Articles | Volume 17, issue 8
https://doi.org/10.5194/acp-17-5331-2017
https://doi.org/10.5194/acp-17-5331-2017
Research article
 | 
25 Apr 2017
Research article |  | 25 Apr 2017

Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor

Brett B. Palm, Pedro Campuzano-Jost, Douglas A. Day, Amber M. Ortega, Juliane L. Fry, Steven S. Brown, Kyle J. Zarzana, William Dube, Nicholas L. Wagner, Danielle C. Draper, Lisa Kaser, Werner Jud, Thomas Karl, Armin Hansel, Cándido Gutiérrez-Montes, and Jose L. Jimenez

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Cited articles

Alvarado, A., Arey, J., and Atkinson, R.: Kinetics of the Gas-Phase Reactions of OH and NO3 Radicals and O3 with the Monoterpene Reaction Products Pinonaldehyde, Caronaldehyde, and Sabinaketone, J. Atmos. Chem., 31, 281–297, https://doi.org/10.1023/A:1006010915971, 1998.
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Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, 197–219, https://doi.org/10.1016/S1352-2310(03)00391-1, 2003.
Atkinson, R. and Aschmann, S. M.: Atmospheric chemistry of the monoterpene reaction products nopinone, camphenilone, and 4-acetyl-1-methylcyclohexene, J. Atmos. Chem., 16, 337–348, https://doi.org/10.1007/BF01032629, 1993.
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Short summary
Ambient forest air was oxidized by OH, O3, or NO3 inside an oxidation flow reactor, leading to formation of particulate matter from any gaseous precursors found in the air. Closure was achieved between the amount of particulate mass formed from O3 and NO3 oxidation and the amount predicted from speciated gaseous precursors, which was in contrast to previous results for OH oxidation (Palm et al., 2016). Elemental analysis of the particulate mass formed in the reactor is presented.
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