://doi.org/10.5194/acp-22-47-2022, 2022
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The recently proposed multiphase buffer theory provides a framework to reconstruct long-term trends and spatial variations in aerosol pH, while non-ideality is a major limitation for its broad applications. Here we proposed a parameterization method to estimate the impact of non-ideality and validated it against long-term observations and global simulations. With this method, the multiphase buffer theory can reproduce well aerosol pH variations estimated by comprehensive thermodynamic models.
Clara M. Nussbaumer, John N. Crowley, Jan Schuladen, Jonathan Williams, Sascha Hafermann, Andreas Reiffs, Raoul Axinte, Hartwig Harder, Cheryl Ernest, Anna Novelli, Katrin Sala, Monica Martinez, Chinmay Mallik, Laura Tomsche, Christian Plass-Dülmer, Birger Bohn, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 21, 18413–18432, https://doi.org/10.5194/acp-21-18413-2021, https://doi.org/10.5194/acp-21-18413-2021, 2021
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HCHO is an important atmospheric trace gas influencing the photochemical processes in the Earth’s atmosphere, including the budget of HOx and the abundance of tropospheric O3. This research presents the photochemical calculations of HCHO and O3 based on three field campaigns across Europe. We show that HCHO production via the oxidation of only four volatile organic compound precursors, i.e., CH4, CH3CHO, C5H8 and CH3OH, can balance the observed loss at all sites well.
Dirk Dienhart, John N. Crowley, Efstratios Bourtsoukidis, Achim Edtbauer, Philipp G. Eger, Lisa Ernle, Hartwig Harder, Bettina Hottmann, Monica Martinez, Uwe Parchatka, Jean-Daniel Paris, Eva Y. Pfannerstill, Roland Rohloff, Jan Schuladen, Christof Stönner, Ivan Tadic, Sebastian Tauer, Nijing Wang, Jonathan Williams, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 21, 17373–17388, https://doi.org/10.5194/acp-21-17373-2021, https://doi.org/10.5194/acp-21-17373-2021, 2021
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We present the first ship-based in situ measurements of formaldehyde (HCHO), hydroxyl radicals (OH) and the OH reactivity around the Arabian Peninsula. Regression analysis of the HCHO production rate and the related OH chemistry revealed the regional HCHO yield αeff, which represents the different chemical regimes encountered. Highest values were found for the Arabian Gulf (also known as the Persian Gulf), which highlights this region as a hotspot of photochemical air pollution.
Clara M. Nussbaumer, Uwe Parchatka, Ivan Tadic, Birger Bohn, Daniel Marno, Monica Martinez, Roland Rohloff, Hartwig Harder, Flora Kluge, Klaus Pfeilsticker, Florian Obersteiner, Martin Zöger, Raphael Doerich, John N. Crowley, Jos Lelieveld, and Horst Fischer
Atmos. Meas. Tech., 14, 6759–6776, https://doi.org/10.5194/amt-14-6759-2021, https://doi.org/10.5194/amt-14-6759-2021, 2021
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NO2 plays a central role in atmospheric photochemical processes and requires accurate measurements. This research presents NO2 data obtained via chemiluminescence using a photolytic converter from airborne studies around Cabo Verde and laboratory investigations. We show the limits and error-proneness of a conventional blue light converter in aircraft measurements affected by humidity and NO levels and suggest the use of an alternative quartz converter for more reliable results.
Vlassis A. Karydis, Alexandra P. Tsimpidi, Andrea Pozzer, and Jos Lelieveld
Atmos. Chem. Phys., 21, 14983–15001, https://doi.org/10.5194/acp-21-14983-2021, https://doi.org/10.5194/acp-21-14983-2021, 2021
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Aerosol particle pH is well-buffered by alkaline compounds, notably NH3 and crustal elements. NH3 is found to supply remarkable buffering capacity on a global scale, from the polluted continents to the remote oceans. Potential future changes in agricultural NH3 must be accompanied by strong reductions of SO2 and NOx to avoid particles becoming highly acidic, with implications for human health (aerosol toxicity), ecosystems (acid deposition), clouds, and climate (aerosol hygroscopicity).
Andrea Pozzer
Geosci. Commun., 4, 453–460, https://doi.org/10.5194/gc-4-453-2021, https://doi.org/10.5194/gc-4-453-2021, 2021
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In this paper we investigate the numbers of pages, references and references per page in open-access EGU journals. We showed that, while the number of references and number of pages have been constantly increasing in the period 2010–2020, the number of references per page did not change in the same period. Furthermore, all the journals showed a similar number of references per page, i.e. ~ 3.8 references per page.
Philipp G. Eger, Luc Vereecken, Rolf Sander, Jan Schuladen, Nicolas Sobanski, Horst Fischer, Einar Karu, Jonathan Williams, Ville Vakkari, Tuukka Petäjä, Jos Lelieveld, Andrea Pozzer, and John N. Crowley
Atmos. Chem. Phys., 21, 14333–14349, https://doi.org/10.5194/acp-21-14333-2021, https://doi.org/10.5194/acp-21-14333-2021, 2021
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We determine the impact of pyruvic acid photolysis on the formation of acetaldehyde and peroxy radicals during summer and autumn in the Finnish boreal forest using a data-constrained box model. Our results are dependent on the chosen scenario in which the overall quantum yield and the photolysis products are varied. We highlight that pyruvic acid photolysis can be an important contributor to acetaldehyde and peroxy radical formation in remote, forested regions.
Jean-Daniel Paris, Aurélie Riandet, Efstratios Bourtsoukidis, Marc Delmotte, Antoine Berchet, Jonathan Williams, Lisa Ernle, Ivan Tadic, Hartwig Harder, and Jos Lelieveld
Atmos. Chem. Phys., 21, 12443–12462, https://doi.org/10.5194/acp-21-12443-2021, https://doi.org/10.5194/acp-21-12443-2021, 2021
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We measured atmospheric methane and CO2 by ship in the Middle East. We probe the origin of methane with a combination of light alkane measurements and modeling. We find strong influence from nearby oil and gas production over the Arabian Gulf. Comparing our data to inventories indicates that inventories overestimate sources from the upstream gas industry but underestimate emissions from oil extraction and processing. The Red Sea was under a complex mixture of sources due to human activity.
Patrick Dewald, Raphael Dörich, Jan Schuladen, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 14, 5501–5519, https://doi.org/10.5194/amt-14-5501-2021, https://doi.org/10.5194/amt-14-5501-2021, 2021
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Organic nitrates generated from the reaction between isoprene and the nitrate radical (ISOP-NITs) were detected via their thermal dissociation in heated quartz inlets to nitrogen dioxide monitored by cavity ring-down spectroscopy. The temperature-dependent dissociation profiles of ISOP-NITs in the presence of ozone (O3) are broad in contrast to narrow profiles of common reference compounds. We demonstrate that this broadening is caused by O3-assisted reactions of ISOP-NITs on quartz surfaces.
Raphael Dörich, Philipp Eger, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 14, 5319–5332, https://doi.org/10.5194/amt-14-5319-2021, https://doi.org/10.5194/amt-14-5319-2021, 2021
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We demonstrate in laboratory experiments that the formation of IOx anions (formed in reactions of I− with O3) or acetate anions (formed e.g. by the reaction of I− with peracetic acid) results in unexpected sensitivity of an iodide chemical ionisation mass spectrometer (I-CIMS) to HNO3 at a mass-to-charge ratio of 62. This helps explain observations of apparent high daytime levels of N2O5. Airborne measurements using I-CIMS confirm these conclusions.
Vinod Kumar, Julia Remmers, Steffen Beirle, Joachim Fallmann, Astrid Kerkweg, Jos Lelieveld, Mariano Mertens, Andrea Pozzer, Benedikt Steil, Marc Barra, Holger Tost, and Thomas Wagner
Atmos. Meas. Tech., 14, 5241–5269, https://doi.org/10.5194/amt-14-5241-2021, https://doi.org/10.5194/amt-14-5241-2021, 2021
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We present high-resolution regional atmospheric chemistry model simulations focused around Germany. We highlight the importance of spatial resolution of the model itself as well as the input emissions inventory and short-scale temporal variability of emissions for simulations. We propose a consistent approach for evaluating the simulated vertical distribution of NO2 using MAX-DOAS measurements while also considering its spatial sensitivity volume and change in sensitivity within this volume.
Simon Rosanka, Bruno Franco, Lieven Clarisse, Pierre-François Coheur, Andrea Pozzer, Andreas Wahner, and Domenico Taraborrelli
Atmos. Chem. Phys., 21, 11257–11288, https://doi.org/10.5194/acp-21-11257-2021, https://doi.org/10.5194/acp-21-11257-2021, 2021
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The strong El Niño in 2015 led to a particular dry season in Indonesia and favoured severe peatland fires. The smouldering conditions of these fires and the high carbon content of peat resulted in high volatile organic compound (VOC) emissions. By using a comprehensive atmospheric model, we show that these emissions have a significant impact on the tropospheric composition and oxidation capacity. These emissions are transported into to the lower stratosphere, resulting in a depletion of ozone.
Klaus Klingmüller and Jos Lelieveld
Geosci. Model Dev., 14, 4429–4441, https://doi.org/10.5194/gmd-14-4429-2021, https://doi.org/10.5194/gmd-14-4429-2021, 2021
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Soil moisture is of great importance for weather and climate. We present a machine learning model that produces accurate predictions of satellite-observed surface soil moisture, based on meteorological data from a climate model. It can be used as soil moisture parametrisation in climate models and to produce comprehensive global soil moisture datasets. Moreover, it may motivate similar applications of machine learning in climate science.
Tamara Emmerichs, Bruno Franco, Catherine Wespes, Vinod Kumar, Andrea Pozzer, Simon Rosanka, and Domenico Taraborrelli
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-584, https://doi.org/10.5194/acp-2021-584, 2021
Revised manuscript not accepted
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Near-surface ozone is a harmful air pollutant and it is strongly affected by radical reactions and surface-atmosphere exchanges which in turn are modulated, directly and indirectly, by weather. Understanding the impact of weather on ozone, and air quality, is thus important also in view of weather extremes. The inclusion of additional ozone-weather links in the global model yields a 2-fold reduction of the ozone bias towards satellite observations.
Ivan Tadic, Clara M. Nussbaumer, Birger Bohn, Hartwig Harder, Daniel Marno, Monica Martinez, Florian Obersteiner, Uwe Parchatka, Andrea Pozzer, Roland Rohloff, Martin Zöger, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 21, 8195–8211, https://doi.org/10.5194/acp-21-8195-2021, https://doi.org/10.5194/acp-21-8195-2021, 2021
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Although mechanisms of tropospheric ozone (O3) formation are well understood, studies reporting on ozone formation derived from field measurements are challenging and remain sparse in number. We use airborne measurements to quantify nitric oxide (NO) and O3 distributions in the upper troposphere over the Atlantic Ocean and western Africa and compare our measurements to model simulations. Our results show that NO and ozone formation are greatest over the tropical areas of western Africa.
Clara M. Nussbaumer, Ivan Tadic, Dirk Dienhart, Nijing Wang, Achim Edtbauer, Lisa Ernle, Jonathan Williams, Florian Obersteiner, Isidoro Gutiérrez-Álvarez, Hartwig Harder, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 21, 7933–7945, https://doi.org/10.5194/acp-21-7933-2021, https://doi.org/10.5194/acp-21-7933-2021, 2021
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Lightning over continental and coastal areas is frequent and accompanied by deep convection, while lightning over marine areas and particularly in tropical cyclones is rare. This research presents in situ observations of the tropical storm Florence 2018 near Cabo Verde. We show the absence of lightning in the tropical storm despite the occurrence of deep convective processes by atmospheric trace gas measurements of O3, NO, CO, H2O2, DMS and CH2I.
Nils Friedrich, Philipp Eger, Justin Shenolikar, Nicolas Sobanski, Jan Schuladen, Dirk Dienhart, Bettina Hottmann, Ivan Tadic, Horst Fischer, Monica Martinez, Roland Rohloff, Sebastian Tauer, Hartwig Harder, Eva Y. Pfannerstill, Nijing Wang, Jonathan Williams, James Brooks, Frank Drewnick, Hang Su, Guo Li, Yafang Cheng, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 21, 7473–7498, https://doi.org/10.5194/acp-21-7473-2021, https://doi.org/10.5194/acp-21-7473-2021, 2021
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This paper uses NOx and NOz measurements from the 2017 AQABA ship campaign in the Mediterranean Sea and around the Arabian Peninsula to examine the influence e.g. of emissions from shipping and oil and gas production. Night-time losses of NOx dominated in the Arabian Gulf and in the Red Sea, whereas daytime losses were more important in the Mediterranean Sea. Nitric acid and organic nitrates were the most prevalent components of NOz.
Jaydeep Singh, Narendra Singh, Narendra Ojha, Amit Sharma, Andrea Pozzer, Nadimpally Kiran Kumar, Kunjukrishnapillai Rajeev, Sachin S. Gunthe, and V. Rao Kotamarthi
Geosci. Model Dev., 14, 1427–1443, https://doi.org/10.5194/gmd-14-1427-2021, https://doi.org/10.5194/gmd-14-1427-2021, 2021
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Atmospheric models often have limitations in simulating the geographically complex and climatically important central Himalayan region. In this direction, we have performed regional modeling at high resolutions to improve the simulation of meteorology and dynamics through a better representation of the topography. The study has implications for further model applications to investigate the effects of anthropogenic pressure over the Himalaya.
Chaim I. Garfinkel, Ohad Harari, Shlomi Ziskin Ziv, Jian Rao, Olaf Morgenstern, Guang Zeng, Simone Tilmes, Douglas Kinnison, Fiona M. O'Connor, Neal Butchart, Makoto Deushi, Patrick Jöckel, Andrea Pozzer, and Sean Davis
Atmos. Chem. Phys., 21, 3725–3740, https://doi.org/10.5194/acp-21-3725-2021, https://doi.org/10.5194/acp-21-3725-2021, 2021
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Water vapor is the dominant greenhouse gas in the atmosphere, and El Niño is the dominant mode of variability in the ocean–atmosphere system. The connection between El Niño and water vapor above ~ 17 km is unclear, with single-model studies reaching a range of conclusions. This study examines this connection in 12 different models. While there are substantial differences among the models, all models appear to capture the fundamental physical processes correctly.
Einar Karu, Mengze Li, Lisa Ernle, Carl A. M. Brenninkmeijer, Jos Lelieveld, and Jonathan Williams
Atmos. Meas. Tech., 14, 1817–1831, https://doi.org/10.5194/amt-14-1817-2021, https://doi.org/10.5194/amt-14-1817-2021, 2021
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A gas measurement device was developed to measure trace gases (ppt level) in the air based on an atomic emission detector. It combines a cryogenic pre-concentrator (CryoTrap), a gas chromatograph (GC), and a new high-resolution atomic emission detector (AED). The CryoTrap–GC–AED instrumental setup, limits of detection, and elemental performance are presented and discussed. Two measurement case studies are reported: one in a Finnish boreal forest and the other based on an aircraft campaign.
Domenico Taraborrelli, David Cabrera-Perez, Sara Bacer, Sergey Gromov, Jos Lelieveld, Rolf Sander, and Andrea Pozzer
Atmos. Chem. Phys., 21, 2615–2636, https://doi.org/10.5194/acp-21-2615-2021, https://doi.org/10.5194/acp-21-2615-2021, 2021
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Atmospheric pollutants from anthropogenic activities and biomass burning are usually regarded as ozone precursors. Monocyclic aromatics are no exception. Calculations with a comprehensive atmospheric model are consistent with this view but only for air masses close to pollution source regions. However, the same model predicts that aromatics, when transported to remote areas, may effectively destroy ozone. This loss of tropospheric ozone rivals the one attributed to bromine.
Sara Bacer, Sylvia C. Sullivan, Odran Sourdeval, Holger Tost, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 21, 1485–1505, https://doi.org/10.5194/acp-21-1485-2021, https://doi.org/10.5194/acp-21-1485-2021, 2021
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We investigate the relative importance of the rates of both microphysical processes and unphysical correction terms that act as sources or sinks of ice crystals in cold clouds. By means of numerical simulations performed with a global chemistry–climate model, we assess the relevance of these rates at global and regional scales. This estimation is of fundamental importance to assign priority to the development of microphysics parameterizations and compare model output with observations.
Klaus Klingmüller, Vlassis A. Karydis, Sara Bacer, Georgiy L. Stenchikov, and Jos Lelieveld
Atmos. Chem. Phys., 20, 15285–15295, https://doi.org/10.5194/acp-20-15285-2020, https://doi.org/10.5194/acp-20-15285-2020, 2020
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Particulate air pollution cools the climate and partially masks the greenhouse warming by reflecting sunlight and enhancing the reflection by clouds. The intensity of this cooling depends on interactions between pollution and desert dust within the atmosphere. Our simulations with a global atmospheric chemistry-climate model indicate that these interactions significantly weaken the cooling.
Matias Berasategui, Damien Amedro, Luc Vereecken, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 13541–13555, https://doi.org/10.5194/acp-20-13541-2020, https://doi.org/10.5194/acp-20-13541-2020, 2020
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Peracetic acid is one of the most abundant organic peroxides in the atmosphere. We combine experiments and theory to show that peracetic acid reacts orders of magnitude more slowly with OH than presently accepted, which results in a significant extension of its atmospheric lifetime.
Bettina Hottmann, Sascha Hafermann, Laura Tomsche, Daniel Marno, Monica Martinez, Hartwig Harder, Andrea Pozzer, Marco Neumaier, Andreas Zahn, Birger Bohn, Greta Stratmann, Helmut Ziereis, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 20, 12655–12673, https://doi.org/10.5194/acp-20-12655-2020, https://doi.org/10.5194/acp-20-12655-2020, 2020
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During OMO we observed enhanced mixing ratios of hydroperoxides (ROOH) in the Asian monsoon anticyclone (AMA) relative to the background. The observed mixing ratios are higher than steady-state calculations and EMAC simulations, especially in the AMA, indicating atmospheric transport of ROOH. Uncertainties in the scavenging efficiencies likely cause deviations from EMAC. Longitudinal gradients indicate a pool of ROOH towards the center of the AMA associated with upwind convection over India.
Nils Friedrich, Ivan Tadic, Jan Schuladen, James Brooks, Eoghan Darbyshire, Frank Drewnick, Horst Fischer, Jos Lelieveld, and John N. Crowley
Atmos. Meas. Tech., 13, 5739–5761, https://doi.org/10.5194/amt-13-5739-2020, https://doi.org/10.5194/amt-13-5739-2020, 2020
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We present a new instrument for the measurement of NOx and NOy based on a combination of the thermal dissociation of NOy to NOx and cavity ring-down spectroscopic detection of NO2. It features a denuder to separate the contributions of gas-phase and particulate nitrates to NOy. We provide a detailed characterization of the instrument and briefly outline results from first deployments.
Cited articles
Ainsworth, E. A., Yendrek, C. R., Sitch, S., Collins, W. J., and Emberson,
L. D.: The effects of tropospheric ozone on net primary productivity and
implications for climate change, Annu. Rev. Plant Biol., 63, 637–661, https://doi.org/10.1146/annurev-arplant-042110-103829, 2012. a, b
Andersen, S. T., Carpenter, L. J., Nelson, B. S., Neves, L., Read, K. A., Reed, C., Ward, M., Rowlinson, M. J., and Lee, J. D.: Long-term NOx measurements in the remote marine tropical troposphere, Atmos. Meas. Tech., 14, 3071–3085, https://doi.org/10.5194/amt-14-3071-2021, 2021. a
Apel, E., Hornbrook, R., Hills, A., Blake, N., Barth, M., Weinheimer, A.,
Cantrell, C., Rutledge, S., Basarab, B., Crawford, J., Diskin, G., Homeyer,
C. R., Campos, T., Flocke, F., Fried, A., Blake, D. R., Brune, W., Pollack,
I., Peischl, J., Ryerson, T., Wennberg, P. O., Crounse, J. D., Wisthaler, A.,
Mikoviny, T., Huey, G., Heikes, B., O'Sullivan, D., and Riemer, D. D.: Upper
tropospheric ozone production from lightning NOx-impacted convection: Smoke
ingestion case study from the DC3 campaign, J. Geophys. Res.-Atmos., 120, 2505–2523, https://doi.org/10.1002/2014JD022121, 2015. a
Brasseur, G. P., Müller, J.-F., and Granier, C.: Atmospheric impact of NOx emissions by subsonic aircraft: A three-dimensional model study, J. Geophys. Res.-Atmospheres, 101, 1423–1428, https://doi.org/10.1029/95JD02363, 1996. a, b
Cazorla, M. and Brune, W. H.: Measurement of Ozone Production Sensor, Atmos. Meas. Tech., 3, 545–555, https://doi.org/10.5194/amt-3-545-2010, 2010. a
Christian, H. J., Blakeslee, R. J., Boccippio, D. J., Boeck, W. L., Buechler,
D. E., Driscoll, K. T., Goodman, S. J., Hall, J. M., Koshak, W. J., Mach,
D. M., and Stewart, M. F.: Global frequency and distribution of lightning as
observed from space by the Optical Transient Detector, J. Geophys.
Res.-Atmos., 108, 4005,, https://doi.org/10.1029/2002JD002347, 2003. a
Cooper, O. R., Stohl, A., Trainer, M., Thompson, A. M., Witte, J. C., Oltmans, S. J., Morris, G., Pickering, K. E., Crawford, J. H., Chen, G., Cohen, R. C., Bertram, T. H., Wooldridge, P., Perring, A., Brune, W. H., Merrill, J., Moody, J. L., Tarasick, D., Nédélec, P., Forbes, G., Newchurch, M. J., Schmidlin, F. J., Johnson, B. J., Turquety, S., Baughcum, S. L., Ren, X., Fehsenfeld, F. C., Meagher, J. F., Spichtinger, N., Brown, C. C., McKeen,
S. A., McDermid, I. S., and Leblanc, T.: Large upper tropospheric ozone
enhancements above midlatitude North America during summer: In situ evidence
from the IONS and MOZAIC ozone measurement network, J. Geophys. Res.-Atmos., 111, D24S05, https://doi.org/10.1029/2006JD007306, 2006. a
Cooper, O. R., Parrish, D., Ziemke, J., Balashov, N., Cupeiro, M., Galbally,
I., Gilge, S., Horowitz, L., Jensen, N., Lamarque, J.-F., Naik, V., Oltmans,
S. J., Schwab, J., Shindell, D. T., Thompson, A. M., Thouret, V., Wang, Y.,
and Zbinden, R. M.: Global distribution and trends of tropospheric ozone: An
observation-based reviewGlobal distribution and trends of tropospheric ozone,
Elementa, 2, 000029, https://doi.org/10.12952/journal.elementa.000029, 2014. a, b
Crutzen, P. J.: Tropospheric ozone: An overview, Springer,
https://doi.org/10.1007/978-94-009-2913-5_1, 1988. a
Dahlmann, K., Grewe, V., Ponater, M., and Matthes, S.: Quantifying the
contributions of individual NOx sources to the trend in ozone radiative
forcing, Atmos. Environ., 45, 2860–2868, https://doi.org/10.1016/j.atmosenv.2011.02.071, 2011. a
Duncan, B. N., Yoshida, Y., Olson, J. R., Sillman, S., Martin, R. V., Lamsal,
L., Hu, Y., Pickering, K. E., Retscher, C., Allen, D. J., and Crawford,
J. H.: Application of OMI observations to a space-based indicator of NOx and VOC controls on surface ozone formation, Atmos. Environ., 44, 2213–2223, https://doi.org/10.1016/j.atmosenv.2010.03.010, 2010. a, b, c, d, e
Dyson, J. E., Whalley, L. K., Slater, E. J., Woodward-Massey, R., Ye, C., Lee, J. D., Squires, F., Hopkins, J. R., Dunmore, R. E., Shaw, M., Hamilton, J. F., Lewis, A. C., Worrall, S. D., Bacak, A., Mehra, A., Bannan, T. J., Coe, H., Percival, C. J., Ouyang, B., Hewitt, C. N., Jones, R. L., Crilley, L. R., Kramer, L. J., Acton, W. J. F., Bloss, W. J., Saksakulkrai, S., Xu, J., Shi, Z., Harrison, R. M., Kotthaus, S., Grimmond, S., Sun, Y., Xu, W., Yue, S., Wei, L., Fu, P., Wang, X., Arnold, S. R., and Heard, D. E.: Impact of HO2 aerosol uptake on radical levels and O3 production during summertime in Beijing, Atmos. Chem. Phys., 23, 5679–5697, https://doi.org/10.5194/acp-23-5679-2023, 2023. a, b
Fischer, H., Kormann, R., Klüpfel, T., Gurk, Ch., Königstedt, R., Parchatka, U., Mühle, J., Rhee, T. S., Brenninkmeijer, C. A. M., Bonasoni, P., and Stohl, A.: Ozone production and trace gas correlations during the June 2000 MINATROC intensive measurement campaign at Mt. Cimone, Atmos. Chem. Phys., 3, 725–738, https://doi.org/10.5194/acp-3-725-2003, 2003. a
Fujita, E. M., Stockwell, W. R., Campbell, D. E., Keislar, R. E., and Lawson,
D. R.: Evolution of the magnitude and spatial extent of the weekend ozone
effect in California's South Coast Air Basin, 1981–2000, J. Air Waste Manage. Assoc., 53, 802–815, https://doi.org/10.1080/10473289.2003.10466225, 2003. a, b
Gough, W. A. and Anderson, V.: Changing Air Quality and the Ozone Weekend
Effect during the COVID-19 Pandemic in Toronto, Ontario, Canada, Climate, 10,
41, https://doi.org/10.3390/cli10030041, 2022. a, b, c
Granier, C., Darras, S., Denier van der Gon, H., Doubalova, J., Elguindi, N.,
Galle, B., Gauss, M., Guevara, M., Jalkanen, J.-P., Kuenen, J., Liousse, C.,
Quack, B., Simpson, D., and Sindelarova, K.: The Copernicus Atmosphere
Monitoring Service global and regional emissions (April 2019 version), Copernicus Atmosphere Monitoring Service (CAMS) report,
https://doi.org/10.24380/d0bn-kx16, 2019. a, b
Grewe, V.: Impact of climate variability on tropospheric ozone, Sci. Total Environ., 374, 167–181, https://doi.org/10.1016/j.scitotenv.2007.01.032, 2007. a
Grewe, V., Brunner, D., Dameris, M., Grenfell, J., Hein, R., Shindell, D., and Staehelin, J.: Origin and variability of upper tropospheric nitrogen oxides and ozone at northern mid-latitudes, Atmos. Environ., 35, 3421–3433,
https://doi.org/10.1016/S1352-2310(01)00134-0, 2001. a
Griffiths, P. T., Murray, L. T., Zeng, G., Shin, Y. M., Abraham, N. L.,
Archibald, A. T., Deushi, M., Emmons, L. K., Galbally, I. E., Hassler, B.,
Horowitz, L. W., Keeble, J., Liu, J., Moeini, O., Naik, V., O'Connor, F. M.,
Oshima, N., Tarasick, D., Tilmes, S., Turnock, S. T., Wild, O., Young, P. J.,
and Zanis, P.: Tropospheric ozone in CMIP6 simulations, Atmos. Chem. Phys., 21, 4187–4218, https://doi.org/10.5194/acp-21-4187-2021, 2021. a
Hao, Y., Zhou, J., Zhou, J., Wang, Y., Yang, S., Huangfu, Y., Li, X., Zhang,
C., Liu, A., Wu, Y., Yang, S., Peng, Y., Qi, J., He, X., Song, X., Chen, Y.,
Yuan, B., and Shao, M.: Measuring and modelling investigation of the Net
Photochemical Ozone Production Rate via an improved dual-channel reaction
chamber technique, Atmos. Chem. Phys. [preprint], https://doi.org/10.5194/acp-2022-823, 2023. a
Henderson, B., Pinder, R., Crooks, J., Cohen, R., Carlton, A., Pye, H., and
Vizuete, W.: Combining Bayesian methods and aircraft observations to
constrain the HO⚫ + NO2 reaction rate, Atmos. Chem. Phys., 12, 653–667, https://doi.org/10.5194/acp-12-653-2012, 2012. a
Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A.,
Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., Schepers, D., Simmons, A., Soci, C., Abdalla, S., Abellan, X., Balsamo, G., Bechtold, P., Biavati, G., Bidlot, J., Bonavita, M., De Chiara, G., Dahlgren, P., Dee, D., Diamantakis, M., Dragani, R., Flemming, J., Forbes, R., Fuentes, M., Geer, A., Haimberger, L., Healy, S., Hogan, R. J., Hólm, E., Janisková, M., Keeley, S., Laloyaux, P., Lopez, P., Lupu, C., Radnoti, G., de Rosnay, P., Rozum, I., Vamborg, F., Villaume, S., and Thépaut, J.-N.: The ERA5 global reanalysis, Q. J. Roy. Meteorol. Soc., 146, 1999–2049, 2020. a
Iglesias-Suarez, F., Kinnison, D. E., Rap, A., Maycock, A. C., Wild, O., and
Young, P. J.: Key drivers of ozone change and its radiative forcing over the
21st century, Atmos. Chem. Phys., 18, 6121–6139, https://doi.org/10.5194/acp-18-6121-2018, 2018. a
Jaeglé, L., Jacob, D. J., Brune, W., Tan, D., Faloona, I., Weinheimer, A., Ridley, B., Campos, T., and Sachse, G.: Sources of HOx and production of ozone in the upper troposphere over the United States, Geophys. Res. Lett., 25, 1709–1712, https://doi.org/10.1029/98GL00041, 1998. a
Jaeglé, L., Jacob, D. J., Brune, W., Faloona, I., Tan, D., Kondo, Y.,
Sachse, G., Anderson, B., Gregory, G., Vay, S., Singh, H., Blake, D., and
Shet, R.: Ozone production in the upper troposphere and the influence of
aircraft during SONEX: Approach of NOx-saturated conditions, Geophys. Res. Lett., 26, 3081–3084, https://doi.org/10.1029/1999GL900451, 1999. a, b, c
Jeuken, A., Siegmund, P., Heijboer, L., Feichter, J., and Bengtsson, L.: On the potential of assimilating meteorological analyses in a global climate model for the purpose of model validation, J. Geophys. Res.-Atmos., 101, 16939–16950, 1996. a
Jin, X., Fiore, A., Boersma, K. F., Smedt, I. D., and Valin, L.: Inferring
Changes in Summertime Surface Ozone–NOx–VOC Chemistry over US Urban Areas from Two Decades of Satellite and Ground-Based Observations, Environ.
Sci. Technol., 54, 6518–6529, https://doi.org/10.1021/acs.est.9b07785, 2020. a, b
Jöckel, P., Tost, H., Pozzer, A., Kunze, M., Kirner, O., Brenninkmeijer,
C. A., Brinkop, S., Cai, D. S., Dyroff, C., Eckstein, J., Frank, F., Garny,
H., Gottschaldt, K.-D., Graf, P., Grewe, V., Kerkweg, A., Kern, B., Matthes,
S., Mertens, M., Meul, S., Neumaier, M., Nützel, M., Oberländer-Hayn, S.,
Ruhnke, R., Runde, T., Sander, R., Scharffe, D., and Zahn, A.: Earth system
chemistry integrated modelling (ESCiMo) with the modular earth submodel
system (MESSy) version 2.51, Geosci. Model Dev., 9, 1153–1200,
https://doi.org/10.5194/gmd-9-1153-2016, 2016. a, b
Jordan, N., Garner, N. M., Matchett, L. C., Tokarek, T. W., Osthoff, H. D.,
Odame-Ankrah, C. A., Grimm, C. E., Pickrell, K. N., Swainson, C., and
Rosentreter, B. W.: Potential interferences in photolytic nitrogen dioxide
converters for ambient air monitoring: Evaluation of a prototype, J. Air Waste Manage. Assoc., 70, 753–764, https://doi.org/10.1080/10962247.2020.1769770, 2020. a
Khodayari, A., Vitt, F., Phoenix, D., and Wuebbles, D. J.: The impact of NOx emissions from lightning on the production of aviation-induced ozone, Atmos. Environ., 187, 410–416, https://doi.org/10.1016/j.atmosenv.2018.05.057,
2018. a
Lacis, A. A., Wuebbles, D. J., and Logan, J. A.: Radiative forcing of climate
by changes in the vertical distribution of ozone, J. Geophys. Res.-Atmos., 95, 9971–9981, https://doi.org/10.1029/JD095iD07p09971, 1990. a
Leighton, P.: Photochemistry of air pollution, Academic Press, Inc., New York, ISBN 978-0124333345, 1961. a
Lelieveld, J. and Dentener, F. J.: What controls tropospheric ozone?, J. Geophys. Res.-Atmos., 105, 3531–3551, https://doi.org/10.1029/1999JD901011, 2000. a
Lelieveld, J. and van Dorland, R.: Ozone chemistry changes in the troposphere
and consequent radiative forcing of climate, in: Atmospheric Ozone as a
Climate Gas: General Circulation Model Simulations, Springer, 227–258, https://doi.org/10.1007/978-3-642-79869-6_16, 1995. a
Lelieveld, J., Bourtsoukidis, E., Brühl, C., Fischer, H., Fuchs, H.,
Harder, H., Hofzumahaus, A., Holland, F., Marno, D., Neumaier, M., Pozzer, A., Schlager, H., Williams, J., Zahn, A., and Ziereis, H.: The South Asian monsoon – pollution pump and purifier, Science, 361, 270–273, 2018. a
Liang, Q., Rodriguez, J., Douglass, A., Crawford, J., Olson, J., Apel, E.,
Bian, H., Blake, D., Brune, W., Chin, M., Colarco, P. R., da Silva, A.,
Diskin, G. S., Duncan, B. N., G.Huey, L., Knapp, D. J., Montzka, D. D.,
Nielsen, J. E., Pawson, S., Riemer, D. D., Weinheimer, A. J., and Wisthaler,
A.: Reactive nitrogen, ozone and ozone production in the Arctic troposphere
and the impact of stratosphere-troposphere exchange, Atmos. Chem. Phys., 11, 13181–13199, https://doi.org/10.5194/acp-11-13181-2011, 2011. a
Lin, X., Trainer, M., and Liu, S.: On the nonlinearity of the tropospheric
ozone production, J. Geophys. Res.-Atmos., 93, 15879–15888, https://doi.org/10.1029/JD093iD12p15879, 1988. a
Liu, S., Trainer, M., Fehsenfeld, F., Parrish, D., Williams, E., Fahey, D. W., Hübler, G., and Murphy, P. C.: Ozone production in the rural troposphere and the implications for regional and global ozone distributions, J. Geophys. Res.-Atmos., 92, 4191–4207, https://doi.org/10.1029/JD092iD04p04191, 1987. a, b, c
Liu, Y., Wang, T., Stavrakou, T., Elguindi, N., Doumbia, T., Granier, C.,
Bouarar, I., Gaubert, B., and Brasseur, G. P.: Diverse response of surface
ozone to COVID-19 lockdown in China, Sci. Total Environ., 789, 147739, https://doi.org/10.1016/j.scitotenv.2021.147739, 2021. a, b
McDonald, B. C., De Gouw, J. A., Gilman, J. B., Jathar, S. H., Akherati, A.,
Cappa, C. D., Jimenez, J. L., Lee-Taylor, J., Hayes, P. L., McKeen, S. A., Cui, Y. Y., Kim, S.-W., Gentner, D. R., Isaacman-VanWertz, G., Goldstein, A. H., Harley, R. A., Frost, G. J., Roberts, J. M., Ryerson, T. B., and Trainer, M.: Volatile chemical products emerging as largest petrochemical source of urban organic emissions, Science, 359, 760–764, https://doi.org/10.1126/science.aaq0524, 2018. a
Milford, J. B., Gao, D., Sillman, S., Blossey, P., and Russell, A. G.: Total
reactive nitrogen (NOy) as an indicator of the sensitivity of ozone to
reductions in hydrocarbon and NOx emissions, J. Geophys. Res.-Atmos., 99, 3533–3542, https://doi.org/10.1029/93JD03224, 1994. a
Mills, G., Pleijel, H., Malley, C. S., Sinha, B., Cooper, O. R., Schultz,
M. G., Neufeld, H. S., Simpson, D., Sharps, K., Feng, Z., Gerosa, G.,
Harmens, H., Kobayashi, K., Saxena, P., Paoletti, E., Sinha, V., and Xu, X.:
Tropospheric Ozone Assessment Report: Present-day tropospheric ozone
distribution and trends relevant to vegetation, Elementa, 6, 47, https://doi.org/10.1525/elementa.302, 2018. a
Miyazaki, K., Eskes, H. J., Sudo, K., and Zhang, C.: Global lightning NOx production estimated by an assimilation of multiple satellite data sets, Atmos. Chem. Phys., 14, 3277–3305, https://doi.org/10.5194/acp-14-3277-2014, 2014. a
Mohnen, V., Goldstein, W., and Wang, W.-C.: Tropospheric ozone and climate
change, Air Waste, 43, 1332–1334, https://doi.org/10.1080/1073161X.1993.10467207, 1993. a
Mollner, A. K., Valluvadasan, S., Feng, L., Sprague, M. K., Okumura, M.,
Milligan, D. B., Bloss, W. J., Sander, S. P., Martien, P. T., Harley, R. A.,
McCoy, A. B., and Carter, W. P. L.: Rate of gas phase association of hydroxyl
radical and nitrogen dioxide, Science, 330, 646–649,
https://doi.org/10.1126/science.1193030, 2010. a
Moxim, W. and Levy, H.: A model analysis of the tropical South Atlantic Ocean
tropospheric ozone maximum: The interaction of transport and chemistry, J. Geophys. Res.-Atmos., 105, 17393–17415, https://doi.org/10.1029/2000JD900175, 2000. a
Murray, L. T.: Lightning NO x and impacts on air quality, Curr. Pollut. Rep., 2, 115–133, https://doi.org/10.1007/s40726-016-0031-7, 2016. a
National Research Council: Rethinking the ozone problem in urban and regional
air pollution, National Academies Press, https://doi.org/10.17226/1889, 1992. a
Nault, B. A., Garland, C., Wooldridge, P. J., Brune, W. H., Campuzano-Jost, P., Crounse, J. D., Day, D. A., Dibb, J., Hall, S. R., Huey, L. G., Jimenez,
J. L., Liu, X., Mao, J., Mikoviny, T., Peischl, J., Pollack, I. B., Ren, X.,
Ryerson, T. B., Scheuer, E., Ullmann, K., Wennberg, P. O., Wisthaler, A.,
Zhang, L., and Cohen, R. C.: Observational Constraints on the Oxidation of NOx in the Upper Troposphere, J. Phys. Chem. A, 120, 1468–1478, https://doi.org/10.1021/acs.jpca.5b07824, 2016. a
Nisbet, E. G., Manning, M. R., Dlugokencky, E. J., Michel, S. E., Lan, X.,
Röckmann, T., van der Denier Gon, H. A., Schmitt, J., Palmer, P. I.,
Dyonisius, M. N., Oh, Y., Fisher, R. E., Lowry, D., France, J. L., White, J.
W. C., Brailsford, G., and Bromley, T.: Atmospheric methane: Comparison
between methane's record in 2006–2022 and during glacial terminations, Global Biogeochem. Cy., 37, e2023GB007875, https://doi.org/10.1029/2023GB007875, 2023. a
Nussbaumer, C. M. and Cohen, R. C.: The Role of Temperature and NOx in Ozone Trends in the Los Angeles Basin, Environ. Sci. Technol., 54, 15652–15659, https://doi.org/10.1021/acs.est.0c04910, 2020. a, b, c
Nussbaumer, C. M., Crowley, J. N., Schuladen, J., Williams, J., Hafermann, S., Reiffs, A., Axinte, R., Harder, H., Ernest, C., Novelli, A., Sala, K., Martinez, M., Mallik, C., Tomsche, L., Plass-Dülmer, C., Bohn, B., Lelieveld, J., and Fischer, H.: Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe, Atmos. Chem. Phys., 21, 18413–18432, https://doi.org/10.5194/acp-21-18413-2021, 2021a. a, b, c
Nussbaumer, C. M., Parchatka, U., Tadic, I., Bohn, B., Marno, D., Martinez, M., Rohloff, R., Harder, H., Kluge, F., Pfeilsticker, K., Obersteiner, F.,
Zöger, M., Doerich, Raphael Crowley, J. N., Lelieveld, J., and Fischer, H.: Modification of a conventional photolytic converter for improving aircraft measurements of NO2 via chemiluminescence, Atmos. Meas. Tech., 14, 6759–6776, https://doi.org/10.5194/amt-14-6759-2021, 2021b. a
Nussbaumer, C. M., Tadic, I., Dienhart, D., Wang, N., Edtbauer, A., Ernle, L., Williams, J., Obersteiner, F., Gutiérrez-Álvarez, I., Harder, H., Lelieveld, J., and Fischer, H.: Measurement report: In situ observations of deep convection without lightning during the tropical cyclone Florence 2018, Atmos. Chem. Phys., 21, 7933–7945, https://doi.org/10.5194/acp-21-7933-2021, 2021c. a, b
Nussbaumer, C. M., Pozzer, A., Tadic, I., Röder, L., Obersteiner, F.,
Harder, H., Lelieveld, J., and Fischer, H.: Tropospheric ozone production and
chemical regime analysis during the COVID-19 lockdown over Europe, Atmos. Chem. Phys., 22, 6151–6165, https://doi.org/10.5194/acp-22-6151-2022, 2022. a, b, c, d, e
Nussbaumer, Clara M., Fischer, Horst, Lelieveld, Jos, and Pozzer, Andrea: Supporting data for: What controls ozone sensitivity in the upper tropical troposphere?, Zenodo [data set], https://doi.org/10.5281/zenodo.8392909, 2023. a
Nuvolone, D., Petri, D., and Voller, F.: The effects of ozone on human health, Environ. Sci. Pollut. Res., 25, 8074–8088, https://doi.org/10.1007/s11356-017-9239-3, 2018. a, b
Peralta, O., Ortínez-Alvarez, A., Torres-Jardón, R., Suárez-Lastra, M., Castro, T., and Ruíz-Suárez, L. G.: Ozone
over Mexico City during the COVID-19 pandemic, Sci. Total Environ., 761, 143183, https://doi.org/10.1016/j.scitotenv.2020.143183, 2021. a
Pickering, K. E., Thompson, A. M., Dickerson, R. R., Luke, W. T., McNamara,
D. P., Greenberg, J. P., and Zimmerman, P. R.: Model calculations of
tropospheric ozone production potential following observed convective events,
J. Geophys. Res.-Atmos., 95, 14049–14062, https://doi.org/10.1029/JD095iD09p14049, 1990. a
Pusede, S. and Cohen, R.: On the observed response of ozone to NOx and VOC reactivity reductions in San Joaquin Valley California 1995–present,
Atmos. Chem. Phys., 12, 8323–8339, https://doi.org/10.5194/acp-12-8323-2012, 2012. a, b, c
Pusede, S. E., Steiner, A. L., and Cohen, R. C.: Temperature and recent trends in the chemistry of continental surface ozone, Chem. Rev., 115, 3898–3918, https://doi.org/10.1021/cr5006815, 2015. a, b, c
Reed, C., Evans, M. J., Carlo, P. D., Lee, J. D., and Carpenter, L. J.:
Interferences in photolytic NO2 measurements: explanation for an apparent missing oxidant?, Atmos. Chem. Phys., 16, 4707–4724,
https://doi.org/10.5194/acp-16-4707-2016, 2016. a
Reifenberg, S. F., Martin, A., Kohl, M., Bacer, S., Hamryszczak, Z., Tadic, I., Röder, L., Crowley, D. J., Fischer, H., Kaiser, K., Schneider, J., Dörich, R., Crowley, J. N., Tomsche, L., Marsing, A., Voigt, C., Zahn, A., Pöhlker, C., Holanda, B. A., Krüger, O., Pöschl, U., Pöhlker, M., Jöckel, P., Dorf, M., Schumann, U., Williams, J., Bohn, B., Curtius, J., Harder, H., Schlager, H., Lelieveld, J., and Pozzer, A.: Numerical simulation of the impact of COVID-19 lockdown on tropospheric composition and aerosol radiative forcing in Europe, Atmos. Chem. Phys., 22, 10901–10917, https://doi.org/10.5194/acp-22-10901-2022, 2022. a
Rowland, S. F.: Stratospheric ozone depletion, Annu. Rev. Phys. Chem., 42, 731–768, https://doi.org/10.1146/annurev.pc.42.100191.003503, 1991. a
Rudlosky, S. D. and Virts, K. S.: Dual geostationary lightning mapper
observations, Mon. Weather Rev., 149, 979–998, 2021. a
Sakamoto, Y., Sadanaga, Y., Li, J., Matsuoka, K., Takemura, M., Fujii, T.,
Nakagawa, M., Kohno, N., Nakashima, Y., Sato, K., Nakayama, T., Kato, S.,
Takami, A., Yoshino, A., Murano, K., and Kajii, Y.: Relative and absolute
sensitivity analysis on ozone production in Tsukuba, a city in Japan, Environ. Sci. Technol., 53, 13629–13635, https://doi.org/10.1021/acs.est.9b03542, 2019. a
Sauvage, B., Martin, R. V., Van Donkelaar, A., and Ziemke, J.: Quantification
of the factors controlling tropical tropospheric ozone and the South Atlantic
maximum, J. Geophys. Res.-Atmos., 112, D11309, https://doi.org/10.1029/2006JD008008, 2007. a
Schumann, U. and Huntrieser, H.: The global lightning-induced nitrogen oxides
source, Atmos. Chem. Phys., 7, 3823–3907, https://doi.org/10.5194/acp-7-3823-2007, 2007. a
Seinfeld, J. H.: Air pollution: A half century of progress, AIChE J., 50, 1096–1108, https://doi.org/10.1002/aic.10102, 2004. a
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from air pollution to climate change, John Wiley & Sons, ISBN 978-1118947401, 1998. a
Shah, V., Jacob, D. J., Dang, R., Lamsal, L. N., Strode, S. A., Steenrod, S. D., Boersma, K. F., Eastham, S. D., Fritz, T. M., Thompson, C., Peischl, J., Bourgeois, I., Pollack, I. B., Nault, B. A., Cohen, R. C., Campuzano-Jost, P., Jimenez, J. L., Andersen, S. T., Carpenter, L. J., Sherwen, T., and Evans, M. J.: Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements, Atmos. Chem. Phys., 23, 1227–1257, https://doi.org/10.5194/acp-23-1227-2023, 2023. a
Sicard, P., Paoletti, E., Agathokleous, E., Araminienė, V., Proietti, C.,
Coulibaly, F., and De Marco, A.: Ozone weekend effect in cities: Deep
insights for urban air pollution control, Environ. Res., 191, 110193, https://doi.org/10.1016/j.envres.2020.110193, 2020. a, b
Sillman, S.: The relation between ozone, NOx and hydrocarbons in urban and polluted rural environments, Atmos. Environ., 33, 1821–1845,
https://doi.org/10.1016/S1352-2310(98)00345-8, 1999. a, b
Sillman, S., Logan, J. A., and Wofsy, S. C.: The sensitivity of ozone to
nitrogen oxides and hydrocarbons in regional ozone episodes, J. Geophys. Res.-Atmos., 95, 1837–1851, https://doi.org/10.1029/JD095iD02p01837, 1990. a
Skeie, R. B., Myhre, G., Hodnebrog, Ø., Cameron-Smith, P. J., Deushi, M.,
Hegglin, M. I., Horowitz, L. W., Kramer, R. J., Michou, M., Mills, M. J., Olivié, D. J. L., O'Connor, F. M., Paynter, D., Samset, B. H., Sellar, A., Shindell, D., Takemura, T., Tilmes, S., and Wu, T.: Historical total ozone radiative forcing derived from CMIP6 simulations, Npj Clim. Atmos. Sci., 3, 32, https://doi.org/10.1038/s41612-020-00131-0, 2020. a
Staehelin, J., Harris, N. R., Appenzeller, C., and Eberhard, J.: Ozone trends: A review, Rev. Geophys., 39, 231–290, https://doi.org/10.1029/1999RG000059,
2001. a, b
Tadic, I., Nussbaumer, C. M., Bohn, B., Harder, H., Marno, D., Martinez, M., Obersteiner, F., Parchatka, U., Pozzer, A., Rohloff, R., Zöger, M., Lelieveld, J., and Fischer, H.: Central role of nitric oxide in ozone production in the upper tropical troposphere over the Atlantic Ocean and western Africa, Atmos. Chem. Phys., 21, 8195–8211, https://doi.org/10.5194/acp-21-8195-2021, 2021. a, b, c
Tonnesen, G. S. and Dennis, R. L.: Analysis of radical propagation efficiency
to assess ozone sensitivity to hydrocarbons and NOx: 1. Local indicators of instantaneous odd oxygen production sensitivity, J. Geophys. Res.-Atmos., 105, 9213–9225, https://doi.org/10.1029/1999JD900371, 2000a. a, b
Tonnesen, G. S. and Dennis, R. L.: Analysis of radical propagation efficiency
to assess ozone sensitivity to hydrocarbons and NOx: 2. Long-lived species as indicators of ozone concentration sensitivity, J. Geophys. Res.-Atmos., 105, 9227–9241, https://doi.org/10.1029/1999JD900372, 2000b. a
Tost, H., Jöckel, P., and Lelieveld, J.: Lightning and convection
parameterisations – uncertainties in global modelling, Atmos. Chem. Phys., 7, 4553–4568, https://doi.org/10.5194/acp-7-4553-2007, 2007. a
Trainer, M., Parrish, D., Buhr, M., Norton, R., Fehsenfeld, F., Anlauf, K.,
Bottenheim, J., Tang, Y., Wiebe, H., Roberts, J., Tanner, R. L., Newman, L., Bowersox, V. C., Meagher, J. F., Olszyna, K. J., Rodgers, M. O., Wang, T., Berresheim, H., Demerjian, K. L., and Roychowdhury, U. K.: Correlation of ozone with NOy in photochemically aged air, J. Geophys. Res.-Atmos., 98, 2917–2925, https://doi.org/10.1029/92JD01910, 1993. a, b
van Dorland, R., Dentener, F. J., and Lelieveld, J.: Radiative forcing due to
tropospheric ozone and sulfate aerosols, J. Geophys. Res.-Atmos., 102, 28079–28100, https://doi.org/10.1029/97JD02499, 1997. a
Vermeuel, M. P., Novak, G. A., Alwe, H. D., Hughes, D. D., Kaleel, R., Dickens, A. F., Kenski, D., Czarnetzki, A. C., Stone, E. A., Stanier, C. O., Pierce, R. B., Millet, D. B., and Bertram, T. H.: Sensitivity of ozone production to NOx and VOC along the Lake Michigan coastline, J. Geophys. Res.-Atmos., 124, 10989–11006, https://doi.org/10.1029/2019JD030842, 2019. a, b
Wang, H., Lu, X., Jacob, D. J., Cooper, O. R., Chang, K.-L., Li, K., Gao, M.,
Liu, Y., Sheng, B., Wu, K., Wu, T., Zhang, J., Sauvage, B., Nédélec, P., Blot, R., and Fan, S.: Global tropospheric ozone trends, attributions, and radiative impacts in 1995–2017: an integrated analysis using aircraft
(IAGOS) observations, ozonesonde, and multi-decadal chemical model
simulations, Atmos. Chem. Phys., 22, 13753–13782,
https://doi.org/10.5194/acp-22-13753-2022, 2022.
a
Wang, J., Ge, B., and Wang, Z.: Ozone production efficiency in highly polluted environments, Curr. Pollut. Rep., 4, 198–207,
https://doi.org/10.1007/s40726-018-0093-9, 2018. a, b
Wang, P., Chen, Y., Hu, J., Zhang, H., and Ying, Q.: Attribution of
tropospheric ozone to NOx and VOC emissions: considering ozone formationin the transition regime, Environ. Sci. Technol., 53, 1404–1412,
https://doi.org/10.1021/acs.est.8b05981, 2018. a, b
Wang, P., Zhu, S., Vrekoussis, M., Brasseur, G. P., Wang, S., and Zhang, H.: Is atmospheric oxidation capacity better in indicating tropospheric O3
formation?, Front. Environ. Sci. Eng., 16, 1–7, https://doi.org/10.1007/s11783-022-1544-5, 2022. a
Wennberg, P., Hanisco, T., Jaegle, L., Jacob, D., Hintsa, E., Lanzendorf, E.,
Anderson, J., Gao, R.-S., Keim, E., Donnelly, S., Negro, L. A. D., Fahey,
D. W., McKeen, S. A., Salawitch, R. J., Webster, C. R., May, R. D., Herman,
R. L., Proffitt, M. H., Margitan, J. J., Atlas, E. L., Schauffeler, S. M.,
Flocke, F., McElroy, C. T., and Bui, T. P.: Hydrogen radicals, nitrogen
radicals, and the production of O3 in the upper troposphere, Science, 279, 49–53, https://doi.org/10.1126/science.279.5347.49, 1998. a
Williams, E. and Sátori, G.: Lightning, thermodynamic and hydrological
comparison of the two tropical continental chimneys, J. Atmos. Sol.-Terr. Phy., 66, 1213–1231, https://doi.org/10.1016/j.jastp.2004.05.015, 2004. a
Wuebbles, D. J.: Weighing functions for ozone depletion and greenhouse gas
effects on climate, Annu. Rev. Energ. Environ., 20, 45–70,
https://doi.org/10.1146/annurev.eg.20.110195.000401, 1995. a
Xue, J., Zhao, T., Luo, Y., Miao, C., Su, P., Liu, F., Zhang, G., Qin, S.,
Song, Y., Bu, N., et al.: Identification of ozone sensitivity for NO2 and secondary HCHO based on MAX-DOAS measurements in northeast China, Environ. Int., 160, 107048, https://doi.org/10.1016/j.envint.2021.107048, 2022. a, b
Yan, Y. Y.: Intertropical Convergence Zone (ITCZ), Springer
Netherlands, Dordrecht, 429–432, https://doi.org/10.1007/1-4020-3266-8_110, 2005. a, b
Young, P. J., Archibald, A. T., Bowman, K. W., Lamarque, J.-F., Naik, V., Stevenson, D. S., Tilmes, S., Voulgarakis, A., Wild, O., Bergmann, D., Cameron-Smith, P., Cionni, I., Collins, W. J., Dalsøren, S. B., Doherty, R. M., Eyring, V., Faluvegi, G., Horowitz, L. W., Josse, B., Lee, Y. H., MacKenzie, I. A., Nagashima, T., Plummer, D. A., Righi, M., Rumbold, S. T., Skeie, R. B., Shindell, D. T., Strode, S. A., Sudo, K., Szopa, S., and Zeng, G.: Pre-industrial to end 21st century projections of tropospheric ozone from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP), Atmos. Chem. Phys., 13, 2063–2090, https://doi.org/10.5194/acp-13-2063-2013, 2013. a
Short summary
Ozone is a greenhouse gas and contributes to the earth’s radiative energy budget and therefore to global warming. This effect is the largest in the upper troposphere. In this study, we investigate the processes controlling ozone formation and the sensitivity to its precursors in the upper tropical troposphere based on model simulations by the ECHAM5/MESSy2 Atmospheric Chemistry (EMAC) model. We find that NO𝑥 emissions from lightning most importantly affect ozone chemistry at these altitudes.
Ozone is a greenhouse gas and contributes to the earth’s radiative energy budget and therefore...
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