Articles | Volume 16, issue 23
Atmos. Chem. Phys., 16, 15397–15412, 2016
Atmos. Chem. Phys., 16, 15397–15412, 2016

Research article 12 Dec 2016

Research article | 12 Dec 2016

Heterogeneous reaction of ClONO2 with TiO2 and SiO2 aerosol particles: implications for stratospheric particle injection for climate engineering

Mingjin Tang et al.

Related authors

Measurement report: Emissions of intermediate-volatility organic compounds from vehicles under real-world driving conditions in an urban tunnel
Hua Fang, Xiaoqing Huang, Yanli Zhang, Chenglei Pei, Zuzhao Huang, Yujun Wang, Yanning Chen, Jianhong Yan, Jianqiang Zeng, Shaoxuan Xiao, Shilu Luo, Sheng Li, Jun Wang, Ming Zhu, Xuewei Fu, Zhenfeng Wu, Runqi Zhang, Wei Song, Guohua Zhang, Weiwei Hu, Mingjin Tang, Xiang Ding, Xinhui Bi, and Xinming Wang
Atmos. Chem. Phys. Discuss.,,, 2021
Preprint under review for ACP
Short summary
Interactions of organosulfates with water vapor under sub- and supersaturated conditions
Chao Peng, Patricia N. Razafindrambinina, Kotiba A. Malek, Lanxiadi Chen, Weigang Wang, Ru-Jin Huang, Yuqing Zhang, Xiang Ding, Maofa Ge, Xinming Wang, Akua A. Asa-Awuku, and Mingjin Tang
Atmos. Chem. Phys. Discuss.,,, 2021
Revised manuscript accepted for ACP
Short summary
Tropospheric aerosol hygroscopicity in China
Chao Peng, Yu Wang, Zhijun Wu, Lanxiadi Chen, Ru-Jin Huang, Weigang Wang, Zhe Wang, Weiwei Hu, Guohua Zhang, Maofa Ge, Min Hu, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 20, 13877–13903,,, 2020
On mineral dust aerosol hygroscopicity
Lanxiadi Chen, Chao Peng, Wenjun Gu, Hanjing Fu, Xing Jian, Huanhuan Zhang, Guohua Zhang, Jianxi Zhu, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 20, 13611–13626,,, 2020
Short summary
High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium
Guohua Zhang, Xiufeng Lian, Yuzhen Fu, Qinhao Lin, Lei Li, Wei Song, Zhanyong Wang, Mingjin Tang, Duohong Chen, Xinhui Bi, Xinming Wang, and Guoying Sheng
Atmos. Chem. Phys., 20, 1469–1481,,, 2020
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant
J. Eric Klobas and David M. Wilmouth
Atmos. Chem. Phys., 19, 6205–6215,,, 2019
Short summary
Global warming potential estimates for the C1–C3 hydrochlorofluorocarbons (HCFCs) included in the Kigali Amendment to the Montreal Protocol
Dimitrios K. Papanastasiou, Allison Beltrone, Paul Marshall, and James B. Burkholder
Atmos. Chem. Phys., 18, 6317–6330,,, 2018
Short summary
UV and infrared absorption spectra, atmospheric lifetimes, and ozone depletion and global warming potentials for CCl2FCCl2F (CFC-112), CCl3CClF2 (CFC-112a), CCl3CF3 (CFC-113a), and CCl2FCF3 (CFC-114a)
Maxine E. Davis, François Bernard, Max R. McGillen, Eric L. Fleming, and James B. Burkholder
Atmos. Chem. Phys., 16, 8043–8052,,, 2016
Short summary
Heterogeneous reaction of N2O5 with airborne TiO2 particles and its implication for stratospheric particle injection
M. J. Tang, P. J. Telford, F. D. Pope, L. Rkiouak, N. L. Abraham, A. T. Archibald, P. Braesicke, J. A. Pyle, J. McGregor, I. M. Watson, R. A. Cox, and M. Kalberer
Atmos. Chem. Phys., 14, 6035–6048,,, 2014
Rate coefficients for the reaction of O(1D) with the atmospherically long-lived greenhouse gases NF3, SF5CF3, CHF3, C2F6, c-C4F8, n-C5F12, and n-C6F14
M. Baasandorj, B. D. Hall, and J. B. Burkholder
Atmos. Chem. Phys., 12, 11753–11764,,, 2012

Cited articles

Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228,, 2013.
Anderson, L. C. and Fahey, D. W.: Studies with ClONO2: Thermal-dissociation rate and catalytic conversion to NO using an NO/O3 chemi-luminescence detector, J. Phys. Chem., 94, 644–652, 1990.
Ball, S. M., Fried, A., Henry, B. E., and Mozurkewich, M.: The hydrolysis of ClONO2 on sub-micron liquid sulfuric acid aerosol, Geophys. Res. Lett., 25, 3339–3342, 1998.
Ballard, J., Johnston, W. B., Gunson, M. R., and Wassell, P. T.: Absolute absorption coefficients of ClONO2 infrared bands at stratospheric temperatures, J. Geophys. Res.-Atmos, 93, 1659–1665, 1988.
Short summary
We have investigated for the first time the heterogeneous hydrolysis of ClONO2 on TiO2 and SiO2 aerosol particles at room temperature and at different relative humidities (RHs), using an aerosol flow tube. The kinetic data reported in our current and previous studies have been included in the UKCA chemistry–climate model to assess the impact of TiO2 injection on stratospheric chemistry and stratospheric ozone in particular.
Final-revised paper