Articles | Volume 17, issue 7
Atmos. Chem. Phys., 17, 4641–4655, 2017
Atmos. Chem. Phys., 17, 4641–4655, 2017
Research article
10 Apr 2017
Research article | 10 Apr 2017

Changing trends and emissions of hydrochlorofluorocarbons (HCFCs) and their hydrofluorocarbon (HFCs) replacements

Peter G. Simmonds et al.

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Cited articles

AFEAS (Alternative Fluorocarbons Environmental Acceptability Study): Production and Use of Fluorocarbons, available at:, last access: May 2016.
Arnold, T., Mühle, J., Salameh, P. K., Harth, C. M., Ivy, D. J., and Weiss, R. F.: Automated measurement of nitrogen trifluoride in ambient air, Anal. Chem., 84, 4798–4804, 2012.
Ashford, P., Clodic, D., McCulloch, A., and Kuijpers, L.: Emission profiles from the foam and refrigeration sectors comparison with atmospheric concentrations. Part 1: Methodology and data, Int. J. Refrig., 27, 687–700, 2004.
Carpenter, L., Reimann, S., Burkholder, J., Clerbaux, C., Hall, B., Hossaini, R., Laube, J., Yvon-Lewis, S., Blake, D., Dorf, M., Dutton, G., Fraser, P., Froidevaux, L., Hendrick, F., Hu, J., Jones, A., Krummel, P., Kuijpers, L., Kurylo, M., Laing, Q., Mahieu, E., Muhle, J., O'Doherty, S., Ohnishi, K., Orkin, V., Pfeilsticker, K., Rigby, M., Simpson, I., and Yokouchi, Y.: Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, Chapter 1 in Scientific Assessment of Ozone Depletion: 2014, Global Ozone Research and Monitoring Project – Report No. 55, 1.1–1.101, World Meteorological Organization, Geneva, Switzerland, 2014.
Cunnold, D. M., Prinn, R. G., Rasmussen, R., Simmonds, P. G., Alyea, F. N., Cardlino, C., Crawford, A. J., Fraser, P. J., and Rosen, R.: The Atmospheric Lifetime Experiment, III: lifetime methodology and application to three years of CFCl3 data, J. Geophys. Res., 88, 8379–8400, 1983.
Short summary
This paper reports how long-term atmospheric measurements demonstrate that the Montreal Protocol has been effective in controlling production and consumption of the hydrochlorofluorocarbons, a group of industrial chemicals that have detrimental effects on the ozone layer and also contribute to global warming as greenhouse gases and their hydrofluorocarbon substitutes which are also potent greenhouse gases but do not materially affect the ozone layer.
Final-revised paper