Articles | Volume 18, issue 6
https://doi.org/10.5194/acp-18-4039-2018
https://doi.org/10.5194/acp-18-4039-2018
Research article
 | 
22 Mar 2018
Research article |  | 22 Mar 2018

A self-consistent, multivariate method for the determination of gas-phase rate coefficients, applied to reactions of atmospheric VOCs and the hydroxyl radical

Jacob T. Shaw, Richard T. Lidster, Danny R. Cryer, Noelia Ramirez, Fiona C. Whiting, Graham A. Boustead, Lisa K. Whalley, Trevor Ingham, Andrew R. Rickard, Rachel E. Dunmore, Dwayne E. Heard, Ally C. Lewis, Lucy J. Carpenter, Jacqui F. Hamilton, and Terry J. Dillon

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Cited articles

Aschmann, S. M. and Atkinson, R.: Rate constants for the gas-phase reactions of OH radicals with E-7-tetradecene, 2-methyl-1-tridecene and the C7-C14 1-alkenes at 295 ± 1 K, Phys. Chem. Chem. Phys., 10, 4159–4164, https://doi.org/10.1039/B803527J, 2008.
Atkinson, R.: Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions, Chem. Rev., 86, 69–201, https://doi.org/10.1021/cr00071a004, 1986.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006.
Braure, T., Bedjanian, Y., Romanias, M. N., Morin, J., Riffault, V., Tomas, A., and Coddeville, P.: Experimental study of the reactions of limonene with OH and OH radicals: kinetics and products, J. Phys. Chem. A, 118, 9482–9490, https://doi.org/10.1021/jp507180g, 2014.
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The lifetime of a chemical in the atmosphere is largely governed by the rate of its reaction...
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