Articles | Volume 18, issue 15
https://doi.org/10.5194/acp-18-11409-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-11409-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Aug 2018
Research article |
| 15 Aug 2018
| 15 Aug 2018
Evaluation of OH and HO2 concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Martin Kaminski
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Bundesamt für Verbraucherschutz, Abteilung 5 –
Methodenstandardisierung, Referenzlaboratorien und Antibiotikaresistenz, Berlin, Germany
Michael Rolletter
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Institute of Nutrition and Food Sciences, Food Chemistry,
University of Bonn, Bonn, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Hans-Peter Dorn
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Xin Li
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: State Key Joint Laboratory of Environmental Simulation and
Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Anna Lutz
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Sascha Nehr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: INBUREX Consulting GmbH, Process Safety, Hamm, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Robert Wegener
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Frank Holland
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
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- Investigation of the α-pinene photooxidation by OH in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-19-11635-2019
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- Re-assessing hydroxyl radical chemistry in the atmosphere: Instrument interferences may explain previous measurement discrepancies P. Price et al. 10.1038/s43247-025-02308-y
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
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- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al. 10.1029/2020MS002420
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Additional HONO and OH Generation from Photoexcited Phenyl Organic Nitrates in the Photoreaction of Aromatics and NOx T. Chen et al. 10.1021/acs.est.3c10193
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. 10.5194/amt-14-1851-2021
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. 10.1029/2020JD032901
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- A Box-Model Simulation of the Formation of Inorganic Ionic Particulate Species and Their Air Quality Implications in Republic of Korea H. Lee et al. 10.5572/ajae.2022.119
20 citations as recorded by crossref.
- Investigation of the α-pinene photooxidation by OH in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-19-11635-2019
- Rapid Adaptive Optimization Model for Atmospheric Chemistry (ROMAC) v1.0 J. Li et al. 10.5194/gmd-16-6049-2023
- The MESSy DWARF (based on MESSy v2.55.2) A. Kerkweg et al. 10.5194/gmd-18-1265-2025
- Re-assessing hydroxyl radical chemistry in the atmosphere: Instrument interferences may explain previous measurement discrepancies P. Price et al. 10.1038/s43247-025-02308-y
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- AtChem (version 1), an open-source box model for the Master Chemical Mechanism R. Sommariva et al. 10.5194/gmd-13-169-2020
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al. 10.1029/2020MS002420
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- Green Leaf Volatiles in the Atmosphere—Properties, Transformation, and Significance K. Sarang et al. 10.3390/atmos12121655
- Additional HONO and OH Generation from Photoexcited Phenyl Organic Nitrates in the Photoreaction of Aromatics and NOx T. Chen et al. 10.1021/acs.est.3c10193
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. 10.5194/amt-14-1851-2021
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. 10.1029/2020JD032901
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- A Box-Model Simulation of the Formation of Inorganic Ionic Particulate Species and Their Air Quality Implications in Republic of Korea H. Lee et al. 10.5572/ajae.2022.119
Latest update: 10 May 2025
Short summary
The impact of photooxidation of 2-methyl-3-butene-2-ol (MBO) on the concentration of radical species was studied in the atmospheric simulation chamber SAPHIR. MBO is a volatile organic compound mainly emitted by ponderosa and lodgepole pines which are very abundant in forests in the central-west USA. A very good agreement between measured and modelled radical concentrations and products from the oxidation of MBO was observed in an environment with NO of ~ 200 pptv.
The impact of photooxidation of 2-methyl-3-butene-2-ol (MBO) on the concentration of radical...
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