Articles | Volume 16, issue 23
https://doi.org/10.5194/acp-16-15397-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-15397-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
12 Dec 2016
Research article |
| 12 Dec 2016
Heterogeneous reaction of ClONO2 with TiO2 and SiO2 aerosol particles: implications for stratospheric particle injection for climate engineering
Mingjin Tang
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
School of Earth Sciences, University of Bristol, Bristol BS8 1RJ, UK
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
James Keeble
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
Paul J. Telford
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
National Centre for Atmospheric Science, NCAS, Cambridge, UK
Francis D. Pope
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Birmingham B15 2TT, UK
Peter Braesicke
IMK-ASF, Karlsruhe Institute of Technology, Karlsruhe, Germany
Paul T. Griffiths
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
National Centre for Atmospheric Science, NCAS, Cambridge, UK
N. Luke Abraham
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
National Centre for Atmospheric Science, NCAS, Cambridge, UK
James McGregor
Department of Chemical and Biological Engineering, University of
Sheffield, Sheffield S1 3JD, UK
I. Matt Watson
School of Earth Sciences, University of Bristol, Bristol BS8 1RJ, UK
R. Anthony Cox
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
John A. Pyle
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
National Centre for Atmospheric Science, NCAS, Cambridge, UK
Markus Kalberer
CORRESPONDING AUTHOR
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK
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- Heterogeneous reaction of HO<sub>2</sub> with airborne TiO<sub>2</sub> particles and its implication for climate change mitigation strategies D. Moon et al. 10.5194/acp-18-327-2018
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- The potential environmental and climate impacts of stratospheric aerosol injection: a review H. Huynh & V. McNeill 10.1039/D3EA00134B
- Comprehensive exploration of the ultraviolet degradation of polychlorinated biphenyls in different media C. Huang et al. 10.1016/j.scitotenv.2020.142590
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- Response of Surface Ultraviolet and Visible Radiation to Stratospheric SO2 Injections S. Madronich et al. 10.3390/atmos9110432
- Measurements of HO2 uptake coefficient on aqueous (NH4)2SO4 aerosol using aerosol flow tube with LIF system Q. Zou et al. 10.1016/j.cclet.2019.07.041
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Heterogeneous reactions of mineral dust aerosol: implications for tropospheric oxidation capacity M. Tang et al. 10.5194/acp-17-11727-2017
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- Experimental reaction rates constrain estimates of ozone response to calcium carbonate geoengineering Z. Dai et al. 10.1038/s43247-020-00058-7
14 citations as recorded by crossref.
- Photochemical formation of hydroxylated polychlorinated biphenyls (OH-PCBs) from decachlorobiphenyl (PCB-209) on solids/air interface C. Li et al. 10.1016/j.jhazmat.2019.120758
- The adsorption and oxidation of SO2on MgO surface: experimental and DFT calculation studies H. Wang et al. 10.1039/C9EN01474H
- Heterogeneous reaction of HO<sub>2</sub> with airborne TiO<sub>2</sub> particles and its implication for climate change mitigation strategies D. Moon et al. 10.5194/acp-18-327-2018
- Technical note: Determination of binary gas-phase diffusion coefficients of unstable and adsorbing atmospheric trace gases at low temperature – arrested flow and twin tube method S. Langenberg et al. 10.5194/acp-20-3669-2020
- The potential environmental and climate impacts of stratospheric aerosol injection: a review H. Huynh & V. McNeill 10.1039/D3EA00134B
- Comprehensive exploration of the ultraviolet degradation of polychlorinated biphenyls in different media C. Huang et al. 10.1016/j.scitotenv.2020.142590
- Formation of hydroxylated derivatives and coupling products from the photochemical transformation of polyfluorinated dibenzo-p-dioxins (PFDDs) on silica surfaces R. Qu et al. 10.1016/j.chemosphere.2019.05.074
- Chlorine nitrate in the atmosphere T. von Clarmann & S. Johansson 10.5194/acp-18-15363-2018
- A fully coupled solid-particle microphysics scheme for stratospheric aerosol injections within the aerosol–chemistry–climate model SOCOL-AERv2 S. Vattioni et al. 10.5194/gmd-17-7767-2024
- Response of Surface Ultraviolet and Visible Radiation to Stratospheric SO2 Injections S. Madronich et al. 10.3390/atmos9110432
- Measurements of HO2 uptake coefficient on aqueous (NH4)2SO4 aerosol using aerosol flow tube with LIF system Q. Zou et al. 10.1016/j.cclet.2019.07.041
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Heterogeneous reactions of mineral dust aerosol: implications for tropospheric oxidation capacity M. Tang et al. 10.5194/acp-17-11727-2017
- Diagnosing the radiative and chemical contributions to future changes in tropical column ozone with the UM-UKCA chemistry–climate model J. Keeble et al. 10.5194/acp-17-13801-2017
1 citations as recorded by crossref.
Discussed (preprint)
Latest update: 20 Nov 2024
Short summary
We have investigated for the first time the heterogeneous hydrolysis of ClONO2 on TiO2 and SiO2 aerosol particles at room temperature and at different relative humidities (RHs), using an aerosol flow tube. The kinetic data reported in our current and previous studies have been included in the UKCA chemistry–climate model to assess the impact of TiO2 injection on stratospheric chemistry and stratospheric ozone in particular.
We have investigated for the first time the heterogeneous hydrolysis of ClONO2 on TiO2 and SiO2...
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