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ACP | Articles | Volume 18, issue 15
Atmos. Chem. Phys., 18, 11409–11422, 2018
https://doi.org/10.5194/acp-18-11409-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Special issue: Simulation chambers as tools in atmospheric research (AMT/ACP/GMD...

Atmos. Chem. Phys., 18, 11409–11422, 2018
https://doi.org/10.5194/acp-18-11409-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 15 Aug 2018

Research article | 15 Aug 2018

Evaluation of OH and HO2 concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR

Anna Novelli et al.

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Cited articles

Bohn, B. and Zilken, H.: Model-aided radiometric determination of photolysis frequencies in a sunlit atmosphere simulation chamber, Atmos. Chem. Phys., 5, 191–206, https://doi.org/10.5194/acp-5-191-2005, 2005. 
Bohn, B., Rohrer, F., Brauers, T., and Wahner, A.: Actinometric measurements of NO2 photolysis frequencies in the atmosphere simulation chamber SAPHIR, Atmos. Chem. Phys., 5, 493–503, https://doi.org/10.5194/acp-5-493-2005, 2005. 
Carrasco, N., Doussin, J. F., Picquet-Varrault, B., and Carlier, P.: Tropospheric degradation of 2-hydroxy-2-methylpropanal, a photo-oxidation product of 2-methyl-3-buten-2-ol: Kinetic and mechanistic study of its photolysis and its reaction with OH radicals, Atmos. Environ., 40, 2011–2019, https://doi.org/10.1016/j.atmosenv.2005.11.042, 2006. 
Carslaw, N., Creasey, D. J., Harrison, D., Heard, D. E., Hunter, M. C., Jacobs, P. J., Jenkin, M. E., Lee, J. D., Lewis, A. C., Pilling, M. J., Saunders, S. M., and Seakins, P. W.: OH and HO2 radical chemistry in a forested region of north-western Greece, Atmos. Environ. , 35, 4725–4737, https://doi.org/10.1016/S1352-2310(01)00089-9, 2001.  
Crounse, J. D., Paulot, F., Kjaergaard, H. G., and Wennberg, P. O.: Peroxy radical isomerization in the oxidation of isoprene, Phys. Chem. Chem. Phys., 13, 13607–13613, https://doi.org/10.1039/c1cp21330j, 2011. 
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Short summary
The impact of photooxidation of 2-methyl-3-butene-2-ol (MBO) on the concentration of radical species was studied in the atmospheric simulation chamber SAPHIR. MBO is a volatile organic compound mainly emitted by ponderosa and lodgepole pines which are very abundant in forests in the central-west USA. A very good agreement between measured and modelled radical concentrations and products from the oxidation of MBO was observed in an environment with NO of ~ 200 pptv.
The impact of photooxidation of 2-methyl-3-butene-2-ol (MBO) on the concentration of radical...
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