Articles | Volume 25, issue 11
https://doi.org/10.5194/acp-25-5793-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-5793-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Jun 2025
Research article |
| 12 Jun 2025
| 12 Jun 2025
Evaluation of O3, H2O, CO, and NOy climatologies simulated by four global models in the upper troposphere–lower stratosphere with IAGOS measurements
Institut Pierre-Simon Laplace, Sorbonne Université/CNRS, Paris, France
Laboratoire des Sciences du Climat et de l'Environnement, LSCE-IPSL (CEA-CNRS-UVSQ), Université Paris-Saclay, Gif-sur-Yvette, France
Didier Hauglustaine
Laboratoire des Sciences du Climat et de l'Environnement, LSCE-IPSL (CEA-CNRS-UVSQ), Université Paris-Saclay, Gif-sur-Yvette, France
Nicolas Bellouin
Institut Pierre-Simon Laplace, Sorbonne Université/CNRS, Paris, France
Department of Meteorology, University of Reading, Reading, UK
Marianne Tronstad Lund
CICERO Center for International Climate Research, Oslo, Norway
Sigrun Matthes
Institut für Physik der Atmosphäre, Deutsches Zentrum für Luft und Raumfahrt, Oberpfaffenhofen, Germany
Agnieszka Skowron
Faculty of Science and Engineering, Manchester Metropolitan University, Manchester, UK
Robin Thor
Institut für Physik der Atmosphäre, Deutsches Zentrum für Luft und Raumfahrt, Oberpfaffenhofen, Germany
Ulrich Bundke
Institute of Energy and Climate Research 8 – Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Petzold
Institute of Energy and Climate Research 8 – Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Institute for Atmospheric and Environmental Research, University of Wuppertal, Wuppertal, Germany
Susanne Rohs
Institute of Energy and Climate Research 8 – Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Valérie Thouret
Laboratoire d'Aérologie, Université de Toulouse, CNRS, UPS, Toulouse, France
Andreas Zahn
Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Helmut Ziereis
Institut für Physik der Atmosphäre, Deutsches Zentrum für Luft und Raumfahrt, Oberpfaffenhofen, Germany
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Kevin Wolf, Nicolas Bellouin, Olivier Boucher, Susanne Rohs, and Yun Li
Atmos. Chem. Phys., 25, 157–181, https://doi.org/10.5194/acp-25-157-2025, https://doi.org/10.5194/acp-25-157-2025, 2025
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Herman G.J. Smit, Torben Galle, Romain Blot, Florian Obersteiner, Philippe Nédélec, Andreas Zahn, Jean-Marc Cousin, Ulrich Bundke, Andreas Petzold, Valerie Thouret, and Hannah Clark
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Julie Carles, Nicolas Bellouin, Najda Villefranque, and Jean-Louis Dufresne
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Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Rodrigo J. Seguel, Charlie Opazo, Yann Cohen, Owen R. Cooper, Laura Gallardo, Björn-Martin Sinnhuber, Florian Obersteiner, Andreas Zahn, Peter Hoor, and Susanne Rohs
EGUsphere, https://doi.org/10.5194/egusphere-2024-3719, https://doi.org/10.5194/egusphere-2024-3719, 2024
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Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 24, 13503–13523, https://doi.org/10.5194/acp-24-13503-2024, https://doi.org/10.5194/acp-24-13503-2024, 2024
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Atmos. Chem. Phys., 24, 12079–12106, https://doi.org/10.5194/acp-24-12079-2024, https://doi.org/10.5194/acp-24-12079-2024, 2024
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Randall Chiu, Florian Obersteiner, Alessandro Franchin, Teresa Campos, Adriana Bailey, Christopher Webster, Andreas Zahn, and Rainer Volkamer
Atmos. Meas. Tech., 17, 5731–5746, https://doi.org/10.5194/amt-17-5731-2024, https://doi.org/10.5194/amt-17-5731-2024, 2024
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The ozone sink into oceans and marine clouds is seldom studied and highly uncertain. Calculations suggest O3 destruction at aqueous surfaces (ocean, droplets) may be strongly accelerated, but field evidence is missing. Here we compare three fast airborne O3 instruments to measure eddy covariance fluxes of O3 over the remote ocean, in clear and cloudy air. We find O3 fluxes below clouds are consistently directed into clouds, while O3 fluxes into oceans are much smaller and spatially variable.
Audran Borella, Olivier Boucher, Keith P. Shine, Marc Stettler, Katsumasa Tanaka, Roger Teoh, and Nicolas Bellouin
Atmos. Chem. Phys., 24, 9401–9417, https://doi.org/10.5194/acp-24-9401-2024, https://doi.org/10.5194/acp-24-9401-2024, 2024
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This work studies how to compare the climate impact of the CO2 emitted and contrails formed by a flight. This is applied to contrail avoidance strategies that would decrease climate impact of flights by changing the trajectory of aircraft to avoid persistent contrail formation, at the risk of increasing CO2 emissions. We find that different comparison methods lead to different quantification of the total climate impact of a flight but lead to similar decisions of whether to reroute an aircraft.
Marit Sandstad, Borgar Aamaas, Ane Nordlie Johansen, Marianne Tronstad Lund, Glen Philip Peters, Bjørn Hallvard Samset, Benjamin Mark Sanderson, and Ragnhild Bieltvedt Skeie
Geosci. Model Dev., 17, 6589–6625, https://doi.org/10.5194/gmd-17-6589-2024, https://doi.org/10.5194/gmd-17-6589-2024, 2024
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The CICERO-SCM has existed as a Fortran model since 1999 that calculates the radiative forcing and concentrations from emissions and is an upwelling diffusion energy balance model of the ocean that calculates temperature change. In this paper, we describe an updated version ported to Python and publicly available at https://github.com/ciceroOslo/ciceroscm (https://doi.org/10.5281/zenodo.10548720). This version contains functionality for parallel runs and automatic calibration.
Henk Eskes, Athanasios Tsikerdekis, Melanie Ades, Mihai Alexe, Anna Carlin Benedictow, Yasmine Bennouna, Lewis Blake, Idir Bouarar, Simon Chabrillat, Richard Engelen, Quentin Errera, Johannes Flemming, Sebastien Garrigues, Jan Griesfeller, Vincent Huijnen, Luka Ilić, Antje Inness, John Kapsomenakis, Zak Kipling, Bavo Langerock, Augustin Mortier, Mark Parrington, Isabelle Pison, Mikko Pitkänen, Samuel Remy, Andreas Richter, Anja Schoenhardt, Michael Schulz, Valerie Thouret, Thorsten Warneke, Christos Zerefos, and Vincent-Henri Peuch
Atmos. Chem. Phys., 24, 9475–9514, https://doi.org/10.5194/acp-24-9475-2024, https://doi.org/10.5194/acp-24-9475-2024, 2024
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The Copernicus Atmosphere Monitoring Service (CAMS) provides global analyses and forecasts of aerosols and trace gases in the atmosphere. On 27 June 2023 a major upgrade, Cy48R1, became operational. Comparisons with in situ, surface remote sensing, aircraft, and balloon and satellite observations show that the new CAMS system is a significant improvement. The results quantify the skill of CAMS to forecast impactful events, such as wildfires, dust storms and air pollution peaks.
Kuo-Ying Wang, Philippe Nedelec, Valerie Thouret, Hannah Clark, Andreas Wahner, and Andreas Petzold
EGUsphere, https://doi.org/10.5194/egusphere-2024-2414, https://doi.org/10.5194/egusphere-2024-2414, 2024
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We use routine in-service commercial passenger airplanes Airbus A340 and A330 to collect air pollutants in the upper troposphere. The beauty in using commercial airplanes is that these commercial airplanes, like taxi on the ground, keep flying all the time. We find that short-lived air pollutants are very sensitive to ground-level emissions. Effective regulation in ground-level emissions can help to reduce air pollution in the upper troposphere.
Sina Hofer, Klaus Gierens, and Susanne Rohs
Atmos. Chem. Phys., 24, 7911–7925, https://doi.org/10.5194/acp-24-7911-2024, https://doi.org/10.5194/acp-24-7911-2024, 2024
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We try to improve the forecast of ice supersaturation (ISS) and potential persistent contrails using data on dynamical quantities in addition to temperature and relative humidity in a modern kind of regression model. Although the results are improved, they are not good enough for flight routing. The origin of the problem is the strong overlap of probability densities conditioned on cases with and without ice-supersaturated regions (ISSRs) in the important range of 70–100 %.
Philipp Joppe, Johannes Schneider, Katharina Kaiser, Horst Fischer, Peter Hoor, Daniel Kunkel, Hans-Christoph Lachnitt, Andreas Marsing, Lenard Röder, Hans Schlager, Laura Tomsche, Christiane Voigt, Andreas Zahn, and Stephan Borrmann
Atmos. Chem. Phys., 24, 7499–7522, https://doi.org/10.5194/acp-24-7499-2024, https://doi.org/10.5194/acp-24-7499-2024, 2024
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From aircraft measurements in the upper troposphere/lower stratosphere, we find a correlation between the ozone and particulate sulfate in the lower stratosphere. The correlation exhibits some variability over the measurement period exceeding the background sulfate-to-ozone correlation. From our analysis, we conclude that gas-to-particle conversion of volcanic sulfur dioxide leads to observed enhanced sulfate aerosol mixing ratios.
Roger Teoh, Zebediah Engberg, Ulrich Schumann, Christiane Voigt, Marc Shapiro, Susanne Rohs, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 6071–6093, https://doi.org/10.5194/acp-24-6071-2024, https://doi.org/10.5194/acp-24-6071-2024, 2024
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The radiative forcing (RF) due to aviation contrails is comparable to that caused by CO2. We estimate that global contrail net RF in 2019 was 62.1 mW m−2. This is ~1/2 the previous best estimate for 2018. Contrail RF varies regionally due to differences in conditions required for persistent contrails. COVID-19 reduced contrail RF by 54% in 2020 relative to 2019. Globally, 2 % of all flights account for 80 % of the annual contrail energy forcing, suggesting a opportunity to mitigate contrail RF.
Federica Castino, Feijia Yin, Volker Grewe, Hiroshi Yamashita, Sigrun Matthes, Simone Dietmüller, Sabine Baumann, Manuel Soler, Abolfazl Simorgh, Maximilian Mendiguchia Meuser, Florian Linke, and Benjamin Lührs
Geosci. Model Dev., 17, 4031–4052, https://doi.org/10.5194/gmd-17-4031-2024, https://doi.org/10.5194/gmd-17-4031-2024, 2024
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We introduce SolFinder 1.0, a decision-making tool to select trade-offs between different objective functions for optimal aircraft trajectories, including fuel use, flight time, NOx emissions, contrail distance, and climate impact. The module is included in the AirTraf 3.0 submodel and uses weather conditions simulated by the EMAC atmospheric model. This paper focuses on the ability of SolFinder to identify eco-efficient trajectories, reducing a flight's climate impact at limited cost penalties.
Sidiki Sanogo, Olivier Boucher, Nicolas Bellouin, Audran Borella, Kevin Wolf, and Susanne Rohs
Atmos. Chem. Phys., 24, 5495–5511, https://doi.org/10.5194/acp-24-5495-2024, https://doi.org/10.5194/acp-24-5495-2024, 2024
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Relative humidity relative to ice (RHi) is a key variable in the formation of cirrus clouds and contrails. This study shows that the properties of the probability density function of RHi differ between the tropics and higher latitudes. In line with RHi and temperature variability, aircraft are likely to produce more contrails with bioethanol and liquid hydrogen as fuel. The impact of this fuel change decreases with decreasing pressure levels but increases from high latitudes to the tropics.
Andreas Petzold, Ulrich Bundke, Anca Hienola, Paolo Laj, Cathrine Lund Myhre, Alex Vermeulen, Angeliki Adamaki, Werner Kutsch, Valerie Thouret, Damien Boulanger, Markus Fiebig, Markus Stocker, Zhiming Zhao, and Ari Asmi
Atmos. Chem. Phys., 24, 5369–5388, https://doi.org/10.5194/acp-24-5369-2024, https://doi.org/10.5194/acp-24-5369-2024, 2024
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Easy and fast access to long-term and high-quality observational data is recognised as fundamental to environmental research and the development of climate forecasting and assessment services. We discuss the potential new directions in atmospheric sciences offered by the atmosphere-centric European research infrastructures ACTRIS, IAGOS, and ICOS, building on their capabilities for standardised provision of data through open access combined with tools and methods of data-intensive science.
Kevin Wolf, Nicolas Bellouin, and Olivier Boucher
Atmos. Chem. Phys., 24, 5009–5024, https://doi.org/10.5194/acp-24-5009-2024, https://doi.org/10.5194/acp-24-5009-2024, 2024
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The contrail formation potential and its tempo-spatial distribution are estimated for the North Atlantic flight corridor. Meteorological conditions of temperature and relative humidity are taken from the ERA5 re-analysis and IAGOS. Based on IAGOS flight tracks, crossing length, size, orientation, frequency of occurrence, and overlap of persistent contrail formation areas are determined. The presented conclusions might provide a guide for statistical flight track optimization to reduce contrails.
Ella Gilbert, Jhaswantsing Purseed, Yun Li, Martina Krämer, Beatrice Altamura, and Nicolas Bellouin
EGUsphere, https://doi.org/10.5194/egusphere-2024-821, https://doi.org/10.5194/egusphere-2024-821, 2024
Preprint withdrawn
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We use a simple experiment to explore the non-CO2 impacts of aviation on climate, which are considerably larger than the impact of the sector’s carbon emissions alone. We show that the main effect of our experiments – which intend to mimic the effect of aircraft soot emissions reaching existing high-altitude cirrus clouds – is to extend cloud lifetime, thereby enhancing their effect on climate.
Huisheng Bian, Mian Chin, Peter R. Colarco, Eric C. Apel, Donald R. Blake, Karl Froyd, Rebecca S. Hornbrook, Jose Jimenez, Pedro Campuzano Jost, Michael Lawler, Mingxu Liu, Marianne Tronstad Lund, Hitoshi Matsui, Benjamin A. Nault, Joyce E. Penner, Andrew W. Rollins, Gregory Schill, Ragnhild B. Skeie, Hailong Wang, Lu Xu, Kai Zhang, and Jialei Zhu
Atmos. Chem. Phys., 24, 1717–1741, https://doi.org/10.5194/acp-24-1717-2024, https://doi.org/10.5194/acp-24-1717-2024, 2024
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This work studies sulfur in the remote troposphere at global and seasonal scales using aircraft measurements and multi-model simulations. The goal is to understand the sulfur cycle over remote oceans, spread of model simulations, and observation–model discrepancies. Such an understanding and comparison with real observations are crucial to narrow down the uncertainties in model sulfur simulations and improve understanding of the sulfur cycle in atmospheric air quality, climate, and ecosystems.
Tanja J. Schuck, Johannes Degen, Eric Hintsa, Peter Hoor, Markus Jesswein, Timo Keber, Daniel Kunkel, Fred Moore, Florian Obersteiner, Matt Rigby, Thomas Wagenhäuser, Luke M. Western, Andreas Zahn, and Andreas Engel
Atmos. Chem. Phys., 24, 689–705, https://doi.org/10.5194/acp-24-689-2024, https://doi.org/10.5194/acp-24-689-2024, 2024
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We study the interhemispheric gradient of sulfur hexafluoride (SF6), a strong long-lived greenhouse gas. Its emissions are stronger in the Northern Hemisphere; therefore, mixing ratios in the Southern Hemisphere lag behind. Comparing the observations to a box model, the model predicts air in the Southern Hemisphere to be older. For a better agreement, the emissions used as model input need to be increased (and their spatial pattern changed), and we need to modify north–south transport.
Ondřej Tichý, Sabine Eckhardt, Yves Balkanski, Didier Hauglustaine, and Nikolaos Evangeliou
Atmos. Chem. Phys., 23, 15235–15252, https://doi.org/10.5194/acp-23-15235-2023, https://doi.org/10.5194/acp-23-15235-2023, 2023
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We show declining trends in NH3 emissions over Europe for 2013–2020 using advanced dispersion and inverse modelling and satellite measurements from CrIS. Emissions decreased by −26% since 2013, showing that the abatement strategies adopted by the European Union have been very efficient. Ammonia emissions are low in winter and peak in summer due to temperature-dependent soil volatilization. The largest decreases were observed in central and western Europe in countries with high emissions.
Yann Cohen, Didier Hauglustaine, Bastien Sauvage, Susanne Rohs, Patrick Konjari, Ulrich Bundke, Andreas Petzold, Valérie Thouret, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 23, 14973–15009, https://doi.org/10.5194/acp-23-14973-2023, https://doi.org/10.5194/acp-23-14973-2023, 2023
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The upper troposphere–lower stratosphere (UTLS) is a key region regarding the lower atmospheric composition. This study consists of a comprehensive evaluation of an up-to-date chemistry–climate model in this layer, using regular in situ measurements based on passenger aircraft. For this purpose, a specific software (Interpol-IAGOS) has been updated and made publicly available. The model reproduces the carbon monoxide peaks due to biomass burning over the continental tropics particularly well.
Maria Tsivlidou, Bastien Sauvage, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Eric Le Flochmoën, Philippe Nédélec, Valérie Thouret, Pawel Wolff, and Brice Barret
Atmos. Chem. Phys., 23, 14039–14063, https://doi.org/10.5194/acp-23-14039-2023, https://doi.org/10.5194/acp-23-14039-2023, 2023
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The tropics are a region where the ozone increase has been most apparent since 1980 and where observations are sparse. Using aircraft, satellite, and model data, we document the characteristics of tropospheric ozone and CO over the whole tropics for the last 2 decades. We explore the origin of the observed CO anomalies and investigate transport processes driving the tropical CO and O3 distribution. Our study highlights the importance of anthropogenic emissions, mostly over the northern tropics.
Sigrun Matthes, Simone Dietmüller, Katrin Dahlmann, Christine Frömming, Patrick Peter, Hiroshi Yamashita, Volker Grewe, Feijia Yin, and Federica Castino
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-92, https://doi.org/10.5194/gmd-2023-92, 2023
Revised manuscript not accepted
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Aviation aims to reduce its climate effect by identifying alternative climate-optimized aircraft trajectories. Such routing strategies requires a dedicated meteorological service in order to inform on regions of the atmosphere where aviation non-CO2 emissions have a large climate effect, e.g. by contrail formation or nitrogen-oxide (NOx)-induced ozone formation. This study presents calibration factors for individual non-CO2 effects by comparing with the climate response model AirClim.
Kevin Wolf, Nicolas Bellouin, and Olivier Boucher
Atmos. Chem. Phys., 23, 14003–14037, https://doi.org/10.5194/acp-23-14003-2023, https://doi.org/10.5194/acp-23-14003-2023, 2023
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Cirrus and contrails considerably impact Earth's energy budget. Such ice clouds can have a positive (warming) or negative (cooling) net radiative effect (RE), which depends on cloud and ambient properties. The effect of eight parameters on the cloud RE is estimated. In total, 283 500 radiative transfer simulations have been performed, spanning the typical parameter ranges associated with cirrus and contrails. Specific cases are selected and discussed. The data set is publicly available.
Saroj Kumar Sahu, Poonam Mangaraj, Gufran Beig, Marianne T. Lund, Bjørn Hallvard Samset, Pallavi Sahoo, and Ashirbad Mishra
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-310, https://doi.org/10.5194/essd-2023-310, 2023
Revised manuscript not accepted
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Elevated emission of particulate matter is not limited to urban areas, led to poor air quality across the country. Emission Inventory is the first line of defensive tools for air quality management and understanding and identification of the source of pollutants. The present work is an attempt to develop a high-resolution (~10 km) national inventory of particulate pollutants in India for 2020 using IPCC methodology. The developed dataset is vital piece of information for mitigation strategies.
Laura J. Wilcox, Robert J. Allen, Bjørn H. Samset, Massimo A. Bollasina, Paul T. Griffiths, James Keeble, Marianne T. Lund, Risto Makkonen, Joonas Merikanto, Declan O'Donnell, David J. Paynter, Geeta G. Persad, Steven T. Rumbold, Toshihiko Takemura, Kostas Tsigaridis, Sabine Undorf, and Daniel M. Westervelt
Geosci. Model Dev., 16, 4451–4479, https://doi.org/10.5194/gmd-16-4451-2023, https://doi.org/10.5194/gmd-16-4451-2023, 2023
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Changes in anthropogenic aerosol emissions have strongly contributed to global and regional climate change. However, the size of these regional impacts and the way they arise are still uncertain. With large changes in aerosol emissions a possibility over the next few decades, it is important to better quantify the potential role of aerosol in future regional climate change. The Regional Aerosol Model Intercomparison Project will deliver experiments designed to facilitate this.
Simone Dietmüller, Sigrun Matthes, Katrin Dahlmann, Hiroshi Yamashita, Abolfazl Simorgh, Manuel Soler, Florian Linke, Benjamin Lührs, Maximilian M. Meuser, Christian Weder, Volker Grewe, Feijia Yin, and Federica Castino
Geosci. Model Dev., 16, 4405–4425, https://doi.org/10.5194/gmd-16-4405-2023, https://doi.org/10.5194/gmd-16-4405-2023, 2023
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Climate-optimized aircraft trajectories avoid atmospheric regions with a large climate impact due to aviation emissions. This requires spatially and temporally resolved information on aviation's climate impact. We propose using algorithmic climate change functions (aCCFs) for CO2 and non-CO2 effects (ozone, methane, water vapor, contrail cirrus). Merged aCCFs combine individual aCCFs by assuming aircraft-specific parameters and climate metrics. Technically this is done with a Python library.
Patrick Weber, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Susanne Hering, Steven Spielman, Gregory Lewis, Andreas Petzold, and Ulrich Bundke
Atmos. Meas. Tech., 16, 3505–3514, https://doi.org/10.5194/amt-16-3505-2023, https://doi.org/10.5194/amt-16-3505-2023, 2023
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This study tests the new water condensation particle counter (MAGIC 210-LP) for deployment on passenger aircraft coordinated by the European research infrastructure IAGOS. We conducted a series of laboratory experiments for flight altitude conditions. We demonstrate that this water condensation particle counter model shows excellent agreement with a butanol-based instrument used in parallel and a Faraday cup electrometer as reference instrument at all tested pressure conditions.
Midhun George, Maria Dolores Andrés Hernández, Vladyslav Nenakhov, Yangzhuoran Liu, John Philip Burrows, Birger Bohn, Eric Förster, Florian Obersteiner, Andreas Zahn, Theresa Harlaß, Helmut Ziereis, Hans Schlager, Benjamin Schreiner, Flora Kluge, Katja Bigge, and Klaus Pfeilsticker
Atmos. Chem. Phys., 23, 7799–7822, https://doi.org/10.5194/acp-23-7799-2023, https://doi.org/10.5194/acp-23-7799-2023, 2023
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The applicability of photostationary steady-state (PSS) assumptions to estimate the amount of the sum of peroxy radicals (RO2*) during the EMeRGe airborne observations from the known radical chemistry and onboard measurements of RO2* precursors, photolysis frequencies, and other trace gases such as NOx and O3 was investigated. The comparison of the calculated RO2* with the actual measurements provides an insight into the main processes controlling their concentration in the air masses measured.
Abolfazl Simorgh, Manuel Soler, Daniel González-Arribas, Florian Linke, Benjamin Lührs, Maximilian M. Meuser, Simone Dietmüller, Sigrun Matthes, Hiroshi Yamashita, Feijia Yin, Federica Castino, Volker Grewe, and Sabine Baumann
Geosci. Model Dev., 16, 3723–3748, https://doi.org/10.5194/gmd-16-3723-2023, https://doi.org/10.5194/gmd-16-3723-2023, 2023
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This paper addresses the robust climate optimal trajectory planning problem under uncertain meteorological conditions within the structured airspace. Based on the optimization methodology, a Python library has been developed, which can be accessed using the following DOI: https://doi.org/10.5281/zenodo.7121862. The developed tool is capable of providing robust trajectories taking into account all probable realizations of meteorological conditions provided by an EPS computationally very fast.
Patrick Weber, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Jannik Schmitt, Gerhard Steiner, Lothar Keck, Andreas Petzold, and Ulrich Bundke
Aerosol Research, 1, 1–12, https://doi.org/10.5194/ar-1-1-2023, https://doi.org/10.5194/ar-1-1-2023, 2023
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The aerosol number concentration is essential information for aerosol science. A condensation particle counter (CPC) can robustly provide this information. Butanol is often used as a working fluid in a CPC. We could show that dimethyl sulfoxide (DMSO) behaves equivalently to butanol in terms of the instrument`s counting efficiency, cut-off diameter and concentration linearity. We tested this on different aerosols, including sodium chloride, ammonium sulfate and fresh combustion soot.
Robin N. Thor, Malte Niklaß, Katrin Dahlmann, Florian Linke, Volker Grewe, and Sigrun Matthes
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-126, https://doi.org/10.5194/gmd-2023-126, 2023
Preprint withdrawn
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We develop a simplied method to estimate the climate effects of single flights through CO2 and non-CO2 effects, exclusively based on the aircraft seat category as well as the origin and destination airports. The derived climate effect functions exhibit a mean relative error of only 15 % with respect to results from a climate response model. The method is designed for climate footprint assessments and covers most commerical airlines with seat capacities starting from 101 passengers.
Marianne Tronstad Lund, Gunnar Myhre, Ragnhild Bieltvedt Skeie, Bjørn Hallvard Samset, and Zbigniew Klimont
Atmos. Chem. Phys., 23, 6647–6662, https://doi.org/10.5194/acp-23-6647-2023, https://doi.org/10.5194/acp-23-6647-2023, 2023
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Here we show that differences, in magnitude and trend, between recent global anthropogenic emission inventories have a notable influence on simulated regional abundances of anthropogenic aerosol over the 1990–2019 period. This, in turn, affects estimates of radiative forcing. Our findings form a basis for comparing existing and upcoming studies on anthropogenic aerosols using different emission inventories.
Luis F. Millán, Gloria L. Manney, Harald Boenisch, Michaela I. Hegglin, Peter Hoor, Daniel Kunkel, Thierry Leblanc, Irina Petropavlovskikh, Kaley Walker, Krzysztof Wargan, and Andreas Zahn
Atmos. Meas. Tech., 16, 2957–2988, https://doi.org/10.5194/amt-16-2957-2023, https://doi.org/10.5194/amt-16-2957-2023, 2023
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The determination of atmospheric composition trends in the upper troposphere and lower stratosphere (UTLS) is still highly uncertain. We present the creation of dynamical diagnostics to map several ozone datasets (ozonesondes, lidars, aircraft, and satellite measurements) in geophysically based coordinate systems. The diagnostics can also be used to analyze other greenhouse gases relevant to surface climate and UTLS chemistry.
Feijia Yin, Volker Grewe, Federica Castino, Pratik Rao, Sigrun Matthes, Katrin Dahlmann, Simone Dietmüller, Christine Frömming, Hiroshi Yamashita, Patrick Peter, Emma Klingaman, Keith P. Shine, Benjamin Lührs, and Florian Linke
Geosci. Model Dev., 16, 3313–3334, https://doi.org/10.5194/gmd-16-3313-2023, https://doi.org/10.5194/gmd-16-3313-2023, 2023
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This paper describes a newly developed submodel ACCF V1.0 based on the MESSy 2.53.0 infrastructure. The ACCF V1.0 is based on the prototype algorithmic climate change functions (aCCFs) v1.0 to enable climate-optimized flight trajectories. One highlight of this paper is that we describe a consistent full set of aCCFs formulas with respect to fuel scenario and metrics. We demonstrate the usage of the ACCF submodel using AirTraf V2.0 to optimize trajectories for cost and climate impact.
Robin N. Thor, Mariano Mertens, Sigrun Matthes, Mattia Righi, Johannes Hendricks, Sabine Brinkop, Phoebe Graf, Volker Grewe, Patrick Jöckel, and Steven Smith
Geosci. Model Dev., 16, 1459–1466, https://doi.org/10.5194/gmd-16-1459-2023, https://doi.org/10.5194/gmd-16-1459-2023, 2023
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We report on an inconsistency in the latitudinal distribution of aviation emissions between two versions of a data product which is widely used by researchers. From the available documentation, we do not expect such an inconsistency. We run a chemistry–climate model to compute the effect of the inconsistency in emissions on atmospheric chemistry and radiation and find that the radiative forcing associated with aviation ozone is 7.6 % higher when using the less recent version of the data.
Chuan-Yao Lin, Wan-Chin Chen, Yi-Yun Chien, Charles C. K. Chou, Chian-Yi Liu, Helmut Ziereis, Hans Schlager, Eric Förster, Florian Obersteiner, Ovid O. Krüger, Bruna A. Holanda, Mira L. Pöhlker, Katharina Kaiser, Johannes Schneider, Birger Bohn, Klaus Pfeilsticker, Benjamin Weyland, Maria Dolores Andrés Hernández, and John P. Burrows
Atmos. Chem. Phys., 23, 2627–2647, https://doi.org/10.5194/acp-23-2627-2023, https://doi.org/10.5194/acp-23-2627-2023, 2023
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During the EMeRGe campaign in Asia, atmospheric pollutants were measured on board the HALO aircraft. The WRF-Chem model was employed to evaluate the biomass burning (BB) plume transported from Indochina and its impact on the downstream areas. The combination of BB aerosol enhancement with cloud water resulted in a reduction in incoming shortwave radiation at the surface in southern China and the East China Sea, which potentially has significant regional climate implications.
Yun Li, Christoph Mahnke, Susanne Rohs, Ulrich Bundke, Nicole Spelten, Georgios Dekoutsidis, Silke Groß, Christiane Voigt, Ulrich Schumann, Andreas Petzold, and Martina Krämer
Atmos. Chem. Phys., 23, 2251–2271, https://doi.org/10.5194/acp-23-2251-2023, https://doi.org/10.5194/acp-23-2251-2023, 2023
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The radiative effect of aviation-induced cirrus is closely related to ambient conditions and its microphysical properties. Our study investigated the occurrence of contrail and natural cirrus measured above central Europe in spring 2014. It finds that contrail cirrus appears frequently in the pressure range 200 to 245 hPa and occurs more often in slightly ice-subsaturated environments than expected. Avoiding slightly ice-subsaturated regions by aviation might help mitigate contrail cirrus.
Maureen Beaudor, Nicolas Vuichard, Juliette Lathière, Nikolaos Evangeliou, Martin Van Damme, Lieven Clarisse, and Didier Hauglustaine
Geosci. Model Dev., 16, 1053–1081, https://doi.org/10.5194/gmd-16-1053-2023, https://doi.org/10.5194/gmd-16-1053-2023, 2023
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Ammonia mainly comes from the agricultural sector, and its volatilization relies on environmental variables. Our approach aims at benefiting from an Earth system model framework to estimate it. By doing so, we represent a consistent spatial distribution of the emissions' response to environmental changes.
We greatly improved the seasonal cycle of emissions compared with previous work. In addition, our model includes natural soil emissions (that are rarely represented in modeling approaches).
Ziming Wang, Luca Bugliaro, Tina Jurkat-Witschas, Romy Heller, Ulrike Burkhardt, Helmut Ziereis, Georgios Dekoutsidis, Martin Wirth, Silke Groß, Simon Kirschler, Stefan Kaufmann, and Christiane Voigt
Atmos. Chem. Phys., 23, 1941–1961, https://doi.org/10.5194/acp-23-1941-2023, https://doi.org/10.5194/acp-23-1941-2023, 2023
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Differences in the microphysical properties of contrail cirrus and natural cirrus in a contrail outbreak situation during the ML-CIRRUS campaign over the North Atlantic flight corridor can be observed from in situ measurements. The cirrus radiative effect in the area of the outbreak, derived from satellite observation-based radiative transfer modeling, is warming in the early morning and cooling during the day.
Eric Förster, Harald Bönisch, Marco Neumaier, Florian Obersteiner, Andreas Zahn, Andreas Hilboll, Anna B. Kalisz Hedegaard, Nikos Daskalakis, Alexandros Panagiotis Poulidis, Mihalis Vrekoussis, Michael Lichtenstern, and Peter Braesicke
Atmos. Chem. Phys., 23, 1893–1918, https://doi.org/10.5194/acp-23-1893-2023, https://doi.org/10.5194/acp-23-1893-2023, 2023
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The airborne megacity campaign EMeRGe provided an unprecedented amount of trace gas measurements. We combine measured volatile organic compounds (VOCs) with trajectory-modelled emission uptakes to identify potential source regions of pollution. We also characterise the chemical fingerprints (e.g. biomass burning and anthropogenic signatures) of the probed air masses to corroborate the contributing source regions. Our approach is the first large-scale study of VOCs originating from megacities.
Kevin Wolf, Nicolas Bellouin, and Olivier Boucher
Atmos. Chem. Phys., 23, 287–309, https://doi.org/10.5194/acp-23-287-2023, https://doi.org/10.5194/acp-23-287-2023, 2023
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Recent studies estimate the radiative impact of contrails to be similar to or larger than that of emitted CO2; thus, contrail mitigation might be an opportunity to reduce the climate effects of aviation. A radiosonde data set is analyzed in terms of the vertical distribution of potential contrails, contrail mitigation by flight altitude changes, and linkages with the tropopause and jet stream. The effect of prospective jet engine developments and alternative fuels are estimated.
Joël Thanwerdas, Marielle Saunois, Isabelle Pison, Didier Hauglustaine, Antoine Berchet, Bianca Baier, Colm Sweeney, and Philippe Bousquet
Atmos. Chem. Phys., 22, 15489–15508, https://doi.org/10.5194/acp-22-15489-2022, https://doi.org/10.5194/acp-22-15489-2022, 2022
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Atmospheric methane (CH4) concentrations have been rising since 2007, resulting from an imbalance between CH4 sources and sinks. The CH4 budget is generally estimated through top-down approaches using CH4 and δ13C(CH4) observations as constraints. The oxidation by chlorine (Cl) contributes little to the total oxidation of CH4 but strongly influences δ13C(CH4). Here, we compare multiple recent Cl fields and quantify the influence of Cl concentrations on CH4, δ13C(CH4), and CH4 budget estimates.
Laura Tomsche, Andreas Marsing, Tina Jurkat-Witschas, Johannes Lucke, Stefan Kaufmann, Katharina Kaiser, Johannes Schneider, Monika Scheibe, Hans Schlager, Lenard Röder, Horst Fischer, Florian Obersteiner, Andreas Zahn, Martin Zöger, Jos Lelieveld, and Christiane Voigt
Atmos. Chem. Phys., 22, 15135–15151, https://doi.org/10.5194/acp-22-15135-2022, https://doi.org/10.5194/acp-22-15135-2022, 2022
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The detection of sulfur compounds in the upper troposphere (UT) and lower stratosphere (LS) is a challenge. In-flight measurements of SO2 and sulfate aerosol were performed during the BLUESKY mission in spring 2020 under exceptional atmospheric conditions. Reduced sinks in the dry UTLS and lower but still significant air traffic influenced the enhanced SO2 in the UT, and aged volcanic plumes enhanced the LS sulfate aerosol impacting the atmospheric radiation budget and global climate.
Johannes Pletzer, Didier Hauglustaine, Yann Cohen, Patrick Jöckel, and Volker Grewe
Atmos. Chem. Phys., 22, 14323–14354, https://doi.org/10.5194/acp-22-14323-2022, https://doi.org/10.5194/acp-22-14323-2022, 2022
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Very fast aircraft can travel long distances in extremely short times and can fly at high altitudes (15 to 35 km). These aircraft emit water vapour, nitrogen oxides, and hydrogen. Water vapour emissions remain for months to several years at these altitudes and have an important impact on temperature. We investigate two aircraft fleets flying at 26 and 35 km. Ozone is depleted more, and the water vapour perturbation and temperature change are larger for the aircraft flying at 35 km.
Paul Konopka, Mengchu Tao, Marc von Hobe, Lars Hoffmann, Corinna Kloss, Fabrizio Ravegnani, C. Michael Volk, Valentin Lauther, Andreas Zahn, Peter Hoor, and Felix Ploeger
Geosci. Model Dev., 15, 7471–7487, https://doi.org/10.5194/gmd-15-7471-2022, https://doi.org/10.5194/gmd-15-7471-2022, 2022
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Pure trajectory-based transport models driven by meteorology derived from reanalysis products (ERA5) take into account only the resolved, advective part of transport. That means neither mixing processes nor unresolved subgrid-scale advective processes like convection are included. The Chemical Lagrangian Model of the Stratosphere (CLaMS) includes these processes. We show that isentropic mixing dominates unresolved transport. The second most important transport process is unresolved convection.
Etienne Terrenoire, Didier A. Hauglustaine, Yann Cohen, Anne Cozic, Richard Valorso, Franck Lefèvre, and Sigrun Matthes
Atmos. Chem. Phys., 22, 11987–12023, https://doi.org/10.5194/acp-22-11987-2022, https://doi.org/10.5194/acp-22-11987-2022, 2022
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Aviation NOx emissions not only have an impact on global climate by changing ozone and methane levels in the atmosphere, but also contribute to the deterioration of local air quality. The LMDZ-INCA global model is applied to re-evaluate the impact of aircraft NOx and aerosol emissions on climate. We investigate the impact of present-day and future (2050) aircraft emissions on atmospheric composition and the associated radiative forcings of climate for ozone, methane and aerosol direct forcings.
Anthony Rey-Pommier, Frédéric Chevallier, Philippe Ciais, Grégoire Broquet, Theodoros Christoudias, Jonilda Kushta, Didier Hauglustaine, and Jean Sciare
Atmos. Chem. Phys., 22, 11505–11527, https://doi.org/10.5194/acp-22-11505-2022, https://doi.org/10.5194/acp-22-11505-2022, 2022
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Emission inventories for air pollutants can be uncertain in developing countries. In order to overcome these uncertainties, we model nitrogen oxide emissions in Egypt using satellite retrievals. We detect a weekly cycle reflecting Egyptian social norms, an annual cycle consistent with electricity consumption and an activity drop due to the COVID-19 pandemic. However, discrepancies with inventories remain high, illustrating the needs for additional data to improve the potential of our method.
Simon F. Reifenberg, Anna Martin, Matthias Kohl, Sara Bacer, Zaneta Hamryszczak, Ivan Tadic, Lenard Röder, Daniel J. Crowley, Horst Fischer, Katharina Kaiser, Johannes Schneider, Raphael Dörich, John N. Crowley, Laura Tomsche, Andreas Marsing, Christiane Voigt, Andreas Zahn, Christopher Pöhlker, Bruna A. Holanda, Ovid Krüger, Ulrich Pöschl, Mira Pöhlker, Patrick Jöckel, Marcel Dorf, Ulrich Schumann, Jonathan Williams, Birger Bohn, Joachim Curtius, Hardwig Harder, Hans Schlager, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 22, 10901–10917, https://doi.org/10.5194/acp-22-10901-2022, https://doi.org/10.5194/acp-22-10901-2022, 2022
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In this work we use a combination of observational data from an aircraft campaign and model results to investigate the effect of the European lockdown due to COVID-19 in spring 2020. Using model results, we show that the largest relative changes to the atmospheric composition caused by the reduced emissions are located in the upper troposphere around aircraft cruise altitude, while the largest absolute changes are present at the surface.
Anne Sophie Daloz, Clemens Schwingshackl, Priscilla Mooney, Susanna Strada, Diana Rechid, Edouard L. Davin, Eleni Katragkou, Nathalie de Noblet-Ducoudré, Michal Belda, Tomas Halenka, Marcus Breil, Rita M. Cardoso, Peter Hoffmann, Daniela C. A. Lima, Ronny Meier, Pedro M. M. Soares, Giannis Sofiadis, Gustav Strandberg, Merja H. Toelle, and Marianne T. Lund
The Cryosphere, 16, 2403–2419, https://doi.org/10.5194/tc-16-2403-2022, https://doi.org/10.5194/tc-16-2403-2022, 2022
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Snow plays a major role in the regulation of the Earth's surface temperature. Together with climate change, rising temperatures are already altering snow in many ways. In this context, it is crucial to better understand the ability of climate models to represent snow and snow processes. This work focuses on Europe and shows that the melting season in spring still represents a challenge for climate models and that more work is needed to accurately simulate snow–atmosphere interactions.
Klaus Gierens, Lena Wilhelm, Sina Hofer, and Susanne Rohs
Atmos. Chem. Phys., 22, 7699–7712, https://doi.org/10.5194/acp-22-7699-2022, https://doi.org/10.5194/acp-22-7699-2022, 2022
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We are interested in the prediction of condensation trails, in particular strong ones. For this we need a good forecast of temperature and humidity in the levels where aircraft cruise. Unfortunately, the humidity forecast is quite difficult for these levels, in particular the ice supersaturation, which is needed for long-lasting contrails. We are thus seeking proxy variables that help distinguish situations where strong contrails can form, for instance the lapse rate.
Patrick Weber, Andreas Petzold, Oliver F. Bischof, Benedikt Fischer, Marcel Berg, Andrew Freedman, Timothy B. Onasch, and Ulrich Bundke
Atmos. Meas. Tech., 15, 3279–3296, https://doi.org/10.5194/amt-15-3279-2022, https://doi.org/10.5194/amt-15-3279-2022, 2022
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In our laboratory closure study, we measured the full set of aerosol optical properties for different light-absorbing aerosols using a set of instruments.
Our key finding is that the extensive and intensive aerosol optical properties obtained agree with data from reference instruments, except the absorption Ångström exponent of externally mixed aerosols. The reported uncertainty in the single-scattering albedo fulfils the defined goals for Global Climate Observing System applications of 10 %.
Camille Abadie, Fabienne Maignan, Marine Remaud, Jérôme Ogée, J. Elliott Campbell, Mary E. Whelan, Florian Kitz, Felix M. Spielmann, Georg Wohlfahrt, Richard Wehr, Wu Sun, Nina Raoult, Ulli Seibt, Didier Hauglustaine, Sinikka T. Lennartz, Sauveur Belviso, David Montagne, and Philippe Peylin
Biogeosciences, 19, 2427–2463, https://doi.org/10.5194/bg-19-2427-2022, https://doi.org/10.5194/bg-19-2427-2022, 2022
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A better constraint of the components of the carbonyl sulfide (COS) global budget is needed to exploit its potential as a proxy of gross primary productivity. In this study, we compare two representations of oxic soil COS fluxes, and we develop an approach to represent anoxic soil COS fluxes in a land surface model. We show the importance of atmospheric COS concentration variations on oxic soil COS fluxes and provide new estimates for oxic and anoxic soil contributions to the COS global budget.
M. Dolores Andrés Hernández, Andreas Hilboll, Helmut Ziereis, Eric Förster, Ovid O. Krüger, Katharina Kaiser, Johannes Schneider, Francesca Barnaba, Mihalis Vrekoussis, Jörg Schmidt, Heidi Huntrieser, Anne-Marlene Blechschmidt, Midhun George, Vladyslav Nenakhov, Theresa Harlass, Bruna A. Holanda, Jennifer Wolf, Lisa Eirenschmalz, Marc Krebsbach, Mira L. Pöhlker, Anna B. Kalisz Hedegaard, Linlu Mei, Klaus Pfeilsticker, Yangzhuoran Liu, Ralf Koppmann, Hans Schlager, Birger Bohn, Ulrich Schumann, Andreas Richter, Benjamin Schreiner, Daniel Sauer, Robert Baumann, Mariano Mertens, Patrick Jöckel, Markus Kilian, Greta Stratmann, Christopher Pöhlker, Monica Campanelli, Marco Pandolfi, Michael Sicard, José L. Gómez-Amo, Manuel Pujadas, Katja Bigge, Flora Kluge, Anja Schwarz, Nikos Daskalakis, David Walter, Andreas Zahn, Ulrich Pöschl, Harald Bönisch, Stephan Borrmann, Ulrich Platt, and John P. Burrows
Atmos. Chem. Phys., 22, 5877–5924, https://doi.org/10.5194/acp-22-5877-2022, https://doi.org/10.5194/acp-22-5877-2022, 2022
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EMeRGe provides a unique set of in situ and remote sensing airborne measurements of trace gases and aerosol particles along selected flight routes in the lower troposphere over Europe. The interpretation uses also complementary collocated ground-based and satellite measurements. The collected data help to improve the current understanding of the complex spatial distribution of trace gases and aerosol particles resulting from mixing, transport, and transformation of pollution plumes over Europe.
Philip J. Ward, James Daniell, Melanie Duncan, Anna Dunne, Cédric Hananel, Stefan Hochrainer-Stigler, Annegien Tijssen, Silvia Torresan, Roxana Ciurean, Joel C. Gill, Jana Sillmann, Anaïs Couasnon, Elco Koks, Noemi Padrón-Fumero, Sharon Tatman, Marianne Tronstad Lund, Adewole Adesiyun, Jeroen C. J. H. Aerts, Alexander Alabaster, Bernard Bulder, Carlos Campillo Torres, Andrea Critto, Raúl Hernández-Martín, Marta Machado, Jaroslav Mysiak, Rene Orth, Irene Palomino Antolín, Eva-Cristina Petrescu, Markus Reichstein, Timothy Tiggeloven, Anne F. Van Loon, Hung Vuong Pham, and Marleen C. de Ruiter
Nat. Hazards Earth Syst. Sci., 22, 1487–1497, https://doi.org/10.5194/nhess-22-1487-2022, https://doi.org/10.5194/nhess-22-1487-2022, 2022
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The majority of natural-hazard risk research focuses on single hazards (a flood, a drought, a volcanic eruption, an earthquake, etc.). In the international research and policy community it is recognised that risk management could benefit from a more systemic approach. In this perspective paper, we argue for an approach that addresses multi-hazard, multi-risk management through the lens of sustainability challenges that cut across sectors, regions, and hazards.
Priscilla A. Mooney, Diana Rechid, Edouard L. Davin, Eleni Katragkou, Natalie de Noblet-Ducoudré, Marcus Breil, Rita M. Cardoso, Anne Sophie Daloz, Peter Hoffmann, Daniela C. A. Lima, Ronny Meier, Pedro M. M. Soares, Giannis Sofiadis, Susanna Strada, Gustav Strandberg, Merja H. Toelle, and Marianne T. Lund
The Cryosphere, 16, 1383–1397, https://doi.org/10.5194/tc-16-1383-2022, https://doi.org/10.5194/tc-16-1383-2022, 2022
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We use multiple regional climate models to show that afforestation in sub-polar and alpine regions reduces the radiative impact of snow albedo on the atmosphere, reduces snow cover, and delays the start of the snowmelt season. This is important for local communities that are highly reliant on snowpack for water resources and winter tourism. However, models disagree on the amount of change particularly when snow is melting. This shows that more research is needed on snow–vegetation interactions.
Helmut Ziereis, Peter Hoor, Jens-Uwe Grooß, Andreas Zahn, Greta Stratmann, Paul Stock, Michael Lichtenstern, Jens Krause, Vera Bense, Armin Afchine, Christian Rolf, Wolfgang Woiwode, Marleen Braun, Jörn Ungermann, Andreas Marsing, Christiane Voigt, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Chem. Phys., 22, 3631–3654, https://doi.org/10.5194/acp-22-3631-2022, https://doi.org/10.5194/acp-22-3631-2022, 2022
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Airborne observations were conducted in the lowermost Arctic stratosphere during the winter of 2015/2016. The observed distribution of reactive nitrogen shows clear indications of nitrification in mid-winter and denitrification in late winter. This was caused by the formation of polar stratospheric cloud particles, which were observed during several flights. The sedimentation and evaporation of these particles and the descent of air masses cause a redistribution of reactive nitrogen.
Martin J. Osborne, Johannes de Leeuw, Claire Witham, Anja Schmidt, Frances Beckett, Nina Kristiansen, Joelle Buxmann, Cameron Saint, Ellsworth J. Welton, Javier Fochesatto, Ana R. Gomes, Ulrich Bundke, Andreas Petzold, Franco Marenco, and Jim Haywood
Atmos. Chem. Phys., 22, 2975–2997, https://doi.org/10.5194/acp-22-2975-2022, https://doi.org/10.5194/acp-22-2975-2022, 2022
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Using the Met Office NAME dispersion model, supported by satellite- and ground-based remote-sensing observations, we describe the dispersion of aerosols from the 2019 Raikoke eruption and the concurrent wildfires in Alberta Canada. We show how the synergy of dispersion modelling and multiple observation sources allowed observers in the London VAAC to arrive at a more complete picture of the aerosol loading at altitudes commonly used by aviation.
Hannah Clark, Yasmine Bennouna, Maria Tsivlidou, Pawel Wolff, Bastien Sauvage, Brice Barret, Eric Le Flochmoën, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, Andreas Petzold, and Valérie Thouret
Atmos. Chem. Phys., 21, 16237–16256, https://doi.org/10.5194/acp-21-16237-2021, https://doi.org/10.5194/acp-21-16237-2021, 2021
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We examined 27 years of IAGOS (In-service Aircraft for a Global Observing System) profiles at Frankfurt to see if there were unusual features during the spring of 2020 related to COVID-19 lockdowns in Europe. Increased ozone near the surface was partly linked to the reduction in emissions. Carbon monoxide decreased near the surface, but the impact of the lockdowns was offset by polluted air masses from elsewhere. There were small reductions in ozone and carbon monoxide in the free troposphere.
Gaëlle Dufour, Didier Hauglustaine, Yunjiang Zhang, Maxim Eremenko, Yann Cohen, Audrey Gaudel, Guillaume Siour, Mathieu Lachatre, Axel Bense, Bertrand Bessagnet, Juan Cuesta, Jerry Ziemke, Valérie Thouret, and Bo Zheng
Atmos. Chem. Phys., 21, 16001–16025, https://doi.org/10.5194/acp-21-16001-2021, https://doi.org/10.5194/acp-21-16001-2021, 2021
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The IASI observations and the LMDZ-OR-INCA model simulations show negative ozone trends in the Central East China region in the lower free (3–6 km column) and the upper free (6–9 km column) troposphere. Sensitivity studies from the model show that the Chinese anthropogenic emissions contribute to more than 50 % in the trend. The reduction in NOx emissions that has occurred since 2013 in China seems to lead to a decrease in ozone in the free troposphere, contrary to the increase at the surface.
Maria Sand, Bjørn H. Samset, Gunnar Myhre, Jonas Gliß, Susanne E. Bauer, Huisheng Bian, Mian Chin, Ramiro Checa-Garcia, Paul Ginoux, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Philippe Le Sager, Marianne T. Lund, Hitoshi Matsui, Twan van Noije, Dirk J. L. Olivié, Samuel Remy, Michael Schulz, Philip Stier, Camilla W. Stjern, Toshihiko Takemura, Kostas Tsigaridis, Svetlana G. Tsyro, and Duncan Watson-Parris
Atmos. Chem. Phys., 21, 15929–15947, https://doi.org/10.5194/acp-21-15929-2021, https://doi.org/10.5194/acp-21-15929-2021, 2021
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Absorption of shortwave radiation by aerosols can modify precipitation and clouds but is poorly constrained in models. A total of 15 different aerosol models from AeroCom phase III have reported total aerosol absorption, and for the first time, 11 of these models have reported in a consistent experiment the contributions to absorption from black carbon, dust, and organic aerosol. Here, we document the model diversity in aerosol absorption.
Yu-Wen Chen, Yi-Chun Chen, Charles C.-K. Chou, Hui-Ming Hung, Shih-Yu Chang, Lisa Eirenschmalz, Michael Lichtenstern, Helmut Ziereis, Hans Schlager, Greta Stratmann, Katharina Kaiser, Johannes Schneider, Stephan Borrmann, Florian Obersteiner, Eric Förster, Andreas Zahn, Wei-Nai Chen, Po-Hsiung Lin, Shuenn-Chin Chang, Maria Dolores Andrés Hernández, Pao-Kuan Wang, and John P. Burrows
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2021-788, https://doi.org/10.5194/acp-2021-788, 2021
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By presenting an approach using EMeRGe-Asia airborne field measurements and surface observations, this study shows that the fraction of OH reactivity due to SO2-OH reaction has a significant correlation with the sulfate concentration. Approximately 30 % of sulfate is produced by SO2-OH reaction. Our results underline the importance of SO2-OH gas-phase oxidation in sulfate formation, and demonstrate that the method can be applied to other regions and under different meteorological conditions.
Meike K. Rotermund, Vera Bense, Martyn P. Chipperfield, Andreas Engel, Jens-Uwe Grooß, Peter Hoor, Tilman Hüneke, Timo Keber, Flora Kluge, Benjamin Schreiner, Tanja Schuck, Bärbel Vogel, Andreas Zahn, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 15375–15407, https://doi.org/10.5194/acp-21-15375-2021, https://doi.org/10.5194/acp-21-15375-2021, 2021
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Airborne total bromine (Brtot) and tracer measurements suggest Brtot-rich air masses persistently protruded into the lower stratosphere (LS), creating a high Brtot region over the North Atlantic in fall 2017. The main source is via isentropic transport by the Asian monsoon and to a lesser extent transport across the extratropical tropopause as quantified by a Lagrange model. The transport of Brtot via Central American hurricanes is also observed. Lastly, the impact of Brtot on LS O3 is assessed.
Liang Guo, Laura J. Wilcox, Massimo Bollasina, Steven T. Turnock, Marianne T. Lund, and Lixia Zhang
Atmos. Chem. Phys., 21, 15299–15308, https://doi.org/10.5194/acp-21-15299-2021, https://doi.org/10.5194/acp-21-15299-2021, 2021
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Severe haze remains serious over Beijing despite emissions decreasing since 2008. Future haze changes in four scenarios are studied. The pattern conducive to haze weather increases with the atmospheric warming caused by the accumulation of greenhouse gases. However, the actual haze intensity, measured by either PM2.5 or optical depth, decreases with aerosol emissions. We show that only using the weather pattern index to predict the future change of Beijing haze is insufficient.
Victor Lannuque, Bastien Sauvage, Brice Barret, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Pierre Cammas, Jean-Marc Cousin, Alain Fontaine, Eric Le Flochmoën, Philippe Nédélec, Hervé Petetin, Isabelle Pfaffenzeller, Susanne Rohs, Herman G. J. Smit, Pawel Wolff, and Valérie Thouret
Atmos. Chem. Phys., 21, 14535–14555, https://doi.org/10.5194/acp-21-14535-2021, https://doi.org/10.5194/acp-21-14535-2021, 2021
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The African intertropical troposphere is one of the world areas where the increase in ozone mixing ratio has been most pronounced since 1980 and where high carbon monoxide mixing ratios are found in altitude. In this article, IAGOS aircraft measurements, IASI satellite instrument observations, and SOFT-IO model products are used to explore the seasonal distribution variations and the origin of ozone and carbon monoxide over the African upper troposphere.
Roeland Van Malderen, Dirk De Muer, Hugo De Backer, Deniz Poyraz, Willem W. Verstraeten, Veerle De Bock, Andy W. Delcloo, Alexander Mangold, Quentin Laffineur, Marc Allaart, Frans Fierens, and Valérie Thouret
Atmos. Chem. Phys., 21, 12385–12411, https://doi.org/10.5194/acp-21-12385-2021, https://doi.org/10.5194/acp-21-12385-2021, 2021
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The main aim of initiating measurements of the vertical distribution of the ozone concentration by means of ozonesondes attached to weather balloons at Uccle in 1969 was to improve weather forecasts. Since then, this measurement technique has barely changed, but the dense, long-term, and homogeneous Uccle dataset currently remains crucial for studying the temporal evolution of ozone from the surface to the stratosphere and is also the backbone of the validation of satellite ozone retrievals.
Lukas Krasauskas, Jörn Ungermann, Peter Preusse, Felix Friedl-Vallon, Andreas Zahn, Helmut Ziereis, Christian Rolf, Felix Plöger, Paul Konopka, Bärbel Vogel, and Martin Riese
Atmos. Chem. Phys., 21, 10249–10272, https://doi.org/10.5194/acp-21-10249-2021, https://doi.org/10.5194/acp-21-10249-2021, 2021
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A Rossby wave (RW) breaking event was observed over the North Atlantic during the WISE measurement campaign in October 2017. Infrared limb sounding measurements of trace gases in the lower stratosphere, including high-resolution 3-D tomographic reconstruction, revealed complex spatial structures in stratospheric tracers near the polar jet related to previous RW breaking events. Backward-trajectory analysis and tracer correlations were used to study mixing and stratosphere–troposphere exchange.
Ryan M. Bright and Marianne T. Lund
Atmos. Chem. Phys., 21, 9887–9907, https://doi.org/10.5194/acp-21-9887-2021, https://doi.org/10.5194/acp-21-9887-2021, 2021
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Humans affect the reflective properties (albedo) of Earth's surface and the amount of solar energy that it absorbs, in turn affecting climate. In recent years, a variety of climate metrics have been applied to characterize albedo perturbations in terms of their
CO2-equivalenteffects, despite the lack of scientific consensus surrounding the methods behind them. We review these metrics, evaluate their (de)merits, provide guidance for future application, and suggest avenues for future research.
Christine Frömming, Volker Grewe, Sabine Brinkop, Patrick Jöckel, Amund S. Haslerud, Simon Rosanka, Jesper van Manen, and Sigrun Matthes
Atmos. Chem. Phys., 21, 9151–9172, https://doi.org/10.5194/acp-21-9151-2021, https://doi.org/10.5194/acp-21-9151-2021, 2021
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The influence of weather situations on non-CO2 aviation climate impact is investigated to identify systematic weather-related sensitivities. If aircraft avoid the most sensitive areas, climate impact might be reduced. Enhanced significance is found for emission in relation to high-pressure systems, jet stream, polar night, and tropopause altitude. The results represent a comprehensive data set for studies aiming at weather-dependent flight trajectory optimization to reduce total climate impact.
Na Zhao, Xinyi Dong, Kan Huang, Joshua S. Fu, Marianne Tronstad Lund, Kengo Sudo, Daven Henze, Tom Kucsera, Yun Fat Lam, Mian Chin, and Simone Tilmes
Atmos. Chem. Phys., 21, 8637–8654, https://doi.org/10.5194/acp-21-8637-2021, https://doi.org/10.5194/acp-21-8637-2021, 2021
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Black carbon acts as a strong climate forcer, especially in vulnerable pristine regions such as the Arctic. This work utilizes ensemble modeling results from the task force Hemispheric Transport of Air Pollution Phase 2 to investigate the responses of Arctic black carbon and surface temperature to various source emission reductions. East Asia contributed the most to Arctic black carbon. The response of Arctic temperature to black carbon was substantially more sensitive than the global average.
Romain Blot, Philippe Nedelec, Damien Boulanger, Pawel Wolff, Bastien Sauvage, Jean-Marc Cousin, Gilles Athier, Andreas Zahn, Florian Obersteiner, Dieter Scharffe, Hervé Petetin, Yasmine Bennouna, Hannah Clark, and Valérie Thouret
Atmos. Meas. Tech., 14, 3935–3951, https://doi.org/10.5194/amt-14-3935-2021, https://doi.org/10.5194/amt-14-3935-2021, 2021
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A lack of information about temporal changes in measurement uncertainties is an area of concern for long-term trend studies of the key compounds which have a direct or indirect impact on climate change. The IAGOS program has measured O3 and CO within the troposphere and lower stratosphere for more than 25 years. In this study, we demonstrated that the IAGOS database can be treated as one continuous program and is therefore appropriate for studies of long-term trends.
Yann Cohen, Virginie Marécal, Béatrice Josse, and Valérie Thouret
Geosci. Model Dev., 14, 2659–2689, https://doi.org/10.5194/gmd-14-2659-2021, https://doi.org/10.5194/gmd-14-2659-2021, 2021
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Assessing long-term chemistry–climate simulations with in situ and frequent observations near the tropopause is possible with the IAGOS commercial aircraft data set. This study presents a method that distributes the IAGOS data (ozone and CO) on a monthly model grid, limiting the impact of resolution for the evaluation of the modelled chemical fields. We applied it to the CCMI REF-C1SD simulation from the MOCAGE CTM and notably highlighted well-reproduced O3 behaviour in the lower stratosphere.
Nikolaos Evangeliou, Yves Balkanski, Sabine Eckhardt, Anne Cozic, Martin Van Damme, Pierre-François Coheur, Lieven Clarisse, Mark W. Shephard, Karen E. Cady-Pereira, and Didier Hauglustaine
Atmos. Chem. Phys., 21, 4431–4451, https://doi.org/10.5194/acp-21-4431-2021, https://doi.org/10.5194/acp-21-4431-2021, 2021
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Ammonia, a substance that has played a key role in sustaining life, has been increasing in the atmosphere, affecting climate and humans. Understanding the reasons for this increase is important for the beneficial use of ammonia. The evolution of satellite products gives us the opportunity to calculate ammonia emissions easier. We calculated global ammonia emissions over the last 10 years, incorporated them into a chemistry model and recorded notable improvement in reproducing observations.
Julia Perim de Faria, Ulrich Bundke, Andrew Freedman, Timothy B. Onasch, and Andreas Petzold
Atmos. Meas. Tech., 14, 1635–1653, https://doi.org/10.5194/amt-14-1635-2021, https://doi.org/10.5194/amt-14-1635-2021, 2021
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An evaluation of the performance and accuracy of a Cavity Attenuated Phase-Shift Single Scattering Albedo Monitor (CAPS PMSSA; Aerodyne Research, Inc.) was conducted in an optical-closure study with proven technologies for aerosol particle optical-property measurements. This study demonstrates that the CAPS PMSSA is a robust and reliable instrument for the direct measurement of the particle scattering and extinction coefficients and thus single-scattering albedo.
Johannes Schneider, Ralf Weigel, Thomas Klimach, Antonis Dragoneas, Oliver Appel, Andreas Hünig, Sergej Molleker, Franziska Köllner, Hans-Christian Clemen, Oliver Eppers, Peter Hoppe, Peter Hoor, Christoph Mahnke, Martina Krämer, Christian Rolf, Jens-Uwe Grooß, Andreas Zahn, Florian Obersteiner, Fabrizio Ravegnani, Alexey Ulanovsky, Hans Schlager, Monika Scheibe, Glenn S. Diskin, Joshua P. DiGangi, John B. Nowak, Martin Zöger, and Stephan Borrmann
Atmos. Chem. Phys., 21, 989–1013, https://doi.org/10.5194/acp-21-989-2021, https://doi.org/10.5194/acp-21-989-2021, 2021
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During five aircraft missions, we detected aerosol particles containing meteoric material in the lower stratosphere. The stratospheric measurements span a latitude range from 15 to 68° N, and we find that at potential temperature levels of more than 40 K above the tropopause; particles containing meteoric material occur at similar abundance fractions across latitudes and seasons. We conclude that meteoric material is efficiently distributed between high and low latitudes by isentropic mixing.
Jonas Gliß, Augustin Mortier, Michael Schulz, Elisabeth Andrews, Yves Balkanski, Susanne E. Bauer, Anna M. K. Benedictow, Huisheng Bian, Ramiro Checa-Garcia, Mian Chin, Paul Ginoux, Jan J. Griesfeller, Andreas Heckel, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Paolo Laj, Philippe Le Sager, Marianne Tronstad Lund, Cathrine Lund Myhre, Hitoshi Matsui, Gunnar Myhre, David Neubauer, Twan van Noije, Peter North, Dirk J. L. Olivié, Samuel Rémy, Larisa Sogacheva, Toshihiko Takemura, Kostas Tsigaridis, and Svetlana G. Tsyro
Atmos. Chem. Phys., 21, 87–128, https://doi.org/10.5194/acp-21-87-2021, https://doi.org/10.5194/acp-21-87-2021, 2021
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Simulated aerosol optical properties as well as the aerosol life cycle are investigated for 14 global models participating in the AeroCom initiative. Considerable diversity is found in the simulated aerosol species emissions and lifetimes, also resulting in a large diversity in the simulated aerosol mass, composition, and optical properties. A comparison with observations suggests that, on average, current models underestimate the direct effect of aerosol on the atmosphere radiation budget.
Marianne T. Lund, Borgar Aamaas, Camilla W. Stjern, Zbigniew Klimont, Terje K. Berntsen, and Bjørn H. Samset
Earth Syst. Dynam., 11, 977–993, https://doi.org/10.5194/esd-11-977-2020, https://doi.org/10.5194/esd-11-977-2020, 2020
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Achieving the Paris Agreement temperature goals requires both near-zero levels of long-lived greenhouse gases and deep cuts in emissions of short-lived climate forcers (SLCFs). Here we quantify the near- and long-term global temperature impacts of emissions of individual SLCFs and CO2 from 7 economic sectors in 13 regions in order to provide the detailed knowledge needed to design efficient mitigation strategies at the sectoral and regional levels.
Bettina Hottmann, Sascha Hafermann, Laura Tomsche, Daniel Marno, Monica Martinez, Hartwig Harder, Andrea Pozzer, Marco Neumaier, Andreas Zahn, Birger Bohn, Greta Stratmann, Helmut Ziereis, Jos Lelieveld, and Horst Fischer
Atmos. Chem. Phys., 20, 12655–12673, https://doi.org/10.5194/acp-20-12655-2020, https://doi.org/10.5194/acp-20-12655-2020, 2020
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During OMO we observed enhanced mixing ratios of hydroperoxides (ROOH) in the Asian monsoon anticyclone (AMA) relative to the background. The observed mixing ratios are higher than steady-state calculations and EMAC simulations, especially in the AMA, indicating atmospheric transport of ROOH. Uncertainties in the scavenging efficiencies likely cause deviations from EMAC. Longitudinal gradients indicate a pool of ROOH towards the center of the AMA associated with upwind convection over India.
Laura J. Wilcox, Zhen Liu, Bjørn H. Samset, Ed Hawkins, Marianne T. Lund, Kalle Nordling, Sabine Undorf, Massimo Bollasina, Annica M. L. Ekman, Srinath Krishnan, Joonas Merikanto, and Andrew G. Turner
Atmos. Chem. Phys., 20, 11955–11977, https://doi.org/10.5194/acp-20-11955-2020, https://doi.org/10.5194/acp-20-11955-2020, 2020
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Projected changes in man-made aerosol range from large reductions to moderate increases in emissions until 2050. Rapid reductions between the present and the 2050s lead to enhanced increases in global and Asian summer monsoon precipitation relative to scenarios with continued increases in aerosol. Relative magnitude and spatial distribution of aerosol changes are particularly important for South Asian summer monsoon precipitation changes, affecting the sign of the trend in the coming decades.
Hiroshi Yamashita, Feijia Yin, Volker Grewe, Patrick Jöckel, Sigrun Matthes, Bastian Kern, Katrin Dahlmann, and Christine Frömming
Geosci. Model Dev., 13, 4869–4890, https://doi.org/10.5194/gmd-13-4869-2020, https://doi.org/10.5194/gmd-13-4869-2020, 2020
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This paper describes the updated submodel AirTraf 2.0 which simulates global air traffic in the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. Nine aircraft routing options have been integrated, including contrail avoidance, minimum economic costs, and minimum climate impact. Example simulations reveal characteristics of different routing options on air traffic performances. The consistency of the AirTraf simulations is verified with literature data.
Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Kenneth C. Aikin, Teresa Campos, Hannah Clark, Róisín Commane, Bruce Daube, Glenn W. Diskin, James W. Elkins, Ru-Shan Gao, Audrey Gaudel, Eric J. Hintsa, Bryan J. Johnson, Rigel Kivi, Kathryn McKain, Fred L. Moore, David D. Parrish, Richard Querel, Eric Ray, Ricardo Sánchez, Colm Sweeney, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Jacquelyn C. Witte, Steve C. Wofsy, and Thomas B. Ryerson
Atmos. Chem. Phys., 20, 10611–10635, https://doi.org/10.5194/acp-20-10611-2020, https://doi.org/10.5194/acp-20-10611-2020, 2020
María A. Burgos, Elisabeth Andrews, Gloria Titos, Angela Benedetti, Huisheng Bian, Virginie Buchard, Gabriele Curci, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Anton Laakso, Julie Letertre-Danczak, Marianne T. Lund, Hitoshi Matsui, Gunnar Myhre, Cynthia Randles, Michael Schulz, Twan van Noije, Kai Zhang, Lucas Alados-Arboledas, Urs Baltensperger, Anne Jefferson, James Sherman, Junying Sun, Ernest Weingartner, and Paul Zieger
Atmos. Chem. Phys., 20, 10231–10258, https://doi.org/10.5194/acp-20-10231-2020, https://doi.org/10.5194/acp-20-10231-2020, 2020
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We investigate how well models represent the enhancement in scattering coefficients due to particle water uptake, and perform an evaluation of several implementation schemes used in ten Earth system models. Our results show the importance of the parameterization of hygroscopicity and model chemistry as drivers of some of the observed diversity amongst model estimates. The definition of dry conditions and the phenomena taking place in this relative humidity range also impact the model evaluation.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, and Valérie Thouret
Atmos. Chem. Phys., 20, 9915–9938, https://doi.org/10.5194/acp-20-9915-2020, https://doi.org/10.5194/acp-20-9915-2020, 2020
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We provide a statistical framework for detecting trends of multiple autocorrelated time series from sparsely sampled profile data. The result is a better and more consistent quantification of trend estimates of vertical profile data. The focus was placed on the long-term ozone time series from commercial aircraft and balloon-borne ozonesonde measurements. This framework can be applied to other trace gases in the atmosphere.
Martin Cussac, Virginie Marécal, Valérie Thouret, Béatrice Josse, and Bastien Sauvage
Atmos. Chem. Phys., 20, 9393–9417, https://doi.org/10.5194/acp-20-9393-2020, https://doi.org/10.5194/acp-20-9393-2020, 2020
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Biomass burning emissions are a major source of carbon monoxide in the atmosphere. Here, the vertical transport that these emissions can undergo until the upper troposphere is investigated, as well as their contribution to carbon monoxide concentrations. It was found that boreal forest emissions were specific to the occurrence of pyroconvection directly above the fires, whereas biomass burning emissions from other regions of the globe relied more on the occurrence of deep convection.
Gunnar Myhre, Bjørn H. Samset, Christian W. Mohr, Kari Alterskjær, Yves Balkanski, Nicolas Bellouin, Mian Chin, James Haywood, Øivind Hodnebrog, Stefan Kinne, Guangxing Lin, Marianne T. Lund, Joyce E. Penner, Michael Schulz, Nick Schutgens, Ragnhild B. Skeie, Philip Stier, Toshihiko Takemura, and Kai Zhang
Atmos. Chem. Phys., 20, 8855–8865, https://doi.org/10.5194/acp-20-8855-2020, https://doi.org/10.5194/acp-20-8855-2020, 2020
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The radiative forcing of the direct aerosol effects can be decomposed into clear-sky and cloudy-sky portions. In this study we use observational methods and two sets of multi-model global aerosol simulations over the industrial era to show that the contribution from cloudy-sky regions is likely weak.
Andreas Petzold, Patrick Neis, Mihal Rütimann, Susanne Rohs, Florian Berkes, Herman G. J. Smit, Martina Krämer, Nicole Spelten, Peter Spichtinger, Philippe Nédélec, and Andreas Wahner
Atmos. Chem. Phys., 20, 8157–8179, https://doi.org/10.5194/acp-20-8157-2020, https://doi.org/10.5194/acp-20-8157-2020, 2020
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The first analysis of 15 years of global-scale water vapour and relative humidity observations by passenger aircraft in the MOZAIC and IAGOS programmes resolves detailed features of water vapour and ice-supersaturated air in the mid-latitude tropopause. Key results provide in-depth insight into seasonal and regional variability and chemical signatures of ice-supersaturated air masses, including trend analyses, and show a close link to cirrus clouds and their highly important effects on climate.
Pierre Sepulchre, Arnaud Caubel, Jean-Baptiste Ladant, Laurent Bopp, Olivier Boucher, Pascale Braconnot, Patrick Brockmann, Anne Cozic, Yannick Donnadieu, Jean-Louis Dufresne, Victor Estella-Perez, Christian Ethé, Frédéric Fluteau, Marie-Alice Foujols, Guillaume Gastineau, Josefine Ghattas, Didier Hauglustaine, Frédéric Hourdin, Masa Kageyama, Myriam Khodri, Olivier Marti, Yann Meurdesoif, Juliette Mignot, Anta-Clarisse Sarr, Jérôme Servonnat, Didier Swingedouw, Sophie Szopa, and Delphine Tardif
Geosci. Model Dev., 13, 3011–3053, https://doi.org/10.5194/gmd-13-3011-2020, https://doi.org/10.5194/gmd-13-3011-2020, 2020
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Our paper describes IPSL-CM5A2, an Earth system model that can be integrated for long (several thousands of years) climate simulations. We describe the technical aspects, assess the model computing performance and evaluate the strengths and weaknesses of the model, by comparing pre-industrial and historical runs to the previous-generation model simulations and to observations. We also present a Cretaceous simulation as a case study to show how the model simulates deep-time paleoclimates.
Peter H. Zimmermann, Carl A. M. Brenninkmeijer, Andrea Pozzer, Patrick Jöckel, Franziska Winterstein, Andreas Zahn, Sander Houweling, and Jos Lelieveld
Atmos. Chem. Phys., 20, 5787–5809, https://doi.org/10.5194/acp-20-5787-2020, https://doi.org/10.5194/acp-20-5787-2020, 2020
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The atmospheric abundance of the greenhouse gas methane is determined by interacting emission sources and sinks in a dynamic global environment. In this study, its global budget from 1997 to 2016 is simulated with a general circulation model using emission estimates of 11 source categories. The model results are evaluated against 17 ground station and 320 intercontinental flight observation series. Deviations are used to re-scale the emission quantities with the aim of matching observations.
Bruna A. Holanda, Mira L. Pöhlker, David Walter, Jorge Saturno, Matthias Sörgel, Jeannine Ditas, Florian Ditas, Christiane Schulz, Marco Aurélio Franco, Qiaoqiao Wang, Tobias Donth, Paulo Artaxo, Henrique M. J. Barbosa, Stephan Borrmann, Ramon Braga, Joel Brito, Yafang Cheng, Maximilian Dollner, Johannes W. Kaiser, Thomas Klimach, Christoph Knote, Ovid O. Krüger, Daniel Fütterer, Jošt V. Lavrič, Nan Ma, Luiz A. T. Machado, Jing Ming, Fernando G. Morais, Hauke Paulsen, Daniel Sauer, Hans Schlager, Johannes Schneider, Hang Su, Bernadett Weinzierl, Adrian Walser, Manfred Wendisch, Helmut Ziereis, Martin Zöger, Ulrich Pöschl, Meinrat O. Andreae, and Christopher Pöhlker
Atmos. Chem. Phys., 20, 4757–4785, https://doi.org/10.5194/acp-20-4757-2020, https://doi.org/10.5194/acp-20-4757-2020, 2020
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Biomass burning smoke from African savanna and grassland is transported across the South Atlantic Ocean in defined layers within the free troposphere. The combination of in situ aircraft and ground-based measurements aided by satellite observations showed that these layers are transported into the Amazon Basin during the early dry season. The influx of aged smoke, enriched in black carbon and cloud condensation nuclei, has important implications for the Amazonian aerosol and cloud cycling.
Frank Roux, Hannah Clark, Kuo-Ying Wang, Susanne Rohs, Bastien Sauvage, and Philippe Nédélec
Atmos. Chem. Phys., 20, 3945–3963, https://doi.org/10.5194/acp-20-3945-2020, https://doi.org/10.5194/acp-20-3945-2020, 2020
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Ozone, carbon monoxide and relative humidity were measured by two China Airlines aircraft equipped with IAGOS instruments during the summer of 2016. We examined landing and take-off profiles near Taipei (Taiwan), in the vicinity of three typhoons, in relation to ERA-5 meteorological reanalyses. Upstream of the storms, these data suggest that air is transported downwards from the stratosphere. Downstream, the troposphere is cleaner and moister due to the uplift of marine boundary layer air.
Philipp Reutter, Patrick Neis, Susanne Rohs, and Bastien Sauvage
Atmos. Chem. Phys., 20, 787–804, https://doi.org/10.5194/acp-20-787-2020, https://doi.org/10.5194/acp-20-787-2020, 2020
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This study compares in situ measurements of temperature and humidity in the upper troposphere and lower stratosphere with reanalysis data from the ECMWF ERA-Interim data set. It is shown that temperature compares well between both data sets. However, extreme values of relative humidity with respect to ice (RHi) are missing in ERA-Interim, and hence the number and size of ice supersaturated regions differ strongly between both data sets.
Tanja J. Schuck, Ann-Katrin Blank, Elisa Rittmeier, Jonathan Williams, Carl A. M. Brenninkmeijer, Andreas Engel, and Andreas Zahn
Atmos. Meas. Tech., 13, 73–84, https://doi.org/10.5194/amt-13-73-2020, https://doi.org/10.5194/amt-13-73-2020, 2020
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Air sample collection aboard aircraft is a tool to measure atmospheric trace gas mixing ratios at altitude. We present results on the stability of 28 halocarbons during storage of air samples collected in stainless-steel flasks inside an automated air sampling unit which is part of the CARIBIC instrument package. Selected fluorinated compounds grew during the experiments while short-lived compounds were depleted. Individual substances were additionally influenced by high mixing ratios of ozone.
Marianne T. Lund, Gunnar Myhre, and Bjørn H. Samset
Atmos. Chem. Phys., 19, 13827–13839, https://doi.org/10.5194/acp-19-13827-2019, https://doi.org/10.5194/acp-19-13827-2019, 2019
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Atmospheric aerosols play an integral role in shaping local and global climate by modifying the energy balance, clouds and precipitation. They are also a leading cause of premature mortality in many areas. New scenarios provide projections of emissions until 2100 given strong, medium or weak air pollution control stringency. We quantify the consequent regional and global aerosol loading and radiative forcing, showing a large spread at the end of the century and regional differences in trends.
Marleen Braun, Jens-Uwe Grooß, Wolfgang Woiwode, Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Hermann Oelhaf, Peter Preusse, Jörn Ungermann, Björn-Martin Sinnhuber, Helmut Ziereis, and Peter Braesicke
Atmos. Chem. Phys., 19, 13681–13699, https://doi.org/10.5194/acp-19-13681-2019, https://doi.org/10.5194/acp-19-13681-2019, 2019
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We analyse nitrification of the LMS in the Arctic winter 2015–2016 based on GLORIA measurements. Vertical cross sections of HNO3 for several flights show complex fine–scale structures and enhanced values down to 9 km. The extent of overall nitrification is quantified based on HNO3–O3 correlations and reaches between 5 ppbv and 7 ppbv at potential temperature levels between 350 and 380 K. Further, we compare our result with the atmospheric model CLaMS.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, Didier Hauglustaine, Michel Ramonet, Cyril Crevoisier, Bianca Baier, Colm Sweeney, and Philippe Bousquet
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-925, https://doi.org/10.5194/acp-2019-925, 2019
Revised manuscript not accepted
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Oxidation by the hydroxyl radical (OH) is the dominant atmospheric sink for methane, contributing to approximately 90 % of the total methane loss. Chemical losses by reaction with atomic oxygen (O1D) and chlorine radicals (Cl) in the stratosphere are other sinks, contributing about 3 % to the total methane destruction. We assess here the impact of atomic Cl on atmospheric methane mixing ratios, methane atmospheric loss and atmospheric isotopic δ13C-CH4 values.
Johannes Eckstein, Roland Ruhnke, Stephan Pfahl, Emanuel Christner, Christopher Diekmann, Christoph Dyroff, Daniel Reinert, Daniel Rieger, Matthias Schneider, Jennifer Schröter, Andreas Zahn, and Peter Braesicke
Geosci. Model Dev., 11, 5113–5133, https://doi.org/10.5194/gmd-11-5113-2018, https://doi.org/10.5194/gmd-11-5113-2018, 2018
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We present ICON-ART-Iso, an extension to the global circulation model ICON, which allows for the simulation of the stable isotopologues of water. The main advantage over other isotope-enabled models is its flexible design with respect to the number of tracers simulated. We compare the results of several simulations to measurements of different scale. ICON-ART-Iso is able to reasonably reproduce the measurements. It is a promising tool to aid in the investigation of the atmospheric water cycle.
Marianne Tronstad Lund, Gunnar Myhre, Amund Søvde Haslerud, Ragnhild Bieltvedt Skeie, Jan Griesfeller, Stephen Matthew Platt, Rajesh Kumar, Cathrine Lund Myhre, and Michael Schulz
Geosci. Model Dev., 11, 4909–4931, https://doi.org/10.5194/gmd-11-4909-2018, https://doi.org/10.5194/gmd-11-4909-2018, 2018
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Atmospheric aerosols play a key role in the climate system, but their exact impact on the energy balance remains uncertain. Accurate representation of the geographical distribution and properties of aerosols in global models is key to reduce this uncertainty. Here we use a new emission inventory and a range of observations to carefully validate a state-of-the-art model and present an updated estimate of the net direct effect of anthropogenic aerosols since the preindustrial era.
Hervé Petetin, Bastien Sauvage, Mark Parrington, Hannah Clark, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, Philippe Nédélec, and Valérie Thouret
Atmos. Chem. Phys., 18, 17277–17306, https://doi.org/10.5194/acp-18-17277-2018, https://doi.org/10.5194/acp-18-17277-2018, 2018
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This study derives a climatology of the impact of biomass burning versus anthropogenic emissions on the strongest CO plumes observed in the troposphere based on a dataset of about 30 000 in situ vertical profiles, combined with Lagrangian simulations coupled to CO emission. Results demonstrate the large contribution of biomass burning to the strongest CO plumes encountered in the troposphere in many locations of the world.
Christiane Schulz, Johannes Schneider, Bruna Amorim Holanda, Oliver Appel, Anja Costa, Suzane S. de Sá, Volker Dreiling, Daniel Fütterer, Tina Jurkat-Witschas, Thomas Klimach, Christoph Knote, Martina Krämer, Scot T. Martin, Stephan Mertes, Mira L. Pöhlker, Daniel Sauer, Christiane Voigt, Adrian Walser, Bernadett Weinzierl, Helmut Ziereis, Martin Zöger, Meinrat O. Andreae, Paulo Artaxo, Luiz A. T. Machado, Ulrich Pöschl, Manfred Wendisch, and Stephan Borrmann
Atmos. Chem. Phys., 18, 14979–15001, https://doi.org/10.5194/acp-18-14979-2018, https://doi.org/10.5194/acp-18-14979-2018, 2018
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Aerosol chemical composition measurements in the tropical upper troposphere over the Amazon region show that 78 % of the aerosol in the upper troposphere consists of organic matter. Up to 20 % of the organic aerosol can be attributed to isoprene epoxydiol secondary organic aerosol (IEPOX-SOA). Furthermore, organic nitrates were identified, suggesting a connection to the IEPOX-SOA formation.
Jan Eiof Jonson, Michael Schulz, Louisa Emmons, Johannes Flemming, Daven Henze, Kengo Sudo, Marianne Tronstad Lund, Meiyun Lin, Anna Benedictow, Brigitte Koffi, Frank Dentener, Terry Keating, Rigel Kivi, and Yanko Davila
Atmos. Chem. Phys., 18, 13655–13672, https://doi.org/10.5194/acp-18-13655-2018, https://doi.org/10.5194/acp-18-13655-2018, 2018
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Focusing on Europe, this HTAP 2 study computes ozone in several global models when reducing anthropogenic emissions by 20 % in different world regions. The differences in model results are explored
by use of a novel stepwise approach combining a tracer, CO and ozone. For ozone the contributions from the rest of the world are larger than from Europe, with the largest contributions from North America and eastern Asia. Contributions do, however, depend on the choice of ozone metric.
Franz Slemr, Andreas Weigelt, Ralf Ebinghaus, Johannes Bieser, Carl A. M. Brenninkmeijer, Armin Rauthe-Schöch, Markus Hermann, Bengt G. Martinsson, Peter van Velthoven, Harald Bönisch, Marco Neumaier, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 18, 12329–12343, https://doi.org/10.5194/acp-18-12329-2018, https://doi.org/10.5194/acp-18-12329-2018, 2018
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Total and elemental mercury were measured in the upper troposphere and lower stratosphere onboard a passenger aircraft. Their concentrations in the upper troposphere were comparable implying low concentrations of oxidized mercury in this region. Large scale seasonally dependent influence of emissions from biomass burning was also observed. Their distributions in the lower stratosphere implies a long stratospheric lifetime, which precludes significant mercury oxidation by ozone.
Sören Johansson, Wolfgang Woiwode, Michael Höpfner, Felix Friedl-Vallon, Anne Kleinert, Erik Kretschmer, Thomas Latzko, Johannes Orphal, Peter Preusse, Jörn Ungermann, Michelle L. Santee, Tina Jurkat-Witschas, Andreas Marsing, Christiane Voigt, Andreas Giez, Martina Krämer, Christian Rolf, Andreas Zahn, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Meas. Tech., 11, 4737–4756, https://doi.org/10.5194/amt-11-4737-2018, https://doi.org/10.5194/amt-11-4737-2018, 2018
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We present two-dimensional cross sections of temperature, HNO3, O3, ClONO2, H2O and CFC-12 from measurements of the GLORIA infrared limb imager during the POLSTRACC/GW-LCYCLE/SALSA aircraft campaigns in the Arctic winter 2015/2016. GLORIA sounded the atmosphere between 5 and 14 km with vertical resolutions of 0.4–1 km. Estimated errors are in the range of 1–2 K (temperature) and 10 %–20 % (trace gases). Comparisons to in situ instruments onboard the aircraft and to Aura/MLS are shown.
Ciao-Kai Liang, J. Jason West, Raquel A. Silva, Huisheng Bian, Mian Chin, Yanko Davila, Frank J. Dentener, Louisa Emmons, Johannes Flemming, Gerd Folberth, Daven Henze, Ulas Im, Jan Eiof Jonson, Terry J. Keating, Tom Kucsera, Allen Lenzen, Meiyun Lin, Marianne Tronstad Lund, Xiaohua Pan, Rokjin J. Park, R. Bradley Pierce, Takashi Sekiya, Kengo Sudo, and Toshihiko Takemura
Atmos. Chem. Phys., 18, 10497–10520, https://doi.org/10.5194/acp-18-10497-2018, https://doi.org/10.5194/acp-18-10497-2018, 2018
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Emissions from one continent affect air quality and health elsewhere. Here we quantify the effects of intercontinental PM2.5 and ozone transport on human health using a new multi-model ensemble, evaluating the health effects of emissions from six world regions and three emission source sectors. Emissions from one region have significant health impacts outside of that source region; similarly, foreign emissions contribute significantly to air-pollution-related deaths in several world regions.
Hervé Petetin, Bastien Sauvage, Herman G. J. Smit, François Gheusi, Fabienne Lohou, Romain Blot, Hannah Clark, Gilles Athier, Damien Boulanger, Jean-Marc Cousin, Philippe Nedelec, Patrick Neis, Susanne Rohs, and Valérie Thouret
Atmos. Chem. Phys., 18, 9561–9581, https://doi.org/10.5194/acp-18-9561-2018, https://doi.org/10.5194/acp-18-9561-2018, 2018
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Based on the numerous profiles available since 1994, this paper investigates the vertical stratification of ozone, carbon monoxide and relative humidity in the lower part of the troposphere (planetary boundary layer, lower free troposphere). Such a characterization of the vertical distribution of pollution is notably important for better understanding vertical exchanges and evaluating models on the vertical dimension.
Fabio Boschetti, Valerie Thouret, Greet Janssens Maenhout, Kai Uwe Totsche, Julia Marshall, and Christoph Gerbig
Atmos. Chem. Phys., 18, 9225–9241, https://doi.org/10.5194/acp-18-9225-2018, https://doi.org/10.5194/acp-18-9225-2018, 2018
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Retrieving surface–atmosphere fluxes from the combination of atmospheric observations with atmospheric transport models can benefit from combining multiple species in a single inversion. The underlying effect is that species such as CO2 and CO have partially overlapping emission patterns for given sectors and fuel types and so share part of the uncertainties, both related to the a priori knowledge of emissions, and to model–data mismatch error. We show this for airborne profile data from IAGOS.
Steven T. Turnock, Oliver Wild, Frank J. Dentener, Yanko Davila, Louisa K. Emmons, Johannes Flemming, Gerd A. Folberth, Daven K. Henze, Jan E. Jonson, Terry J. Keating, Sudo Kengo, Meiyun Lin, Marianne Lund, Simone Tilmes, and Fiona M. O'Connor
Atmos. Chem. Phys., 18, 8953–8978, https://doi.org/10.5194/acp-18-8953-2018, https://doi.org/10.5194/acp-18-8953-2018, 2018
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A simple parameterisation was developed in this study to provide a rapid assessment of the impacts and uncertainties associated with future emission control strategies by predicting changes to surface ozone air quality and near-term climate forcing of ozone. Future emissions scenarios based on currently implemented legislation are shown to worsen surface ozone air quality and enhance near-term climate warming, with changes in methane becoming increasingly important in the future.
Florian Berkes, Norbert Houben, Ulrich Bundke, Harald Franke, Hans-Werner Pätz, Franz Rohrer, Andreas Wahner, and Andreas Petzold
Atmos. Meas. Tech., 11, 3737–3757, https://doi.org/10.5194/amt-11-3737-2018, https://doi.org/10.5194/amt-11-3737-2018, 2018
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The need for in situ nitrogen oxide measurements on a global scale is crucial to improve the chemistry in global chemistry models and evaluate satellite retrievals. Here we present the characterization of the new IAGOS NOx instrument installed on passenger aircraft, which will provide statistical robust measurements from the surface up to 13 km.
Klaus-Dirk Gottschaldt, Hans Schlager, Robert Baumann, Duy Sinh Cai, Veronika Eyring, Phoebe Graf, Volker Grewe, Patrick Jöckel, Tina Jurkat-Witschas, Christiane Voigt, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 18, 5655–5675, https://doi.org/10.5194/acp-18-5655-2018, https://doi.org/10.5194/acp-18-5655-2018, 2018
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This study places aircraft trace gas measurements from within the Asian summer monsoon anticyclone into the context of regional, intra- and interannual variability. We find that the processes reflected in the measurements are present throughout multiple simulated monsoon seasons. Dynamical instabilities, photochemical ozone production, lightning and entrainments from the lower troposphere and from the tropopause region determine the distinct composition of the anticyclone and its outflow.
Yann Cohen, Hervé Petetin, Valérie Thouret, Virginie Marécal, Béatrice Josse, Hannah Clark, Bastien Sauvage, Alain Fontaine, Gilles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 18, 5415–5453, https://doi.org/10.5194/acp-18-5415-2018, https://doi.org/10.5194/acp-18-5415-2018, 2018
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Measurements of ozone and carbon monoxide were performed during 1994–2013 around the tropopause on board commercial aircraft. Seasonal cycles and trends were calculated above eight well-sampled regions in Northern Hemisphere midlatitudes. CO shows decreasing concentrations over the last 10 years, thus reflecting the impact of the legislation on anthropogenic emissions. Ozone amounts increased over the 20 years in the upper troposphere during different seasons, depending on the longitudes.
Meinrat O. Andreae, Armin Afchine, Rachel Albrecht, Bruna Amorim Holanda, Paulo Artaxo, Henrique M. J. Barbosa, Stephan Borrmann, Micael A. Cecchini, Anja Costa, Maximilian Dollner, Daniel Fütterer, Emma Järvinen, Tina Jurkat, Thomas Klimach, Tobias Konemann, Christoph Knote, Martina Krämer, Trismono Krisna, Luiz A. T. Machado, Stephan Mertes, Andreas Minikin, Christopher Pöhlker, Mira L. Pöhlker, Ulrich Pöschl, Daniel Rosenfeld, Daniel Sauer, Hans Schlager, Martin Schnaiter, Johannes Schneider, Christiane Schulz, Antonio Spanu, Vinicius B. Sperling, Christiane Voigt, Adrian Walser, Jian Wang, Bernadett Weinzierl, Manfred Wendisch, and Helmut Ziereis
Atmos. Chem. Phys., 18, 921–961, https://doi.org/10.5194/acp-18-921-2018, https://doi.org/10.5194/acp-18-921-2018, 2018
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We made airborne measurements of aerosol particle concentrations and properties over the Amazon Basin. We found extremely high concentrations of very small particles in the region between 8 and 14 km altitude all across the basin, which had been recently formed by gas-to-particle conversion at these altitudes. This makes the upper troposphere a very important source region of atmospheric particles with significant implications for the Earth's climate system.
Tilman Hüneke, Oliver-Alex Aderhold, Jannik Bounin, Marcel Dorf, Eric Gentry, Katja Grossmann, Jens-Uwe Grooß, Peter Hoor, Patrick Jöckel, Mareike Kenntner, Marvin Knapp, Matthias Knecht, Dominique Lörks, Sabrina Ludmann, Sigrun Matthes, Rasmus Raecke, Marcel Reichert, Jannis Weimar, Bodo Werner, Andreas Zahn, Helmut Ziereis, and Klaus Pfeilsticker
Atmos. Meas. Tech., 10, 4209–4234, https://doi.org/10.5194/amt-10-4209-2017, https://doi.org/10.5194/amt-10-4209-2017, 2017
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This paper describes a novel instrument for the aircraft-borne remote sensing of trace gases and liquid and solid water. Until recently, such measurements could only be evaluated under clear-sky conditions. We present a characterization and error assessment of the novel "scaling method", which allows for the retrieval of absolute trace gas concentrations under all sky conditions, significantly expanding the applicability of such measurements to study atmospheric photochemistry.
Huisheng Bian, Mian Chin, Didier A. Hauglustaine, Michael Schulz, Gunnar Myhre, Susanne E. Bauer, Marianne T. Lund, Vlassis A. Karydis, Tom L. Kucsera, Xiaohua Pan, Andrea Pozzer, Ragnhild B. Skeie, Stephen D. Steenrod, Kengo Sudo, Kostas Tsigaridis, Alexandra P. Tsimpidi, and Svetlana G. Tsyro
Atmos. Chem. Phys., 17, 12911–12940, https://doi.org/10.5194/acp-17-12911-2017, https://doi.org/10.5194/acp-17-12911-2017, 2017
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Atmospheric nitrate contributes notably to total aerosol mass in the present day and is likely to be more important over the next century, with a projected decline in SO2 and NOx emissions and increase in NH3 emissions. This paper investigates atmospheric nitrate using multiple global models and measurements. The study is part of the AeroCom phase III activity. The study is the first attempt to look at global atmospheric nitrate simulation at physical and chemical process levels.
Florian Berkes, Patrick Neis, Martin G. Schultz, Ulrich Bundke, Susanne Rohs, Herman G. J. Smit, Andreas Wahner, Paul Konopka, Damien Boulanger, Philippe Nédélec, Valerie Thouret, and Andreas Petzold
Atmos. Chem. Phys., 17, 12495–12508, https://doi.org/10.5194/acp-17-12495-2017, https://doi.org/10.5194/acp-17-12495-2017, 2017
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This study highlights the importance of independent global measurements with high and long-term accuracy to quantify long-term changes, especially in the UTLS region, and to help identify inconsistencies between different data sets of observations and models. Here we investigated temperature trends over different regions within a climate-sensitive area of the atmosphere and demonstrated the value of the IAGOS temperature observations as an anchor point for the evaluation of reanalyses.
Bengt G. Martinsson, Johan Friberg, Oscar S. Sandvik, Markus Hermann, Peter F. J. van Velthoven, and Andreas Zahn
Atmos. Chem. Phys., 17, 10937–10953, https://doi.org/10.5194/acp-17-10937-2017, https://doi.org/10.5194/acp-17-10937-2017, 2017
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We find that the aerosol of the lowermost stratosphere has a considerable climate forcing. The upper tropospheric (UT) particulate sulfur is strongly influenced by stratospheric sources the first half of the year, whereas tropospheric sources dominate in fall; 50 % of the UT particulate sulfur (S) was found to be stratospheric at background condition, and 70 % under moderate influence from volcanism. The Asian monsoon is found to be an important tropospheric source of S in the NH extratropical UT.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, Pawan K. Bhartia, Zhaonan Cai, Marc Allaart, Gérard Ancellet, Bertrand Calpini, Gerrie J. R. Coetzee, Emilio Cuevas-Agulló, Manuel Cupeiro, Hugo De Backer, Manvendra K. Dubey, Henry E. Fuelberg, Masatomo Fujiwara, Sophie Godin-Beekmann, Tristan J. Hall, Bryan Johnson, Everette Joseph, Rigel Kivi, Bogumil Kois, Ninong Komala, Gert König-Langlo, Giovanni Laneve, Thierry Leblanc, Marion Marchand, Kenneth R. Minschwaner, Gary Morris, Michael J. Newchurch, Shin-Ya Ogino, Nozomu Ohkawara, Ankie J. M. Piters, Françoise Posny, Richard Querel, Rinus Scheele, Frank J. Schmidlin, Russell C. Schnell, Otto Schrems, Henry Selkirk, Masato Shiotani, Pavla Skrivánková, René Stübi, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Matthew B. Tully, Roeland Van Malderen, Holger Vömel, Peter von der Gathen, Jacquelyn C. Witte, and Margarita Yela
Atmos. Meas. Tech., 10, 2455–2475, https://doi.org/10.5194/amt-10-2455-2017, https://doi.org/10.5194/amt-10-2455-2017, 2017
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It is essential to understand the data quality of +10-year OMI ozone product and impacts of the “row anomaly” (RA). We validate the OMI Ozone Profile (PROFOZ) product from Oct 2004 to Dec 2014 against ozonesonde observations globally. Generally, OMI has good agreement with ozonesondes. The spatiotemporal variation of retrieval performance suggests the need to improve OMI’s radiometric calibration especially during the post-RA period to maintain the long-term stability.
Marianne T. Lund, Borgar Aamaas, Terje Berntsen, Lisa Bock, Ulrike Burkhardt, Jan S. Fuglestvedt, and Keith P. Shine
Earth Syst. Dynam., 8, 547–563, https://doi.org/10.5194/esd-8-547-2017, https://doi.org/10.5194/esd-8-547-2017, 2017
Johannes Bieser, Franz Slemr, Jesse Ambrose, Carl Brenninkmeijer, Steve Brooks, Ashu Dastoor, Francesco DeSimone, Ralf Ebinghaus, Christian N. Gencarelli, Beate Geyer, Lynne E. Gratz, Ian M. Hedgecock, Daniel Jaffe, Paul Kelley, Che-Jen Lin, Lyatt Jaegle, Volker Matthias, Andrei Ryjkov, Noelle E. Selin, Shaojie Song, Oleg Travnikov, Andreas Weigelt, Winston Luke, Xinrong Ren, Andreas Zahn, Xin Yang, Yun Zhu, and Nicola Pirrone
Atmos. Chem. Phys., 17, 6925–6955, https://doi.org/10.5194/acp-17-6925-2017, https://doi.org/10.5194/acp-17-6925-2017, 2017
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We conducted a multi model study to investigate our ability to reproduce the vertical distribution of mercury in the atmosphere. For this, we used observational data from over 40 aircraft flights in EU and US. We compared observations to the results of seven chemistry transport models and found that the models are able to reproduce vertical gradients of total and elemental Hg. Finally, we found that different chemical reactions seem responsible for the oxidation of Hg depending on altitude.
Marianne T. Lund, Terje K. Berntsen, and Bjørn H. Samset
Atmos. Chem. Phys., 17, 6003–6022, https://doi.org/10.5194/acp-17-6003-2017, https://doi.org/10.5194/acp-17-6003-2017, 2017
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This study investigates possibilities for improving the representation of black carbon (BC) distribution in a global atmospheric chemistry-transport model by exploring uncertainties in key processes controlling the removal of aerosols from the atmosphere. Our results provide an increased understanding of the processes contributing to uncertainties in the BC abundance and climate impact and underline the importance of more observations and experimental data further constrain models.
Klaus-D. Gottschaldt, Hans Schlager, Robert Baumann, Heiko Bozem, Veronika Eyring, Peter Hoor, Patrick Jöckel, Tina Jurkat, Christiane Voigt, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 17, 6091–6111, https://doi.org/10.5194/acp-17-6091-2017, https://doi.org/10.5194/acp-17-6091-2017, 2017
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We present upper-tropospheric trace gas measurements in the Asian summer monsoon anticyclone, obtained with the HALO research aircraft in September 2012. The anticyclone is one of the largest atmospheric features on Earth, but many aspects of it are not well understood. With the help of model simulations we find that entrainments from the tropopause region and the lower troposphere, combined with photochemistry and dynamical instabilities, can explain the observations.
Liang Feng, Paul I. Palmer, Hartmut Bösch, Robert J. Parker, Alex J. Webb, Caio S. C. Correia, Nicholas M. Deutscher, Lucas G. Domingues, Dietrich G. Feist, Luciana V. Gatti, Emanuel Gloor, Frank Hase, Rigel Kivi, Yi Liu, John B. Miller, Isamu Morino, Ralf Sussmann, Kimberly Strong, Osamu Uchino, Jing Wang, and Andreas Zahn
Atmos. Chem. Phys., 17, 4781–4797, https://doi.org/10.5194/acp-17-4781-2017, https://doi.org/10.5194/acp-17-4781-2017, 2017
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We use the GEOS-Chem global 3-D model of atmospheric chemistry and transport and an ensemble Kalman filter to simultaneously infer regional fluxes of methane (CH4) and carbon dioxide (CO2) directly from GOSAT retrievals of XCH4:XCO2, using sparse ground-based CH4 and CO2 mole fraction data to anchor the ratio. Our results show that assimilation of GOSAT data significantly reduced the posterior uncertainty and changed the a priori spatial distribution of CH4 emissions.
Johannes Eckstein, Roland Ruhnke, Andreas Zahn, Marco Neumaier, Ole Kirner, and Peter Braesicke
Atmos. Chem. Phys., 17, 2775–2794, https://doi.org/10.5194/acp-17-2775-2017, https://doi.org/10.5194/acp-17-2775-2017, 2017
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Data on atmospheric trace gases have been collected with instruments on-board a commercial airliner for more than 10 years in the CARIBIC project. We investigate which species in the dataset can be used for a representative climatology, by comparing data from the chemistry–climate model EMAC along the flight paths to a larger set of model data. We find that long-lived species are captured quite well by the CARIBIC sample while this is not the case for more variable, shorter-lived species.
Gunnar Myhre, Wenche Aas, Ribu Cherian, William Collins, Greg Faluvegi, Mark Flanner, Piers Forster, Øivind Hodnebrog, Zbigniew Klimont, Marianne T. Lund, Johannes Mülmenstädt, Cathrine Lund Myhre, Dirk Olivié, Michael Prather, Johannes Quaas, Bjørn H. Samset, Jordan L. Schnell, Michael Schulz, Drew Shindell, Ragnhild B. Skeie, Toshihiko Takemura, and Svetlana Tsyro
Atmos. Chem. Phys., 17, 2709–2720, https://doi.org/10.5194/acp-17-2709-2017, https://doi.org/10.5194/acp-17-2709-2017, 2017
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Over the past decades, the geographical distribution of emissions of substances that alter the atmospheric energy balance has changed due to economic growth and pollution regulations. Here, we show the resulting changes to aerosol and ozone abundances and their radiative forcing using recently updated emission data for the period 1990–2015, as simulated by seven global atmospheric composition models. The global mean radiative forcing is more strongly positive than reported in IPCC AR5.
Garlich Fischbeck, Harald Bönisch, Marco Neumaier, Carl A. M. Brenninkmeijer, Johannes Orphal, Joel Brito, Julia Becker, Detlev Sprung, Peter F. J. van Velthoven, and Andreas Zahn
Atmos. Chem. Phys., 17, 1985–2008, https://doi.org/10.5194/acp-17-1985-2017, https://doi.org/10.5194/acp-17-1985-2017, 2017
Thomas Gasser, Philippe Ciais, Olivier Boucher, Yann Quilcaille, Maxime Tortora, Laurent Bopp, and Didier Hauglustaine
Geosci. Model Dev., 10, 271–319, https://doi.org/10.5194/gmd-10-271-2017, https://doi.org/10.5194/gmd-10-271-2017, 2017
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Simple models of the Earth system are useful, especially because of their high computing efficiency. This work describes the OSCAR model: a new simple Earth system model calibrated on state-of-the-art complex models. It will add to the pool of the few simple models currently used by the community, and it will therefore improve the robustness of future studies. Its source code is available upon request.
Bärbel Vogel, Gebhard Günther, Rolf Müller, Jens-Uwe Grooß, Armin Afchine, Heiko Bozem, Peter Hoor, Martina Krämer, Stefan Müller, Martin Riese, Christian Rolf, Nicole Spelten, Gabriele P. Stiller, Jörn Ungermann, and Andreas Zahn
Atmos. Chem. Phys., 16, 15301–15325, https://doi.org/10.5194/acp-16-15301-2016, https://doi.org/10.5194/acp-16-15301-2016, 2016
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The identification of transport pathways from the Asian monsoon anticyclone into the lower stratosphere is unclear. Global simulations with the CLaMS model demonstrate that source regions in Asia and in the Pacific Ocean have a significant impact on the chemical composition of the lower stratosphere of the Northern Hemisphere by flooding the extratropical lower stratosphere with young moist air masses. Two main horizontal transport pathways from the Asian monsoon anticyclone are identified.
Hervé Petetin, Valérie Thouret, Alain Fontaine, Bastien Sauvage, Giles Athier, Romain Blot, Damien Boulanger, Jean-Marc Cousin, and Philippe Nédélec
Atmos. Chem. Phys., 16, 15147–15163, https://doi.org/10.5194/acp-16-15147-2016, https://doi.org/10.5194/acp-16-15147-2016, 2016
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Ozone (O3) and carbon monoxide (CO) are two compounds of major importance in the atmosphere. In this paper we investigated their variability and trends at Frankfurt based on the MOZAIC–IAGOS dataset, a unique dataset of about 21 300 vertical profiles recorded by commercial aircraft. The CO concentrations have been decreasing since 2002, while no strong tendency is observed for O3 since 1994. However, the O3 seasonal variations are changing, with the spring maximum occurring earlier and earlier.
Palmira Messina, Juliette Lathière, Katerina Sindelarova, Nicolas Vuichard, Claire Granier, Josefine Ghattas, Anne Cozic, and Didier A. Hauglustaine
Atmos. Chem. Phys., 16, 14169–14202, https://doi.org/10.5194/acp-16-14169-2016, https://doi.org/10.5194/acp-16-14169-2016, 2016
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We provide BVOC emissions for the present scenario, employing the updated ORCHIDEE emission module and the MEGAN model. The modelling community still faces the problem of emission model evaluation because of the absence of adequate observations. The accurate analysis performed, employing the two models, allowed the various processes modelled to be investigated, in order to fully understand the origin of the mismatch between the model estimates and to quantify the emission uncertainties.
Camilla Weum Stjern, Bjørn Hallvard Samset, Gunnar Myhre, Huisheng Bian, Mian Chin, Yanko Davila, Frank Dentener, Louisa Emmons, Johannes Flemming, Amund Søvde Haslerud, Daven Henze, Jan Eiof Jonson, Tom Kucsera, Marianne Tronstad Lund, Michael Schulz, Kengo Sudo, Toshihiko Takemura, and Simone Tilmes
Atmos. Chem. Phys., 16, 13579–13599, https://doi.org/10.5194/acp-16-13579-2016, https://doi.org/10.5194/acp-16-13579-2016, 2016
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Air pollution can reach distant regions through intercontinental transport. Here we first present results from the Hemispheric Transport of Air Pollution Phase 2 exercise, where many models performed the same set of coordinated emission-reduction experiments. We find that mitigations have considerable extra-regional effects, and show that this is particularly true for black carbon emissions, as long-range transport elevates aerosols to higher levels where their radiative influence is stronger.
Ralf Weigel, Peter Spichtinger, Christoph Mahnke, Marcus Klingebiel, Armin Afchine, Andreas Petzold, Martina Krämer, Anja Costa, Sergej Molleker, Philipp Reutter, Miklós Szakáll, Max Port, Lucas Grulich, Tina Jurkat, Andreas Minikin, and Stephan Borrmann
Atmos. Meas. Tech., 9, 5135–5162, https://doi.org/10.5194/amt-9-5135-2016, https://doi.org/10.5194/amt-9-5135-2016, 2016
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The subject of our study concerns measurements with optical array probes (OAPs) on fast-flying aircraft such as the G550 (HALO or HIAPER). At up to Mach 0.7 the effect of air compression upstream of underwing-mounted instruments and particles' inertia need consideration for determining ambient particle concentrations. Compared to conventional practices the introduced correction procedure eliminates ambiguities and exhibits consistency over flight speeds between 50 and 250 m s−.
B. Quennehen, J.-C. Raut, K. S. Law, N. Daskalakis, G. Ancellet, C. Clerbaux, S.-W. Kim, M. T. Lund, G. Myhre, D. J. L. Olivié, S. Safieddine, R. B. Skeie, J. L. Thomas, S. Tsyro, A. Bazureau, N. Bellouin, M. Hu, M. Kanakidou, Z. Klimont, K. Kupiainen, S. Myriokefalitakis, J. Quaas, S. T. Rumbold, M. Schulz, R. Cherian, A. Shimizu, J. Wang, S.-C. Yoon, and T. Zhu
Atmos. Chem. Phys., 16, 10765–10792, https://doi.org/10.5194/acp-16-10765-2016, https://doi.org/10.5194/acp-16-10765-2016, 2016
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This paper evaluates the ability of six global models and one regional model in reproducing short-lived pollutants (defined here as ozone and its precursors, aerosols and black carbon) concentrations over Asia using satellite, ground-based and airborne observations.
Key findings are that models homogeneously reproduce the trace gas observations although nitrous oxides are underestimated, whereas the aerosol distributions are heterogeneously reproduced, implicating important uncertainties.
Stefan Müller, Peter Hoor, Heiko Bozem, Ellen Gute, Bärbel Vogel, Andreas Zahn, Harald Bönisch, Timo Keber, Martina Krämer, Christian Rolf, Martin Riese, Hans Schlager, and Andreas Engel
Atmos. Chem. Phys., 16, 10573–10589, https://doi.org/10.5194/acp-16-10573-2016, https://doi.org/10.5194/acp-16-10573-2016, 2016
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In situ airborne measurements performed during TACTS/ESMVal 2012 were analysed to investigate the chemical compostion of the upper troposphere and lower stratosphere. N2O, CO and O3 data show an increase in tropospherically affected air masses within the extratropical stratosphere from August to September 2012, which originate from the Asian monsoon region. Thus, the Asian monsoon anticyclone significantly affected the chemical composition of the extratropical stratosphere during summer 2012.
Jinfeng Chang, Philippe Ciais, Mario Herrero, Petr Havlik, Matteo Campioli, Xianzhou Zhang, Yongfei Bai, Nicolas Viovy, Joanna Joiner, Xuhui Wang, Shushi Peng, Chao Yue, Shilong Piao, Tao Wang, Didier A. Hauglustaine, Jean-Francois Soussana, Anna Peregon, Natalya Kosykh, and Nina Mironycheva-Tokareva
Biogeosciences, 13, 3757–3776, https://doi.org/10.5194/bg-13-3757-2016, https://doi.org/10.5194/bg-13-3757-2016, 2016
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We derived the global maps of grassland management intensity of 1901–2012, including the minimum area of managed grassland with fraction of mown/grazed part. These maps, to our knowledge for the first time, provide global, time-dependent information for drawing up global estimates of management impact on biomass production and yields and for global vegetation models to enable simulations of carbon stocks and GHG budgets beyond simple tuning of grassland productivities to account for management.
Franz Slemr, Andreas Weigelt, Ralf Ebinghaus, Hans H. Kock, Jan Bödewadt, Carl A. M. Brenninkmeijer, Armin Rauthe-Schöch, Stefan Weber, Markus Hermann, Julia Becker, Andreas Zahn, and Bengt Martinsson
Atmos. Meas. Tech., 9, 2291–2302, https://doi.org/10.5194/amt-9-2291-2016, https://doi.org/10.5194/amt-9-2291-2016, 2016
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The goal of CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrumented Container) is to carry out regular and detailed observations of atmospheric chemistry at 9–12 km altitude. Mercury has been measured since May 2005 during intercontinental flights between Europe and South and North America, Africa, and Asia. Here we describe the instrument modifications, the post-flight processing of the raw instrument signal, and the fractionation experiments.
Markus Hermann, Andreas Weigelt, Denise Assmann, Sascha Pfeifer, Thomas Müller, Thomas Conrath, Jens Voigtländer, Jost Heintzenberg, Alfred Wiedensohler, Bengt G. Martinsson, Terry Deshler, Carl A. M. Brenninkmeijer, and Andreas Zahn
Atmos. Meas. Tech., 9, 2179–2194, https://doi.org/10.5194/amt-9-2179-2016, https://doi.org/10.5194/amt-9-2179-2016, 2016
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Aerosol particles are an important component of the Earth's atmosphere. Here we describe the composition and characterization of a new optical particle size spectrometer (OPSS) for aircraft-borne measurements of the aerosol particle size distribution (how many particles there are with a certain size) in the 140–1050 nm size range. The OPSS was characterized throughout concerning its measurement capabilities (response, pressure dependence, coincidence) and validated versus balloon measurement.
Tina Jurkat, Stefan Kaufmann, Christiane Voigt, Dominik Schäuble, Philipp Jeßberger, and Helmut Ziereis
Atmos. Meas. Tech., 9, 1907–1923, https://doi.org/10.5194/amt-9-1907-2016, https://doi.org/10.5194/amt-9-1907-2016, 2016
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The paper details novel mass spectrometric measurements with AIMS-TG aboard the new German research aircraft HALO. The measurements comprise a wide range of tracers with characteristic source regions. Using these tracers, stratospheric and tropospheric air in the UTLS is tagged. The instrument is equipped with a new discharge ionization source, an in-flight calibration and improved transmission of adhesive gases like HNO3 and HCl. AIMS was built to characterize transport and mixing in the UTLS.
Patrick Jöckel, Holger Tost, Andrea Pozzer, Markus Kunze, Oliver Kirner, Carl A. M. Brenninkmeijer, Sabine Brinkop, Duy S. Cai, Christoph Dyroff, Johannes Eckstein, Franziska Frank, Hella Garny, Klaus-Dirk Gottschaldt, Phoebe Graf, Volker Grewe, Astrid Kerkweg, Bastian Kern, Sigrun Matthes, Mariano Mertens, Stefanie Meul, Marco Neumaier, Matthias Nützel, Sophie Oberländer-Hayn, Roland Ruhnke, Theresa Runde, Rolf Sander, Dieter Scharffe, and Andreas Zahn
Geosci. Model Dev., 9, 1153–1200, https://doi.org/10.5194/gmd-9-1153-2016, https://doi.org/10.5194/gmd-9-1153-2016, 2016
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With an advanced numerical global chemistry climate model (CCM) we performed several detailed
combined hind-cast and projection simulations of the period 1950 to 2100 to assess the
past, present, and potential future dynamical and chemical state of the Earth atmosphere.
The manuscript documents the model and the various applied model set-ups and provides
a first evaluation of the simulation results from a global perspective as a quality check of the data.
Andreas Weigelt, Ralf Ebinghaus, Nicola Pirrone, Johannes Bieser, Jan Bödewadt, Giulio Esposito, Franz Slemr, Peter F. J. van Velthoven, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 16, 4135–4146, https://doi.org/10.5194/acp-16-4135-2016, https://doi.org/10.5194/acp-16-4135-2016, 2016
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We show the first mercury profile measurements over Europe since 1996. Besides gaseous elemental mercury (GEM) and total gaseous mercury (TGM), the gases CO, SO2, NOx, and O3 were measured from aboard a research aircraft over four European locations. Compared to the boundary layer, the concentration of GEM and TGM in the free troposphere was 10–30% lower. Inside the individual layers no vertical gradient was apparent. Combined with CARIBIC data, a unique profile from 0.4 to 10.5 km is provided.
Armin Rauthe-Schöch, Angela K. Baker, Tanja J. Schuck, Carl A. M. Brenninkmeijer, Andreas Zahn, Markus Hermann, Greta Stratmann, Helmut Ziereis, Peter F. J. van Velthoven, and Jos Lelieveld
Atmos. Chem. Phys., 16, 3609–3629, https://doi.org/10.5194/acp-16-3609-2016, https://doi.org/10.5194/acp-16-3609-2016, 2016
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The flying laboratory CARIBIC onboard a passenger aircraft measured trace gases and aerosol particles in the upper tropospheric Indian summer monsoon anticyclone in summer 2008. We used the measurements together with meteorological analyses to investigate the chemical signature of the northern and southern part of the monsoon, the source regions from where the air was entrained into the monsoon and which parts of the world received polluted air that had been chemically processed in the monsoon.
A. Stohl, B. Aamaas, M. Amann, L. H. Baker, N. Bellouin, T. K. Berntsen, O. Boucher, R. Cherian, W. Collins, N. Daskalakis, M. Dusinska, S. Eckhardt, J. S. Fuglestvedt, M. Harju, C. Heyes, Ø. Hodnebrog, J. Hao, U. Im, M. Kanakidou, Z. Klimont, K. Kupiainen, K. S. Law, M. T. Lund, R. Maas, C. R. MacIntosh, G. Myhre, S. Myriokefalitakis, D. Olivié, J. Quaas, B. Quennehen, J.-C. Raut, S. T. Rumbold, B. H. Samset, M. Schulz, Ø. Seland, K. P. Shine, R. B. Skeie, S. Wang, K. E. Yttri, and T. Zhu
Atmos. Chem. Phys., 15, 10529–10566, https://doi.org/10.5194/acp-15-10529-2015, https://doi.org/10.5194/acp-15-10529-2015, 2015
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This paper presents a summary of the findings of the ECLIPSE EU project. The project has investigated the climate and air quality impacts of short-lived climate pollutants (especially methane, ozone, aerosols) and has designed a global mitigation strategy that maximizes co-benefits between air quality and climate policy. Transient climate model simulations allowed quantifying the impacts on temperature (e.g., reduction in global warming by 0.22K for the decade 2041-2050) and precipitation.
J. G. Levine, A. R. MacKenzie, O. J. Squire, A. T. Archibald, P. T. Griffiths, N. L. Abraham, J. A. Pyle, D. E. Oram, G. Forster, J. F. Brito, J. D. Lee, J. R. Hopkins, A. C. Lewis, S. J. B. Bauguitte, C. F. Demarco, P. Artaxo, P. Messina, J. Lathière, D. A. Hauglustaine, E. House, C. N. Hewitt, and E. Nemitz
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-24251-2015, https://doi.org/10.5194/acpd-15-24251-2015, 2015
Revised manuscript has not been submitted
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This study explores our ability to simulate atmospheric chemistry stemming from isoprene emissions—a reactive gas emitted from vegetation—in pristine and polluted regions of the Amazon basin. We explore how two contrasting models fare in reproducing recent airborne measurements in the region. Their differing treatments of transport and mixing are found to: profoundly affect their performance; and yield very different pictures of the exposure of the rainforest to harmful ozone concentrations.
C. Rolf, A. Afchine, H. Bozem, B. Buchholz, V. Ebert, T. Guggenmoser, P. Hoor, P. Konopka, E. Kretschmer, S. Müller, H. Schlager, N. Spelten, O. Sumińska-Ebersoldt, J. Ungermann, A. Zahn, and M. Krämer
Atmos. Chem. Phys., 15, 9143–9158, https://doi.org/10.5194/acp-15-9143-2015, https://doi.org/10.5194/acp-15-9143-2015, 2015
W. Tao, J. Liu, G. A. Ban-Weiss, D. A. Hauglustaine, L. Zhang, Q. Zhang, Y. Cheng, Y. Yu, and S. Tao
Atmos. Chem. Phys., 15, 8597–8614, https://doi.org/10.5194/acp-15-8597-2015, https://doi.org/10.5194/acp-15-8597-2015, 2015
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We examine the responses of a range of meteorological and air quality indicators to the expansion of urban land using WRF/Chem. Sensitivity studies indicate that the responses of pollutant concentrations to the spatial extent of urbanization are linear near the surface but nonlinear at higher altitudes. The results of process analysis demonstrate that urban heat island circulation and a deeper boundary layer with stronger turbulent intensities play a significant role in relocating pollutants.
J. Meyer, C. Rolf, C. Schiller, S. Rohs, N. Spelten, A. Afchine, M. Zöger, N. Sitnikov, T. D. Thornberry, A. W. Rollins, Z. Bozóki, D. Tátrai, V. Ebert, B. Kühnreich, P. Mackrodt, O. Möhler, H. Saathoff, K. H. Rosenlof, and M. Krämer
Atmos. Chem. Phys., 15, 8521–8538, https://doi.org/10.5194/acp-15-8521-2015, https://doi.org/10.5194/acp-15-8521-2015, 2015
J. Ungermann, J. Blank, M. Dick, A. Ebersoldt, F. Friedl-Vallon, A. Giez, T. Guggenmoser, M. Höpfner, T. Jurkat, M. Kaufmann, S. Kaufmann, A. Kleinert, M. Krämer, T. Latzko, H. Oelhaf, F. Olchewski, P. Preusse, C. Rolf, J. Schillings, O. Suminska-Ebersoldt, V. Tan, N. Thomas, C. Voigt, A. Zahn, M. Zöger, and M. Riese
Atmos. Meas. Tech., 8, 2473–2489, https://doi.org/10.5194/amt-8-2473-2015, https://doi.org/10.5194/amt-8-2473-2015, 2015
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The GLORIA sounder is an airborne infrared limb-imager combining a two-dimensional infrared detector with a Fourier transform spectrometer. It was operated aboard the new German Gulfstream G550 research aircraft HALO during the TACTS and ESMVAL campaigns in summer 2012. This paper describes the retrieval of temperature, as well as H2O, HNO3, and O3 cross sections from GLORIA dynamics mode spectra. A high correlation is achieved between the remote sensing and the in situ trace gas measurements.
R. Wang, Y. Balkanski, O. Boucher, L. Bopp, A. Chappell, P. Ciais, D. Hauglustaine, J. Peñuelas, and S. Tao
Atmos. Chem. Phys., 15, 6247–6270, https://doi.org/10.5194/acp-15-6247-2015, https://doi.org/10.5194/acp-15-6247-2015, 2015
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This study makes a first attempt to estimate the temporal trend of Fe emissions from anthropogenic and natural combustion sources from 1960 to 2007 and the emissions of Fe from mineral dust based on a recent mineralogical database. The new emission inventory is introduced into a global aerosol model. The simulated total Fe and soluble Fe concentrations in surface air as well as the deposition of total Fe are evaluated by observations over major continental and oceanic regions globally.
C. Dyroff, S. Sanati, E. Christner, A. Zahn, M. Balzer, H. Bouquet, J. B. McManus, Y. González-Ramos, and M. Schneider
Atmos. Meas. Tech., 8, 2037–2049, https://doi.org/10.5194/amt-8-2037-2015, https://doi.org/10.5194/amt-8-2037-2015, 2015
A. Worringen, K. Kandler, N. Benker, T. Dirsch, S. Mertes, L. Schenk, U. Kästner, F. Frank, B. Nillius, U. Bundke, D. Rose, J. Curtius, P. Kupiszewski, E. Weingartner, P. Vochezer, J. Schneider, S. Schmidt, S. Weinbruch, and M. Ebert
Atmos. Chem. Phys., 15, 4161–4178, https://doi.org/10.5194/acp-15-4161-2015, https://doi.org/10.5194/acp-15-4161-2015, 2015
P. Neis, H. G. J. Smit, M. Krämer, N. Spelten, and A. Petzold
Atmos. Meas. Tech., 8, 1233–1243, https://doi.org/10.5194/amt-8-1233-2015, https://doi.org/10.5194/amt-8-1233-2015, 2015
H. G. J. Smit, S. Rohs, P. Neis, D. Boulanger, M. Krämer, A. Wahner, and A. Petzold
Atmos. Chem. Phys., 14, 13241–13255, https://doi.org/10.5194/acp-14-13241-2014, https://doi.org/10.5194/acp-14-13241-2014, 2014
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Long-term water vapour measurements from the MOZAIC programme are a unique source for upper troposphere humidity data. However, due to an error in the calibration procedure, RH data from MOZAIC were biased towards higher values for the period starting in year 2000. Here we report the procedures followed to reanalyse the calibrations and to reprocess the entire MOZAIC RH data. This study serves as the reference publication for the reanalysed MOZAIC RH data base for the period 1994 to 2009.
B. Vogel, G. Günther, R. Müller, J.-U. Grooß, P. Hoor, M. Krämer, S. Müller, A. Zahn, and M. Riese
Atmos. Chem. Phys., 14, 12745–12762, https://doi.org/10.5194/acp-14-12745-2014, https://doi.org/10.5194/acp-14-12745-2014, 2014
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Enhanced tropospheric trace gases (e.g. pollutants) were measured in situ in
the lowermost stratosphere over Northern Europe on 26 September 2012
during the TACTS aircraft campaign. We found that the combination of rapid uplift by a typhoon and eastward eddy shedding from the Asian monsoon anticyclone is a novel fast transport pathway
that may carry boundary emissions from Southeast
Asia/western Pacific within approximately 5 weeks to the lowermost
stratosphere in Northern Europe.
P. Ricaud, B. Sič, L. El Amraoui, J.-L. Attié, R. Zbinden, P. Huszar, S. Szopa, J. Parmentier, N. Jaidan, M. Michou, R. Abida, F. Carminati, D. Hauglustaine, T. August, J. Warner, R. Imasu, N. Saitoh, and V.-H. Peuch
Atmos. Chem. Phys., 14, 11427–11446, https://doi.org/10.5194/acp-14-11427-2014, https://doi.org/10.5194/acp-14-11427-2014, 2014
D. A. Hauglustaine, Y. Balkanski, and M. Schulz
Atmos. Chem. Phys., 14, 11031–11063, https://doi.org/10.5194/acp-14-11031-2014, https://doi.org/10.5194/acp-14-11031-2014, 2014
L. P. Schenk, S. Mertes, U. Kästner, F. Frank, B. Nillius, U. Bundke, D. Rose, S. Schmidt, J. Schneider, A. Worringen, K. Kandler, N. Bukowiecki, M. Ebert, J. Curtius, and F. Stratmann
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amtd-7-10585-2014, https://doi.org/10.5194/amtd-7-10585-2014, 2014
Revised manuscript has not been submitted
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A pumped counterflow virtual impactor (PCVI) was set up to separate ice nucleating particle (INP) counter produced ice particles that had been activated to ice from non-activated aerosol particles. The released INP were characterized with regard to their physico-chemical properties. A successful separation (PCVI) of INP for water-subsaturated conditions is proven. First results of INP properties are presented which were gained during a campaign at the high altitude research station Jungfraujoch.
C. Warneke, F. Geiger, P. M. Edwards, W. Dube, G. Pétron, J. Kofler, A. Zahn, S. S. Brown, M. Graus, J. B. Gilman, B. M. Lerner, J. Peischl, T. B. Ryerson, J. A. de Gouw, and J. M. Roberts
Atmos. Chem. Phys., 14, 10977–10988, https://doi.org/10.5194/acp-14-10977-2014, https://doi.org/10.5194/acp-14-10977-2014, 2014
A. M. Thompson, N. V. Balashov, J. C. Witte, J. G. R. Coetzee, V. Thouret, and F. Posny
Atmos. Chem. Phys., 14, 9855–9869, https://doi.org/10.5194/acp-14-9855-2014, https://doi.org/10.5194/acp-14-9855-2014, 2014
B. G. Martinsson, J. Friberg, S. M. Andersson, A. Weigelt, M. Hermann, D. Assmann, J. Voigtländer, C. A. M. Brenninkmeijer, P. J. F. van Velthoven, and A. Zahn
Atmos. Meas. Tech., 7, 2581–2596, https://doi.org/10.5194/amt-7-2581-2014, https://doi.org/10.5194/amt-7-2581-2014, 2014
K.-P. Heue, H. Riede, D. Walter, C. A. M. Brenninkmeijer, T. Wagner, U. Frieß, U. Platt, A. Zahn, G. Stratmann, and H. Ziereis
Atmos. Chem. Phys., 14, 6621–6642, https://doi.org/10.5194/acp-14-6621-2014, https://doi.org/10.5194/acp-14-6621-2014, 2014
J. Tian, N. Riemer, M. West, L. Pfaffenberger, H. Schlager, and A. Petzold
Atmos. Chem. Phys., 14, 5327–5347, https://doi.org/10.5194/acp-14-5327-2014, https://doi.org/10.5194/acp-14-5327-2014, 2014
G. W. Mann, K. S. Carslaw, C. L. Reddington, K. J. Pringle, M. Schulz, A. Asmi, D. V. Spracklen, D. A. Ridley, M. T. Woodhouse, L. A. Lee, K. Zhang, S. J. Ghan, R. C. Easter, X. Liu, P. Stier, Y. H. Lee, P. J. Adams, H. Tost, J. Lelieveld, S. E. Bauer, K. Tsigaridis, T. P. C. van Noije, A. Strunk, E. Vignati, N. Bellouin, M. Dalvi, C. E. Johnson, T. Bergman, H. Kokkola, K. von Salzen, F. Yu, G. Luo, A. Petzold, J. Heintzenberg, A. Clarke, J. A. Ogren, J. Gras, U. Baltensperger, U. Kaminski, S. G. Jennings, C. D. O'Dowd, R. M. Harrison, D. C. S. Beddows, M. Kulmala, Y. Viisanen, V. Ulevicius, N. Mihalopoulos, V. Zdimal, M. Fiebig, H.-C. Hansson, E. Swietlicki, and J. S. Henzing
Atmos. Chem. Phys., 14, 4679–4713, https://doi.org/10.5194/acp-14-4679-2014, https://doi.org/10.5194/acp-14-4679-2014, 2014
A. Wisher, D. E. Oram, J. C. Laube, G. P. Mills, P. van Velthoven, A. Zahn, and C. A. M. Brenninkmeijer
Atmos. Chem. Phys., 14, 3557–3570, https://doi.org/10.5194/acp-14-3557-2014, https://doi.org/10.5194/acp-14-3557-2014, 2014
J. C. Corbin, B. Sierau, M. Gysel, M. Laborde, A. Keller, J. Kim, A. Petzold, T. B. Onasch, U. Lohmann, and A. A. Mensah
Atmos. Chem. Phys., 14, 2591–2603, https://doi.org/10.5194/acp-14-2591-2014, https://doi.org/10.5194/acp-14-2591-2014, 2014
C. Dyroff, A. Zahn, S. Sanati, E. Christner, A. Rauthe-Schöch, and T. J. Schuck
Atmos. Meas. Tech., 7, 743–755, https://doi.org/10.5194/amt-7-743-2014, https://doi.org/10.5194/amt-7-743-2014, 2014
J. E. Williams, G. Le Bras, A. Kukui, H. Ziereis, and C. A. M. Brenninkmeijer
Atmos. Chem. Phys., 14, 2363–2382, https://doi.org/10.5194/acp-14-2363-2014, https://doi.org/10.5194/acp-14-2363-2014, 2014
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 7, 241–266, https://doi.org/10.5194/amt-7-241-2014, https://doi.org/10.5194/amt-7-241-2014, 2014
V. Grewe, C. Frömming, S. Matthes, S. Brinkop, M. Ponater, S. Dietmüller, P. Jöckel, H. Garny, E. Tsati, K. Dahlmann, O. A. Søvde, J. Fuglestvedt, T. K. Berntsen, K. P. Shine, E. A. Irvine, T. Champougny, and P. Hullah
Geosci. Model Dev., 7, 175–201, https://doi.org/10.5194/gmd-7-175-2014, https://doi.org/10.5194/gmd-7-175-2014, 2014
R. M. Zbinden, V. Thouret, P. Ricaud, F. Carminati, J.-P. Cammas, and P. Nédélec
Atmos. Chem. Phys., 13, 12363–12388, https://doi.org/10.5194/acp-13-12363-2013, https://doi.org/10.5194/acp-13-12363-2013, 2013
P. Jeßberger, C. Voigt, U. Schumann, I. Sölch, H. Schlager, S. Kaufmann, A. Petzold, D. Schäuble, and J.-F. Gayet
Atmos. Chem. Phys., 13, 11965–11984, https://doi.org/10.5194/acp-13-11965-2013, https://doi.org/10.5194/acp-13-11965-2013, 2013
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, and V. Thouret
Atmos. Meas. Tech., 6, 3393–3406, https://doi.org/10.5194/amt-6-3393-2013, https://doi.org/10.5194/amt-6-3393-2013, 2013
S. Hou, J. Chappellaz, D. Raynaud, V. Masson-Delmotte, J. Jouzel, P. Bousquet, and D. Hauglustaine
Clim. Past, 9, 2549–2554, https://doi.org/10.5194/cp-9-2549-2013, https://doi.org/10.5194/cp-9-2549-2013, 2013
P. D. Kalabokas, J.-P. Cammas, V. Thouret, A. Volz-Thomas, D. Boulanger, and C. C. Repapis
Atmos. Chem. Phys., 13, 10339–10352, https://doi.org/10.5194/acp-13-10339-2013, https://doi.org/10.5194/acp-13-10339-2013, 2013
A. Petzold, J. A. Ogren, M. Fiebig, P. Laj, S.-M. Li, U. Baltensperger, T. Holzer-Popp, S. Kinne, G. Pappalardo, N. Sugimoto, C. Wehrli, A. Wiedensohler, and X.-Y. Zhang
Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, https://doi.org/10.5194/acp-13-8365-2013, 2013
G. Wetzel, H. Oelhaf, G. Berthet, A. Bracher, C. Cornacchia, D. G. Feist, H. Fischer, A. Fix, M. Iarlori, A. Kleinert, A. Lengel, M. Milz, L. Mona, S. C. Müller, J. Ovarlez, G. Pappalardo, C. Piccolo, P. Raspollini, J.-B. Renard, V. Rizi, S. Rohs, C. Schiller, G. Stiller, M. Weber, and G. Zhang
Atmos. Chem. Phys., 13, 5791–5811, https://doi.org/10.5194/acp-13-5791-2013, https://doi.org/10.5194/acp-13-5791-2013, 2013
A. Petzold, T. Onasch, P. Kebabian, and A. Freedman
Atmos. Meas. Tech., 6, 1141–1151, https://doi.org/10.5194/amt-6-1141-2013, https://doi.org/10.5194/amt-6-1141-2013, 2013
A. Inness, F. Baier, A. Benedetti, I. Bouarar, S. Chabrillat, H. Clark, C. Clerbaux, P. Coheur, R. J. Engelen, Q. Errera, J. Flemming, M. George, C. Granier, J. Hadji-Lazaro, V. Huijnen, D. Hurtmans, L. Jones, J. W. Kaiser, J. Kapsomenakis, K. Lefever, J. Leitão, M. Razinger, A. Richter, M. G. Schultz, A. J. Simmons, M. Suttie, O. Stein, J.-N. Thépaut, V. Thouret, M. Vrekoussis, C. Zerefos, and the MACC team
Atmos. Chem. Phys., 13, 4073–4109, https://doi.org/10.5194/acp-13-4073-2013, https://doi.org/10.5194/acp-13-4073-2013, 2013
S. Groß, M. Esselborn, B. Weinzierl, M. Wirth, A. Fix, and A. Petzold
Atmos. Chem. Phys., 13, 2487–2505, https://doi.org/10.5194/acp-13-2487-2013, https://doi.org/10.5194/acp-13-2487-2013, 2013
R. Weller, A. Minikin, A. Petzold, D. Wagenbach, and G. König-Langlo
Atmos. Chem. Phys., 13, 1579–1590, https://doi.org/10.5194/acp-13-1579-2013, https://doi.org/10.5194/acp-13-1579-2013, 2013
M. Gysel, M. Laborde, A. A. Mensah, J. C. Corbin, A. Keller, J. Kim, A. Petzold, and B. Sierau
Atmos. Meas. Tech., 5, 3099–3107, https://doi.org/10.5194/amt-5-3099-2012, https://doi.org/10.5194/amt-5-3099-2012, 2012
T. Hamburger, G. McMeeking, A. Minikin, A. Petzold, H. Coe, and R. Krejci
Atmos. Chem. Phys., 12, 11533–11554, https://doi.org/10.5194/acp-12-11533-2012, https://doi.org/10.5194/acp-12-11533-2012, 2012
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Tracking daily NOx emissions from an urban agglomeration based on TROPOMI NO2 and a local ensemble transform Kalman filter
Source contribution to ozone pollution during June 2021 fire events in Arizona: insights from WRF-Chem-tagged O3 and CO
High-resolution mapping of on-road vehicle emissions with real-time traffic datasets based on big data
Sensitivity of climate–chemistry model simulated atmospheric composition to the application of an inverse relationship between NOx emission and lightning flash frequency
Regional and sectoral contributions of NOx and reactive carbon emission sources to global trends in tropospheric ozone during the 2000–2018 period
Underappreciated contributions of biogenic volatile organic compounds from urban green spaces to ozone pollution
Chemistry–climate feedback of atmospheric methane in a methane-emission-flux-driven chemistry–climate model
Surface ozone trend variability across the United States and the impact of heat waves (1990–2023)
Sensitivity of climate effects of hydrogen to leakage size, location, and chemical background
Evaluating tropospheric nitrogen dioxide in UKCA using OMI satellite retrievals over south and east Asia
Technical note: A comparative study of chemistry schemes for volcanic sulfur dioxide in Lagrangian transport simulations – a case study of the 2019 Raikoke eruption
Revisiting the high tropospheric ozone over southern Africa: role of biomass burning and anthropogenic emissions
Monoterpene oxidation pathways initiated by acyl peroxy radical addition
Local and transboundary contributions to NOy loadings across East Asia using CMAQ-ISAM and a GEMS-informed emission inventory during the winter–spring transition
Estimating the variability in NOx emissions from Wuhan with TROPOMI NO2 data during 2018 to 2023
Enhanced understanding of atmospheric blocking modulation on ozone dynamics within a high-resolution Earth system model
Natural emissions of VOC and NOx over Africa constrained by TROPOMI HCHO and NO2 data using the MAGRITTEv1.1 model
Contributions of lightning to long-term trends and inter-annual variability in global atmospheric chemistry constrained by Schumann Resonance observations
Simulated photochemical response to observational constraints on aerosol vertical distribution over North China
Impacts of wildfire smoke aerosols on near-surface ozone photochemistry
Anthropogenic emission controls reduce summertime ozone–temperature sensitivity in the United States
Investigating the response of China's surface ozone concentration to the future changes of multiple factors
Assessing the relative impacts of satellite ozone and its precursor observations to improve global tropospheric ozone analysis using multiple chemical reanalysis systems
Evaluating present-day and future impacts of agricultural ammonia emissions on atmospheric chemistry and climate
Air-pollution-satellite-based CO2 emission inversion: system evaluation, sensitivity analysis, and future research direction
The impact of sea spray aerosol on photochemical ozone formation over eastern China: heterogeneous reaction of chlorine particles and radiative effect
Insights into ozone pollution control in urban areas by decoupling meteorological factors based on machine learning
Quantification of regional net CO2 flux errors in the Orbiting Carbon Observatory-2 (OCO-2) v10 model intercomparison project (MIP) ensemble using airborne measurements
Reactive nitrogen in and around the northeastern and mid-Atlantic US: sources, sinks, and connections with ozone
Preindustrial-to-present-day changes in atmospheric carbon monoxide: agreement and gaps between ice archives and global model reconstructions
Investigating processes influencing simulation of local Arctic wintertime anthropogenic pollution in Fairbanks, Alaska, during ALPACA-2022
Urban ozone formation and sensitivities to volatile chemical products, cooking emissions, and NOx upwind of and within two Los Angeles Basin cities
Causes of growing middle-to-upper tropospheric ozone over the northwest Pacific region
Impact of introducing electric vehicles on ground-level O3 and PM2.5 in the Greater Tokyo Area: yearly trends and the importance of changes in the urban heat island effect
Modelling Arctic Lower Tropospheric Ozone: processes controlling seasonal variations
Climate-driven biogenic emissions alleviate the impact of man-made emission reduction on O3 control in Pearl River Delta region, southern China
South Asia ammonia emission inversion through assimilating IASI observations
Constraining the budget of NOx and VOCs at a remote Tropical island using multi-platform observations and WRF-Chem model simulations
A CO2–Δ14CO2 inversion setup for estimating European fossil CO2 emissions
Maximum ozone concentrations in the southwestern US and Texas: implications of the growing predominance of the background contribution
Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen)
Comparative ozone production sensitivity to NOx and VOCs in Quito, Ecuador and Santiago, Chile: implications for control strategies in times of climate action
Seasonal, regional, and vertical characteristics of high-carbon-monoxide plumes along with their associated ozone anomalies, as seen by IAGOS between 2002 and 2019
Tropospheric ozone trends and attributions over East and Southeast Asia in 1995–2019: An integrated assessment using statistical methods, machine learning models, and multiple chemical transport models
The potential of drone observations to improve air quality predictions by 4D-Var
Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York
Ozone source attribution in polluted European areas during summer 2017 as simulated with MECO(n)
Characterization of reactive nitrogen in the global upper troposphere using recent and historical commercial and research aircraft campaigns and GEOS-Chem
Opinion: Challenges and needs of tropospheric chemical mechanism development
Decrease of the European NOx anthropogenic emissions between 2005 and 2019 as seen from the OMI and TROPOMI NO2 satellite observations
Yawen Kong, Bo Zheng, and Yuxi Liu
Atmos. Chem. Phys., 25, 5959–5976, https://doi.org/10.5194/acp-25-5959-2025, https://doi.org/10.5194/acp-25-5959-2025, 2025
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Current high-resolution satellite remote sensing technologies provide a unique opportunity to derive timely high-resolution emission data. We developed an emission inversion system to assimilate satellite NO2 data to obtain daily kilometer-scale NOx emission inventories. Our results enhance inventory accuracy, allowing us to capture the effects of pollution control policies on daily emissions (e.g., during COVID-19 lockdowns) and improve fine-scale air quality modeling.
Yafang Guo, Mohammad Amin Mirrezaei, Armin Sorooshian, and Avelino F. Arellano
Atmos. Chem. Phys., 25, 5591–5616, https://doi.org/10.5194/acp-25-5591-2025, https://doi.org/10.5194/acp-25-5591-2025, 2025
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We assess the contributions of fire and anthropogenic emissions to O3 levels in Phoenix, Arizona, during a period of intense heat and drought conditions. We find that fire exacerbates O3 pollution and that interactions between weather, climate, and air chemistry are important to consider. This has implications for activities related to formulating emission reduction strategies in areas that are currently understudied yet becoming relevant due to reports of increasing global aridity.
Yujia Wang, Hongbin Wang, Bo Zhang, Peng Liu, Xinfeng Wang, Shuchun Si, Likun Xue, Qingzhu Zhang, and Qiao Wang
Atmos. Chem. Phys., 25, 5537–5555, https://doi.org/10.5194/acp-25-5537-2025, https://doi.org/10.5194/acp-25-5537-2025, 2025
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This study established a bottom-up approach that employs real-time traffic flows and interpolation to obtain a spatially continuous on-road vehicle emission mapping for the main urban area of Jinan. The diurnal variation, spatial distribution, and emission hotspots were analyzed with clustering and hotspot analysis, showing unique fine-scale variation characteristics of on-road vehicle emissions. Future scenario analysis demonstrates remarkable benefits of electrification on emission reduction.
Francisco J. Pérez-Invernón, Francisco J. Gordillo-Vázquez, Heidi Huntrieser, Patrick Jöckel, and Eric J. Bucsela
Atmos. Chem. Phys., 25, 5557–5575, https://doi.org/10.5194/acp-25-5557-2025, https://doi.org/10.5194/acp-25-5557-2025, 2025
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Lightning plays a significant role in tropospheric chemistry by producing substantial amounts of nitrogen oxides. According to recent estimates, thunderstorms that produce a higher lightning frequency rate also produce less nitrogen oxide per flash. We implemented the dependency of nitrogen oxide production per flash on lightning flash frequency in a chemical atmospheric model.
Aditya Nalam, Aura Lupaşcu, Tabish Ansari, and Tim Butler
Atmos. Chem. Phys., 25, 5287–5311, https://doi.org/10.5194/acp-25-5287-2025, https://doi.org/10.5194/acp-25-5287-2025, 2025
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Tropospheric O3 molecules are labeled with the identity of their precursor source to simulate contributions from various emission sources to the global tropospheric O3 burden (TOB) and its trends. With an equatorward shift, anthropogenic NOx emissions become significantly more efficient at producing O3 and play a major role in driving TOB trends, mainly due to larger convection at the tropics effectively lifting O3 and its precursors to the free troposphere, where O3 lifetime is longer.
Haofan Wang, Yuejin Li, Yiming Liu, Xiao Lu, Yang Zhang, Qi Fan, Chong Shen, Senchao Lai, Yan Zhou, Tao Zhang, and Dingli Yue
Atmos. Chem. Phys., 25, 5233–5250, https://doi.org/10.5194/acp-25-5233-2025, https://doi.org/10.5194/acp-25-5233-2025, 2025
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This study explores how urban green spaces (UGSs) in Guangzhou influence ozone levels. By using advanced models, we found that natural emissions from these areas can significantly affect air quality. Our results suggest that the design and planning of UGSs should not only consider aesthetics and social factors but also their environmental impacts on air quality.
Laura Stecher, Franziska Winterstein, Patrick Jöckel, Michael Ponater, Mariano Mertens, and Martin Dameris
Atmos. Chem. Phys., 25, 5133–5158, https://doi.org/10.5194/acp-25-5133-2025, https://doi.org/10.5194/acp-25-5133-2025, 2025
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Methane, the second most important anthropogenic greenhouse gas, is chemically decomposed in the atmosphere. The chemical sink of atmospheric methane is not constant but depends on the temperature and on the abundance of its reaction partners. In this study, we use a global chemistry–climate model to assess the feedback of atmospheric methane induced by changes in the chemical sink in a warming climate and its implications for the chemical composition and the surface air temperature change.
Kai-Lan Chang, Brian C. McDonald, Colin Harkins, and Owen R. Cooper
Atmos. Chem. Phys., 25, 5101–5132, https://doi.org/10.5194/acp-25-5101-2025, https://doi.org/10.5194/acp-25-5101-2025, 2025
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Exposure to high levels of ozone can be harmful to human health. This study shows consistent and robust evidence of decreasing ozone extremes across much of the United States over the period from 1990 to 2023, previously attributed to ozone precursor emission controls. Nevertheless, we also show that the increasing heat wave frequencies are likely to contribute to additional ozone exceedances, slowing the progress of decreasing the frequency of ozone exceedances.
Ragnhild Bieltvedt Skeie, Marit Sandstad, Srinath Krishnan, Gunnar Myhre, and Maria Sand
Atmos. Chem. Phys., 25, 4929–4942, https://doi.org/10.5194/acp-25-4929-2025, https://doi.org/10.5194/acp-25-4929-2025, 2025
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Hydrogen leakages can alter the amount of climate gases in the atmosphere and hence have a climate impact. In this study we investigate, using an atmospheric chemistry model, how this indirect climate effect differs with different amounts of leakages and with where the hydrogen leaks and if this effect changes in the future. The effect is largest for emissions far from areas where hydrogen is removed from the atmosphere by the soil, but these are not relevant locations for a future hydrogen economy.
Alok K. Pandey, David S. Stevenson, Alcide Zhao, Richard J. Pope, Ryan Hossaini, Krishan Kumar, and Martyn P. Chipperfield
Atmos. Chem. Phys., 25, 4785–4802, https://doi.org/10.5194/acp-25-4785-2025, https://doi.org/10.5194/acp-25-4785-2025, 2025
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Nitrogen dioxide is an air pollutant largely controlled by human activity that affects ozone, methane, and aerosols. Satellite instruments can quantify column NO2 and, by carefully matching the time and location of measurements, enable evaluation of model simulations. NO2 over south and east Asia is assessed, showing that the model captures not only many features of the measurements, but also important differences that suggest model deficiencies in representing several aspects of the atmospheric chemistry of NO2.
Mingzhao Liu, Lars Hoffmann, Jens-Uwe Grooß, Zhongyin Cai, Sabine Grießbach, and Yi Heng
Atmos. Chem. Phys., 25, 4403–4418, https://doi.org/10.5194/acp-25-4403-2025, https://doi.org/10.5194/acp-25-4403-2025, 2025
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We studied the transport and chemical decomposition of volcanic SO2, focusing on the 2019 Raikoke event. By comparing two different chemistry modeling schemes, we found that including complex chemical reactions leads to a more accurate prediction of how long SO2 stays in the atmosphere. This research helps improve our understanding of volcanic pollution and its impact on air quality and climate, providing better tools for scientists to track and predict the movement of these pollutants.
Yufen Wang, Ke Li, Xi Chen, Zhenjiang Yang, Minglong Tang, Pascoal M. D. Campos, Yang Yang, Xu Yue, and Hong Liao
Atmos. Chem. Phys., 25, 4455–4475, https://doi.org/10.5194/acp-25-4455-2025, https://doi.org/10.5194/acp-25-4455-2025, 2025
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The impacts of biomass burning and anthropogenic emissions on high tropospheric ozone levels are not well studied in southern Africa. We combined model simulations with recent observations at the surface and from space to quantify tropospheric ozone and its drivers in southern Africa. Our work focuses on the impact of emissions from different sources at different spatial scales, contributing to a comprehensive understanding of air pollution drivers and their uncertainties in southern Africa.
Dominika Pasik, Thomas Golin Almeida, Emelda Ahongshangbam, Siddharth Iyer, and Nanna Myllys
Atmos. Chem. Phys., 25, 4313–4331, https://doi.org/10.5194/acp-25-4313-2025, https://doi.org/10.5194/acp-25-4313-2025, 2025
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We used quantum chemistry methods to investigate the oxidation mechanisms of acyl peroxy radicals (APRs) with various monoterpenes. Our findings reveal unique oxidation pathways for different monoterpenes, leading to either chain-terminating products or highly reactive intermediates that can contribute to particle formation in the atmosphere. This research highlights APRs as potentially significant but underexplored atmospheric oxidants that may influence future approaches to modelling climate.
Jincheol Park, Yunsoo Choi, and Sagun Kayastha
Atmos. Chem. Phys., 25, 4291–4311, https://doi.org/10.5194/acp-25-4291-2025, https://doi.org/10.5194/acp-25-4291-2025, 2025
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We investigated NOx emission contributions to NOy loadings across five regions of East Asia during the 2022 winter–spring transition through chemical transport modeling informed by satellite data. As seasons progress, local contributions within each region to its NOy budget decreased from 32 %–43 % to 23 %–30 %, while transboundary contributions increased from 16 %–33 % to 27 %–37 %, driven by a shift in synoptic settings that allowed pollutants to spread more broadly across the regions.
Qianqian Zhang, K. Folkert Boersma, Chiel van der Laan, Alba Mols, Bin Zhao, Shengyue Li, and Yuepeng Pan
Atmos. Chem. Phys., 25, 3313–3326, https://doi.org/10.5194/acp-25-3313-2025, https://doi.org/10.5194/acp-25-3313-2025, 2025
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Accurate NOx emission estimates are required to better understand air pollution. This study investigates and demonstrates the ability of the superposition column model in combination with TROPOMI tropospheric NO2 column data to estimate city-scale NOx emissions and lifetimes and their variabilities. The results of this work nevertheless confirm the strength of the superposition column model in estimating urban NOx emissions with reasonable accuracy.
Wenbin Kou, Yang Gao, Dan Tong, Xiaojie Guo, Xiadong An, Wenyu Liu, Mengshi Cui, Xiuwen Guo, Shaoqing Zhang, Huiwang Gao, and Lixin Wu
Atmos. Chem. Phys., 25, 3029–3048, https://doi.org/10.5194/acp-25-3029-2025, https://doi.org/10.5194/acp-25-3029-2025, 2025
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Unlike traditional numerical studies, we apply a high-resolution Earth system model, improving simulations of surface ozone and large-scale circulations such as atmospheric blocking. Besides local heat waves, we quantify the impact of atmospheric blocking on downstream ozone concentrations, which is closely associated with the blocking position. We identify three major pathways of Rossby wave propagation, stressing the critical role of large-scale circulation in regional air quality.
Beata Opacka, Trissevgeni Stavrakou, Jean-François Müller, Isabelle De Smedt, Jos van Geffen, Eloise A. Marais, Rebekah P. Horner, Dylan B. Millet, Kelly C. Wells, and Alex B. Guenther
Atmos. Chem. Phys., 25, 2863–2894, https://doi.org/10.5194/acp-25-2863-2025, https://doi.org/10.5194/acp-25-2863-2025, 2025
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Vegetation releases biogenic volatile organic compounds, while soils and lightning contribute to the natural emissions of nitrogen oxides into the atmosphere. These gases interact in complex ways. Using satellite data and models, we developed a new method to simultaneously optimize these natural emissions over Africa in 2019. Our approach resulted in an increase in natural emissions, supported by independent data indicating that current estimates are underestimated.
Xiaobo Wang, Yuzhong Zhang, Tamás Bozóki, Ruosi Liang, Xinchun Xie, Shutao Zhao, Rui Wang, Yujia Zhao, and Shuai Sun
EGUsphere, https://doi.org/10.5194/egusphere-2025-370, https://doi.org/10.5194/egusphere-2025-370, 2025
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Schumann Resonance observations are used to parameterize lightning NOx emissions for better capturing global lightning trend and variability. Updated simulations reveal insignificant trend but greater variability in lightning NOx emissions, impacting tropospheric NOx, O3 and OH. Lightning generally counteracts non-lightning factors, reducing the inter-annua variability of tropospheric O3 and OH. Variations of global lightning play important role in understanding the atmospheric methane budget.
Xi Chen, Ke Li, Ting Yang, Xipeng Jin, Lei Chen, Yang Yang, Shuman Zhao, Bo Hu, Bin Zhu, Zifa Wang, and Hong Liao
EGUsphere, https://doi.org/10.5194/egusphere-2025-430, https://doi.org/10.5194/egusphere-2025-430, 2025
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Aerosol vertical distribution that plays a crucial role in aerosol-photolysis interaction (API) remains underrepresented in chemical models. We integrated lidar and radiosonde observations to constrain the simulated aerosol profiles over North China and quantified the photochemical responses. The increased photolysis rates in the lower layers led to increased ozone and accounted for a 36 %–56 % reduction in API effects, resulting in enhanced atmospheric oxidizing capacity and aerosol formation.
Jiaqi Shen, Ronald C. Cohen, Glenn M. Wolfe, and Xiaomeng Jin
EGUsphere, https://doi.org/10.5194/egusphere-2025-706, https://doi.org/10.5194/egusphere-2025-706, 2025
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This study shows large chemical and radiative effects of smoke aerosols from fires on near-surface ozone production. Aerosol loading and NOx levels are identified as the primary factors influencing these effects. Furthermore, we show that the surface PM2.5 to NO2 column ratio can be used as an indicator for identifying aerosol-dominated regimes, facilitating the assessments of aerosol impacts on ozone formation through satellite observations.
Shuai Li, Haolin Wang, and Xiao Lu
Atmos. Chem. Phys., 25, 2725–2743, https://doi.org/10.5194/acp-25-2725-2025, https://doi.org/10.5194/acp-25-2725-2025, 2025
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Summertime ozone–temperature sensitivity has decreased by 50 % from 3.0 ppbv per K in 1990 to 1.5 ppb per K in 2021 in the US. GEOS-Chem simulations show that anthropogenic nitrogen oxide emission reduction is the dominant driver of ozone–temperature sensitivity decline by influencing both temperature direct and temperature indirect processes. Reduced ozone–temperature sensitivity has decreased ozone enhancement from low to high temperatures by an average of 6.8 ppbv across the US.
Jinya Yang, Yutong Wang, Lei Zhang, and Yu Zhao
Atmos. Chem. Phys., 25, 2649–2666, https://doi.org/10.5194/acp-25-2649-2025, https://doi.org/10.5194/acp-25-2649-2025, 2025
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We develop a modeling framework to predict future ozone concentrations (till the 2060s) in China following an IPCC scenario. We evaluate the contributions of climatic, anthropogenic, and biogenic factors by season and region. We find persistent emission controls will alter the nonlinear response of ozone to its precursors and dominate the declining ozone level. The outcomes highlight the importance of human actions, even with a climate penalty on air quality.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
Atmos. Chem. Phys., 25, 2243–2268, https://doi.org/10.5194/acp-25-2243-2025, https://doi.org/10.5194/acp-25-2243-2025, 2025
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Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursor measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows an evaluation of the dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying magnitudes among the systems.
Maureen Beaudor, Didier Hauglustaine, Juliette Lathière, Martin Van Damme, Lieven Clarisse, and Nicolas Vuichard
Atmos. Chem. Phys., 25, 2017–2046, https://doi.org/10.5194/acp-25-2017-2025, https://doi.org/10.5194/acp-25-2017-2025, 2025
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Agriculture is the biggest ammonia (NH3) source, impacting air quality, climate, and ecosystems. Because of food demand, NH3 emissions are projected to rise by 2100. Using a global model, we analyzed the impact of present and future NH3 emissions generated from a land model. Our results show improved ammonia patterns compared to a reference inventory. Future scenarios predict up to 70 % increase in global NH3 burden, with significant changes in radiative forcing that can greatly elevate N2O.
Hui Li, Jiaxin Qiu, and Bo Zheng
Atmos. Chem. Phys., 25, 1949–1963, https://doi.org/10.5194/acp-25-1949-2025, https://doi.org/10.5194/acp-25-1949-2025, 2025
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We conduct a sensitivity analysis with 31 tests on various factors including prior emissions, model resolution, satellite constraint, and other system configurations to assess the vulnerability of emission estimates across temporal, sectoral, and regional dimensions. This reveals the robustness of emissions estimated by this air-pollution-satellite-based CO2 emission inversion system, with relative change between tests and base inversion below 4.0 % for national annual NOx and CO2 emissions.
Yingying Hong, Yuqi Zhu, Yuxuan Huang, Yiming Liu, Chuqi Xiong, and Qi Fan
EGUsphere, https://doi.org/10.5194/egusphere-2024-4132, https://doi.org/10.5194/egusphere-2024-4132, 2025
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This study investigates the impact of sea spray aerosol on ozone formation across Eastern China, highlighting its complex influence through both chemical reactions and radiative effects, which vary seasonally and geographically.
Yuqing Qiu, Xin Li, Wenxuan Chai, Yi Liu, Mengdi Song, Xudong Tian, Qiaoli Zou, Wenjun Lou, Wangyao Zhang, Juan Li, and Yuanhang Zhang
Atmos. Chem. Phys., 25, 1749–1763, https://doi.org/10.5194/acp-25-1749-2025, https://doi.org/10.5194/acp-25-1749-2025, 2025
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The chemical reactions of ozone (O3) formation are related to meteorology and local emissions. Here, a random forest approach was used to eliminate the effects of meteorological factors (dispersion or transport) on O3 and its precursors. Variations in the sensitivity of O3 formation and the apportionment of emission sources were revealed after meteorological normalization. Our results suggest that meteorological variations should be considered when diagnosing O3 formation.
Jeongmin Yun, Junjie Liu, Brendan Byrne, Brad Weir, Lesley E. Ott, Kathryn McKain, Bianca C. Baier, Luciana V. Gatti, and Sebastien C. Biraud
Atmos. Chem. Phys., 25, 1725–1748, https://doi.org/10.5194/acp-25-1725-2025, https://doi.org/10.5194/acp-25-1725-2025, 2025
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This study quantifies errors in regional net surface–atmosphere CO2 flux estimates from an inverse model ensemble using airborne CO2 measurements. Our results show that flux error estimates based on observations significantly exceed those computed from the ensemble spread of flux estimates in regions with high fossil fuel emissions. This finding suggests the presence of systematic biases in the inversion estimates, associated with errors in the fossil fuel emissions common to all models.
Min Huang, Gregory R. Carmichael, Kevin W. Bowman, Isabelle De Smedt, Andreas Colliander, Michael H. Cosh, Sujay V. Kumar, Alex B. Guenther, Scott J. Janz, Ryan M. Stauffer, Anne M. Thompson, Niko M. Fedkin, Robert J. Swap, John D. Bolten, and Alicia T. Joseph
Atmos. Chem. Phys., 25, 1449–1476, https://doi.org/10.5194/acp-25-1449-2025, https://doi.org/10.5194/acp-25-1449-2025, 2025
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We use model simulations along with multiplatform, multidisciplinary observations and a range of analysis methods to estimate and understand the distributions, temporal changes, and impacts of reactive nitrogen and ozone over the most populous US region that has undergone significant environmental changes. Deposition, biogenic emissions, and extra-regional sources have been playing increasingly important roles in controlling pollutant budgets in this area as local anthropogenic emissions drop.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Philip Place
Atmos. Chem. Phys., 25, 1105–1119, https://doi.org/10.5194/acp-25-1105-2025, https://doi.org/10.5194/acp-25-1105-2025, 2025
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Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry–climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonné, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
Atmos. Chem. Phys., 25, 1063–1104, https://doi.org/10.5194/acp-25-1063-2025, https://doi.org/10.5194/acp-25-1063-2025, 2025
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Processes influencing dispersion of local anthropogenic pollution in Arctic wintertime are investigated with Lagrangian dispersion modelling. Simulated power plant plume rise that considers temperature inversion layers improves results compared to observations (interior Alaska). Modelled surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching −35°C are required to reproduce observed NOx.
Chelsea E. Stockwell, Matthew M. Coggon, Rebecca H. Schwantes, Colin Harkins, Bert Verreyken, Congmeng Lyu, Qindan Zhu, Lu Xu, Jessica B. Gilman, Aaron Lamplugh, Jeff Peischl, Michael A. Robinson, Patrick R. Veres, Meng Li, Andrew W. Rollins, Kristen Zuraski, Sunil Baidar, Shang Liu, Toshihiro Kuwayama, Steven S. Brown, Brian C. McDonald, and Carsten Warneke
Atmos. Chem. Phys., 25, 1121–1143, https://doi.org/10.5194/acp-25-1121-2025, https://doi.org/10.5194/acp-25-1121-2025, 2025
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In urban areas, emissions from everyday products like paints, cleaners, and personal care products, along with non-traditional sources such as cooking, are increasingly important and impact air quality. This study uses a box model to evaluate how these emissions impact ozone in the Los Angeles Basin and quantifies the impact of gaseous cooking emissions. Accurate representation of these and other anthropogenic sources in inventories is crucial for informing effective air quality policies.
Xiaodan Ma, Jianping Huang, Michaela I. Hegglin, Patrick Jöckel, and Tianliang Zhao
Atmos. Chem. Phys., 25, 943–958, https://doi.org/10.5194/acp-25-943-2025, https://doi.org/10.5194/acp-25-943-2025, 2025
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Our research explored changes in ozone levels in the northwest Pacific region over 30 years, revealing a significant increase in the middle-to-upper troposphere, especially during spring and summer. This rise is influenced by both stratospheric and tropospheric sources, which affect climate and air quality in East Asia. This work underscores the need for continued study to understand underlying mechanisms.
Hiroo Hata, Norifumi Mizushima, and Tomohiko Ihara
Atmos. Chem. Phys., 25, 1037–1061, https://doi.org/10.5194/acp-25-1037-2025, https://doi.org/10.5194/acp-25-1037-2025, 2025
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The introduction of battery electric vehicles (BEVs) is expected to reduce the primary air pollutants from vehicular exhaust and evaporative emissions while reducing the anthropogenic heat produced by vehicles, ultimately mitigating the urban heat island (UHI) effect. This study revealed the impact of introducing BEVs on the decrease in the UHI effect and the impact of BEVs on the formation of tropospheric ozone and fine particulate matter in the Greater Tokyo Area of Japan.
Wanmin Gong, Stephen R. Beagley, Kenjiro Toyota, Henrik Skov, Jesper Heile Christensen, Alexandru Lupu, Diane Pendlebury, Junhua Zhang, Ulas Im, Yugo Kanaya, Alfonso Saiz-Lopez, Roberto Sommariva, Peter Effertz, John W. Halfacre, Nis Jepsen, Rigel Kivi, Theodore K. Koenig, Katrin Müller, Claus Nordstrøm, Irina Petropavlovskikh, Paul B. Shepson, William R. Simpson, Sverre Solberg, Ralf M. Staebler, David W. Tarasick, Roeland Van Malderen, and Mika Vestenius
EGUsphere, https://doi.org/10.5194/egusphere-2024-3750, https://doi.org/10.5194/egusphere-2024-3750, 2025
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This study showed that the springtime O3 depletion plays a critical role in driving the surface O3 seasonal cycle in Central Arctic. The O3 depletion events, while occurring most notably within the lowest few hundred metres above the Arctic Ocean, can induce a 5–7 % of loss in the pan-Arctic tropospheric O3 burden during springtime. The study also found an enhancement in O3 and NOy (mostly PAN) concentrations in the Arctic due to northern boreal wildfires, particularly at altitudes.
Nan Wang, Song Liu, Jiawei Xu, Yanyu Wang, Chun Li, Hua Lu, and Fumo Yang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3771, https://doi.org/10.5194/egusphere-2024-3771, 2025
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We found that climate warming and changes in vegetation have increased biogenic volatile organic compound emissions in the Pearl River Delta region. These increasing natural emissions, mainly due to climate warming, are weakening the benefits of reducing man-made emission control, leading to higher ozone levels. This work helps us understand how climate change influences air quality and provides important insights for improving pollution control strategies in the future.
Ji Xia, Yi Zhou, Li Fang, Yingfei Qi, Dehao Li, Hong Liao, and Jianbing Jin
EGUsphere, https://doi.org/10.5194/egusphere-2024-3938, https://doi.org/10.5194/egusphere-2024-3938, 2025
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This study established an ammonia emission inventory in South Asia via assimilation-based inversion system. The posterior emissions, calculated by integrating the CEDS inventory and IASI satellite observations, showed significant improvement over the prior. Validation against various measurements all support our posterior emission. It offers valuable insights of ammonia emissions for policymakers and researchers aiming to develop air quality management and mitigation strategies there.
Catalina Poraicu, Jean-François Müller, Trissevgeni Stavrakou, Crist Amelynck, Bert W. D. Verreyken, Niels Schoon, Corinne Vigouroux, Nicolas Kumps, Jérôme Brioude, Pierre Tulet, and Camille Mouchel-Vallon
EGUsphere, https://doi.org/10.5194/egusphere-2024-3555, https://doi.org/10.5194/egusphere-2024-3555, 2025
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We investigated the sources and impacts of nitrogen oxides and organic compounds over a remote tropical island. High-resolution WRF-Chem simulations were evaluated using in situ, FTIR and satellite measurements. This work highlights gaps in current models, like missing sources of key organic compounds and inaccuracies in emission inventories, emphasizing the importance of improving chemical and dynamical processes in atmospheric modelling for budget estimates in tropical regions.
Carlos Gómez-Ortiz, Guillaume Monteil, Sourish Basu, and Marko Scholze
Atmos. Chem. Phys., 25, 397–424, https://doi.org/10.5194/acp-25-397-2025, https://doi.org/10.5194/acp-25-397-2025, 2025
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In this paper, we test new implementations of our inverse modeling tool to estimate the weekly and regional CO2 emissions from fossil fuels in Europe. We use synthetic atmospheric observations of CO2 and radiocarbon (14CO2) to trace emissions to their sources, while separating the natural and fossil CO2. Our tool accurately estimates fossil CO2 emissions in densely monitored regions like western/central Europe. This approach aids in developing strategies for reducing CO2 emissions.
David D. Parrish, Ian C. Faloona, and Richard G. Derwent
Atmos. Chem. Phys., 25, 263–289, https://doi.org/10.5194/acp-25-263-2025, https://doi.org/10.5194/acp-25-263-2025, 2025
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Observation-based estimates of contributions to maximum ozone (O3) concentrations show that background O3 can exceed the air quality standard of 70 ppb in the southwestern US, precluding standard attainment. Over the past 4 decades, US anthropogenic O3 has decreased by a factor of ~ 6.3, while wildfire contributions have increased, so that the background now dominates maximum concentrations, even in Los Angeles, and the occurrence of maximum O3 has shifted from the eastern to the western US.
William P. L. Carter, Jia Jiang, John J. Orlando, and Kelley C. Barsanti
Atmos. Chem. Phys., 25, 199–242, https://doi.org/10.5194/acp-25-199-2025, https://doi.org/10.5194/acp-25-199-2025, 2025
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This paper describes the scientific basis for gas-phase atmospheric chemical mechanisms derived using the SAPRC mechanism generation system, MechGen. It can derive mechanisms for most organic compounds with C, H, O, or N atoms, including initial reactions of organics with OH, O3, NO3, and O3P or by photolysis, as well as the reactions of the various types of intermediates that are formed. The paper includes a description of areas of uncertainty where additional research and updates are needed.
María Cazorla, Melissa Trujillo, Rodrigo Seguel, and Laura Gallardo
EGUsphere, https://doi.org/10.5194/egusphere-2024-3720, https://doi.org/10.5194/egusphere-2024-3720, 2024
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The current climate emergency imposes the need to take actions in cities to curb ozone as a pollutant and a climate forcer. In this work we analyze how reducing the levels of ozone precursor would affect photochemical smog in Quito, Ecuador and Santiago, Chile. Results show that if environmental policy were implemented to reduce only nitrogen oxides, the production of ozone would increase substantially for which more integral solutions are needed.
Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Our study examines intense-carbon-monoxide (CO) pollution events measured by commercial aircraft from the In-service Aircraft for a Global Observing System (IAGOS) research infrastructure. We combine these measurements with the SOFT-IO model to trace the origin of the observed CO. A comprehensive analysis of the geographical origin, source type, seasonal variation, and ozone levels of these pollution events is provided.
Xiao Lu, Yiming Liu, Jiayin Su, Xiang Weng, Tabish Ansari, Yuqiang Zhang, Guowen He, Yuqi Zhu, Haolin Wang, Ganquan Zeng, Jingyu Li, Cheng He, Shuai Li, Teerachai Amnuaylojaroen, Tim Butler, Qi Fan, Shaojia Fan, Grant L. Forster, Meng Gao, Jianlin Hu, Yugo Kanaya, Mohd Talib Latif, Keding Lu, Philippe Nédélec, Peer Nowack, Bastien Sauvage, Xiaobin Xu, Lin Zhang, Ke Li, Ja-Ho Koo, and Tatsuya Nagashima
EGUsphere, https://doi.org/10.5194/egusphere-2024-3702, https://doi.org/10.5194/egusphere-2024-3702, 2024
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This study analyzes summertime ozone trends in East and Southeast Asia derived from a comprehensive observational database spanning from 1995 to 2019, incorporating aircraft observations, ozonesonde data, and measurements from 2500 surface sites. Multiple models are applied to attribute to changes in anthropogenic emissions and climate. The results highlight increases in anthropogenic emission are the primary driver of ozone increases both in the free troposphere and at the surface.
Hassnae Erraji, Philipp Franke, Astrid Lampert, Tobias Schuldt, Ralf Tillmann, Andreas Wahner, and Anne Caroline Lange
Atmos. Chem. Phys., 24, 13913–13934, https://doi.org/10.5194/acp-24-13913-2024, https://doi.org/10.5194/acp-24-13913-2024, 2024
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Four-dimensional variational data assimilation allows for the simultaneous optimisation of initial values and emission rates by using trace-gas profiles from drone observations in a regional air quality model. Assimilated profiles positively impact the representation of air pollutants in the model by improving their vertical distribution and ground-level concentrations. This case study highlights the potential of drone data to enhance air quality analyses including local emission evaluation.
Christopher Lawrence, Mary Barth, John Orlando, Paul Casson, Richard Brandt, Daniel Kelting, Elizabeth Yerger, and Sara Lance
Atmos. Chem. Phys., 24, 13693–13713, https://doi.org/10.5194/acp-24-13693-2024, https://doi.org/10.5194/acp-24-13693-2024, 2024
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This work uses chemical transport and box modeling to study the gas- and aqueous-phase production of organic acid concentrations measured in cloud water at the summit of Whiteface Mountain on 1 July 2018. Isoprene was the major source of formic, acetic, and oxalic acid. Gas-phase chemistry greatly underestimated formic and acetic acid, indicating missing sources, while cloud chemistry was a key source of oxalic acid. More studies of organic acids are required to better constrain their sources.
Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 24, 13503–13523, https://doi.org/10.5194/acp-24-13503-2024, https://doi.org/10.5194/acp-24-13503-2024, 2024
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Anthropogenic emissions are a major source of precursors of tropospheric ozone. As ozone formation is highly non-linear, we apply a global–regional chemistry–climate model with a source attribution method (tagging) to quantify the contribution of anthropogenic emissions to ozone. Our analysis shows that the contribution of European anthropogenic emissions largely increases during large ozone periods, indicating that emissions from these sectors drive ozone values.
Nana Wei, Eloise A. Marais, Gongda Lu, Robert G. Ryan, and Bastien Sauvage
EGUsphere, https://doi.org/10.5194/egusphere-2024-3388, https://doi.org/10.5194/egusphere-2024-3388, 2024
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This study uses reactive nitrogen observations from NASA DC-8 research aircraft and The In-service Aircraft for a Global Observing System (IAGOS) campaigns to characterise reactive nitrogen seasonality and composition in the global upper troposphere and to diagnose the greatest knowledge gaps from comparison to a state-of-science model GEOS-Chem that need to be resolved for climate, nitrogen cycle and air pollution assessments.
Barbara Ervens, Andrew Rickard, Bernard Aumont, William P. L. Carter, Max McGillen, Abdelwahid Mellouki, John Orlando, Bénédicte Picquet-Varrault, Paul Seakins, William R. Stockwell, Luc Vereecken, and Timothy J. Wallington
Atmos. Chem. Phys., 24, 13317–13339, https://doi.org/10.5194/acp-24-13317-2024, https://doi.org/10.5194/acp-24-13317-2024, 2024
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Chemical mechanisms describe the chemical processes in atmospheric models that are used to describe the changes in the atmospheric composition. Therefore, accurate chemical mechanisms are necessary to predict the evolution of air pollution and climate change. The article describes all steps that are needed to build chemical mechanisms and discusses the advances and needs of experimental and theoretical research activities needed to build reliable chemical mechanisms.
Audrey Fortems-Cheiney, Grégoire Broquet, Robin Plauchu, Elise Potier, Antoine Berchet, Isabelle Pison, Adrien Martinez, Rimal Abeed, Gaelle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, Henk Eskes, Hugo A. C. Denier van der Gon, and Stijn N. C. Dellaert
EGUsphere, https://doi.org/10.5194/egusphere-2024-3679, https://doi.org/10.5194/egusphere-2024-3679, 2024
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This study assesses the potential of the OMI and TROPOMI satellite observations to inform about the evolution of NOx anthropogenic emissions between year 2005 and year 2019 at the regional to national scales in Europe. Both the OMI and TROPOMI inversions show decreases in European NOx anthropogenic emission budgets between 2005 and 2019, but with different magnitudes.
Cited articles
Allen, D., Pickering, K., Duncan, B., and Damon, M.: Impact of lightning NO emissions on North American photochemistry as determined using the Global Modeling Initiative (GMI) model, J. Geophys. Res.-Atmos., 115, https://doi.org/10.1029/2010JD014062, 2010. a, b
Archibald, A. T., O'Connor, F. M., Abraham, N. L., Archer-Nicholls, S., Chipperfield, M. P., Dalvi, M., Folberth, G. A., Dennison, F., Dhomse, S. S., Griffiths, P. T., Hardacre, C., Hewitt, A. J., Hill, R. S., Johnson, C. E., Keeble, J., Köhler, M. O., Morgenstern, O., Mulcahy, J. P., Ordóñez, C., Pope, R. J., Rumbold, S. T., Russo, M. R., Savage, N. H., Sellar, A., Stringer, M., Turnock, S. T., Wild, O., and Zeng, G.: Description and evaluation of the UKCA stratosphere–troposphere chemistry scheme (StratTrop vn 1.0) implemented in UKESM1, Geosci. Model Dev., 13, 1223–1266, https://doi.org/10.5194/gmd-13-1223-2020, 2020. a, b, c
Bellouin, N., Bickel, M., Burkhardt, U., Cohen, Y., Dedoussi, I., Dollner, M., Fuglestvedt, J., Gettelman, A., Gierens, K., Grewe, V., Hahofer, J., Hauglustaine, D., Hendricks, J., Kanji, Z., Kärcher, B., Krämer, M., Lee, D., de Leon, R. R., Li, Y., Lohmann, U., Lund, M. T., Maruhashi, J., Matthes, S., Paoli, R., Penner, J., Petzold, A., Quaas, J., Quadros, F., Righi, M., Samset, B., Skowron, A., Terrenoire, E., Tesche, M., Unterstrasser, S., Voigt, C., and Weinzierl, B.: Assessment of the uncertainty in the effective radiative forcing of aviation: nitrogen oxide emissions, contrail cirrus formation, and aerosol-cloud interactions, in preparation, 2025.
Berntsen, T. K. and Isaksen, I. S. A.: A global three-dimensional chemical transport model for the troposphere: 1. Model description and CO and ozone results, J. Geophys. Res.-Atmos., 102, 21239–21280, https://doi.org/10.1029/97JD01140, 1997. a
Blot, R., Nedelec, P., Boulanger, D., Wolff, P., Sauvage, B., Cousin, J.-M., Athier, G., Zahn, A., Obersteiner, F., Scharffe, D., Petetin, H., Bennouna, Y., Clark, H., and Thouret, V.: Internal consistency of the IAGOS ozone and carbon monoxide measurements for the last 25 years, Atmos. Meas. Tech., 14, 3935–3951, https://doi.org/10.5194/amt-14-3935-2021, 2021. a
Bojinski, S., Verstraete, M., Peterson, T. C., Richter, C., Simmons, A., and Zemp, M.: The Concept of Essential Climate Variables in Support of Climate Research, Applications, and Policy, B. Am. Meteor. Soc., 95, 1431–1443, https://doi.org/10.1175/BAMS-D-13-00047.1, 2014. a
Boulanger, D., Blot, R., Bundke, U., Gerbig, C., Hermann, M., Nédélec, P., Rohs, S., and Ziereis, H.: IAGOS time series, AERIS [data set], https://doi.org/10.25326/06, 2018. a
Brasseur, G. P., Hauglustaine, D. A., Walters, S., Rasch, P. J., Müller, J.-F., Granier, C., and Tie, X.: MOZART, a global chemical transport model for ozone and related tracers, Part 1: model description, J. Geophys. Res.-Atmos., 103, 28265–28289 https://doi.org/10.1029/98JD02397, 1998. a
Brenninkmeijer, C. A. M., Crutzen, P. J., Fischer, H., Güsten, H., Hans, W., Heinrich, G., Heintzenberg, J., Hermann, M., Immelmann, T., Kersting, D., Maiss, M., Nolle, M., Pitscheider, A., Pohlkamp, H., Scharffe, D., Specht, K., and Wiedensohler, A.: CARIBIC–Civil Aircraft for Global Measurement of Trace Gases and Aerosols in the Tropopause Region, J. Atmos. Ocean Tech., 16, 1373–1383, https://doi.org/10.1175/1520-0426(1999)016<1373:CCAFGM>2.0.CO;2, 1999. a
Brenninkmeijer, C. A. M., Crutzen, P., Boumard, F., Dauer, T., Dix, B., Ebinghaus, R., Filippi, D., Fischer, H., Franke, H., Frieβ, U., Heintzenberg, J., Helleis, F., Hermann, M., Kock, H. H., Koeppel, C., Lelieveld, J., Leuenberger, M., Martinsson, B. G., Miemczyk, S., Moret, H. P., Nguyen, H. N., Nyfeler, P., Oram, D., O'Sullivan, D., Penkett, S., Platt, U., Pupek, M., Ramonet, M., Randa, B., Reichelt, M., Rhee, T. S., Rohwer, J., Rosenfeld, K., Scharffe, D., Schlager, H., Schumann, U., Slemr, F., Sprung, D., Stock, P., Thaler, R., Valentino, F., van Velthoven, P., Waibel, A., Wandel, A., Waschitschek, K., Wiedensohler, A., Xueref-Remy, I., Zahn, A., Zech, U., and Ziereis, H.: Civil Aircraft for the regular investigation of the atmosphere based on an instrumented container: The new CARIBIC system, Atmos. Chem. Phys., 7, 4953–4976, https://doi.org/10.5194/acp-7-4953-2007, 2007. a
Brunner, D., Staehelin, J., Rogers, H. L., Köhler, M. O., Pyle, J. A., Hauglustaine, D., Jourdain, L., Berntsen, T. K., Gauss, M., Isaksen, I. S. A., Meijer, E., van Velthoven, P., Pitari, G., Mancini, E., Grewe, G., and Sausen, R.: An evaluation of the performance of chemistry transport models by comparison with research aircraft observations. Part 1: Concepts and overall model performance, Atmos. Chem. Phys., 3, 1609–1631, https://doi.org/10.5194/acp-3-1609-2003, 2003. a
Cecil, D. J., Buechler, D. E., and Blakeslee, R. J.: Gridded lightning climatology from TRMM-LIS and OTD: Dataset description, Atmos. Res., 135-136, 404–414, https://doi.org/10.1016/j.atmosres.2012.06.028, 2014. a
Cohen, Y., Petetin, H., Thouret, V., Marécal, V., Josse, B., Clark, H., Sauvage, B., Fontaine, A., Athier, G., Blot, R., Boulanger, D., Cousin, J.-M., and Nédélec, P.: Climatology and long-term evolution of ozone and carbon monoxide in the upper troposphere–lower stratosphere (UTLS) at northern midlatitudes, as seen by IAGOS from 1995 to 2013, Atmos. Chem. Phys., 18, 5415–5453, https://doi.org/10.5194/acp-18-5415-2018, 2018. a, b, c, d
Cohen, Y., Thouret, V., Marécal, V., and Josse, B.: Interpol-IAGOS software, AERIS [code], https://doi.org/10.25326/81, 2020. a
Cohen, Y., Marécal, V., Josse, B., and Thouret, V.: Interpol-IAGOS: a new method for assessing long-term chemistry–climate simulations in the UTLS based on IAGOS data, and its application to the MOCAGE CCMI REF-C1SD simulation, Geosci. Model Dev., 14, 2659–2689, https://doi.org/10.5194/gmd-14-2659-2021, 2021. a, b, c, d
Cohen, Y., Hauglustaine, D., Sauvage, B., Rohs, S., Konjari, P., Bundke, U., Petzold, A., Thouret, V., Zahn, A., and Ziereis, H.: Evaluation of modelled climatologies of O3, CO, water vapour and NOy in the upper troposphere–lower stratosphere using regular in situ observations by passenger aircraft, Atmos. Chem. Phys., 23, 14973–15009, https://doi.org/10.5194/acp-23-14973-2023, 2023. a, b, c, d, e, f, g, h, i, j, k, l, m, n, o, p
Cohen, Y., Hauglustaine, D., Dedoussi, I., Lund, M., Matthes, S., Righi, M., Quadros, F., Skowron, A., Staniaszek, Z., and Thor, R.: Impact of aviation NOx and aerosol emissions on atmospheric composition and climate: results from a model intercomparison, in preparation, 2025.
Cooper, O. R., Eckhardt, S., Crawford, J. H., Brown, C. C., Cohen, R. C., Bertram, T. H., Wooldridge, P., Perring, A., Brune, W. H., Ren, X., Brunner, D., and Baughcum, S. L.: Summertime buildup and decay of lightning NOx and aged thunderstorm outflow above North America, J. Geophys. Res.-Atmos., 114, D01101, https://doi.org/10.1029/2008JD010293, 2009. a
Cristofanelli, P., Bracci, A., Sprenger, M., Marinoni, A., Bonafè, U., Calzolari, F., Duchi, R., Laj, P., Pichon, J. M., Roccato, F., Venzac, H., Vuillermoz, E., and Bonasoni, P.: Tropospheric ozone variations at the Nepal Climate Observatory-Pyramid (Himalayas, 5079 m a.s.l.) and influence of deep stratospheric intrusion events, Atmos. Chem. Phys., 10, 6537–6549, https://doi.org/10.5194/acp-10-6537-2010, 2010. a
David, L. M., Ravishankara, A., Brewer, J. F., Sauvage, B., Thouret, V., Venkataramani, S., and Sinha, V.: Tropospheric ozone over the Indian subcontinent from 2000 to 2015: Data set and simulation using GEOS-Chem chemical transport model, Atmos. Environ., 219, 117039, https://doi.org/10.1016/j.atmosenv.2019.117039, 2019. a
de F. Forster, P. M. and Shine, K. P.: Radiative forcing and temperature trends from stratospheric ozone changes, J. Geophys. Res.-Atmos., 102, 10841–10855, https://doi.org/10.1029/96JD03510, 1997. a
Deckert, R., Jöckel, P., Grewe, V., Gottschaldt, K.-D., and Hoor, P.: A quasi chemistry-transport model mode for EMAC, Geosci. Model Dev., 4, 195–206, https://doi.org/10.5194/gmd-4-195-2011, 2011. a
Diallo, M., Ern, M., and Ploeger, F.: The advective Brewer–Dobson circulation in the ERA5 reanalysis: climatology, variability, and trends, Atmos. Chem. Phys., 21, 7515–7544, https://doi.org/10.5194/acp-21-7515-2021, 2021. a
Dietmüller, S., Jöckel, P., Tost, H., Kunze, M., Gellhorn, C., Brinkop, S., Frömming, C., Ponater, M., Steil, B., Lauer, A., and Hendricks, J.: A new radiation infrastructure for the Modular Earth Submodel System (MESSy, based on version 2.51), Geosci. Model Dev., 9, 2209–2222, https://doi.org/10.5194/gmd-9-2209-2016, 2016. a
Dyroff, C., Zahn, A., Christner, E., Forbes, R., Tompkins, A. M., and van Velthoven, P. F. J.: Comparison of ECMWF analysis and forecast humidity data with CARIBIC upper troposphere and lower stratosphere observations, Q. J. Roy. Meteor. Soc., 141, 833–844, https://doi.org/10.1002/qj.2400, 2015. a
Eyring, V., Lamarque, J.-F., Hess, P., Arfeuille, F., Bowman, K., Chipperfield, M. P., Duncan, B., Fiore, A., Gettelman, A., Giorgetta, M. A., Granier, C., Hegglin, M., Kinnison, D., Kunze, M., Langematz, U., Luo, B., Martin, R., Matthes, K., Newman, P. A., Peter, T., Robock, A., Ryerson, T., Saiz-Lopez, A., Salawitch, A., Schultz, M., Shepherd, T. G., Shindell, D., Staehelin, J., Tegtmeier, S., Thomason, L., Tilmes, S., Vernier, J.-P., Waugh, D. W., and Young, P. J.: Overview of IGAC/SPARC Chemistry-Climate Model Initiative (CCMI) Community Simulations in Support of Upcoming Ozone and Climate Assessments, SPARC Newsletter, 48–66, 2013. a
Fadnavis, S., Semeniuk, K., Schultz, M. G., Kiefer, M., Mahajan, A., Pozzoli, L., and Sonbawane, S.: Transport pathways of peroxyacetyl nitrate in the upper troposphere and lower stratosphere from different monsoon systems during the summer monsoon season, Atmos. Chem. Phys., 15, 11477–11499, https://doi.org/10.5194/acp-15-11477-2015, 2015. a
Finney, D. L., Doherty, R. M., Wild, O., Young, P. J., and Butler, A.: Response of lightning NOx emissions and ozone production to climate change: Insights from the Atmospheric Chemistry and Climate Model Intercomparison Project, Geophys. Res. Lett., 43, 5492–5500, https://doi.org/10.1002/2016GL068825, 2016. a
Folberth, G. A., Hauglustaine, D. A., Lathière, J., and Brocheton, F.: Interactive chemistry in the Laboratoire de Météorologie Dynamique general circulation model: model description and impact analysis of biogenic hydrocarbons on tropospheric chemistry, Atmos. Chem. Phys., 6, 2273–2319, https://doi.org/10.5194/acp-6-2273-2006, 2006. a
Gaudel, A., Clark, H., Thouret, V., Jones, L., Inness, A., Flemming, J., Stein, O., Huijnen, V., Eskes, H., Nédélec, P., and Boulanger, D.: On the use of MOZAIC-IAGOS data to assess the ability of the MACC reanalysis to reproduce the distribution of ozone and CO in the UTLS over Europe, Tellus B, 67, 27955, https://doi.org/10.3402/tellusb.v67.27955, 2015. a
Gettelman, A., Hegglin, M. I., Son, S.-W., Kim, J., Fujiwara, M., Birner, T., Kremser, S., Rex, M., Añel, J. A., Akiyoshi, H., Austin, J., Bekki, S., Braesike, P., Brühl, C., Butchart, N., Chipperfield, M., Dameris, M., Dhomse, S., Garny, H., Hardiman, S. C., Jöckel, P., Kinnison, D. E., Lamarque, J. F., Mancini, E., Marchand, M., Michou, M., Morgenstern, O., Pawson, S., Pitari, G., Plummer, D., Pyle, J. A., Rozanov, E., Scinocca, J., Shepherd, T. G., Shibata, K., Smale, D., Teyssèdre, H., and Tian, W.: Multimodel assessment of the upper troposphere and lower stratosphere: Tropics and global trends, J. Geophys. Res.-Atmos., 115, D00M08, https://doi.org/10.1029/2009JD013638, 2010. a
Gettelman, A., Hoor, P., Pan, L. L., Randel, W. J., Hegglin, M. I., and Birner, T.: The extratropical upper troposphere and lower stratosphere, Rev. Geophys., 49, RG3003, https://doi.org/10.1029/2011RG000355, 2011. a
Giannakopoulos, C., Chipperfield, T., Law, K., and Pyle, J.: Validation and intercomparison of wet and dry deposition schemes using Pb-210 in a global three-dimensional off-line chemical transport model, J. Geophys. Res., 104, 23761–23784, 1999. a
Gidden, M. J., Riahi, K., Smith, S. J., Fujimori, S., Luderer, G., Kriegler, E., van Vuuren, D. P., van den Berg, M., Feng, L., Klein, D., Calvin, K., Doelman, J. C., Frank, S., Fricko, O., Harmsen, M., Hasegawa, T., Havlik, P., Hilaire, J., Hoesly, R., Horing, J., Popp, A., Stehfest, E., and Takahashi, K.: Global emissions pathways under different socioeconomic scenarios for use in CMIP6: a dataset of harmonized emissions trajectories through the end of the century, Geosci. Model Dev., 12, 1443–1475, https://doi.org/10.5194/gmd-12-1443-2019, 2019. a
Gottschaldt, K.-D., Schlager, H., Baumann, R., Cai, D. S., Eyring, V., Graf, P., Grewe, V., Jöckel, P., Jurkat-Witschas, T., Voigt, C., Zahn, A., and Ziereis, H.: Dynamics and composition of the Asian summer monsoon anticyclone, Atmos. Chem. Phys., 18, 5655–5675, https://doi.org/10.5194/acp-18-5655-2018, 2018. a, b
Granier, C., Lamarque, J.-F., Mieville, A., Muller, J.-F., Olivier, J., Orlando, J., Peters, J., Petron, G., Tyndall, G., and Wallens, S.: POET, a database of surface emissions of ozone precursors, http://www.aero.jussieu.fr/projet/ACCENT/POET.php (last access: 12 May 2022), 2005. a
Grewe, V., Brunner, D., Dameris, M., Grenfell, J., Hein, R., Shindell, D., and Staehelin, J.: Origin and variability of upper tropospheric nitrogen oxides and ozone at northern mid-latitudes, Atmos. Environ., 35, 3421–3433, https://doi.org/10.1016/S1352-2310(01)00134-0, 2001. a
Grooß, J.-U. and Russell III, J. M.: Technical note: A stratospheric climatology for O3, H2O, CH4, NOx, HCl and HF derived from HALOE measurements, Atmos. Chem. Phys., 5, 2797–2807, https://doi.org/10.5194/acp-5-2797-2005, 2005. a
Grooß, J.-U., Brühl, C., and Peter, T.: Impact of aircraft emissions on tropospheric and stratospheric ozone. Part I: chemistry and 2-D model results, Atmos. Environ., 32, 3173–3184, https://doi.org/10.1016/S1352-2310(98)00016-8, 1998. a
Guth, J., Josse, B., Marécal, V., Joly, M., and Hamer, P.: First implementation of secondary inorganic aerosols in the MOCAGE version R2.15.0 chemistry transport model, Geosci. Model Dev., 9, 137–160, https://doi.org/10.5194/gmd-9-137-2016, 2016. a
Hack, J. J.: Parameterization of moist convection in the NCAR community climate model (CCM2), J. Geophys. Res.-Atmos., 99, 5833–5866, https://doi.org/10.1029/93JD03478, 1994. a
Hakim, Z. Q., Archer-Nicholls, S., Beig, G., Folberth, G. A., Sudo, K., Abraham, N. L., Ghude, S., Henze, D. K., and Archibald, A. T.: Evaluation of tropospheric ozone and ozone precursors in simulations from the HTAPII and CCMI model intercomparisons – a focus on the Indian subcontinent, Atmos. Chem. Phys., 19, 6437–6458, https://doi.org/10.5194/acp-19-6437-2019, 2019. a
Hauglustaine, D. A., Hourdin, F., Jourdain, L., Filiberti, M.-A., Walters, S., Lamarque, J.-F., and Holland, E. A.: Interactive chemistry in the Laboratoire de Météorologie Dynamique general circulation model: Description and background tropospheric chemistry evaluation, J. Geophys. Res.-Atmos., 109, https://doi.org/10.1029/2003JD003957, 2004. a, b, c
Hauglustaine, D. A., Balkanski, Y., and Schulz, M.: A global model simulation of present and future nitrate aerosols and their direct radiative forcing of climate, Atmos. Chem. Phys., 14, 11031–11063, https://doi.org/10.5194/acp-14-11031-2014, 2014. a
Hegglin, M. I., Gettelman, A., Hoor, P., Krichevsky, R., Manney, G. L., Pan, L. L., Son, S.-W., Stiller, G., Tilmes, S., Walker, K. A., Eyring, V., Shepherd, T. G., Waugh, D., Akiyoshi, H., Añel, J. A., Austin, J., Baumgaertner, A., Bekki, S., Braesicke, P., Brühl, C., Butchart, N., Chipperfield, M., Dameris, M., Dhomse, S., Frith, S., Garny, H., Hardiman, S. C., Jöckel, P., Kinnison, D. E., Lamarque, J.-F., Mancini, E., Michou, M., Morgenstern, O., Nakamura, T., Olivié, D., Pawson, S., Pitari, G., Plummer, D. A., Pyle, J. A., Rozanov, E., Scinocca, J. F., Shibata, K., Smale, D., Teyssèdre, H., Tian, W., and Yamashita, Y.: Multimodel assessment of the upper troposphere and lower stratosphere: Extratropics, J. Geophys. Res.-Atmos., 115, https://doi.org/10.1029/2010JD013884, 2010. a, b
Helten, M., Smit, H. G. J., Sträter, W., Kley, D., Nédélec, P., Zöger, M., and Busen, R.: Calibration and performance of automatic compact instrumentation for the measurement of relative humidity from passenger aircraft, J. Geophys. Res.-Atmos., 103, 25643–25652, https://doi.org/10.1029/98JD00536, 1998. a
Hesstvedt, E., Hov, O., and Isaksen, I. S. A.: Quasi-steady-state approximations in air pollution modeling: Comparison of two numerical schemes for oxidant prediction, Int. J. Chem. Kinet., 10, 971–994, https://doi.org/10.1002/kin.550100907, 1978. a
Hodnebrog, Ø., Berntsen, T. K., Dessens, O., Gauss, M., Grewe, V., Isaksen, I. S. A., Koffi, B., Myhre, G., Olivié, D., Prather, M. J., Pyle, J. A., Stordal, F., Szopa, S., Tang, Q., van Velthoven, P., Williams, J. E., and Ødemark, K.: Future impact of non-land based traffic emissions on atmospheric ozone and OH – an optimistic scenario and a possible mitigation strategy, Atmos. Chem. Phys., 11, 11293–11317, https://doi.org/10.5194/acp-11-11293-2011, 2011. a
Hodnebrog, Ø., Berntsen, T. K., Dessens, O., Gauss, M., Grewe, V., Isaksen, I. S. A., Koffi, B., Myhre, G., Olivié, D., Prather, M. J., Stordal, F., Szopa, S., Tang, Q., van Velthoven, P., and Williams, J. E.: Future impact of traffic emissions on atmospheric ozone and OH based on two scenarios, Atmos. Chem. Phys., 12, 12211–12225, https://doi.org/10.5194/acp-12-12211-2012, 2012. a
Hoesly, R. M., Smith, S. J., Feng, L., Klimont, Z., Janssens-Maenhout, G., Pitkanen, T., Seibert, J. J., Vu, L., Andres, R. J., Bolt, R. M., Bond, T. C., Dawidowski, L., Kholod, N., Kurokawa, J.-I., Li, M., Liu, L., Lu, Z., Moura, M. C. P., O'Rourke, P. R., and Zhang, Q.: Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS), Geosci. Model Dev., 11, 369–408, https://doi.org/10.5194/gmd-11-369-2018, 2018. a
Holtslag, A. and Boville, B. A.: Local versus nonlocal boundary-layer diffusion in a global climate model, J. Climate, 6, 1825–1842, https://doi.org/10.1175/1520-0442(1993)006<1825:LVNBLD>2.0.CO;2, 1993. a
Holtslag, A. A. M., De Bruijn, E. I. F., and Pan, H.-L.: A high resolution air mass transformation model for short-range weather forecasting, Mon. Weather Rev., 118, 1561–1575, https://doi.org/10.1175/1520-0493(1990)118<1561:AHRAMT>2.0.CO;2, 1990. a
Hoor, P., Borken-Kleefeld, J., Caro, D., Dessens, O., Endresen, O., Gauss, M., Grewe, V., Hauglustaine, D., Isaksen, I. S. A., Jöckel, P., Lelieveld, J., Myhre, G., Meijer, E., Olivie, D., Prather, M., Schnadt Poberaj, C., Shine, K. P., Staehelin, J., Tang, Q., van Aardenne, J., van Velthoven, P., and Sausen, R.: The impact of traffic emissions on atmospheric ozone and OH: results from QUANTIFY, Atmos. Chem. Phys., 9, 3113–3136, https://doi.org/10.5194/acp-9-3113-2009, 2009. a, b
Hourdin, F., Musat, I., Bony, S., Braconnot, P., Codron, F., Dufresne, J.-L., Fairhead, L., Filiberti, M.-A., Friedlingstein, P., Grandpeix, J.-Y., Krinner, G., LeVan, P., Li, Z.-X., and Lott, F.: The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection, Clim. Dynam., 27, 787–813, https://doi.org/10.1007/s00382-006-0158-0, 2006. a, b
IAGOS: IAGOS-Core and IAGOS-CARIBIC data, https://doi.org/10.25326/20, 2022. a
Iglesias-Suarez, F., Kinnison, D. E., Rap, A., Maycock, A. C., Wild, O., and Young, P. J.: Key drivers of ozone change and its radiative forcing over the 21st century, Atmos. Chem. Phys., 18, 6121–6139, https://doi.org/10.5194/acp-18-6121-2018, 2018. a
Jöckel, P., Kerkweg, A., Pozzer, A., Sander, R., Tost, H., Riede, H., Baumgaertner, A., Gromov, S., and Kern, B.: Development cycle 2 of the Modular Earth Submodel System (MESSy2), Geosci. Model Dev., 3, 717–752, https://doi.org/10.5194/gmd-3-717-2010, 2010. a
Jöckel, P., Tost, H., Pozzer, A., Kunze, M., Kirner, O., Brenninkmeijer, C. A. M., Brinkop, S., Cai, D. S., Dyroff, C., Eckstein, J., Frank, F., Garny, H., Gottschaldt, K.-D., Graf, P., Grewe, V., Kerkweg, A., Kern, B., Matthes, S., Mertens, M., Meul, S., Neumaier, M., Nützel, M., Oberländer-Hayn, S., Ruhnke, R., Runde, T., Sander, R., Scharffe, D., and Zahn, A.: Earth System Chemistry integrated Modelling (ESCiMo) with the Modular Earth Submodel System (MESSy) version 2.51, Geosci. Model Dev., 9, 1153–1200, https://doi.org/10.5194/gmd-9-1153-2016, 2016. a
Joppe, P., Schneider, J., Kaiser, K., Fischer, H., Hoor, P., Kunkel, D., Lachnitt, H.-C., Marsing, A., Röder, L., Schlager, H., Tomsche, L., Voigt, C., Zahn, A., and Borrmann, S.: The influence of extratropical cross-tropopause mixing on the correlation between ozone and sulfate aerosol in the lowermost stratosphere, Atmos. Chem. Phys., 24, 7499–7522, https://doi.org/10.5194/acp-24-7499-2024, 2024. a
Josse, B., Simon, P., and Peuch, V.-H.: Radon global simulations with the multiscale chemistry and transport model MOCAGE, Tellus B, 56, 339–356, https://doi.org/10.3402/tellusb.v56i4.16448, 2004. a
Jourdain, L. and Hauglustaine, D. A.: The global distribution of lightning NOx simulated on-line in a general circulation model, Phys. Chem. Earth Pt. C, 26, 585–591, https://doi.org/10.1016/S1464-1917(01)00051-4, 2001. a
Kinnison, D. E., Brausser, G. P., Walters, S., Garcia, R. R., Marsh, D. R., Sassi, F., Harvey, V. L., Randall, C. E., Emmons, L., Lamarque, J. F., Hess, P., Orlando, J. J., Tie, X. X., Randel, W., Pan, L. L., Gettelman, A., Granier, C., Diehl, T., Niemeier, U., and Simmons, A. J.: Sensitivity of chemical tracers to meteorological parameters in the MOZART-3 chemical transport model, J. Geophys. Res.-Atmos., 112, D20302, https://doi.org/10.1029/2006JD007879, 2007. a
Krinner, G., Viovy, N., de Noblet-Ducoudré, N., Ogée, J., Polcher, J., Friedlingstein, P., Ciais, P., Sitch, S., and Prentice, I. C.: A dynamic global vegetation model for studies of the coupled atmosphere-biosphere system, Global Biogeochem. Cy., 19, https://doi.org/10.1029/2003GB002199, 2005. a
Lacis, A. A., Wuebbles, D. J., and Logan, J. A.: Radiative forcing of climate by changes in the vertical distribution of ozone, J. Geophys. Res.-Atmos., 95, 9971–9981, https://doi.org/10.1029/JD095iD07p09971, 1990. a
Lamarque, J.-F., Shindell, D. T., Josse, B., Young, P. J., Cionni, I., Eyring, V., Bergmann, D., Cameron-Smith, P., Collins, W. J., Doherty, R., Dalsoren, S., Faluvegi, G., Folberth, G., Ghan, S. J., Horowitz, L. W., Lee, Y. H., MacKenzie, I. A., Nagashima, T., Naik, V., Plummer, D., Righi, M., Rumbold, S. T., Schulz, M., Skeie, R. B., Stevenson, D. S., Strode, S., Sudo, K., Szopa, S., Voulgarakis, A., and Zeng, G.: The Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): overview and description of models, simulations and climate diagnostics, Geosci. Model Dev., 6, 179–206, https://doi.org/10.5194/gmd-6-179-2013, 2013. a
Lannuque, V., Sauvage, B., Barret, B., Clark, H., Athier, G., Boulanger, D., Cammas, J.-P., Cousin, J.-M., Fontaine, A., Le Flochmoën, E., Nédélec, P., Petetin, H., Pfaffenzeller, I., Rohs, S., Smit, H. G. J., Wolff, P., and Thouret, V.: Origins and characterization of CO and O3 in the African upper troposphere, Atmos. Chem. Phys., 21, 14535–14555, https://doi.org/10.5194/acp-21-14535-2021, 2021. a, b, c, d, e
Law, K. S., Plantevin, P.-H., Thouret, V., Marenco, A., Asman, W. A. H., Lawrence, M., Crutzen, P. J., Muller, J.-F., Hauglustaine, D. A., and Kanakidou, M.: Comparison between global chemistry transport model results and Measurement of Ozone and Water Vapor by Airbus In-Service Aircraft (MOZAIC) data, J. Geophys. Res.-Atmos., 105, 1503–1525, https://doi.org/10.1029/1999JD900474, 2000. a
Lee, D., Fahey, D., Skowron, A., Allen, M., Burkhardt, U., Chen, Q., Doherty, S., Freeman, S., Forster, P., Fuglestvedt, J., Gettelman, A., De León, R., Lim, L., Lund, M., Millar, R., Owen, B., Penner, J., Pitari, G., Prather, M., Sausen, R., and Wilcox, L.: The contribution of global aviation to anthropogenic climate forcing for 2000 to 2018, Atmos. Environ., 244, 117834, https://doi.org/10.1016/j.atmosenv.2020.117834, 2021. a
Li, Y., Dhomse, S. S., Chipperfield, M. P., Feng, W., Chrysanthou, A., Xia, Y., and Guo, D.: Effects of reanalysis forcing fields on ozone trends and age of air from a chemical transport model, Atmos. Chem. Phys., 22, 10635–10656, https://doi.org/10.5194/acp-22-10635-2022, 2022. a
Lin, S. J. and Rood, R. B.: A fast flux form semi-Lagrangian transport scheme on the sphere, Mon. Weather Rev., 124, 2046–2070, https://doi.org/10.1175/1520-0493(1996)124<2046:MFFSLT>2.0.CO;2, 1996. a
Liu, Y., Liu, C. X., Wang, H. P., Tie, X. X., Gao, S. T., Kinnison, D., and Brasseur, G.: Atmospheric tracers during the 2003–2004 stratospheric warming event and impact of ozone intrusions in the troposphere, Atmos. Chem. Phys., 9, 2157–2170, https://doi.org/10.5194/acp-9-2157-2009, 2009. a
Livesey, N. J., Logan, J. A., Santee, M. L., Waters, J. W., Doherty, R. M., Read, W. G., Froidevaux, L., and Jiang, J. H.: Interrelated variations of O3, CO and deep convection in the tropical/subtropical upper troposphere observed by the Aura Microwave Limb Sounder (MLS) during 2004–2011, Atmos. Chem. Phys., 13, 579–598, https://doi.org/10.5194/acp-13-579-2013, 2013. a
Lund, M. T., Myhre, G., Haslerud, A. S., Skeie, R. B., Griesfeller, J., Platt, S. M., Kumar, R., Myhre, C. L., and Schulz, M.: Concentrations and radiative forcing of anthropogenic aerosols from 1750 to 2014 simulated with the Oslo CTM3 and CEDS emission inventory, Geosci. Model Dev., 11, 4909–4931, https://doi.org/10.5194/gmd-11-4909-2018, 2018. a, b
Marenco, A., Thouret, V., Nédélec, P., Smit, H., Helten, M., Kley, D., Karsher, F., Simon, P., Law, K., Pyle, J., Poschmann, G., Von Wrede, R., Hume, C., and Cook, T.: Measurement of ozone and water vapour by Airbus in-service aircraft : The MOZAIC airborne programme, an overview, J. Geophys. Res., 103, 25631–25642, https://doi.org/10.1029/98JD00977, 1998. a
Messina, P., Lathière, J., Sindelarova, K., Vuichard, N., Granier, C., Ghattas, J., Cozic, A., and Hauglustaine, D. A.: Global biogenic volatile organic compound emissions in the ORCHIDEE and MEGAN models and sensitivity to key parameters, Atmos. Chem. Phys., 16, 14169–14202, https://doi.org/10.5194/acp-16-14169-2016, 2016. a
Millán, L. F., Hoor, P., Hegglin, M. I., Manney, G. L., Boenisch, H., Jeffery, P., Kunkel, D., Petropavlovskikh, I., Ye, H., Leblanc, T., and Walker, K.: Exploring ozone variability in the upper troposphere and lower stratosphere using dynamical coordinates, Atmos. Chem. Phys., 24, 7927–7959, https://doi.org/10.5194/acp-24-7927-2024, 2024. a
Morgenstern, O., Braesicke, P., O'Connor, F. M., Bushell, A. C., Johnson, C. E., Osprey, S. M., and Pyle, J. A.: Evaluation of the new UKCA climate-composition model – Part 1: The stratosphere, Geosci. Model Dev., 2, 43–57, https://doi.org/10.5194/gmd-2-43-2009, 2009. a
Mulcahy, J. P., Jones, C., Sellar, A., Johnson, B., Boutle, I. A., Jones, A., Andrews, T., Rumbold, S. T., Mollard, J., Bellouin, N., Johnson, C. E., Williams, K. D., Grosvenor, D. P., and McCoy, D. T.: Improved aerosol processes and effective radiative forcing in HadGEM3 and UKESM1, J. Adv. Model. Earth Sy., 10, 2786–2805, https://doi.org/10.1029/2018MS001464, 2018. a
Murray, L. T., Jacob, D. J., Logan, J. A., Hudman, R. C., and Koshak, W. J.: Optimized regional and interannual variability of lightning in a global chemical transport model constrained by LIS/OTD satellite data, J. Geophys. Res.-Atmos., 117, https://doi.org/10.1029/2012JD017934, 2012. a
Müller, J.-F.: Geographical distribution and seasonal variation of surface emissions and deposition velocities of atmospheric trace gases, J. Geophys. Res.-Atmos., 97, 3787–3804, https://doi.org/10.1029/91JD02757, 1992. a
Nedelec, P., Cammas, J.-P., Thouret, V., Athier, G., Cousin, J.-M., Legrand, C., Abonnel, C., Lecoeur, F., Cayez, G., and Marizy, C.: An improved infrared carbon monoxide analyser for routine measurements aboard commercial Airbus aircraft: technical validation and first scientific results of the MOZAIC III programme, Atmos. Chem. Phys., 3, 1551–1564, https://doi.org/10.5194/acp-3-1551-2003, 2003. a
Nédélec, P., Blot, R., Boulanger, D., Athier, G., Cousin, J.-M., Gautron, B., Petzold, A., Volz-Thomas, A., and Thouret, V.: Instrumentation on commercial aircraft for monitoring the atmospheric composition on a global scale: the IAGOS system, technical overview of ozone and carbon monoxide measurements, Tellus B, 67, 27791, https://doi.org/10.3402/tellusb.v67.27791, 2015. a
Neis, P., Smit, H. G. J., Krämer, M., Spelten, N., and Petzold, A.: Evaluation of the MOZAIC Capacitive Hygrometer during the airborne field study CIRRUS-III, Atmos. Meas. Tech., 8, 1233–1243, https://doi.org/10.5194/amt-8-1233-2015, 2015a. a
Neis, P., Smit, H. G. J., Rohs, S., Bundke, U., Krämer, M., Spelten, N., Ebert, V., Buchholz, B., Thomas, K., and Petzold, A.: Quality assessment of MOZAIC and IAGOS capacitive hygrometers: insights from airborne field studies, Tellus B, 67, 28320, https://doi.org/10.3402/tellusb.v67.28320, 2015b. a
Neu, J. L., Prather, M. J., and Penner, J. E.: Global atmospheric chemistry: Integrating over fractional cloud cover, J. Geophys. Res.-Atmos., 112, https://doi.org/10.1029/2006JD008007, 2007. a
Nussbaumer, C. M., Fischer, H., Lelieveld, J., and Pozzer, A.: What controls ozone sensitivity in the upper tropical troposphere?, Atmos. Chem. Phys., 23, 12651–12669, https://doi.org/10.5194/acp-23-12651-2023, 2023. a
O'Connor, F. M., Johnson, C. E., Morgenstern, O., Abraham, N. L., Braesicke, P., Dalvi, M., Folberth, G. A., Sanderson, M. G., Telford, P. J., Voulgarakis, A., Young, P. J., Zeng, G., Collins, W. J., and Pyle, J. A.: Evaluation of the new UKCA climate-composition model – Part 2: The Troposphere, Geosci. Model Dev., 7, 41–91, https://doi.org/10.5194/gmd-7-41-2014, 2014. a
Orbe, C., Plummer, D. A., Waugh, D. W., Yang, H., Jöckel, P., Kinnison, D. E., Josse, B., Marecal, V., Deushi, M., Abraham, N. L., Archibald, A. T., Chipperfield, M. P., Dhomse, S., Feng, W., and Bekki, S.: Description and Evaluation of the specified-dynamics experiment in the Chemistry-Climate Model Initiative, Atmos. Chem. Phys., 20, 3809–3840, https://doi.org/10.5194/acp-20-3809-2020, 2020. a
Ott, L. E., Pickering, K. E., Stenchikov, G. L., Allen, D. J., DeCaria, A. J., Ridley, B., Lin, R.-F., Lang, S., and Tao, W.-K.: Production of lightning NOx and its vertical distribution calculated from three-dimensional cloud-scale chemical transport model simulations, J. Geophys. Res.-Atmos., 115, https://doi.org/10.1029/2009JD011880, 2010. a, b, c
Pätz, H.-W., Volz-Thomas, A., Hegglin, M. I., Brunner, D., Fischer, H., and Schmidt, U.: In-situ comparison of the NOy instruments flown in MOZAIC and SPURT, Atmos. Chem. Phys., 6, 2401–2410, https://doi.org/10.5194/acp-6-2401-2006, 2006. a
Petzold, A., Thouret, V., Gerbig, C., Zahn, A., Brenninkmeijer, C., Gallagher, M., Hermann, M., Pontaud, M., Ziereis, H., Boulanger, D., Marshall, J., Nédélec, P., Smit, H., Friess, U., Flaud, J.-M., Wahner, A., Cammas, J.-P., and Volz-Thomas, A.: Global-scale atmosphere monitoring by in-service aircraft – current achievements and future prospects of the European Research Infrastructure IAGOS, Tellus B, 67, 28452, https://doi.org/10.3402/tellusb.v67.28452, 2015. a
Petzold, A., Neis, P., Rütimann, M., Rohs, S., Berkes, F., Smit, H. G. J., Krämer, M., Spelten, N., Spichtinger, P., Nédélec, P., and Wahner, A.: Ice-supersaturated air masses in the northern mid-latitudes from regular in situ observations by passenger aircraft: vertical distribution, seasonality and tropospheric fingerprint, Atmos. Chem. Phys., 20, 8157–8179, https://doi.org/10.5194/acp-20-8157-2020, 2020. a, b
Pickering, K. E., Wang, Y. S., Tao, W. K., Price, C., and Müller, J.: Vertical distributions of lightning NOx for use in regional and global chemical transport models, J. Geophys. Res.-Atmos, 103, 31203–31216, https://doi.org/10.1029/98JD02651, 1998. a, b
Pletzer, J., Hauglustaine, D., Cohen, Y., Jöckel, P., and Grewe, V.: The climate impact of hydrogen-powered hypersonic transport, Atmos. Chem. Phys., 22, 14323–14354, https://doi.org/10.5194/acp-22-14323-2022, 2022. a
Ploeger, F., Diallo, M., Charlesworth, E., Konopka, P., Legras, B., Laube, J. C., Grooß, J.-U., Günther, G., Engel, A., and Riese, M.: The stratospheric Brewer–Dobson circulation inferred from age of air in the ERA5 reanalysis, Atmos. Chem. Phys., 21, 8393–8412, https://doi.org/10.5194/acp-21-8393-2021, 2021. a
Prather, M. J.: Numerical advection by conservation of second-order moments, J. Geophys. Res.-Atmos., 91, 6671–6681, https://doi.org/10.1029/JD091iD06p06671, 1986. a
Prather, M. J.: Fast-JX version 6.5, http://www.ess.uci.edu/~prather/fastJX.html (last access: 1 September 2009), 2009. a
Price, C. and Rind, D.: A simple lightning parameterization for calculating global lightning distributions, J. Geophys. Res.-Atmos., 97, 9919–9933, https://doi.org/10.1029/92JD00719, 1992. a, b, c
Price, C., Penner, J., and Prather, M.: NOx from lightning: 1. Global distribution based on lightning physics, J. Geophys. Res.-Atmos., 102, 5929–5941, https://doi.org/10.1029/96JD03504, 1997. a, b
Riese, M., Ploeger, F., Rap, A., Vogel, B., Konopka, P., Dameris, M., and Forster, P.: Impact of uncertainties in atmospheric mixing on simulated UTLS composition and related radiative effects, J. Geophys. Res., 117, D16305, https://doi.org/10.1029/2012JD017751, 2012. a
Righi, M., Eyring, V., Gottschaldt, K.-D., Klinger, C., Frank, F., Jöckel, P., and Cionni, I.: Quantitative evaluation of ozone and selected climate parameters in a set of EMAC simulations, Geosci. Model Dev., 8, 733–768, https://doi.org/10.5194/gmd-8-733-2015, 2015. a
Roeckner, E., Brokopf, R., Esch, M., Giorgetta, M., Hagemann, S., Kornblueh, L., Manzini, E., Schlese, U., and Schulzweida, U.: Sensitivity of Simulated Climate to Horizontal and Vertical Resolution in the ECHAM5 Atmosphere Model, J. Climate, 19, 3771–3791, https://doi.org/10.1175/JCLI3824.1, 2006. a
Rolf, C., Rohs, S., Smit, H., G. J., Krämer, M., Bozóki, Z., Hofmann, S., Franke, H., Maser, R., Hoor, P., and Petzold, A.: Evaluation of compact hygrometers for continuous airborne measurements, Meteorol. Z., 33, 15–34, https://doi.org/10.1127/metz/2023/1187, 2023. a
Russo, M. R., Kerridge, B. J., Abraham, N. L., Keeble, J., Latter, B. G., Siddans, R., Weber, J., Griffiths, P. T., Pyle, J. A., and Archibald, A. T.: Seasonal, interannual and decadal variability of tropospheric ozone in the North Atlantic: comparison of UM-UKCA and remote sensing observations for 2005–2018, Atmos. Chem. Phys., 23, 6169–6196, https://doi.org/10.5194/acp-23-6169-2023, 2023. a
Sander, R., Baumgaertner, A., Cabrera-Perez, D., Frank, F., Gromov, S., Grooß, J.-U., Harder, H., Huijnen, V., Jöckel, P., Karydis, V. A., Niemeyer, K. E., Pozzer, A., Riede, H., Schultz, M. G., Taraborrelli, D., and Tauer, S.: The community atmospheric chemistry box model CAABA/MECCA-4.0, Geosci. Model Dev., 12, 1365–1385, https://doi.org/10.5194/gmd-12-1365-2019, 2019. a
Sander, S. P., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., Orkin, V. L., Friedl, R. R., and Keller-Rudek, H.: Chemical kinetics and photochemical data for use in atmospheric studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, https://jpldataeval.jpl.nasa.gov (last access: 2 June 2025), 2006. a, b
Sauvage, B., Thouret, V., Cammas, J.-P., Brioude, J., Nédélec, P., and Mari, C.: Meridional ozone gradients in the African upper troposphere, Geophys. Res. Lett., 34, L03817, https://doi.org/10.1029/2006GL028542, 2007. a
Sauvage, B., Fontaine, A., Eckhardt, S., Auby, A., Boulanger, D., Petetin, H., Paugam, R., Athier, G., Cousin, J.-M., Darras, S., Nédélec, P., Stohl, A., Turquety, S., Cammas, J.-P., and Thouret, V.: Source attribution using FLEXPART and carbon monoxide emission inventories: SOFT-IO version 1.0, Atmos. Chem. Phys., 17, 15271–15292, https://doi.org/10.5194/acp-17-15271-2017, 2017. a
Scharffe, D., Slemr, F., Brenninkmeijer, C. A. M., and Zahn, A.: Carbon monoxide measurements onboard the CARIBIC passenger aircraft using UV resonance fluorescence, Atmos. Meas. Tech., 5, 1753–1760, https://doi.org/10.5194/amt-5-1753-2012, 2012. a
Sellar, A. A., Jones, C. G., Mulcahy, J. P., Tang, Y., Yool, A., Wiltshire, A., O'Connor, F. M., Stringer, M., Hill, R., Palmieri, J., Woodward, S., de Mora, L., Kuhlbrodt, T., Rumbold, S. T., Kelley, D. I., Ellis, R., Johnson, C. E., Walton, J., Abraham, N. L., Andrews, M. B., Andrews, T., Archibald, A. T., Berthou, S., Burke, E., Blockley, E., Carslaw, K., Dalvi, M., Edwards, J., Folberth, G. A., Gedney, N., Griffiths, P. T., Harper, A. B., Hendry, M. A., Hewitt, A. J., Johnson, B., Jones, A., Jones, C. D., Keeble, J., Liddicoat, S., Morgenstern, O., Parker, R. J., Predoi, V., Robertson, E., Siahaan, A., Smith, R. S., Swaminathan, R., Woodhouse, M. T., Zeng, G., and Zerroukat, M.: UKESM1: Description and Evaluation of the U.K. Earth System Model, J. Adv. Model. Earth Sy., 11, 4513–4558, https://doi.org/10.1029/2019MS001739, 2019. a
Skowron, A., Lee, D. S., and De León, R. R.: Variation of radiative forcings and global warming potentials from regional aviation NOx/emissions, Atmos. Environ., 104, 69–78, https://doi.org/10.1016/j.atmosenv.2014.12.043, 2015. a
Skowron, A., Lee, D. S., De León, R. R., Lim, L. L., and Owen, B.: Greater fuel efficiency is potentially preferable to reducing NOx/emissions for aviation’s climate impacts, Nat. Commun., 12, 564, https://doi.org/10.1038/s41467-020-20771-3, 2021. a
Smit, H. G. J., Rohs, S., Neis, P., Boulanger, D., Krämer, M., Wahner, A., and Petzold, A.: Technical Note: Reanalysis of upper troposphere humidity data from the MOZAIC programme for the period 1994 to 2009, Atmos. Chem. Phys., 14, 13241–13255, https://doi.org/10.5194/acp-14-13241-2014, 2014. a
Søvde, O. A., Prather, M. J., Isaksen, I. S. A., Berntsen, T. K., Stordal, F., Zhu, X., Holmes, C. D., and Hsu, J.: The chemical transport model Oslo CTM3, Geosci. Model Dev., 5, 1441–1469, https://doi.org/10.5194/gmd-5-1441-2012, 2012. a, b, c
Søvde, O. A., Matthes, S., Skowron, A., Iachetti, D., Lim, L., Owen, B., Hodnebrog, Ø., Di Genova, G., Pitari, G., Lee, D. S., Myhre, G., and Isaksen, I. S.: Aircraft emission mitigation by changing route altitude: A multi-model estimate of aircraft NOx emission impact on O3 photochemistry, Atmos. Environ., 95, 468–479, https://doi.org/10.1016/j.atmosenv.2014.06.049, 2014. a, b
Staniaszek, Z., Hauglustaine, D., Cohen, Y., Matthes, S., Skowron, A., Thor, R., and Lund, M. T.: Dependence of future aviation NOx impacts on background conditions, in preparation, 2025.
Stordal, F., Isaksen, I. S. A., and Horntveth, K.: A diabatic circulation two-dimensional model with photochemistry: Simulations of ozone and long-lived tracers with surface sources, J. Geophys. Res.-Atmos., 90, 5757–5776, https://doi.org/10.1029/JD090iD03p05757, 1985. a
Stratmann, G., Ziereis, H., Stock, P., Brenninkmeijer, C., Zahn, A., Rauthe-Schöch, A., Velthoven, P., Schlager, H., and Volz-Thomas, A.: NO and NOy in the upper troposphere: Nine years of CARIBIC measurements onboard a passenger aircraft, Atmos. Environ., 133, 93–111, https://doi.org/10.1016/j.atmosenv.2016.02.035, 2016. a, b, c, d
Terrenoire, E., Hauglustaine, D. A., Cohen, Y., Cozic, A., Valorso, R., Lefèvre, F., and Matthes, S.: Impact of present and future aircraft NOx and aerosol emissions on atmospheric composition and associated direct radiative forcing of climate, Atmos. Chem. Phys., 22, 11987–12023, https://doi.org/10.5194/acp-22-11987-2022, 2022. a, b
Thor, R. N., Mertens, M., Matthes, S., Righi, M., Hendricks, J., Brinkop, S., Graf, P., Grewe, V., Jöckel, P., and Smith, S.: An inconsistency in aviation emissions between CMIP5 and CMIP6 and the implications for short-lived species and their radiative forcing, Geosci. Model Dev., 16, 1459–1466, https://doi.org/10.5194/gmd-16-1459-2023, 2023. a, b
Thouret, V., Marenco, A., Logan, J. A., Nédélec, P., and Grouhel, C.: Comparisons of ozone measurements from the MOZAIC airborne program and the ozone sounding network at eight locations, J. Geophys. Res., 103, 25695–25720, https://doi.org/10.1029/98JD02243, 1998. a
Thouret, V., Cammas, J.-P., Sauvage, B., Athier, G., Zbinden, R., Nédélec, P., Simon, P., and Karcher, F.: Tropopause referenced ozone climatology and inter-annual variability (1994–2003) from the MOZAIC programme, Atmos. Chem. Phys., 6, 1033–1051, https://doi.org/10.5194/acp-6-1033-2006, 2006. a
Tiedtke, M.: A comprehensive mass flux scheme for cumulus parameterization in large-scale models, Mon. Weather Rev., 117, 1779–1800, https://doi.org/10.1175/1520-0493(1989)117<1779:ACMFSF>2.0.CO;2, 1989. a
Tilmes, S., Pan, L. L., Hoor, P., Atlas, E., Avery, M. A., Campos, T., Christensen, L. E., Diskin, G. S., Gao, R.-S., Herman, R. L., Hintsa, E. J., Loewenstein, M., Lopez, J., Paige, M. E., Pittman, J. V., Podolske, J. R., Proffitt, M. R., Sachse, G. W., Schiller, C., Schlager, H., Smith, J., Spelten, N., Webster, C., Weinheimer, A., and Zondlo, M. A.: An aircraft-based upper troposphere lower stratosphere O3, CO, and H2O climatology for the Northern Hemisphere, J. Geophys. Res.-Atmos., 115, D14303, https://doi.org/10.1029/2009JD012731, 2010. a
Tilmes, S., Lamarque, J.-F., Emmons, L. K., Kinnison, D. E., Marsh, D., Garcia, R. R., Smith, A. K., Neely, R. R., Conley, A., Vitt, F., Val Martin, M., Tanimoto, H., Simpson, I., Blake, D. R., and Blake, N.: Representation of the Community Earth System Model (CESM1) CAM4-chem within the Chemistry-Climate Model Initiative (CCMI), Geosci. Model Dev., 9, 1853–1890, https://doi.org/10.5194/gmd-9-1853-2016, 2016. a
van Marle, M. J. E., Kloster, S., Magi, B. I., Marlon, J. R., Daniau, A.-L., Field, R. D., Arneth, A., Forrest, M., Hantson, S., Kehrwald, N. M., Knorr, W., Lasslop, G., Li, F., Mangeon, S., Yue, C., Kaiser, J. W., and van der Werf, G. R.: Historic global biomass burning emissions for CMIP6 (BB4CMIP) based on merging satellite observations with proxies and fire models (1750–2015), Geosci. Model Dev., 10, 3329–3357, https://doi.org/10.5194/gmd-10-3329-2017, 2017. a
Volz-Thomas, A., Berg, M., Heil, T., Houben, N., Lerner, A., Petrick, W., Raak, D., and Pätz, H.-W.: Measurements of total odd nitrogen (NOy) aboard MOZAIC in-service aircraft: instrument design, operation and performance, Atmos. Chem. Phys., 5, 583–595, https://doi.org/10.5194/acp-5-583-2005, 2005. a
Walters, D., Baran, A. J., Boutle, I., Brooks, M., Earnshaw, P., Edwards, J., Furtado, K., Hill, P., Lock, A., Manners, J., Morcrette, C., Mulcahy, J., Sanchez, C., Smith, C., Stratton, R., Tennant, W., Tomassini, L., Van Weverberg, K., Vosper, S., Willett, M., Browse, J., Bushell, A., Carslaw, K., Dalvi, M., Essery, R., Gedney, N., Hardiman, S., Johnson, B., Johnson, C., Jones, A., Jones, C., Mann, G., Milton, S., Rumbold, H., Sellar, A., Ujiie, M., Whitall, M., Williams, K., and Zerroukat, M.: The Met Office Unified Model Global Atmosphere 7.0/7.1 and JULES Global Land 7.0 configurations, Geosci. Model Dev., 12, 1909–1963, https://doi.org/10.5194/gmd-12-1909-2019, 2019. a, b
Wuebbles, D. J., Patten, K. O., Wang, D., Youn, D., Martínez-Avilés, M., and Francisco, J. S.: Three-dimensional model evaluation of the Ozone Depletion Potentials for n-propyl bromide, trichloroethylene and perchloroethylene, Atmos. Chem. Phys., 11, 2371–2380, https://doi.org/10.5194/acp-11-2371-2011, 2011. a
Young, P. J., Naik, V., Fiore, A. M., Gaudel, A., Guo, J., Lin, M. Y., Neu, J. L., Parrish, D. D., Rieder, H. E., Schnell, J. L., Tilmes, S., Wild, O., Zhang, L., Ziemke, J. R., Brandt, J., Delcloo, A., Doherty, R. M., Geels, C., Hegglin, M. I., Hu, L., Im, U., Kumar, R., Luhar, A., Murray, L., Plummer, D., Rodriguez, J., Saiz-Lopez, A., Schultz, M. G., Woodhouse, M. T., and Zeng, G.: Tropospheric Ozone Assessment Report: Assessment of global-scale model performance for global and regional ozone distributions, variability, and trends, Elem. Sci. Anth., 6, https://doi.org/10.1525/elementa.265, 2018. a
Zahn, A., Weppner, J., Widmann, H., Schlote-Holubek, K., Burger, B., Kühner, T., and Franke, H.: A fast and precise chemiluminescence ozone detector for eddy flux and airborne application, Atmos. Meas. Tech., 5, 363–375, https://doi.org/10.5194/amt-5-363-2012, 2012. a
Zahn, A., Christner, E., van Velthoven, P. F. J., Rauthe-Schöch, A., and Brenninkmeijer, C. A. M.: Processes controlling water vapor in the upper troposphere/lowermost stratosphere: An analysis of 8 years of monthly measurements by the IAGOS-CARIBIC observatory, J. Geophys. Res.-Atmos., 119, 11505–11525, https://doi.org/10.1002/2014JD021687, 2014. a, b, c, d
Zhang, G. J. and McFarlane, N. A.: Sensitivity of climate simulations to the parameterization of cumulus convection in the Canadian climate centre general circulation model, Atmos.-Ocean, 33, 407–446, https://doi.org/10.1080/07055900.1995.9649539, 1995. a
Ziereis, H., Schlager, H., Schulte, P., van Velthoven, P. F. J., and Slemr, F.: Distributions of NO, NOx, and NOy in the upper troposphere and lower stratosphere between 28° and 61° N during POLINAT 2, J. Geophys. Res.-Atmos., 105, 3653–3664, https://doi.org/10.1029/1999JD900870, 2000. a
Short summary
The chemical composition of the atmosphere near the tropopause is a key parameter for evaluating the climate impact of subsonic aviation pollutants. This study uses in situ data collected aboard passenger aircraft to assess the ability of four chemistry–climate models to reproduce (bi-)decadal climatologies of ozone, carbon monoxide, water vapour, and reactive nitrogen in this region. The models reproduce the very distinct ozone seasonality in the upper troposphere and in the lower stratosphere well.
The chemical composition of the atmosphere near the tropopause is a key parameter for evaluating...
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