Articles | Volume 20, issue 19
https://doi.org/10.5194/acp-20-11451-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-20-11451-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Oct 2020
Research article |
| 07 Oct 2020
| 07 Oct 2020
Formation and sink of glyoxal and methylglyoxal in a polluted subtropical environment: observation-based photochemical analysis and impact evaluation
Zhenhao Ling
School of Atmospheric Sciences, Guangdong Province Key Laboratory
for Climate Change and Natural Disaster Studies, Sun Yat-sen University and
Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai),
Zhuhai, China
Qianqian Xie
Institute for Environmental and Climate Research, Jinan
University, Guangzhou, China
Min Shao
Institute for Environmental and Climate Research, Jinan
University, Guangzhou, China
Guangdong-Hongkong-Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou, China
Division of Environment and Sustainability, The Hong Kong University
of Science and Technology, Hong Kong, China
Guangdong-Hongkong-Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou, China
Department of Civil and Environmental Engineering, Hong Kong
Polytechnic University, Hong Kong, China
Department of Civil and Environmental Engineering, Hong Kong
Polytechnic University, Hong Kong, China
Xuemei Wang
CORRESPONDING AUTHOR
Institute for Environmental and Climate Research, Jinan
University, Guangzhou, China
Guangdong-Hongkong-Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou, China
Related authors
Jie Wang, Haichao Wang, Yee Jun Tham, Lili Ming, Zelong Zheng, Guizhen Fang, Cuizhi Sun, Zhenhao Ling, Jun Zhao, and Shaojia Fan
Atmos. Chem. Phys., 24, 977–992, https://doi.org/10.5194/acp-24-977-2024, https://doi.org/10.5194/acp-24-977-2024, 2024
Short summary
Short summary
Many works report NO3 chemistry in inland regions while less target marine regions. We measured N2O5 and related species on a typical island and found intensive nighttime chemistry and rapid NO3 loss. NO contributed significantly to NO3 loss despite its sub-ppbv level, suggesting nocturnal NO3 reactions would be largely enhanced once free from NO emissions in the open ocean. This highlights the strong influences of urban outflow on downward marine areas in terms of nighttime chemistry.
Qiuyue Zhao, Jun Bi, Qian Liu, Zhenghao Ling, Guofeng Shen, Feng Chen, Yuezhen Qiao, Chunyan Li, and Zongwei Ma
Atmos. Chem. Phys., 20, 3905–3919, https://doi.org/10.5194/acp-20-3905-2020, https://doi.org/10.5194/acp-20-3905-2020, 2020
Short summary
Short summary
Understanding the composition, temporal variability and source apportionment of volatile organic compounds (VOCs) is necessary for determining effective control measures to minimize VOCs and their related photochemical pollution. This study conducted source apportionments of VOCs and evaluated their contributions to ozone formation at an urban site in Nanjing with data from 1-year of field measurements.
Zhuoran He, Xuemei Wang, Zhenhao Ling, Jun Zhao, Hai Guo, Min Shao, and Zhe Wang
Atmos. Chem. Phys., 19, 8801–8816, https://doi.org/10.5194/acp-19-8801-2019, https://doi.org/10.5194/acp-19-8801-2019, 2019
Short summary
Short summary
In this study, source apportionment of volatile organic compounds (VOCs) and their contributions to photochemical O3 formation were analyzed by the positive matrix factorization model and an observation-based model using data collected at a receptor site in the Pearl River Delta (PRD) region. Furthermore, the policies for controlling VOCs are briefly reviewed. The findings could provide quantitative information for devising appropriate measures against VOCs, NOx and O3 pollution in the PRD.
Liqing Wu, Xuemei Wang, Sihua Lu, Min Shao, and Zhenhao Ling
Atmos. Chem. Phys., 19, 8141–8161, https://doi.org/10.5194/acp-19-8141-2019, https://doi.org/10.5194/acp-19-8141-2019, 2019
Short summary
Short summary
Semi-volatile and intermediate-volatility organic compounds (S–IVOCs) are considered critical precursors of secondary organic aerosol (SOA), which is an important component of fine particulate matter (PM2.5). In this study, an emission inventory of S–IVOCs in the Pearl River Delta (PRD) region was developed for the first time for the year 2010, while the contributions of S–IVOCs to SOA formation was evaluated by the WRF-Chem model.
Yiming Liu, Qi Fan, Xiaoyang Chen, Jun Zhao, Zhenhao Ling, Yingying Hong, Weibiao Li, Xunlai Chen, Mingjie Wang, and Xiaolin Wei
Atmos. Chem. Phys., 18, 2709–2724, https://doi.org/10.5194/acp-18-2709-2018, https://doi.org/10.5194/acp-18-2709-2018, 2018
Short summary
Short summary
We develop the Anthropogenic Chlorine Emission Inventory for China (ACEIC) for the first time, including the emissions of HCl and Cl2 from coal combustion and prescribed waste incineration. We incorporate the ACEIC into the CMAQ model and find that it potentially increases the 1 h O3 concentration by up to ~ 8 ppbv in China. This study highlights the need for the inclusion of anthropogenic chlorine emission in air quality modeling and demonstrates its importance in tropospheric O3 formation.
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2755, https://doi.org/10.5194/egusphere-2024-2755, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were made based on a 325 m tower in urban Beijing. Vertical changes in concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Mingxue Li, Men Xia, Chunshui Lin, Yifan Jiang, Weihang Sun, Yurun Wang, Yingnan Zhang, Maoxia He, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3137, https://doi.org/10.5194/egusphere-2024-3137, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Our field campaigns observed a strong diel pattern of chloroacetic acid as well as a strong correlation between its level and those of reactive chlorine species at a coastal site. Using quantum chemical calculations and box model simulation with updated MCM, we found that the formation pathway of chloroacetic acid involved multiphase processes. Our study deepens the understanding of atmospheric VOC-Cl chemistry and highlights the crucial role of multiphase reactions in atmospheric chemistry.
Zhouxing Zou, Tianshu Chen, Qianjie Chen, Weihang Sun, Shichun Han, Zhuoyue Ren, Xinyi Li, Wei Song, Aoqi Ge, Qi Wang, Xiao Tian, Chenglei Pei, Xinming Wang, Yanli Zhang, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3210, https://doi.org/10.5194/egusphere-2024-3210, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
We measured ambient OH and HO2 concentrations at a subtropical rural site and compared our observations with model results. During warm periods, the model overestimated the concentrations of OH and HO2, leading to overestimation of ozone and nitric acid production. Our findings highlight the need to better understand how OH and HO2are formed and removed, which is important for accurate air quality and climate predictions.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuweng Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-2654, https://doi.org/10.5194/egusphere-2024-2654, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with aerosol water and water-rich fogs and clouds.
Jun Zhou, Chunsheng Zhang, Aiming Liu, Bin Yuan, Yan Wang, Wenjie Wang, Jie-Ping Zhou, Yixin Hao, Xiao-Bing Li, Xianjun He, Xin Song, Yubin Chen, Suxia Yang, Shuchun Yang, Yanfeng Wu, Bin Jiang, Shan Huang, Junwen Liu, Yuwen Peng, Jipeng Qi, Minhui Deng, Bowen Zhong, Yibo Huangfu, and Min Shao
Atmos. Chem. Phys., 24, 9805–9826, https://doi.org/10.5194/acp-24-9805-2024, https://doi.org/10.5194/acp-24-9805-2024, 2024
Short summary
Short summary
In-depth understanding of the near-ground vertical variability in photochemical ozone (O3) formation is crucial for mitigating O3 pollution. Utilizing a self-built vertical observation system, a direct net photochemical O3 production rate detection system, and an observation-based model, we diagnosed the vertical distributions and formation mechanism of net photochemical O3 production rates and sensitivity in the Pearl River Delta region, one of the most O3-polluted areas in China.
Xianzhong Duan, Ming Chang, Guotong Wu, Suping Situ, Shengjie Zhu, Qi Zhang, Yibo Huangfu, Weiwen Wang, Weihua Chen, Bin Yuan, and Xuemei Wang
Atmos. Meas. Tech., 17, 4065–4079, https://doi.org/10.5194/amt-17-4065-2024, https://doi.org/10.5194/amt-17-4065-2024, 2024
Short summary
Short summary
Accurately estimating biogenic volatile organic compound (BVOC) emissions in forest ecosystems has been challenging. This research presents a framework that utilizes drone-based lidar, photogrammetry, and image recognition technologies to identify plant species and estimate BVOC emissions. The largest cumulative isoprene emissions were found in the Myrtaceae family, while those of monoterpenes were from the Rubiaceae family.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
Short summary
Short summary
Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Sihang Wang, Bin Yuan, Xianjun He, Ru Cui, Xin Song, Yubin Chen, Caihong Wu, Chaomin Wang, Yibo Huangfu, Xiao-Bing Li, Boguang Wang, and Min Shao
Atmos. Chem. Phys., 24, 7101–7121, https://doi.org/10.5194/acp-24-7101-2024, https://doi.org/10.5194/acp-24-7101-2024, 2024
Short summary
Short summary
Emissions of reactive organic gases from industrial volatile chemical product sources are measured. There are large differences among these industrial sources. We show that oxygenated species account for significant contributions to reactive organic gas emissions, especially for industrial sources utilizing water-borne chemicals.
Qing Yang, Xiao-Bing Li, Bin Yuan, Xiaoxiao Zhang, Yibo Huangfu, Lei Yang, Xianjun He, Jipeng Qi, and Min Shao
Atmos. Chem. Phys., 24, 6865–6882, https://doi.org/10.5194/acp-24-6865-2024, https://doi.org/10.5194/acp-24-6865-2024, 2024
Short summary
Short summary
Online vertical gradient measurements of formic and isocyanic acids were made based on a 320 m tower in a megacity. Vertical variations and sources of the two acids were analyzed in this study. We find that formic and isocyanic acids exhibited positive vertical gradients and were mainly contributed by photochemical formations. The formation of formic and isocyanic acids was also significantly enhanced in urban regions aloft.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
Short summary
Short summary
This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
Wenjie Wang, Bin Yuan, Hang Su, Yafang Cheng, Jipeng Qi, Sihang Wang, Wei Song, Xinming Wang, Chaoyang Xue, Chaoqun Ma, Fengxia Bao, Hongli Wang, Shengrong Lou, and Min Shao
Atmos. Chem. Phys., 24, 4017–4027, https://doi.org/10.5194/acp-24-4017-2024, https://doi.org/10.5194/acp-24-4017-2024, 2024
Short summary
Short summary
This study investigates the important role of unmeasured volatile organic compounds (VOCs) in ozone formation. Based on results in a megacity of China, we show that unmeasured VOCs can contribute significantly to ozone fomation and also influence the determination of ozone control strategy. Our results show that these unmeasured VOCs are mainly from human sources.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-693, https://doi.org/10.5194/egusphere-2024-693, 2024
Short summary
Short summary
This paper employs a regional chemical transport model to quantify the sensitivity of air pollutants and photochemical parameters to specified emission reductions in China for conditions of winter and summer as representative. The study provides insights into the further air quality control in China with reduced primary emissions.
Liting Yang, Ming Chang, Shuping Situ, Weiwen Wang, and Xuemei Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-28, https://doi.org/10.5194/egusphere-2024-28, 2024
Preprint archived
Short summary
Short summary
The study aims to develop and apply the WRF-uEMEP model to simulate air quality at the city scale, with a focus on Foshan, the city with the highest industrial density. The research process included model development, calibration, and validation using existing air quality data in Foshan. Research shows that WRF-uEMEP model effectively captures the impact of urban structure on air pollutant processes and reveals the spatial and temporal distribution of air pollutants in Foshan.
Jie Wang, Haichao Wang, Yee Jun Tham, Lili Ming, Zelong Zheng, Guizhen Fang, Cuizhi Sun, Zhenhao Ling, Jun Zhao, and Shaojia Fan
Atmos. Chem. Phys., 24, 977–992, https://doi.org/10.5194/acp-24-977-2024, https://doi.org/10.5194/acp-24-977-2024, 2024
Short summary
Short summary
Many works report NO3 chemistry in inland regions while less target marine regions. We measured N2O5 and related species on a typical island and found intensive nighttime chemistry and rapid NO3 loss. NO contributed significantly to NO3 loss despite its sub-ppbv level, suggesting nocturnal NO3 reactions would be largely enhanced once free from NO emissions in the open ocean. This highlights the strong influences of urban outflow on downward marine areas in terms of nighttime chemistry.
Yongliang She, Jingyi Li, Xiaopu Lyu, Hai Guo, Momei Qin, Xiaodong Xie, Kangjia Gong, Fei Ye, Jianjiong Mao, Lin Huang, and Jianlin Hu
Atmos. Chem. Phys., 24, 219–233, https://doi.org/10.5194/acp-24-219-2024, https://doi.org/10.5194/acp-24-219-2024, 2024
Short summary
Short summary
In this study, we use multi-site volatile organic compound (VOC) measurements to evaluate the CMAQ-model-predicted VOCs and assess the impacts of VOC bias on O3 simulation. Our results demonstrate that current modeling setups and emission inventories are likely to underpredict VOC concentrations, and this underprediction of VOCs contributes to lower O3 predictions in China.
Yifan Jiang, Men Xia, Zhe Wang, Penggang Zheng, Yi Chen, and Tao Wang
Atmos. Chem. Phys., 23, 14813–14828, https://doi.org/10.5194/acp-23-14813-2023, https://doi.org/10.5194/acp-23-14813-2023, 2023
Short summary
Short summary
This study provides the first estimate of high rates of formic acid (HCOOH) production from the photochemical aging of real ambient particles and demonstrates the potential importance of this pathway in the formation of HCOOH under ambient conditions. Incorporating this pathway significantly improved the performance of a widely used chemical model. Our solution irradiation experiments demonstrated the importance of nitrate photolysis in HCOOH production via the production of oxidants.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
Atmos. Chem. Phys., 23, 14127–14158, https://doi.org/10.5194/acp-23-14127-2023, https://doi.org/10.5194/acp-23-14127-2023, 2023
Short summary
Short summary
In this study, we used a regional chemical transport model to characterize the different parameters of atmospheric oxidative capacity in recent chemical environments in China. These parameters include the production and destruction rates of ozone and other oxidants, the ozone production efficiency, the OH reactivity, and the length of the reaction chain responsible for the formation of ozone and ROx. They are also affected by the aerosol burden in the atmosphere.
Meng Wang, Yusen Duan, Zhuozhi Zhang, Qi Yuan, Xinwei Li, Shuwen Han, Juntao Huo, Jia Chen, Yanfen Lin, Qingyan Fu, Tao Wang, Junji Cao, and Shun-cheng Lee
Atmos. Chem. Phys., 23, 10313–10324, https://doi.org/10.5194/acp-23-10313-2023, https://doi.org/10.5194/acp-23-10313-2023, 2023
Short summary
Short summary
Hourly elemental carbon (EC) and NOx were continuously measured for 5 years (2016–2020) at a sampling site near a highway in western Shanghai. We use a machine learning model to rebuild the measured EC and NOx, and a business-as-usual (BAU) scenario was assumed in 2020 and compared with the measured EC and NOx.
Yixin Hao, Jun Zhou, Jie-Ping Zhou, Yan Wang, Suxia Yang, Yibo Huangfu, Xiao-Bing Li, Chunsheng Zhang, Aiming Liu, Yanfeng Wu, Yaqing Zhou, Shuchun Yang, Yuwen Peng, Jipeng Qi, Xianjun He, Xin Song, Yubin Chen, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 23, 9891–9910, https://doi.org/10.5194/acp-23-9891-2023, https://doi.org/10.5194/acp-23-9891-2023, 2023
Short summary
Short summary
By employing an improved net photochemical ozone production rate (NPOPR) detection system based on the dual-channel reaction chamber technique, we measured the net photochemical ozone production rate in the Pearl River Delta in China. The photochemical ozone formation mechanisms in the reaction and reference chambers were investigated using the observation-data-constrained box model, which helped us to validate the NPOPR detection system and understand photochemical ozone formation mechanism.
Yiyu Cai, Chenshuo Ye, Wei Chen, Weiwei Hu, Wei Song, Yuwen Peng, Shan Huang, Jipeng Qi, Sihang Wang, Chaomin Wang, Caihong Wu, Zelong Wang, Baolin Wang, Xiaofeng Huang, Lingyan He, Sasho Gligorovski, Bin Yuan, Min Shao, and Xinming Wang
Atmos. Chem. Phys., 23, 8855–8877, https://doi.org/10.5194/acp-23-8855-2023, https://doi.org/10.5194/acp-23-8855-2023, 2023
Short summary
Short summary
We studied the variability and molecular composition of ambient oxidized organic nitrogen (OON) in both gas and particle phases using a state-of-the-art online mass spectrometer in urban air. Biomass burning and secondary formation were found to be the two major sources of OON. Daytime nitrate radical chemistry for OON formation was more important than previously thought. Our results improved the understanding of the sources and molecular composition of OON in the polluted urban atmosphere.
Zhouxing Zou, Qianjie Chen, Men Xia, Qi Yuan, Yi Chen, Yanan Wang, Enyu Xiong, Zhe Wang, and Tao Wang
Atmos. Chem. Phys., 23, 7057–7074, https://doi.org/10.5194/acp-23-7057-2023, https://doi.org/10.5194/acp-23-7057-2023, 2023
Short summary
Short summary
We present OH observation and model simulation results at a coastal site in Hong Kong. The model predicted the OH concentration under high-NOx well but overpredicted it under low-NOx conditions. This implies an insufficient understanding of OH chemistry under low-NOx conditions. We show evidence of missing OH sinks as a possible cause of the overprediction.
Yuting Wang, Yong-Feng Ma, Domingo Muñoz-Esparza, Jianing Dai, Cathy Wing Yi Li, Pablo Lichtig, Roy Chun-Wang Tsang, Chun-Ho Liu, Tao Wang, and Guy Pierre Brasseur
Atmos. Chem. Phys., 23, 5905–5927, https://doi.org/10.5194/acp-23-5905-2023, https://doi.org/10.5194/acp-23-5905-2023, 2023
Short summary
Short summary
Air quality in urban areas is difficult to simulate in coarse-resolution models. This work exploits the WRF (Weather Research and Forecasting) model coupled with a large-eddy simulation (LES) component and online chemistry to perform high-resolution (33.3 m) simulations of air quality in a large city. The evaluation of the simulations with observations shows that increased model resolution improves the representation of the chemical species near the pollution sources.
Tingting Feng, Yingkun Wang, Weiwei Hu, Ming Zhu, Wei Song, Wei Chen, Yanyan Sang, Zheng Fang, Wei Deng, Hua Fang, Xu Yu, Cheng Wu, Bin Yuan, Shan Huang, Min Shao, Xiaofeng Huang, Lingyan He, Young Ro Lee, Lewis Gregory Huey, Francesco Canonaco, Andre S. H. Prevot, and Xinming Wang
Atmos. Chem. Phys., 23, 611–636, https://doi.org/10.5194/acp-23-611-2023, https://doi.org/10.5194/acp-23-611-2023, 2023
Short summary
Short summary
To investigate the impact of aging processes on organic aerosols (OA), we conducted a comprehensive field study at a continental remote site using an on-line mass spectrometer. The results show that OA in the Chinese outflows were strongly influenced by upwind anthropogenic emissions. The aging processes can significantly decrease the OA volatility and result in a varied viscosity of OA under different circumstances, signifying the complex physiochemical properties of OA in aged plumes.
Yongkang Wu, Weihua Chen, Yingchang You, Qianqian Xie, Shiguo Jia, and Xuemei Wang
Atmos. Chem. Phys., 23, 453–469, https://doi.org/10.5194/acp-23-453-2023, https://doi.org/10.5194/acp-23-453-2023, 2023
Short summary
Short summary
Relying on observed and simulated data, we determine the spatiotemporal characteristics of nocturnal O3 increase (NOI) events in the Pearl River Delta region during 2006–2019. Low-level jets and convective storms are the main meteorological processes causing NOI. Daytime O3 is another essential influencing factor. More importantly, a more prominent role of meteorological processes in NOI has been demonstrated. Our study highlights the important role of meteorology in nocturnal O3 pollution.
Yubin Chen, Bin Yuan, Chaomin Wang, Sihang Wang, Xianjun He, Caihong Wu, Xin Song, Yibo Huangfu, Xiao-Bing Li, Yijia Liao, and Min Shao
Atmos. Meas. Tech., 15, 6935–6947, https://doi.org/10.5194/amt-15-6935-2022, https://doi.org/10.5194/amt-15-6935-2022, 2022
Short summary
Short summary
In this study, we demonstrate that selective online measurements of cycloalkanes can be achieved using proton transfer reaction time-of-flight mass spectrometry with NO+ chemical ionization (NO+ PTR-ToF-MS), with fast response and low detection limits. Applications of this method in both urban air and emission sources will be shown.
Haichao Wang, Bin Yuan, E Zheng, Xiaoxiao Zhang, Jie Wang, Keding Lu, Chenshuo Ye, Lei Yang, Shan Huang, Weiwei Hu, Suxia Yang, Yuwen Peng, Jipeng Qi, Sihang Wang, Xianjun He, Yubin Chen, Tiange Li, Wenjie Wang, Yibo Huangfu, Xiaobing Li, Mingfu Cai, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 14837–14858, https://doi.org/10.5194/acp-22-14837-2022, https://doi.org/10.5194/acp-22-14837-2022, 2022
Short summary
Short summary
We present intensive field measurement of ClNO2 in the Pearl River Delta in 2019. Large variation in the level, formation, and atmospheric impacts of ClNO2 was found in different air masses. ClNO2 formation was limited by the particulate chloride (Cl−) and aerosol surface area. Our results reveal that Cl− originated from various anthropogenic emissions rather than sea sources and show minor contribution to the O3 pollution and photochemistry.
Yue Tan and Tao Wang
Atmos. Chem. Phys., 22, 14455–14466, https://doi.org/10.5194/acp-22-14455-2022, https://doi.org/10.5194/acp-22-14455-2022, 2022
Short summary
Short summary
We present a timely analysis of the effects of the recent lockdown in Shanghai on ground-level ozone (O3). Despite a huge reduction in human activity, O3 concentrations frequently exceeded the O3 air quality standard during the 2-month lockdown, implying that future emission reductions similar to those that occurred during the lockdown will not be sufficient to eliminate O3 pollution in many urban areas without the imposition of additional VOC controls or substantial decreases in NOx emissions.
Biao Luo, Ye Kuang, Shan Huang, Qicong Song, Weiwei Hu, Wei Li, Yuwen Peng, Duohong Chen, Dingli Yue, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 22, 12401–12415, https://doi.org/10.5194/acp-22-12401-2022, https://doi.org/10.5194/acp-22-12401-2022, 2022
Short summary
Short summary
We performed comprehensive analysis on biomass burning organic aerosol (BBOA) size distributions, as well as mass scattering and absorption efficiencies, with an improved method of on-line quantification of brown carbon absorptions. Both BBOA volume size distribution and retrieved refractive index depend highly on combustion conditions represented by the black carbon content, which has significant implications for BBOA climate effect simulations.
Qiongqiong Wang, Shan Wang, Yuk Ying Cheng, Hanzhe Chen, Zijing Zhang, Jinjian Li, Dasa Gu, Zhe Wang, and Jian Zhen Yu
Atmos. Chem. Phys., 22, 11239–11253, https://doi.org/10.5194/acp-22-11239-2022, https://doi.org/10.5194/acp-22-11239-2022, 2022
Short summary
Short summary
Secondary organic aerosol (SOA) is often enhanced during fine-particulate-matter (PM2.5) episodes. We examined bi-hourly measurements of SOA molecular tracers in suburban Hong Kong during 11 city-wide PM2.5 episodes. The tracers showed regional characteristics for both anthropogenic and biogenic SOA as well as biomass-burning-derived SOA. Multiple tracers of the same precursor revealed the dominance of low-NOx formation pathways for isoprene SOA and less-aged monoterpene SOA during winter.
Xiao-Bing Li, Bin Yuan, Sihang Wang, Chunlin Wang, Jing Lan, Zhijie Liu, Yongxin Song, Xianjun He, Yibo Huangfu, Chenglei Pei, Peng Cheng, Suxia Yang, Jipeng Qi, Caihong Wu, Shan Huang, Yingchang You, Ming Chang, Huadan Zheng, Wenda Yang, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 22, 10567–10587, https://doi.org/10.5194/acp-22-10567-2022, https://doi.org/10.5194/acp-22-10567-2022, 2022
Short summary
Short summary
High-time-resolution measurements of volatile organic compounds (VOCs) were made using an online mass spectrometer at a 600 m tall tower in urban region. Compositions, temporal variations, and sources of VOCs were quantitatively investigated in this study. We find that VOC measurements in urban regions aloft could better characterize source characteristics of anthropogenic emissions. Our results could provide important implications in making future strategies for control of VOCs.
Yishuo Guo, Chao Yan, Yuliang Liu, Xiaohui Qiao, Feixue Zheng, Ying Zhang, Ying Zhou, Chang Li, Xiaolong Fan, Zhuohui Lin, Zemin Feng, Yusheng Zhang, Penggang Zheng, Linhui Tian, Wei Nie, Zhe Wang, Dandan Huang, Kaspar R. Daellenbach, Lei Yao, Lubna Dada, Federico Bianchi, Jingkun Jiang, Yongchun Liu, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 22, 10077–10097, https://doi.org/10.5194/acp-22-10077-2022, https://doi.org/10.5194/acp-22-10077-2022, 2022
Short summary
Short summary
Gaseous oxygenated organic molecules (OOMs) are able to form atmospheric aerosols, which will impact on human health and climate change. Here, we find that OOMs in urban Beijing are dominated by anthropogenic sources, i.e. aromatic (29 %–41 %) and aliphatic (26 %–41 %) OOMs. They are also the main contributors to the condensational growth of secondary organic aerosols (SOAs). Therefore, the restriction on anthropogenic VOCs is crucial for the reduction of SOAs and haze formation.
Sihang Wang, Bin Yuan, Caihong Wu, Chaomin Wang, Tiange Li, Xianjun He, Yibo Huangfu, Jipeng Qi, Xiao-Bing Li, Qing'e Sha, Manni Zhu, Shengrong Lou, Hongli Wang, Thomas Karl, Martin Graus, Zibing Yuan, and Min Shao
Atmos. Chem. Phys., 22, 9703–9720, https://doi.org/10.5194/acp-22-9703-2022, https://doi.org/10.5194/acp-22-9703-2022, 2022
Short summary
Short summary
Volatile organic compound (VOC) emissions from vehicles are measured using online mass spectrometers. Differences between gasoline and diesel vehicles are observed with higher emission factors of most oxygenated VOCs (OVOCs) and heavier aromatics from diesel vehicles. A higher aromatics / toluene ratio could provide good indicators to distinguish emissions from both vehicle types. We show that OVOCs account for significant contributions to VOC emissions from vehicles, especially diesel vehicles.
Yihang Yu, Peng Cheng, Huirong Li, Wenda Yang, Baobin Han, Wei Song, Weiwei Hu, Xinming Wang, Bin Yuan, Min Shao, Zhijiong Huang, Zhen Li, Junyu Zheng, Haichao Wang, and Xiaofang Yu
Atmos. Chem. Phys., 22, 8951–8971, https://doi.org/10.5194/acp-22-8951-2022, https://doi.org/10.5194/acp-22-8951-2022, 2022
Short summary
Short summary
We have investigated the budget of HONO at an urban site in Guangzhou. Budget and comprehensive uncertainty analysis suggest that at such locations as ours, HONO direct emissions and NO + OH can become comparable or even surpass other HONO sources that typically receive greater attention and interest, such as the NO2 heterogeneous source and the unknown daytime photolytic source. Our findings emphasize the need to reduce the uncertainties of both conventional and novel HONO sources and sinks.
Qi Zhang, Shiguo Jia, Weihua Chen, Jingying Mao, Liming Yang, Padmaja Krishnan, Sayantan Sarkar, Min Shao, and Xuemei Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-394, https://doi.org/10.5194/acp-2022-394, 2022
Revised manuscript not accepted
Short summary
Short summary
We use satellite data in the establishment of methylamines marine biological emission (MBE) inventory for the first time, which considers effects of actual marine environment on methylamines emission fluxes. MBE fluxes of monomethylamine and trimethylamines can be comparable with or even higher than that of terrestrial anthropogenic emissions , while for dimethylamines, the ocean acts as a sink. Wind and Chlorophyll-a were potentially the most important factors affecting MBE fluxes.
Mingfu Cai, Shan Huang, Baoling Liang, Qibin Sun, Li Liu, Bin Yuan, Min Shao, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Zelong Wang, Duohong Chen, Haobo Tan, Hanbin Xu, Fei Li, Xuejiao Deng, Tao Deng, Jiaren Sun, and Jun Zhao
Atmos. Chem. Phys., 22, 8117–8136, https://doi.org/10.5194/acp-22-8117-2022, https://doi.org/10.5194/acp-22-8117-2022, 2022
Short summary
Short summary
This study investigated the size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei (CCN) activity. We found that the physical properties of OA could vary in a large range at different particle sizes and affected the number concentration of CCN (NCCN) at all supersaturations. Our results highlight the importance of evaluating the atmospheric evolution processes of OA at different size ranges and their impact on climate effects.
Li Liu, Ye Kuang, Miaomiao Zhai, Biao Xue, Yao He, Jun Tao, Biao Luo, Wanyun Xu, Jiangchuan Tao, Changqin Yin, Fei Li, Hanbing Xu, Tao Deng, Xuejiao Deng, Haobo Tan, and Min Shao
Atmos. Chem. Phys., 22, 7713–7726, https://doi.org/10.5194/acp-22-7713-2022, https://doi.org/10.5194/acp-22-7713-2022, 2022
Short summary
Short summary
Using simultaneous measurements of a humidified nephelometer system and an aerosol chemical speciation monitor in winter in Guangzhou, the strongest scattering ability of more oxidized oxygenated organic aerosol (MOOA) among aerosol components considering their dry-state scattering ability and water uptake ability was revealed, leading to large impacts of MOOA on visibility degradation. This has important implications for visibility improvement in China and aerosol radiative effect simulation.
Suxia Yang, Bin Yuan, Yuwen Peng, Shan Huang, Wei Chen, Weiwei Hu, Chenglei Pei, Jun Zhou, David D. Parrish, Wenjie Wang, Xianjun He, Chunlei Cheng, Xiao-Bing Li, Xiaoyun Yang, Yu Song, Haichao Wang, Jipeng Qi, Baolin Wang, Chen Wang, Chaomin Wang, Zelong Wang, Tiange Li, E Zheng, Sihang Wang, Caihong Wu, Mingfu Cai, Chenshuo Ye, Wei Song, Peng Cheng, Duohong Chen, Xinming Wang, Zhanyi Zhang, Xuemei Wang, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4539–4556, https://doi.org/10.5194/acp-22-4539-2022, https://doi.org/10.5194/acp-22-4539-2022, 2022
Short summary
Short summary
We use a model constrained using observations to study the formation of nitrate aerosol in and downwind of a representative megacity. We found different contributions of various chemical reactions to ground-level nitrate concentrations between urban and suburban regions. We also show that controlling VOC emissions are effective for decreasing nitrate formation in both urban and regional environments, although VOCs are not direct precursors of nitrate aerosol.
Wenjie Wang, Bin Yuan, Yuwen Peng, Hang Su, Yafang Cheng, Suxia Yang, Caihong Wu, Jipeng Qi, Fengxia Bao, Yibo Huangfu, Chaomin Wang, Chenshuo Ye, Zelong Wang, Baolin Wang, Xinming Wang, Wei Song, Weiwei Hu, Peng Cheng, Manni Zhu, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 22, 4117–4128, https://doi.org/10.5194/acp-22-4117-2022, https://doi.org/10.5194/acp-22-4117-2022, 2022
Short summary
Short summary
From thorough measurements of numerous oxygenated volatile organic compounds, we show that their photodissociation can be important for radical production and ozone formation in the atmosphere. This effect was underestimated in previous studies, as measurements of them were lacking.
Ming Chang, Jiachen Cao, Qi Zhang, Weihua Chen, Guotong Wu, Liping Wu, Weiwen Wang, and Xuemei Wang
Geosci. Model Dev., 15, 787–801, https://doi.org/10.5194/gmd-15-787-2022, https://doi.org/10.5194/gmd-15-787-2022, 2022
Short summary
Short summary
Despite the importance of nitrogen deposition, its simulation is still insufficiently represented in current atmospheric chemistry models. In this study, the improvement of the canopy stomatal resistance mechanism and the nitrogen-limiting schemes in Noah-MP-WDDM v1.42 give new options for simulating nitrogen dry deposition velocity. This study finds that the combined BN-23 mechanism agrees better with the observed NO2 dry deposition velocity, with the mean bias reduced by 50.1 %.
Men Xia, Xiang Peng, Weihao Wang, Chuan Yu, Zhe Wang, Yee Jun Tham, Jianmin Chen, Hui Chen, Yujing Mu, Chenglong Zhang, Pengfei Liu, Likun Xue, Xinfeng Wang, Jian Gao, Hong Li, and Tao Wang
Atmos. Chem. Phys., 21, 15985–16000, https://doi.org/10.5194/acp-21-15985-2021, https://doi.org/10.5194/acp-21-15985-2021, 2021
Short summary
Short summary
ClNO2 is an important precursor of chlorine radical that affects photochemistry. However, its production and impact are not well understood. Our study presents field observations of ClNO2 at three sites in northern China. These observations provide new insights into nighttime processes that produce ClNO2 and the significant impact of ClNO2 on secondary pollutions during daytime. The results improve the understanding of photochemical pollution in the lower part of the atmosphere.
Yuliang Liu, Wei Nie, Yuanyuan Li, Dafeng Ge, Chong Liu, Zhengning Xu, Liangduo Chen, Tianyi Wang, Lei Wang, Peng Sun, Ximeng Qi, Jiaping Wang, Zheng Xu, Jian Yuan, Chao Yan, Yanjun Zhang, Dandan Huang, Zhe Wang, Neil M. Donahue, Douglas Worsnop, Xuguang Chi, Mikael Ehn, and Aijun Ding
Atmos. Chem. Phys., 21, 14789–14814, https://doi.org/10.5194/acp-21-14789-2021, https://doi.org/10.5194/acp-21-14789-2021, 2021
Short summary
Short summary
Oxygenated organic molecules (OOMs) are crucial intermediates linking volatile organic compounds to secondary organic aerosols. Using nitrate time-of-flight chemical ionization mass spectrometry in eastern China, we performed positive matrix factorization (PMF) on binned OOM mass spectra. We reconstructed over 1000 molecules from 14 derived PMF factors and identified about 72 % of the observed OOMs as organic nitrates, highlighting the decisive role of NOx in OOM formation in populated areas.
Ziwei Mo, Ru Cui, Bin Yuan, Huihua Cai, Brian C. McDonald, Meng Li, Junyu Zheng, and Min Shao
Atmos. Chem. Phys., 21, 13655–13666, https://doi.org/10.5194/acp-21-13655-2021, https://doi.org/10.5194/acp-21-13655-2021, 2021
Short summary
Short summary
There is a lack of detailed understanding of NMVOC emissions from the use of volatile chemical products (VCPs) in China. This study used a mass balance method to compile a long-term emission inventory for solvent use (including coatings, adhesives, inks, pesticides, cleaners and personal care products) in China during 2000–2017. The striking growth and recent trend of solvent use NMVOC emissions can give important implications for air quality modeling and NMVOC control strategies in China.
Thierno Doumbia, Claire Granier, Nellie Elguindi, Idir Bouarar, Sabine Darras, Guy Brasseur, Benjamin Gaubert, Yiming Liu, Xiaoqin Shi, Trissevgeni Stavrakou, Simone Tilmes, Forrest Lacey, Adrien Deroubaix, and Tao Wang
Earth Syst. Sci. Data, 13, 4191–4206, https://doi.org/10.5194/essd-13-4191-2021, https://doi.org/10.5194/essd-13-4191-2021, 2021
Short summary
Short summary
Most countries around the world have implemented control measures to combat the spread of the COVID-19 pandemic, resulting in significant changes in economic and personal activities. We developed the CONFORM (COvid-19 adjustmeNt Factors fOR eMissions) dataset to account for changes in emissions during lockdowns. This dataset was created with the intention of being directly applicable to existing global and regional inventories used in chemical transport models.
Zhiyong Wu, Leiming Zhang, John T. Walker, Paul A. Makar, Judith A. Perlinger, and Xuemei Wang
Geosci. Model Dev., 14, 5093–5105, https://doi.org/10.5194/gmd-14-5093-2021, https://doi.org/10.5194/gmd-14-5093-2021, 2021
Short summary
Short summary
A community dry deposition algorithm for modeling the gaseous dry deposition process in chemistry transport models was extended to include an additional 12 oxidized volatile organic compounds and hydrogen cyanide based on their physicochemical properties and was then evaluated using field flux measurements over a mixed forest. This study provides a useful tool that is needed in chemistry transport models with increasing complexity for simulating an important atmospheric process.
Luolin Wu, Jian Hang, Xuemei Wang, Min Shao, and Cheng Gong
Geosci. Model Dev., 14, 4655–4681, https://doi.org/10.5194/gmd-14-4655-2021, https://doi.org/10.5194/gmd-14-4655-2021, 2021
Short summary
Short summary
In order to investigate street-scale flow and air quality, this study has developed APFoam 1.0 to examine the reactive pollutant formation and dispersion in the urban area. The model has been validated and shows good agreement with wind tunnel experimental data. Model sensitivity cases reveal that vehicle emissions, background concentrations, and wind conditions are the key factors affecting the photochemical reaction process.
Benjamin A. Nault, Duseong S. Jo, Brian C. McDonald, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Jason C. Schroder, James Allan, Donald R. Blake, Manjula R. Canagaratna, Hugh Coe, Matthew M. Coggon, Peter F. DeCarlo, Glenn S. Diskin, Rachel Dunmore, Frank Flocke, Alan Fried, Jessica B. Gilman, Georgios Gkatzelis, Jacqui F. Hamilton, Thomas F. Hanisco, Patrick L. Hayes, Daven K. Henze, Alma Hodzic, James Hopkins, Min Hu, L. Greggory Huey, B. Thomas Jobson, William C. Kuster, Alastair Lewis, Meng Li, Jin Liao, M. Omar Nawaz, Ilana B. Pollack, Jeffrey Peischl, Bernhard Rappenglück, Claire E. Reeves, Dirk Richter, James M. Roberts, Thomas B. Ryerson, Min Shao, Jacob M. Sommers, James Walega, Carsten Warneke, Petter Weibring, Glenn M. Wolfe, Dominique E. Young, Bin Yuan, Qiang Zhang, Joost A. de Gouw, and Jose L. Jimenez
Atmos. Chem. Phys., 21, 11201–11224, https://doi.org/10.5194/acp-21-11201-2021, https://doi.org/10.5194/acp-21-11201-2021, 2021
Short summary
Short summary
Secondary organic aerosol (SOA) is an important aspect of poor air quality for urban regions around the world, where a large fraction of the population lives. However, there is still large uncertainty in predicting SOA in urban regions. Here, we used data from 11 urban campaigns and show that the variability in SOA production in these regions is predictable and is explained by key emissions. These results are used to estimate the premature mortality associated with SOA in urban regions.
Ye Kuang, Shan Huang, Biao Xue, Biao Luo, Qicong Song, Wei Chen, Weiwei Hu, Wei Li, Pusheng Zhao, Mingfu Cai, Yuwen Peng, Jipeng Qi, Tiange Li, Sihang Wang, Duohong Chen, Dingli Yue, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 21, 10375–10391, https://doi.org/10.5194/acp-21-10375-2021, https://doi.org/10.5194/acp-21-10375-2021, 2021
Short summary
Short summary
We found that organic aerosol factors with identified sources perform much better than oxidation level parameters in characterizing variations in organic aerosol hygroscopicity, and secondary aerosol formations associated with different sources have distinct effects on organic aerosol hygroscopicity. It reveals that source-oriented organic aerosol hygroscopicity investigations might result in more appropriate parameterization approaches in chemical and climate models.
Jianing Dai and Tao Wang
Atmos. Chem. Phys., 21, 8747–8759, https://doi.org/10.5194/acp-21-8747-2021, https://doi.org/10.5194/acp-21-8747-2021, 2021
Short summary
Short summary
We used the WRF–Chem model with the latest HONO and ClNO2 processes to investigate their effects on the concentrations of ROx radicals, O3, and PM2.5 in Asia during summer. The results show that the ship-derived HONO and ClNO2 increased the ROx radical concentration by 2–3 times and subsequently increased the O3 and PM2.5 concentrations in marine areas. These findings indicate the importance of these nitrogen processes in the evaluation of the impact of ship emissions on air quality.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Zhe Wang, Junichi Kurokawa, Jiani Tan, Kan Huang, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 21, 8709–8734, https://doi.org/10.5194/acp-21-8709-2021, https://doi.org/10.5194/acp-21-8709-2021, 2021
Short summary
Short summary
This study presents the detailed analysis of acid deposition over southeast Asia based on the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Simulated wet deposition is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The difficulties of models to capture observations are related to the model performance on precipitation. The precipitation-adjusted approach was applied, and the distribution of wet deposition was successfully revised.
Mingfu Cai, Baoling Liang, Qibin Sun, Li Liu, Bin Yuan, Min Shao, Shan Huang, Yuwen Peng, Zelong Wang, Haobo Tan, Fei Li, Hanbin Xu, Duohong Chen, and Jun Zhao
Atmos. Chem. Phys., 21, 8575–8592, https://doi.org/10.5194/acp-21-8575-2021, https://doi.org/10.5194/acp-21-8575-2021, 2021
Short summary
Short summary
This study investigated the contribution of new particle formation (NPF) events to the number concentration of cloud condensation nuclei (NCCN) and its controlling factors in the Pearl River Delta region. The results show that the surfactant effect can decrease the critical diameter and significantly increase the NCCN during the NPF event. In addition, the growth rate is founded to be the most important controlling factor that affects NCCN for growth of newly-formed particles to the CCN sizes.
Chenshuo Ye, Bin Yuan, Yi Lin, Zelong Wang, Weiwei Hu, Tiange Li, Wei Chen, Caihong Wu, Chaomin Wang, Shan Huang, Jipeng Qi, Baolin Wang, Chen Wang, Wei Song, Xinming Wang, E Zheng, Jordan E. Krechmer, Penglin Ye, Zhanyi Zhang, Xuemei Wang, Douglas R. Worsnop, and Min Shao
Atmos. Chem. Phys., 21, 8455–8478, https://doi.org/10.5194/acp-21-8455-2021, https://doi.org/10.5194/acp-21-8455-2021, 2021
Short summary
Short summary
We performed measurements of gaseous and particulate organic compounds using a state-of-the-art online mass spectrometer in urban air. Using the dataset, we provide a holistic chemical characterization of oxygenated organic compounds in the polluted urban atmosphere, which can serve as a reference for the future field measurements of organic compounds in cities.
Xuewu Fu, Chen Liu, Hui Zhang, Yue Xu, Hui Zhang, Jun Li, Xiaopu Lyu, Gan Zhang, Hai Guo, Xun Wang, Leiming Zhang, and Xinbin Feng
Atmos. Chem. Phys., 21, 6721–6734, https://doi.org/10.5194/acp-21-6721-2021, https://doi.org/10.5194/acp-21-6721-2021, 2021
Short summary
Short summary
TGM concentrations and isotopic compositions in 10 Chinese cities showed strong seasonality with higher TGM concentrations and Δ199Hg and lower δ202Hg in summer. We found the seasonal variations in TGM concentrations and isotopic compositions were highly related to regional surface Hg(0) emissions, suggesting land surface Hg(0) emissions are an important source of atmospheric TGM that contribute dominantly to the seasonal variations in TGM concentrations and isotopic compositions.
Wenjie Wang, Jipeng Qi, Jun Zhou, Bin Yuan, Yuwen Peng, Sihang Wang, Suxia Yang, Jonathan Williams, Vinayak Sinha, and Min Shao
Atmos. Meas. Tech., 14, 2285–2298, https://doi.org/10.5194/amt-14-2285-2021, https://doi.org/10.5194/amt-14-2285-2021, 2021
Short summary
Short summary
We designed a new reactor for measurements of OH reactivity (i.e., OH radical loss frequency) based on the comparative reactivity method under
high-NOx conditions, such as in cities. We performed a series of laboratory tests to evaluate the new reactor. The new reactor was used in the field and performed well in measuring OH reactivity in air influenced by upwind cities.
Yuting Wang, Yong-Feng Ma, Domingo Muñoz-Esparza, Cathy W. Y. Li, Mary Barth, Tao Wang, and Guy P. Brasseur
Atmos. Chem. Phys., 21, 3531–3553, https://doi.org/10.5194/acp-21-3531-2021, https://doi.org/10.5194/acp-21-3531-2021, 2021
Short summary
Short summary
Large-eddy simulations (LESs) were performed in the mountainous region of the island of Hong Kong to investigate the degree to which the rates of chemical reactions between two reactive species are reduced due to the segregation of species within the convective boundary layer. We show that the inhomogeneity in emissions plays an important role in the segregation effect. Topography also has a significant influence on the segregation locally.
Yujiao Zhu, Likun Xue, Jian Gao, Jianmin Chen, Hongyong Li, Yong Zhao, Zhaoxin Guo, Tianshu Chen, Liang Wen, Penggang Zheng, Ye Shan, Xinfeng Wang, Tao Wang, Xiaohong Yao, and Wenxing Wang
Atmos. Chem. Phys., 21, 1305–1323, https://doi.org/10.5194/acp-21-1305-2021, https://doi.org/10.5194/acp-21-1305-2021, 2021
Short summary
Short summary
This work investigates the long-term changes in new particle formation (NPF) events under reduced SO2 emissions at the summit of Mt. Tai during seven campaigns from 2007 to 2018. We found the NPF intensity increased 2- to 3-fold in 2018 compared to 2007. In contrast, the probability of new particles growing to CCN size largely decreased. Changes to biogenic VOCs and anthropogenic emissions are proposed to explain the distinct NPF characteristics.
Wenjie Wang, David D. Parrish, Xin Li, Min Shao, Ying Liu, Ziwei Mo, Sihua Lu, Min Hu, Xin Fang, Yusheng Wu, Limin Zeng, and Yuanhang Zhang
Atmos. Chem. Phys., 20, 15617–15633, https://doi.org/10.5194/acp-20-15617-2020, https://doi.org/10.5194/acp-20-15617-2020, 2020
Short summary
Short summary
During the past decade, China has devoted very substantial resources to improving the environment. These efforts have improved atmospheric particulate matter loading, but ambient ozone levels have continued to increase. In this paper we investigate the causes of the increasing ozone concentrations through analysis of a data set that is, to our knowledge, unique: a 12-year data set including ground-level O3, NOx, and VOC precursors collected at an urban site in Beijing.
Caihong Wu, Chaomin Wang, Sihang Wang, Wenjie Wang, Bin Yuan, Jipeng Qi, Baolin Wang, Hongli Wang, Chen Wang, Wei Song, Xinming Wang, Weiwei Hu, Shengrong Lou, Chenshuo Ye, Yuwen Peng, Zelong Wang, Yibo Huangfu, Yan Xie, Manni Zhu, Junyu Zheng, Xuemei Wang, Bin Jiang, Zhanyi Zhang, and Min Shao
Atmos. Chem. Phys., 20, 14769–14785, https://doi.org/10.5194/acp-20-14769-2020, https://doi.org/10.5194/acp-20-14769-2020, 2020
Short summary
Short summary
Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Sarah E. Benish, Hao He, Xinrong Ren, Sandra J. Roberts, Ross J. Salawitch, Zhanqing Li, Fei Wang, Yuying Wang, Fang Zhang, Min Shao, Sihua Lu, and Russell R. Dickerson
Atmos. Chem. Phys., 20, 14523–14545, https://doi.org/10.5194/acp-20-14523-2020, https://doi.org/10.5194/acp-20-14523-2020, 2020
Short summary
Short summary
Airborne observations of ozone and related pollutants show smog was pervasive in spring 2016 over Hebei Province, China. We find high amounts of ozone precursors throughout and even above the PBL, continuing to generate ozone at high rates to be potentially transported downwind. Concentrations even in the rural areas of this highly industrialized province promote widespread ozone production, and we show that to improve air quality over Hebei both NOx and VOCs should be targeted.
Chaomin Wang, Bin Yuan, Caihong Wu, Sihang Wang, Jipeng Qi, Baolin Wang, Zelong Wang, Weiwei Hu, Wei Chen, Chenshuo Ye, Wenjie Wang, Yele Sun, Chen Wang, Shan Huang, Wei Song, Xinming Wang, Suxia Yang, Shenyang Zhang, Wanyun Xu, Nan Ma, Zhanyi Zhang, Bin Jiang, Hang Su, Yafang Cheng, Xuemei Wang, and Min Shao
Atmos. Chem. Phys., 20, 14123–14138, https://doi.org/10.5194/acp-20-14123-2020, https://doi.org/10.5194/acp-20-14123-2020, 2020
Short summary
Short summary
We utilized a novel online mass spectrometry method to measure the total concentration of higher alkanes at each carbon number at two different sites in China, allowing us to take into account SOA contributions from all isomers for higher alkanes. We found that higher alkanes account for significant fractions of SOA formation at the two sites. The contributions are comparable to or even higher than single-ring aromatics, the most-recognized SOA precursors in urban air.
Chao Peng, Yu Wang, Zhijun Wu, Lanxiadi Chen, Ru-Jin Huang, Weigang Wang, Zhe Wang, Weiwei Hu, Guohua Zhang, Maofa Ge, Min Hu, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 20, 13877–13903, https://doi.org/10.5194/acp-20-13877-2020, https://doi.org/10.5194/acp-20-13877-2020, 2020
Baozhu Ge, Syuichi Itahashi, Keiichi Sato, Danhui Xu, Junhua Wang, Fan Fan, Qixin Tan, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Jung-Hun Woo, Junichi Kurokawa, Yuepeng Pan, Qizhong Wu, Xuejun Liu, and Zifa Wang
Atmos. Chem. Phys., 20, 10587–10610, https://doi.org/10.5194/acp-20-10587-2020, https://doi.org/10.5194/acp-20-10587-2020, 2020
Short summary
Short summary
Performances of the simulated deposition for different reduced N (Nr) species in China were conducted with the Model Inter-Comparison Study for Asia. Results showed that simulated wet deposition of oxidized N was overestimated in northeastern China and underestimated in south China, but Nr was underpredicted in all regions by all models. Oxidized N has larger uncertainties than Nr, indicating that the chemical reaction process is one of the most importance factors affecting model performance.
Mingfu Cai, Baoling Liang, Qibin Sun, Shengzhen Zhou, Xiaoyang Chen, Bin Yuan, Min Shao, Haobo Tan, and Jun Zhao
Atmos. Chem. Phys., 20, 9153–9167, https://doi.org/10.5194/acp-20-9153-2020, https://doi.org/10.5194/acp-20-9153-2020, 2020
Short summary
Short summary
Cloud condensation nuclei activity in marine atmosphere affects cloud formation and the solar radiation balance over ocean. We employed advanced instruments to measure aerosol hygroscopicity and chemical composition in the northern South China Sea. Our results show that marine aerosols can be affected by local emissions or pollutants from long-range transport. Our study highlights dynamical variations in particle properties and the impact of long-range transport on this region during summertime.
Wei Pu, Zhouxing Zou, Weihao Wang, David Tanner, Zhe Wang, and Tao Wang
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2020-252, https://doi.org/10.5194/amt-2020-252, 2020
Revised manuscript not accepted
Short summary
Short summary
The hydroxyl radical (OH) is responsible for the degradation of trace gases and plays key roles in major environmental issues such as photochemical pollution. However, the measurement of atmospheric OH radical is a huge challenge due to its high reactivity. Our study provides systematic optimization of a chemical ionization mass spectrometer (CIMS) for OH measurement as a reference for other CIMS users. The ambient result demonstrates the capability of the CIMS for ambient OH measurement.
Junchen Guo, Shengzhen Zhou, Mingfu Cai, Jun Zhao, Wei Song, Weixiong Zhao, Weiwei Hu, Yele Sun, Yao He, Chengqiang Yang, Xuezhe Xu, Zhisheng Zhang, Peng Cheng, Qi Fan, Jian Hang, Shaojia Fan, Xinming Wang, and Xuemei Wang
Atmos. Chem. Phys., 20, 7595–7615, https://doi.org/10.5194/acp-20-7595-2020, https://doi.org/10.5194/acp-20-7595-2020, 2020
Short summary
Short summary
We characterized non-refractory submicron particulate matter (PM1.0) during winter in Guangzhou, south China. Chemical composition and key sources of ambient PM1.0 are revealed, highlighting the significant role of SOA. The relationship with SOA and peroxy radicals indicated gas-phase oxidation contributed predominantly to SOA formation during non-pollution periods, while heterogeneous/multiphase reactions played more important roles in SOA formation during pollution periods.
Jiani Tan, Joshua S. Fu, Gregory R. Carmichael, Syuichi Itahashi, Zhining Tao, Kan Huang, Xinyi Dong, Kazuyo Yamaji, Tatsuya Nagashima, Xuemei Wang, Yiming Liu, Hyo-Jung Lee, Chuan-Yao Lin, Baozhu Ge, Mizuo Kajino, Jia Zhu, Meigen Zhang, Hong Liao, and Zifa Wang
Atmos. Chem. Phys., 20, 7393–7410, https://doi.org/10.5194/acp-20-7393-2020, https://doi.org/10.5194/acp-20-7393-2020, 2020
Short summary
Short summary
This study evaluated the performance of 12 chemical transport models from MICS-Asia III for predicting the particulate matter (PM) over East Asia. Four model processes were investigated as the possible reasons for model bias with measurements and the factors causing inconsistent predictions of PM from different models: (1) model inputs, (2) gas–particle conversion, (3) dust emission modules and (4) removal mechanisms (wet and dry depositions). The influence of each process was discussed.
Shengzhen Zhou, Luolin Wu, Junchen Guo, Weihua Chen, Xuemei Wang, Jun Zhao, Yafang Cheng, Zuzhao Huang, Jinpu Zhang, Yele Sun, Pingqing Fu, Shiguo Jia, Jun Tao, Yanning Chen, and Junxia Kuang
Atmos. Chem. Phys., 20, 6435–6453, https://doi.org/10.5194/acp-20-6435-2020, https://doi.org/10.5194/acp-20-6435-2020, 2020
Short summary
Short summary
In this work, measurements of size-segregated aerosols were conducted at three altitudes (ground level, 118 m, and 488 m) on the 610 m high Canton Tower in southern China. Vertical variations of PM and size-segregated chemical compositions were investigated. The results indicated that meteorological parameters and atmospheric aqueous and heterogeneous reactions together led to aerosol formation and haze episodes in the Pearl River Delta region during the measurement periods.
Yiming Liu and Tao Wang
Atmos. Chem. Phys., 20, 6305–6321, https://doi.org/10.5194/acp-20-6305-2020, https://doi.org/10.5194/acp-20-6305-2020, 2020
Short summary
Short summary
This study revealed the effects of changes in meteorology and anthropogenic emissions on the summer ozone variations from 2013 to 2017 across China by conducting numerical experiments. We highlighted the important but varying roles of meteorology in ozone variations attributed to the synergistic or counteracting effects from individual meteorological factors. Developing future ozone pollution mitigation policies should consider the counteracting impact of meteorological changes.
Yiming Liu and Tao Wang
Atmos. Chem. Phys., 20, 6323–6337, https://doi.org/10.5194/acp-20-6323-2020, https://doi.org/10.5194/acp-20-6323-2020, 2020
Short summary
Short summary
Surface ozone levels in urban areas of China were increasing despite the implementation of stringent emission control measures since 2013. Our modeling results show that the decrease in NOx, SO2, and PM emissions and increase in VOC emissions contributed to the urban ozone increases due to the nonlinear ozone chemistry and complex aerosol affects. VOC reduction measures should be implemented in the current and future policies to achieve the goal of improving the overall air quality.
Men Xia, Xiang Peng, Weihao Wang, Chuan Yu, Peng Sun, Yuanyuan Li, Yuliang Liu, Zhengning Xu, Zhe Wang, Zheng Xu, Wei Nie, Aijun Ding, and Tao Wang
Atmos. Chem. Phys., 20, 6147–6158, https://doi.org/10.5194/acp-20-6147-2020, https://doi.org/10.5194/acp-20-6147-2020, 2020
Short summary
Short summary
ClNO2 and Cl2 can be photolyzed by sunlight to produce a highly reactive Cl atom which affects air quality and climate. We observed high ClNO2 and Cl2 concentrations during a recent field study in east China. We analyzed the data and proposed a new hypothesis on the Cl2 production mechanism. Yields of ClNO2 and Cl2 from N2O2 uptake were parameterized using observational constraints, and they can be used in air quality models to improve simulations of atmospheric photochemistry and air quality.
Havala O. T. Pye, Athanasios Nenes, Becky Alexander, Andrew P. Ault, Mary C. Barth, Simon L. Clegg, Jeffrey L. Collett Jr., Kathleen M. Fahey, Christopher J. Hennigan, Hartmut Herrmann, Maria Kanakidou, James T. Kelly, I-Ting Ku, V. Faye McNeill, Nicole Riemer, Thomas Schaefer, Guoliang Shi, Andreas Tilgner, John T. Walker, Tao Wang, Rodney Weber, Jia Xing, Rahul A. Zaveri, and Andreas Zuend
Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, https://doi.org/10.5194/acp-20-4809-2020, 2020
Short summary
Short summary
Acid rain is recognized for its impacts on human health and ecosystems, and programs to mitigate these effects have had implications for atmospheric acidity. Historical measurements indicate that cloud and fog droplet acidity has changed in recent decades in response to controls on emissions from human activity, while the limited trend data for suspended particles indicate acidity may be relatively constant. This review synthesizes knowledge on the acidity of atmospheric particles and clouds.
Chuan Yu, Zhe Wang, Men Xia, Xiao Fu, Weihao Wang, Yee Jun Tham, Tianshu Chen, Penggang Zheng, Hongyong Li, Ye Shan, Xinfeng Wang, Likun Xue, Yan Zhou, Dingli Yue, Yubo Ou, Jian Gao, Keding Lu, Steven S. Brown, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 20, 4367–4378, https://doi.org/10.5194/acp-20-4367-2020, https://doi.org/10.5194/acp-20-4367-2020, 2020
Short summary
Short summary
This study provides a holistic picture of N2O5 heterogeneous uptake on ambient aerosols and the influencing factors under various climatic and chemical conditions in China, and it proposes an observation-based empirical parameterization. The empirical parameterization can be used in air quality models to improve the prediction of PM2.5 and photochemical pollution in China and similar polluted regions of the world.
Qiuyue Zhao, Jun Bi, Qian Liu, Zhenghao Ling, Guofeng Shen, Feng Chen, Yuezhen Qiao, Chunyan Li, and Zongwei Ma
Atmos. Chem. Phys., 20, 3905–3919, https://doi.org/10.5194/acp-20-3905-2020, https://doi.org/10.5194/acp-20-3905-2020, 2020
Short summary
Short summary
Understanding the composition, temporal variability and source apportionment of volatile organic compounds (VOCs) is necessary for determining effective control measures to minimize VOCs and their related photochemical pollution. This study conducted source apportionments of VOCs and evaluated their contributions to ozone formation at an urban site in Nanjing with data from 1-year of field measurements.
Syuichi Itahashi, Baozhu Ge, Keiichi Sato, Joshua S. Fu, Xuemei Wang, Kazuyo Yamaji, Tatsuya Nagashima, Jie Li, Mizuo Kajino, Hong Liao, Meigen Zhang, Zhe Wang, Meng Li, Junichi Kurokawa, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 20, 2667–2693, https://doi.org/10.5194/acp-20-2667-2020, https://doi.org/10.5194/acp-20-2667-2020, 2020
Short summary
Short summary
This study gives an overview of acid deposition from the Model Inter-Comparison Study for Asia (MICS-Asia) phase III. Wet deposition simulated by a total of nine models is evaluated with observation data from the Acid Deposition Monitoring Network in East Asia (EANET). The total deposition maps comparing to emissions over Asia are presented. To seek a way to improve the model performance, ensemble approaches and the precipitation-adjusted method are discussed.
Fan Zhang, Hai Guo, Yingjun Chen, Volker Matthias, Yan Zhang, Xin Yang, and Jianmin Chen
Atmos. Chem. Phys., 20, 1549–1564, https://doi.org/10.5194/acp-20-1549-2020, https://doi.org/10.5194/acp-20-1549-2020, 2020
Short summary
Short summary
Particulate matter (PM) emitted from ships has gained more attention in recent decades. Organic matter, elemental carbon, water-soluble ions and heavy metals in PM and particle numbers are the main points. However, studies of detailed chemical compositions in particles with different size ranges emitted from ships are in shortage. This study could bring new and detailed measurement data into the field of size-segregated particles from ships and be of great source emission interest.
Tao Li, Zhe Wang, Yaru Wang, Chen Wu, Yiheng Liang, Men Xia, Chuan Yu, Hui Yun, Weihao Wang, Yan Wang, Jia Guo, Hartmut Herrmann, and Tao Wang
Atmos. Chem. Phys., 20, 391–407, https://doi.org/10.5194/acp-20-391-2020, https://doi.org/10.5194/acp-20-391-2020, 2020
Short summary
Short summary
This work presents a field study of cloud water chemistry and interactions of cloud, gas, and aerosols in the polluted coastal boundary layer in southern China. Substantial dissolved organic matter in the acidic cloud water was observed, and the gas- and aqueous-phase partitioning of carbonyl compounds was investigated. The results demonstrated the significant role of cloud processing in altering aerosol properties, especially in producing aqueous organics and droplet-mode aerosols.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Joshua S. Fu, Xuemei Wang, Syuichi Itahashi, Kazuyo Yamaji, Tatsuya Nagashima, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Lei Chen, Meigen Zhang, Zhining Tao, Jie Li, Mizuo Kajino, Hong Liao, Zhe Wang, Kengo Sudo, Yuesi Wang, Yuepeng Pan, Guiqian Tang, Meng Li, Qizhong Wu, Baozhu Ge, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 181–202, https://doi.org/10.5194/acp-20-181-2020, https://doi.org/10.5194/acp-20-181-2020, 2020
Short summary
Short summary
Evaluation and uncertainty investigation of NO2, CO and NH3 modeling over China were conducted in this study using 14 chemical transport model results from MICS-Asia III. All models largely underestimated CO concentrations and showed very poor performance in reproducing the observed monthly variations of NH3 concentrations. Potential factors related to such deficiencies are investigated and discussed in this paper.
Luolin Wu, Ming Chang, Xuemei Wang, Jian Hang, Jinpu Zhang, Liqing Wu, and Min Shao
Geosci. Model Dev., 13, 23–40, https://doi.org/10.5194/gmd-13-23-2020, https://doi.org/10.5194/gmd-13-23-2020, 2020
Short summary
Short summary
We developed the Real-time On-road Emission (ROE v1.0) model to obtain the street-scale on-road hot emissions by using real-time big data for traffic provided by the Gaode Map navigation application. The results are close to other emission inventories. Meanwhile, we applied our results to a street-level air quality model for studying the impact of the national holiday traffic volume change on air quality. The model can be further extended to more districts in China or other countries.
Jie Li, Tatsuya Nagashima, Lei Kong, Baozhu Ge, Kazuyo Yamaji, Joshua S. Fu, Xuemei Wang, Qi Fan, Syuichi Itahashi, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Meigen Zhang, Zhining Tao, Mizuo Kajino, Hong Liao, Meng Li, Jung-Hun Woo, Jun-ichi Kurokawa, Zhe Wang, Qizhong Wu, Hajime Akimoto, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 19, 12993–13015, https://doi.org/10.5194/acp-19-12993-2019, https://doi.org/10.5194/acp-19-12993-2019, 2019
Short summary
Short summary
This study evaluated and intercompared 14 CTMs with ozone observations in East Asia, within the framework of the Model Inter-Comparison Study for ASIA Phase III (MICS-Asia III). Potential causes of the discrepancies between model results and observation were investigated by assessing the planetary boundary layer heights, emission fluxes, dry deposition, chemistry and vertical transport among models. Finally, a multi-model estimate of pollution distributions was provided.
Mingjin Tang, Chak K. Chan, Yong Jie Li, Hang Su, Qingxin Ma, Zhijun Wu, Guohua Zhang, Zhe Wang, Maofa Ge, Min Hu, Hong He, and Xinming Wang
Atmos. Chem. Phys., 19, 12631–12686, https://doi.org/10.5194/acp-19-12631-2019, https://doi.org/10.5194/acp-19-12631-2019, 2019
Short summary
Short summary
Hygroscopicity is one of the most important properties of aerosol particles, and a number of experimental techniques, which differ largely in principles, configurations and cost, have been developed to investigate hygroscopic properties of atmospherically relevant particles. Our paper provides a comprehensive and critical review of available techniques for aerosol hygroscopicity studies.
Lei Chen, Yi Gao, Meigen Zhang, Joshua S. Fu, Jia Zhu, Hong Liao, Jialin Li, Kan Huang, Baozhu Ge, Xuemei Wang, Yun Fat Lam, Chuan-Yao Lin, Syuichi Itahashi, Tatsuya Nagashima, Mizuo Kajino, Kazuyo Yamaji, Zifa Wang, and Jun-ichi Kurokawa
Atmos. Chem. Phys., 19, 11911–11937, https://doi.org/10.5194/acp-19-11911-2019, https://doi.org/10.5194/acp-19-11911-2019, 2019
Short summary
Short summary
Simulated aerosol concentrations from 14 CTMs within the framework of MICS-Asia III are detailedly evaluated with an extensive set of measurements in East Asia. Similarities and differences among model performances are also analyzed. Although more considerable capacities for reproducing the aerosol concentrations and their variations are shown in current CTMs than those in MICS-Asia II, more efforts are needed to reduce diversities of simulated aerosol concentrations among air quality models.
Yahui Bian, Zhijiong Huang, Jiamin Ou, Zhuangmin Zhong, Yuanqian Xu, Zhiwei Zhang, Xiao Xiao, Xiao Ye, Yuqi Wu, Xiaohong Yin, Cheng Li, Liangfu Chen, Min Shao, and Junyu Zheng
Atmos. Chem. Phys., 19, 11701–11719, https://doi.org/10.5194/acp-19-11701-2019, https://doi.org/10.5194/acp-19-11701-2019, 2019
Short summary
Short summary
During 2006–2015, emissions of SO2, NOx, PM2.5 and PM10 saw an obvious downtrend. However, most emissions still have large reduction potential. On-road mobile sources and solvent use are the two key sources that should receive more effective control measures in GD. Also, controls measures on VOC and NH3 should be weighted since they still increased in 2006–2015. Since most control measures focused on PRD rather than non-PRD in GD, emissions in non-PRD were increasingly important.
Wenjie Wang, Xin Li, Min Shao, Min Hu, Limin Zeng, Yusheng Wu, and Tianyi Tan
Atmos. Chem. Phys., 19, 9413–9429, https://doi.org/10.5194/acp-19-9413-2019, https://doi.org/10.5194/acp-19-9413-2019, 2019
Short summary
Short summary
We quantitatively evaluated the relationship between photolysis frequencies and AOD based on 4 years of observational data in Beijing. This study concludes that the influence of aerosol on photolysis frequencies and thus on the rate of oxidation of VOCs and NOx to ozone is important for determining the atmospheric effects of controlling the precursor emissions of these two important air pollutants (aerosols and ozone).
Zhuoran He, Xuemei Wang, Zhenhao Ling, Jun Zhao, Hai Guo, Min Shao, and Zhe Wang
Atmos. Chem. Phys., 19, 8801–8816, https://doi.org/10.5194/acp-19-8801-2019, https://doi.org/10.5194/acp-19-8801-2019, 2019
Short summary
Short summary
In this study, source apportionment of volatile organic compounds (VOCs) and their contributions to photochemical O3 formation were analyzed by the positive matrix factorization model and an observation-based model using data collected at a receptor site in the Pearl River Delta (PRD) region. Furthermore, the policies for controlling VOCs are briefly reviewed. The findings could provide quantitative information for devising appropriate measures against VOCs, NOx and O3 pollution in the PRD.
Liqing Wu, Xuemei Wang, Sihua Lu, Min Shao, and Zhenhao Ling
Atmos. Chem. Phys., 19, 8141–8161, https://doi.org/10.5194/acp-19-8141-2019, https://doi.org/10.5194/acp-19-8141-2019, 2019
Short summary
Short summary
Semi-volatile and intermediate-volatility organic compounds (S–IVOCs) are considered critical precursors of secondary organic aerosol (SOA), which is an important component of fine particulate matter (PM2.5). In this study, an emission inventory of S–IVOCs in the Pearl River Delta (PRD) region was developed for the first time for the year 2010, while the contributions of S–IVOCs to SOA formation was evaluated by the WRF-Chem model.
Zhaofeng Tan, Keding Lu, Andreas Hofzumahaus, Hendrik Fuchs, Birger Bohn, Frank Holland, Yuhan Liu, Franz Rohrer, Min Shao, Kang Sun, Yusheng Wu, Limin Zeng, Yinsong Zhang, Qi Zou, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 19, 7129–7150, https://doi.org/10.5194/acp-19-7129-2019, https://doi.org/10.5194/acp-19-7129-2019, 2019
Short summary
Short summary
Atmospheric OH, HO2, and RO2 radicals; OH reactivity; and trace gases measured in the Pearl River Delta in autumn 2014 are used for radical budget analyses. The RO2 budget suggests that unexplained OH reactivity is due to unmeasured volatile organic compounds. The OH budget points to a missing OH source and that of RO2 to a missing RO2 sink at low NO. This could indicate a common, unknown process that converts RO2 to OH without the involvement of NO, which would reduce ozone production by 30 %.
Lu Shen, Daniel J. Jacob, Xiong Liu, Guanyu Huang, Ke Li, Hong Liao, and Tao Wang
Atmos. Chem. Phys., 19, 6551–6560, https://doi.org/10.5194/acp-19-6551-2019, https://doi.org/10.5194/acp-19-6551-2019, 2019
Xufei Liu, Xiaopu Lyu, Yu Wang, Fei Jiang, and Hai Guo
Atmos. Chem. Phys., 19, 5127–5145, https://doi.org/10.5194/acp-19-5127-2019, https://doi.org/10.5194/acp-19-5127-2019, 2019
Xiaopu Lyu, Nan Wang, Hai Guo, Likun Xue, Fei Jiang, Yangzong Zeren, Hairong Cheng, Zhe Cai, Lihui Han, and Ying Zhou
Atmos. Chem. Phys., 19, 3025–3042, https://doi.org/10.5194/acp-19-3025-2019, https://doi.org/10.5194/acp-19-3025-2019, 2019
Short summary
Short summary
Through analyses on the synoptic systems, pollution characteristics of O3 precursors, and modeling of local O3 formation and processes influencing O3 level, we found that this O3 pollution event was induced by a uniform pressure field over the Shandong Peninsula and also aggravated by a low-pressure trough in the last few days. This finding indicated that the NCP might be an O3 source region, which exported photochemical pollution to the adjoining regions or even to the neighboring countries.
Guo Li, Yafang Cheng, Uwe Kuhn, Rongjuan Xu, Yudong Yang, Hannah Meusel, Zhibin Wang, Nan Ma, Yusheng Wu, Meng Li, Jonathan Williams, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Hang Su
Atmos. Chem. Phys., 19, 2209–2232, https://doi.org/10.5194/acp-19-2209-2019, https://doi.org/10.5194/acp-19-2209-2019, 2019
Short summary
Short summary
VOCs play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air–soil exchange of 13 VOCs at ambient air conditions of an urban background site in Beijing.
Xiao Fu, Tao Wang, Li Zhang, Qinyi Li, Zhe Wang, Men Xia, Hui Yun, Weihao Wang, Chuan Yu, Dingli Yue, Yan Zhou, Junyun Zheng, and Rui Han
Atmos. Chem. Phys., 19, 1–14, https://doi.org/10.5194/acp-19-1-2019, https://doi.org/10.5194/acp-19-1-2019, 2019
Short summary
Short summary
This study has identified the major contributors to the observed high HONO levels during a severe winter pollution episode and highlighted the importance of HONO chemistry in the combined photochemical and haze pollution in a subtropical region. It also highlighted the critical need to include and update HONO sources in regional air quality models in order to predict ozone and other secondary pollutants better during heavy pollution events in southern China and similar regions.
Hui Yun, Weihao Wang, Tao Wang, Men Xia, Chuan Yu, Zhe Wang, Steven C. N. Poon, Dingli Yue, and Yan Zhou
Atmos. Chem. Phys., 18, 17515–17527, https://doi.org/10.5194/acp-18-17515-2018, https://doi.org/10.5194/acp-18-17515-2018, 2018
Short summary
Short summary
Based on the data analysis of simultaneous measurement of N2O5 and ClNO2 in a severe winter haze in the Pearl River Delta, this study underscores the importance of N2O5 heterogeneous reactions in nitrate formation and calls for better parameterization of N2O5 heterogeneous chemistry in order to predict haze pollution in China.
Weihao Wang, Zhe Wang, Chuan Yu, Men Xia, Xiang Peng, Yan Zhou, Dingli Yue, Yubo Ou, and Tao Wang
Atmos. Meas. Tech., 11, 5643–5655, https://doi.org/10.5194/amt-11-5643-2018, https://doi.org/10.5194/amt-11-5643-2018, 2018
Short summary
Short summary
This study introduces an in situ experimental approach to direct measurement of N2O5 heterogeneous reactivity in polluted environments. Laboratory tests, model simulations, and field deployment of the method at a polluted site in south China demonstrated its applicability in accurately measuring N2O5 uptake coefficient with high ambient pollutants levels and air mass changes. The introduced method is also applicable to in situ measurement of reactivity of other trace gases on ambient aerosols.
Daocheng Gong, Hao Wang, Shenyang Zhang, Yu Wang, Shaw Chen Liu, Hai Guo, Min Shao, Congrong He, Duohong Chen, Lingyan He, Lei Zhou, Lidia Morawska, Yuanhang Zhang, and Boguang Wang
Atmos. Chem. Phys., 18, 14417–14432, https://doi.org/10.5194/acp-18-14417-2018, https://doi.org/10.5194/acp-18-14417-2018, 2018
Short summary
Short summary
The complex air pollution in the air-polluted Pearl River Delta (PRD) region in southern China has significantly elevated the background atmospheric oxidative capacity of the adjacent forests and subsequently lowered the levels of important biogenic volatile organic compounds, such as isoprene, which probably affect the regional air quality and ecological environment in the long term.
Yee Jun Tham, Zhe Wang, Qinyi Li, Weihao Wang, Xinfeng Wang, Keding Lu, Nan Ma, Chao Yan, Simonas Kecorius, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 18, 13155–13171, https://doi.org/10.5194/acp-18-13155-2018, https://doi.org/10.5194/acp-18-13155-2018, 2018
Short summary
Short summary
This study addresses the limited understanding of heterogeneous N2O5 uptake and ClNO2 production in the polluted environment of China. The results showed that N2O5 uptake and ClNO2 yield cannot be well explained by previous parameterizations and were largely influenced by factors like aerosol water content and biomass burning emission. Our findings illuminate the need to realistically parameterize these heterogeneous processes for better simulation of photochemical and haze pollution in China.
Michael Le Breton, Åsa M. Hallquist, Ravi Kant Pathak, David Simpson, Yujue Wang, John Johansson, Jing Zheng, Yudong Yang, Dongjie Shang, Haichao Wang, Qianyun Liu, Chak Chan, Tao Wang, Thomas J. Bannan, Michael Priestley, Carl J. Percival, Dudley E. Shallcross, Keding Lu, Song Guo, Min Hu, and Mattias Hallquist
Atmos. Chem. Phys., 18, 13013–13030, https://doi.org/10.5194/acp-18-13013-2018, https://doi.org/10.5194/acp-18-13013-2018, 2018
Short summary
Short summary
We apply state-of-the-art chemical characterization to determine the chloride radical production in Beijing via measurement of inorganic halogens at a semi-rural site. The high concentration of inorganic halogens, namely nitryl chloride, enables the production of chlorinated volatile organic compounds which are measured in both the gas and particle phases simultaneously. This enables the secondary production of aerosols via chlorine oxidation to be directly observed in ambient air.
Weiqiang Yang, Yanli Zhang, Xinming Wang, Sheng Li, Ming Zhu, Qingqing Yu, Guanghui Li, Zhonghui Huang, Huina Zhang, Zhenfeng Wu, Wei Song, Jihua Tan, and Min Shao
Atmos. Chem. Phys., 18, 12663–12682, https://doi.org/10.5194/acp-18-12663-2018, https://doi.org/10.5194/acp-18-12663-2018, 2018
Short summary
Short summary
We present observation-based evaluations of the reduction of ambient VOCs under intervention control measures during APEC China 2014 in Beijing and the contributions of emissions from domestic solid fuel burning to ambient VOCs during winter heating. Controlling vehicle exhaust and solvent use was found to be effective in reducing ambient VOCs in non-heating periods, and controlling emissions from residential burning of solid fuels became much more important during winter heating.
Zhaofeng Tan, Franz Rohrer, Keding Lu, Xuefei Ma, Birger Bohn, Sebastian Broch, Huabin Dong, Hendrik Fuchs, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Yuhan Liu, Anna Novelli, Min Shao, Haichao Wang, Yusheng Wu, Limin Zeng, Min Hu, Astrid Kiendler-Scharr, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 18, 12391–12411, https://doi.org/10.5194/acp-18-12391-2018, https://doi.org/10.5194/acp-18-12391-2018, 2018
Short summary
Short summary
We present the first wintertime OH, HO2, and RO2 measurements in Beijing, China. OH concentrations are nearly 2-fold larger than those observed in foreign cities during wintertime. The high OH and large OH reactivities indicate photochemical processes can be effective even during wintertime. A box model largely underestimated HO2 and RO2 concentrations during pollution episodes correlated with high NOx, indicating a deficit current chemistry in the high NOx regime.
Liang Wen, Likun Xue, Xinfeng Wang, Caihong Xu, Tianshu Chen, Lingxiao Yang, Tao Wang, Qingzhu Zhang, and Wenxing Wang
Atmos. Chem. Phys., 18, 11261–11275, https://doi.org/10.5194/acp-18-11261-2018, https://doi.org/10.5194/acp-18-11261-2018, 2018
Short summary
Short summary
We present the first piece of observational evidence of the increasing trend of fine nitrate aerosol in the North China Plain (NCP) during 2005–2015. The summertime nitrate formation mechanism is dissected with a multiphase chemical box model based on observations at three different sites. The nitrate formation is most sensitive to NO2 and to a lesser extent to O3. NH3 plays a significant role in prompting the nitrate formation, but it is usually in excess in summer in the NCP region.
Shiguo Jia, Xuemei Wang, Qi Zhang, Sayantan Sarkar, Luolin Wu, Minjuan Huang, Jinpu Zhang, and Liming Yang
Atmos. Chem. Phys., 18, 11125–11133, https://doi.org/10.5194/acp-18-11125-2018, https://doi.org/10.5194/acp-18-11125-2018, 2018
Short summary
Short summary
Aerosol pH are often directly compared across studies while ignoring the inconsistency in standard states. This study attempts to address this issue by comparing aerosol pH with different standard states on the basis of theoretical considerations followed with a set of field data as an example. Application of a pH standardization protocol including a precise statement of thermodynamic model parameters is recommended to avoid biases in cross-comparison.
Zhuofei Du, Min Hu, Jianfei Peng, Wenbin Zhang, Jing Zheng, Fangting Gu, Yanhong Qin, Yudong Yang, Mengren Li, Yusheng Wu, Min Shao, and Shijin Shuai
Atmos. Chem. Phys., 18, 9011–9023, https://doi.org/10.5194/acp-18-9011-2018, https://doi.org/10.5194/acp-18-9011-2018, 2018
Short summary
Short summary
By combining approaches involving chassis dynamometer measurements and environmental chamber simulations, we find that gasoline direct injection (GDI) vehicles contribute more primary aerosol and secondary organic aerosol than port fuel injection (PFI) vehicles. Our results highlight the considerable potential contribution of GDI vehicles to urban air pollution, since the market share of GDI vehicles will dominate over that of PFI vehicles in the future.
Liwei Wang, Xinfeng Wang, Rongrong Gu, Hao Wang, Lan Yao, Liang Wen, Fanping Zhu, Weihao Wang, Likun Xue, Lingxiao Yang, Keding Lu, Jianmin Chen, Tao Wang, Yuanghang Zhang, and Wenxing Wang
Atmos. Chem. Phys., 18, 4349–4359, https://doi.org/10.5194/acp-18-4349-2018, https://doi.org/10.5194/acp-18-4349-2018, 2018
Short summary
Short summary
This study presents concentrations, variation characteristics, sources and secondary formations of nitrated phenols, a major component of brown carbon, in typical seasons at four sites in northern China. The results highlight the strong influences and contributions of anthropogenic activities, in particular coal combustion and the aging processes, to the atmospheric nitrated phenols in this region.
Hao Wang, Xiaopu Lyu, Hai Guo, Yu Wang, Shichun Zou, Zhenhao Ling, Xinming Wang, Fei Jiang, Yangzong Zeren, Wenzhuo Pan, Xiaobo Huang, and Jin Shen
Atmos. Chem. Phys., 18, 4277–4295, https://doi.org/10.5194/acp-18-4277-2018, https://doi.org/10.5194/acp-18-4277-2018, 2018
Short summary
Short summary
While oceanic air is generally thought to be clean, the air pollution over waters in proximity to the coasts is not well recognized. This research indicated that ozone was higher over South China Sea (SCS) than that in the adjacent continental area, while continental anticyclone, tropical cyclone and land breeze favored O3 formation over SCS. In addition, weaker NO titration and stronger atmospheric oxidative capacity led to higher O3 production efficiency over SCS.
Yiming Liu, Qi Fan, Xiaoyang Chen, Jun Zhao, Zhenhao Ling, Yingying Hong, Weibiao Li, Xunlai Chen, Mingjie Wang, and Xiaolin Wei
Atmos. Chem. Phys., 18, 2709–2724, https://doi.org/10.5194/acp-18-2709-2018, https://doi.org/10.5194/acp-18-2709-2018, 2018
Short summary
Short summary
We develop the Anthropogenic Chlorine Emission Inventory for China (ACEIC) for the first time, including the emissions of HCl and Cl2 from coal combustion and prescribed waste incineration. We incorporate the ACEIC into the CMAQ model and find that it potentially increases the 1 h O3 concentration by up to ~ 8 ppbv in China. This study highlights the need for the inclusion of anthropogenic chlorine emission in air quality modeling and demonstrates its importance in tropospheric O3 formation.
Guo Li, Hang Su, Uwe Kuhn, Hannah Meusel, Markus Ammann, Min Shao, Ulrich Pöschl, and Yafang Cheng
Atmos. Chem. Phys., 18, 2669–2686, https://doi.org/10.5194/acp-18-2669-2018, https://doi.org/10.5194/acp-18-2669-2018, 2018
Short summary
Short summary
Coated-wall flow tube reactors are frequently used to investigate gas uptake and heterogeneous or multiphase reaction kinetics under laminar flow conditions. In previous applications, the effects of coating surface roughness on flow conditions were not well quantified. In this study, a criterion is proposed to eliminate/minimize the potential effects of coating surface roughness on laminar flow in coated-wall flow tube experiments and validate the applications of diffusion correction methods.
Shengzhen Zhou, Perry K. Davy, Minjuan Huang, Jingbo Duan, Xuemei Wang, Qi Fan, Ming Chang, Yiming Liu, Weihua Chen, Shanju Xie, Travis Ancelet, and William J. Trompetter
Atmos. Chem. Phys., 18, 2049–2064, https://doi.org/10.5194/acp-18-2049-2018, https://doi.org/10.5194/acp-18-2049-2018, 2018
Short summary
Short summary
We collected hourly samples of PM2.5 and PM2.5–10 at an industrial city in the PRD, China. The samples were analyzed for black carbon and elemental compositions. Receptor modeling of the dataset by positive matrix factorization was used to identify PM sources. Human health exposure risks to the selected trace elements in PM released from the specific sources were estimated. The source–risk apportionment method helps decision makers to manage air quality more effectively.
Zhe Wang, Weihao Wang, Yee Jun Tham, Qinyi Li, Hao Wang, Liang Wen, Xinfeng Wang, and Tao Wang
Atmos. Chem. Phys., 17, 12361–12378, https://doi.org/10.5194/acp-17-12361-2017, https://doi.org/10.5194/acp-17-12361-2017, 2017
Short summary
Short summary
This work addresses unclear roles of heterogeneous N2O5 reactions and chlorine activation processes in the polluted residual layer from a mountaintop measurement in northern China. The results revealed efficient ClNO2 production in the coal-fired plumes in this region, having large impacts on next-morning photochemistry. Fast heterogeneous N2O5 reactions dominate the nocturnal NOx loss and contribute to substantial nitrate formation, which may boost the haze pollution in northern China.
Yu Wang, Hao Wang, Hai Guo, Xiaopu Lyu, Hairong Cheng, Zhenhao Ling, Peter K. K. Louie, Isobel J. Simpson, Simone Meinardi, and Donald R. Blake
Atmos. Chem. Phys., 17, 10919–10935, https://doi.org/10.5194/acp-17-10919-2017, https://doi.org/10.5194/acp-17-10919-2017, 2017
Short summary
Short summary
Though the Hong Kong government has made great efforts toward a reduction in emissions, ambient O3 levels have presented an increasing trend in the past decade. Data analysis and model simulations indicated that the locally produced O3 in Hong Kong varied by seasons, while regional transport from the PRD region made a substantial contribution to ambient O3 in Hong Kong and even increased in autumn. This long-term study has important implications for other Chinese cities to reduce O3 pollution.
Jianfei Peng, Min Hu, Song Guo, Zhuofei Du, Dongjie Shang, Jing Zheng, Jun Zheng, Limin Zeng, Min Shao, Yusheng Wu, Don Collins, and Renyi Zhang
Atmos. Chem. Phys., 17, 10333–10348, https://doi.org/10.5194/acp-17-10333-2017, https://doi.org/10.5194/acp-17-10333-2017, 2017
Short summary
Short summary
Rapid growth of BC particles was observed in Beijing using a new outdoor chamber, with an average growth rate of 26 ± 11 nm h−1. Secondary organic aerosol (SOA) accounted for more than 90 % of the coating mass. The hygroscopic growth factor of BC particles increased to 1.06–1.08 upon ageing. The κ (kappa) values for BC particles were calculated as only 0.035, indicating that initial photochemical ageing of BC particles does not appreciably alter the particle hygroscopicity in Beijing.
Li Zhang, Qinyi Li, Tao Wang, Ravan Ahmadov, Qiang Zhang, Meng Li, and Mengyao Lv
Atmos. Chem. Phys., 17, 9733–9750, https://doi.org/10.5194/acp-17-9733-2017, https://doi.org/10.5194/acp-17-9733-2017, 2017
Short summary
Short summary
Little is known of the integrated impacts of HONO and ClNO2 on lower-tropospheric ozone so far. In this study, we updated WRF-Chem with the CBMZ_ReNOM module, which considers both the sources and chemistry of HONO and ClNO2. The revised model revealed that the two reactive nitrogen compounds significantly affected the oxidation capacity and ozone formation at the surface and within the lower troposphere over polluted regions and noticeably improved summertime O3 predictions over China.
Yudong Yang, Min Shao, Stephan Keßel, Yue Li, Keding Lu, Sihua Lu, Jonathan Williams, Yuanhang Zhang, Liming Zeng, Anke C. Nölscher, Yusheng Wu, Xuemei Wang, and Junyu Zheng
Atmos. Chem. Phys., 17, 7127–7142, https://doi.org/10.5194/acp-17-7127-2017, https://doi.org/10.5194/acp-17-7127-2017, 2017
Short summary
Short summary
Total OH reactivity is an important parameter to evaluate understanding of atmospheric chemistry, especially the VOC contribution to air pollution. Measured by comparative reactivity methods, total OH reactivity in Beijing and Heshan revealed significant differences between measured and calculated results, such as missing reactivity, which were related to unmeasured primary or secondary species. This missing reactivity would introduce a 21–30 % underestimation for ozone production efficiency.
Jiaping Wang, Aki Virkkula, Yuan Gao, Shuncheng Lee, Yicheng Shen, Xuguang Chi, Wei Nie, Qiang Liu, Zheng Xu, Xin Huang, Tao Wang, Long Cui, and Aijun Ding
Atmos. Chem. Phys., 17, 2653–2671, https://doi.org/10.5194/acp-17-2653-2017, https://doi.org/10.5194/acp-17-2653-2017, 2017
Short summary
Short summary
Multi-year observations at a coastal station in Hong Kong reveals that aerosol optical properties showed clear temporal variations according to the dominant sources of aerosols. LPDM modeling and correlation analysis gave similar signals about the freshness of aerosols during different seasons. Fresh emissions of particles from nearby cities and ship exhausts affected light optical properties and particle size in summer and aged air mass in winter caused larger variability of light extinction.
Zhaofeng Tan, Hendrik Fuchs, Keding Lu, Andreas Hofzumahaus, Birger Bohn, Sebastian Broch, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinsong Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 663–690, https://doi.org/10.5194/acp-17-663-2017, https://doi.org/10.5194/acp-17-663-2017, 2017
Short summary
Short summary
In this study, we performed accurate OH measurements as well as selective HO2 and RO2 measurements at a rural site in North China Plain with state-of-the-art instruments newly developed. We confirmed the previous discovery on the enhancement of the OH in low NOx with which little O3 production was associated, and we found a missing RO2 source in high NOx which promoted higher O3 production. Our results are of vital importance for ozone abatement strategies currently under discussion for China.
Hendrik Fuchs, Zhaofeng Tan, Keding Lu, Birger Bohn, Sebastian Broch, Steven S. Brown, Huabin Dong, Sebastian Gomm, Rolf Häseler, Lingyan He, Andreas Hofzumahaus, Frank Holland, Xin Li, Ying Liu, Sihua Lu, Kyung-Eun Min, Franz Rohrer, Min Shao, Baolin Wang, Ming Wang, Yusheng Wu, Limin Zeng, Yinson Zhang, Andreas Wahner, and Yuanhang Zhang
Atmos. Chem. Phys., 17, 645–661, https://doi.org/10.5194/acp-17-645-2017, https://doi.org/10.5194/acp-17-645-2017, 2017
Short summary
Short summary
OH reactivity was measured during a 1-month long campaign at a rural site in the North China Plain in 2014. OH reactivity measurements are compared to calculations using OH reactant measurements. Good agreement is found indicating that all important OH reactants were measured. In addition, the chemical OH budget is analyzed. In contrast to previous campaigns in China in 2006, no significant imbalance between OH production and destruction is found.
Yee Jun Tham, Zhe Wang, Qinyi Li, Hui Yun, Weihao Wang, Xinfeng Wang, Likun Xue, Keding Lu, Nan Ma, Birger Bohn, Xin Li, Simonas Kecorius, Johannes Größ, Min Shao, Alfred Wiedensohler, Yuanhang Zhang, and Tao Wang
Atmos. Chem. Phys., 16, 14959–14977, https://doi.org/10.5194/acp-16-14959-2016, https://doi.org/10.5194/acp-16-14959-2016, 2016
Short summary
Short summary
This work addresses the unclear global significance of chlorine activation processes in the troposphere. The first high-quality measurement data set of ClNO2 in northern China revealed strong ClNO2 production in the residual layers, and demonstrated its significant effects on radical budget and ozone production. Our findings imply the widespread effects of ClNO2 over the polluted regions of northern China, which may increase photochemical and haze pollution.
Qinyi Li, Li Zhang, Tao Wang, Yee Jun Tham, Ravan Ahmadov, Likun Xue, Qiang Zhang, and Junyu Zheng
Atmos. Chem. Phys., 16, 14875–14890, https://doi.org/10.5194/acp-16-14875-2016, https://doi.org/10.5194/acp-16-14875-2016, 2016
Short summary
Short summary
The regional distributions and impacts of N2O5 and ClNO2 remain poorly understood. To address the problem, we developed a chemical transport model further and conducted the first high-resolution simulation of the distributions of the two species. Our research demonstrated the significant impacts of the two gases on the lifetime of nitrogen oxides, secondary nitrate production and ozone formation in southern China and highlighted the necessity of considering this chemistry in air quality models.
Weihua Chen, Xuemei Wang, Jason Blake Cohen, Shengzhen Zhou, Zhisheng Zhang, Ming Chang, and Chuen-Yu Chan
Atmos. Chem. Phys., 16, 13271–13289, https://doi.org/10.5194/acp-16-13271-2016, https://doi.org/10.5194/acp-16-13271-2016, 2016
Short summary
Short summary
Measurements of size-resolved aerosols (0.25–18 μm) were conducted at three sites (urban, suburban and background sites) in southern China during monsoon season (May–June) in 2010 aqueous-phase reaction was the main formation pathway of droplet mode sulfate. New particle formation, chemical aging, and long-range transport from upwind urban or biomass burning regions were also found to be important in at least some of the sights on some of the sampling days.
Wei Hu, Min Hu, Wei-Wei Hu, Hongya Niu, Jing Zheng, Yusheng Wu, Wentai Chen, Chen Chen, Lingyu Li, Min Shao, Shaodong Xie, and Yuanhang Zhang
Atmos. Chem. Phys., 16, 13213–13230, https://doi.org/10.5194/acp-16-13213-2016, https://doi.org/10.5194/acp-16-13213-2016, 2016
Short summary
Short summary
An Aerodyne high-resolution time-of-flight AMS was deployed at a suburban site in the Sichuan Basin, southwestern China, under high emission intensity, and unique geographical and adverse meteorological conditions. OA was the most abundant component (36 %) in PM1, characterized by a relatively high oxidation state. The contributions of BBOA and BC to PM1 were high in primary emission episodes, highlighting the critical influence of biomass burning.
Xiaopu Lyu, Nan Chen, Hai Guo, Lewei Zeng, Weihao Zhang, Fan Shen, Jihong Quan, and Nan Wang
Atmos. Chem. Phys., 16, 10671–10687, https://doi.org/10.5194/acp-16-10671-2016, https://doi.org/10.5194/acp-16-10671-2016, 2016
Lei Sun, Likun Xue, Tao Wang, Jian Gao, Aijun Ding, Owen R. Cooper, Meiyun Lin, Pengju Xu, Zhe Wang, Xinfeng Wang, Liang Wen, Yanhong Zhu, Tianshu Chen, Lingxiao Yang, Yan Wang, Jianmin Chen, and Wenxing Wang
Atmos. Chem. Phys., 16, 10637–10650, https://doi.org/10.5194/acp-16-10637-2016, https://doi.org/10.5194/acp-16-10637-2016, 2016
Short summary
Short summary
We compiled the available observations of surface O3 at Mt. Tai – the highest mountain in the North China Plain, and found a significant increase of O3 concenrations from 2003 to 2015. The observed O3 increase was mainly due to the increase of O3 precursors, especially VOCs. Our analysis shows that controlling NOx alone, in the absence of VOC controls, is not sufficient to reduce regional O3 levels in North China in a short period.
Guo Li, Hang Su, Xin Li, Uwe Kuhn, Hannah Meusel, Thorsten Hoffmann, Markus Ammann, Ulrich Pöschl, Min Shao, and Yafang Cheng
Atmos. Chem. Phys., 16, 10299–10311, https://doi.org/10.5194/acp-16-10299-2016, https://doi.org/10.5194/acp-16-10299-2016, 2016
Short summary
Short summary
Indoor and outdoor formaldehyde (HCHO) are both of considerable concern because of its health effects and its role in atmospheric chemistry. The heterogeneous reactions between gaseous HCHO with soils can pose important impact on both HCHO budget and soil ecosystem. Our results confirms that HCHO uptake by soil is a complex process involving both adsorption/desorption and chemical reactions. Soil and soil-derived airborne particles can either act as a source or a sink for HCHO.
Likun Xue, Rongrong Gu, Tao Wang, Xinfeng Wang, Sandra Saunders, Donald Blake, Peter K. K. Louie, Connie W. Y. Luk, Isobel Simpson, Zheng Xu, Zhe Wang, Yuan Gao, Shuncheng Lee, Abdelwahid Mellouki, and Wenxing Wang
Atmos. Chem. Phys., 16, 9891–9903, https://doi.org/10.5194/acp-16-9891-2016, https://doi.org/10.5194/acp-16-9891-2016, 2016
Short summary
Short summary
The chemical budgets and principal sources of ROx and NO3 radicals during a multi-day photochemical smog episode in Hong Kong are elucidated by an observation-constrained MCM model. NO3 was shown to be an important oxidant even during daytime in a pollution case when high aerosol loading attenuated the solar irradiation. This study suggests the potential important role of daytime NO3 chemistry in polluted atmospheres under conditions with the co-existence of abundant O3, NO2, VOCs, and aerosols.
Zhenhao Ling, Hai Guo, Isobel Jane Simpson, Sandra Maria Saunders, Sean Ho Man Lam, Xiaopu Lyu, and Donald Ray Blake
Atmos. Chem. Phys., 16, 8141–8156, https://doi.org/10.5194/acp-16-8141-2016, https://doi.org/10.5194/acp-16-8141-2016, 2016
Xiaopu Lyu, Hai Guo, Isobel J. Simpson, Simone Meinardi, Peter K. K. Louie, Zhenhao Ling, Yu Wang, Ming Liu, Connie W. Y. Luk, Nan Wang, and Donald R. Blake
Atmos. Chem. Phys., 16, 6609–6626, https://doi.org/10.5194/acp-16-6609-2016, https://doi.org/10.5194/acp-16-6609-2016, 2016
Short summary
Short summary
In this study, the effectiveness of a LPG converter replacement program was evaluated. It was found that LPG-related VOCs and NOx decreased significantly due to the implementation of the program. Source apportionment also revealed the reduction of VOCs and NOx in LPG-fueled vehicle exhaust. From before to during the program, O3 increased slightly, mainly due to the reduction of NOx in LPG-fueled vehicle exhaust. To retain zero O3 increment, the lowest reduction ratio of VOCs / NOx was determined.
Xuekun Fang, Min Shao, Andreas Stohl, Qiang Zhang, Junyu Zheng, Hai Guo, Chen Wang, Ming Wang, Jiamin Ou, Rona L. Thompson, and Ronald G. Prinn
Atmos. Chem. Phys., 16, 3369–3382, https://doi.org/10.5194/acp-16-3369-2016, https://doi.org/10.5194/acp-16-3369-2016, 2016
Short summary
Short summary
This is the first study reporting top-down estimates of benzene and toluene emissions in southern China using atmospheric measurement data from a rural site in the area, an atmospheric transport model and an inverse modeling method. This study shows in detail the temporal and spatial differences between the inversion estimate and four different bottom-up emission inventories (RCP, REAS, MEIC; Yin et al., 2015). We propose that more observations are urgently needed in future.
Yaning Kang, Mingxu Liu, Yu Song, Xin Huang, Huan Yao, Xuhui Cai, Hongsheng Zhang, Ling Kang, Xuejun Liu, Xiaoyuan Yan, Hong He, Qiang Zhang, Min Shao, and Tong Zhu
Atmos. Chem. Phys., 16, 2043–2058, https://doi.org/10.5194/acp-16-2043-2016, https://doi.org/10.5194/acp-16-2043-2016, 2016
Short summary
Short summary
The multi-year (1980–2012) comprehensive ammonia emissions inventories were compiled for China on 1 km × 1 km grid.
Various realistic parameters (ambient temperature, wind speed, soil acidity, synthetic fertilizer types, etc.) were considered in these inventories to synthetically refine the emission factors of ammonia volatilization according to local agricultural practice.
This paper shows the interannual trend and spatial distribution of ammonia emissions in details over recent decades.
L. K. Xue, S. M. Saunders, T. Wang, R. Gao, X. F. Wang, Q. Z. Zhang, and W. X. Wang
Geosci. Model Dev., 8, 3151–3162, https://doi.org/10.5194/gmd-8-3151-2015, https://doi.org/10.5194/gmd-8-3151-2015, 2015
Short summary
Short summary
A detailed chemical mechanism including 205 reactions is developed for use in the Master Chemical Mechanism. With this new chlorine mechanism, it was found that the nocturnal formation of ClNO2 has high potential to perturb the next day's atmospheric photochemistry, by enhancing the radical production and cycling, VOC oxidation and O3 formation, in the polluted coastal environments.
T. Li, Y. Wang, W. J. Li, J. M. Chen, T. Wang, and W. X. Wang
Atmos. Chem. Phys., 15, 8987–9002, https://doi.org/10.5194/acp-15-8987-2015, https://doi.org/10.5194/acp-15-8987-2015, 2015
Short summary
Short summary
Twelve trace elements in fine particles and clouds at a mountain site in southern China were investigated.
Long-range transport contributed the most to element concentrations, whereas the YRD and the area around Mt. Lushan exhibited the highest element solubility.
We demonstrated that cloud processing can enhance aerosol element solubility and increase sulfate concentration correspondingly, by irreversibly altering the morphology of metal particles in cloud droplet residues.
Z. Y. Wu, L. Zhang, X. M. Wang, and J. W. Munger
Atmos. Chem. Phys., 15, 7487–7496, https://doi.org/10.5194/acp-15-7487-2015, https://doi.org/10.5194/acp-15-7487-2015, 2015
Short summary
Short summary
In this study, we have developed a modified micrometeorological gradient method (MGM), although based on existing micrometeorological theory, to estimate O3 dry deposition fluxes over a forest canopy using concentration gradients between a level above and a level below the canopy top. The new method provides an alternative approach in monitoring/estimating long-term deposition fluxes of similar pollutants over tall canopies and is expected to be useful for the scientific community.
Y. Liu, B. Yuan, X. Li, M. Shao, S. Lu, Y. Li, C.-C. Chang, Z. Wang, W. Hu, X. Huang, L. He, L. Zeng, M. Hu, and T. Zhu
Atmos. Chem. Phys., 15, 3045–3062, https://doi.org/10.5194/acp-15-3045-2015, https://doi.org/10.5194/acp-15-3045-2015, 2015
M. Wang, M. Shao, W. Chen, S. Lu, Y. Liu, B. Yuan, Q. Zhang, Q. Zhang, C.-C. Chang, B. Wang, L. Zeng, M. Hu, Y. Yang, and Y. Li
Atmos. Chem. Phys., 15, 1489–1502, https://doi.org/10.5194/acp-15-1489-2015, https://doi.org/10.5194/acp-15-1489-2015, 2015
L. K. Xue, T. Wang, J. Gao, A. J. Ding, X. H. Zhou, D. R. Blake, X. F. Wang, S. M. Saunders, S. J. Fan, H. C. Zuo, Q. Z. Zhang, and W. X. Wang
Atmos. Chem. Phys., 14, 13175–13188, https://doi.org/10.5194/acp-14-13175-2014, https://doi.org/10.5194/acp-14-13175-2014, 2014
X. Li, F. Rohrer, T. Brauers, A. Hofzumahaus, K. Lu, M. Shao, Y. H. Zhang, and A. Wahner
Atmos. Chem. Phys., 14, 12291–12305, https://doi.org/10.5194/acp-14-12291-2014, https://doi.org/10.5194/acp-14-12291-2014, 2014
Q. Zhang, B. Yuan, M. Shao, X. Wang, S. Lu, K. Lu, M. Wang, L. Chen, C.-C. Chang, and S. C. Liu
Atmos. Chem. Phys., 14, 6089–6101, https://doi.org/10.5194/acp-14-6089-2014, https://doi.org/10.5194/acp-14-6089-2014, 2014
M. Wang, M. Shao, W. Chen, B. Yuan, S. Lu, Q. Zhang, L. Zeng, and Q. Wang
Atmos. Chem. Phys., 14, 5871–5891, https://doi.org/10.5194/acp-14-5871-2014, https://doi.org/10.5194/acp-14-5871-2014, 2014
M. Li, Q. Zhang, D. G. Streets, K. B. He, Y. F. Cheng, L. K. Emmons, H. Huo, S. C. Kang, Z. Lu, M. Shao, H. Su, X. Yu, and Y. Zhang
Atmos. Chem. Phys., 14, 5617–5638, https://doi.org/10.5194/acp-14-5617-2014, https://doi.org/10.5194/acp-14-5617-2014, 2014
K. D. Lu, F. Rohrer, F. Holland, H. Fuchs, T. Brauers, A. Oebel, R. Dlugi, M. Hu, X. Li, S. R. Lou, M. Shao, T. Zhu, A. Wahner, Y. H. Zhang, and A. Hofzumahaus
Atmos. Chem. Phys., 14, 4979–4999, https://doi.org/10.5194/acp-14-4979-2014, https://doi.org/10.5194/acp-14-4979-2014, 2014
W. T. Chen, M. Shao, S. H. Lu, M. Wang, L. M. Zeng, B. Yuan, and Y. Liu
Atmos. Chem. Phys., 14, 3047–3062, https://doi.org/10.5194/acp-14-3047-2014, https://doi.org/10.5194/acp-14-3047-2014, 2014
X. Wang, T. Wang, C. Yan, Y. J. Tham, L. Xue, Z. Xu, and Q. Zha
Atmos. Meas. Tech., 7, 1–12, https://doi.org/10.5194/amt-7-1-2014, https://doi.org/10.5194/amt-7-1-2014, 2014
H. Liu, X. M. Wang, J. M. Pang, and K. B. He
Atmos. Chem. Phys., 13, 12013–12027, https://doi.org/10.5194/acp-13-12013-2013, https://doi.org/10.5194/acp-13-12013-2013, 2013
S. Situ, A. Guenther, X. Wang, X. Jiang, A. Turnipseed, Z. Wu, J. Bai, and X. Wang
Atmos. Chem. Phys., 13, 11803–11817, https://doi.org/10.5194/acp-13-11803-2013, https://doi.org/10.5194/acp-13-11803-2013, 2013
Z. B. Wang, M. Hu, D. Mogensen, D. L. Yue, J. Zheng, R. Y. Zhang, Y. Liu, B. Yuan, X. Li, M. Shao, L. Zhou, Z. J. Wu, A. Wiedensohler, and M. Boy
Atmos. Chem. Phys., 13, 11157–11167, https://doi.org/10.5194/acp-13-11157-2013, https://doi.org/10.5194/acp-13-11157-2013, 2013
L. K. Xue, T. Wang, J. Gao, A. J. Ding, X. H. Zhou, D. R. Blake, X. F. Wang, S. M. Saunders, S. J. Fan, H. C. Zuo, Q. Z. Zhang, and W. X. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-27243-2013, https://doi.org/10.5194/acpd-13-27243-2013, 2013
Revised manuscript not accepted
W. W. Hu, M. Hu, B. Yuan, J. L. Jimenez, Q. Tang, J. F. Peng, W. Hu, M. Shao, M. Wang, L. M. Zeng, Y. S. Wu, Z. H. Gong, X. F. Huang, and L. Y. He
Atmos. Chem. Phys., 13, 10095–10112, https://doi.org/10.5194/acp-13-10095-2013, https://doi.org/10.5194/acp-13-10095-2013, 2013
C.-C. Chang, M. Shao, C. C. K. Chou, S.-C. Liu, J.-L. Wang, K.-Z. Lee, C.-H. Lai, T. Zhu, and P.-H. Lin
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-25939-2013, https://doi.org/10.5194/acpd-13-25939-2013, 2013
Revised manuscript not accepted
B. Yuan, W. W. Hu, M. Shao, M. Wang, W. T. Chen, S. H. Lu, L. M. Zeng, and M. Hu
Atmos. Chem. Phys., 13, 8815–8832, https://doi.org/10.5194/acp-13-8815-2013, https://doi.org/10.5194/acp-13-8815-2013, 2013
L. K. Xue, T. Wang, H. Guo, D. R. Blake, J. Tang, X. C. Zhang, S. M. Saunders, and W. X. Wang
Atmos. Chem. Phys., 13, 8551–8567, https://doi.org/10.5194/acp-13-8551-2013, https://doi.org/10.5194/acp-13-8551-2013, 2013
H. Guo, Z. H. Ling, K. Cheung, F. Jiang, D. W. Wang, I. J. Simpson, B. Barletta, S. Meinardi, T. J. Wang, X. M. Wang, S. M. Saunders, and D. R. Blake
Atmos. Chem. Phys., 13, 3881–3898, https://doi.org/10.5194/acp-13-3881-2013, https://doi.org/10.5194/acp-13-3881-2013, 2013
W. Nie, T. Wang, L. K. Xue, A. J. Ding, X. F. Wang, X. M. Gao, Z. Xu, Y. C. Yu, C. Yuan, Z. S. Zhou, R. Gao, X. H. Liu, Y. Wang, S. J. Fan, S. Poon, Q. Z. Zhang, and W. X. Wang
Atmos. Chem. Phys., 12, 11985–11995, https://doi.org/10.5194/acp-12-11985-2012, https://doi.org/10.5194/acp-12-11985-2012, 2012
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition
Opinion: How will advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution?
Measurement report: Intra-annual variability of black carbon and brown carbon and their interrelation with meteorological conditions over Gangtok, Sikkim
Long-range transport of air pollutants increases the concentration of hazardous components of PM2.5 in northern South America
Dominant influence of biomass combustion and cross-border transport on nitrogen-containing organic compound levels in the southeastern Tibetan Plateau
Impacts of elevated anthropogenic emissions on physicochemical characteristics of black-carbon-containing particles over the Tibetan Plateau
Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses
Atmospheric evolution of environmentally persistent free radicals in the rural North China Plain: effects on water solubility and PM2.5 oxidative potential
Two distinct ship emission profiles for organic-sulfate source apportionment of PM in sulfur emission control areas
Automated compound speciation, cluster analysis, and quantification of organic vapors and aerosols using comprehensive two-dimensional gas chromatography and mass spectrometry
Measurement report: Occurrence of aminiums in PM2.5 during winter in China – aminium outbreak during polluted episodes and potential constraints
Bridging gas and aerosol properties between the northeastern US and Bermuda: analysis of eight transit flights
The behaviour of charged particles (ions) during new particle formation events in urban Leipzig, Germany
Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China
Measurement report: Characteristics of airborne black-carbon-containing particles during the 2021 summer COVID-19 lockdown in a typical Yangtze River Delta city, China
Aerosol optical properties within the atmospheric boundary layer predicted from ground-based observations compared to Raman lidar retrievals during RITA-2021
Hygroscopic growth and activation changed submicron aerosol composition and properties in the North China Plain
Measurement report: Formation of tropospheric brown carbon in a lifting air mass
Vertical variability of aerosol properties and trace gases over a remote marine region: a case study over Bermuda
Differences in aerosol and cloud properties along the central California coast when winds change from northerly to southerly
International airport emissions and their impact on local air quality: chemical speciation of ambient aerosols at Madrid–Barajas Airport during the AVIATOR campaign
Significant role of biomass burning in heavy haze formation in a megacity: Molecular-level insights from intensive PM2.5 sampling on winter hazy days
The local ship speed reduction effect on black carbon emissions measured at a remote marine station
High-altitude aerosol chemical characterization and source identification: insights from the CALISHTO campaign
Measurement report: Impact of emission control measures on environmental persistent free radicals and reactive oxygen species – a short-term case study in Beijing
Characterizing water solubility of fresh and aged secondary organic aerosol in PM2.5 with the stable carbon isotope technique
Measurement report: Impact of cloud processes on secondary organic aerosols at a forested mountain site in southeastern China
Critical contribution of chemically diverse carbonyl molecules to the oxidative potential of atmospheric aerosols
Seasonal Investigation of Ultrafine Particle Composition in an Eastern Amazonian Rainforest
Measurement report: Vanadium-containing ship exhaust particles detected in and above the marine boundary layer in the remote atmosphere
Diverging trends in aerosol sulfate and nitrate measured in the remote North Atlantic in Barbados are attributed to clean air policies, African smoke, and anthropogenic emissions
Technical note: Quantified organic aerosol subsaturated hygroscopicity by a simple optical scatter monitor system through field measurements
Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean
The water-insoluble organic carbon in PM2.5 of typical Chinese urban areas: light-absorbing properties, potential sources, radiative forcing effects, and a possible light-absorbing continuum
Measurement report: Size-resolved secondary organic aerosol formation modulated by aerosol water uptake in wintertime haze
In situ measurement of organic aerosol molecular markers in urban Hong Kong during a summer period: temporal variations and source apportionment
Technical note: Determining chemical composition of atmospheric single particles by a standard-free mass calibration algorithm
Different formation pathways of nitrogen-containing organic compounds in aerosols and fog water in northern China
Impact of weather patterns and meteorological factors on PM2.5 and O3 responses to the COVID-19 lockdown in China
Daytime and nighttime aerosol soluble iron formation in clean and slightly polluted moist air in a coastal city in eastern China
Non-negligible secondary contribution to brown carbon in autumn and winter: inspiration from particulate nitrated and oxygenated aromatic compounds in urban Beijing
A Multi-site Passive Approach for Studying the Emissions and Evolution of Smoke from Prescribed Fires
Non-sea-salt aerosols that contain trace bromine and iodine are widespread in the remote troposphere
Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations
High-resolution analyses of concentrations and sizes of black carbon particles deposited on northwest Greenland over the past 350 years – Part 2: Seasonal and temporal trends in black carbon originated from fossil fuel combustion and biomass burning
Bayesian inference-based estimation of hourly primary and secondary organic carbon in suburban Hong Kong: multi-temporal-scale variations and evolution characteristics during PM2.5 episodes
Formation and chemical evolution of SOA in two different environments: A dual chamber study
Enhanced daytime secondary aerosol formation driven by gas-particle partitioning in downwind urban plumes
Multiple eco-regions contribute to the seasonal cycle of Antarctic aerosol size distributions
Matthew Boyer, Diego Aliaga, Lauriane L. J. Quéléver, Silvia Bucci, Hélène Angot, Lubna Dada, Benjamin Heutte, Lisa Beck, Marina Duetsch, Andreas Stohl, Ivo Beck, Tiia Laurila, Nina Sarnela, Roseline C. Thakur, Branka Miljevic, Markku Kulmala, Tuukka Petäjä, Mikko Sipilä, Julia Schmale, and Tuija Jokinen
Atmos. Chem. Phys., 24, 12595–12621, https://doi.org/10.5194/acp-24-12595-2024, https://doi.org/10.5194/acp-24-12595-2024, 2024
Short summary
Short summary
We analyze the seasonal cycle and sources of gases that are relevant for the formation of aerosol particles in the central Arctic. Since theses gases can form new particles, they can influence Arctic climate. We show that the sources of these gases are associated with changes in the Arctic environment during the year, especially with respect to sea ice. Therefore, the concentration of these gases will likely change in the future as the Arctic continues to warm.
Imad El Haddad, Danielle Vienneau, Kaspar R. Daellenbach, Robin Modini, Jay G. Slowik, Abhishek Upadhyay, Petros N. Vasilakos, David Bell, Kees de Hoogh, and Andre S. H. Prevot
Atmos. Chem. Phys., 24, 11981–12011, https://doi.org/10.5194/acp-24-11981-2024, https://doi.org/10.5194/acp-24-11981-2024, 2024
Short summary
Short summary
This opinion paper explores how advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution. We advocate for a shift in the way we target PM pollution, focusing on the most harmful anthropogenic emissions. We highlight key observations, modelling developments, and emission measurements needed to achieve this shift.
Pramod Kumar, Khushboo Sharma, Ankita Malu, Rajeev Rajak, Aparna Gupta, Bidyutjyoti Baruah, Shailesh Yadav, Thupstan Angchuk, Jayant Sharma, Rakesh Kumar Ranjan, Anil Kumar Misra, and Nishchal Wanjari
Atmos. Chem. Phys., 24, 11585–11601, https://doi.org/10.5194/acp-24-11585-2024, https://doi.org/10.5194/acp-24-11585-2024, 2024
Short summary
Short summary
This work monitors and assesses air pollution, especially black and brown carbon, its controlling factor, and its effect on the environment of Sikkim Himalayan region. The huge urban sprawl in recent decades has led to regional human-induced air pollution in the region. Black carbon was highest in April 2021 and March 2022, exceeding the WHO limit. The monsoon season causes huge rainfall over the region, which reduces the pollutants by scavenging (rainout and washout).
Maria P. Velásquez-García, K. Santiago Hernández, James A. Vergara-Correa, Richard J. Pope, Miriam Gómez-Marín, and Angela M. Rendón
Atmos. Chem. Phys., 24, 11497–11520, https://doi.org/10.5194/acp-24-11497-2024, https://doi.org/10.5194/acp-24-11497-2024, 2024
Short summary
Short summary
In the Aburrá Valley, northern South America, local emissions determine air quality conditions. However, we found that external sources, such as regional fires, Saharan dust, and volcanic emissions, increase particulate concentrations and worsen chemical composition by introducing elements like heavy metals. Dry winds and source variability contribute to seasonal influences on these events. This study assesses the air quality risks posed by such events, which can affect broad regions worldwide.
Meng Wang, Qiyuan Wang, Steven Sai Hang Ho, Jie Tian, Yong Zhang, Shun-cheng Lee, and Junji Cao
Atmos. Chem. Phys., 24, 11175–11189, https://doi.org/10.5194/acp-24-11175-2024, https://doi.org/10.5194/acp-24-11175-2024, 2024
Short summary
Short summary
We studied nitrogen-containing organic compounds (NOCs) in particulate matter <2.5 µm particles on the southeastern Tibetan Plateau. We found that biomass burning and transboundary transport are the main sources of NOCs in the high-altitude area. Understanding these aerosol sources informs how they add to regional and potentially global climate changes. Our findings could help shape effective environmental policies to enhance air quality and address climate impacts in this sensitive region.
Jinbo Wang, Jiaping Wang, Yuxuan Zhang, Tengyu Liu, Xuguang Chi, Xin Huang, Dafeng Ge, Shiyi Lai, Caijun Zhu, Lei Wang, Qiaozhi Zha, Ximeng Qi, Wei Nie, Congbin Fu, and Aijun Ding
Atmos. Chem. Phys., 24, 11063–11080, https://doi.org/10.5194/acp-24-11063-2024, https://doi.org/10.5194/acp-24-11063-2024, 2024
Short summary
Short summary
In this study, we found large spatial discrepancies in the physical and chemical properties of black carbon over the Tibetan Plateau (TP). Elevated anthropogenic emissions from low-altitude regions can significantly change the mass concentration, mixing state and chemical composition of black-carbon-containing aerosol in the TP region, further altering its light absorption ability. Our study emphasizes the vulnerability of remote plateau regions to intense anthropogenic influences.
Liyuan Zhou, Qianyun Liu, Christian M. Salvador, Michael Le Breton, Mattias Hallquist, Jian Zhen Yu, Chak K. Chan, and Åsa M. Hallquist
Atmos. Chem. Phys., 24, 11045–11061, https://doi.org/10.5194/acp-24-11045-2024, https://doi.org/10.5194/acp-24-11045-2024, 2024
Short summary
Short summary
Our research on city bus emissions reveals that alternative fuels (compressed natural gas and biofuels) reduce fresh particle emissions compared to diesel. However, all fuels lead to secondary air pollution. Aiming at guiding better environmental policies, we studied 76 buses using advanced emission measurement techniques. This work sheds light on the complex effects of bus fuels on urban air quality, emphasizing the need for comprehensive evaluations of future transportation technologies.
Xu Yang, Fobang Liu, Shuqi Yang, Yuling Yang, Yanan Wang, Jingjing Li, Mingyu Zhao, Zhao Wang, Kai Wang, Chi He, and Haijie Tong
Atmos. Chem. Phys., 24, 11029–11043, https://doi.org/10.5194/acp-24-11029-2024, https://doi.org/10.5194/acp-24-11029-2024, 2024
Short summary
Short summary
A study in the rural North China Plain showed environmentally persistent free radicals (EPFRs) in atmospheric particulate matter (PM), with a notable water-soluble fraction likely from atmospheric oxidation during transport. Significant positive correlations between EPFRs and the water-soluble oxidative potential of PM2.5 were found, primarily attributable to the water-soluble fractions of EPFRs. These findings emphasize understanding EPFRs' atmospheric evolution for climate and health impacts.
Kirsten N. Fossum, Chunshui Lin, Niall O'Sullivan, Lu Lei, Stig Hellebust, Darius Ceburnis, Aqeel Afzal, Anja Tremper, David Green, Srishti Jain, Steigvilė Byčenkienė, Colin O'Dowd, John Wenger, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 24, 10815–10831, https://doi.org/10.5194/acp-24-10815-2024, https://doi.org/10.5194/acp-24-10815-2024, 2024
Short summary
Short summary
The chemical composition and sources of submicron aerosol in the Dublin Port area were investigated over a month-long campaign. Two distinct types of ship emissions were identified and characterised: sulfate-rich plumes from the use of heavy fuel oil with scrubbers and organic-rich plumes from the use of low-sulfur fuels. The latter were more frequent, emitting double the particle number and having a typical V / Ni ratio for ship emission.
Xiao He, Xuan Zheng, Shuwen Guo, Lewei Zeng, Ting Chen, Bohan Yang, Shupei Xiao, Qiongqiong Wang, Zhiyuan Li, Yan You, Shaojun Zhang, and Ye Wu
Atmos. Chem. Phys., 24, 10655–10666, https://doi.org/10.5194/acp-24-10655-2024, https://doi.org/10.5194/acp-24-10655-2024, 2024
Short summary
Short summary
This study introduces an innovative method for identifying and quantifying complex organic vapors and aerosols. By combining advanced analytical techniques and new algorithms, we categorized thousands of compounds from heavy-duty diesel vehicles and ambient air and highlighted specific tracers for emission sources. The innovative approach enhances peak identification, reduces quantification uncertainties, and offers new insights for air quality management and atmospheric chemistry.
Yu Xu, Tang Liu, Yi-Jia Ma, Qi-Bin Sun, Hong-Wei Xiao, Hao Xiao, Hua-Yun Xiao, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 10531–10542, https://doi.org/10.5194/acp-24-10531-2024, https://doi.org/10.5194/acp-24-10531-2024, 2024
Short summary
Short summary
This study investigates the characteristics of aminiums and ammonium in PM2.5 on clean and polluted winter days in 11 Chinese cities, highlighting the possibility of the competitive uptake of ammonia versus amines on acidic aerosols or the displacement of aminiums by ammonia under high-ammonia conditions. The overall results deepen the understanding of the spatiotemporal differences in aminium characteristics and formation in China.
Cassidy Soloff, Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Francesca Gallo, Johnathan W. Hair, Miguel Ricardo A. Hilario, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 10385–10408, https://doi.org/10.5194/acp-24-10385-2024, https://doi.org/10.5194/acp-24-10385-2024, 2024
Short summary
Short summary
Using aircraft measurements over the northwestern Atlantic between the US East Coast and Bermuda and trajectory modeling of continental outflow, we identify trace gas and particle properties that exhibit gradients with offshore distance and quantify these changes with high-resolution measurements of concentrations and particle chemistry, size, and scattering properties. This work furthers our understanding of the complex interactions between continental and marine environments.
Alex Rowell, James Brean, David C. S. Beddows, Zongbo Shi, Avinash Kumar, Matti Rissanen, Miikka Dal Maso, Peter Mettke, Kay Weinhold, Maik Merkel, and Roy M. Harrison
Atmos. Chem. Phys., 24, 10349–10361, https://doi.org/10.5194/acp-24-10349-2024, https://doi.org/10.5194/acp-24-10349-2024, 2024
Short summary
Short summary
Ions enhance the formation and growth rates of new particles, affecting the Earth's radiation budget. Despite these effects, there is little published data exploring the sources of ions in the urban environment and their role in new particle formation (NPF). Here we show that natural ion sources dominate in urban environments, while traffic is a secondary source. Ions contribute up to 12.7 % of the formation rate of particles, indicating that they are important for forming urban PM.
Yuan Cheng, Xu-bing Cao, Sheng-qiang Zhu, Zhi-qing Zhang, Jiu-meng Liu, Hong-liang Zhang, Qiang Zhang, and Ke-bin He
Atmos. Chem. Phys., 24, 9869–9883, https://doi.org/10.5194/acp-24-9869-2024, https://doi.org/10.5194/acp-24-9869-2024, 2024
Short summary
Short summary
The agreement between observational and modeling results is essential for the development of efficient air pollution control strategies. Here we constrained the modeling results of carbonaceous aerosols by field observation in Northeast China, a historically overlooked but recently targeted region of national clean-air actions. Our study suggested that the simulation of agricultural fire emissions and secondary organic aerosols remains challenging.
Yuan Dai, Junfeng Wang, Houjun Wang, Shijie Cui, Yunjiang Zhang, Haiwei Li, Yun Wu, Ming Wang, Eleonora Aruffo, and Xinlei Ge
Atmos. Chem. Phys., 24, 9733–9748, https://doi.org/10.5194/acp-24-9733-2024, https://doi.org/10.5194/acp-24-9733-2024, 2024
Short summary
Short summary
Short-term strict emission control can improve air quality, but its effectiveness needs assessment. During the 2021 summer COVID-19 lockdown in Yangzhou, we found that PM2.5 levels did not decrease despite reduced primary emissions. Aged black-carbon particles increased substantially due to higher O3 levels and transported pollutants. High humidity and low wind also played key roles. The results highlight the importance of a regionally balanced control strategy for future air quality management.
Xinya Liu, Diego Alves Gouveia, Bas Henzing, Arnoud Apituley, Arjan Hensen, Danielle van Dinther, Rujin Huang, and Ulrike Dusek
Atmos. Chem. Phys., 24, 9597–9614, https://doi.org/10.5194/acp-24-9597-2024, https://doi.org/10.5194/acp-24-9597-2024, 2024
Short summary
Short summary
The vertical distribution of aerosol optical properties is important for their effect on climate. This is usually measured by lidar, which has limitations, most notably the assumption of a lidar ratio. Our study shows that routine surface-level aerosol measurements are able to predict this lidar ratio reasonably well within the lower layers of the atmosphere and thus provide a relatively simple and cost-effective method to improve lidar measurements.
Weiqi Xu, Ye Kuang, Wanyun Xu, Zhiqiang Zhang, Biao Luo, Xiaoyi Zhang, Jiangchuang Tao, Hongqin Qiao, Li Liu, and Yele Sun
Atmos. Chem. Phys., 24, 9387–9399, https://doi.org/10.5194/acp-24-9387-2024, https://doi.org/10.5194/acp-24-9387-2024, 2024
Short summary
Short summary
We deployed an advanced aerosol–fog sampling system at a rural site in the North China Plain to investigate impacts of aerosol hygroscopic growth and activation on the physicochemical properties of submicron aerosols. Observed results highlighted remarkably different aqueous processing of primary and secondary submicron aerosol components under distinct ambient relative humidity (RH) conditions and that RH levels significantly impact aerosol sampling through the aerosol swelling effect.
Can Wu, Xiaodi Liu, Ke Zhang, Si Zhang, Cong Cao, Jianjun Li, Rui Li, Fan Zhang, and Gehui Wang
Atmos. Chem. Phys., 24, 9263–9275, https://doi.org/10.5194/acp-24-9263-2024, https://doi.org/10.5194/acp-24-9263-2024, 2024
Short summary
Short summary
Brown carbon (BrC) is prevalent in the troposphere and can efficiently absorb solar and terrestrial radiation. Our observations show that the enhanced light absorption of BrC relative to black carbon at the tropopause can be attributed to the formation of nitrogen-containing organic compounds through the aqueous-phase reactions of carbonyls with ammonium.
Taiwo Ajayi, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Marta A. Fenn, Richard A. Ferrare, Johnathan W. Hair, Miguel Ricardo A. Hilario, Chris A. Hostetler, Simon Kirschler, Richard H. Moore, Taylor J. Shingler, Michael A. Shook, Cassidy Soloff, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9197–9218, https://doi.org/10.5194/acp-24-9197-2024, https://doi.org/10.5194/acp-24-9197-2024, 2024
Short summary
Short summary
This study uses airborne data to examine vertical profiles of trace gases, aerosol particles, and meteorological variables over a remote marine area (Bermuda). Results show distinct differences based on both air mass source region (North America, Ocean, Caribbean/North Africa) and altitude for a given air mass type. This work highlights the sensitivity of remote marine areas to long-range transport and the importance of considering the vertical dependence of trace gas and aerosol properties.
Kira Zeider, Grace Betito, Anthony Bucholtz, Peng Xian, Annette Walker, and Armin Sorooshian
Atmos. Chem. Phys., 24, 9059–9083, https://doi.org/10.5194/acp-24-9059-2024, https://doi.org/10.5194/acp-24-9059-2024, 2024
Short summary
Short summary
The predominant wind direction along the California coast (northerly) reverses several times during the summer (to southerly). The effects of these wind reversals on aerosol and cloud characteristics are not well understood. Using data from multiple datasets we found that southerly flow periods had enhanced signatures of anthropogenic emissions due to shipping and continental sources, and clouds had more but smaller droplets.
Saleh Alzahrani, Doğuşhan Kılıç, Michael Flynn, Paul I. Williams, and James Allan
Atmos. Chem. Phys., 24, 9045–9058, https://doi.org/10.5194/acp-24-9045-2024, https://doi.org/10.5194/acp-24-9045-2024, 2024
Short summary
Short summary
This paper investigates emissions from aviation activities at an international airport to evaluate their impact on local air quality. The study provides detailed insights into the chemical composition of aerosols and key pollutants in the airport environment. Source apportionment analysis using positive matrix factorisation (PMF) identified three significant sources: less oxidised oxygenated organic aerosol, alkane organic aerosol, and more oxidised oxygenated organic aerosol.
Mingjie Kang, Mengying Bao, Wenhuai Song, Aduburexiati Abulimiti, Fang Cao, Sönke Szidat, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2098, https://doi.org/10.5194/egusphere-2024-2098, 2024
Short summary
Short summary
Reports on the molecular level knowledge of high temporal resolution PM2.5 components on hazy days are still limited. This study investigated many individual PM2.5 species and sources. The results show biomass burning (BB) was the main source of organic carbon. Moreover, BB enhanced fungal spore emissions and secondary aerosol formation. The contribution of non-fossils increased with increasing haze pollution. These findings suggest BB may be an important driver of haze events in winter.
Mikko Heikkilä, Krista Luoma, Timo Mäkelä, and Tiia Grönholm
Atmos. Chem. Phys., 24, 8927–8941, https://doi.org/10.5194/acp-24-8927-2024, https://doi.org/10.5194/acp-24-8927-2024, 2024
Short summary
Short summary
Black carbon (BC) concentration was measured from 211 ship exhaust gas plumes at a remote marine station. Emission factors of BC were calculated in grams per kilogram of fuel. Ships with an exhaust gas cleaning system (EGCS) were found to have median BC emissions per fuel consumed 5 times lower than ships without an EGCS. However, this might be because of non-EGCS ships running at low engine loads rather than the EGCS itself. A local speed restriction would increase BC emissions of ships.
Olga Zografou, Maria Gini, Prodromos Fetfatzis, Konstantinos Granakis, Romanos Foskinis, Manousos Ioannis Manousakas, Fotios Tsopelas, Evangelia Diapouli, Eleni Dovrou, Christina N. Vasilakopoulou, Alexandros Papayannis, Spyros N. Pandis, Athanasios Nenes, and Konstantinos Eleftheriadis
Atmos. Chem. Phys., 24, 8911–8926, https://doi.org/10.5194/acp-24-8911-2024, https://doi.org/10.5194/acp-24-8911-2024, 2024
Short summary
Short summary
Characterization of PM1 and positive matrix factorization (PMF) source apportionment of organic and inorganic fractions were conducted at the high-altitude station (HAC)2. Cloud presence reduced PM1, affecting sulfate more than organics. Free-troposphere (FT) conditions showed more black carbon (eBC) than planetary boundary layer (PBL) conditions.
Yuanyuan Qin, Xinghua Zhang, Wei Huang, Juanjuan Qin, Xiaoyu Hu, Yuxuan Cao, Tianyi Zhao, Yang Zhang, Jihua Tan, Ziyin Zhang, Xinming Wang, and Zhenzhen Wang
Atmos. Chem. Phys., 24, 8737–8750, https://doi.org/10.5194/acp-24-8737-2024, https://doi.org/10.5194/acp-24-8737-2024, 2024
Short summary
Short summary
Environmental persistent free radicals (EPFRs) and reactive oxygen species (ROSs) play an active role in the atmosphere. Despite control measures having effectively reduced their emissions, reductions were less than in PM2.5. Emission control measures performed well in achieving Parade Blue, but reducing the impact of the atmosphere on human health remains challenging. Thus, there is a need to reassess emission control measures to better address the challenges posed by EPFRs and ROSs.
Fenghua Wei, Xing Peng, Liming Cao, Mengxue Tang, Ning Feng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 24, 8507–8518, https://doi.org/10.5194/acp-24-8507-2024, https://doi.org/10.5194/acp-24-8507-2024, 2024
Short summary
Short summary
The water solubility of secondary organic aerosols (SOAs) is a crucial factor in determining their hygroscopicity and climatic impact. Stable carbon isotope and mass spectrometry techniques were combined to assess the water solubility of SOAs with different aging degrees in a coastal megacity in China. This work revealed a much higher water-soluble fraction of aged SOA compared to fresh SOA, indicating that the aging degree of SOA has considerable impacts on its water solubility.
Zijun Zhang, Weiqi Xu, Yi Zhang, Wei Zhou, Xiangyu Xu, Aodong Du, Yinzhou Zhang, Hongqin Qiao, Ye Kuang, Xiaole Pan, Zifa Wang, Xueling Cheng, Lanzhong Liu, Qingyan Fu, Douglas R. Worsnop, Jie Li, and Yele Sun
Atmos. Chem. Phys., 24, 8473–8488, https://doi.org/10.5194/acp-24-8473-2024, https://doi.org/10.5194/acp-24-8473-2024, 2024
Short summary
Short summary
We investigated aerosol composition and sources and the interaction between secondary organic aerosol (SOA) and clouds at a regional mountain site in southeastern China. Clouds efficiently scavenge more oxidized SOA; however, cloud evaporation leads to the production of less oxidized SOA. The unexpectedly high presence of nitrate in aerosol particles indicates that nitrate formed in polluted areas has undergone interactions with clouds, significantly influencing the regional background site.
Feifei Li, Shanshan Tang, Jitao Lv, Shiyang Yu, Xu Sun, Dong Cao, Yawei Wang, and Guibin Jiang
Atmos. Chem. Phys., 24, 8397–8411, https://doi.org/10.5194/acp-24-8397-2024, https://doi.org/10.5194/acp-24-8397-2024, 2024
Short summary
Short summary
Targeted derivatization and non-targeted analysis with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) were used to reveal the molecular composition of carbonyl molecules in PM2.5, and the important role of carbonyls in increasing the oxidative potential of organic aerosol was found in real samples.
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
EGUsphere, https://doi.org/10.5194/egusphere-2024-2230, https://doi.org/10.5194/egusphere-2024-2230, 2024
Short summary
Short summary
We present measurements of the composition of ultrafine particles collected from the eastern Amazon, a relatively understudied region that is subjected to increasing human influence. We find that while isoprene chemistry is likely significant to ultrafine particle growth throughout the year, compounds related to other sources such as biological spore emissions and biomass burning exhibit striking seasonal differences, implying an extensive variation in regional ultrafine particle sources.
Maya Abou-Ghanem, Daniel M. Murphy, Gregory P. Schill, Michael J. Lawler, and Karl D. Froyd
Atmos. Chem. Phys., 24, 8263–8275, https://doi.org/10.5194/acp-24-8263-2024, https://doi.org/10.5194/acp-24-8263-2024, 2024
Short summary
Short summary
Using particle analysis by laser mass spectrometry, we examine vanadium-containing ship exhaust particles measured on NASA's DC-8 during the Atmospheric Tomography Mission (ATom). Our results reveal ship exhaust particles are sufficiently widespread in the marine atmosphere and experience atmospheric aging. Finally, we use laboratory calibrations to determine the vanadium, sulfate, and organic single-particle mass fractions of vanadium-containing ship exhaust particles.
Cassandra J. Gaston, Joseph M. Prospero, Kristen Foley, Havala O. T. Pye, Lillian Custals, Edmund Blades, Peter Sealy, and James A. Christie
Atmos. Chem. Phys., 24, 8049–8066, https://doi.org/10.5194/acp-24-8049-2024, https://doi.org/10.5194/acp-24-8049-2024, 2024
Short summary
Short summary
To understand how changing emissions have impacted aerosols in remote regions, we measured nitrate and sulfate in Barbados and compared them to model predictions from EPA’s Air QUAlity TimE Series (EQUATES). Nitrate was stable, except for spikes in 2008 and 2010 due to transported smoke. Sulfate decreased in the 1990s due to reductions in sulfur dioxide (SO2) in the US and Europe; then it increased in the 2000s, likely due to anthropogenic emissions from Africa.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
EGUsphere, https://doi.org/10.5194/egusphere-2024-1390, https://doi.org/10.5194/egusphere-2024-1390, 2024
Short summary
Short summary
This study shows the derived organic aerosol hygroscopicity under high humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), after knowing the aerosol chemical composition.
Jiao Xue, Tian Zhang, Keyhong Park, Jinpei Yan, Young Jun Yoon, Jiyeon Park, and Bingbing Wang
Atmos. Chem. Phys., 24, 7731–7754, https://doi.org/10.5194/acp-24-7731-2024, https://doi.org/10.5194/acp-24-7731-2024, 2024
Short summary
Short summary
Ice formation by particles is an important way of making mixed-phase and ice clouds. We found that particles collected in the marine atmosphere exhibit diverse ice nucleation abilities and mixing states. Sea salt mixed-sulfate particles were enriched in ice-nucleating particles. Selective aging on sea salt particles made particle populations more externally mixed. Characterizations of particles and their mixing state are needed for a better understanding of aerosol–cloud interactions.
Yangzhi Mo, Jun Li, Guangcai Zhong, Sanyuan Zhu, Shizhen Zhao, Jiao Tang, Hongxing Jiang, Zhineng Cheng, Chongguo Tian, Yingjun Chen, and Gan Zhang
Atmos. Chem. Phys., 24, 7755–7772, https://doi.org/10.5194/acp-24-7755-2024, https://doi.org/10.5194/acp-24-7755-2024, 2024
Short summary
Short summary
In this study, we found that biomass burning (31.0 %) and coal combustion (31.1 %) were the dominant sources of water-insoluble organic carbon in China, with coal combustion sources exhibiting the strongest light-absorbing capacity. Additionally, we propose a light-absorbing carbonaceous continuum, revealing that components enriched with fossil sources tend to have stronger light-absorbing capacity, higher aromaticity, higher molecular weights, and greater recalcitrance in the atmosphere.
Jing Duan, Ru-Jin Huang, Ying Wang, Wei Xu, Haobin Zhong, Chunshui Lin, Wei Huang, Yifang Gu, Jurgita Ovadnevaite, Darius Ceburnis, and Colin O'Dowd
Atmos. Chem. Phys., 24, 7687–7698, https://doi.org/10.5194/acp-24-7687-2024, https://doi.org/10.5194/acp-24-7687-2024, 2024
Short summary
Short summary
The chemical composition of atmospheric particles has shown significant changes in recent years. We investigated the potential effects of changes in inorganics on aerosol water uptake and, thus, secondary organic aerosol formation in wintertime haze based on the size-resolved measurements of non-refractory fine particulate matter (NR-PM2.5) in Xi’an, northwestern China. We highlight the key role of aerosol water as a medium to link inorganics and organics in their multiphase processes.
Hongyong Li, Xiaopu Lyu, Likun Xue, Yunxi Huo, Dawen Yao, Haoxian Lu, and Hai Guo
Atmos. Chem. Phys., 24, 7085–7100, https://doi.org/10.5194/acp-24-7085-2024, https://doi.org/10.5194/acp-24-7085-2024, 2024
Short summary
Short summary
Organic aerosol is ubiquitous in the atmosphere and largely explains the gap between current levels of fine particulate matter in many cities and the World Health Organization guideline values. This study highlights the dominant contributions of cooking emissions to organic aerosol when marine air prevailed in Hong Kong, which were occasionally overwhelmed by aromatics-derived secondary organic aerosol in continental ouflows.
Shao Shi, Jinghao Zhai, Xin Yang, Yechun Ruan, Yuanlong Huang, Xujian Chen, Antai Zhang, Jianhuai Ye, Guomao Zheng, Baohua Cai, Yaling Zeng, Yixiang Wang, Chunbo Xing, Yujie Zhang, Tzung-May Fu, Lei Zhu, Huizhong Shen, and Chen Wang
Atmos. Chem. Phys., 24, 7001–7012, https://doi.org/10.5194/acp-24-7001-2024, https://doi.org/10.5194/acp-24-7001-2024, 2024
Short summary
Short summary
The determination of ions in the mass spectra of individual particles remains uncertain. We have developed a standard-free mass calibration algorithm applicable to more than 98 % of ambient particles. With our algorithm, ions with ~ 0.05 Th mass difference could be determined. Therefore, many more atmospheric species could be determined and involved in the source apportionment of aerosols, the study of chemical reaction mechanisms, and the analysis of single-particle mixing states.
Wei Sun, Xiaodong Hu, Yuzhen Fu, Guohua Zhang, Yujiao Zhu, Xinfeng Wang, Caiqing Yan, Likun Xue, He Meng, Bin Jiang, Yuhong Liao, Xinming Wang, Ping'an Peng, and Xinhui Bi
Atmos. Chem. Phys., 24, 6987–6999, https://doi.org/10.5194/acp-24-6987-2024, https://doi.org/10.5194/acp-24-6987-2024, 2024
Short summary
Short summary
The formation pathways of nitrogen-containing compounds (NOCs) in the atmosphere remain unclear. We investigated the composition of aerosols and fog water by state-of-the-art mass spectrometry and compared the formation pathways of NOCs. We found that NOCs in aerosols were mainly formed through nitration reaction, while ammonia addition played a more important role in fog water. The results deepen our understanding of the processes of organic particulate pollution.
Fuzhen Shen, Michaela I. Hegglin, and Yue Yuan
Atmos. Chem. Phys., 24, 6539–6553, https://doi.org/10.5194/acp-24-6539-2024, https://doi.org/10.5194/acp-24-6539-2024, 2024
Short summary
Short summary
We attempt to use a novel structural self-organising map and machine learning models to identify a weather system and quantify the importance of each meteorological factor in driving the unexpected PM2.5 and O3 changes under the specific weather system during the COVID-19 lockdown in China. The result highlights that temperature under the double-centre high-pressure system plays the most crucial role in abnormal events.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
Atmos. Chem. Phys., 24, 6495–6508, https://doi.org/10.5194/acp-24-6495-2024, https://doi.org/10.5194/acp-24-6495-2024, 2024
Short summary
Short summary
Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Yanqin Ren, Zhenhai Wu, Yuanyuan Ji, Fang Bi, Junling Li, Haijie Zhang, Hao Zhang, Hong Li, and Gehui Wang
Atmos. Chem. Phys., 24, 6525–6538, https://doi.org/10.5194/acp-24-6525-2024, https://doi.org/10.5194/acp-24-6525-2024, 2024
Short summary
Short summary
Nitrated aromatic compounds (NACs) and oxygenated derivatives of polycyclic aromatic hydrocarbons (OPAHs) in PM2.5 were examined from an urban area in Beijing during the autumn and winter. The OPAH and NAC concentrations were much higher during heating than before heating. They majorly originated from the combustion of biomass and automobile emissions, and the secondary generation was the major contributor throughout the whole sampling period.
Rime El Asmar, Zongrun Li, David J. Tanner, Yongtao Hu, Susan O’Neill, L. Gregory Huey, M. Talat Odman, and Rodney J. Weber
EGUsphere, https://doi.org/10.5194/egusphere-2024-1485, https://doi.org/10.5194/egusphere-2024-1485, 2024
Short summary
Short summary
Prescribed burning is an important method for managing ecosystems and preventing wildfires, however, smoke from prescribed fires can have a significant impact on air quality. Here, using a network of fixed sites and sampling throughout an extended prescribed burning period in two different years, we characterize the emissions and evolution up to 8 hours of PM2.5 mass, BC, and BrC in smoke from burning of forested lands in the southeastern US.
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Tomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
EGUsphere, https://doi.org/10.5194/egusphere-2024-1399, https://doi.org/10.5194/egusphere-2024-1399, 2024
Short summary
Short summary
Using single-particle mass spectrometry, we show that trace concentrations of bromine and iodine are ubiquitous in remote tropospheric aerosol, and suggest that aerosols are an important part of the global reactive iodine budget. Comparisons to a global climate model with detailed iodine chemistry are favorable in the background atmosphere; however, the model cannot replicate our measurements near the ocean surface, in biomass burning plumes, and in the stratosphere.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024, https://doi.org/10.5194/acp-24-6305-2024, 2024
Short summary
Short summary
Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Zhichao Dong, Chandra Mouli Pavuluri, Peisen Li, Zhanjie Xu, Junjun Deng, Xueyan Zhao, Xiaomai Zhao, Pingqing Fu, and Cong-Qiang Liu
Atmos. Chem. Phys., 24, 5887–5905, https://doi.org/10.5194/acp-24-5887-2024, https://doi.org/10.5194/acp-24-5887-2024, 2024
Short summary
Short summary
Comprehensive study of optical properties of brown carbon (BrC) in fine aerosols from Tianjin, China, implied that biological emissions are major sources of BrC in summer, whereas fossil fuel combustion and biomass burning emissions are in cold periods. The direct radiation absorption caused by BrC in short wavelengths contributed about 40 % to that caused by BrC in 300–700 nm. Water-insoluble but methanol-soluble BrC contains more protein-like chromophores (PLOM) than that of water-soluble BrC.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, and Teruo Aoki
EGUsphere, https://doi.org/10.5194/egusphere-2024-1498, https://doi.org/10.5194/egusphere-2024-1498, 2024
Short summary
Short summary
Monthly records spanning 350 years from a Greenland ice core reveal trends in black carbon (BC) concentrations and sizes. BC concentrations have risen since the late 19th century due to the inflow of anthropogenic BC, with these particles being larger than those from biomass burning (BB). High BB BC concentration peaks in summer originating from BB could reduce albedo. However, BB BC showed no upward trend until the early 2000s. Our findings are crucial for validating aerosol and climate models.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
Short summary
Short summary
In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Andreas Aktypis, Dontavious Sippial, Christina Vasilakopoulou, Angeliki Matrali, Christos Kaltsonoudis, Andrea Simonati, Marco Paglione, Matteo Rinaldi, Stefano Decesari, and Spyros Pandis
EGUsphere, https://doi.org/10.5194/egusphere-2024-1317, https://doi.org/10.5194/egusphere-2024-1317, 2024
Short summary
Short summary
A dual chamber system was deployed in two different environments (Po Valley, Italy and Pertouli forest, Greece) to study the potential of ambient air directly injected into the chambers, to form secondary aerosol. In the Po Valley, the system reacts rapidly forming large amounts of SOA, while in Pertouli the corresponding SOA formation chemistry appears to have been practically terminated before the beginning of most experiments, so there is little additional SOA formation potential left.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baolin Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
EGUsphere, https://doi.org/10.5194/egusphere-2024-887, https://doi.org/10.5194/egusphere-2024-887, 2024
Short summary
Short summary
This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas-particle partitioning when the site was affected by urban plumes. Box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
James Brean, David C. S. Beddows, Eija Asmi, Ari Virkkula, Lauriane L. J. Quéléver, Mikko Sipilä, Floortje Van Den Heuvel, Thomas Lachlan-Cope, Anna Jones, Markus Frey, Angelo Lupi, Jiyeon Park, Young Jun Yoon, Ralf Weller, Giselle L. Marincovich, Gabriela C. Mulena, Roy M. Harrison, and Manuel Dall´Osto
EGUsphere, https://doi.org/10.5194/egusphere-2024-987, https://doi.org/10.5194/egusphere-2024-987, 2024
Short summary
Short summary
Our results emphasize how understanding the geographical variation in surface types across the Antarctic is key to understanding secondary aerosol sources.
Cited articles
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–4658, 2003.
Aumont, B., Valorso, R., Mouchel-Vallon, C., Camredon, M., Lee-Taylor, J., and Madronich, S.: Modeling SOA formation from the oxidation of intermediate volatility n-alkanes, Atmos. Chem. Phys., 12, 7577–7589, https://doi.org/10.5194/acp-12-7577-2012, 2012.
Baum, E.: Chemical property estimation: theory and application, Crc Press,
1997.
Benavent, N., Garcia-Nieto, D., Wang, S. S., and Saiz-Lopez, A.: Max-DOAS
measurements and vertical profiles of glyoxal and formaldehyde in Madrid,
Spain, Atmos. Environ., 199, 357–367, 2019.
Bloss, C., Wagner, V., Bonzanini, A., Jenkin, M. E., Wirtz, K., Martin-Reviejo, M., and Pilling, M. J.: Evaluation of detailed aromatic mechanisms (MCMv3 and MCMv3.1) against environmental chamber data, Atmos. Chem. Phys., 5, 623–639, https://doi.org/10.5194/acp-5-623-2005, 2005.
Buxton, G. V., Malone, T. N., and Salmon, G. A.: Arthur Salmon, G.:
Oxidation of glyoxal initiated by OH in oxygenated aqueous solution, J.
Chem. Soc. Faraday Trans., 93, 2889–2891, 1997.
Calvert, G.: Evidence from functional magnetic resonance imaging of
crossmodal binding in the human heteromodal cortex, Curr. Biol., 10,
649–657, 2000.
Calvert, J., Mellouki, A., Orlando, J., Pilling, M., and Wallington, T.:
Mechanisms of atmospheric oxidation of the oxygenates, OUP USA, 2011.
Carlton, A. G., Wiedinmyer, C., and Kroll, J. H.: A review of Secondary Organic Aerosol (SOA) formation from isoprene, Atmos. Chem. Phys., 9, 4987–5005, https://doi.org/10.5194/acp-9-4987-2009, 2009.
Chang, D., Wang, Z., Guo, J., Li, T., Liang, Y. H., Kang, L. Y., Xia, M.,
Wang, Y., Yu, C., Yun, H., Yue, D. L., and Wang, T.: Characterization of
organic aerosols and their precursors in southern China during a severe haze
episode in January 2017, Sci. Total Environ., 691, 101–111, 2019.
Corrigan, A. L., Hanley, S. W., and De Haan, D. O.: Uptake of glyoxal by
organic and inorganic aerosol, Environ. Sci. Technol., 42, 4428–4433,
2008.
De Haan, D. O., Corrigan, A. L., Tolbert, M. A., Jimenez, J. L., Wood, S.
E., and Turley, J. J.: Secondary organic aerosol formation by sel-reactions
of methylglyoxal and glyoxal in evaporating droplets, Environ. Sci.
Technol., 43, 8184–8190, 2009.
De Haan, D. O., Jimenez, N. G., De Loera, A., Cazaunau, M., Gratien, A., and
Pangui, E.: Methylglyoxal Uptake Coefficients on Aqueous Aerosol Surfaces.
J. Phys. Chem. A., 122, 4854–4860, 2018.
DiGangi, J. P., Henry, S. B., Kammrath, A., Boyle, E. S., Kaser, L., Schnitzhofer, R., Graus, M., Turnipseed, A., Park, J.-H., Weber, R. J., Hornbrook, R. S., Cantrell, C. A., Maudlin III, R. L., Kim, S., Nakashima, Y., Wolfe, G. M., Kajii, Y., Apel, E. C., Goldstein, A. H., Guenther, A., Karl, T., Hansel, A., and Keutsch, F. N.: Observations of glyoxal and formaldehyde as metrics for the anthropogenic impact on rural photochemistry, Atmos. Chem. Phys., 12, 9529–9543, https://doi.org/10.5194/acp-12-9529-2012, 2012.
Ding, X., He, Q. F., Shen, R. Q., Yu, Q. Q., Zhang, Y. Q., Xin, J. Y., Wen,
T. X., and Wang, X. M.: Spatial and seasonal variations of isoprene
secondary organic aerosol in China: Significant impact of biomass burning
during winter, Sci. Rep., 6, 20411, https://doi.org/10.1038/srep20411, 2016.
Ding, X., Zhang, Y. Q., He, Q. F., Yu, Q. Q., Wang, J. Q., Shen, R. Q.,
Song, W., Wang, Y. S., and Wang, X. M.: Significant increase of
aromatics-derived secondary organic aerosol during fall to winter in China,
Environ. Sci. Technol. 51, 7432–7441, 2017.
Ervens, B. and Volkamer, R.: Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles, Atmos. Chem. Phys., 10, 8219–8244, https://doi.org/10.5194/acp-10-8219-2010, 2010.
Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069–11102, https://doi.org/10.5194/acp-11-11069-2011, 2011.
Fan, S. J., Fan, Q., Yu, W., Luo, X. Y., Wang, B. M., Song, L. L., and Leong, K. L.: Atmospheric boundary layer characteristics over the Pearl River Delta, China, during the summer of 2006: measurement and model results, Atmos. Chem. Phys., 11, 6297–6310, https://doi.org/10.5194/acp-11-6297-2011, 2011.
Fick, J., Pommer, L., Nilsson, C., and Andersson, B.: Effect of OH radicals,
relative humidity, and time on the composition of the products formed in the
ozonolysis of α-pinene, Atmos. Environ., 37, 4087–4096, 2003.
Friedfeld, S., Fraser, M., Ensor, K., Tribble, S., Rehle, D., Leleux, D.,
and Tittel, F.: Statistical analysis of primary and secondary atmospheric
formaldehyde, Atmos. Environ., 36, 4767–4775, 2002.
Fu, T.-M., Jacob, D. J., Wittrock, F., Burrows, J. P., Vrekoussis, M., and
Henze, D. K.: Global budgets of atmospheric glyoxal and methylglyoxal, and
implications for formation of secondary organic aerosols, J. Geophys. Res.,
113, D15303, https://doi.org/10.1029/2007JD009505, 2008.
Fu, T.-M., Cao, J. J., Zhang, X. Y., Lee, S. C., Zhang, Q., Han, Y. M., Qu, W. J., Han, Z., Zhang, R., Wang, Y. X., Chen, D., and Henze, D. K.: Carbonaceous aerosols in China: top-down constraints on primary sources and estimation of secondary contribution, Atmos. Chem. Phys., 12, 2725–2746, https://doi.org/10.5194/acp-12-2725-2012, 2012.
Gomez, M. E., Lin, Y., Guo, S., and Zhang, R.: Heterogeneous chemistry of
glyoxal on acidic solutions. An oligomerization pathway for secondary
organic aerosol formation, J. Phys. Chem. A., 119, 4457–4463, 2015.
Grosjean, D., Grosjean, E., and Gertler, A.: On-road emissions of carbonyls
from light-duty and heavy-duty vehicles, Environ. Sci. Technol., 351, 45–53,
2001.
Guo, S., Hu, M., Guo, Q., Zhang, X., Zheng, M., Zheng, J., Chang, C. C.,
Schauer, J. J., and Zhang, R.: Primary sources and secondary formation of
organic aerosols in Beijing, China, Environ. Sci. Technol., 46, 9846–9853,
2012.
He, L.-Y., Huang, X.-F., Xue, L., Hu, M., Zheng, J., Zhang, R. Y., and
Zhang, Y. H.: Submicron aerosol analysis and organic source apportionment in
an urban atmosphere in Pearl River Delta of China using high-resolution
aerosol mass spectrometry, J. Geophys. Res., 116, D12304,
https://doi.org/10.1029/2010JD014566, 2011.
Hofzumahaus, A., Rohrer, F., Lu, K. D., Bohn, B., Brauers, T., Chang, C.-C.,
Fuchs, H., Holland, F., Kita, K., Kondo, Y., Li, X., Lou, S. R., Shao, M.,
Zeng, L., Wahner, A., and Zhang, Y. H.: Amplified trace gas removal in the
troposphere, Science, 324, 1702–1704, 2009.
Hoyle, C. R., Myhre, G., Berntsen, T. K., and Isaksen, I. S. A.: Anthropogenic influence on SOA and the resulting radiative forcing, Atmos. Chem. Phys., 9, 2715–2728, https://doi.org/10.5194/acp-9-2715-2009, 2009.
Hu, J., Wang, P., Ying, Q., Zhang, H., Chen, J., Ge, X., Li, X., Jiang, J., Wang, S., Zhang, J., Zhao, Y., and Zhang, Y.: Modeling biogenic and anthropogenic secondary organic aerosol in China, Atmos. Chem. Phys., 17, 77–92, https://doi.org/10.5194/acp-17-77-2017, 2017.
Huang, R. J., Zhang, Y. L., Bozzetti, C., Ho, K. F., Cao, J. J., Han, Y. M.,
Daellenbach, K. R., Slowik, J. G., Platt, S. M., Canonaco, F., Zotter, P.,
Wolf, R., Pieber, S. M., Bruns, E. A., Crippa, M., Ciarelli, G.,
Piazzalunga, A., Schwikowski, M., Abbaszade, G., Schnelle-Kreis, J.,
Zimmermann, R., An, Z. S., Szidat, S., Baltensperger, U., Haddad, I. E., and
Prévôt, A. S. H.: High secondary aerosol contribution to particulate
pollution during haze events in China, Nature, 514, 218–222, 2014.
Jimenez, J. L., Canagaratna, M. R., Donahue, N. M., Prevot, A. S., Zhang,
Q., Kroll, J. H., Decarlo, P. F., Allan, J. D., Coe, H., and Ng, N. L.:
Evolution of organic aerosols in the atmosphere, Science, 326, 1525–1529,
2009.
Johnson, D., Jenkin, M. E., Wirtz, K., and Martin-Reviejo, M.: Simulating
the formation of secondary organic aerosol from the photooxidation of
toluene, Environ. Chem., 1, 150–165, 2004.
Johnson, D., Jenkin, M. E., Wirtz, K., and Martin-Reviejo, M.: Simulating
the formation of secondary organic aerosol from the photooxidation of
aromatic hydrocarbons, Environ. Chem., 2, 35–48, 2005.
Johnson, D., Utembe, S. R., and Jenkin, M. E.: Simulating the detailed chemical composition of secondary organic aerosol formed on a regional scale during the TORCH 2003 campaign in the southern UK, Atmos. Chem. Phys., 6, 419–431, https://doi.org/10.5194/acp-6-419-2006, 2006.
Kamens, R., Jang, M., Chien, C. J., and Leach, K.: Aerosol Formation from
the Reaction of α-Pinene and Ozone Using a Gas-Phase
Kinetics-Aerosol Partitioning Model, Environ. Sci. Technol. 33, 1430–1438,
1999.
Kampf, C. J., Waxman, E. M., Slowik, J. G., Dommen, J., Pfaffenberger, L.,
Praplan, A. P., Prévôt, A. S. H., Baltensperger, U., Hoffmann, T.,
and Volkamer, R.: Effective Henry's law partitioning and the salting
constant of glyoxal in aerosols containing sulfate, Environ. Sci. Technol.,
47, 4236–4244, 2013.
Kanaya, Y., Cao, R., Akimoto, H., Fukuda, M., Komazaki, Y., Yokouchi, Y.,
Koike, M., Tanimoto, H., Takegawa, N., and Kondo, Y.: Urban photochemistry
in central Tokyo: 1. Observed and modeled OH and HO2 radical
concentrations during the winter and summer of 2004, J. Geophys. Res.,
112, https://doi.org/10.1029/2007JD008670, 2007.
Knote, C., Hodzic, A., Jimenez, J. L., Volkamer, R., Orlando, J. J., Baidar, S., Brioude, J., Fast, J., Gentner, D. R., Goldstein, A. H., Hayes, P. L., Knighton, W. B., Oetjen, H., Setyan, A., Stark, H., Thalman, R., Tyndall, G., Washenfelder, R., Waxman, E., and Zhang, Q.: Simulation of semi-explicit mechanisms of SOA formation from glyoxal in aerosol in a 3-D model, Atmos. Chem. Phys., 14, 6213–6239, https://doi.org/10.5194/acp-14-6213-2014, 2014.
Kroll, J. H., Ng, N. L., Murphy, S. M., Flagan, R. C., and Seinfeld, J. H.:
Secondary organic aerosol formation from isoprene photooxidation under
high-NOx conditions, Geophys. Res. Lett., 32, L18808, https://doi.org/10.1029/2005GL023637, 2005.
Lam, S. H. M., Saunders, S. M., Guo, H., Ling, Z. H., Jiang, F., Wang, X.
M., and Wang, T. J.: Modelling VOC source impacts on high ozone episode days
observed at a mountain summit in Hong Kong under the influence of
mountain-valley breezes, Atmos. Environ., 81, 166–176, 2013.
Lee-Taylor, J., Madronich, S., Aumont, B., Baker, A., Camredon, M., Hodzic, A., Tyndall, G. S., Apel, E., and Zaveri, R. A.: Explicit modeling of organic chemistry and secondary organic aerosol partitioning for Mexico City and its outflow plume, Atmos. Chem. Phys., 11, 13219–13241, https://doi.org/10.5194/acp-11-13219-2011, 2011.
Li, J., Cleveland, M., Ziemba, L. D., Griffin, R. J., Barsanti, K. C., and
Pankow, J. F.: Modeling regional secondary organic aerosol using the Master
Chemical Mechanism, Atmos. Environ., 102, 52–61, 2015.
Li, N., Fu, T. M., Cao, JJ., Lee, S., Huang, X. F., He, L. Y., Ho, K. F.,
Fu, J. S., and Lam, Y. F.: Sources of secondary organic aerosols in the
Pearl River Delta region in fall: Contributions from the aqueous reactive
uptake of dicarbonyls, Atmos. Environ., 763, 200–207, 2013.
Li, T., Wang, Z., Wang, Y., Wu, C., Liang, Y., Xia, M., Yu, C., Yun, H., Wang, W., Wang, Y., Guo, J., Herrmann, H., and Wang, T.: Chemical characteristics of cloud water and the impacts on aerosol properties at a subtropical mountain site in Hong Kong SAR, Atmos. Chem. Phys., 20, 391–407, https://doi.org/10.5194/acp-20-391-2020, 2020.
Li, X., Brauers, T., Hofzumahaus, A., Lu, K., Li, Y. P., Shao, M., Wagner, T., and Wahner, A.: MAX-DOAS measurements of NO2, HCHO and CHOCHO at a rural site in Southern China, Atmos. Chem. Phys., 13, 2133–2151, https://doi.org/10.5194/acp-13-2133-2013, 2013.
Li, X., Rohrer, F., Brauers, T., Hofzumahaus, A., Lu, K., Shao, M., Zhang, Y. H., and Wahner, A.: Modeling of HCHO and CHOCHO at a semi-rural site in southern China during the PRIDE-PRD2006 campaign, Atmos. Chem. Phys., 14, 12291–12305, https://doi.org/10.5194/acp-14-12291-2014, 2014.
Liggio, J., Li, S. M., and Mclaren, R.: Reactive uptake of glyoxal by
particulate matter, J. Geophys. Res., 110, D10304, https://doi.org/10.1029/2004JD005113, 2005.
Ling, Z. H., Guo, H., Lam, S. H. M., Saunders, S. M., and Wang, T.:
Atmospheric photochemical reactivity and ozone production at two sites in
Hong Kong: Application of a master chemical mechanism–photochemical box
model, J. Geophys. Res., 119, 10567–10582, 2014.
Ling, Z. H., He, Z. R., Wang, Z., Shao, M., and Wang, X. M.: Sources of
methacrolein and methyl vinyl ketone and their contributions to
methylglyoxal and formaldehyde at a receptor site in Pearl River Delta, J.
Environ. Sci., 5, 1–10, 2019.
Liu, X. G., Cheng, Y. F., Zhang, Y. H., Jung, J. S., Sugimoto, N., Chang, S.-Y., Kim, Y. J., Fan, S. J., and Zeng, L. M.: Influences of relative humidity and particle chemical composition on aerosol scattering properties during the 2006 PRD campaign, Atmos. Environ., 42, 1525–1536, 2008.
Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Häseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta – China in summer 2006: measurement and model results, Atmos. Chem. Phys., 10, 11243–11260, https://doi.org/10.5194/acp-10-11243-2010, 2010.
Lu, K. D., Hofzumahaus, A., Holland, F., Bohn, B., Brauers, T., Fuchs, H., Hu, M., Häseler, R., Kita, K., Kondo, Y., Li, X., Lou, S. R., Oebel, A., Shao, M., Zeng, L. M., Wahner, A., Zhu, T., Zhang, Y. H., and Rohrer, F.: Missing OH source in a suburban environment near Beijing: observed and modelled OH and HO2 concentrations in summer 2006, Atmos. Chem. Phys., 13, 1057–1080, https://doi.org/10.5194/acp-13-1057-2013, 2013.
Lv, S., Gong, D., Ding, Y., Lin, Y., Wang, H., and Ding, H.: Elevated levels
of glyoxal and methylglyoxal at a remote mountain site in southern China:
Prompt in-situ formation combined with strong regional transport, Sci. Total
Environ., 672, 869–882, 2019.
Lyu, X. P., Chen, N., Guo, H., Zhang, W. H., and Liu, M.: Ambient volatile
organic compounds and their effect on ozone production in Wuhan, central
China, Sci. Total Environ., 541, 200–209, 2015.
Ma, X., Tan, Z., Lu, K., Yang, X., Liu, Y., Li, S., Li, X., Chen, S.,
Novelli, A., Cho, C., and Zeng, L.: Winter photochemistry in Beijing:
Observation and model simulation of OH and HO2 radicals at an urban
site, Sci. Total Environ., 685, 85–95, 2019.
Madronich, S. and Flocke, S.: Theoretical estimation of biologically
effective UV radiation at the Earth's surface, in: Solar ultraviolet radiation,
152, 23–48, 1997.
Matsunaga, A. and Ziemann, P. J.: Gas-wall partitioning of organic
compounds in a Teflon film chamber and potential effects on reaction product
and aerosol yield measurements, Aerosol Sci. Technol., 44, 881–892,
2010.
McNeill, V. F.: Aqueous Organic Chemistry in the Atmosphere: Sources and
Chemical Processing of Organic Aerosols, Environ. Sci. Technol., 49,
1237–1244, 2015.
Mellouki, A., Wallington, T. J., and Chen, J.: Atmospheric chemistry of
oxygenated volatile organic compounds: impacts on air quality and climate,
Chem. Rev., 10, 3984–4014, 2015.
Nishino, N., Arey, J., and Atkinson, R.: Formation yields of glyoxal and
methylglyoxal from the gas-phase OH radical-initiated reactions of toluene,
xylenes, and trimethylbenzenes as a function of NO2 concentration, J.
Phys. Chem. A., 114, 10140–10147, 2010.
Noziere, B., Dziedzic, P., and Córdova, A.: Products and kinetics of the
liquid-phase reaction of glyoxal catalyzed by ammonium ions
(NH
Pye, H. O. T., Murphy, B. N., Xu, L., Ng, N. L., Carlton, A. G., Guo, H., Weber, R., Vasilakos, P., Appel, K. W., Budisulistiorini, S. H., Surratt, J. D., Nenes, A., Hu, W., Jimenez, J. L., Isaacman-VanWertz, G., Misztal, P. K., and Goldstein, A. H.: On the implications of aerosol liquid water and phase separation for organic aerosol mass, Atmos. Chem. Phys., 17, 343–369, https://doi.org/10.5194/acp-17-343-2017, 2017.
Ren, X., Brune, W. H., Mao, J., Mitchell, M. J., Lesher, R. L., Simpas, J.
B., Metcalf, A. R., Schwab, J. J., Cai, C., Li, Y., and Demerjian, K. L.:
Behavior of OH and HO2 in the winter atmosphere in New York City,
Atmos. Environ., 40, 252–263, 2006.
Schweitzer, F., Magi, L., Mirabel, P., and George, C.: Uptake rate
measurements of methanesulfonic acid and glyoxal by aqueous droplets, J.
Phys. Chem. A., 102, 593–600, 1998.
Stavrakou, T., Müller, J.-F., De Smedt, I., Van Roozendael, M., Kanakidou, M., Vrekoussis, M., Wittrock, F., Richter, A., and Burrows, J. P.: The continental source of glyoxal estimated by the synergistic use of spaceborne measurements and inverse modelling, Atmos. Chem. Phys., 9, 8431–8446, https://doi.org/10.5194/acp-9-8431-2009, 2009.
Stein, S. E. and Brown, R. L.: Estimation of normal boiling points from group contributions, J. Chem. Info. Comp. Sci., 34, 581–587, 1994.
Steinfeld, J. I., Francisco, J. S., and Hase, W. L.: Chemical Kinetics and
Dynamics, 2nd edn., Pearson, 1998.
Stroud, C. A., Makar, P. A., Michelangeli, D. V., Mozurkewich, M., Hastie,
D. R., Barbu, A., and Humble, J.: Simulating organic aerosol formation
during the photooxidation of toluene/Nox mixtures: comparing the equilibrium
and kinetic assumption, Environ. Sci. Technol., 38, 1471–1479, 2004.
Sumner, A. J., Woo, J. L., and McNeill, V. F.: Model Analysis of secondary
organic aerosol formation by glyoxal in laboratory studies: The case for
photoenhanced chemistry, Environ. Sci. Technol., 48, 11919–11925, 2014.
Tan, Z., Lu, K., Hofzumahaus, A., Fuchs, H., Bohn, B., Holland, F., Liu, Y., Rohrer, F., Shao, M., Sun, K., Wu, Y., Zeng, L., Zhang, Y., Zou, Q., Kiendler-Scharr, A., Wahner, A., and Zhang, Y.: Experimental budgets of OH, HO2, and RO2 radicals and implications for ozone formation in the Pearl River Delta in China 2014, Atmos. Chem. Phys., 19, 7129–7150, https://doi.org/10.5194/acp-19-7129-2019, 2019.
Volkamer, R., Barnes, I., Platt, U., Molina, L. T., and Molina, M. J.:
Remote sensing of glyoxal by differential optical absorption spectroscopy
(DOAS): Advancements in simulation chamber and field experiments, in:
Environmental Simulation Chambers: Application to Atmospheric Chemical
Processes, Springer, 2006.
Volkamer, R., San Martini, F., Molina, L. T., Salcedo, D., Jimenez, J. L.,
and Molina, M. J.: A missing sink for gas-phase glyoxal in Mexico City:
Formation of secondary organic aerosol, Geophys. Res. Lett., 34, 255–268,
2007.
Wang, M., Zeng, L., Lu, S., Shao, M., Liu, X., and Yu, X.: Development and
validation of a cryogen-free automatic gas chromatograph system (GC-MS/FID)
for online measurements of volatile organic compounds, Anal. Methods., 6,
9424–9434, 2014.
Wang, S., Wu, D., Wang, X. M., Fung, J. C. H., and Yu, J. Z.: Relative
contributions of secondary organic aerosol formation from toluene, xylenes,
isoprene, and monoterpenes in Hong Kong and Guangzhou in the Pearl River
Delta, China: an emission-based box modeling study, J. Geophys. Res., 118,
507–519, 2013.
Wang, X. M.: Study on the roles of semi-volatile organic compound in the
formation of secondary organic aerosol in East China. NSFC briefing in
Guangzhou, China, p. 3, 2019.
Wang, X. M., Wu, Z. Y., and Liang, G. X.: WRF/CHEM modeling of impacts of
weather conditions modified by urban expansion on secondary organic aerosol
formation over Pearl River Delta, Particuology, 7, 384–391, 2009.
Wang, Y., Wang, H., Guo, H., Lyu, X., Cheng, H., Ling, Z., Louie, P. K. K., Simpson, I. J., Meinardi, S., and Blake, D. R.: Long-term O3–precursor relationships in Hong Kong: field observation and model simulation, Atmos. Chem. Phys., 17, 10919–10935, https://doi.org/10.5194/acp-17-10919-2017, 2017.
Washenfelder, R. A., Young, C. J., Brown, S. S., Angevine, W. M., Atlas, E.
L., Blake, D. R., Bon, D. M., Cubison, M. J., De Gouw, J. A., Dusanter, S.,
Flynn, J., Gilman, J. B., Graus, M., Griffith, S., Grossberg, N., Hayes, P.
L., Jimenez, J. L., Kuster, W. C., Lefer, B. L., Pollack, I. B., Ryerson, T.
B., Stark, H., Stevens, P. S., and Trainer, M. K.: The glyoxal budget and
its contribution to organic aerosol for Los Angeles, California, during
CalNex 2010, J. Geophys. Res., 116, D00V02,
https://doi.org/10.1029/2011JD016314, 2011.
Waxman, E. M., Dzepina, K., Erves, B., Lee-Taylor, J., Aumont, B., Jimenez,
J. L., Madronich, S., and Volkamer, R.: Secondary organic aerosol formation
from semi- and intermediate volatility organic compounds and glyoxal:
relevance of O/C as a tracer for aqueous multiphase chemistry, Geophys. Res.
Lett., 40, 978–982, 2013.
Waxman, E. M., Elm, J., Kurtén, T., Mikkelsen, K. V., Ziemann, P. J.,
and Volkamer, R.: Glyoxal and methylglyoxal setschenow salting constants in
sulfate, nitrate, and chloride solutions: Measurements and Gibbs energies,
Environ. Sci. Technol., 49, 11500–11508, 2015.
Wu, L., Wang, X., Lu, S., Shao, M., and Ling, Z.: Emission inventory of semi-volatile and intermediate-volatility organic compounds and their effects on secondary organic aerosol over the Pearl River Delta region, Atmos. Chem. Phys., 19, 8141–8161, https://doi.org/10.5194/acp-19-8141-2019, 2019.
Xu, Z., Wang, T., Xue, L. K., Louie, P. K. K., Luk, C. W. Y., and Gao, J.:
Evaluating the uncertainties of thermal catalytic conversion in measuring
atmospheric nitrogen dioxide at four differently polluted sites in China,
Atmos. Environ., 76, 221–226, 2013.
Xue, L. K., Wang, T., Gao, J., Ding, A. J., Zhou, X. H., Blake, D. R., Wang, X. F., Saunders, S. M., Fan, S. J., Zuo, H. C., Zhang, Q. Z., and Wang, W. X.: Ground-level ozone in four Chinese cities: precursors, regional transport and heterogeneous processes, Atmos. Chem. Phys., 14, 13175–13188, https://doi.org/10.5194/acp-14-13175-2014, 2014a.
Xue, L. K., Wang, T., Louie, P. K. K., Luk, C. W. Y., Blake, D. R., and Xu,
Z.: Increasing external effects negate local efforts to control ozone air
pollution: a case study of Hong Kong and implications for other Chinese
cities, Environ. Sci. Technol., 48, 10769–10775, 2014b.
Ying, Q., Li, J., and Kota, S. H.: Significant contributions of isoprene to
summertime secondary organic aerosol in eastern United States, Environ. Sci.
Technol., 49, 7834–7842, 2015.
Yu, G., Bayer, A. R., Galloway, M. M., Korshavn, K. J., Fry, C. G., and
Keutsch, F. N.: Glyoxal in aqueous ammonium sulfate solutions: products,
kinetics and hydration effects, Environ. Sci. Technol., 45, 6336–6342, 2011.
Yuan, B., Hu, W. W., Shao, M., Wang, M., Chen, W. T., Lu, S. H., Zeng, L. M., and Hu, M.: VOC emissions, evolutions and contributions to SOA formation at a receptor site in eastern China, Atmos. Chem. Phys., 13, 8815–8832, https://doi.org/10.5194/acp-13-8815-2013, 2013.
Yun, H., Wang, W., Wang, T., Xia, M., Yu, C., Wang, Z., Poon, S. C. N., Yue, D., and Zhou, Y.: Nitrate formation from heterogeneous uptake of dinitrogen pentoxide during a severe winter haze in southern China, Atmos. Chem. Phys., 18, 17515–17527, https://doi.org/10.5194/acp-18-17515-2018, 2018.
Zhang, R. Y., Wang, G. H., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang,
W. G., Hu, M., and Wang, Y.: Formation of urban fine particle matter, Chem.
Rev., 115, 3803–3855, 2015.
Zhang, X. and Seinfeld, J. H.: A functional group oxidation model (FGOM) for SOA formation and aging, Atmos. Chem. Phys., 13, 5907–5926, https://doi.org/10.5194/acp-13-5907-2013, 2013.
Zhang, X., Cappa, C. D., Jathar, S. H., McVay, R. C., Ensberg, J. J.,
Kleeman, M. J., and Seinfeld, J. H.: Influence of vapor wall loss in
laboratory chambers on yields of secondary organic aerosol, P. Natl. Acad. Sci., 111, 5802–5807, 2014.
Zhang, Y. L., Wang, X. M., Sheng, W., Herrmann, H., Yang, W. Q., Huang, X.
Y., Zhou, Z., Huang, Z. H., He, Q. F., and George, C.: On-road vehicle
emissions of glyoxal and methylglyoxal from tunnel tests in urban Guangzhou,
China. Atmos. Environ., 127, 55–60, 2016.
Zhang, Z., Wang, H., Chen, D., Li, Q., Thai, P., and Gong, D.: Emission
characteristics of volatile organic compounds and their secondary organic
aerosol formation potentials from a petroleum refinery in pearl river delta,
China, Sci. Total Environ., 584–585, 1162–1174, 2017.
Zhou, X. and Mopper, K.: Measurement of sub-parts-per-billion levels of
carbonyl compounds in marine air by a simple cartridge trapping procedure
followed by liquid chromatography, Environ. Sci. Technol., 24, 1482–1485,
1990.
Zhu, T., Shang, J., and Zhao, D. F.: The roles of heterogeneous chemical
processes in the formation of an air pollution complex and gray haze, Sci.
China. Chem., 54, 145–153, 2011.
Short summary
The observation data from a receptor site in the Pearl River Delta region were analyzed by a photochemical box model with near-explicit chemical mechanisms (i.e., the Master Chemical Mechanism, MCM), improvements with reversible and irreversible heterogeneous processes of glyoxal and methylglyoxal, and the gas-particle partitioning of oxidation products in the present study.
The observation data from a receptor site in the Pearl River Delta region were analyzed by a...
Altmetrics
Final-revised paper
Preprint