Articles | Volume 16, issue 4
https://doi.org/10.5194/acp-16-2139-2016
https://doi.org/10.5194/acp-16-2139-2016
Research article
 | 
24 Feb 2016
Research article |  | 24 Feb 2016

Secondary formation of nitrated phenols: insights from observations during the Uintah Basin Winter Ozone Study (UBWOS) 2014

Bin Yuan, John Liggio, Jeremy Wentzell, Shao-Meng Li, Harald Stark, James M. Roberts, Jessica Gilman, Brian Lerner, Carsten Warneke, Rui Li, Amy Leithead, Hans D. Osthoff, Robert Wild, Steven S. Brown, and Joost A. de Gouw

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Cited articles

Atkinson, R., Aschmann, S. M., and Arey, J.: Reactions of hydroxyl and nitrogen trioxide radicals with phenol, cresols, and 2-nitrophenol at 296 ± 2 K, Environ. Sci. Technol., 26, 1397–1403, https://doi.org/10.1021/es00031a018, 1992.
Bardini, P.: Atmospheric Chemistry of Dimethylphenols & Nitrophenols, PhD, University College Cork, Corcaigh, 1–156, 2006.
Bartmess, J. E.: Negative Ion Energetics Data, NIST Chemistry WebBook, NIST Standard Reference Database Number 69, edited by: Linstrom, P. J. and Mallard, W. G., National Institute of Standards and Technology, Gaithersburg MD, 20899, available at: http://webbook.nist.gov, last access: 28 August 2015.
Bejan, I., Abd El Aal, Y., Barnes, I., Benter, T., Bohn, B., Wiesen, P., and Kleffmann, J.: The photolysis of ortho-nitrophenols: a new gas phase source of HONO, Phys. Chem. Chem. Phys., 8, 2028–2035, 2006.
Bejan, I., Barnes, I., Olariu, R., Zhou, S., Wiesen, P., and Benter, T.: Investigations on the gas-phase photolysis and OH radical kinetics of methyl-2-nitrophenols, Phys. Chem. Chem. Phys., 9, 5686–5692, https://doi.org/10.1039/B709464G, 2007.
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We describe high-resolution measurements of nitrated phenols using a time-of-flight chemical ionization mass spectrometer (ToF-CIMS). Strong diurnal profiles were observed for nitrated phenols, with concentration maxima at night. Box model simulations were able to reproduce the measured nitrated phenols.
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